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  • Polymer and Materials Science  (40,892)
  • Organic Chemistry  (9,511)
  • Chemical Engineering  (6,025)
  • Engineering  (4,828)
  • 1995-1999  (22,281)
  • 1980-1984  (22,495)
  • 1970-1974  (16,480)
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  • 1
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Latexes based on styrene-glycidyl methacrylate copolymers were prepared by the emulsifier-free dispersion copolymerization technique. The main factors affecting the size and morphology of the latex particles and their distribution are the initiator concentration (K2S2O8), the total ionic strength of the aqueous phase, and the total monomer concentration. The existence of critical values for these variables was demonstrated. In the range in which these factors had values below the critical, the synthesized latex particles were spherical, homogeneous, and in varied sizes, depending on the abovementioned parameters in the range of 220-500 nm. Above the critical values of these variables the latex particles consisted of spherical aggregates of smaller particles. The reactive oxirane groups of the latex particles were modified later by hydrolysis, ammonolysis, reaction with Na2S, or periodic acid oxidation of the hydrolyzed or ammonolyzed forms of the latex particles.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 595-602 
    ISSN: 0887-6266
    Keywords: demixing ; spinodal quench ; polymer blends ; lower critical solution temperature ; isotope effect ; pressure dependence ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Liquid-liquid demixing, following spinodal quenches of poly-2-chlorostyrene/polystyrene blends, was followed by light scattering at 632.8 nm. The dependences of demixing on H/D substitution and molecular weight of the polystyrene, and on pressure, are reported. In the region of interest, the phase diagram is of the lower critical solution (LCS) type, and demixing is induced by raising the temperature. The transition temperature is lowered by deuterium substitution. At constant quench depth the transition proceeds more rapidly at elevated pressure. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 75-86 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: Two finite element algorithms suitable for long term simulation of geothermal reservoirs are presented. Both methods use a diagonal mass matrix and a Newton iteration scheme. The first scheme solves the 2N unsymmetric algebraic equations resulting from the finite element discretization of the equations governing the flow of heat and mass in porous media by using a banded equation solver. The second method, suitable for problems in which the transmissibility terms are small compared to the accumulation terms, reduces the set of N equations for the Newton corrections to a symmetric system. Comparison with finite difference schemes indicates that the proposed algorithms are competitive with existing methods.
    Additional Material: 7 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 39 (1996), S. 3065-3082 
    ISSN: 0029-5981
    Keywords: biomechanics ; damage ; finite element method ; plasticity ; standard generalized material ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Motivated by mechanical analysis of cancellous bone, a 3D constitutive law describing the simultaneous flow of rate-independent plasticity and damage is developed in the framework of thermodynamics of irreversible processes with internal variables. Following the hypothesis of standard generalized materials, a free energy and a dissipation potential are postulated and the associated flow rules derived with the tools of convex analysis. On the computational side, the classical implicit projection (or catching up) algorithm used in plasticity is extended to account for the additional flow of damage. Due to the existence of a dissipation potential, linearization of the incremental algorithm provides a symmetric tangent operator. Numerical resolutions of several boundary value problems and a biomechanical application are presented to illustrate the potential of the constitutive model and demonstrate the quadratic convergence of the algorithm.
    Additional Material: 10 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 7 (1982), S. 107-109 
    ISSN: 0721-3115
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mixtures of crystalline explosive and water have as a rule detonation properties different from the dry material. It has been shown that the character of those changes is closely related to the structure of the particles (crystals, granules) of the explosives. The critical diameters and detonation velocities have been measured for a range of explosive-water mixtures, and the results are interpreted in terms of the hotspot theory.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 2343-2344 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 43 (1998), S. 733-753 
    ISSN: 0029-5981
    Keywords: extrapolation ; series ; sequences ; binomial power series ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The problem of extrapolation based just on a few initial terms of a sequence or series is discussed. Possible regularity of the extrapolation formula is postulated. Binomial power series is regarded as sufficiently regular and several extrapolation formulae using 3, 4, or 5 initial terms and based on binomial power series are derived. They are called the ‘bs-extrapolation formulae’ and compared to other extrapolation algorithms. Good accuracy in many particular cases is stated. Three examples of applications in mechanics are quoted: they consider consecutive FEM-solutions, postbuckling behaviour of an Euler column and optimal plastic design of a plane T-head. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 67 (1995), S. 1346-1349 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 324 (1982), S. 964-972 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Investigations on the Thermal Decomposition of n-Dodecylcyclopentane in the Gas PhaseIn the thermal decomposition of n-dodecylcyclopentane at 670 and 750°C in a laboratory tubular reactor mixtures of hydrogen and 57 and 113 hydrocarbons respectively are formed. The mixtures have been analyzed and identified by capillary gas chromatography and by mass spectrometry. The distribution of the reaction products is used for mechanistic discussions.
    Additional Material: 2 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 66-74 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kinetic Investigations of the Pyrolysis of Mono-n-alkyl-cyclohexanesThe thermal decomposition of cyclohexane and six mono-n-alkylcyclohexanes was studied kinetically in a metallic laboratory tubular reactor at 650 to 850°C and atmospheric pressure.Kinetic parameters were found to be a function of length of the alkylic side chain. A comparison with analogous parameters of n-paraffins and the unsubstituted cyclohexane allowed the conclusion that C—C-scission in the alkylic chain is the initial reaction in pyrolysis of n-alkylcyclohexanes followed by radical attacks to all C—H-bonds of the feed molecules.
    Additional Material: 4 Ill.
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