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  • American Chemical Society  (262,814)
  • Nature Publishing Group  (27,222)
  • 2000-2004  (148,239)
  • 1995-1999  (141,797)
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Year
  • 1
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    Bending-related faulting and mantle serpentinization at the Middle America Trench (2003)
    Nature Publishing Group
    Details
    Publication Date: 2023-09-26
    Description: The dehydration of subducting oceanic crust and upper mantle has been inferred both to promote the partial melting leading to arc magmatism and to induce intraslab intermediate-depth earthquakes, at depths of 50–300 km. Yet there is still no consensus about how slab hydration occurs or where and how much chemically bound water is stored within the crust and mantle of the incoming plate. Here we document that bending-related faulting of the incoming plate at the Middle America trench creates a pervasive tectonic fabric that cuts across the crust, penetrating deep into the mantle. Faulting is active across the entire ocean trench slope, promoting hydration of the cold crust and upper mantle surrounding these deep active faults. The along-strike length and depth of penetration of these faults are also similar to the dimensions of the rupture area of intermediate-depth earthquakes.
    Type: Article , PeerReviewed
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  • 2
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    Deep-breathing cephalopods? (1996)
    Nature Publishing Group
    In:  Nature, 384 (6608). p. 421.
    Details
    Publication Date: 2021-08-20
    Type: Article , PeerReviewed
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  • 3
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    Oceanic respite for wandering albatrosses (2000)
    Nature Publishing Group
    In:  Nature, 406 . pp. 955-956.
    Details
    Publication Date: 2021-07-01
    Description: Birds taking time off from breeding head for their favourite long-haul destinations. What oceanic seabirds do outside their breeding periods is something of a mystery, although altogether these "sabbaticals' add up to more than half of their lifetime and are probably a key feature of their life history. Here we use geolocation systems based on light-intensity measurements to show that during these periods wandering albatrosses (Diomedea exulans) leave the foraging grounds that they frequent while breeding for specific, individual oceanic sectors and spend the rest of the year there — each bird probably returns to the same area throughout its life. This discovery of individual home-range preferences outside the breeding season has important implications for the conservation of albatrosses threatened by the development of longline fisheries.
    Type: Article , PeerReviewed
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  • 4
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    Increased El Niño frequency in a climate model forced by future greenhouse warming (1999)
    Nature Publishing Group
    In:  Nature, 398 (6729). pp. 694-697.
    Details
    Publication Date: 2021-02-25
    Description: The El Niño/Southern Oscillation (ENSO) phenomenon is the strongest natural interannual climate fluctuation1. ENSO originates in the tropical Pacific Ocean and has large effects on the ecology of the region, but it also influences the entire global climate system and affects the societies and economies of manycountries2. ENSO can be understood as an irregular low-frequency oscillation between a warm (El Niño) and a cold (La Niña) state. The strong El Niños of 1982/1983 and 1997/1998, along with the more frequent occurrences of El Niños during the past few decades, raise the question of whether human-induced 'greenhouse' warming affects, or will affect, ENSO3. Several global climate models have been applied to transient greenhouse-gas-induced warming simulations to address this question4, 6, but the results have been debated owing to the inability of the models to fully simulate ENSO (because of their coarse equatorial resolution)7. Here we present results from a global climate model with sufficient resolution in the tropics to adequately represent the narrow equatorial upwelling and low-frequency waves. When the model is forced by a realistic future scenario of increasing greenhouse-gas concentrations, more frequent El-Niño-like conditions and stronger cold events in the tropical Pacific Ocean result
    Type: Article , PeerReviewed
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  • 5
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    Turned out nice again (2000)
    Nature Publishing Group
    In:  Nature, 404 (6780). p. 814.
    Details
    Publication Date: 2021-02-25
    Description: Book review of: The Change in the Weather: People, Weather, and the Science of Climate by William K. Stevens Delacorte: 2000. 432 pp. $24.95
    Type: Article , NonPeerReviewed
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  • 6
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    Sex in giant squid (1997)
    Nature Publishing Group
    In:  Nature, 389 (6652). pp. 683-684.
    Details
    Publication Date: 2021-02-15
    Description: Recent captures of two female giant squid ( Architeuthis ) off southern Australia have provided the first record of a mated female specimen of these almost mythical deepsea creatures. We found sperm packages (spermatophores) embedded within the skin of both ventral arms of the larger of the two specimens. It seems that male giant squids may use their muscular elongate penis to ‘inject’ sperm packages under pressure directly into the arms of females.
    Type: Article , PeerReviewed
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  • 7
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    Penicillium expansum : Consistent Production of Patulin, Chaetoglobosins, and Other Secondary Metabolites in Culture and Their Natural Occurrence in Fruit Products (2004)
    American Chemical Society
    In:  Journal of Agricultural and Food Chemistry, 52 (8). pp. 2421-2428.
    Details
    Publication Date: 2020-09-03
    Description: Penicillium expansum is known for its destructive rot and patulin production in apple juice. According to the literature, P. expansum can, among other compounds, produce citrinin, ochratoxin A, patulin, penitrem A, and rubratoxin B. In this study the qualitative production of metabolites was examined using TLC (260 isolates), HPLC (85 isolates), and MS (22 isolates). The results showed that none of the 260 isolates produced ochratoxin A, penitrem A, or rubratoxin B. However, chaetoglobosin A and communesin B were produced consistently by all 260 isolates. Patulin and roquefortine C were produced by 98% of the isolates. Expansolides A/B and citrinin were detected in 91 and 85% of the isolates, respectively. Chaetoglobosins and communesins were detected in naturally infected juices and potato pulp, whereas neither patulin nor citrinin was found. Because most P. expansum isolates produce patulin, citrinin, chaetoglobosins, communesins, roquefortine C, and expansolides A and B, foods contaminated with this fungus should ideally be examined for chaetoglobosin A as well as patulin.
    Type: Article , PeerReviewed
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  • 8
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    Gas Hydrates: Review of Physical/Chemical Properties (1998)
    American Chemical Society
    In:  Energy & Fuels, 12 (2). pp. 191-196.
    Details
    Publication Date: 2020-07-31
    Description: An overview is provided of time-independent physical/chemical properties as related to crystal structures. The following two points are illustrated in this review:  (1) Physical and chemical properties of structure I (sI) and structure II (sII) hydrates are well-defined; measurements have begun on sH. Properties of sI and sII are determined by the molecular structures, described by three heuristics:  (i) Mechanical properties approximate those of ice, perhaps because hydrates are 85 mol % water. Yet each volume of hydrate may contain as much as 180 volumes (STP) of the hydrate-forming species. (ii) Phase equilibrium is set by the size ratio of guest molecules within host cages, and three-phase (Lw−H−V) equilibrium pressure depends exponentially upon temperature. (iii) Heats of formation are set by the hydrogen-bonded crystals and are reasonably constant within a range of guest sizes. (2) Fundamental research challenges are (a) to routinely measure the hydrate phase (via diffraction, NMR, Raman, etc.), and (b) to formulate an acceptable model for hydrate formation kinetics. The reader may wish to investigate details of this review further, via references contained in several recent monographs.
    Type: Article , PeerReviewed
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  • 9
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    Aldisine alkaloids from the Philippine sponge Stylissa massa are potent inhibitors of mitogen-activated protein kinase kinase-1 (MEK-1) (2002)
    American Chemical Society
    In:  Journal of Medicinal Chemistry, 45 (2). pp. 529-532.
    Details
    Publication Date: 2020-07-23
    Description: Raf/MEK-1/MAPK cascade inhibitor activity-directed fractionation of the sponge Stylissa massa afforded eight known alkaloids:  aldisine (1), 2-bromoaldisine (2), 10Z-debromohymenialdisine (3), 10E-hymenialdisine (4), 10Z-hymenialdisine (5), hymenin (6), oroidin (7), and 4,5-dibromopyrrole-2-carbonamide (8). Both 4 and 5 showed significant enzyme inhibitory activity (IC50 3 and 6 nM, respectively). Secondary assays identified these compounds as potent MEK-1 inhibitors. Compounds 4 and 5 also inhibited the growth of human tumor LoVo cells.
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  • 10
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    Microcionamides A and B, bioactive peptides from the Philippine sponge Clathria (Thalysias) abietina (2004)
    American Chemical Society
    In:  Journal of Organic Chemistry, 69 (12). pp. 4170-4176.
    Details
    Publication Date: 2020-07-22
    Description: Microcionamides A (1) and B (2) have been isolated from the Philippine marine sponge Clathria (Thalysias) abietina. These new linear peptides are cyclized via a cystine moiety and have their C-terminus blocked by a 2-phenylethylenamine group. Their total structures, including absolute stereochemistry, were determined by a combination of spectral and chemical methods. Compound 1 was shown to slowly isomerize about the C-36/C-37 double bond when stored in DMSO. Microcionamides A (1) and B (2) exhibited significant cytotoxicity against the human breast tumor cells lines MCF-7 and SKBR-3 and displayed inhibitory activity against Mycobacterium tuberculosis H37Ra.
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