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  • Articles  (143)
  • heavy metals  (102)
  • agriculture  (41)
  • 1995-1999  (127)
  • 1990-1994  (16)
  • Energy, Environment Protection, Nuclear Power Engineering  (143)
  • 1
    Electronic Resource
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    Springer
    Risk analysis 18 (1998), S. 563-573 
    ISSN: 1539-6924
    Keywords: Risk assessment ; mourning doves ; hunting ; radionuclides ; heavy metals ; lead shot ; cesium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Recreational and subsistence hunters and anglers consume a wide range of species, including birds, mammals, fish and shellfish, some of which represent significant exposure pathways for environmental toxic agents. This study focuses on the Department of Energy's (DOE's) Savannah River Site (SRS), a former nuclear weapons production facility in South Carolina. The potential risk of contaminant intake from consuming mourning doves (Zenaida macroura), the most popular United States game bird, was examined under various risk scenarios. For all of these scenarios we used the mean tissue concentration of six metals (lead, mercury, cadmium, selenium, chromium, manganese) and radiocesium, in doves collected on and near SRS. We also estimated risk to a child consuming doves that had the maximum contaminant level. We used the cancer slope factor for radiocesium, the Environmental Protection Agencies Uptake/Biokinetic model for lead, and published reference doses for the other metals. As a result of our risk assessments we recommend management of water levels in contaminated reservoirs so that lake bed sediments are not exposed to use by gamebirds and other terrestrial wildlife. Particularly, measures should be taken to insure that the hunting public does not have access to such a site. Our data also indicate that doves on popular hunting areas are exposed to excess lead, suggesting that banning lead shot for doves, as has been done for waterfowl, is desirable.
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  • 2
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    Biodegradation 3 (1992), S. 161-170 
    ISSN: 1572-9729
    Keywords: bioremediation ; cadmium ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Cadmium pollution arises mainly from contamination of minerals used in agriculture and from industrial processes. The usual situation is of large volumes of soil and water that are contaminated with low — but significant — concentrations of cadmium. Therefore, detoxification of the polluted water and soil involves the concentration of the metal, or binding it in a way that makes it biologically inert. Cadmium is one of the more toxic metals, that is also carcinogenic and teratogenic. Its effects are short term, even acute (diseases like Itai-itai), or long term. The long term effects are intensified due to the fact that cadmium accumulates in the body. This paper describes a study involving several hundred cadmium-resistant bacterial isolates. These bacteria could be divided into three groups—the largest group consisted of bacteria resistant to cadmium by effluxing it from the cells. The bacteria of the other two groups were capable of binding cadmium or of detoxifying it. We concentrated on one strain that could bind cadmium very efficiently, depending on the bacterial biomass and on the pH. This strain could effectively remove cadmium from contaminated water and soil.
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  • 3
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    Natural hazards 6 (1992), S. 109-129 
    ISSN: 1573-0840
    Keywords: Drought ; agriculture ; hydrology ; monitoring ; research
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract The 1988 drought conditions, which prevailed over the southern portion of the Canadian prairie provinces, resulted in severe impacts on agriculture, water resources, forestry, and waterfowl production. In this paper, the climatological aspects of the drought are reviewed and the impacts of the drought are described. In addition, a number of the environmental factors that may have aggravated the drought's impacts are discussed. Processes contributing to the 1988 drought are considered in terms of their scales, relative importance and possible effects. It was evident from the information needs of government agencies and private businesses which had to cope with the effects of the 1988 drought, that studies are needed to effectively monitor drought and adjust to its impacts. In this paper, these needs are discussed; several specific hypotheses concerning drought-related processes are advanced and a framework for addressing the scientific aspects of droughts on the Canadian prairies is proposed. It is anticipated that many of these identified research needs and opportunities are applicable to other drought-prone areas of the world.
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  • 4
    ISSN: 1572-9729
    Keywords: acid mine drainage ; algae ; heavy metals ; high rate algal ponds ; sulphate reducing bacteria ; waste stabilisation ponds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Acid mine drainage pollution may be associated with large water volume flows and exceptionally long periods of time over which the drainage may require treatment. While the use and role of sulphate reducing bacteria has been demonstrated in active treatment systems for acid mine drainage remediation, reactor size requirement and the cost and availability of the carbon and electron donor source are factors which constrain process development. Little attention has focussed on the use of waste stabilisation ponding processes for acid mine drainage treatment. Wastewater ponding is a mature technology for the treatment of large water volumes and its use as a basis for appropriate reactor design for acid mine drainage treatment is described including high rates of sulphate reduction and the precipitation of metal sulphides. Together with the co-disposal of organic wastes, algal biomass is generated as an independent carbon source for SRB production. Treatment of tannery effluent in a custom-designed high rate algal ponding process, and its use as a carbon source in the generation and precipitation of metal sulphides, has been demonstrated through piloting to the implementation of a full-scale process.The treatment of both mine drainage and zinc refinery wastewaters are reported. A complementary role for microalgal production in the generation of alkalinity and bioadsorptive removal of metals has been utilised and an Integrated 'Algal Sulphate Reducing Ponding Process for the Treatment of Acidic and Metal Wastewaters' (ASPAM) has been described.
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  • 5
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    Biodegradation 9 (1998), S. 311-318 
    ISSN: 1572-9729
    Keywords: glucosinolates ; gypsum ; heavy metals ; phyto-extraction ; phytoremediation ; sulfate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Sulfur is a major nutrient for all organisms. Plant species have a high biodiversity in uptake, metabolization and accumulation of sulfur so that there are potentials to use plants for phytoremediation of sulfur-enriched sites. A survey of soils enriched with sulfur either naturally or by human activities shows that a surplus of sulfur is mostly accompanied with a surplus of other chemical elements which may limit phytoremediation because these co-occurring elements are more toxic to plants than sulfur. In addition, the accumulation of the other elements makes the plant material (phyto-extraction) less suitable for the use as fodder and for human consumption.
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  • 6
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    Biodegradation 9 (1998), S. 411-422 
    ISSN: 1572-9729
    Keywords: agrochemicals ; heavy metals ; NMR imaging ; NMR spectroscopy ; subcellular compartmentation xenobiotic metabolism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The application of non-invasive nuclear magnetic resonance (NMR) methods in xenobiotic research is reviewed in relation to: (i) the characterisation of the effects of xenobiotics on the metabolism of plants and plant cell suspensions; (ii) the direct detection of xenobiotics and their degradation products in vivo; and (iii) the spatial localisation of xenobiotics and their derivatives at the subcellular and tissue levels. Novel information has been generated by in vivo NMR studies of both agrochemicals and heavy metals, but a lack of generality in the methods makes it difficult to extrapolate from one successful application to the next. In vivo NMR spectroscopy is shown to be informative when a xenobiotic perturbs metabolic pathways that are accessible to the technique, and it is useful for probing the partitioning of paramagnetic metal ions between the cytoplasm and the vacuole. The successful application of 19F NMR to the analysis of plant tissue extracts also suggests that in vivo 19F NMR spectroscopy may have a role in biotransformation studies of fluorinated xenobiotics. In contrast NMR imaging techniques have been little used for xenobiotic research in plants, and while the method has been shown to be capable of monitoring the uptake and translocation of paramagnetic ions in plants, the potential use of high resolution 1H and 19F NMR imaging for mapping agrochemicals in tissues is still in its infancy.
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  • 7
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    Mitigation and adaptation strategies for global change 1 (1996), S. 139-165 
    ISSN: 1573-1596
    Keywords: Adaptation ; agriculture ; agroforestry ; climate change ; drought ; ecological degradation ; factor bias ; Senegal ; sustainability ; social relations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract The ongoing drought in the Sahel region of West Africa highlights the vulnerability of food-producing systems to climate change and variability. Adaptation to climate should therefore increase the sustainability of agriculture under a long-term drought. Progress towards sustainability and adaptation in the the Senegal River Basin is hampered by an existing set of social and ecological relationships that define the control over the means of production and how people interact with their environment. These relationships are sensitive to the technological inputs and the administration of food production, or the factor bias in the different policy alternatives for rural development. One option is based on state-controlled, irrigated plantations to provide rice (Oryza) for the capital, Dakar. This policy emphasizes a top-down management approach, mechanized agriculture and a reliance on external inputs which strengthens the relationships introduced during the colonial period. A time series decomposition of the annual flow in the Senegal River at Bakel in Senegal suggests that water resources availability has been substantially curtailed since 1960, and a review of the water resources budget or availability in the basin suggests that this policy's food production system is not sustainable under the current climate of the basin. Under these conditions, this program is exacerbating existing problems of landscape degradation and desertification, which increases rural poverty. A natural resource management policy offers two adaptation strategies that favour decentralized management and a reduction of external inputs. The first alternative, “Les Perimetres Irrigués”, emphasizes village-scale irrigation, low water consumption cereal crops and traditional socio-political structures. The second alternative emphasizes farm-level irrigation and agro-forestry projects to redress the primary effects of desertification. The water requirements of both the rice import substitution program and the natural resource management program are calculated. A water resources simulation model/optimization analysis using dynamic programming is used to compare these two alternatives to the rice import substitution programs. Results indicate that the natural resource management policy could potentially bring a large area into production while using far less water than the rice import substitution program. The natural resource management policy, in particular the second alternative with its emphasis on individual ownership and ecological rehabiliation, defines a different set of social and ecological relationships that appear to enhance the sustainability of food production under a long-term drought.
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  • 8
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    Mitigation and adaptation strategies for global change 2 (1997), S. 19-44 
    ISSN: 1573-1596
    Keywords: adaptation ; Africa ; agriculture ; climate change ; vulnerability ; water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract The intersection of present vulnerability and the prospect of climate change in Africa warrants proactive action now to reduce the risk of large-scale, adverse impacts. The process of planning adaptive strategies requires a systematic evaluation of priorities and constraints, and the involvement of stakeholders. An overview of climate change in Africa and case studies of impacts for agriculture and water underlie discussion of a typology of adaptive responses that may be most effective for different stakeholders. The most effective strategies are likely to be to reduce present vulnerability and to enhance a broad spectrum of capacity in responding to environmental, resource and economic perturbations. In some cases, such as design of water systems, an added risk factor should be considered.
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  • 9
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    Mitigation and adaptation strategies for global change 2 (1997), S. 19-44 
    ISSN: 1573-1596
    Keywords: adaptation ; Africa ; agriculture ; climate change ; vulnerability ; water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract The intersection of present vulnerability and the prospect of climate change in Africa warrants proactive action now to reduce the risk of large-scale, adverse impacts. The process of planning adaptive strategies requires a systematic evaluation of priorities and constraints, and the involvement of stakeholders. An overview of climate change in Africa and case studies of impacts for agriculture and water underlie discussion of a typology of adaptive responses that may be most effective for different stakeholders. The most effective strategies are likely to be to reduce present vulnerability and to enhance a broad spectrum of capacity in responding to environmental, resource and economic perturbations. In some cases, such as design of water systems, an added risk factor should be considered.
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  • 10
    ISSN: 1573-2932
    Keywords: acid deposition ; heavy metals ; cadmium ; soil contamination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Simultaneous soil acidification and deposition of heavy metals is a major concern for forest and agricultural soils of the Black Triangle region of East Central Europe including southern former East Germany, northern Bohemia of the Czech Republic, and southern Poland. The objective of this project was to develop historical and future projections of acid and heavy metal deposition to soils (As, Cd, Pb, Zn) and to produce a preliminary map of soil sensitivity to cadmium pollution and uptake by crops. Ultimately, we wish to assess the relative hazard and recovery times of soils to metals deposition in the region. Emission and deposition data bases obtained from several models developed at IIASA were linked using the Geographical Information System ARC/INFO to produce soil maps of sensitivity to cadmium mobility based on metals deposition, soil type, soil texture, organic matter content, and acid deposition. RAINS 6.1 (Alcamo et al., 1990) was utilized to produce maps of acid deposition for EMEP grids (150 km x 150 km). The largest amount of acid load is deposited in southern East Germany. Sulfur deposition in that area was 10–12 gS/m2/yr in 1990, and S+N deposition exceeded 8000 eq/ha/yr. But the “hot spot” for metals deposition is further to the east, in the Silesia area of southern Poland. The TRACE2 trajectory model of Alcamo, Bartnicki, and Olendrzynski (1992) was used to estimate cumulative metals deposition since 1955 with scenarios to 2010. Pb has improved over Europe since 1970 when depositions in the Ruhr River Valley of West Germany exceeded 60 mg/m2/yr. But cadmium deposition in southern Poland (Katowice and Krakow) has now accumulated to 60–70 mg/m2 by atmospheric deposition alone. During base case simulations from 1955–87, approximately 1.8 mg/kg Pb and 0.12 mg/kg Cd have been added to the mixed plow-layer of ∼30 cm. If these emissions continue indefinitely, the accumulation of metals will become problematic for agriculture and the food chain.
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  • 11
    ISSN: 1573-2932
    Keywords: Pulp and paper mill sludge ; nitrogen ; DOC ; heavy metals ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Primary sludge, secondary sludge, and wood ash from a pulp and paper mill were combined with sand to create a synthetic topsoil (C:N ratio of 18:1) to restore an abandoned gravel pit. Synthetic topsoil was applied to field microcosms at rates equivalent to 0, 2170, 4341, or 6511 kg N/ha; each was seeded with grass. Fifteen chemical constituents in leachate were measured during two field seasons. Cadmium, Ni and Zn were mobilized rapidly by soil disturbance. Chloride and SO4-S eluted rapidly from the sludge along with Na. Nitrate leached with Ca late in each field season when sludge N-mineralization and nitrification exceeded plant uptake and microbial immobilization. Ammonium elution was negligible. Dissolved organic carbon (DOC) was mobilized by decomposition of organic matter in the sludge, as were Mg and K. Copper eluted with DOC, probably as an organic ligand. Lead and ortho-P were below our detection limits. We concluded that a synthetic topsoil with a 30:1 C:N ratio applied at a rate of 2100-4300 kg N/ha should provide adequate plant nutrition while minimizing water quality hazards.
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  • 12
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    Water, air & soil pollution 89 (1996), S. 317-335 
    ISSN: 1573-2932
    Keywords: Soil remediation ; extraction ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Effective remediation and sanitation technologies for soils contaminated with heavy metals are limited. We investigated the feasibility of a counter-current metal extraction procedure for the removal of selected heavy metals (Cd, Cu, Ph, and Zn) from two contaminated soils. The process involved a decarbonation (removal of carbonates), acid solubilisation, washing, and liming step. Results from batch equilibration experiments simulating the counter-current process showed more than 85% of the Cd present to be removed. Removal efficiencies for Cu and Pb were limited to approximately 15%, this mainly due to resorption of these elements during the decarbonation step. As most Zn was found to be present in a more difficult acid-extractable solid phase, its extractability accounted for only 25%. While reaction (pH) conditions of both decarbonation and solubilisation determined removal efficiencies, washing the extracted soil with deionized water only slightly increased the amount of metals removed. Metal distribution among solid phases — exchangeable, carbonate, reducible, organically bound, and residual — was affected by the different treatments. The amount of metals contained in the exchangeable and residual fractions determined their extractability. Except for Cu, the reducible and organically bound fractions were less important. After solubilisation 13 to 70% of the metals were present in an exchangeable solid phase. This implicates that washing the solubilized soil with a salt may increase the extractability of metals, especially for Zn and Pb. Based on our results the process is critically evaluated and possibilities for optimization formulated.
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  • 13
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    Water, air & soil pollution 90 (1996), S. 531-542 
    ISSN: 1573-2932
    Keywords: heavy metals ; smelting ; soil contamination ; plant contamination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Forms of Cu, Ni, and Zn in the contaminated soils of the Sudbury mining/smelting district were studied to assess metal mobility and plant availability. Soil, tufted grass (Deschampsia caespitosa (L.) Beauv.), tickle grass (Agrostis scabra Willd.), dwarf birch (Betula pumila L. var. glandulifera Regel) and white birch (Betula paprifera Marsh.) leaf and twig samples were taken from 20 locations around three Cu-Ni smelters. The sampling sites were collected to cover a wide range of soil pH and soil Cu and Ni concentrations. The water-soluble, exchangeable, sodium acetate-soluble, and total concentrations of the metals in the soils were analyzed. The soils were contaminated with Cu and Ni up to 2000 µg g−1. Zinc concentrations were also elevated in some samples above the normal soil level of 100 µg g−1. The mobility of Cu and Zn, expressed as the proportion of metals in Fl and F2 forms, increased with soil pH decrease. A strong positive correlation was found between the soil exchangeable (F2) Ni and the soil pH. Concentrations of Cu and Ni in birch twigs showed a good linear relationship with exchangeable forms of the metals in soils. A highly significant correlation was also found between total Ni in soils and the metal content of the twigs. No significant correlation was found between Zn concentrations in the soils and plants. Birch twigs are a good indicator (better than leaves) of Cu and Ni contamination of the Sudbury soils. The mobile forms of Cu and Ni and low pH seem to be the main factors that will control the success of revegetation. Strong variability of the soil metal mobility requires any reclamation effort be site-specific.
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  • 14
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    Water, air & soil pollution 90 (1996), S. 543-556 
    ISSN: 1573-2932
    Keywords: heavy metals ; solubility ; redox potential ; pH ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract To assess the mobilities of Pb, Cd, and Zn from a contaminated soil, the effects of redox potential and pH value on metal solubilities were investigated. Both redox potential and pH were found to greatly affect heavy metal solubility in the soil. Results showed that the soil suspension under continuous oxygen aeration for 21 days resulted in increases of redox potential from 290 to 440 mV and pH value from 6.9 to 7.0, respectively. Soluble concentrations of Pb, Cd, and Zn varied with time, and were all lower than 1 mg kg−1. When the soil suspension was aerated with nitrogen, final redox potential was −140 mV and pH value of 7.1. The soluble metal concentrations were slightly higher than those aerated with oxygen. The equilibrium solubility experiments were conducted under three different pH values (3.3, 5.0, 8.0) and three redox potential (325, 0, −100 mV). Results showed that metals were sparingly soluble under alkaline conditions (pH = 8.0). Metal solubilities were higher when under slightly acidic conditions (pH = 5.0), and increased drastically when pH was kept at 3.3. When solubilities were compared under same pH values, it was observed that metal solubilities increased as redox potential decreased. Generally speaking, acidic and reducing conditions were most favorable for metal solubilization, and the effect of pH was more significant than that of redox potential. It was proposed that heavy metals were mostly adsorbed onto Fe-Mn oxyhydroxides. The pH-dependent metal adsorption reaction and the dissolution of Fe-Mn oxyhydroxides under reducing conditions was the mechanism controlling the release of heavy metals from soils.
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  • 15
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    Water, air & soil pollution 93 (1997), S. 395-408 
    ISSN: 1573-2932
    Keywords: air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsula were surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kola smelters were on an average twice as high as on the Finnish side of the border. The Cu and Ni concentrations near the smelters were almost 100-fold the mean values in northern Finland. There was a marked decrease in the sulphur and heavy metal concentrations with increasing distance from the emission sources. The effects of emission from the Kola Peninsula were evident in Finland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland) where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur and heavy metal concentrations in most of northern Finland were low. However were the concentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissions from the Tornio refined steel plants.
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  • 16
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    Water, air & soil pollution 93 (1997), S. 409-417 
    ISSN: 1573-2932
    Keywords: CO2 evolution ; heavy metals ; loading effect ; metal equivalent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a laboratory study the effects on soil respiration of trace metals (Ni, Cd, Cu, Mn, Pb, Zn) added at loading rates ranging from 0 to 1000μg g−1 were determined. Differences in toxicity with respect to the type of metal salt added were also evaluated. The inhibitory effect on soil respiration differed considerably among the heavy metals and increased with the increasing loading rate. No linear relationships were found between the degree of inhibition and the levels of total and available metals. Toxicity evaluation at 20 and 50% inhibition of soil respiration showed Cu as the most toxic and Mn as the most tolerable metal. A ‘metal equivalent’ was calculated as the sum of the amounts of the available metals weighted to their relative toxicity with respect to the least toxic one: Mn equivalent=Mn+1.9Pb+2.1Ni+2.5Zn+6.7Cd+6.7Cu. The ionic potential of the heavy metals was found to be positively related to the percent inhibition of soil respiration. Chlorides and sulphates appeared to depress soil respiration more than nitrates, the latter counter-balancing the toxic effect of the heavy metals.
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  • 17
    ISSN: 1573-2932
    Keywords: soil ; pollution ; heavy metals ; smelters ; factoranalysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A combined statistical and computergraphic approach is proposed for apportionment and attribution of soil contaminants in complex areas. The field test site lies north of Swansea, south Wales and contains two major pollutant sources, an active nickel refiner and (4 km away) the site of major base metal smelting in the nineteenth century (the Lower Swansea Valley reclamation study area). Soil samples (70 samples, 0–15 cm) were collected on a regular grid of 1000 m interval. They were extracted using 0.05 M diammonium EDTA and the extracts analysed for Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn. Soil pH and %organic content were also determined. Factor analysis yielded three groups which explained 73.8% of the data variance (1: Cd, Cu, %OM, Pb, Zn, Ni; 2: Cd, Zn, Mn, pH; 3: Cu, Mn, Co, Ni, Fe). Isoline plots were classifiable into the same three groups. It was concluded that factor 3 contained those elements associated with smelter emissions, factor 1 with contamination from the Lower Swansea Valley and in factor 2 pedogenetic processes control the occurrence of the elements.
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  • 18
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    Water, air & soil pollution 99 (1997), S. 255-263 
    ISSN: 1573-2932
    Keywords: heavy metals ; sediments ; pollution ; resuspension ; release processes ; bioavailability ; anthropogenic ; metal ; residual inetal ; geochemical phases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The space-time distribution of some pollutants (Cu, Ph, Zn, Cd, Fe, Mn, V, Ni, Cr) in the sludge of the canals of Venice was studied. The contamination levels were comparable to, or higher, than those measured in the most polluted sediments of the Lagoon of Venice Sediments were collected by two different sampling techniques I ) collection of sediment cores (upper 5 cm) by a syringe-type corer, 2) collection by traps, placed on the bottom of the canal Traps pennitted the sampling of sediments essentially resuspended by overlying water turbulence This sediment fraction is subjected to variations of its physicochemical parameters (principally change of redox conditions) and therefore to pollutant exchange at the water/sediment interface The metals principally exchanged during sediment resuspension were Cd, Pb, Zn and Cu These metals have principally an anthropogenic origin and are bound to the most labile geochemical phases of the sediment (such as sulphides), which can be oxidised during sediment resuspension, releasing metals into the water Fe, Cr and Ni were only partially exchanged, while Mn and V were generally not exchanged, a significant fraction of these metals is of natural origin and is bound to the most refractory phases of the sediment.
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  • 19
    ISSN: 1573-2932
    Keywords: fractionation ; redistribution ; saturation ; kinetics ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformations of Cd, Cu, Cr, Ni and Zn, added as soluble salts at several levels to two arid-zone soils, were studied over a period of one year. The soils were maintained under a saturated-paste regime and sampled periodically. A selective sequential dissolution procedure was employed to determine the changes in metal distribution among six operationally defined solid-phase fractions. A function, Uts was introduced to measure the fractional attainment of equilibrium of the soils following a perturbation. The direction and rate of redistribution of the added metals in the soils were affected by the nature of the metal, the soil properties and the metal loading level. Cd added to the soils was transferred from the exchangeable (EXC) into the carbonate (CARB) fraction. When soluble Cu, Cr, Ni and Zn were added at low loading levels, metals were transferred from the reducible oxides(RO) bound and easily reducible oxides (ERO) bound fractions and the EXC fraction, into the CARB fraction. However, at the higher loading level, metals were transferred from the EXC and CARB fractions into the organic matter bound (OM), ERO and RO fractions. The Uts function approached lower values as incubation continued but remained removed from 1. The overall flux of metals among fractions was the combined result of the readjustment of the metals in the native soil to changing conditions due to saturation, and the transfer of added soluble metals to the less labile fractions.
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  • 20
    ISSN: 1573-2932
    Keywords: Acari ; bioindicators ; Gamasida ; heavy metals ; Oribatida ; Scots pine forest
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The soil mites were investigated in the areas covered with dead needles in young Scots pine forests (plant associationLeucobryo-Pinetum), polluted by a copper smelting works at Głogów, and in a control plot. The concentration of heavy metals, mainly copper and lead, was the lowest in the control plot, and increased towards the pollution source. A high concentration of these metals reduced the density of mites and species number of Oribatida and Gamasida, while small concentrations were associated with the increasing abundance of mites and species number of Oribatida. Among mites, the following categories were distinguished: a) sensitive to heavy metals, b) sensitive to a high concentration, but tolerant of small concentrations, and c) tolerant of these metals. The changed vertical distribution of mites in the most polluted soil was also observed, due to accumulation of heavy metals in the Of/h horizon.
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  • 21
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    Water, air & soil pollution 99 (1997), S. 651-659 
    ISSN: 1573-2932
    Keywords: River sediments ; biofilms ; organic micropollutants ; heavy metals ; temporal variations ; biosorption ; accumulation processes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a partly urbanized catchment to the south of Trier, Germany, short term variations in river sediment compounds as well as the bioaccumulation of pollutants on surface associated microbial coatings (biofilms) were investigated weekly during a period of six months. Concentrations of selected heavy metals (Cu, Zn, Pb), polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB) and for microbial characterisation protein, carbohydrate and uronic acid were analyzed. Sorption processes on biofilms were determined by temporal variations in pollutants and microbial parameters and through the comparison of sorbed substances in biofilms and sediments. The results show, that sorption events on biofilms play an important and dynamic role in spring and summer for transport and accumulation of the investigated pollutants in the aquatic environment. The amount of pollutants sorbed on sediment particles is not only dependent on the particulate bound or solved pollutants in the river water, but is strongly controlled by the changing conditions of the biofilms.
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    Environmental monitoring and assessment 50 (1998), S. 159-171 
    ISSN: 1573-2959
    Keywords: age ; biomonitoring ; heavy metals ; seabirds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The effects of age on cadmium concentrations was investigated in Cory's shearwater, Calonectris diomedea, Lesser black-backed gull, Larus fuscus, and great skuas, Catharacta skua. There was no evidence for the continued accumulation of cadmium with increasing adult age. Adult shearwaters did have higher concentrations of cadmium compared to young fledglings, but there was no significant difference between cadmium concentrations in adult and sub-adult gulls. In addition, the sample of great skuas were of known age (3–22 yrs old) and showed no evidence of increasing cadmium concentrations with adult age in liver or kidney. However, it is possible that age accumulation of cadmium in great skuas was masked by individual dietary preferences overriding the effects of increasing age. It is often assumed that cadmium concentrations continue to accumulate with increasing adult age, but seabirds may have evolved some as yet unknown mechanism for excretion or more rapid turnover of cadmium than previously thought. The implications of this for the use of seabirds as biomonitors is discussed.
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    Environmental monitoring and assessment 55 (1999), S. 389-399 
    ISSN: 1573-2959
    Keywords: accumulation ; heavy metals ; mine spoils ; vegetation ; soil-plant relationships
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The presence of heavy metals (Cr, Ni and Fe) in soil and accumulated by herbs, shrubs and trees regenerated naturally on the minewaste-dumps of Sukinda chromite mines (TISCO sector) were investigated. There was significant correlationship between Cr and Fe in the soil where a tree species (Catunaregam spinosa) occurred. Guazuma ulmifolia and Diospyros montana also did show significant correlation between leaf, stem and soil for Cr, Ni and Fe. Among the shrubs (Calotropis gigantea, Chromolaena odorata, Phyllanthus reticulatus and Woodfordia fruticosa) significant and positive correlations were obtained for Cr and Ni in soil and iron and nickel in leaf and chromium and nickel in stem. Among the annual herbs, whole plant of tephrosia purpurea and Borrevia articularis showed significant and positive correlation with chromium and nickel with the maximum correlation coefficient value. It was concluded that the above information would be useful in revegetation programmes in subtropical regions having seasonal rainfall.
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  • 24
    ISSN: 1573-2959
    Keywords: birds ; environmental pollutants ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Levels of environmental pollutants are usually higher in mainland and coastal areas than in offshore or oceanic islands due to higher inputs from agricultural and industrial sources. Levels of heavy metals are usually higher in adult than in young birds, because they have had longer to accumulate metals in their tissues, and/or because they may eat larger, more contaminated, prey. We examined the levels of arsenic, cadmium, chromium, lead, manganese, mercury, and selenium in the adults and young of Bonin petrel (Pterodroma hypoleuca), Christmas shearwater (Puffinus nativitatis) and red-tailed tropicbird (Phaethon rubricauda) on Midway Atoll, and adult wedge-tailed shearwater (Puffinus pacificus) on Midway Atoll and on Manana Island (off Oahu) in the northern Pacific. All birds were analyzed individually except for Christmas Shearwater chicks where samples were pooled to obtain sufficient quantities for analysis. Significant (p〈0.05) age-related differences were found for mercury, selenium, manganese and chromium in Bonin petrels, for selenium and mercury in Christmas shearwaters, and for chromium and mercury in Red-tailed Tropicbirds. Lead approached significance for all three species. Adults had higher levels than young except for chromium and manganese in the petrels and arsenic in all three species. There were significant interspecific differences in concentrations of all metals except arsenic for the adults nesting on Midway. Christmas shearwaters had the highest levels of all metals except mercury and chromium. Bonin petrels, the smallest species examined, had mercury levels that were over three times higher than any of the adults of the other three species. For wedge-tailed shearwaters, levels of chromium and lead were significantly higher, and manganese and selenium were lower on Midway than Manana. Knowledge of the foraging ranges and habits of these far-ranging seabirds is inadequately known, but does not currently explain the observed differences among species. We could not find a consistent pattern of differences between the burrow nesting species (Bonin petrel, Wedge-tailed shearwater) and the surface nesting tropicbirds. There was no consistent pairwise correlation between any metals across all species.
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    Environmental monitoring and assessment 59 (1999), S. 321-330 
    ISSN: 1573-2959
    Keywords: agar diffusion assay ; Arabian Gulf ; chromogenic bacteria ; heavy metals ; toxicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A simple method – direct agar diffusion assay – was optimised for rapid assessment of heavy metal toxicity to marine chromogenic and non-chromogenic bacteria. The procedure involved spotting of a 10 microliter test solution on the seeded agar plate and incubation of the plates at 30°C to accelerate bacterial growth. Under optimum conditions, test results were obtainable within 12–18 hr instead of 96 hr incubation time generally required for a marine bacterial assay by conventional agar plate methods. A range of sixteen heavy metals, each at 5 different concentrations was tested. Toxicity was demonstrated by the formation of a clear zone of growth inhibition around the point of application. Toxicity of tested chemicals could be easily demonstrated at concentrations as low as 0.1 μg per spot on the agar plate. A dose dependent relation between metal concentration (μg/spot) and the diameter of the clear zone on agar plate was observed, suggesting potential of this method as an easy and economical tool in quantitative toxicology studies.
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  • 26
    ISSN: 1573-3009
    Keywords: agriculture ; ecology ; Carabidae ; contingency tables ; partial association
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The influence of the cultivated plant stand, subject to the timing of sampling, on the occurrence of selected carabid species is investigated for three years running. Due to the nominal character of the factors (cultivar, timing, carabid species and year) we used log-linear models of four dimensional contingency tables under certain hypotheses of independence. A coefficient of contingency is calculated for characterizing the partial association between two factors respectively. The difference in G 2 's between two nested models is used to test if there are differences between the three years concerning the strength of partial association between the number of beetles in the selected species and the cultivar or the sampling time respectively.
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  • 27
    ISSN: 1573-322X
    Keywords: climate change ; food ; agriculture ; ethics ; technologies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract Burning fossil fuel in the North American continent contributes more to the CO2 global warming problem than in any other continent. The resulting climate changes are expected to alter food production. The overall changes in temperature, moisture, carbon dioxide, insect pests, plant pathogens, and weeds associated with global warming are projected to reduce food production in North America. However, in Africa, the projected slight rise in rainfall is encouraging, especially since Africa already suffers from severe shortages of rainfall. For all regions, a reduction in fossil fuel burning is vital. Adoption of sound ecological resource management, especially soil and water conservation and the prevention of deforestation, is important. Together, these steps will benefit agriculture, the environment, farmers, and society as a whole.
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    Journal of agricultural and environmental ethics 3 (1990), S. 5-20 
    ISSN: 1573-322X
    Keywords: agriculture ; waste ; environment ; economic ; social ; costs ; erosion ; pesticides ; water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract Because the agriculture/food sectors appear to be driven by short-term economic and political forces, cheap energy, and agricultural-chemical technologies, waste and environmental/social problems in the agricultural/food sectors are estimated to cost the nation at least $150 billion per year. Most of the waste and environmental/social problems can be eliminated through better resource management policies and the adoption of sustainable agricultural practices.
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    Journal of agricultural and environmental ethics 7 (1994), S. 157-172 
    ISSN: 1573-322X
    Keywords: press ; agriculture ; ethics ; newspapers ; farm magazines
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract All major journalism ethical codes explicitly state that journalists should protect editorial copy from undue influence by outside sources. However, much of the previous research on agricultural information has concentrated on what information various media communicate (gatekeeping studies) or communication's role in increasing innovation adoption (diffusion studies). Few studies have concentrated specifically on organizational and structural constraints that might adversely affect agricultural journalists' ethical standards; those that have, focus largely on farm magazines. A study of newspaper reporters who cover agricultural news found that the most pressing ethical concern is the effect of advertiser (agri-business) pressure on editorial copy, and that their concerns in general parallel those of farm magazine writers and editors. The majority reported being in situations in which they might be exposed to advertiser pressure, including pressures to change or withhold editorial copy. Large minorities suggested that advertising pressures affect the overall environment in which agricultural journalists work, and more than one in ten said they allow advertiser pressures to influence editorial decisions. The newspaper reporters who cover agricultural beats showed slightly more resistance to advertiser pressure than did farm magazine editors in a parallel study.
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  • 30
    ISSN: 1573-1642
    Keywords: decomposition ; heavy metals ; litterbags ; nitrification ; nitrogen mineralization ; urbanization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We investigated litter mass loss and soil nitrogen (N)-transformation rates in oak stands along a 130-km, urban-rural transect originating in New York City to examine the relationship between changes in these parameters and previously documented differences in soil temperature, heavy metal and total salt concentrations, and soil biota. Reference litter from a rural site was placed in litterbags, and rates of mass loss and changes in N concentration in litter residues were measured over a 6-month period. Net N-mineralization and nitrification rates were measured in A horizon soils using laboratory incubations under constant moisture and temperature. Both mass loss (76%) and N release (65%) from litterbags reached their maximum in urban stands, whereas net N-mineralization rates were 2.3-fold higher than in rural A horizon soils. Litter fragmentation by earthworms and higher soil temperatures are potential causes of the higher mass loss rates observed in urban stands. The higher releases of N measured in the urban litterbags could be a result of their faster mass loss rates, exogenous inputs of N from atmospheric deposition, a relatively low heterotrophic demand for N, or a combination of these factors. The results of this study suggest that in comparison with rural stands, urban forests are characterized by comparatively high rates of litter decomposition, and may also be characterized by comparatively high rates of N mineralization. Additional studies are needed to test whether these effects are common to urban environments in general.
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    Environmental and resource economics 1 (1991), S. 313-332 
    ISSN: 1573-1502
    Keywords: Manure problem ; nutrient policy ; nutrient surplus ; regulatory levy ; sustainability ; agriculture ; intensive livestock sector ; acidification ; groundwater pollution ; eutrophication
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Rapid increases in livestock production in the Netherlands have changed manure from a valuable input into a mere waste product. This is especially true for the southern and eastern parts of the country, where specialized pig and poultry farms have concentrated on sandy soils. As these farms generally own very little land, they largely depend on imported feedstuffs. As a consequence, manure is applied to the land in such large quantities that serious environmental problems have resulted: (1) eutrophication of surface water by phosphate emissions; (2) pollution of groundwater by nitrate emissions; and (3) acidification by ammonia emissions. In the last few years the Dutch government has developed a manure policy to counteract these effects. Our analysis of that policy has revealed at least three fundamental defects, which render the manure policy ineffective and inefficient. In this paper proposals are made to remove the defects in current manure policy. Much attention is paid to the problem of designing a mixture of policy instruments which is both effective as well as efficient in limiting the environmental problems caused by manure. It is shown that the use of financial incentives in regulation can substantially improve the efficiency of the manure policy. Finally, the main economic consequences of the proposed policy are examined for the public sector as well as for the agricultural sector.
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    Environmental and resource economics 3 (1993), S. 285-296 
    ISSN: 1573-1502
    Keywords: Pollution control ; nitrogen taxation ; agriculture
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Economics
    Notes: Abstract Amongst possible economic incentives to encourage reduced nitrate contamination of water, this paper emphasizes a nitrogen tax as a possible solution. This finding is based on models estimated from panel data for 100 intensive livestock farms. For each farm a threshold is established (nitrogen units which can be spread per hectare without damage) above which there is an excess of nitrogen. The 100 farms can consequently be classified into two subsamples. The demand for nitrogen is derived for each sub-sample using the dual approach. Both categories are pooled together and a tobit model is estimated. This is used to derive total nitogen demand if all farms were under the threshold. A mineral nitrogen tax would lead to a reduced nitrate concentration in water supplies, because of a more efficient use of organic nitrogen together with a reduction in the use of mineral nitrogen in crop production.
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    Mitigation and adaptation strategies for global change 4 (1999), S. 25-41 
    ISSN: 1573-1596
    Keywords: adaptation ; agriculture ; climate change ; Kazakhstan
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract Agriculture in Kazakhstan is sensitive to climate, and wheat yields could be reduced up to 70% under climate change. With the transition from a socialist economy to a free market economy, decisions are being made now that will affect Kazakhstan's ability to cope with climate change. A team of Kazakh and American researchers examined the cost-effectiveness and barriers to implementations of adaptation options for climate change. Twelve adaptation options that increase flexibility to respond to climate change were identified using a screening matrix. Four options, forecasting pest outbreaks, developing regional centers for preserving genetic diversity of seeds, supporting a transition to a free market, and reducing soil erosion through the use of changed farming practices, were examined. The Adaptation Decision Matrix (ADM) was then applied to estimate benefits using expert judgment (using an arbitrary numerical scale, not monetary values) and benefits estimates were compared to costs to determine cost-effectiveness. The ADM uses subjective measures of how well adaptation options meet policy objectives. Controlling soil erosion was estimated to have the highest benefits, but the high costs of implementation appears to make it relatively cost-ineffective. Supporting a transition to a free market was ranked as the most cost-effective measure, with regional centers second. However, use of different scales to quantify benefits or different weights can result in regional centers being more cost-effective than the transition to a free market. Regional centers was also judged to have fewer barriers to implementation than a transition to a free market. These results will be incorporated in Kazakhstan's National Action Plan. The ADM and other tools are relatively easy to apply, but are quite subjective and difficult to evaluate. The tools can be quite useful by decision makers to analyze advantages and disadvantages between different adaptation options, but should be supplemented with additional, particularly quantitative analysis.
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    Mitigation and adaptation strategies for global change 4 (1999), S. 137-165 
    ISSN: 1573-1596
    Keywords: adaptation ; agriculture ; climate change ; decision-making ; variability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract This work presents a framework for viewing agricultural adaptation, emphasizing the multiple spatial and temporal scales on which individuals and institutions process information on changes in their environment. The framework is offered as a means to gain perspective on the role of climate variability and change in agricultural adaptation, and developed for a case study of Australian agriculture. To study adaptation issues at the scale of individual farms we developed a simple modelling framework. The model highlights the decision making element of adaptation in light of uncertainty, and underscores the importance of decision information related to climate variability. Model results show that the assumption of perfect information for farmers systematically overpredicts adaptive performance. The results also suggest that farmers who make tactical planting decisions on the basis of historical climate information are outperformed by those who use even moderately successful seasonal forecast information. Analysis at continental scales highlights the prominent role of the decline in economic operating conditions on Australian agriculture. Examples from segments of the agricultural industry in Australia are given to illustrate the importance of appropriate scale attribution in adapting to environmental changes. In particular, adaptations oriented toward short time scale changes in the farming environment (droughts, market fluctuations) can be limited in their efficacy by constraints imposed by broad changes in the soil/water base and economic environment occuring over longer time scales. The case study also makes the point that adaptation must be defined in reference to some goal, which is ultimately a social and political exercise. Overall, this study highlights the importance of allowing more complexity (limited information, risk aversion, cross-scale interactions, mis-attribution of cause and effect, background context, identification of goals) in representing adaptation processes in climate change studies.
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    Mitigation and adaptation strategies for global change 1 (1996), S. 139-165 
    ISSN: 1573-1596
    Keywords: Adaptation ; agriculture ; agroforestry ; climate change ; drought ; ecological degradation ; factor bias ; Senegal ; sustainability ; social relations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract The ongoing drought in the Sahel region of West Africa highlights the vulnerability of food-producing systems to climate change and variability. Adaptation to climate should therefore increase the sustainability of agriculture under a long-term drought. Progress towards sustainability and adaptation in the the Senegal River Basin is hampered by an existing set of social and ecological relationships that define the control over the means of production and how people interact with their environment. These relationships are sensitive to the technological inputs and the administration of food production, or the factor bias in the different policy alternatives for rural development. One option is based on state-controlled, irrigated plantations to provide rice (Oryza) for the capital, Dakar. This policy emphasizes a top-down management approach, mechanized agriculture and a reliance on external inputs which strengthens the relationships introduced during the colonial period. A time series decomposition of the annual flow in the Senegal River at Bakel in Senegal suggests that water resources availability has been substantially curtailed since 1960, and a review of the water resources budget or availability in the basin suggests that this policy's food production system is not sustainable under the current climate of the basin. Under these conditions, this program is exacerbating existing problems of landscape degradation and desertification, which increases rural poverty. A natural resource management policy offers two adaptation strategies that favour decentralized management and a reduction of external inputs. The first alternative, “Les Perimetres Irrigués”, emphasizes village-scale irrigation, low water consumption cereal crops and traditional socio-political structures. The second alternative emphasizes farm-level irrigation and agro-forestry projects to redress the primary effects of desertification. The water requirements of both the rice import substitution program and the natural resource management program are calculated. A water resources simulation model/optimization analysis using dynamic programming is used to compare these two alternatives to the rice import substitution programs. Results indicate that the natural resource management policy could potentially bring a large area into production while using far less water than the rice import substitution program. The natural resource management policy, in particular the second alternative with its emphasis on individual ownership and ecological rehabiliation, defines a different set of social and ecological relationships that appear to enhance the sustainability of food production under a long-term drought.
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    Mitigation and adaptation strategies for global change 1 (1997), S. 219-232 
    ISSN: 1573-1596
    Keywords: climate change ; mediterranean region ; agriculture ; cereal production ; impact assessment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract Current trends in Mediterranean agriculture reveal differences between the Northern and Southern Mediterranean countries as related to population growth, land and water use, and food supply and demand. The changes in temperature and precipitation predicted by general circulation models for the Mediterranean region will affect water availability and resource management, critically shaping the patterns of future crop production. Three companion papers analyze in detail future impacts of predicted climate change on wheat (Triticum aestivum L.) and maize (Zea mays L.) production in Spain, Greece, and Egypt, and test farm- level adaptation strategies such as early planting and cultivar change with the aid of dynamic crop models. Strategies to improve the assessment of the potential effects of future climate change on agricultural production are discussed.
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    Mitigation and adaptation strategies for global change 1 (1997), S. 273-288 
    ISSN: 1573-1596
    Keywords: climate change ; vulnerability ; adaptation ; agriculture ; Spain ; wheat ; maize
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract This study evaluates the theoretical impact of climate change on yields and water use of two crops with different responses to increased CO2 and which represent contrasting agricultural systems in Spain. In all cases the simulated effects of a CO2-induced climate change depended on the counteracting effects between higher daily ET rates, shortening of crop growth duration and changes in precipitation patterns as well as the simulated effects of CO2 on the water use efficiency of the crops. For summer irrigated crops such as maize, the yield reductions and the exacerbated problems of irrigation water availability simulated with climate change may force the crop out of production in some regions. For winter dryland crops such as wheat, productivity increased significantly in some regions, suggesting a northward shift of area suitable for wheat production in future climates. The study considered strategies for improving the efficiency of water use based on the optimization of crop management decisions in a CO2-driven warmer climate.
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    Mitigation and adaptation strategies for global change 1 (1997), S. 233-250 
    ISSN: 1573-1596
    Keywords: climate change ; vulnerability ; adaptation ; agriculture ; Egypt
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract If no timely measures are taken to adapt Egyptian agriculture to possible climate warming, the effects may be negative and serious. Egypt appears to be particularly vulnerable to climate change because of its dependence on the Nile River as the primary water source, its large traditional agricultural base, and its long coastline, already undergoing both intensifying development and erosion. A simulation study characterized potential yield and water use efficiency decreases on two reference crops in the main agricultural regions with possible future climatic variation, even when the beneficial effects of increased CO2 were taken into account. On-farm adaptation techniques which imply no additional cost to the agricultural system, did not compensate for the yield losses with the warmer climate or improve the crop water-use efficiency. Economic adjustments such as the improvement of the overall water-use efficiency of the agricultural system, soil drainage and conservation, land management, and crop alternatives are essential. If appropriate measures are taken, negative effects of climate change in agricultural production and other major resource sectors (water and land) may be lessened.
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    Mitigation and adaptation strategies for global change 1 (1997), S. 219-232 
    ISSN: 1573-1596
    Keywords: climate change ; mediterranean region ; agriculture ; cereal production ; impact assessment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract Current trends in Mediterranean agriculture reveal differences between the Northern and Southern Mediterranean countries as related to population growth, land and water use, and food supply and demand. The changes in temperature and precipitation predicted by general circulation models for the Mediterranean region will affect water availability and resource management, critically shaping the patterns of future crop production. Three companion papers analyze in detail future impacts of predicted climate change on wheat (Triticum aestivum L.) and maize (Zea mays L.) production in Spain, Greece, and Egypt, and test farm- level adaptation strategies such as early planting and cultivar change with the aid of dynamic crop models. Strategies to improve the assessment of the potential effects of future climate change on agricultural production are discussed.
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    Mitigation and adaptation strategies for global change 1 (1997), S. 233-250 
    ISSN: 1573-1596
    Keywords: climate change ; vulnerability ; adaption ; agriculture ; Egypt
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract If no timely measures are taken to adapt Egyptian agriculture to possible climate warming, the effects may be negative and serious. Egypt appears to be particularly vulnerable to climate change because of its dependence on the Nile River as the primary water source, its large traditional agricultural base, and its long coastline, already undergoing both intensifying development and erosion. A simulation study characterized potential yield and water use efficiency decreases on two reference crops in the main agricultural regions with possible future climatic variation, even when the beneficial effects of increased CO2 were taken into account. On-farm adaptation techniques which imply no additional cost to the agricultural system, did not compensate for the yield losses with the warmer climate or improve the crop water-use efficiency. Economic adjustments such as the improvement of the overall water-use efficiency of the agricultural system, soil drainage and conservation, land management, and crop alternatives are essential. If appropriate measures are taken, negative effects of climate change in agricultural production and other major resource sectors (water and land) may be lessened.
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    Mitigation and adaptation strategies for global change 1 (1997), S. 273-288 
    ISSN: 1573-1596
    Keywords: climate change ; vulnerability ; adaptation ; agriculture ; Spain ; wheat ; maize
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract This study evaluates the theoretical impact of climate change on yields and water use of two crops with different responses to increased CO2 and which represent contrasting agricultural systems in Spain. In all cases the simulated effects of a CO2-induced climate change depended on the counteracting effects between higher daily ET rates, shortening of crop growth duration and changes in precipitation patterns as well as the simulated effects of CO2 on the water use efficiency of the crops. For summer irrigated crops such as maize, the yield reductions and the exacerbated problems of irrigation water availability simulated with climate change may force the crop out of production in some regions. For winter dryland crops such as wheat, productivity increased significantly in some regions, suggesting a northward shift of area suitable for wheat production in future climates. The study considered strategies for improving the efficiency of water use based on the optimization of crop management decisions in a CO2-driven warmer climate.
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    Human ecology 20 (1992), S. 145-167 
    ISSN: 1572-9915
    Keywords: agriculture ; development ; diversity ; stability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Ethnic Sciences
    Notes: Abstract This paper reconsiders two widely held hypotheses about the effects of the green revolution, that it led to biological simplification and instability. The hypothesis of biological simplification (genetic erosion) is tested with evidence from Andean agriculture, where farmers maintain a significant degree of crop diversity even as they adopt modern crop varieties. The hypothesis of increased instability is tested with evidence from Asia where wheat and rice yields show no general pattern of increased instability. Neither of these hypotheses is confirmed. The conventional wisdom about the green revolution should be reconsidered with emphasis on resilience and variation in modernizing farming systems.
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    Human ecology 25 (1997), S. 223-242 
    ISSN: 1572-9915
    Keywords: agriculture ; population ; settlement ; land tenure ; conflict ; Nigeria
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Ethnic Sciences
    Notes: Abstract While many studies have explored how agriculture changes when population density rises, this paper examines actions farmers may take to control whether population density rises. Using information from ethnographic fieldwork, colonial archives, and air photography, two agricultural groups migrating into an agricultural frontier in the Nigerian savanna are compared. Population density in Kofyar communities has risen to over 100/km 2 ; Tiv communities, although older, have maintained population densities of around 50/km 2 , in part through intimidation of encroachers. This use of intimidation is a component of a distinctive adaptive strategy that includes settlement stability, high population mobility tied to witchcraft accusations, relatively extensive cultivation allowing considerable off-time, and reliance on social networks to facilitate residential mobility and land access. Population pressure must be seen as an integral part of this adaptive strategy, rather than as cause or consequence.
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    ISSN: 1572-9915
    Keywords: South American Indians ; Brazil ; Amazonia ; development ; human ecology ; land use ; Xavánte ; agriculture ; land use ; nutrition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Ethnic Sciences
    Notes: Abstract This paper explores the process of change in a Brazilian indigenous community, relating it to historical, economical, and political forces at the regional and national levels, as well as to environmental variables. In the light of current fieldwork, we examine the predictions of a model constructed 20 years ago based on fieldwork in this and three other Indian communities of Central Brazil by Daniel Gross and collaborators. This model ascribed involvement in the market economy of small-scale communities primarily to land circumscription and resulting environmental degradation, increasing the labor cost of subsistence food production. We find that in the case of the Xavánte community entry into the market was more the result of a top-down government plan to implement mechanized rice production on Xavánte reservations. With the collapse of the project the Xavánte have, on the one hand, returned to a more “traditional” economy based on hunting, gathering, and swidden agriculture and, on the other hand, are innovating by marketing their cultural image through connections with national and international environmentalist organizations.
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  • 45
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    Human ecology 23 (1995), S. 291-334 
    ISSN: 1572-9915
    Keywords: agriculture ; sustainability ; Africa ; crop pests ; crop diseases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Ethnic Sciences
    Notes: Abstract This paper attempts to identify the main threats to and sources of sustainability in African agricultural systems by examining cases of unsustainability and resilience at various levels. Current concepts of sustainable agriculture are based mainly on the experiences and norms of western industrial nations and may not be appropriate to sub-Saharan Africa and other developing regions. The things we want to sustain comprise a hierarchy of attributes, components, and systems at increasing scales, and it is important to examine the dynamics of sustainability at each significant level as well as the impacts of events at one level on others. Cases of crop declines and of collapses of larger systems indicate that extreme perturbations, both biophysical and social, are more important as causes of unsustainability than suggested in the literature, while the significance of resource degradation or of overuse of technological inputs have been overemphasized. Survey data from Kenya and Nigeria show that the main causes of crop disappearances have been major disease or pest outbreaks, followed by changes in crop preferences. Fertility and land use stresses have been only a tertiary factor. Sources of resilience that have buffered households and larger systems from the impacts of these range from farmers' strategies of crop and income diversification and searches for resistant cultivars to interventions by national and international bodies. Numerous population and large-scale system collapses have also occurred over the past century in Africa, almost all caused by extreme social and/or biophysical perturbations. There is no evidence that land degradation or land use pressure has played a significant role in these. Increased land use pressure has led to the disappearance or alteration of many prior practices, though farmers have generally adapted to these. Resource management systems have also declined due to outmigration as regions undergo a transition from remote and relatively closed systems to more open systems. These may call for a greater rather than lower use of modern technology to enhance the income earning potential of agricultural production.
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  • 46
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    Human ecology 18 (1990), S. 105-130 
    ISSN: 1572-9915
    Keywords: agriculture ; forest farming ; social history ; Appalachia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Ethnic Sciences
    Notes: Abstract This research uses aggregate statistical sources to describe agricultural diversity in a 31 county area of Appalachian Kentucky over the period 1880–1910. In particular, it considers the distribution and duration of forest farming in this region. It examines the causes of agricultural diversity by testing a series of hypotheses conceptually based in ecological theory. For 1880, counties differed in the degree to which they had the characteristics expected for forest farming. This variation was geographically patterned. While there was still geographical variation in county agricultural characteristics in 1910, sufficient change had occurred so that none of the counties continued to closely conform to the pattern expected for forest farming. Variation and change in county agricultural characteristics were found to be related to population density and growth, soil quality, the presence of railroads, and the development of commercial coal mining.
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  • 47
    ISSN: 1572-9915
    Keywords: land use ; land cover ; Amazon ; estuary ; flooded forest ; aÇai ; palms ; agriculture ; pastures ; swidden ; slash-and-burn agriculture ; succession ; remote sensing ; GIS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Ethnic Sciences
    Notes: Abstract Landsat TM scenes for 1985 and 1991 are used to produce a georeferenced map of land cover and land use for an area of the Amazon estuary inhabited by three populations of caboclos with distinct patterns of land use. This information is combined in a geographic information system with ethnographic and survey research carried out over the past 5 years to develop representative spectral “signatures” which permit measurement and differentiation of land uses and the detection of change even between small areas of managed floodplain forest and unmanaged forest, and between three distinct age/growth classes of secondary succession following deforestation. Implementation of these procedures permit the scaling up or down of research at different resolutions. Three distinct patterns of land use are examined with differential impact on the environment. Mechanized agriculture at one site has eliminated virtually all the mature upland forest and is now dominated by secondary successional vegetation. The more traditional system of diversified land use at the next site shows a subtle cycling of flooded forest to managed palm forest through time in response to the price of palm fruit and cycling in the use of fallow land. A third site, based on palm fruit extractivism, shows minimal changes in land cover due to persistent specialization on management of flooded forest extraction. There is little evidence that the community with the greatest impact on forest cover is any better off economically than the two communities which have minimal impact on the landscape. This study suggests how a balance between use and conservation in Amazonia may be achieved in floodplain and estuarine areas, and the effectiveness of monitoring these types of land cover from satellite platforms.
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  • 48
    ISSN: 1573-2932
    Keywords: copper ; element flux ; heavy metals ; Pinus ; soil pollution ; understorey vegetation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Distribution and fluxes of copper within Pinus sylvestris stands were studied during 1992–1994 along a heavy-metal pollution gradient in south-western Finland. The stands are situated at distances of 0.5, 4 and 8 km from a copper-nickel smelter that started operating in 1945 at Harjavalta. According to the results, copper concentrations in the soil, in the understorey vegetation and in the trees increased steeply towards the smelter. Almost 50 years' accumulation of heavy metals in the soil has caused direct toxic effects to soil microbes, thus decreasing decomposition and nutrient mineralisation. During the past few years, sulphur and heavy metal emissions from the copper and nickel smelter have been radically decreased. However, the heavy metals which have been accumulating in the soil for decades continue to affect the vegetation for a long time through soil processes. Consequently, long-term accumulation in the soil has to be taken into account when determining the critical loads of forest ecosystems for heavy metals.
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  • 49
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    Water, air & soil pollution 85 (1995), S. 1891-1896 
    ISSN: 1573-2932
    Keywords: emissions ; nitrogen ; ammonia ; agriculture ; integrated assessment modelling ; abatement strategies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract European emissions of reduced nitrogen, arising principally from agriculture, are comparable with those of oxidised nitrogen from mobile and stationary combustion sources. It is therefore important to include ammonia emissions in working towards a new protocol on nitrogen under the programme of the UN Economic Commission for Europe on the control of transboundary air pollution. However the nature of the sources and the subsequent atmospheric transport and chemistry are very different from other acidifying pollutants. This paper describes work in hand under the MARACCAS project to compare agricultural activities in different European countries and to assess the applicability and efficacy of potential abatement measures. The aim is to derive abatement costs for each country relating successive emission reductions to the costs of achieving them, to be used by the UN ECE Task Force on Integrated Assessment Modelling (TFIAM) — in particular with our Abatement Strategies Assessment Model, ASAM. The paper will also address the large uncertainties involved in integrated assessment modelling with respect to ammonia, and suggest how these may be allowed for in deriving cost-effective abatement strategies.
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  • 50
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    Water, air & soil pollution 96 (1997), S. 61-71 
    ISSN: 1573-2932
    Keywords: allotment gardens ; dustfall ; ground water ; heavy metals ; oil refinery ; soil ; vegetables
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In the period 1984–1990 the following vegetables were grown: red beet, carrot and parsley in four allotment gardens of Płock city (Central Poland), situated near the refinery and petrochemical works. Cadmium, lead, copper, chromium, zinc and manganese concentrations were determined in the leaves and roots of vegetables. The heavy metal accumulation in the soil, dustfall (measure of air pollution), and ground water was determined. The quality of the vegetable yield, notably of the leaves, was low. This was mainly due to the excessive chromium and cadmium content in the leaves. Accumulation of heavy metals was relatively low in the soil, rather high in the ground water and variable in the dust.
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  • 51
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    Water, air & soil pollution 96 (1997), S. 1-16 
    ISSN: 1573-2932
    Keywords: heavy metals ; pollution ; sandy soils ; zinc smelter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sandy soils, in the border area of Belgium and the Netherlands (the Kempen region), are heavily contaminated by atmospheric deposition of cadmium and zinc from nearby smelters. Groundwater contamination by leaching from these low retention soils is subject of study. There are reports of high cadmium and zinc concentrations in groundwater in the area, but in most cases the direct sources are unknown. In an attempt to predict present or future risk of groundwater contamination by soil leaching, metal binding processes (retardation) were studied that are specific for these soil types under the existing acidifying conditions. From four fields nine contaminated profiles were sampled and analyzed for cadmium and zinc. Average concentrations of 131 μg g-1 zinc and 1.6 μg g-1 cadmium with maximum values of 2989 μg g-1 respectively 16.3 μg g-1 were found. In addition pH and contents of organic matter, aluminium, iron, and manganese were determined. The relative importance of these soil parameters for metal retardation is derived from the profiles. The data show that organic matter is the most important soil component for binding cadmium and zinc. Adsorption of cadmium and zinc on aluminium, iron and manganese (hydr) oxides appears to be of minor importance at low pH (〈5.5).
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  • 52
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    Water, air & soil pollution 96 (1997), S. 1-16 
    ISSN: 1573-2932
    Keywords: heavy metals ; pollution ; sandy soils ; zinc smelter
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sandy soils, in the border area of Belgium and the Netherlands (the Kempen region), are heavily contaminated by atmospheric deposition of cadmium and zinc from nearby smelters. Groundwater contamination by leaching from these low retention soils is subject of study. There are reports of high cadmium and zinc concentrations in groundwater in the area, but in most cases the direct sources are unknown. In an attempt to predict present or future risk of groundwater contamination by soil leaching, metal binding processes (retardation) were studied that are specific for these soil types under the existing acidifying conditions. From four fields nine contaminated profiles were sampled and analyzed for cadmium and zinc. Average concentrations of 131μg g−1 zinc and 1.6μg g−1 cadmium with maximum values of 2989μg g−1 respectively 16.3μg g−1 were found. In addition pH and contents of organic matter, aluminium, iron, and manganese were determined. The relative importance of these soil parameters for metal retardation is derived from the profiles. The data show that organic matter is the most important soil component for binding cadmium and zinc. Adsorption of cadmium and zinc on aluminium, iron and manganese (hydr) oxides appears to be of minor importance at low pH (〈5.5).
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  • 53
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    Water, air & soil pollution 96 (1997), S. 39-59 
    ISSN: 1573-2932
    Keywords: acid mine drainage ; heavy metals ; jarosite ; soils ; Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The discharge of acidic mine drainage waters onto a hillslope in Dalarna, central Sweden, has lead to the contamination of the podzol soils with Cu, Fe, Ni, Pb, Zn and sulfate. Samples from contaminated and reference soils have been collected for chemical and mineralogical analyses. Jarosite is identified by x-ray diffraction analysis as a precipitate in the upper horizons (A, E, B) of the contaminated soils, where the soil acidity (pHKCl∼2.6) promotes jarosite stability. The sequential chemical extraction of soil samples indicates that, in the reference A horizon, Cu, Pb, Ni and Zn are bound primarily to cation exchange sites and organic matter. In the A horizon of the contaminated soils closest to the rock dump, metal partitioning is dominated by the Fe oxide fractions, despite the high organic matter content; Pb is almost completely bound to crystalline Fe oxides, possibly adsorbed to Fe oxides or occuring in a jarosite solid solution. In the reference B and C horizons, Cu, Ni and Zn are primarily adsorbed/coprecipitated in the Fe oxide fractions, while Pb remains with a large fraction bound to organic matter. In the Fe-rich B horizon of the contaminated soils, the partitioning of the metals in cation exchange sites and to organic matter has greatly increased relative to the reference soils, resulting from the mobilization of organo-metal complexes down the profile.
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  • 54
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    Water, air & soil pollution 96 (1997), S. 61-71 
    ISSN: 1573-2932
    Keywords: allotment gardens ; dustfall ; ground water ; heavy metals ; oil refinery ; soil ; vegetables
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In the period 1984–1990 the following vegetables were grown: red beet, carrot and parsley in four allotment gardens of Płock city (Central Poland), situated near the refinery and petrochemical works. Cadmium, lead, copper, chromium, zinc and manganese concentrations were determined in the leaves and roots of vegetables. The heavy metal accumulation in the soil, dustfall (measure of air pollution), and ground water was determined. The quality of the vegetable yield, notably of the leaves, was low. This was mainly due to the excessive chromium and cadmium content in the leaves. Accumulation of heavy metals was relatively low in the soil, rather high in the ground water and variable in the dust.
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  • 55
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    Water, air & soil pollution 92 (1996), S. 41-51 
    ISSN: 1573-2932
    Keywords: Philippines ; agriculture ; rice ; corn ; CCCM ; CERES-Corn ; CERES-Rice ; GFDL ; GISS ; UKMO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The potential impact of climate change on rice and corn crops in the Philippines was assessed using preliminary results from four general circulation models and the Decision Support System for Agrotechnology Transfer. The results showed both increases and decreases in the yield of two rice varieties. The results for corn showed a consistent decrease in yield. The decrease in crop yield may be due to a shorter maturity period and an increase in potential evapotranspiration as a result of increased daytime and nighttime temperatures, which are critical to dry matter production. Rainfall in tropical areas such as the Philippines is generally high, and so a decrease in rainfall of only 10% may not affect the water supply significantly, but an increase of the same magnitude may affect crop production tremendously because of frequent occurrences of floods. One potential negative impact not included in this analysis is the effects of strong winds due to typhoons.
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  • 56
    ISSN: 1573-2932
    Keywords: Asia ; Pacific island nations ; adaptation ; agriculture ; forest ; coastal resources ; water resources ; sea level rise ; national action plans
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Regional Workshop on Climate Change Vulnerability and Adaptation Assessment in Asia and the Pacific metto present and discuss assessments of vulnerability and adaptation to climate change in agriculture, forests, coastal resources, and water resources. Discussions were held in breakout and plenary sessions about the state of the science for vulnerability and adaptation assessment, conclusions that can be drawn about the vulnerability of the region to climate change, and where future research efforts should be directed. The workshop concluded that sea level rise is of greatest concern to island and coastal nations in the region, climate change will have a significant effect on agriculture, water resources are sensitive to changes in average climate conditions and to tropical monsoons and cyclones, and forests could be significantly affected by climate change. The workshop recommended that efforts to improve general circulation models continue and that countries in the region cooperate on the analyses of vulnerability and addressing adaptation measures. The workshop also concluded that results of vulnerability and adaptation assessments should be presented to policy makers and the public and that assessments continue to be undertaken to improve our understanding of the issue.
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  • 57
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    Water, air & soil pollution 92 (1996), S. 29-39 
    ISSN: 1573-2932
    Keywords: Indonesia ; Java ; agriculture ; rice ; drought ; El Nino ; GFDL ; GISS ; UKMO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract About 60% of the nearly 40 x 106 t of rice produced in Indonesia are from the island of Java. However, the rice self-sufficiency that has been attained and maintained since 1984 could be threatened by changing climate, and has been affected by the climate variability effects of the El Nino/Southern Oscillation phenomenon. To aid policy makers and planners in formulating strategic policy options, the effects of recurring droughts and possible climate change on rice yields were studied using climate and crop models. Three models were used to simulate climate change: those of the Goddard Institute for Space Studies, Geophysical Fluid Dynamics Laboratory, and the United Kingdom Meteorological Office. Several climate scenarios were generated for Ngawi, in East Java, and Sukamandi, in West Java. These models indicate that doubling greenhouse gases would increase solar radiation by 1.2–2.1%, minimum and maximum temperatures by 7.6–16.8°C, and precipitation by 20.5–91.7%. The Goddard Institute for Space Studies transient climate change scenarios indicate that maximum and minimum temperatures would increase by 3.5 and 4.9%, respectively, in 2010, 6.9 and 9.8%, respectively, in 2030, and 11.1 and 15.7%, respectively, in 2050. The rainfall Agrotechnology Transfer crop model slightly under-predicts lowland rice yields of several experimental plots in three sites in Java and one site in Sumatra, but the results are almost equal to or a little higher than farm level yields. Nevertheless, the simulation outputs and experimental plots yields are closely related with a coefficient of determination value of 87%. Changes in climate in the decades of 2010, 2030, and 2050 could drastically reduce rice yield: the rice yield is estimated to decrease by about 1 % annually in East Java and less in West Java. Currently, the rice yields in dry
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  • 58
    ISSN: 1573-2932
    Keywords: heavy metals ; TNR ; stream sediments ; Suquía River
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Suquía is a semiarid (rainfall, 700-900 mm y-1), medium-size (7700 km2) riversystem located in central Argentina. Its mountainous upper catchment includes pristine areas aswell as a variety of human settlements and a reservoir lake. A large city (Córdoba, ca. 1.3million inhabitants) and a terminal hypersaline lake are included in the middle and lower basin.Total non-residual (TNR) heavy metals (Pb, Cu, Ni, Zn, Mn, and Fe) have been determined inriver bed sediments in two seasons (spring and autumn), seeking to establish the factors whichcontrol the temporal and spatial variability. The major findings were: a) concentrations of TNRmetals were, in general, higher during springtime than during autumn, particularly downstreamfrom the city of Córdoba; b) organic matter played a significant role as a controlling factorwherever it defined reducing conditions, lowering the concentrations of Mn and Fe hydrousoxides; c) a higher organic load (e.g., downstream the city) and more pronounced reducingconditions could be the causes for the increased Fe concentration, probably precipitated assulfides; d) organic matter exhibited a closer correlation with some TNR metals in autumn,probably caused by a larger capacity for complexation in the biologically-processed organicdebris; and, e) the existence of pristine areas in the drainage basin allowed for the calculation ofenrichment factors (EF) which show the significance of several environmental impacts in theSuquía system.
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  • 59
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    Water, air & soil pollution 93 (1997), S. 395-408 
    ISSN: 1573-2932
    Keywords: air pollution ; pine bark ; sulphur ; pH ; conductivity ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sulphur and heavy metal deposition in northern Finland (= in Lapland) and the Kola Peninsulawere surveyed using Scots pine bark samples. Sulphur concentrations in bark close to the Kolasmelters were on an average twice as high as on the Finnish side of the border. The Cu and Niconcentrations near the smelters were almost 100-fold the mean values in northern Finland. Therewas a marked decrease in the sulphur and heavy metal concentrations with increasing distancefrom the emission sources. The effects of emissions from the Kola Peninsula were evident inFinland only close to the border, especially in the eastern parts of Inari (NE corner of Lapland)where the Cu and Ni concentrations were 2- to 6-fold those in western Lapland. The sulphur andheavy metal concentrations in most of northern Finland were low. However were theconcentrations of Cr in bark in the SW corner of Lapland considerably high, due to the emissionsfrom the Tornio refined steel plants.
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  • 60
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    Water, air & soil pollution 93 (1997), S. 409-417 
    ISSN: 1573-2932
    Keywords: CO2 evolution ; heavy metals ; loading effect ; metal equivalent
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In a laboratory study the effects on soil respiration of trace metals (Ni, Cd, Cu, Mn, Pb, Zn)added at loading rates ranging from 0 to 1000 µg g-1 were determined. Differences intoxicity with respect to the type of metal salt added were also evaluated. The inhibitory effect onsoil respiration differed considerably among the heavy metals and increased with the increasingloading rate. No linear relationships were found between the degree of inhibition and the levels oftotal and available metals. Toxicity evaluation at 20 and 50% inhibition of soil respiration showedCu as the most toxic and Mn as the most tolerable metal. A ‘metal equivalent’ was calculated asthe sum of the amounts of the available metals weighted to their relative toxicity with respect tothe least toxic one: Mn equivalent = Mn + 1.9Pb + 2.1Ni + 2.5Zn + 6.7Cd + 6.7Cu. The ionicpotential of the heavy metals was found to be positively related to the percent inhibition of soilrespiration. Chlorides and sulphates appeared to depress soil respiration more than nitrates, thelatter counter-balancing the toxic effect of the heavy metals.
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  • 61
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    Water, air & soil pollution 93 (1997), S. 93-108 
    ISSN: 1573-2932
    Keywords: straw ash ; ashes ; bottom ash ; fly ash ; biofuel ; cereal straw ; rape straw ; straw combustion ; fertilizer ; plant nutrients ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The composition of 79 samples of straw ash from seven heating plants in Sweden wasanalysed with the aim of evaluating straw ash as a fertilizer and liming agent. The variation in ashcomposition was explained mainly by ash fraction (bottom ash vs. fly ash) and straw type (wheat,barley, rye, rape) but also by heating plant. Compared with concentrations of Zn, Pb and Cd inbottom ash, levels in fly ash were 10-90 times higher. Fly ash also contained more Cu and Kcompared with bottom ash. The Cd/P ratio was 0.03 in bottom ash and 0.6 g Cd/kg P in fly ash.Ash from rape straw had a higher Ca content and liming effect compared with ash from cerealstraw; e.g., the liming effect of rape ash was more than three times higher than that of wheat ash.The liming effect varied between 3.5 and 44% CaO and depended mainly on the Ca content. Theaverage P content was 1.7% (0.2-4.4%), with slightly higher concentration in rape ash than inwheat ash. The potential for using straw ash as a fertilizer and liming agent is discussed. Compared withcommercial fertilizers the use of bottom ash as a P fertilizer results in a lower addition of Cd.However, the total heavy metal content of straw ash poses a potential problem.
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  • 62
    ISSN: 1573-2932
    Keywords: heavy metals ; TNR ; stream sediments ; Suquía River
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Suquía is a semiarid (rainfall, 700–900 mm y−1), medium-size (7700 km2) river system located in central Argentina. Its mountainous upper catchment includes pristine areas as well as a variety of human settlements and a reservoir lake. A large city (Córdoba, ca. 1.3 million inhabitants) and a terminal hypersaline lake are included in the middle and lower basin. Total non-residual (TNR) heavy metals (Pb, Cu, Ni, Zn, Mn, and Fe) have been determined in river bed sediments in two seasons (spring and autumn), seeking to establish the factors which control the temporal and spatial variability. The major findings were: a) concentrations of TNR metals were, in general, higher during springtime than during autumn, particularly downstream from the city of Córdoba; b) organic matter played a significant role as a controlling factor wherever it defined reducing conditions, lowering the concentrations of Mn and Fe hydrous oxides; c) a higher organic load (e.g., downstream the city) and more pronounced reducing conditions could be the causes for the increased Fe concentration, probably precipitated as sulfides; d) organic matter exhibited a closer correlation with some TNR metals in autumn, probably caused by a larger capacity for complexation in the biologically-processed organic debris; and, e) the existence of pristine areas in the drainage basin allowed for the calculation of enrichment factors (EF) which show the significance of several environmental impacts in the Suquía system.
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  • 63
    ISSN: 1573-2932
    Keywords: soil ; pollution ; heavy metals ; smelters ; factor analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A combined statistical and computergraphic approach is proposed for apportionment and attribution of soil contaminants in complex areas. The field test site lies north of Swansea, south Wales and contains two major pollutant sources, an active nickel refiner and (4 km away) the site of major base metal smelting in the nineteenth century (the Lower Swansea Valley reclamation study area). Soil samples (70 samples, 0–15 cm) were collected on a regular grid of 1000 m interval. They were extracted using 0.05 M diammonium EDTA and the extracts analysed for Cd, Co, Cu, Fe, Mn, Ni, Pb and Zn. Soil pH and %organic content were also determined. Factor analysis yielded three groups which explained 73.8% of the data variance (1: Cd, Cu, %OM, Pb, Zn, Ni; 2: Cd, Zn, Mn, pH; 3: Cu, Mn, Co, Ni, Fe). Isoline plots were classifiable into the same three groups. It was concluded that factor 3 contained those elements associated with smelter emissions, factor 1 with contamination from the Lower Swansea Valley and in factor 2 pedogenetic processes control the occurrence of the elements.
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  • 64
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    Water, air & soil pollution 94 (1997), S. 361-372 
    ISSN: 1573-2932
    Keywords: heavy metals ; contamination ; mobilization ; cadmium ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Analysis of spatial distribution of sewage-sludge born cadmium on the experimental plot revealed positive correlation of total cadmium and organic matter. Soil pH fluctuated randomly on the field. ‘Bioavailable’ concentrations, as determined by NH4-acetate extraction, were closely correlated to the total cadmium levels, and only negligible effects of pH and/or organic matter fluctuations were recorded. Desorption model using modified Freundlich isotherm was applied to predict risks of cadmium solubilization at different conditions. Simulations revealed that the organic matter content within the ranges found at the experimental field cannot support a proper immobilization of cadmium at pH-range observed at the field. The phenomenon was explained by ineffective care for the soil in the past.
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    Water, air & soil pollution 94 (1997), S. 361-372 
    ISSN: 1573-2932
    Keywords: heavy metals ; contamination ; mobilization ; cadmium ; soil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Analysis of spatial distribution of sewage-sludge born cadmium on the experimental plot revealed positive correlation of total cadmium and organic matter. Soil pH fluctuated randomly on the field. ‘Bioavailable’ concentrations, as determined by NH4-acetate extraction, were closely correlated to the total cadmium levels, and only negligible effects of pH and/or organic matter fluctuations were recorded. Desorption model using modified Freundlich isotherm was applied to predict risks of cadmium solubilization at different conditions. Simulations revealed that the organic matter content within the ranges found at the experimental field cannot support a proper immobilization of cadmium at pH-range observed at the field. The phenomenon was explained by ineffective care for the soil in the past.
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    Water, air & soil pollution 99 (1997), S. 615-622 
    ISSN: 1573-2932
    Keywords: Near-shore sediments ; heavy metals ; bioindicators ; bivalves ; benthic populations ; multivariate analysis ; multiple regression analysis ; predictive models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Copper, lead, cadmium, zinc, chromium, manganese, iron and nickel were determined in near-shore sediments in the harbour of Trieste (Northern Adriatic), in an area highly exposed to urban and industrial wastes, where severe alteration of benthic population was observed. A typical bivalve of this area,Corbula gibba, was used as bioindicator of sea-bottom pollution. Multivariate statistical analysis of the chemical data interpret concentrations and distributions of heavy metals in these sediments, attesting anthropogenic source for Cu, Pb, Cd and Zn. Using labile fractions of heavy metals in sediments as ‘predictors’, and length or bionnass of the bivalve as dependent variables, we obtained, by a multiple regression procedure, a predictive model showing the influence of metals on this benthic organism of this polluted area.
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  • 67
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    Environmental monitoring and assessment 50 (1998), S. 189-200 
    ISSN: 1573-2959
    Keywords: grapevines ; heavy metals ; mining ; smelting ; xylem sap
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract No data are available on the content of heavy metals in the xylem sap of grapevines growing in contaminated areas. The aim of this work was to obtain data on the concentration of Pb, Zn, Cd and Cu in the xylem sap of grapevine (Vitis vinifera) cultivar Monica (ungrafted), growing near contaminated sites: a smelter, an abandoned and an active mine, and to investigate relationships between xylem sap mineral composition and the heavy metal content of the soil. The concentrations of Pb, Zn, Cd and Cu in the sap were enhanced compared to that of the soil, ranging from 4.3 to 611.4 µg Pb $$g_{d.wt.}^{ - 1} $$]〉$$ , 801 to 6176 µg Zn $$g_{d.wt.}^{ - 1} $$]〉$$ , 2.5 to 45 µg Cd $$g_{d.wt.}^{ - 1} $$]〉$$ and 19.8 to 161 µg Cu $$g_{d.wt.}^{ - 1} $$]〉$$ . Dry matter of xylem sap was significantly related to the heavy metals content in xylem saps, but no significant relationship between the metals in sap and total and DTPA/TEA extractable metal fraction in soil was found.
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  • 68
    ISSN: 1573-3017
    Keywords: heavy metals ; old-fields ; municipal sludge ; blackfaced leafhopper ; Graminella nigrifrons ; Cicadellidae ; cabbage looper moth ; Noctuidae ; Trichoplusia ni
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Municipal sewage sludge containing heavy metals had a toxic effect on the development of the cabbage looper, Trichoplusia ni (Lepidoptera: Noctuidae), one of two herbivorous insects commonly found in an Ohio old-field which had been subjected to long-term sewage sludge application. Soils were removed in 1992 from an old-field following 11 years of heavy nutrient enrichment (1978 to 1988) with applications of either sewage sludge (Milorganite®) containing heavy metal contaminants or urea-phosphate fertilizer. Egg to adult development rate and survival of the blackfaced leafhopper, Graminella nigrifrons (Homoptera: Cicadellidae), and the cabbage looper was determined on maize (leafhopper) and broccoli (looper) seedlings grown in soils from sludge-treated, fertilizer-treated, or untreated control plots of the old-field. Fertilizer and sludgetreated soils had higher levels of N. P and organic matter, and a lower pH than the untreated control soils, while sludge-treated soils contained significantly higher concentrations of Cd, Cu, Pb, and Zn. Maize appeared to be unaffected by the three soil treatments, and survival and rate of egg to adult development of the leafhopper was not affected. Broccoli seedlings grown in both the high nutrient fertilizer and sludge soils were greener and larger than broccoli grown in control soils. However, the cabbage looper had significant larval and pupal mortality (25 to 40%) and prolonged egg to adult development on sludge-grown broccoli compared to control and fertilizer treatments. As assimilation into the food chain of heavy metals and other organic pollutants, such as PCBs, is in part a function of the interaction of soil chemistry and type of plant, the application of municipal sludges to old-fields needs to be carefully monitored, as contaminants may have significant developmental and behavioural effects on some secondary links in the old-field food chain.
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  • 69
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    Journal of agricultural and environmental ethics 6 (1993), S. 75-88 
    ISSN: 1573-322X
    Keywords: biotechnology ; education ; agriculture ; socio-economic issues
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract An interdisciplinary course was designed as an introduction to the applications of, and the socio-economic issues associated with, biotechnology. College students enrolled in the course were surveyed prior to the first formal lecture, and again upon completion of the course. Assessment was made of the impact of the educational materials on the attitudes and perceptions of the students toward the applications of biotechnology to agriculture. Data were collected for the first three semesters in which the course was offered. Answers to survey questions were analyzed on a before and after basis. It was found that students were very accepting of biotechnology prior to taking the course, despite a generally low level of exposure to this type of technology. The course was effective in increasing the knowledge base of the students, but not as effective in allaying their perceptions of risks associated with biotechnology.
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  • 70
    ISSN: 1573-3017
    Keywords: Swainson's hawks ; mortality ; monocrotophos ; agriculture ; Argentina
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Swainson's hawks (Buteo swainsoni) were observed in the grasslands (pampas) of Argentina during the austral summer of 1995–96. Widespread agrochemical use to control insects had a profound effect on flocks of hawks foraging on grasshoppers and caterpillars throughout the pampas. We describe 19 mortality incidents and an estimated 5,095 dead hawks. Forensic analysis indicated that the organophosphate insecticide monocrotophos was responsible for the deaths at six separate sites, accounting for over 4,000 of the mortalities. Brain cholinesterase was lethally inhibited (〉95%) and monocrotophos residues (n=31/45, mean=0.20 ppm, range 0.05–1.08 ppm) were found in the contents of the gastrointestinal tract. No other insecticide residues were found. Sample analyses, combined with interviews with farmers, indicated that monocrotophos was responsible for deaths at 17 of 19 mortality incidents.
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  • 71
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    Water, air & soil pollution 95 (1997), S. 119-131 
    ISSN: 1573-2932
    Keywords: geochemical investigations ; geochemical validation ; heavy metals ; ICP-AES ; environmental monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A little known alternative to highcost environmental analysis, especially in Europe, is the use of commercially available, lowcost exploration geochemical laboratory analysis. To test for suitable accuracy and precision, both indicated parameters were monitored during several sample runs for environmental examinations at a selected commercial geochemical laboratory using various digestive methods and ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometry). By evaluating duplicate samples and repeated measurements of internal standards and comparing the results with precision needed for environmental investigations, exploration geochemical analysis is found to be more than adequate for most elements and digestive methods in environmental applications. Accuracy is highest for total digestion ICP-AES analysis, with expectedly greater error margins for aqua regia digestion. Lowcost exploration geochemical analysis is an inexpensive analytical tool for screening, detailed investigations and monitoring of contaminated sites.
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  • 72
    ISSN: 1573-2932
    Keywords: fractionation ; redistribution ; saturation ; kinetics ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformations of Cd, Cu, Cr, Ni and Zn, added as soluble salts at several levels to two arid-zone soils, were studied over a period of one year. The soils were maintained under a saturated-paste regime and sampled periodically. A selective sequential dissolution procedure was employed to determine the changes in metal distribution among six operationally defined solid-phase fractions. A function,U ts was introduced to measure the fractional attainment of equilibrium of the soils following a perturbation. The direction and rate of redistribution of the added metals in the soils were affected by the nature of the metal, the soil properties and the metal loading level. Cd added to the soils was transferred from the exchangeable (EXC) into the carbonate (GARB) fraction. When soluble Cu, Cr, Ni and Zn were added at low loading levels, metals were transferred from the reducible oxides(RO) bound and easily reducible oxides (ERO) bound fractions and the EXC fraction, into the CARB fraction. However, at the higher loading level, metals were transferred from the EXC and CARB fractions into the organic matter bound (OM), ERO and RO fractions. TheU ts function approached lower values as incubation continued but remained removed from 1. The overall flux of metals among fractions was the combined result of the readjustment of the metals in the native soil to changing conditions due to saturation, and the transfer of added soluble metals to the less labile fractions.
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  • 73
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    Water, air & soil pollution 96 (1997), S. 39-59 
    ISSN: 1573-2932
    Keywords: acid mine drainage ; heavy metals ; jarosite ; soils ; Sweden
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The discharge of acidic mine drainage waters onto a hillslope in Dalarna, central Sweden, has lead to the contamination of the podzol soils with Cu, Fe, Ni, Pb, Zn and sulfate. Samples from contaminated and reference soils have been collected for chemical and mineralogical analyses. Jarosite is identified by x-ray diffraction analysis as a precipitate in the upper horizons (A, E, B) of the contaminated soils, where the soil acidity (pHKCl ∼ 2.6) promotes jarosite stability. The sequential chemical extraction of soil samples indicates that, in the reference A horizon, Cu, Pb, Ni and Zn are bound primarily to cation exchange sites and organic matter. In the A horizon of the contaminated soils closest to the rock dump, metal partitioning is dominated by the Fe oxide fractions, despite the high organic matter content; Pb is almost completely bound to crystalline Fe oxides, possibly adsorbed to Fe oxides or occuring in a jarosite solid solution. In the reference B and C horizons, Cu, Ni and Zn are primarily adsorbed/coprecipitated in the Fe oxide fractions, while Pb remains with a large fraction bound to organic matter. In the Fe-rich B horizon of the contaminated soils, the partitioning of the metals in cation exchange sites and to organic matter has greatly increased relative to the reference soils, resulting from the mobilization of organo-metal complexes down the profile.
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  • 74
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    Water, air & soil pollution 96 (1997), S. 185-201 
    ISSN: 1573-2932
    Keywords: Avenidas basin ; Pachuca mines ; hydrochemistry ; hydrochemical facies ; heavy metals ; groundwater
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Groundwater in the Rio de las Avenidas sub-basin corresponds to the bicarbonate-sodium and bicarbonate-calcium hydrochemical facies, which result from the mineralization of water passing through alkaline rocks (andesites) which prevail in this basin. However, the presence of high concentrations of Na+ and K+ reveals the existence of an external inflow of these elements: the registered mean values are respectively 94.3 and 19.0 ppm, with the Tèllez and Tizayuca areas standing out with reported values of up to 142 ppm. As for the concentration of soluble water cations, we find in decreasing order: Na+, Ca2+, Mg2+, K+, along with the anions HCO3 −, Cl−, SO4 2−, CO3 −, which combine to form the NaHCO3, NaCl, Ca(HCO3)2, MgSO4 and KCl salts. The presence of biological contaminants, P and detergents in the groundwater indicates that it may have been contaminated by waste water. In addition to the contaminants mentioned above, large quantities of Pb, B, Zn, Fe, Mn, Cr, Co were detected and although Fe, Pb, Zn, B, and Mn are closely related to the local lithology, the high concentrations of these elements along with the occurrence of Co, Cr, Cd, and Ni confirm the gradual degradation of the aquifers in the sub-basin. The water temperature indicates the existence of low temperature thermal processes in the area.
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  • 75
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    Water, air & soil pollution 96 (1997), S. 185-201 
    ISSN: 1573-2932
    Keywords: Avenidas basin ; Pachuca mines ; hydrochemistry ; hydrochemical facies ; heavy metals ; groundwater
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Groundwater in the Rio de las Avenidas sub-basin corresponds to the bicarbonate-sodium and bicarbonate-calcium hydrochemical facies, which result from the mineralization of water passing through alkaline rocks (andesites) which prevail in this basin. However, the presence of high concentrations of Na+ and K+ reveals the existence of an external inflow of these elements: the registered mean values are respectively 94.3 and 19.0 ppm, with the Tèllez and Tizayuca areas standing out with reported values of up to 142 ppm. As for the concentration of soluble water cations, we find in decreasing order: Na+, Ca2+, Mg2+, K+,along with the anions HCO3 -, Cl-, SO4 2-, CO3 -, which combine to form the NaHCO3, NaCl, Ca(HCO3 2, MgSO4 and KCl salts. The presence of biological contaminants, P and detergents in the groundwater indicates that it may have been contaminated by waste water. In addition to the contaminants mentioned above, large quantities of Pb, B, Zn, Fe, Mn, Cr, Co were detected and although Fe, Pb, Zn, B,and Mn are closely related to the local lithology, the high concentrations of these elements along with the occurrence of Co, Cr, Cd, and Ni confirm the gradual degradation of the aquifers in the sub-basin. The water temperature indicates the existence of low temperature thermal processes in the area.
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  • 76
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    Water, air & soil pollution 92 (1996), S. 63-73 
    ISSN: 1573-2932
    Keywords: China ; agriculture ; maize ; rice ; wheat ; GFDL ; MPI ; UKMO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper discusses the vulnerability and adaptation of the agricultural sector of China to global warming. Based on a summarization of Chinese agricultural and general circulation model trends, adverse impacts on China's agriculture caused by a warming and drying climate were identified. Because of limited irrigation potential, the sustainable development of Chinese agriculture will be difficult. Six sensitive agricultural areas located on the edges of different agroecological zones, and seven provinces with high vulnerability to the impacts on agriculture, were identified. On the basis of an estimation ofthe potential supply of agricultural products and demand for food, the annual incremental costs for adaptation to climate change would be US$0.8–3.48 billion; without adaptation, the annual agricultural loss due to global warming would be US$1.37–79.98 billion from 2000 to 2050. Adaptive measures discussed include intensive management and the possibility of a tripartite structure of planting that would entail coordinated development of gain crops, feed crops, and cash crops.
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  • 77
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    Water, air & soil pollution 92 (1996), S. 53-62 
    ISSN: 1573-2932
    Keywords: Bangladesh ; agriculture ; rice ; wheat ; CCCM ; CERES-Rice ; CERES-Wheat ; GFDL
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A simulation study was conducted to assess the vulnerability of foodgrain production in Bangladesh to potential climate change. Simulation runs were made for high yield varieties office for Aus (March-August), Aman (July-November), and Boro (February-July), the traditional growing seasons, using the CERES-Rice model. Simulation runs were made for wheat, which is grown from November through March, using the CERES-Wheat model. Three scenarios (baseline, Canadian Climate Centre Model, and Geophysical Fluid Dynamics Laboratory) and sensitivity analyses for temperature increases of 2 and 4°C at three levels of CO2 (330, 580, and 660 ppm) were used. In the simulation, increased CO2 levels increased rice yields over baseline, and considerable spatial and temporal variations were noted. Higher temperatures reduced the yields in almost all study locations and in all seasons, and it was particularly pronounced with a 4°C increase. The detrimental effect of temperature rise was observed even with increased CO2 levels. Wheat yields increased with increased CO2 level in all three locations. The adverse effects of increased temperature were more pronounced for wheat than for rice at all levels of increased CO2. In the scenarios of the Canadian Climate Centre Model and Geophysical Fluid Dynamics Laboratory, both rice and wheat yields were decreased (35% and 31 %, respectively) over baseline in all seasons, especially in the Aus season, and in all locations. The adverse effects of the climate under the Geophysical Fluid Dynamics Laboratory scenario were more pronounced for wheat that for rice. The greatest reductions in aggregated production for both crops were noted at 330 PPM CO2 with a 4°C temperature rise. The greatest increases in aggregated production for rice and wheat were observed at a 660 ppm CO2 with no temperature increase.
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  • 78
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    Water, air & soil pollution 92 (1996), S. 75-85 
    ISSN: 1573-2932
    Keywords: China ; agriculture ; maize ; GFDL ; MPI ; UKMO
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This study assessed the impacts of potential climate change on maize yields in China, using the CERES-Maize model under rainfed and irrigated conditions, based on 35 maize modeling sites in eastern China that characterize the main maize regions. The Chinese Weather Generator was developed to generate a long time series of daily climate data as baseline climate for 51 sites in China. Climate change scenarios were created from three equilibrium general circulation models: the Geophysical Fluid Dynamics Laboratory model, the high-resolution United Kingdom Meteorological Office model, and the Max Planck Institute model. At most sites, simulated yields of both rainfed and irrigated maize decreased under climate change scenarios, primarily because of increases in temperature, which shorten maize growth duration, particularly the grain-filling period. Decreases of simulated yields varied across the general circulation model scenarios. Simulated yields increased at only a few northern sites, probably because maize growth is currently temperature-limited at these relatively high latitudes. To analyze the possible impacts of climate variability on maize yield, we specified incremental changes to variabilities of temperature and precipitation and applied these changes to the general circulation model scenarios to create sensitivity scenarios. Arbitrary climate variability sensitivity tests were conducted at three sites in the North China Plain to test maize model responses to a range of changes (0%, +10%, and +20%) inthe monthly standard deviations of temperature and monthly variation coefficients of precipitation. The results from the three sites showed that incremental climate variability caused simulated yield decreases, and the decreases in rainfed yield were greater than those of irrigated yield.
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  • 79
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    Water, air & soil pollution 92 (1996), S. 87-94 
    ISSN: 1573-2932
    Keywords: Sri Lanka ; agriculture ; tea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The tea industry is Sri Lanka's main net foreign exchange earner and source of income for the majority of laborers. Tea yield is greatly influenced by weather, and especially by droughts, which cause irreparable losses because irrigation is seldom used on tea plantations. At the other extreme, heavy rains erode top soil and wash away fertilizers and other chemicals. In the recently published Sri Lanka country report on climate change, it was reported that the island will experience extreme rainfall intensities and warmer temperatures as a result of climate change. The possibility of a 10% increase in the length of dry and wet seasons per year in the main plantation area was also indicated. Thus both drought damages and soil losses in tea production areas will increase in the years to come. An analysis of the results of field experiments with weather data shows that increases in temperature, soil moisture deficit, and saturation vapor pressure deficit in the low elevations will adversely affect growth and yield of tea. Reports have also shown that about 30 cm of soil has already been eroded from upland tea plantations. Under these circumstances, the tea industry in Sri Lanka is clearly vulnerable to predicted climate changes, and subsequently greater economic, social, and environmental problems. This paper discusses the various aspects of the adverse effects of climate change on Sri Lanka's tea industry.
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  • 80
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    Water, air & soil pollution 92 (1996), S. 343-374 
    ISSN: 1573-2932
    Keywords: long-range transport ; atmospheric deposition ; heavy metals ; country budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Heavy Metal Eulerian Transport (HMET) model has been used to calculate the exchange of As, Cd, Pb and Zn between European countries in 1985. The model was run separately for each emitter country and the computed deposition field was used to calculate the contribution of the emitter to each receptor country. The results of these computations are presented in the form of a country budget matrix for each metal. Accuracy of such computations is dependant on the size and linearity of the numerical method applied to the transport equation. Exchange of heavy metals due to atmospheric transport over Europe is significant. Approximately 30% to 90% of the heavy metals emitted from each country is deposited in other countries. The remaining mass is deposited in European seas, Atlantic Ocean and transported outside the model domain. The largest part of the emission from each country is deposited in the same country. The next largest fraction is transported to the nearest neighbors. The results indicate also a significant long range ransport of heavy metals to the Soviet Union. This is partly justified by the size and location of this receptor country, as well as, the prevailing meteorological conditions in Europe. However, this large transport to USSR is slightly overestimated due to some artificial properties of the numerical method applied to basic model equations. In addition to the country budget, export versus import and emission versus deposition of metals were analyzed for each country. The largest positive difference between export and import was found for Poland, German Federal Republic and Yugoslavia (As, Cd and Zn), and United Kingdom, Italy and Belgium (Pb). The Soviet Union and Czechoslovakia are the countries where import of all metals is significantly larger than export. When emission versus deposition of heavy metals is analyzed, the Soviet Union has much higher emissions than deposition of all metals compared to other European countries.
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  • 81
    ISSN: 1573-2959
    Keywords: heavy metals ; organochlorines ; red fox
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Heavy metals and organochlorine contamination were analyzed in tissues of red foxes (Vulpes vulpes) from the Province of Siena (central Italy). Mercury (Hg), cadmium (Cd) and lead (Pb) concentrations were assessed in liver tissues and the data were analyzed for differences in relation to sex and age. Overall Hg, Cd and Pb mean values were 0.16, 0.62 and 0.64 μg g_1 d.w., respectively. HCB, DDT and PCB concentrations were assayed in fatty tissues and muscle. The highest levels of those pollutants were found in muscle (0.47, 1.16 and 20.2 μg g_1 lipid basis of HCB, DDTs and PCBs respectively), rather than in fat (0.23, 0.49 and 7.2 μg g_1 l.b. of HCB, DDTs and PCBs respectively). Pollutant accumulation was analyzed in relation to sex, age and sexual maturity of females.
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    Environmental monitoring and assessment 54 (1999), S. 229-237 
    ISSN: 1573-2959
    Keywords: coastal index ; discriminant analysis ; fishing areas ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The quality assessment of fishing areas on the basis of the levels of heavy metals in clams ( Chamelea gallina) was attempted by using discriminant analysis. Five metals, Hg, Pb, Cd, Cu and Zn, were analyzed in the soft edible parts of clams from three fishing areas. The descriptive methods applied to data obtained do not show enough differences between sampling stations for management purposes. Only discriminant analysis is successful in the differentiation between all fishing areas. Through the first discriminant function, the group centroids are proposed as index of different source of clams. These values standardized are proposed as coastal quality index.
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    Environmental monitoring and assessment 56 (1999), S. 177-193 
    ISSN: 1573-2959
    Keywords: accumulation ; bioindicators ; concentrations ; heavy metals ; Karelia ; wildlife
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The levels of mercury, cadmium, lead, copper, nickel, zinc and iron were determined in samples of liver, kidney, skeletal muscle, heart, lungs and hair of moose (N = 67), reindeer (N = 45), brown bear (N = 18), wild boar (N = 10) and squirrel (N = 18) shot in Karelia from 1989 to 1991 during regular hunting. The highest heavy-metal concentrations were found in livers, kidney, lungs and hair samples. The samples of muscle contained lowest levels of these elements. The tissues of moose, reindeer and brown bear were contaminated with heavy metals to a greatest extent. Lowest levels of toxicants were recorded in wild boar. Results indicate a widespread presence of heavy metal in the environment and in wildlife, which may be linked to acid precipitation. There was no evidence of these elements accumulated to toxic levels, but Karelian public have been informed that the eating of moose liver and kidney would probably result in their exceeding WHO standard weekly intake limit for cadmium.
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    Environmental modeling and assessment 4 (1999), S. 115-132 
    ISSN: 1573-2967
    Keywords: agriculture ; land use ; wheat production ; simulation models ; China
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract CERES-Wheat, a dynamic process crop growth model, is specified and validated for eight sites in the major wheat-growing regions of China. Crop model results are then used to test the Mitscherlich-Baule and the quadratic functional forms for yield response to nitrogen fertilizer, irrigation water, temperature, and precipitation. The resulting functions are designed to be used in a linked biophysical-economic model of land-use and land-cover change in China. While both functions predict yield responses adequately, the Mitscherlich-Baule function is preferable to the quadratic function because its parameters are biologically and physically realistic. Variables explaining a significant proportion of simulated yield variance are nitrogen, irrigation water, and precipitation; temperature was a less significant component of yield variation within the range of observed year-to-year variability at the study sites. Crop model simulations with a generic soil with median characteristics of the eight sites compared to simulations with site-specific soils showed that agricultural soils in China have similar and, in general, low-to-moderate water-holding capacities and organic matter contents. The validated crop model is useful for simulating the range of conditions under which wheat is grown in China, and provides the means to estimate production functions when experimental field data are not available.
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    Environmental modeling and assessment 4 (1999), S. 287-294 
    ISSN: 1573-2967
    Keywords: risk analysis ; global change ; agriculture
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A novel approach to the problem of estimating climate impact on social systems is suggested. This approach is based on a risk concept, where the notion of critical events is introduced and the probability of such events is estimated. The estimation considers both the inherent stochasticity of climatic processes and the artificial stochasticity of climate predictions due to scientific uncertainties. The method is worked out in some detail for the regional problem of crop production and the risks associated with global climate change, and illustrated by a case study (Kursk region of the FSU). In order to get local climatic characteristics (weather), a so-called “statistical weather generator” is used. One interesting finding is that the 3% risk level remains constant up to 1.0–1.1°C rise of mean seasonal temperature, if the variance does not change. On the other hand, the risk grows rapidly with increasing variance (even if the mean temperature rises very slowly). The risk approach is able to separate two problems: (i) assessment of global change impact, and (ii) decision making. The main task for the scientific community is to provide the politicians with different options; the choice of admissible (from the social point of view) critical events and the corresponding risk levels is the business of decision makers.
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    Environmental and ecological statistics 1 (1994), S. 21-36 
    ISSN: 1573-3009
    Keywords: agriculture ; economic index ; statistical tests ; total factor productivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract An agricultural system is sustainable if productive output is maintained economically over time when assessed in relation to environmental concern. This paper considers ways of statistically evaluating measures of sustainability illustrated by reference to extensive data from the Classical Experiments at Rothamsted.
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    Ecotoxicology 3 (1994), S. 180-192 
    ISSN: 1573-3017
    Keywords: adaptation ; damage ; drought ; fluorinated compounds ; heavy metals ; phytochelatins ; proline ; putrescine ; seleno amino acids ; stress
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The potential of metabolites, enzymatic processes and changes in plant performance as biomarkers in environmental assessment is reviewed. Biomarkers may be used as an early warning system of specific or general stress at each biological level, from molecules to ecosystems. The sensitivity of a species and, thus, the efficiency of a biomarker will depend on the degree of already present adaptation to environmental stress and on the homogeneity of the investigated population. Biomarkers for specific environmental stresses are scarce; better known are biomarkers for environmental stress complexes such as heavy metals, physiological drought and extreme temperature or biomarkers as a reaction on a full scale of environmental stresses. It is argued that a battery of biomarkers is necessary to evaluate chemical hazards to species.
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  • 88
    ISSN: 1573-3017
    Keywords: striped bass ; opossum shrimp ; agriculture ; toxicity ; bioassay
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The striped bass (Morone saxatilis) population of the Sacramento-San Joaquin Delta has declined approximately 80% since the mid-1970s. This decline has been attributed to factors such as water diversions, pollution and reduced abundance of food organisms. One source of potential pollutants is agricultural return water. The Colusa Basin Drain discharges water from over 150 000 acres and can account for over 20% of the flow of the Sacramento River. Because discharge occurs at the same time striped bass are spawning, early developmental stages could be adversely affected. Toxicity studies conducted over a 3 year period consistently demonstrated acute toxicity to striped bass larvae and to opossum shrimp (Neomysis mercedis), an important food organism for juvenile striped bass. Acute toxicity was also demonstrated with striped bass embryos. In addition, a model based on pesticide use more effectively predicted striped bass recruitment during the period of decline than did a model based on historically important river flows and delta diversions. These studies indicate that agricultural return water should not be disregarded when considering potential causes of the decline of striped bass.
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  • 89
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    Ecotoxicology 7 (1998), S. 161-173 
    ISSN: 1573-3017
    Keywords: copper ; heavy metals ; laboratory experiment ; soft sediment ; macrofauna ; assemblages
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Assemblages of marine benthic invertebrates have been shown to differ in areas with or without contamination by heavy metals. In this study, soft sediment assemblages were exposed to sediments and water treated with copper (in the form of Cu EDTA) in a laboratory experiment to test the hypothesis that copper could create differences in infaunal assemblages. The patterns of survival of all taxa were monitored and compared to the controls. Copper was found to reduce the abundance of most taxa, but the size of the response varied between taxa. Crustaceans were particularly sensitive to both the laboratory conditions and copper and were the most severely affected. Polychaetes were more resilient, surviving well in the controls and being reduced in abundance in polluted treatments, but with some families persisting in even the severely polluted treatment until the end of the experiment. Bivalves and gastropods were also reduced in number in the polluted treatments and unaffected in the controls. Oligochaetes and nemerteans did not respond in any particular pattern to any treatment or control. The results are discussed in relation to extrapolating results from ecotoxicological studies to predictions of ecosystem response to heavy metal pollution and pollution in general. It is concluded that laboratory ecotoxicological studies provide excellent evidence for potential effects. If used in collaboration with surveys and manipulative experiments in the field they can demonstrate causal links between pollutants and environmental impacts.
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  • 90
    ISSN: 1573-3017
    Keywords: NOEC ; competition ; biodiversity ; nematodes ; heavy metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In estimating the effects of toxic substances on ecosystems we generally lack information on the sensitivity (expressed as a no-observed effect concentration, NOEC) of individual species in the field, and have to rely on information from laboratory test species, expressed as a frequency distribution of NOECs. In this case we can express toxic stress as the fraction of organisms that is exposed above its NOEC: the potentially affected fraction (PAF). This paper describes a model of the soil food web and the effect of toxic stress by persistent pollutants. The model predicts that in the absence of competition, individual species disappear from the foodweb at toxic concentrations 3–5 times their NOEC. With competition present, species affected by toxic stress are replaced by less sensitive ones. This has a twofold effect: species disappear from the foodweb at a lower concentration because loss of competitiveness occurs well before absolute extinction, but the replacement of disappearing species implies that the effect on total biomass and diversity becomes only noticeable at a PAF level near 100%. Model predictions are in good agreement with observations on nematode communities in experimental fields contaminated with copper and zinc. The model serves to illustrate why overall measures of ecosystem functioning (total biomass, production, diversity) are affected by toxic stress only at high levels of pollution, which is particularly true for systems with a high diversity. This apparent robustness masks a considerable genetic ‘erosion’, i.e. the disappearance of sensitive species or genotypes. The PAF is a good indicator of the latter effect.
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  • 91
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    Journal of agricultural and environmental ethics 6 (1993), S. 1-19 
    ISSN: 1573-322X
    Keywords: agroecosystems ; agriculture ; ecology ; sustainability ; biodiversity ; competition ; succession ; culture
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract In the final analysis, sustainable agriculture must derive from applied ecology, especially the principle of the regulation of the abundance and distribution of species (and, secondarily, their activities) in space and time. Interspecific competition in natural ecosystems has its counterparts in agriculture, designed to divert greater amounts of energy, nutrients, and water into crops. Whereas natural ecosystems select for a diversity of species in communities, recent agriculture has minimized diversity in favour of vulnerable monocultures. Such systems show intrinsically less stability and resilience to perturbations. Some kinds of crop rotation resemble ecological succession in that one crop prepares the land for successive crop production. Such rotations enhance soil organic processes such as decomposition and material cycling, build a nutrient capital to sustain later crop growth, and reduce the intensity of pest buildup. Species in natural communities occur at discrete points along the r-K continuum of reproductive maturity. Clearing forested land for agriculture, rotational burning practices, and replacing perennial grassland communities by cereal monocultures moves the agricultural community towards the r extreme. Plant breeders select for varieties which yield at an earlier age and lower plant biomass, effectively moving a variety towards the r type. Features of more natural landscapes, such as hedgerows, may act as physical and biological adjuncts to agricultural production. They should exist as networks in agricultural lands to be most effective. Soil is of major importance in agroecosystems, and maintaining, deliberately, its vitality and resilience to agricultural perturbations is the very basis of sustainable land use.
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  • 92
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    Journal of agricultural and environmental ethics 8 (1995), S. 17-29 
    ISSN: 1573-322X
    Keywords: pesticides ; pests ; targets ; application ; technology ; agriculture ; environment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract Less than 0.1% of pesticides applied for pest control reach their target pests. Thus, more than 99.9% of pesticides used move into the environment where they adversely affect public health and beneficial biota, and contaminate soil, water, and the atmosphere of the ecosystem. Improved pesticide application technologies can improve pesticide use efficiency and protect public health and the environment.
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  • 93
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    Water, air & soil pollution 102 (1998), S. 313-328 
    ISSN: 1573-2932
    Keywords: dredged sediment derived surface soils ; heavy metals ; sedimentdisposal site ; sequential extraction DTPA
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The objective of this study was to characterise pollution with heavy metals in surface soils sampled at various dredged sediment disposal sites in the Flemish region (Belgium). The sites selected varied in the period since sediment disposal ceased and in current vegetation and land use. Total metal contents (Cd, Co, Cu, Fe, Mn, Ni, Pb, and Zn) in the surface soils varied widely. For some disposal sites Cd and Zn concentrations greatly exceeded reference values for clean soil. The distribution of the metals as determined by sequential extraction differed between elements, but was simular for all the soils. This suggested that metals in these sediment derived surface soils were accumulated and transformed in a similar way. Residual fractions were low compared to total contents (2 – 4% for Cd, 25% – 35% for Co, 7 – 18% for Mn, 4 – 22% for Zn, 12 – 41% for Ni, 11 – 42% for Pb, 20 – 45% for Cu, 〈 10% for Zn). High metal concentrations in the acid-extractable and reducible fractions may indicate pollution from anthropogenic sources. DTPA-extractable metals, which may be considered indicative of plant-available contents, were relatively high compared to the total contents. The relative extractability, expressed as the ratio of DTPA-extractable to total contents, decreased in the order Cd (38%) 〉 Cu (28%) = Zn (26%) 〉 Pb (13%) 〉 Ni (10%) 〉 Co (3%). Most of the sites studied would be of concern if they were used for agricultural activities. No trends in metal availability in the period following disposal were apparent from the data.
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  • 94
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    Water, air & soil pollution 109 (1999), S. 1-15 
    ISSN: 1573-2932
    Keywords: EDTA ; heavy metals ; leaching ; lead ; soil remediation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The performance of EDTA for the treatment of calcareous soils contaminated with heavy metals from mining and smelting activities was evaluated in this study. Soil samples containing variable levels of contamination, from 500 to 35 000 mg kg-1 Pb and 700 to 20 000 mg kg-1 Zn, were subjected to EDTA treatment and the extraction of heavy metals was found to vary, ranging between 50 and 98% for Pb and 50 to 100% for Zn. Total residual concentrations were above the limits set by regulatory authorities; leachable metals, however, were efficiently removed and treated soils were all acceptable in terms of toxicity. The effect of EDTA concentration and pulp density was studied on a soil sample containing 12 000 mg kg-1 Pb and 10 000 mg kg-1 Zn. Heavy metals removal was improved at low pulp densities and when EDTA concentration was increased from 0.025 to 0.25 M. The tetrasodium salt Na4-EDTA was found to be less effective for metals removal compared to the disodium salt Na2-EDTA, though applied at higher concentrations. This experimental work has also demonstrated the great importance of soil matrix for the overall evaluation of the EDTA leaching as a cost effective remedial option. The simultaneous dissolution of calcite was found to consume approximately 90% of the available EDTA. It was thus concluded that for the treatment of calcareous soils the design criteria and cost estimations should be based on the calcite content of the soil.
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  • 95
    ISSN: 1573-2932
    Keywords: critical load ; deposition ; heavy metals ; persistent organic pollutants ; soil quality ; water quality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In the pilot study ESQUAD the impact of atmospheric deposition of three heavy metals (cadmium, copper and lead) and two persistent organic pollutants (benzo(a)-pyrene and lindane) on the quality of European soils and seawater has been calculated. Calculations have been made of atmospheric transport and deposition using a detailed emissions database for Europe. This enabled deposition maps to be produced to a resolution of approximately 50 km. The distribution of pollutant concentrations in forest soils was calculated for each grid cell using a database of soil property parameters in Europe. For the North Sea, a model was used to map long-term concentrations in water and sediment, which are due to atmospheric deposition and other, non-atmospheric sources. The model calculations allowed detailed comparisons of deposition fluxes and concentrations of the substances studied with critical loads and environmental quality threshold values, including critical loads. Although significant uncertainties were identified, the study gives insight in how threshold exceedance rates in Europe relate to pollutant type, threshold type, environmental compartment and chemophysical phase (adsorbed, dissolved). For all pollutants and for all compartments exceedances were calculated for at least some of the quality thresholds that were chosen.
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  • 96
    ISSN: 1573-2932
    Keywords: anions ; cations ; chemical composition ; heavy metals ; rain
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Precipitation events were collected during the period from October 1996 to April 1997 from two sites in the city of Amman, Jordan. The samples were analyzed for major cations (Na+, K+, Ca2+, Mg2+ and NH4+), major anions (F-, Cl-, NO3- and SO42-), in addition to heavy metals (Cu2+, Cd2+, Zn2+, and Pb2+). High levels of Ca2+ and SO42- were observed. The results were comparable with some regional values and they indicate that about 58% of Na+ and Cl- are of marine origin, while Ca2+, K+ and a large fraction of SO42- are of soil dust origin. Heavy metals were detectable in most of the samples, zinc showed the highest concentrations. Significant correlation was obtained between zinc and lead, which may indicate automobile emission source.
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  • 97
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    Water, air & soil pollution 112 (1999), S. 21-40 
    ISSN: 1573-2932
    Keywords: China ; eutrophication ; heavy metals ; palaeolimnology ; spheroidal carbonaceous particles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract There is growing concern about the environmental impact of rapid economic growth in China. The problem is compounded by the scarcity of baseline data on the state of China's natural environment. As a step towards solving this problem, palaeolimnological methods have been applied to seven lakes in the Jianghan Plain, China, to evaluate recent changes in human impact. Lake sediment cores show enhanced concentrations of fossil fuel derived spheroidal carbonaceous particles (SCP) and Pb at all sites across the Jianghan Plain. The distribution of these industrial contaminants shows the overwhelming influence of the industrial cities. Wuhan dominates the fossil fuel derived pollution, while the copper smelter at Daye dominates the heavy metal pollution. Analysis of sediment diatom assemblages indicates mean total phosphorus concentrations of greater than 40 μg L-1 P in the lakes of the more intensely agricultural western part of the Jianghan Plain. The sediment concentration profiles for biogenic elements at these sites indicates a post-1960 eutrophication. Evidence for eutrophication in the eastern lakes is much weaker, though some evidence is present at all sites. The tracers of industrial pollution (Pb and SCP) correlate with Mn in the many of the lake sediments. This is compatible with both soil acidification, and soil gleyification due to intensified rice production.
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  • 98
    ISSN: 1573-2932
    Keywords: arid-zone soils ; field capacity ; fractionation ; heavy metals ; kinetics ; redistribution ; transformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Solid-phase transformation of added Cd, Cu, Cr, Ni, Pb and Zn, in two arid-zone soils incubated in the field capacity moisture regime for one year, were studied. The heavy metals were fractionated into six empirically defined fractions using a selective sequential dissolution (SSD) protocol optimized for arid-zone soils. Each of these fractions was named based on the major soil component targeted for dissolution during the specific SSD step, but it is not assumed that they are mineralogically and chemically totally specific. The transformations of the metals in the two soils incubated at the field capacity regime were compared with those at the moisture saturation regime (Han and Banin, 1997). An initial fast stage of transformation of the soluble metals from the exchangeable (EXC) fraction to the less labile fractions (the carbonate (CARB) fraction for Cd, Pb, Zn, Ni and Cu, and the organic matter (OM) fraction for Cr, and to some extent Cu and Ni) occurred during the fractionation and within one hour after addition. This was followed by a second stage, involving long-term transformation processes of all metals: added Cd was transferred from the EXC into the CARB fraction; added Cr was transferred from the CARB to the OM fraction and Pb was transferred very slowly to the easily reducible oxide (ERO) fraction. Added Cu, Ni and Zn were transferred from the EXC and CARB fractions into the ERO fraction and to some extent OM and RO fractions. In Part I of this series, we reported that during incubation in the saturated moisture regime, Zn and Ni were transferred mainly into the RO and OM fractions. Cadmium, Cr and Pb underwent the same transformation pathways during the slow long-term process, with slightly different rates, in both water regimes. At low levels of addition, the incubated soils moved over one year towards a distribution similar to that of the native soil. At higher levels, the soils still remained removed from the quasi-equilibrium which characterized the native soil, even at the end of one year of incubation.
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  • 99
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    Water, air & soil pollution 114 (1999), S. 377-394 
    ISSN: 1573-2932
    Keywords: heavy metals ; snow quality ; urban snow
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The aim of the study was to investigate how the quality of snow varies within a city. The study area is situated in the Luleå municipality, in northern Sweden (lat. 65°35′N and long. 22°10′E). For this study, the city was divided into three different types of areas: housing areas, city centre and outskirts. In one area of each type, sampling sites were selected. Snow samples were taken at nine occasions, once every fourteenth day in the city centre and in the housing area. Analyses were carried out for pH, conductivity, suspended solids and both the total and dissolved concentration of phosphorus and selected metals. It was concluded that traffic or activities related to traffic were a major source of heavy metals and phosphorus in urban snow, both in the city centre and in the housing area. Also, the type of area and the design of the street were important for the quality of snow. A clear relation was found between the pH and the quantity of suspended solids in the snow. Higher pH values were found in snow samples from sites with higher traffic loads, and lower pH values at sites, which were the no-traffic sites, with small quantities of particles. The particulate and dissolved substances in the snow behaved in different ways.
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  • 100
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    Water, air & soil pollution 91 (1996), S. 233-248 
    ISSN: 1573-2932
    Keywords: Arabian Gulf ; Bahrain ; heavy metals ; marine organisms ; provisional tolerable weekly intake
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A total of 162 fish and shellfish samples representing important species have been collected from different coastal areas of Bahrain in the Arabian Gulf, and analyzed for lead, cadmium, mercury, and arsenic using electrothermal atomic absorption spectrophotometric method. The dverall mean levels for Pb, Cd, Hg and As in fish samples were 0.132, 0.032, 0.084 and 1.7 µg g−1 wet weight, respectively, whereas for shellfish they were 0.149, 0.045, 0.042 and 3.61 µg g−1 wet weight. These values indicate higher levels of metals in shellfish when compared with fish, except for mercury, and reveal that generally the levels of metals in these organisms are lower than existing guidelines, except for arsenic. The provisional tolerable weekly intake of Pb, Cd, Hg and As through fish was estimated to be 0.7, 0.17, 0.45 and 9 µg kg−1 bodyweight per week, respectively. Our results did not reveal a clear pattern regarding variations of metals concentration between areas and species.
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