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  • polyethoxydisiloxanes  (1)
  • silica film  (1)
  • 2000-2004  (2)
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  • 2000-2004  (2)
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  • 1
    ISSN: 1573-4846
    Schlagwort(e): sol-gel process ; silica film ; AFM ; refractive index
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Scratch-resistance of sol-gel derived nano porous silica films were studied. The thin films were prepared with a dip-coating method from both one-step and two-step catalyzed silica sols, and treated in a mixture gas of ammonia and water vapour afterwards. The thin films were characterized by using Atomic Force Microscope (AFM), ellipsometer, Fourier-transform Infrared Spectroscope (FTIR), respectively. Experimental results have shown that the two-step catalysis remarkably improves strength of the films, and abrasion-resistance and adhesion of the silica films were further increased after the mixture gas treatment. It is attributed to the cross-linking of silica particles in the sols by randomly branched or/and entangled linear chains and more Si–O–Si bonds formed by the mixture gas treatment.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of sol gel science and technology 19 (2000), S. 677-680 
    ISSN: 1573-4846
    Schlagwort(e): silica aerogel ; sol-gel ; polyethoxydisiloxanes ; supercritical drying
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Silica aerogels were made by sol-gel techniques using industrial silicon derivatives (polyethoxydisiloxanes, E-40), followed by supercritical drying with ethanol. The morphology and microstructure of the silica aerogels were investigated by using specific surface area, SBET, SEM, TEM and the pore size distribution techniques. The thermal conductivity was also measured as a function of air pressure. The results show that the diameter of the silica particles is about 13 nm and the pore size of the silica aerogels is 20–80 nm. The specific surface area of the silica aerogel is about 470 m2/g and the thermal conductivity of the silica aerogel prepared with E-40 is 0.014 w m−1 K−1 at room temperature and 1 atm.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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