ALBERT

Description: Nanoindentation experiments were performed to investigate the irradiation effects on the mechanical properties of 6H-SiC irradiated by 4 MeV Kr ions at high fluences from room temperature (RT) to 550°C. The irradiation temperature is the primary factor that affects modifications of the comprehensive mechanical properties, while the effect of the fluence is less significant. Elastic modulus and hardness decrease drastically for RT-irradiated samples, but they almost recover for elevated temperature samples, with hardness slightly higher than its original value. The hardness increases first and then decreases with increasing temperature, and the elastic modulus decreases linearly as the swelling increases. Meyer's index is related to the indentation size effect of hardness and the magnitude of the lattice damage. The ratio of irreversible work is associated with the degree of elastic recovery and the ratio of hardness to elastic modulus of SiC. Compared with the unirradiated value, fracture toughness changes slightly for RT irradiation, while increasing significantly for elevated temperature irradiation and has the same variation tendency of hardness. Results indicate that mechanical properties change with the variations of interatomic bond strength, dislocation mobility, and the behavior of crack propagation, which is strongly affected by the defects induced by heavy-ion irradiation.

Description: In this study, based on self-reactive quenching technique, hollow ceramic microspheres (HCMs) containing barium ferrites were synthesized using Al+Fe 2 O 3 +BaO 2 +sucrose+ epoxy resin as the reactive system and polyethylene glycol (PEG) as the foaming agent. The influence of PEG on the particle size and microwave absorption properties of HCMs is investigated using SEM, XRD, laser particle size analyzer and vector network analyzer. Preliminary results show that the average particle size increases initially from 28 μm to 53 μm after adding PEG, as well as the particle distribution gets narrower and the surface takes on classical hexagonal crystals. BaFe 2 O 4 , the intermediate phase of M-type barium ferrites (BaFe 12 O 19 ), can be seen in XRD. The microwave absorption properties are improved greatly in the frequency range of 8–18 GHz. And the minimum reflection loss can reach −10 dB.

Description: Homogenous liquid precursor for ZrC – SiC was prepared by blending of Zr ( OC 4 H 9 ) 4 and Poly[(methylsilylene)acetylene]. This precursor could be cured at 250°C and converted into binary ZrC – SiC composite ceramics upon heat treatment at 1700°C. The pyrolysis mechanism and optimal molar ratio of the precursor were investigated by XRD. The morphology and elements analyses were conducted by SEM and corresponding energy-dispersive spectrometer. The evolution of carbon during ceramization was studied by Raman spectroscopy. The results showed that the precursor samples heat treated at 900°C consisted of t- ZrO 2 (main phase) and m- ZrO 2 (minor phase). The higher temperature induced phase transformation and t- ZrO 2 converted into m- ZrO 2 . Further heating led to the formation of ZrC and SiC due to the carbothermal reduction, and the ceramic sample changed from compact to porous due to the generation of carbon oxides. With the increasing molar ratios of C / Zr , the residual oxides in 1700°C ceramic samples converted into ZrC and almost pure ZrC – SiC composite ceramics could be obtained in ZS-3 sample. The Zr , Si , and C elements were well distributed in the obtained ceramics powders and particles with a distribution of 100 ~ 300 nm consisted of well-crystallized ZrC and SiC phases.

Description: The implementation of Ceramic Matrix Composites necessitates the understanding of stress-dependent damage evolution. Toward this goal, two liquid silicon infiltrated SiCf reinforced SiC composites were tensile tested with electrical resistance (ER) monitoring as well as acoustic emission to quantify matrix cracking. ER was modeled using a combination of resistors in series and parallel to model transverse matrix cracks and fiber/matrix segments between matrix cracks. It is shown that resistance change is sensitive to transverse matrix crack formation and stress-dependent debonding length. The model appears to be accurate up to the stress for matrix crack saturation.

Description: LaMgAl 11 O 19 -3 mol% yttria partially stabilized zirconia ceramics were successfully prepared by pressureless sintering at 1550°C for 3 h. The ceramic's mechanical properties were measured, and the phase composition and microstructure observed using X-ray diffraction and scanning electron microscopy. The results show that the mechanical properties of the ceramic were initially improved on addition of LaMgAl 11 O 19, but further additions were detrimental. When the amount of LMA added was equal to 2 wt.%, the bending strength and fracture toughness reached 812 ± 37 MPa and 14.0 ± 0.3 MPa·m 1/2 . This equates to an increase of 8.0% and 6.9% compared with untreated 3 mol% yttria partially stabilized zirconia (3YSZ) ceramic, respectively. However, the bending strength and fracture toughness both decreased when the amount of LaMgAl 11 O 19 added was 4 and 6 wt.%. A crack propagation and force analysis of the crack tips in LaMgAl 11 O 19 -platelet-reinforced 3YSZ ceramic were also carried out. The results indicate that phase transformation and crack deflection were the dominant toughening mechanisms in the LaMgAl 11 O 19 -3YSZ ceramic. At the same time, energy dissipation by the LaMgAl 11 O 19 platelets also helps to restrain crack propagation in the matrix, which improves toughness more effectively.

Description: Ce -doped BaTiO 3 -based ceramics were prepared and studied to satisfy ultra-broad temperature stability (from −55°C to 300°C, capacitance variation rate based on C 20°C is within ±15%). The sample with 0.6 mol% CeO 2 succeeds to achieve this performance with a remarkably high ceiling temperature of 300°C. Meanwhile, the sample has good dielectric and electrical properties at room temperature (ε r  = 1667, tanδ = 1.478%, ρ V  = 5.9 × 10 12  Ω·cm). Ce ion can substitute for Ti ion as Ce 4+ or Ba ion as Ce 3+ . The substitution decreases the spontaneous polarization of BaTiO 3 , and then weakens the ferroelectricity of BaTiO 3 . As a result, the temperature stability of samples is improved obviously. Besides, CeO 2 addition promotes the formation of exaggerated grains, which are consisting of Ba 6 Ti 17 O 40 .

Description: This study aims to optimize quantitative X-ray diffraction (XRD) mineralogical analysis of the minority phases in clinker. The proposed method consists of applying Rietveld quantitative refinement to the XRD patterns for both clinker and the insoluble residue remaining after it is attacked with methanol and salicylic acid (Takashima method). The method was tested with industrial clinker and the same material after modifying its mineralogy by refiring at 1500°C followed by slow cooling. The findings showed that the C 4 AF / C 3 A ratios for quickly and gradually cooled clinker were much higher when the clinker diffractograms were refined with the Rietveld procedure than when the proposed method was used. The proportion of C 3 A found with the proposed method was ≈2.8-fold higher than when Rietveld only was applied to the diffractograms for clinkers. Taken together, the refinement data for the two materials (clinker and Takashima residua) revealed that Rietveld quantitative XRD applied to clinker underestimates the low C 3 A content. These findings are supported by postsulfate attack durability studies conducted on cements prepared with the two clinkers.

Description: The effect of increasing poling fields on the properties of (1− x )BZT– x BCT compositions across the morphotropic phase boundary (MPB) is studied using large signal polarization and strain, small signal permittivity and piezoelectric coefficient, and XRD measurements. Successive poling causes charge carrier migration inducing an internal bias field, which becomes large with respect to the coercive field resulting in biased ferroelectric and ferroelastic switching. Improvements in piezoelectric coefficient of 9% are significantly smaller in the tetragonal 60BCT composition compared with the improvement of approximately 50% in the rhombohedral 40BCT and MPB 50BCT compositions. While the properties continue to change with increased poling fields, the remnant ferroelastic domain texture parallel to the field direction, as observed from XRD, stays approximately constant. The improvement in overall domain alignment leading to largely enhanced intrinsic piezoelectricity originates from the alignment of 180° domains and possibly non-180° domains in grains with orientations inclined to the electric field. As a result, poling is most effective in BZT–BCT materials that have low coercive fields, show low distortions and possess more polarization orientations, such as compositions in the rhombohedral phase field or near the MPB.

Description: The defect chemistry-modulated dielectric properties of dense yttria-doped zirconia ceramics prepared by conventional sintering (at 1350°C–1500°C) and electric field-assisted flash sintering (55 V/cm at 900°C) were studied by impedance spectroscopy. While the bulk dielectric properties from both sets of samples showed only small and insignificant changes in conductivity and permittivity, respectively, a huge increase of these properties was measured for the grain boundaries in the flash sintered specimens. A close analysis of these results suggests that flash sintering reduced grain-boundary thickness (by about 30%), while increasing the concentration of oxygen vacancies near these interfaces (by about 49%). The underlying mechanism proposed is electric field-assisted generation and accommodation of defects in the space-charge layers adjacent to the grain surface. The changes in measured permittivity are attributed to the boundary thickness effect on capacitance, while conductivity involved variations in its defect density-dependent intrinsic value, accounting for changes also observed in grain-boundary relaxation frequencies. Therefore, in terms of modifications to the specific dielectric properties of these materials, the overall consequence of flash sintering was to considerably lower the semi-blocking character of the grain boundaries.

Description: This article presents a detailed study on the nanoscaled interface between microelongated gold particles (GP) and biphase leucite/feldspar glass-ceramic matrix. The glass-ceramic composite with a nonuniform GP distribution was processed through hot-pressing under vacuum using a commercial dental ceramic furnace for glass-ceramic dental crown manufacturing. Heat treatments at 900°C, 1100°C, and 1300°C were conducted, and microstructural features along the interface were used to verify the chemical reactions between GP and glass-ceramic matrix. It was observed that the amorphous glass-ceramic matrix had nanoscaled biphase structures, and the distributed nanoscaled amorphous leucite phase was attracted to GP during hot-pressing, and was more reactive with GP than the feldspar phase. The thickness of the interfacial phase formed through chemical reactions between GP and glass-ceramic matrix is around 30 nm. The chemically bonded interface has contributed significantly toward the substantial improvements in both strength and toughness of the GP-reinforced glass-ceramic matrix composite. Characterization techniques, including X-ray diffraction and field-emission scanning electron Microscopy, incorporating X-ray microanalysis using energy dispersive spectrometry, have been employed in this study.

Description: The cyclic oxidation of bulk Ti 2 AlC at intermediate temperatures of 600–1000°C in air was studied by thermogravimetric analysis. It was demonstrated that Ti 2 AlC exhibited good cyclic-oxidation resistance at temperatures above 700°C. The cyclic-oxidation kinetics approximately follows a parabolic rate law at 700–1000°C range. The surface scales are dense, resistant to spalling and adhesive to Ti 2 AlC substrate. An abnormal oxidation whose cyclic-oxidation kinetics obeys a linear law is observed at 600°C. As revealed by scanning electron microscope (SEM), oxidation-induced cracks present at 600°C results in poor protectivity and accounts for the abnormal oxidation. The cracks are caused by the stress associated with the volume expansion due the formation of anatase TiO 2 in the scale.

Description: Recent investigations have revealed the great potential of Raman spectroscopy for the characterization of clinker minerals and commercial Portland cements. The usefulness of this technique for the identification of anhydrous, hydrated, and carbonated phases in cement-based materials has been demonstrated. In the present work, the application of micro-Raman spectroscopy for the characterization of the main clinker phases of calcium aluminate cements and calcium sulfoaluminate cement is explored. The main stable hydrated phases as well as several important carbonated phases are investigated. Raman measurements on the following phases are reported: (i) pure, unhydrated phases: CA, C 12 A 7 , CA 2 , C 2 AS, cubic- C 3 A , C 4 AF, and C 4 A 3 ; (ii) hydrated phases: ettringite, monosulfoaluminate, and hydrogarnet ( C 3 AH 6 ); (iii) carboaluminate phases: hemicarboaluminate and monocarboaluminate. The present results, which are discussed in terms of the internal vibrational modes of the aluminate, carbonate, and sulfate molecular groups as well as stretching O–H vibrations, show the ability of Raman spectroscopy to identify the main hydrated and unhydrated phases in the aluminate and sulfoaluminate cements. The Raman spectra obtained in this work provide an extended database to the existing data published in the literature.

Description: Acmite ( NaFeSi 2 O 6 ) films were formed on steel coupons via solvothermal reaction of silica, sodium hydroxide, and 1, 4-butanediol in an autoclave under autogenous pressure. Systematic variation in processing variables led to homogenous coatings comprised of pinacoidal acmite grains with an average grain size of ~33 μm. The coatings were produced on the steel coupons from reactant conditions of 0.635 m SiO 2 , 2.546 m NaOH , and 3.087 m 1,4-butanediol for 72 h at 240°C.

Description: The nanocomposite CeO 2 /Y 2 O 3 partially stabilized zirconia (Ce-PSZ/Y-PSZ)-toughened alumina was prepared by wet chemical simultaneous coprecipitation process. The thermal stability of phases and morphology of powders were characterized by TG-DTA, FTIR, and FESEM. The microstructure, stabilization of phases and compositional analysis with different mol% CeO 2 /Y 2 O 3 -doped zirconia in alumina are characterized by FESEM, XRD, and EDAX spectra. Significant improvement in fracture toughness and flexural strength has been observed in 10 vol% of partially stabilized zirconia (2.5 mol% Y 2 O 3 in ZrO 2 /9 mol% CeO 2 in ZrO 2 )-toughened alumina, which is suitable for high-speed machining applications.

Description: Bassem El Zoghbi, Rafael Estevez, and Christian Olagnon Intergranular slow crack growth in zirconia polycrystal is described with a cohesive zone model that simulate mechanically the reaction-rupture mechanism underlying stress and environmentally assisted failure. A 2D polycrystal is considered with cohesive surfaces inserted along the grain boundarie ... [Theor. Appl. Mech. Lett. 3 , 051001 (2013)] published Tue Sep 10, 2013 .

Description: Long Li, Jizeng Wang, and Youhe Zhou This study intends to investigate how the elasticity of a bacterial phage can affect the process of DNA packaging and ejection. For this purpose, we propose a unified continuum and statistical mechanics model by taking into account the effects of DNA bending deformation, electrostatic repulsion be ... [Theor. Appl. Mech. Lett. 3 , 054003 (2013)] published Tue Sep 10, 2013 .

Description: Ahmad Sedaghat and Mohammad Ali Badri In this study, a flow solver was developed based on the governing RANS equations of compressible flows and was further extended to include the effects of electromagnetic forces namely Lorentz forces. Lorentz forces may be added as a source term in the governing fluid flow equations. Numerical stud ... [Theor. Appl. Mech. Lett. 3 , 052003 (2013)] published Tue Sep 10, 2013 .

Description: Meie Li, Chao Jin, and Jinxiong Zhou Hydrogel can swell to many times of its dry volume, resulting in large deformation which is vital for its function. The swelling process is regulated by many physical and chemical mechanisms, and can, to some extent, be fairly described by the poroelasticity theory. Implementation of the poroelast ... [Theor. Appl. Mech. Lett. 3 , 054009 (2013)] published Tue Sep 10, 2013 .

Description: Chaofeng Lü, Wen Chen, and Jinxiong Zhou et al. Abstract not available. [Theor. Appl. Mech. Lett. 3 , 054001 (2013)] published Sun Sep 01, 2013 .

Description: Wenxiang Xu, Huisu Chen, and Wen Chen When interfacial layers are viewed as a separate phase, the interface thickness plays an essential role in assessing physico-mechanical properties of particulate materials. However, the interface thickness from sectional analysis is often overestimated, due to the irregularity of surface textures ... [Theor. Appl. Mech. Lett. 3 , 054008 (2013)] published Tue Sep 10, 2013 .

Description: Yu Wan, Quanshui Zheng, and Zhiping Xu Nano-particle capture is a key process in filtration, separation, and biomedical applications. Here we explored the mechanisms of soft particle capture using nanofiber networks. We identified possible states of the capture process, which are defined by their structural and material parameters. By ... [Theor. Appl. Mech. Lett. 3 , 054002 (2013)] published Tue Sep 10, 2013 .

Description: Ke-Qing Xia The system of turbulent thermal convection is introduced. Progresses in recent decades in the four major areas of research in turbulent convection are briefly reviewed. Some of the recent trends of the field are then discussed, which also serve to point out that the future directions in this impor ... [Theor. Appl. Mech. Lett. 3 , 052001 (2013)] published Tue Sep 10, 2013 .

Description: A 50:50 vol% MgO – Y 2 O 3 nanocomposite with ~150 nm grain size was prepared in an attempt to make 3–5 μm infrared-transmitting windows with increased durability and thermal shock resistance. Flexure strength of the composite at 21°C is 679 MPa for 0.88 cm 2 under load. Hardness is consistent with that of the constituents with similar grain size. For 3-mm-thick material at 4.85 μm, the total scatter loss is 1.5%, forward scatter is 0.2%, and absorptance is 1.8%. Optical scatter below 2 μm is 100%. Variable intensity OH absorption (~6% absorptance) is observed near 3 μm. The refractive index is ~0.4% below the volume-fraction-weighted average of those of the constituents. Thermal expansion is equal to the volume-fraction-weighted average of expansion of the constituents. Specific heat capacity is equal to the mass-fraction-weighted average of heat capacities of the constituents. Thermal conductivity lies between those of the constituents up to 1200 K. Elastic constants lie between those of the constituents. The Hasselman mild thermal shock resistance parameter for the composite is twice as great as that of common 3–5 μm window materials, but half as great as that of c -plane sapphire.

Description: In this work, novel Y 2 Si 2 O 7 / ZrO 2 composites were developed for structural and coating applications by taking advantage of their unique properties, such as good damage tolerance, tunable mechanical properties, and superior wear resistance. The γ- Y 2 Si 2 O 7 / ZrO 2 composites showed improved mechanical properties compared to the γ- Y 2 Si 2 O 7 matrix material, that is, the Young's modulus was enhanced from 155 to 188 GPa (121%) and the flexural strength from 135 to 254 MPa (181%); when the amount of ZrO 2 was increased from 0 to 50 vol%, the γ- Y 2 Si 2 O 7 / ZrO 2 composites also presented relatively high facture toughness (〉1.7 MPa·m 1/2 ), but this exhibited an inverse relationship with the ZrO 2 content. The composition–mechanical property–tribology relationships of the Y 2 Si 2 O 7 / ZrO 2 composites were elucidated. The wear resistance of the composites is not only influenced by the applied load, hardness, strength, toughness, and rigidity but also effectively depends on micromechanical stability properties of the microstructures. The easy growth of subcritical microcracks in Y 2 Si 2 O 7 grains and at grain boundaries significantly contributes to the macroscopic fracture toughness, but promotes the pull-out of individual grains, thus resulting in a lack of correlation between the wear rate and the macroscopic fracture toughness of the composites.

Description: The as-prepared BiFeO 3 ceramic shows a piezoelectric d 33 coefficient of −14 pC/N, that is, an obvious ferroelectric self-poling phenomenon. The temperature gradient between the two surfaces of BiFeO 3 ceramic was intentionally enlarged when BiFeO 3 was prepared with a rapid liquid sintering method. This temperature gradient and the corresponding thermal strain can introduce defect dipoles through separating bismuth vacancies from oxygen vacancies. A mass of these dipoles introduce a macroscopic internal electric field ( E in ) which downward poles BiFeO 3 ceramic during its cooling down process. As expected, an E in of 〉10 kV/cm is confirmed by the asymmetrical polarization/strain versus electric field curves.

Description: The effect of Ba content on the stress sensitivity of the antiferroelectric to ferroelectric phase transition in ( Pb 0.94− x La 0.04 Ba x )[( Zr 0.60 Sn 0.40 ) 0.84 Ti 0.16 ] O 3 ceramics is investigated through monitoring electric field-induced polarization and longitudinal strain under compressive prestresses. It is found that incorporation of Ba significantly suppresses the stress sensitivity of the phase transition, as manifested by slight decreases under prestresses up to 100 MPa in the maximum polarization ( P m ) and longitudinal strain ( x m ). The energy storage density is even increased under the mechanical confinement in compositions x  = 0.02 and 0.04. X-ray diffraction, transmission electron microscopy, and dielectric measurements indicate that the suppressed stress sensitivity is associated with the disruption of micrometersized antiferroelectric domains into nanodomains and the transition from antiferroelectric to relaxor behavior.

Description: Powders and nanoceramics composed of composites of CoFe 2 O 4 , CoFe 2 , and a small amount of FeO were prepared by heating CoFe 2 O 4 powder in reducing atmosphere and by sintering the product of reducing reaction at 350°C via spark plasma sintering technology. In the powders, increase in the molar ratios of CoFe 2 : CoFe 2 O 4 and a great change in magnetic parameters were observed with the change in heating temperature from 300°C to 400°C, and the dominance of dipole interaction over exchange coupling in the interparticle interactions was confirmed by the steps in magnetic hysteresis loops and the negative Henkel plots. However, in the nanoceramics, significant enhancement in exchange coupling was found when the sintering temperature was raised to 500°C and 650°C, which was confirmed by both the positivity of Henkel plot and the single-phase style of the magnetic hysteresis loop.

Description: Gas adsorption porosity measurement of geopolymers (GPs) is required for quantitative understanding of such mesoporous structures, but the complex nature of the GP system makes analysis difficult. Previous results in the literature are often ambiguous or contradictory. A systematic investigation of metakaolin GP gas adsorption results was conducted to optimize the use of this measurement technique and verify that results match known theory about GP structure. It was found that GP undergoes structural change upon degassing at 100°C or higher. If and only if this change is prevented by degassing at a lower temperature could it be shown that specific surface area and total gas adsorption increases with both increasing curing temperature and decreased Si : Al ratio. This observation is consistent with previous suggestions of increased zeolitic character under these conditions, where previous gas adsorption investigations had not observed this expected relationship. Hydrogen physisorption is proposed as a substitute technique for micropore isotherms in GPs due to the difficulty of removing trace gasses from GPs and the measurement effect of such gasses at high vacuum. A hydrogen physisorption isotherm qualitatively resembled an equivalent nitrogen micropore isotherm.

Description: The (1- x )(K 0.5 Na 0.5 )NbO 3 - x LaFeO 3 (abbreviated as (1- x )KNN- x LF, x  =   0–0.03) ceramics were synthesized by the conventional solid-state sintering method. X-ray diffraction analysis shows that the phase structure of the (1- x )KNN- x LF ceramics transfers from orthorhombic to pseudocubic with increasing the LF content. The SEM studies reveal that a small amount of LF, as a grain growth inhibitor, has an evident effect on grain size reduction. The (1- x )KNN- x LF ( x  =   0.02) ceramics show high permittivity maximum (near 2000) and low dielectric loss (〈5%) in the temperature range of 100–400°C, and the capacitance variation (ΔC/C 150°C ) is keeping within ±15%, indicating the potential application for the high-temperature capacitors.

Description: In this work, the sinterability of forsterite powder synthesized via solid-state reaction was investigated. X-ray diffraction (XRD) analyses indicate that the synthesized powder possessed peaks that correspond to stoichiometric forsterite. Scanning electron micrographs revealed that the powders were formed agglomerates, which were made up of loosely packed fine particles. Subsequently, the forsterite powders were cold isostatically pressed into a disk shape under 200 MPa and sintered in air at temperature ranging from 1200°C to 1500°C (interval of 50°C) with ramp rate of 10°C/min and dwelling time of 2 h. The sinterability of each sintered samples was examined in terms of phase stability, relative density, Vickers hardness, fracture toughness, and microstructural examination. XRD examination on all the sintered samples exhibited pure forsterite, in which the generated peaks were found to be in a good agreement with JCPDS card no. 34-0189. The densification of forsterite progressed to reach a maximum relative density of ~91% at 1500°C. This study also revealed that high-strength forsterite ceramic can be synthesized via solid-state reaction as forsterite attained favorable mechanical properties, having fracture toughness of 4.88 MPam 1/2 and hardness of 7.11 GPa at 1400°C.

Description: In this work, the role of europium doping of glasses formulated in the ternary system ZnO – CdO – TeO 2 is described. The Eu -doped oxide glasses were prepared by the conventional melt-quenching method and by using three different compositions. Structural studies reveal that there exists a good affinity between Cd and some rare earth (RE) ions to form the crystalline phase. The X-ray diffraction (XRD) diagrams display that the structure of these glasses is amorphous and with the increase in CdO content and the compatibility of Eu 3+ , there is a tendency to form nanocrystals of CdTe 2 O 5 . The scanning electron microscopic (SEM) observation of their microstructure confirms the presence of phase separation. Differential thermal analysis (DTA) of these glasses showed small exothermic peaks noted around 450°C for the V2 glass and 480°C for V1 and V3 glasses, which could be attributed to the formation of these crystals. The infrared spectra showed a main absorption band around 800–600 cm −1 corresponding to the Te – O stretching mode in TeO 4 and TeO 3 groups. By optical absorption (OA), the band gap ( E g ) for each glass was determined; these values were 3.27, 3.14, and 3.3 eV for the V1–V3 glasses, respectively. Furthermore, the presence of Eu 3+ was detected in the 370–470 nm short-range wavelengths. The photoluminescence (PL) experiments of the glasses showed light emission due to the following transitions: 5D0 → 7F1, 5D0 → 7F2, 5D0 → 7F3, and 5D0 → 7F4.

Description: This article presents a novel systematic approach to the fabrication of highly functionalized, silica (SiO 2 ) nanoparticles used for the adsorption of heavy-metal ions (Hg 2+ , Pb 2+ , Cd 2+ , Zn 2+ ). Almost monodispersed silica (SiO 2 ) nanoparticles with narrow particle size distributions of around 85 ± 5 nm were formed using the Stöber process. The prepared SiO 2 nanoparticles were successfully surface-treated during a one-step procedure by the covalent attachment of mercaptopropyl groups onto the surfaces of the SiO 2 nanoparticles. A FTIR spectra analysis confirmed that the binding of the mercaptosilane molecules onto the surface of the silica nanoparticles mediated the Si–O–Si and –SH vibrations. TEM/EDXS micrographs indicated the almost monodispersed and spherical morphology of the prepared product with strong signals of Si and S, thus implying that the coating procedure involving the mercapto groups onto the silica surface had been successfully accomplished. The final results for the heavy-metal (Hg 2+ , Pb 2+ , Cd 2+ , Zn 2+ ) adsorption showed the strongest affinity within the following sequence Hg 2+ (99.9%) 〉 Pb 2+ (55.9%) 〉 Cd 2+ (50.2%) 〉 Zn 2+ (4%). Adsorption equilibrium was achieved after 1 h for all the analyzed samples.

Description: Surfactant-assisted hydrothermal synthesis of magnesium-doped hydroxyapatite (Ca 10− x Mg x (PO 4 ) 6 (OH) 2 ) with 0 ≤  x  ≤ 1) was realized in aqueous solution at 90°C. β-TCP phase was formed in the Mg 0.6 -HA sample after heat treatment at 1000°C. Magnesium was found to degrade the sintering ability of Mg x -HA ceramics. Flexural strength (σ f ) was found to decrease as a function of Mg-doped HA. The using of carbon nanotubes as reinforcing agents mitigated the strength loss of Mg-HA ceramics. The flexural strength of Mg 0.6 -HA was then increased by nearly 20% from approximately 33 to 39 MPa with an optimum addition of 3 wt% of multi-walled nanotubes.

Description: The conductivity of nominal CaWO 4 , CaW 0.99 Ta 0.01 O 4–δ , 0.7( CaWO 4 )–0.3( La 0.99 Ca 0.01 NbO 4–δ ), and Ca 0.9 La 0.1 WO 4+δ has been studied by means of a.c. impedance measurements. Proton conductivity was observed for CaW 0.99 Ta 0.01 O 4–δ , which displayed exothermic hydration with enthalpy and entropy of –82 kJ/mol and –120 J/molK, respectively. The proton mobility in CaW 0.99 Ta 0.01 O 4–δ was low, with enthalpy and preexponential factor of mobility of 82 kJ/mol and 0.7 cm 2 K/Vs. The high enthalpy of mobility is interpreted to reflect association between the acceptor dopant and protonic defects, whereas the low preexponential factor of mobility may reflect a lower proton concentration than assumed. Rietveld refinement indicated low solubilities of La on Ca -site and Ta on W-site. Proton conductivity was also observed in undoped CaWO 4 , however, not in Ca 0.9 La 0.1 WO 4+δ . The conductivity of 0.7( CaWO 4 )–0.3( La 0.99 Ca 0.01 NbO 4–δ ) behaved much like that of undoped LaNbO 4 , likely due to a very low acceptor dopant concentration.

Description: A new lead-free BNT-based piezoelectric ceramics of (1 −  x ) Bi 0.5 Na 0.5 TiO 3 – x Bi ( Al 0.5 Ga 0.5 ) O 3 ( x  = 0, 0.02, 0.03, 0.04, and 0.05) were synthesized using a conventional ceramic fabrication method. Their structures and electrical properties were investigated. All the samples show a typical ferroelectric P ( E ) loops and S ( E ) curves at room temperature. The optimal properties are obtained at the composition of the x  = 0.03. The substitution of Bi ( Al 0.5 Ga 0.5 ) O 3 enhances piezoelectric constant and increases Curie temperature from 58 pC/N and 310°C of pure BNT to 93 pC/N and 325°C of the x  = 0.03. The temperature-dependent P ( E ) loops and S ( E ) curves of 0.97BNT–0.03BAG indicate that phase transition from ferroelectric to antiferroelectric takes place over a very wide temperature region from 80°C to 180°C. The results show that the introduction of BAG improves the electrical properties of BNT.

Description: Haiping Tian, Shaoqiong Yang, and Lu Cheng et al. Experiments were conducted in a water tunnel by tomographic time-resolved particle image velocimetry (Tomo-TRPIV). The Reynolds number Reθ is 2 460 on the base of momentum thickness. According to the physical mechanism of the stretch and compression of multi-scale vortex structures in the wall-bou ... [Theor. Appl. Mech. Lett. 3 , 052002 (2013)] published Tue Sep 10, 2013 .

Description: Junjie Sheng, Hualing Chen, and Lei Liu et al. Viscoelasticity and temperature can significantly affect the performance of a dielectric elastomer. In the current study, we use a thermodynamic model to describe the effect of temperature and viscoelasticity on the electromechanical response undergoing a cyclic electric load by taking into accoun ... [Theor. Appl. Mech. Lett. 3 , 054005 (2013)] published Tue Sep 10, 2013 .

Description: Fengchao Wang and Hengan Wu Spreading of nanofluids on solid substrate was studied via molecular dynamics simulations. Simulation models for two immiscible fluids (oil and water based nanofluids) confined in a slit between two planar solid walls were set up. The influence of the volume concentration of the nanoparticles on t ... [Theor. Appl. Mech. Lett. 3 , 054006 (2013)] published Tue Sep 10, 2013 .

Description: Xiang He, Pengfei Wang, and Guoyou Huang et al. Indentation is a simple and nondestructive method to measure the mechanical properties of soft materials, such as hydrogels, elastomers and soft tissues. In this work, we have developed a micro-indentation system with high-precision to measure the mechanical properties of soft materials, where the ... [Theor. Appl. Mech. Lett. 3 , 054004 (2013)] published Tue Sep 10, 2013 .

Description: Junshi Zhang, Hualing Chen, and Junjie Sheng et al. In this paper, we present a modified model describing the constitutive relation of viscoelastic dielectric elastomer (DE). The uniform uniaxial tension-recovery experiment was carried out at different stretching rates. Based on Yeoh hyper-elastic model, model-fitting approach is put forward to obt ... [Theor. Appl. Mech. Lett. 3 , 054011 (2013)] published Tue Sep 10, 2013 .

Description: Yugang Tang, Ying Liu, and Qingshan Yang Considering the effects of osmotic pressure, elastic bending, Maxwell pressure, surface tension, as well as flexo-electric and dielectric properties of phospholipid membrane, the shape equation for sphere vesicle in alternation (AC) electric field is derived based on the liquid crystal model by mi ... [Theor. Appl. Mech. Lett. 3 , 054010 (2013)] published Tue Sep 10, 2013 .

Description: Jianying Hu, Yuhao He, and Jincheng Lei et al. In periodic cellular structures, novel pattern transformations are triggered by a reversible elastic instability under the axial compression. Based on the deformation-triggered new pattern, periodic cellular structures can achieve special mechanical properties. In this paper, the designed architec ... [Theor. Appl. Mech. Lett. 3 , 054007 (2013)] published Tue Sep 10, 2013 .

Description: Abdessattar Abdelkefi and Mehdi Ghommem Wing flapping and morphing can be very beneficial to managing the weight of micro air vehicles through coupling the aerodynamic forces with stability and control. In this letter, harvesting energy from the wing morphing is studied to power cameras, sensors, or communication devices of micro air ve ... [Theor. Appl. Mech. Lett. 3 , 052004 (2013)] published Tue Sep 10, 2013 .

Description: We studied ancient enamels on gilded copper from a collection of archeological horse harness pendants of the Museo Instituto Valencia de Don Juan (Madrid, Spain) to test the benefits of a new, nondestructive analytical methodology based on chemometric analysis (i.e., Principal Component Analysis, PCA) on micro-ATR-FTIR spectral data and chemical quantification using SEM-EDS. The novelty of this approach was threefold: (i) PCA allowed the discrimination of the different harness pendants of known origin and attributed to the 14th and 15th centuries according to the chemical complex composition, nanostructure, glass weathering, and/or coloring mechanisms of each colored enamel, separately (i.e., red, purple, blue, and white), (ii) it is a cheap, easily available and nondestructive methodology that enables us to (iii) draw archeological conclusions about the quality of the manufacturing process, reassess the chronology of these objects and attempt to attribute them to different workshops according to the different traditional recipes identified. In particular, the enamels were made of alkali and/or alkaline earth lead-glass with a wide range of chemical compounds in the form of pigments or opacifiers. Two types of coloring mechanisms were identified, colloidal particles such as copper-ruby for red enamels, and ionic mechanisms such as Fe (II) and Co (II) to achieve a blue pigments; Mn (III) in the purple pigment; and two kind of white enamels were identified, i.e., tin oxide as an opacifier and uranium oxide. In addition, we established the reason for the poor state of conservation of some of the enamels by means of the identification of depolymerization and ion exchanges, well-known harmful effects of glass weathering, and finally a chronology was assigned for some of these pieces according to the enamel composition.

Description: Novel glass-ceramics with embedded thermoelectric Bi 2 Se 3 crystals were prepared from glass matrices in the Ge 20 Se 100− x Bi x ( x  = 5, 10, 12 mol%) system. Based on DSC results performed at different heating rates, characteristic activation energies ( E c ) and Avrami exponents ( n ) were obtained and analyzed by using Kissinger's relation, Ozawa's method, Augis–Bennett approximation and Matusita–Sakka theory. XRD results showed that pure Bi 2 Se 3 crystalline phase precipitated upon annealing at different temperatures for various time. The crystal size and crystalline fraction in the samples could be tuned by controlling the annealing time.

Description: In the present investigations nano size high alumina cements (HAC) were prepared by very effective co-melt precursor sintering technique from their metal nitrate precursors. The prime cementing phases observed were CA, CA 2 , and C 12 A 7 . The addition of nano structured cements in refractory castables has improved the thermo-chemical-mechanical properties to a significant extent. Each batch of low cement castables (LCC) was prepared from calcined Chinese bauxite, HAC, and superfine additives. The effect of HAC in bauxite castable with the additives similar to Silicon Carbide, reactive alumina, and micro-fine silica on the sinterability and properties of these castables was investigated. Physical properties such as apparent porosity and bulk density, mechanical properties such as hot modulus of rupture (HMOR), cold and hot modulus of rupture (CMOR), and cold crushing strength (CCS) of hydrated and sintered castables were studied. The sintered castables were also characterized for their solid phase compositions and microstructure using X-ray diffraction (XRD) and FE-SEM, respectively. In the castables new phases such as mullite, α-alumina were formed at the expense of bauxite and silica. Solid solution of mullite formed at high temperature acts as a bonding phase and is accounted for high HMOR, CMOR, and CCS values. These excellent properties of such castables may enable their uses in various applications such as refractory lining for fabrication of steel, aluminium, copper, glass, cement, chemicals, and ceramics.

Description: Shabram Sadeghi Esfahlani, Hassan Shirvani, and Sunny Nwaubani et al. Structural optimization for crashworthiness criteria is of particular significance especially at early stage of design. The comparative study of Kriging and radial basis function network (RBFN) was performed in order to improve the crashworthiness effects of honeycomb. Improving the crashworthines ... [Theor. Appl. Mech. Lett. 3 , 031002 (2013)] published Fri May 10, 2013 .

Description: Guyue Jiao and Ruojing Zhang The erythrocytes play an important role in the human body. The healthy erythrocytes can undergo extremely large deformation while passing through small capillaries. Their infection by Malaria Plasmodium falcipurum (P.f.) will lead to capillary blockage and blood flow obstruction. Many experimental ... [Theor. Appl. Mech. Lett. 3 , 034001 (2013)] published Fri May 10, 2013 .

Description: Su Yean Teh, Hock Lye Koh, and Donald L. DeAngelis et al. Predicting potential changes in groundwater salinity in low-lying coastal regions due to climate change is important, where coastal vegetation is abundant, succession competition between halophytes and glycophytes plays a significant role in the salinity budget. Sea level rise enhances salinity in ... [Theor. Appl. Mech. Lett. 3 , 032001 (2013)] published Fri May 10, 2013 .

Description: Zn 2 GeO 4 ceramic materials were synthesized by the solid-state method. Zn 2 GeO 4 powders were investigated with X-ray powder diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Oxygen defects in the Zn 2 GeO 4 ceramics were investigated by photoluminescence, Raman, and EDS spectra. Conductivity of Zn 2 GeO 4 was 0.18 S/cm at low temperature of 773 K, and its activation energy was 0.49 eV. The results showed that Zn 2 GeO 4 was a promising low-temperature electrolyte with high conductivity.

Description: Using a high-speed and high-resolution-camera system of droplets in glaze sprays and their impact on the surface of a green ceramic body based on silicate tiles have been characterized. The influence of the surface tension of the glaze slips on the droplet size distribution and their wetting behavior on contact with the green silicate body surface have been investigated. The unfired glaze layers have been studied by means of scanning electron microscopy and computer tomography. The impact angle of the droplets as well as the size of the droplets is of great importance for a high glaze surface quality.

Description: Dense (97.3%) zirconium diboride (ZrB 2 ) ceramics were obtained via gelcasting and pressureless sintering. Four wt% B 4 C was used as sintering aid. ZrB 2 , SiC, and B 4 C can codisperse well in the alkaline region, using a polyacrylate dispersant. Compared with monolithic ZrB 2 (Z), the mechanical properties of ZrB 2 -SiC (ZS) were enhanced. The Vickers hardness and fracture toughness of ZS were (13.1 ± 0.6) GPa and (2.5 ± 0.4) MPa m 1/2 , respectively.

Description: This article details the influence of zirconium doping on the piezoelectric properties and relaxor characteristics of 94( Bi 1/2 Na 1/2 ) TiO 3 –6 Ba ( Zr x Ti 1− x ) O 3 (BNT–6BZT) bulk ceramics. Neutron diffraction measurements of BNT–6BZT doped with 0%–15% Zr revealed an electric-field-induced transition of the average crystal structure from pseudo-cubic to rhombohedral/tetragonal symmetries across the entire compositional range. The addition of Zr up to 10% stabilizes this transition, resulting in saturated polarization hysteresis loops with a maximum polarization of 40 μC/cm 2 at 5.5 kV/mm, while corresponding strain hysteresis measurements yield a maximum strain of 0.3%. With further Zr addition, the ferroelectric order is progressively destabilized and typical relaxor characteristics such as double peaks in the current density loops are observed. In the strain hysteresis, this destabilization leads to an increase of the maximum strain by 0.05%. These changes to the physical behavior caused by Zr addition are consistent with a reduction of the transition temperature T F-R , above which the field-induced transformation from the relaxor to ferroelectric state becomes reversible.

Description: Precursor glasses for the ferroelectric barium bismuth titanate ( BaBi 4 Ti 4 O 15 ) (BBiT) have been prepared by the melt-quench technique in the SiO 2 – K 2 O – BaO – Bi 2 O 3 – TiO 2 (SKBBT) glass system with and without Eu 2 O 3 doping. BBiT glass–ceramic (GC) nanocomposites have been derived from these glasses by controlled heat treatment. The structural properties of the GCs have been investigated using X-ray diffraction (XRD), electron microscopy (FE-SEM, TEM), and FT-IR reflectance spectroscopy. FE-SEM images show the formation of randomly oriented hexagonal rod-shaped crystals of 200–400 nm and TEM images show 10–20 nm crystallites. FT-IR spectra exhibit the characteristic bands of BBiT at 480, 585, and 680 cm −1 . The activation energy of crystallization ( E c ) varies from 295 to 307 kJ/mol. The dielectric constants (ε r ) of glass and GC nanocomposites increase with an increase in frequency up to 3.0 MHz and then decrease up to 5.0 MHz. Heat-treated GCs show higher ε r values, in the range 25–55, compared to the precursor glasses (20–37). Dielectric losses (tan δ) for all the samples increase from 0.005 to 1.0 with an increase in frequency from 100 Hz to 5.0 MHz. Excitation spectra were recorded by monitoring emission at 613 nm corresponding to the 5 D 0 → 7 F 2 transition. An intense 466 nm excitation band corresponding to the 7 F 0 → 5 D 2 transition was observed. Emission spectra were then recorded by exciting the glass samples at 466 nm. Longer heat-treatment times led to a 15-fold increase in the intensity of the red emission at 612 nm, attributed to the segregation of Eu 3+ ions into the low phonon energy BBiT crystallites. The hardness (3.8–5.1 GPa) and fracture toughness (1.8–3.5 MPam 0.5 ) values obtained in the GCs are high and suitable for structural applications.

Description: Carbon doping is known to be very effective for enhancing the high-field properties of magnesium diboride, MgB 2 , but not for the low-field properties. Here, we report that both the high- and the low-field properties can be improved simultaneously without doping by increasing the initial magnesium partial pressure, by simply reducing the size of the magnesium particles. It is shown that in situ processed bulk MgB 2 sintered with fine magnesium powders has superior superconducting properties compared with a bulk sample fabricated using coarse magnesium lumps. The change in the lattice parameters was almost negligible; however, a clear increase in lattice strain can be observed for the sample sintered with fine magnesium powders. The increase in the lattice strain results in an enhancement of the high-field properties. Furthermore, it has also been found that the low-field critical current density is not reduced, but rather slightly increased for the fine magnesium powder sample. This is due to a closer linkage among the grains that drastically improves grain connectivity. These findings demonstrate that the initial growth mechanism of MgB 2 is very crucial for its superior superconducting properties, and it especially indicates the importance of magnesium vapor pressure.

Description: Revisiting classic phase diagrams and chemical phase relations in the solid state of a very well-studied oxide system, such as the lithium aluminosilicate (LAS) system, can open a new window for the design of new advanced materials with improved properties. Crystal chemistry and phase equilibria are used to demonstrate the ability to design materials with particular desired properties in the alumina-rich corner of the LAS phase diagram. The experimental results demonstrate the alumina and β-eucryptite solid-state compatibility.

Description: This work reports the crystallization, microstructure, and surface composition of Cu In 0.7 Ga 0.3 Se 2 (CIGS) thin films grown by femtosecond pulsed laser deposition at different annealing temperatures. The structural and optical properties of the CIGS films were characterized by X-ray diffraction, Raman scattering, UV-visible spectroscopy, and Hall effect measurement. The results indicate that binary crystals of CuS e initially formed on the as-deposited film, but then completely turned into a quaternary chalcopyrite structure after annealing at 400°C. Phase transformation significantly affects the surface morphology, Hall properties, and band gap. Transmission electron microscopy further revealed that an interface between the Mo substrate and CIGS crystallites contains an amorphous layer even at the high temperature of 500°C. For the application of photovoltaic devices, we also report on the photoresponse of both as-deposited and annealed films as demonstrated by preliminary tests.

Description: Reactive sintering of 3 Ti : Sn :2 C and 3Ti:Sn:2C:0.6Fe powder mixtures is studied in the temperature range 510°C–1200°C under argon. It is demonstrated that the recently discovered Ti 3 SnC 2 phase is formed, provided that Fe is added to a 3 Ti : Sn :2 C reactant mixture within the synthesis conditions used. Using dilatometric and X-Ray diffraction analyses, the formation mechanism of Ti 3 SnC 2 is discussed. Results show that at low temperature (about 510°C), tin is consumed to form Fe x Sn y intermetallics. At high temperature (about 1060°C), tin is newly available to form Ti 3 SnC 2 due to the melting of Fe x Sn y . Then, the intermediate phases, TiC and Ti 2 SnC , and/or Ti 5 Sn 3 , TiC , C , and Ti are dissolved in the ( Fe  +  Sn ) liquid phase and Ti 3 SnC 2 very likely precipitate from the melt. The second part of the study deals with the optimization of the Fe content in the initial 3Ti:Sn:2C reactant powder mixture to synthesize samples with larger Ti 3 SnC 2 content by hot isostatic pressing.

Description: The effects of non-stoichiometry on the microstructure, oxygen vacancies, and piezoelectric properties of ( Na 0.5 K 0.5 ) x NbO 3 (NK x N, where x  =   0.98, 1.00, 1.01, and 1.02) ceramics doped with sintering aid CuTa 2 O 6 (CT) doping were investigated. X-ray diffraction (XRD) patterns indicated that a secondary phase formed in CT-doped NK x N (NK x NCT) ceramics with x  〈   1.00 and that a pure phase was obtained with x  ≥   1.00. The grain size of NK x NCT ceramics increased with increasing x value due to the formation of a liquid phase. The internal bias field, activation energy, and Raman analysis for NK x NCT ceramics showed that the number of induced oxygen vacancies increased with decreasing x value. The high mechanical quality factor ( Q m ) value obtained for NK x NCT ceramics did not correspond to a higher concentration of oxygen vacancies, illustrating that the suitable compensation (excess Na and K ) is more important than the concentration of oxygen vacancies to obtain the ceramics with high Q m values. The NK x NCT ceramics with x  =   1.01 exhibited excellent piezoelectric properties, with k p and Q m values of 39.9% and 2,070, respectively.

Description: Low-temperature sintering of β-spodumene ceramics with low coefficient of thermal expansion (CTE) was attained using Li 2 O – GeO 2 sintering additive. Single-phase β-spodumene ceramics could be synthesized by heat treatment at 1000°C using highly pure and fine amorphous silica, α-alumina, and lithium carbonate powders mixture via the solid-state reaction route. The mixture was calcined at 950°C, finely pulverized, compacted, and finally sintered with or without the sintering additive at 800°C–1400°C for 2 h. The relative density reached 98% for the sample sintered with 3 mass% Li 2 O – GeO 2 additive at 1000°C. Its Young's modulus was 167 GPa and flexural strength was 115 MPa. Its CTE (from R.T. to 800°C) was 0.7 × 10 −6  K −1 and dielectric constant was 6.8 with loss tangent of 0.9% at 5 MHz. These properties were excellent or comparative compared with those previously reported for the samples sintered at around 1300°C–1400°C via melt-quenching routes. As a result, β-spodumene ceramics with single phase and sufficient properties were obtained at about 300°C lower sintering temperature by adding Li 2 O – GeO 2 sintering additive via the conventional solid-state reaction route. These results suggest that β-spodumene ceramics sintered with Li 2 O – GeO 2 sintering additive has a potential use as LTCC for multichip modules.

Description: Pyrochlore-structured lanthanide stannate ceramic ( Ln 2 Sn 2 O 7 ) has been synthesized via a new complex precipitation method. A suite of characterization techniques, including FTIR, Raman, X-ray, and electron diffraction as well as nitrogen sorption were employed to investigate the structural evolution of the synthesized and calcined powder. Raman, XRD, and selected area electron diffraction results confirm the presence of the pyrochlore structure after calcination of the powder above 1200°C. TEM imaging shows fine crystallites gradually increased in size from approximately 100 nm to about 500 nm with higher calcination temperatures. Grain growth and powder densification upon increasing the calcination temperature was confirmed by nitrogen sorption results. This aqueous synthetic method provides a simple pathway for the preparation of homogeneous lanthanide stannate ceramics.

Description: Heng Ren and Xiyun Lu A vortex ring impacting a three-dimensional circular cylinder is studied using large eddy simulation (LES) for a Reynolds number Re = 4×104 based on the initial translation speed and diameter of the vortex ring. We have investigated the evolution of vortical structures and identified three typical ... [Theor. Appl. Mech. Lett. 3 , 032007 (2013)] published Fri May 10, 2013 .

Description: Juan Chen and Chongjun Li Basic requirement for applying isoparametric element is that the element has to be convex and no violent distortion is allowed. In this paper, a cubic quadrilateral spline element with 12 nodes has been developed using the triangular area coordinates and the B-net method, which can exactly model t ... [Theor. Appl. Mech. Lett. 3 , 031003 (2013)] published Fri May 10, 2013 .

Description: Bin Wu, Yousheng Xu, and Youqu Zheng et al. The finite volume method (FVM) and the lattice Boltzmann method (LBM) are coupled with each other to construct a new cross-scaling method to deal with the porous flow problem. To check the effectiveness of our developed cross-scaling LBM—FVM, the above mentioned problem is also solved by the well ... [Theor. Appl. Mech. Lett. 3 , 032009 (2013)] published Fri May 10, 2013 .

Description: Xi Zhao, Hua Liu, and Benlong Wang Potential tsunami generated in the Okinawa Trench or the Manila Trench may attack the southeast coast of China. The continental shelves with extremely gentle slope in the China Seas affect the evolvement of tsunami waves. In this paper, we carry out the simulation of tsunami propagation based on t ... [Theor. Appl. Mech. Lett. 3 , 032005 (2013)] published Fri May 10, 2013 .

Description: Shawn Y. Sim, Zhenhua Huang, and Adam D. Switzer In recent studies, the effects of complex costal topography on tsunami run-up has sparked heated discussion. This study mainly aims at investigating the effects of complex costal topography on the tsunami inundation distance and the effectiveness of sand dunes in dissipating tsunami wave energy. T ... [Theor. Appl. Mech. Lett. 3 , 032006 (2013)] published Fri May 10, 2013 .

Description: Xiaofeng Yang, Mei Feng, and Yanyan Chen et al. The dynamics of fluid flow through nanochannels is different from those in macroscopic systems. By using the molecular dynamics simulations, we investigate the influence of surface polarity of nanotube on the transport properties of the water fluid. The nanotube used here resembles the carbon nano ... [Theor. Appl. Mech. Lett. 3 , 032008 (2013)] published Fri May 10, 2013 .

Description: Ceramics have played a crucial role in the development of fission based nuclear power, in glass & glass composite high level wasteforms, in composite cements to encapsulate intermediate level wastes (ILW) and also for oxide nuclear fuels based on UO 2 and PuO 2 /UO 2 mixed oxides. They are also used as porous filters with the ability to absorb radionuclides (RN) from air and liquids and are playing a key role in the cleanup at Fukushima. Non-oxides also find current fission applications including in graphite moderators and B 4 C control rods. Ceramics will continue to be significant in the near-term expansion of nuclear power via next-step developments of fuels with inert matrices or based on thoria and in wasteforms using alternative composite cements or single or multiphase ceramics that can host Pu & other difficult RN. Longer term advances for Generation IV reactors, which will operate at higher temperatures & with higher fuel burn-up require innovative fuel developments potentially via carbides & nitrides or composite fuel systems. Novel non-thermal (cement-like) and thermal techniques are currently being developed to treat some of the difficult legacy wastes. Non-thermally derived wasteforms developed from geopolymers, composite cements, hydroceramics, and phosphate-bonded ceramics and thermally derived wasteforms made by Hot Isostatic Pressing and fluidized bed steam reforming (FBSR) as well as vitrification techniques based on cold crucible melting (CCM), Joule-heater in-container melting and plasma melting (PM) are described. Future developments in waste treatment will be based on separation technologies for partitioning individual RN along with design & construction of RN-containing ceramic targets for inducing transmutation reactions. Near demonstration actinide-hosting ceramic wasteforms including multiphase Synroc systems are described. Opportunities also exist for ceramics in structural applications in Generation IV reactors such as composite SiC / SiC and C / C for fuel cladding and control rods and MAX phases and ultrahigh-temperature ceramics (UHTCs) may find near core fuel coating and cladding applications. Uses of ceramics in fusion reactor systems will be both functional (ceramic superconductors in magnet systems for plasma control and in Li silicate breeder blankets in tokamaks) and structural including as sapphire diagnostic windows, graphite diverters, and plasma facing C and UHTCs. In all these cases, performance is limited by poorly understood radiation damage and interface controlled processes, which demands a combined modeling/experimental approach.

Description: Lianda Zhao, Fujiang Yu, and Jingming Hou et al. The tsunami was a sudden marine disasters. Tsunami waves can quickly spread to near-shore and cause the disaster after the tsunami. So it is very important of timely monitoring and early warning of the tsunami. After several unsuccessful tsunami forecasting, the United States developed tsunami buo ... [Theor. Appl. Mech. Lett. 3 , 032002 (2013)] published Fri May 10, 2013 .

Description: Xiaokai Wang, Zhijun Zheng, and Jilin Yu Crashworthiness of cellular metals with a linear density gradient was analyzed by using cell-based finite element models and shock models. Mechanisms of energy absorption and deformation of graded cellular metals were explored by shock wave propagation analysis. Results show that a positive densit ... [Theor. Appl. Mech. Lett. 3 , 031001 (2013)] published Fri May 10, 2013 .

Description: Benlong Wang and Hua Liu Kinematic dynamo problem is studied with tsunami motion in open oceans. Using long wave approximation, a series solution of the dynamo problem is established with fast convergent rate based on a small parameter relating water wave dispersive effects. Taking solitary wave and single wave as typical ... [Theor. Appl. Mech. Lett. 3 , 032003 (2013)] published Fri May 10, 2013 .

Description: Wenyang Duan and Binbin Zhao The Green-Naghdi (GN) theory is used here to simulate two-dimensional (2D) underwater landslide-induce tsunamis. Finite difference method is used to solve the GN equations. GN theory has different levels. There are GN-1, GN-2, ⋯, GN-K theory in GN theory. When K goes up, the GN equations will be m ... [Theor. Appl. Mech. Lett. 3 , 032004 (2013)] published Fri May 10, 2013 .

Description: Graphite foams with low, medium, and high densities were joined to Cu-clad-Mo, 430 stainless steel, titanium, and Inconel 625 using Cusil-ABA ® and Palcusil-5 ® . Copper-clad-molybdenum and steel were also joined to SiC-coated foam. Well-bonded joints with partially infiltrated foam and with carbon ligaments enriched with Ti formed in Cusil-ABA joints of coated and uncoated foam. Low-density foams showed greatest braze penetration and penetration distance decreased with increasing foam density. Foam/metal joints with Palcusil-5 showed less penetration than Cusil-ABA. The tension test on foam/Cu-clad-Mo and foam/430 stainless steel joints made using Cusil-ABA revealed that the joints were always stronger than the foam.

Description: In situ reduction of tungstic acid and cobalt chloride by dextrose in silica gel resulted in co-deposition of tungsten carbide-cobalt (WC–Co) nanoparticles with different proportions of cobalt (5–15 wt % of WC). X-ray powder diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM) and Fourier-transform infrared (FT-IR) spectroscopy have been used for characterizing these nanoparticles. WC-Co aggregates of 25–30 nm size have been achieved, successfully.

Description: The promotion of zircon ( ZrSiO 4 ) crystallization by ZnO from a zirconium-based frit glaze was studied and the possible mechanism was discussed. X-ray diffraction was used to analyze the relative quantities of zircon and other transitional crystals in the samples. The results show that ZnO can significantly decrease the crystallization temperature of zirconium-based glaze, depress the formation of Ca 2 ZrSi 4 O 12 , and promote the devitrification of transitional crystals t - ZrO 2 and Ca 2 ZnSi 2 O 7 , as well as lead to the formation of more zircon than the ZnO -free glaze. It was also found that zircon not only can form from the interaction between t - ZrO 2 and SiO 2 but also can devitrify directly from the glass phase of zirconium-based glaze.

Description: Barium-substituted CsAlSi 2 O 6 pollucites, Cs x Ba (1− x )/2 AlSi 2 O 6 , and barium- and iron-substituted pollucites, Cs x Ba (1− x )/2 Al x Fe 1− x Si 2 O 6 and Cs x Ba 1− x Al x Fe 1− x Si 2 O 6 were synthesized with 1 ≥  x ≥ 0.7 using a hydrothermal synthesis procedure. Rietveld analysis of X-ray diffraction data confirmed the substitution of Ba for Cs and Fe for Al , respectively. The crystallographic analysis also describes the effects of three different types of pollucite substitutions on the pollucite unit cell: Ba 2+ for Cs 1+ cation results in little effect on cell dimensions, intermediate concentrations of Ba 2+ and Fe 3+ substitution result in net minor expansion due to Fe 3+ addition, and large Ba and Fe substitutions result in overall framework contraction. Elemental analysis combined with microscopy further supports the phase purity of these new phases. These materials can be used to study the stability of CsAlSi 2 O 6 as a durable ceramic waste form, which could accommodate with time Cs and its decay product, Ba . Furthermore, success in iron substitution for aluminum into the pollucite lattice predicts that redox charge compensation for Cs cation decay is possible.

Description: Nitrogen-doped mullite fibers were first synthesized through the nitridation of Al 2 O 3 – SiO 2 gel fibers in NH 3 . The results showed that nitrogen take-up began at 800°C, reached the maximum at 900°C, and then decreased with increasing temperature. The ceramic fibers nitridated at 900°C were essentially amorphous, but contained a small amount of nano-sized Al – Si spinel crystals. Mullite was formed after nitridation at 1200°C, accompanied by crystallization of χ- SiAlON and δ- Al 2 O 3 . The incorporation of nitrogen resulted in the formation of a variety of nitrogen-containing crystalline phases. The grain size of the mullite fibers can be adjusted by changing of the nitrogen content.

Description: The solubility limit of Ca in 99.99% pure α- Al 2 O 3 (alumina) was measured using a wavelength dispersive spectrometer mounted on a scanning electron microscope. Al 2 O 3 samples were equilibrated at a concentration which ensured saturation of the Al 2 O 3 grains with Ca , and were quenched in water from 1600°C. The results were compared with those from samples which were furnace cooled from 1600°C. For the quenched samples, the Ca solubility limit was found to be 51 ± 1 ppm, which is significantly larger than the solubility limit for samples which were furnace cooled (26 ± 1 ppm).

Description: The dispersion and rheology of aqueous ZrB 2 nanosuspensions were investigated by zeta potential measurements, particle size measurements, sedimentation tests, and rheology measurements, with poly (acrylic acid) (PAA) as dispersant. Results showed that the dispersion and rheology of nanosized ZrB 2 suspensions in aqueous media were dependent on pH value, PAA concentration, solid loading, and ball milling time. Concentrated (up to 30 vol% solid loading) and well-stabilized aqueous ZrB 2 nanosuspension with low viscosity (0.485 Pa s at 60/s) was prepared at pH 10, with 1.0 wt% PAA.

Description: This work focuses on the fabrication and assembly of cylindrical plasma containment tubes using DuPont's 951 low temperature co-fired ceramics (LTCC) for use in miniature electrostatic thrusters. The tube is used to contain argon plasma, which is generated by a spiral inductively coupled plasma antenna, which is also fabricated in LTCC. The tube also interfaces with two electrically biased grids on the opposite end, which accelerate the plasma out of the tube. These interfaces are highly dependent on the dimensions and tolerances of the containment tube. The development of the fabrication process will be presented for the incorporation of the tubes and grids onto the base as a single structure. This includes constructing the antenna base, shaping the “rolled” LTCC containment tube using a jig and isostatic press, and integrating the tube and antenna base during the firing. Following the fabrication, measurements will be taken to determine tube circularity and hermeticity of the seal at the interface between the tube and the antenna base. The results will be presented and characterized to evaluate the effectiveness of the structure as well as the documentation of the development of a rolled LTCC tube structure integrated with a planar LTCC antenna base.

Description: This article summarizes the opportunities and challenges for future research in ceramics used in biology and medicine. The summary was prepared from the seven presentations at the 4th International Congress on Ceramics held from July 15 to 19, 2012, in Chicago, USA. The major emerging opportunities identified were as follows: (i) developing fundamental understanding of bioactive ions used in bioceramics, (ii) possibility of using novel manufacturing methods such as 3D printing, (iii) attaching bioceramics to metallic implants, and (iv) enabling collaboration between ceramicist, biologist, industry, and medical professionals.

Description: Hydroxyapatite coating was developed with high degree of crystallinity on SS316L substrate by the microplasma spraying technique. Systematic in vitro study of the coating was conducted after the immersion into the simulated body fluid for 1–14 days. Inductively coupled plasma–atomic emission spectroscopy, X-ray diffraction, Fourier transformed infrared spectroscopy, and scanning electron microscopy were utilized for physicochemical and microstructural characterizations. Nanoindentation technique employed to evaluate the nanohardness and Young's modulus of the coating at a constant load of 100 mN. Further, the tribological characteristic was also examined by microscratch testing at a ramping normal load of 10–10.6 N.

Description: Titania micropatterns with periodic arrangements were successfully formed on glass substrates for use with electromagnetic wave energy resonance and localizations in terahertz frequency ranges. Geometric arrangements of acrylic polygonal tablets with titania particle dispersions were fabricated by using micropatterning stereolithography. Moreover, periodically arranged full anatase-phase titania tablets were created homogeneously through liquid-phase crystal depositions of water solvent processes, using microtemplates fabricated by using the stereolithography system. The terahertz wave properties were measured and calculated by using a time-domain spectroscopic system and finite-difference time-domain method.

Description: The possibility of developing large solid oxide fuel cell (SOFC) stacks based upon 25 cm 2 ceramic oxide anode-supported cells is investigated. Planar fuel cells comprising strontium titanate-based anode support impregnated with active catalysts were prepared using a combination of deposition techniques. The fuel cell tests performed in a semisealed rig have shown power densities of 185 mW cm −2 at 850°C using humidified hydrogen as fuel and air as oxidant. The structure and evolution of the catalytically active impregnated materials-10 mol% Gd -doped CeO 2 and nickel- are analysed using electron microscopy at the end of the fuel cell test, revealing that a ceria and nickel layer surrounds the titanate backbone grains while ~50–150 nm spherical-like nickel particles uniformly decorate this top layer.

Description: Structural and dielectric properties of (1− x ) BaTiO 3 – x Bi ( Mg 1/2 Ti 1/2 ) O 3 ( x  = 0.1–0.5) were investigated to understand the binary system and utilize it for high-voltage, high energy density capacitors. The solubility limit for Bi ( Mg 1/2 Ti 1/2 ) O 3 in a BaTiO 3 perovskite was between x  = 0.4 and x  = 0.5. A phase with pseudocubic symmetry was formed for x  = 0.1–0.4; a secondary phase developed at x  = 0.5. Dielectric measurements showed highly diffusive and dispersive relaxor-like characteristics from 10 to 40 mol% of Bi ( Mg 1/2 Ti 1/2 ) O 3 . These compositions also showed high relative permittivity with low-temperature coefficients of permittivity over a wide range of temperatures −100°C–600°C. Relaxation behavior was quantitatively investigated using the Vogel–Fulcher model, which revealed the activation energy of 0.17–0.22 eV. Prototyped multilayer capacitors of 18 mm × 17 mm × 4 mm dimensions with a capacitance of 12.5 nF at 1 kHz were successfully constructed and demonstrated multiple charge–discharge characteristics up to 10 kV.

Description: K 3 Gd ( PO 4 ) 2 : RE 3+ (RE = Eu, Tb) are prepared by solid-state reaction and their photoluminescence (PL) properties are investigated under UV and VUV excitation, respectively. The obtained experimental data show that no energy transfer happens among the activator ions Tb 3+ or Eu 3+ under UV excitation. Under 147-nm excitation, the strongest emission intensity of K 3 Gd ( PO 4 ) 2 : RE 3+ (RE = Eu, Tb) is obtained when the activator ions Tb 3+ or Eu 3+ concentration is 0.8 mol, the integrate emission intensity of K 3 Gd 0.2 (PO 4 ) 2 :0.8Tb 3+ is about 204% of commercial phosphor Zn 1.96 SiO 4 :0.04 Mn 2+ with chromaticity coordinates of (0.340, 0.561) and the decay time of about 5.09 ms under 147-nm excitation. We analyze the experimental data and propose a possible energy-transfer mechanism under 147-nm excitation.

Description: The 0.72 Bi ( Fe 1− x Al x ) O 3 –0.28 BaTiO 3 ( x  = 0, 0.01, 0.03, 0.05, and 0.07, abbreviated as BFA x – BT ) lead-free high-temperature ceramics were prepared by the conventional ceramic processing. Systematic investigation on the microstructures, crystalline structures, dielectric and piezoelectric properties, and high-temperature stability of piezoelectric properties was carried out. The crystalline structures of BFA x –BT ceramics evolve from rhombohedral structure with x 〈  0.01 to the coexistence of rhombohedral structure and pseudocubic phases with x  ≈ 0.01, finally to pseudocubic phases when x 〉  0.03. Remarkably high-temperature stability with near-zero temperature coefficient of piezoelectric properties ( TCk p ), together with improved piezoelectric properties has been achieved for x  = 0.01 BFA x –BT ceramics. The BFA x –BT( x  = 0.01) ceramics simultaneously show the excellent piezoelectric properties of d 33  = 151 pC/N, k p  = 0.31 and super-high-temperature stability of T d  = 420°C, TCk p  = 1 × 10 −4 . It is considered that the observed strong piezoelectricity and remarkably high-temperature stability should be ascribed to the phase coexistence of rhombohedral and pseudocubic phases. The rhombohedral phases have a positive TCk p value and the pseudocubic phases possess a negative TCk p value. Thus, the TCk p value of BFA x –BT ceramics can be tuned by composition of x .

Description: Owing to the widespread presence of electromagnetic interferences, it is necessary to develop new materials with excellent high-temperature electromagnetic wave (EM) absorption properties. In the present work, ZnO is infiltrated into porous ZrSiO 4 substrates to form ZnO / ZrSiO 4 composite ceramics using sol-gel process. The doping of aluminum results in the improvement of electrical conductivity and the significant change in the morphology of ZnO . With the increase in environment temperature during measurement, the permittivity of the composite ceramics increases first and then decreases dramatically, which is attributed to the change in conductive loss. The electrical conductivity increases with increasing measurement temperature. However, the concentration of oxygen vacancies decreases under air atmosphere when the measurement temperature increases continuously, which results in the reduction in conductivity. Therefore, permittivities of the undoped and doped ceramics measured at 673 K are higher than the ones at the other temperatures. The composite ceramics maintain a relatively high EM absorption coefficient, low reflection coefficient (RC), and wide effective absorption bandwidth at environment temperatures up to 773 K. As a result, we conclude that the ZnO / ZrSiO 4 composite ceramics exhibit a promising prospect as a kind of high-temperature EM absorbing material.

Description: [0001] textured alumina ceramics with a fine grain size were fabricated between 1400°C and 1600°C via templated grain growth (TGG) using fine alumina platelets (~0.6 and ~3 μm diameter) aligned by tape casting in either a 50 nm α- Al 2 O 3 matrix powder, or in a seeded boehmite sol. The 3 μm templates could be readily aligned by tape casting in both matrices (orientation parameters r  = 0.27 and 0.18, respectively), whereas 0.6 μm diameter templates were well aligned in the seeded boehmite sol only ( r  = 0.29). Improved alignment in boehmite sols is attributed to inorganic gelation, resulting in a strongly pseudo-plastic rheology that preserves template alignment against the influence of Brownian motion. The in situ formation of fine α- Al 2 O 3 matrix after transformation in the seeded boehmite system results in a higher driving force for TGG and improves texture development. The combination of 3 μm templates with a seeded boehmite matrix results in extremely high texture qualities (texture fraction f  = 0.97–0.99, r  = 0.17) while maintaining a relatively fine grain size (5–10 μm in diameter and 1.5–3 μm in thickness). Although undoped samples can be fully textured at 1600°C, adding as little as ~0.25 wt% CaO / SiO 2 dopant improves TGG kinetics and yields full texture at 1400°C.

Description: Yttria partially stabilized zirconia Y-PSZ/glass-ceramic composites were prepared by reaction sintering using powder mixtures of a SiO 2 – Al 2 O 3 – ZnO – CaO – ZrO 2 – TiO 2 -based glass and yttria partially stabilized zirconia (Y-PSZ). The glass crystallized during sintering at temperatures of 1173, 1273, and 1373 K to give a glass-ceramic matrix for high-temperature protecting coatings. With the increasing firing time, the added zirconia reacted with the base glass and a glass-ceramic material with dispersed zircon particles was prepared in situ . Furthermore, the added zirconia changed the crystallization behavior of the base glass, affecting the shape, amount, and distribution of zircon in the microstructure. The bipyramid-like zircon grains with imbedded residual zirconia particles turned out to have two growth mechanisms: the inward growth and the outward growth, and its rapid growth was mainly dominated by the later one. For comparison, the referenced glass-ceramic was prepared by sintering using exclusive glass granules and its crystallization behavior at 1173–1373 K was examined as well. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and X-ray diffraction (XRD) were used to characterize the crystallization behavior of the base glass and the phase evolution of the Y-PSZ/glass-ceramic composites.

Description: In this study, we present the preparation of a bulk material with a composition of 80 GeTe 2 –20 Ga 2 Te 3 by combining mechanosynthesis and sintering. This composition cannot be prepared by conventional melt/quenching technique. The progressive evolution of the powder during ball-milling is followed by X-ray Diffraction (XRD) and Differential Scanning Calorimetry analysis. The final powder obtained is highly crystalline, but a glass transition temperature ( T g ) is observed, indicating the presence of some amorphous phase remaining, allowing for its efficient sintering. By hot-pressing, a dense bulk material with a fine microstructure and a high electrical conductivity is obtained. The synthesis method described represents a simple and cost-effective way to produce tellurium-based materials of desired dimension with potential applications for optical storage or thermoelectric devices.

Description: Revealing and understanding the microscopic origins of the macroscopic properties of aluminosilicate glasses is important for the design of new glasses with optimized properties. In this work, we study the composition-structure-property relationships in 20 MgO / CaO sodium aluminosilicate glasses upon Al 2 O 3 -for- SiO 2 and MgO -for- CaO substitutions. We find that some properties (density, molar volume, Young's modulus, and shear modulus) are linear through the investigated range of Al 2 O 3 compositions, while others (refractive index, coefficient of thermal expansion, Vickers hardness, isokom temperatures, and liquid fragility index) exhibit a change in the slope around the composition with [ Al 2 O 3 ] = [ Na 2 O ], which is especially pronounced for the glasses containing MgO . We discuss these phenomena based on structural information obtained by NMR spectroscopy and topological considerations.

Description: In this article the changes on the surface of the 45S5 bioglass submitted to an enrichment with calcium ions were investigated. The method employed was the immersion of bioglass in calcium molten salt bath at 450°C. Changes in composition were probed by different techniques of chemical analysis. The use of SEM-EDS allowed estimating the thickness modified, as being about 10 μm. X-ray photoelectron spectroscopy enabled to infer over the structural changes on the surface of 45S5 bioactive glass. The entry of calcium in the vitreous network promoted the phase separation of microdomains rich in silica and phosphate on the surface of the glass. The formation of immiscibility region was attributed a depolymerization of silica network and also, to a possible migration of phosphate species from the bulk. The results of this study indicate a great change in the surface properties of this biomaterial. In addition, the method proposed in this study proved to be very promising in the possibility of designing the surface of bioactive glasses, to modulate the desired properties, keeping the bulk unchanged.

Description: Octylamine-coated silver nanoparticles with an average size of 10 nm were synthesized and added to the AZO powder as fillers to increase the density of the sintered target. The resulting Ag–AZO nanocomposite powder was formed into compacts by a uniaxial pressing process. It was found that the addition of octylamine- coated silver nanoparticles can increase the density of AZO powder compacts by ~ 4% after sintering. The optimum content of silver addition is about 0.13 wt%. It is suggested that the melted silver fills the void space between agglomerate pores and enhances the interconnection between nanocrystalline AZO powders. The films deposited using the here-synthesized Ag–AZO target showed lower resistivity and high carrier concentration compared with the one using AZO target.

Description: It is known that several factors can affect the clinical success and durability of fixed partial dentures. Therefore, the aim of the present study was to present a literature review about the longevity, clinical success, and quality, as well as, patients' and dental surgeons' satisfaction of ceramic fixed dentures. High rate of patients' satisfaction has been observed in relation to the esthetic of ceramic crowns. In addition, the literature has shown that dental ceramics can be used in several clinical situations with high success rate and longevity. Despite of failures and complications of ceramic restorations, nowadays, with the improvement of mechanical properties of such materials, ceramic crowns present a favorable prognosis and can be used in several clinical situations with high success rate, clinical quality, and great patients' satisfaction.

Description: The self-reactive quenching technology, which combines flame thermal spraying technology, self-propagating high-temperature synthesis (SHS), and rapid solidification, is a new method for preparation of hollow microspheres. Based on this, the effect of heat released by different exothermic systems on preparation of hollow ceramic microspheres was studied. The results show that for low-exothermic system Si -Sucrose- NH 4 Cl , the self-propagating reactions cannot occur, and the quenching products are Si microspheres with porous structure. For the moderate exothermic system Al – SiO 2 -Sucrose, the quenching products consist of some grains, which are hollow spherical or nearly spherical particles and irregular powders. Formation of Al 2 O 3 – Si indicates possible occurrence of SHS reactions. Meanwhile, for high-exothermic system Al – Cr 2 O 3 -Sucrose- Si -Epoxy Resin, the quenching products consist of internal hollow spherical grains and irregular-shaped porous particles; the phase composition mainly contains Al 2 O 3 , Cr 3 C 2 , Cr 7 C 3 , Cr 3 Si , and mullite, showing completeness of SHS reactions. The higher the adiabatic combustion temperature of the system is, the more heat it releases is higher, and the ceramic droplets form easilier.

Description: Lanthanum hexaaluminate is a promising competitor to establish yttria partially stabilized zirconia as a thermal barrier coating material for Ni -based superalloy due to its relative low intrinsic thermal conductivity and low sinterability at temperatures exceeding 1100°C. Sr 2+ and Ti 4+ were selected as two dopants to partially substitute the La 3+ and Al 3+ in LaMgAl 11 O 19 , respectively. The variation in thermal conductivity with Sr 2+ and Ti 4+ fractions was analyzed based on structure information provided by X-ray diffraction and Raman spectroscopy. The average crystal size of LaMgAl 11 O 19 sintered at 1600°C for 10 min by spark plasma sintering is in nanoscale. The fully dense La 1− x Sr x MgAl 11− x Ti x O 19 solid solution showed a minimum thermal conductivity value (λ = 1.12 W/(m K) −1 , T  = 1273 K) at the composition of La 0.5 Sr 0.5 MgAl 10.5 Ti 0.5 O 19 ,which possibly reduces from the enhanced phonon scattering due to mass and strain fluctuations at the Ln 3+ and B 3+ sites.

Description: Aqueous 3Y-TZP inks with solid contents of 22 and 27 vol% were used for fabricating three-dimensional ceramic components by the direct ink-jet printing process (DIP). The DIP fabrication was realized using a thermal ink-jet (TIJ) printing system. Despite the different physical properties of the inks, both inks were successfully ejected and deposited. To define the optimum window of the ink properties required for a stable printing operation, both ceramic inks as well as a typical TIJ ink were characterized in terms of particle size distribution, zeta potential, viscosity, surface tension, and the inverse Ohnesorge number ( Oh −1 ). Moreover, single drops of all inks were deposited and analyzed by scanning electron microscopy (SEM) to examine the form and integrity of the ejected drops. Demonstration objects (a base with curved channels and a sample molar tooth) were DIP fabricated using both of the ceramic inks. These objects show the potentials of the DIP process for ceramics manufacturing particularly by using TIJ printing systems.

Description: Spherical granules of aluminum nitride (AlN) with an average particle size of about 50 μm were produced from aqueous suspensions using an AlN powder surface treated against hydrolysis with aluminum dihydrogenphosphate [Al(H 2 PO 4 ) 3 ]. Two different amounts of Al(H 2 PO 4 ) 3 were tested and the effects of surface treatment and aging time were evaluated by various techniques (XRD, TG-DTA, zeta potential and pH measurements). The treated powder exhibited antihydrolytic property and good dispersing behavior, enabling the preparation of low-viscosity and high-concentration aqueous AlN slurries for freeze granulation. The spherical AlN granules were sintered in a boron nitride (BN) powder bed followed by ultrasonic washing of the AlN granulates/BN mixture to remove BN. The sintered spherical AlN granules present excellent crystallinity and high sphericity as observed from SEM micrographs.

Description: Near-infrared (NIR) quantum cutting involving the emission of two NIR photons for each visible photon absorbed is realized from Eu 2+ /Yb 3+ codoped chalcohalide glasses. Excitation, emission and decay spectra are measured to prove the occurrence of cooperative energy transfer (ET) from Eu 2+ to Yb 3+ . The maximum ET efficiency obtained is as high as 85%. The ET from Eu 2+ to Yb 3+ is followed by dipole-dipole interaction. The possible mechanism of ET is discussed.