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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters  (1)
  • anorthite  (1)
  • American Institute of Physics  (1)
  • Copernicus  (1)
  • American Chemical Society (ACS)
  • 2010-2014  (2)
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  • 1
    Publication Date: 2017-04-04
    Description: Etna volcano, Italy, hosts one of the major groundwater systems of the island of Sicily. Waters circulate within highly permeable fractured, mainly hawaiitic, volcanic rocks. Aquifers are limited downwards by the underlying impermeable sedimentary terrains. Thickness of the volcanic rocks generally does not exceed some 300 m, preventing the waters to reach great depths. This is faced by short travel times (years to tens of years) and low thermalisation of the Etnean groundwaters. Measured temperatures are, in fact, generally lower than 25 °C. But the huge annual meteoric recharge (about 0.97 kmˆ3) with a high actual infiltration coefficient (0.75) implies a great underground circulation. During their travel from the summit area to the periphery of the volcano, waters acquire magmatic heat together with volcanic gases and solutes through water-rock interaction processes. In the last 20 years the Etnean aquifers has been extensively studied. Their waters were analysed for dissolved major, minor and trace element, O, H, C, S, B, Sr and He isotopes, and dissolved gas composition. These data have been published in several articles. Here, after a summary of the obtained results, the estimation of the magmatic heat flux through the aquifer will be discussed. To calculate heat uptake during subsurface circulation, for each sampling point (spring, well or drainage gallery) the following data have been considered: flow rate, water temperature, and oxygen isotopic composition. The latter was used to calculate the mean recharge altitude through the measured local isotopic lapse rate. Mean recharge temperatures, weighted for rain amount throughout the year, were obtained from the local weather station network. Calculations were made for a representative number of sampling points (216) including all major issues and corresponding to a total water flow of about 0.315 kmˆ3/a, which is 40% of the effective meteoric recharge. Results gave a total energy output of about 140 MW/a the half of which is ascribable to only 13 sampling points. These correspond to the highest flow drainage galleries with fluxes ranging from 50 to 1000 l/s and wells with pumping rates from 70 to 250 l/s. Geographical distribution indicates that, like magmatic gas leakage, heat flow is influenced by structural features of the volcanic edifice. The major heat discharge through groundwater are all tightly connected either to the major regional tectonic systems or to the major volcanic rift zones along which the most important flank eruptions take place. But rift zones are much more important for heat upraise due to the frequent dikes injection than for gas escape because generally when dikes have been emplaced the structure is no more permeable to gases because it becomes sealed by the cooling magma.
    Description: Published
    Description: Vienna, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: groundwaters ; volcanic surveillance ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 2
    Publication Date: 2017-04-04
    Description: The effect of pressure on melt viscosity was investigated for five compositions along the join An(CaAl2Si2O8)–Di(CaMgSi2O6) and four alkali silicates containing lithium, sodium, and potassium in constant ratio of ∼ 1:1:1, but alkali-silica ratios are varying. The experiments were performed in an internally heated gas pressure vessel at pressures from 50 to 400 MPa in the viscosity range from 108 to 1011.5 Pa⋅s using parallel plate viscometry. The polymerized An composition shows a negative pressure dependence of viscosity while the other, more depolymerized compositions of the join An–Di have neutral to positive pressure coefficients. The alkali silicates display neutral to slightly positive pressure coefficients for melt viscosity. These findings in the high viscosity range of 108–1011 Pa⋅s, where pressure appears to be more efficient than in low viscous melts at high temperature, are consistent with previous results on the viscosity of polymerized to depolymerized melts in the system NaAlSi3O8–CaMgSi2O6 by Behrens and Schulze [ H. Behrens and F. Schulze, Am. Mineral. 88, 1351 (2003) ]. Thus we confirm that the sign of the pressure coefficient for viscosity is mainly related to the degree of melt polymerization in silicate and aluminosilicate melts.
    Description: DFG Grant n.°BE1720/9
    Description: Published
    Description: 044504-14
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: open
    Keywords: viscosity ; polymerisation ; anorthite ; diopside ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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