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  • Artikel  (47)
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  • Springer  (47)
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Thema
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of polymers and the environment 8 (2000), S. 151-154 
    ISSN: 1572-8900
    Schlagwort(e): Lyocell ; cellulose ; rheology ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Energietechnik , Maschinenbau
    Notizen: Abstract Rheological measurements were used to characterize the behavior of lyocell solutions, i.e., cellulose dissolved in N-methymorpholine-N-oxide. Cellulose sources included dissolving pulp, kraft pulp, sugar cane fibers, and kenaf fibers. The dominance of viscous behavior, G′ values, over elastic behavior, G″ values, is affected by cellulose concentration and molecular weight. At lower concentrations and degrees of polymerization (DP), dissolving pulp solutions show viscous, inelastic behavior at low frequencies. At higher concentration and DP, dissolving pulp solutions are more elastic at higher frequencies. Solutions prepared with kenaf and sugar cane fibers show similar properties to those using pure dissolving pulp, and comparisons suggest the molecular weight and/or the presence of other substances such as lignin in the cellulose from these alternative sources affect the rheology.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of polymers and the environment 8 (2000), S. 145-150 
    ISSN: 1572-8900
    Schlagwort(e): Starch ; particle size ; composite ; viscosity ; polyester
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Energietechnik , Maschinenbau
    Notizen: Abstract The effect of starch granule size on the viscosity of starch-filled poly(hydroxy ester ether) (PHEE) composites was characterized using size-fractionated potato starch, as well as unfractionated starches (rice, corn, wheat, and potato). Potato starch was separated using an air classifier into four particle size fractions: 〈18 μm, 18-24 μm, 24-30 μm, and 〉30 μm. The starch was dried to a moisture content of 0.5% to minimize moisture effects on composite rheology. PHEE and potato starch were extruded with starch volume fractions of 0.46 and 0.66. Stress relaxation, frequency and strain sweep, and temperature-dependence measurements were carried out. Although small variations in viscosity were seen with the different potato starch fractions, differences were not significant at a volume fraction of 0.46. Viscosity differences between the different particle size fractions were more pronounced at a volume fraction of 0.66. The temperature dependence could be described by an Arrhenius relation, with an apparent activation energy of 84 kJ/mole. At a volume fraction of 0.46, the starch/PHEE viscosities increased in the order potato starch 〈 wheat starch ≃ corn starch 〈 rice starch.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 5 (1972), S. 113-125 
    ISSN: 1572-9613
    Schlagwort(e): Nonequilibrium thermodynamics ; electrolyte solution ; high-temperature plasma ; state variable ; forces and fluxes ; nonlocal linear relation ; Onsager reciprocity ; hydrodynamic equation of motion for component ; Navier-Stokes equation ; diffusion ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Ahydrodynamic equation of motion for each component of a multicomponent fluid is derived on the basis of nonequilibrium thermodynamics. Special care has been directed to the choice of state variables. In some limiting cases, this equation leads to customary phenomenological equations, such as the equation for diffusion and the Navier-Stokes equation. The viscosity is a consequence of nonlocal coupling of forces and fluxes. The reciprocity between the linear coefficients is examined closely.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 20 (2000), S. 279-297 
    ISSN: 1572-8986
    Schlagwort(e): Transport coefficients ; transport properties ; viscosity ; thermal conductivity ; electrical conductivity ; diffusion coefficient ; Chapman–Enskog method ; hydrogen ; argon ; plasma
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract Calculated values of the viscosity, thermal conductivity, and electrical conductivity of hydrogen and mixtures of argon and hydrogen at high temperatures are presented. Combined ordinary, pressure, temperature, and electric field diffusion coefficients are also given for the mixtures. The calculations, which assume local thermodynamic equilibrium, are performed for atmospheric pressure plasmas in the temperature range from 300 to 30,000 K. The results are compared with those of previously published studies. Generally, the agreement is reasonable; those discrepancies that exist are attributed to the improved values of some of the collision integrals used here in calculating the transport coefficients.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Springer
    Journal of fluorescence 10 (2000), S. 161-161 
    ISSN: 1573-4994
    Schlagwort(e): Excited state ; quinolyl ; structural relaxation ; viscosity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract The absorption and fluorescence spectra of five cations protonated at the quinolyl nitrogen atom (IH+−VH+) and one ethylated (IEt+) cation were investigated. For these compounds (except VH+) both an anomalously large fluorescence Stokes shift (up to 238 nm) and a large short-wavelength fluorescence shift (up to 145 nm) at decreasing temperatures (down to 77 K) were observed. This is not the case for unprotonated molecules. The ground-state conjugation between quinolyl and another molecular fragment was found for II, IH+, IIH+, and IEt+. The relaxation process of excited cations is medium viscosity and temperature dependent. The experimental results are explained in terms of excited-state structural relaxation.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical geology 3 (1971), S. 227-238 
    ISSN: 1573-8868
    Schlagwort(e): classification ; data processing ; graphics ; mapping ; mathematics ; plotting ; sampling ; statistics ; sedimentology ; stratigraphy ; grain-size analysis ; textural analysis ; glacial geology ; Pleistocene stratigraphy ; till
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Mathematik
    Notizen: Abstract Relative percentages of sand, silt, and clay from samples of the same till unit are not identical because of different lithologies in the source areas, sorting in transport, random variation, and experimental error. Random variation and experimental error can be isolated from the other two as follows. For each particle-size class of each till unit, a standard population is determined by using a normally distributed, representative group of data. New measurements are compared with the standard population and, if they compare satisfactorily, the experimental error is not significant and random variation is within the expected range for the population. The outcome of the comparison depends on numerical criteria derived from a graphical method rather than on a more commonly used one-way analysis of variance with two treatments. If the number of samples and the standard deviation of the standard population are substituted in at-test equation, a family of hyperbolas is generated, each of which corresponds to a specific number of subsamples taken from each new sample. The axes of the graphs of the hyperbolas are the standard deviation of new measurements (horizontal axis) and the difference between the means of the new measurements and the standard population (vertical axis). The area between the two branches of each hyperbola corresponds to a satisfactory comparison between the new measurements and the standard population. Measurements from a new sample can be tested by plotting their standard deviation vs. difference in means on axes containing a hyperbola corresponding to the specific number of subsamples used. If the point lies between the branches of the hyperbola, the measurements are considered reliable. But if the point lies outside this region, the measurements are repeated. Because the critical segment of the hyperbola is approximately a straight line parallel to the horizontal axis, the test is simplified to a comparison between the means of the standard population and the means of the subsample. The minimum number of subsamples required to prove significant variation between samples caused by different lithologies in the source areas and sorting in transport can be determined directly from the graphical method. The minimum number of subsamples required is the maximum number to be run for economy of effort.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical geology 3 (1971), S. 335-355 
    ISSN: 1573-8868
    Schlagwort(e): nearest neighbor analysis ; regression analysis ; statistics ; trend analysis ; structure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Mathematik
    Notizen: Abstract A quantitative analysis was made of the spatial arrangement of 149explosion craters in the western rift of Uganda. A variety of methods demonstrate that the spatial pattern of the craters reveals significant structural patterns that have guided volcanism to the surface. It is shown that the east-west elements in the field affected location, and the main rift fault is resolved into two main components. Tentatively, a possible dextral transform fault is identified that affected the relative location of the two main zones of activity. Grouping techniques demonstrate that crater groups obey an exponential rank-size rule and allow a mapping of the craters into energy classes that reveals a concentric pattern of energy in the field. The effect of the topography on energy levels and crater size show that only topography greater than 11,000ft could have prevented all eruptive activity, but the smaller energies and craters are sensitive to height differences on the order of the height of the rift wall, about 1000ft. Total energy in each crater class size is roughly constant, and the field energy could create one or two single craters comparable in size to small central volcanoes.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical geology 4 (1972), S. 1-24 
    ISSN: 1573-8868
    Schlagwort(e): discrete frequency distributions ; statistics ; general geology
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Mathematik
    Notizen: Abstract Geologists unfamiliar with the application of probability theory to discrete data in other fields of research are usually acquainted with only three discrete theoretical frequency distributions: Poisson, binomial, and negative binomial distributions. In some situations these distributions may fail to adequately describe a set of experimental data. Other distributions such as the Poisson with zeros, Neyman type A, logarithmic with zeros, Poisson-binomial, and Thomas double Poisson together with the more common Poisson, binomial, and negative binomial form a generalized subset of discrete theoretical distributions, one of which should fit almost any experimental data set. A computer program is presented which allows testing of any combination of these distributions against observed discrete data.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical geology 4 (1972), S. 147-153 
    ISSN: 1573-8868
    Schlagwort(e): classification ; statistical inference ; statistics ; geochemistry ; petrochemistry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Mathematik
    Notizen: Abstract This paper embodies petrographical and statistical investigations of three gabbro occurrences. The Mangaon and Kunkeri gabbros are similar in petrography and petrochemistry, whereas they are completely different from the Vajrat gabbro. Application of recently developed statistical tests help in classifying these gabbros by using three oxides, CaO, FeO, and K2O.This study shows that the evolution of the Mangaon and Kunkeri gabbros probably proceeded along different lines as compared to the Vajrat gabbro.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical geology 4 (1972), S. 203-218 
    ISSN: 1573-8868
    Schlagwort(e): correlated independent variables ; regression analysis ; ridge trace ; statistics ; trend analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Geologie und Paläontologie , Mathematik
    Notizen: Abstract Multiple linear regression analysis may be used to describe the relation of one geologic variable to a number of other (independent) variables, and also may be used to fit a trend surface to geographically distributed variables. The leastsquares estimates of the regression coefficients differ unpredictably from the true coefficients if the independent variables are correlated. The estimates can be too large in absolute value, and may have the wrong sign. Also, the least-squares solution may be unstable in that replicate samples can give widely differing values of the regression coefficients. Ridgeregression analysis is a technique for removing the effect of correlations from the regression analysis. The procedure involves addition of a small constant K to the diagonal elements of the standardized covariance matrix. The estimates obtained are biased but have smaller sums of squared deviations between the coefficients and their estimates. The ridge trace, a plot of the coefficients versus K, helps determine the value of K that stabilizes the estimates. Correlations between geologic variables are common, and regression coefficients based on these data may be suspect. In trendsurface analysis, correlations between the geographic coordinates may differ widely, and extreme correlations may be introduced if higher order terms are used in the trend. Ridgeregression analysis serves to guide the geologist to a more reliable interpretation of the results of multiple regression if the independent variables are correlated.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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