ALBERT

Description: Two foraminiferal assemblages are observed in surface sediments of the Elbe estuarv. an Elphidium excavatum assemblaae and an Ahmonia/Protelphidium assemblage. They are the result of test-size sorting in accordance to the grain size of the sediments. These assemblages of mainly empty tests differ basically from the living population, which is dominated exclusively by E. excavatum. The average test size is decreasing when advancing from the Open sea into the estuary and the living fauna disappears near the entrance of the Kiel Canal. In the dead assemblage the diversity is distinctively higher and the average test size varies with the grain size of the sediment. The assemblages found in plankton tows are nearly identical with those in corresponding bottom samples. This indicates the distribution pattern to be caused by transport in currents (mainly in suspension). This type of foraminiferal assemblages characterize macro- and mesotidal estuaries and might indicate a high tidal range when observed in sediments of fossil estuaries.

Description: Geothermal waters with maximum temperatures of 103°C emanate from two sublacustrine hot spring areas which are located in the northem part of Lake Tanganyika (East African Riftsystem). The hydrothermalism leads to the formation of crust- and stockwork-like massive sulfide bodies on the lake bottom to a maximum water depth of 46 m. These geothermal vent areas were investigated and sampled during the German-French TANGANYDRO-campaign in 1991. The aim of this work is to characterize the mineralogy and geochemistry of these sulfides and to reconstruct their genesis. Mineralogical methods that have been used inc1ude scatter electron microscopy (SEM), polarization microscopy, and X-ray diffraction analysis. The geochemical methods inc1ude electron microprobe analysis (EMP) and inductively coupled plasma mass spectrometry (ICP-MS) for the major and trace elements and sulfur isotope measurements in order to determine the d34S-values of the samples. The samples consist exc1usively of iron sulfides. The dominant minerals are marcasite and melnicovite with subordinate pyrite. All samples show collophorm textures indicating their origin from gel-like precursors. They are characterized by high contents of As (up to 3.4 wt%), Sb (up to 0.6 wt%) and Tl (up to 2.6 wt%). Low d34S-values in the range of -11.6 %0 to +2.4 %0 (rel. PDB) indicate bacterial sulfur fractionation. The crystallization of the gel-like precursor leads to the formation of marcasite and pyrite with melnicovite as a transitional phase. Pyrite is formed by the replacement of either melnicovite or marcasite. This mechanism accords to previously postulated models for the formation of iron sulfides in low temperature (〈100°C) hydrothermal systems. A significant sulfur isotope fractionation (increase of d34S) has been observed during the replace- ment of melnicovite by the mature phases marcasite and pyrite. Biogenie impact on the sulfide formation is indicated by low Co/Ni-ratios (〈1), the negative d34S-values and the occurrence of framboidal pyrite. The metabolism of sulfur oxidizing and sulphate reducing bacteria at the wall rock of the vents and in the spring waters is suggested to actively influence the setting of specific pH-values required for the formation of either marcasite or pyrite. The altemating pyrite-marcasite layers are the result of fluctuations in the productivity of those bacteria, which may depend on seasonal variations or changing nutrient support.

Description: Based on foraminiferal transfer-functions, the distribution patterns of early Holocene sea- surface temperatures (SST) were studied, using the information from 154 deep-sea sediment cores (92 Atlantic, 62 Indian Ocean and Western Pacific). For our reconstruction, we employed a uniform high-resolution, AMS 14C-calibrated d18O-chronology, converted to a calendar timescale, and the new SIMMAX-Transfer-Technique in the Atlantic Oceans (Pflaumann et al. in press). The short-term SST fluctuations during the last 30,000 years are not directly related to the relatively slow changes in insolation during this period, reaching maximum seasonal deviations from modern values at approximaterly 11,000 years B.P. Although seasonal changes in solar radiation must have triggered global warming to the modern, interglacial mode, there is little evidence for linear warming and heat transport by ocean currents. The SIMMAX-temperature estimates indicate an early and rapid warming in the Equatorial Atlantic, as well as in the eastern North Atlantic, where modern SSTs were reached for a short time between 20,000 to 16,000 kalendar-years B.P. On a core transect crossing the Island-Faroer Ridge, the history of high-latitude warming along the eastern margins of the big North Atlantic gyres was reconstructed. Prior to the Younger Dryas cold interval (12,000 kalendar years), SSTs of the Norwegian Greenland Sea were still at glacial levels. After the Younger Dryas, there was a rapid inflow of warm Atlantic surface waters into the Norwegian-Greenland basins. In the northern Indian Ocean, the SST-patterns were totally different from the Atlantic during the last 20,000 years. Temperature variations did not exeed 2-3°C in the open ocean. During the Last Glacial Maximum (18,000 years B.P.), temperatures were higher than today whereas they were lowest during the early Holocene. This was caused by changes in the monsoon-induced oceanic upwelling intensity. At this time trade winds off Northwest Africa were also stronger, related to the stronger seasonal constrasts in insolation. Perhaps, the atmospheric circulation was generally enhanced at 10,000 years B.P. High-resolution SST-records from the southern Ocean (Pichon et al. 1992) indicate a slight asymmetry between the two Hemispheres. At 10,000 years B.P, SSTs were 1-2°C higher than today in the southern Indian Ocean. At the same time, somewhat colder SSTs imply still cool, boreal conditions in the middle and high latitudes of the northern hemisphere. Although SSTs of both seasons are only little different from the modern patterns, differences in the direction and strength of the major ocean currents are indicated by internally consistent positive and negative temperature anomaly fields. They were found in both, in the lower and in the high latitudes. The distribution of the anomalies in the North Atlantic further suggests, that the remnants of the ice shields still had a strong impact on the SST distribution. The particulary stronger insolation in the high northern latitudes during summers had nearly no influence. Finally, many details in the SST fluctuations and in the distribution of temperature anomalies imply a more dynamic surface circulation than today which may be the most characteristic difference between the early Holocene and modern surface ocean.

Description: Although they are fossils of uncertain origin, bolboforms are the best calcareous microfossil group for Neogene biostratigraphy in the North Atlantic. Fifty-two Bolboforma species were observed at the Hatton-Rockall Basin in Ocean Drilling Program Holes 982A (26 samples) and 982B (301 samples) and in Deep Sea Drilling Project Hole 116 (71 samples). The sequence investigated spans the interval from lower Miocene to upper Pliocene. Fourteen zones/subzones were identified and correlated with the calcareous nannoplankton zones, the planktonic foraminifer biostratigraphy, and the time (Ma). The last occurrence of the genus Bolboforma can be dated to 2.84 Ma. Different Bolboforma specimens of middle Miocene age, observed in upper Miocene and upper middle Miocene sediments at Site 982, document redeposition of sediment from the Rockall Bank into the Hatton-Rockall Basin during the latest middle Miocene and late Miocene.

Description: The maximum grain sizes of plagioclase and magnetite in the groundmass of the sheeted dike complex drilled at Hole 504B have been measured. Downhole variations through a 440-m-long section show a crude zig-zag pattern consisting of a gradual decrease or increase followed by an abrupt jump. The gradual decrease or increase in grain size extends over many lithologic units, and hence, does not reflect variations in grain size within a single dike. Such a zig-zag pattern is well explained by grain-size variations through multiple dikes. By using the observed inclination of sheeted dikes of 81° ± 2.5°, thickness of the multiple dikes varies from 0.7 to 8.5 m and averages to 4 ± 1 m. The average thickness of individual dikes forming multiple dikes is 0.8 m. We expect such multiple dikes to be formed during rifting events beneath mid-oceanic spreading ridges. If the average expansion at rifting episodes is twice as wide as the average width of the multiple dike units, the full spreading rate of 7.2 cm/yr of Cocos Ridge gives 112 ± 33 yr for a time interval of the rifting. A simple one-dimensional conductive cooling model is applied to solidification of multiple dikes. Numerical simulations show that the grain-size variations observed through the drill hole are more consistent with a model where a new injection of a dike occurs periodically with a constant time interval rather than one where the next dike intrudes just after the solidification of the previous one. Grain-size variations within simple dikes from Iritono, Japan, and those for Makaopuhi lava lake, Hawaii, show that square root of crystallization time is linearly correlated with the logarithm of plagioclase size. By using an empirically derived relationship between these two variables, the variations of plagioclase size through Hole 504B are directly compared with the calculated times for crystallization. Each rifting episode at the Costa Rica Rift lasts for several years, and periodic injection of a new dike occurs into the center of a previously solidified multiple dike at time intervals varying from 1 to 12 months.

Description: Au contents have been determined in 77 samples of basalts and sheeted diabase dikes. Pd has been evaluated in 39 of the samples. The mean amount of Au is 3 parts per billion (ppb), fluctuating from 0.4 to 10 ppb. Au contents appear to be independent in type and intensity of alteration as well as with depth sub-bottom, although in the lower part of Hole 504B, 1900-2000 mbsf, Au contents are markedly decreased (mean: 1.1 ppb) and show a distinct correlation with a decrease in Zn contents. Pd contents vary from 2 to 360 ppb (mean: 37 ppb) Pd is higher in basalts (53.7 ppb) and lower in diabase dikes (30 ppb), especially in moderately or strongly altered ones (12.5 ppb).

Description: The late Paleocene thermal maximum (LPTM) was a dramatic, short-term global warming event that occurred ~55 Ma. Warming of high-latitude surface waters and global deep waters during the LPTM has been well documented; however, current data suggest that subtropical and tropical sea surface temperatures (SSTs) did not change during the event. Conventional paradigms of global climate change, such as CO2-induced greenhouse warming, predict greater warming in the high latitudes than in the tropics or subtropics but, nonetheless, cannot account for the stable tropical/subtropical SSTs. We measured the stable isotope values of well-preserved late Paleocene to early Eocene planktonic foraminifera from South Atlantic Deep Sea Drilling Project (DSDP) Site 527 to evaluate the subtropical response to the climatic and environmental changes of the LPTM. Planktonic foraminiferal d18O values at Site 527 decrease by ~0.94 per mil from pre-LPTM to excursion values, providing the first evidence for subtropical warming during the LPTM. We estimate that subtropical South Atlantic SSTs warmed by at least ~1°-4°C, on the basis of possible changes in evaporation and precipitation. The new evidence for subtropical SST warming supports a greenhouse mechanism for global warming involving elevated atmospheric CO2 levels.