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  • Chemical Engineering  (3,179)
  • Wiley-Blackwell  (3,179)
  • Institute of Physics
  • Springer
  • 2010-2014
  • 1980-1984  (2,596)
  • 1955-1959  (583)
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Year
  • 101
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 20J 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 102
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 103
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 21J 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 104
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 20J 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 105
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 281-281 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 106
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 107
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 290-295 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Three viscosity correlations were tested for liquids at their boiling points. Compounds studied included normal paraffins, branched-chain hydrocarbons, aromatics, halogenated methanes and ethanes, water, and aliphatic alcohols. The correlations were tested for the most part with viscosity and thermodynamic data found in the literature. Some experimental viscosity measurements were made, however, for normal paraffins from pentane to octane at temperatures up to about 300°F., which is higher than has previously been reported.Two correlations are based on Eyring's theory of absolute reaction rates. The third is based on the compressibility factor of the saturated liquid, and this correlation is unique, as all available data for normal paraffins with eight or more carbon atoms are represented by a single curve. The three correlations presented here can be used to extrapolate viscosity data over large temperature ranges up to the critical temperature. Logical predictions of the viscosities of related compounds are possible.
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 337-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Air bubbles were formed in water and in mineral oil by use of single, circular, horizontal, square-edged orifices facing upward. Twenty orifices were tested, ranging from 0.017 to 0.79 cm. (0.0067 to 0.31 in.) in radius. Incieasms the whime, of the gas chamber below the orifice (over the range of 4 to 4,000 cc.) was found to increase the bubble size. The gas-chamber volume was minimized in most of the work in order to confine attention to the effects of orifice size and gas-flow rate. The liquid containers were large enough to eliminate significant wall effects, and operations were conducted at atmospheric pressure.The gas-flow rate was varised from about 0.01 to about 250 cc./sec. over the course of the work. At relatively low rates, the orifices generally formed single “static” bubbles, the volumes of which were proportional to the surface tension and orifice radius and independent of the gas-flow rate. At high flow rates the bubble frequency became high and the bubble volume became proportional to the gas-flow rate and independent of the surface tension. The bubble frequency reached a maximum value for each orifice, this value being a function of the orifice radius. For air bubbles in water, the correlation of the maximum bubble frequency, nm bubbles/sec., with the orifice radius, r cm., and the air-flow rate, q cc./sec., was found to be nm = 9.1q0.13/r0.43. The maximum frequencies ranged from about 25 bubbles/sec. for the largest orifices to about 75 bubbles/sec. for the smallest orifices used.It was found that consecutive bubbles paired or coalesced in definite ways in certain ranges of the gas-flow rate. A description is given of this bubble behavior, based on stroboscopic and photographic observation.
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  • 109
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 343-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of estimating enthalpies of mixtures of light hydrocarbons is presented. Enthalpes so obtained are consistent with equilibrium-vaporization constants that have been correlated with the composition characterization factor, the molal average boiling point (M.A.B.P.).Values of the isothermal-pressure corrections to the enthalpy of ideal gas mixtures (H° — H) are presented on three plots with parameters of temperature, pressure, and molal-average boiling point. Pressures range from zero to 1,500 lb./sq. in. abs., temperatures from -200° to 500°F., and M.A.B.P. from -200° to 150°F.
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  • 110
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 347-353 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A rigorous analysis of the available data presented in the literature for all the saturated aliphatic hydrocarbons from methane through n-eicosane was conducted to establish the constants A, B, C, and D of the vapor-pressure equation developed by Frost and Kalkwarf (21). With all the constants determined, vapor pressures can be calculated accurately from the triple to the critical point. The actual constants A, B, C, and D have been calculated from the available reported vapor-pressure data of eighty-seven saturated aliphatic hydrocarbons and include all the normal paraffins through eicosane and all the isomeric paraffins through the nonanes.In order to ascertain the validity of calculated-vapor-pressure constants, values of A, B, C, and D were produced from the molecular structure and normal boiling point for all the normal paraffins through eicosane and all the thirty-four isomeric nonanes. The normal paraffins were selected to cover the range of the saturated aliphatic hydrocarbons; whereas the nonanes were chosen because they represent the most complex structures for which reported vapor pressures are available.With the calculated constants, vapor pressures were evaluated from the equation at several representative points and were compared with reported values to produce an overall absolute average percentage of deviation of 0.58 for the normal paraffins and 0.73 for the isomeric nonanes, or 0.68 for these fifty-four saturated aliphatic hydrocarbons.
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  • 111
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    AIChE Journal 2 (1956), S. 389-392 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By use of saturated-vapor enthalpies determined by accepted procedures in conjunction with differential latent heats of condensation, the saturated-liquid enthalpies are established for the system methane-ethane at 200, 400, and 600 lb./sq. in. abs. and for the system ethane-n-butane and propane-n-butane at the two lower pressures. Where comparison is possible, the liquid-enthalpy values obtained by this method are in general agreement with those previously determined by Edmister and Canjar. The procedure used is thermodynamically rigorous and may be applied to any binary mixture, provided the Benedict-Rubin-Webb equation of state is valid in the vapor phase and P-V-T-x data are available.
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  • 112
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    AIChE Journal 2 (1956), S. 393-403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 113
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    AIChE Journal 2 (1956), S. 426-427 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 11S 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 115
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 116
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 117
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 118
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    AIChE Journal 2 (1956), S. 529-535 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This investigation was undertaken to show how the efficiency of solute transfer between two immiscible liquids is influenced by the type, size, and submergence and rotational speed of the impeller and the degree of baffling, residence time, and phase ratio. The system water-kerosene-n-butylamine solute was agitated in a continuous-flow 14 3/4-in. -diam. vessel using propellers, spiral turbines, and flat-blade turbines from 4 to 10 in. in diameter. The feed streams were introduced at the wall at the bottom of the vessel and left at the top of the vessel.On the basis of the power required for a given level of stage efficiency, the best agitator design is any impeller that has a diameter about 40% of the vessel diameter and is centered in the unbaffled vessel. Without baffles the impeller type and depth of submergence have little effect on performance. The power increase required by the addition of baffles is small at the highest stage efficiencies, especially with the larger radial-flow impellers, but may be severalfold at efficiency levels of 70 to 90%. This presumably results from the lowered mass transfer driving force caused by the increase in end-to-end mixing due to wall baffles. Whether baffles have such a large adverse effect if the feed is introduced into the impeller rather than at the vessel wall is not fully established, but there is some evidence that baffling is also undesirable in this case. For baffled operation, impeller type and submergence do affect performance.A correlation of stage efficiency is presented in terms of Reynolds number and power number. In addition, energy input per volume of total flow is correlated in terms of residence time and stage efficiency for one size of baffled propeller.Spot samples taken from the vessel showed large, random-concentration fluctuations out to 20 residence times and perhaps indefinitely. Reproducible results were obtained by taking time-averaged samples.
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  • 119
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    AIChE Journal 2 (1956), S. 545-551 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid-liquid phase separation and mass transfer studies were made in a 4-in.-diam. cyclone of conventional construction. The cyclone was tested with oil-water volume phase ratios ranging from values of 1/3 to 9/1 and for total flows up to 24 gal./min., although most variables were studied at a feed rate of 10 gal./min. Kerosene or a white oil (vis. 9 centipoises at 77°F.) was used as the oil phase. Valve or line premixing was used to disperse the feed. Valve pressure drops were in the range of 0.1 to 1.0 lb./sq.in., and inlet drop sizes, where determined, were about 1 mm. The optimum cyclone geometry (volume, diameter of inlet, overflow and underflow lines) and the optimum split (overflow/underflow) were determined in terms of a phase-separation efficiency Es.At optimum geometry and split a number of mass transfer runs were made in which monobutylamine solute was transferred from the kerosene to the water phase. These runs indicated that Es decreased but mass transfer efficiency increased as the feed rate or pressure drop across the mixing valve was increased.
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  • 120
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    AIChE Journal 2 (1956), S. 552-554 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By use of Cp values from the literature and experimentally determined vapor-pressure-temperature and pressure-volume-temperature relationships, a thermodynamic network has been established for tertiary butyl alcohol in the range of 78° to 500°F. and 14.7 to 700 lb./sq. in. abs. The results include tabulated values of p, v, T, H, S, f, and Z, as well as the vapor-pressure-temperature curve, the critical properties, and constants for the Beattie-Bridgeman equation.The original pressure data were accurate to within 0.14% in the high range and to within 4% in the low range. The limits on the experimental volume data were 0.07% for large vapor volumes and 2% for liquid volumes. The temperature was determined to within 0.1 °F., or less than 0.02% of the absolute temperature.Experimentally determined vapor pressures were found to be lower than those reported in the literature in the range above 1 atm. Values previously reported were obtained by extrapolation of a vapor-pressure-temperature relation developed for use at subatmospheric pressures. For pressures below 1 atm. the experimental values agreed with the reported values.
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  • 121
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    AIChE Journal 2 (1956), S. 555-560 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes an investigation of the factors affecting the change in composition with vaporization of a binary-component spray in heated air at atmospheric pressure. The behavior of the system orthodichlorobenzene-tetrachloroethylene was studied in air ranging from 400° to 1,000°F. Initial drop diameters in the sprays were in the 20- to 400-µ range. The experimental data obtained indicated that the rate of change of spray composition during vaporization was affected only by the chamber-air temperature, the initial feed composition, and the nozzle characteristics.Equations are presented which mathematically describe the vaporization process, liquid diffusion being assumed within the drop controls. These equations have been solved by a stepwise procedure for three initial drop sizes. Results of these calculations have been added statistically according to the initial-drop-size distribution in order to predict the vaporization behavior of the spray. Details of this process of statistical combination have been summarized by Culverwell (1).The calculations agreed with the experimental data previously obtained during the first 5 in. of nozzle-to-tray travel. After 5 in. the deviation was great. Future experimental work to determine more precise values of drop-size distribution, initial drop velocity, and liquid diffusion coefficient may result in more complete agreement.
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  • 122
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    AIChE Journal 2 (1956), S. 560-567 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The production of oil and gas by pressure depletion involves both the formation of bubbles and the diffusion of gas from the liquid phase into these bubbles. Studies were undertaken to outline in detail the process of bubble formation when the driving force is small. This work shows that the formation of bubbles is a random process which can, however, be described by a simple probability distribution function. Also, calculations have been made to determine how fast gas will diffuse into uniformly distributed gas bubbles.These results make it possible to describe the manner in which a gas phase is established during the pressure depletion process. In this process the rate of pressure decline is the most important factor influencing the total number of bubbles produced. Laboratory tests have substantiated the finding that in certain types of porous media the amount of oil recovered is sensitive to the number of bubbles formed.
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  • 123
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    AIChE Journal 2 (1956), S. 568-571 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data are reported for the ignition of single grains of solid propellant in a stream of gas at high temperature. The investigation encompassed gas temperatures from 578° to 1,070°K., gas velocities corresponding to free-stream Reynolds numbers from 156 to 624, a complete range of oxygen-nitrogen mixtures, and a few oxygen-carbon dioxide mixtures. Pyrocellulose and double-base propellants were tested. The grains were approximately 1/8 in. in diameter and extended through the gas stream, so that ignition was forced to take place on the cylindrical surface rather than on the end of the grain. The exposure before ignition was measured for a large number of grains. The data can be represented by an equation that is consistent with the known effect of flow rate on convective heat transfer and the known effect of temperature on chemical reaction rates, an indication that both processes are important in ignition.
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  • 124
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    AIChE Journal 2 (1956), S. 572-573 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reactor-unit concept proposed by Hurt is extended in this paper to include fractional-order reactions and to show the effect of volume change on the system. Equations defining the reactor unit for homogeneous and heterogeneous reactions are derived.The catalytic dehydration of tertiary butanol was chosen as a means of studying the validity of the extended reactor-unit concept. The experimental investigation was conducted over a wide range of flow rates, catalyst bed heights, and temperatures. The result of the application of this modified reactor-unit expression to the correlation of the data was excellent.
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  • 125
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 126
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    AIChE Journal 2 (1956), S. 577 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 127
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    AIChE Journal 2 (1956), S. 12D-12D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 128
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 129
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    AIChE Journal 2 (1956), S. 12D-12D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 130
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    AIChE Journal 2 (1956), S. 12D-12D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 131
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    AIChE Journal 2 (1956), S. 578 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 132
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    AIChE Journal 3 (1957) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 133
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    AIChE Journal 3 (1957), S. 1-1 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 134
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    AIChE Journal 26 (1980), S. 1038-1041 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 135
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    AIChE Journal 26 (1980), S. 1044-1046 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 136
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    AIChE Journal 26 (1980), S. 1048-1049 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 137
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    AIChE Journal 27 (1981), S. 13-20 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A suboptimal control algorithm is derived for a continuous latex reactor subject to deterministic and stochastic disturbances to control the pathological behavior of the reactor. An extended Kalman filter based on an instantaneous local linearization technique is used to estimate the reactor states, and a quadratic performance index is used to derive the suboptimal feedback control law. This study successfully demonstrates the application of the multivariable control theory to the control of a simulated continuous latex reactor operating under limit-cycle conditions. The mathematical model used for the control studies was previously developed and has been shown to describe the performance of an actual reactor system extremely well over its entire range of operation.
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  • 138
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    AIChE Journal 27 (1981), S. 33-40 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Infinite dilution activity coefficients (γ∞) in binary liquid mixtures are data of wide practical and theoretical applicability, but their extensive use has been hindered by the experimental limitations of classical vapor-liquid equilibrium techniques. Two new experimental methods for accurate γ∞ determinations are presented. These techniques, both faster and more accurate than classical methods, are complementary, and their applicability to different types of binary systems is discussed.
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  • 139
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    AIChE Journal 27 (1981), S. 59-65 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Kerosine or propane was injected near the base of a small, air-fluidized bed of sand at 940°C. The fraction of fuel burnt within the bed was determined from a heat balance, for various particle sizes, fluidizing velocities, and bed depths.Assuming the initial formation of a train of fuel vapor bubbles, theoretical analysis indicated two stages of combustion: (1) rapid consumption of the oxygen initially between fuel vapor bubbles; (2) slow consumption of oxygen initially outside the fuel vapor region by radial diffusion of oxygen and fuel vapor, analogous to a diffusion flame.Comparison of experiment with theory gave effective radial diffusion coefficients of the same order of magnitude as the molecular diffusion coefficient. It was inferred that combustion occurs largely by a diffusion flame within the bed, with diffusion through the particulate phase being the rate-controlling step. This explains why fuel distribution is so important in attaining efficient combustion.
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    Notes: The gas chromatography technique was applied to measurements of diffusion of n-butane in zeolite NaY. The linear chromatography theory failed to explain these results quantitatively, and a significant system nonlinearity was demonstrated. This nonlinearity is likely associated with non-Fickian diffusion. Order of magnitude estimates of the diffusivity could still be obtained, however. Over the range of temperatures 105 to 240°C, the n-butane diffusivities were in the range 10-8 to 10-6 cm2/s. Similar results were obtained with n-hexane and calculated diffusivities were about an order of magnitude smaller than the corresponding n-butane values. In contrast, limited experiments with cyclohexane, 2, 2-dimethylbutane, and trans-decalin were entirely consistent with the linear chromatography theory. At the measurement temperatures, the intracrystalline diffusion was too rapid to be detected in any of these systems. Attempts to operate at lower temperatures where diffusion might be significant were frustrated by extensive peak broadening and concomitant loss of detector response.
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    AIChE Journal 27 (1981), S. 125-131 
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Alteration in concentration-independent catalyst decay rates due to the presence of finite external and internal mass transfer resistances is examined. Analytical expressions for external and overall time-dependent catalytic effectiveness are developed. Analysis of diffusion-limited catalyst deactivation in flow reactors is discussed.
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    AIChE Journal 27 (1981), S. 138-148 
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    Notes: A correlation is developed for the solubility of hydrogen in hydrocarbon solvents at temperatures from 310 to 700 K and pressures to 30 MPa (300 bar). The fugacity of dissolved hydrogen at zero pressure is correlated as a function of solubility parameter and temperature. The high-pressure fugacity is obtained upon applying a Poynting factor for which the required partial molal volume of hydrogen is also correlated in terms of solubility parameter and temperature. The Henry constant of hydrogen is included in the correlation. The correlated results are compared with experimental data for 22 systems of binary and ternary solutions and five narrow-boiling cuts of coal liquids. The overall average absolute deviation for all systems studied is approximately 6%.
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    AIChE Journal 27 (1981), S. 120-125 
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The interrelation between internal diffusion and concentration-independent deactivation is examined using a simple mathematical model. Analytical procedures are developed for evaluating the performance of single catalyst particles in the presence of diffusion and deactivation. By incorporating time-dependent effectiveness factors in design equations, reactor performance under the combined influence of diffusion and deactivation is predicted. By analogy to the effectiveness factor for non-deactivating systems, the concept of a deactivation effectiveness factor is introduced.
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    AIChE Journal 27 (1981), S. 159-162 
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    AIChE Journal 27 (1981), S. 163-166 
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    AIChE Journal 27 (1981), S. 170-172 
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    AIChE Journal 27 (1981), S. 174-174 
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    AIChE Journal 27 (1981) 
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    AIChE Journal 27 (1981), S. 203-207 
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    Notes: A new static cell for vapor-liquid equilibria up to 100 MPa between 233 and 433 K is presented. A detachable sampling microcell and a special chromatographic injector are used in a new sampling system suitable for gas chromatographic analysis of mixtures with high boiling components. The test system is N2 - n-Heptane at 305.45 K.
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    AIChE Journal 27 (1981), S. 193-202 
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    Notes: Dust particles originally generated by two steelmaking processes were dispersed in an air stream and passed through a pilot-scale high gradient magnetic filter. In accordance with theoretical predictions, the experimental results showed that collection was improved by increasing the depth or density of the steel wool filter, increasing the applied magnetic field, or decreasing the filtration velocity. Collection efficiency increased with particle size up to about 2 μm, above which the efficiency tapered off, apparently due to reentrainment effects. Collection efficiencies of greater than 99% were obtained, indicating that high gradient magnetic filtration may be a practical method of controlling particulate emission from processes in the iron and steel industry.
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    AIChE Journal 27 (1981), S. 284-292 
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    Notes: The existence of multiple stable and unstable steady states in a continuous stirred tank biological reactor (CSTBR) was demonstrated experimentally for the first time. These experiments resulted in the determination of growth rate, yield and intermediate metabolite concentration data entirely from continuous culture. This information was used to qualitatively interpret the stability behavior in terms of the biochemistry and bioenergetics of substrate metabolism.
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    AIChE Journal 27 (1981), S. 301-303 
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    AIChE Journal 27 (1981), S. 316-316 
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    AIChE Journal 27 (1981) 
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    AIChE Journal 27 (1981), S. 372-377 
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    Notes: This paper presents numerical solutions to the nonlinear, coupled boundary-layer equations governing laminar condensation heat and mass transfer in the vicinity of the forward stagnation point of a spherical cold water droplet translating in a saturated mixture of three components. The environment surrounding the droplet is composed of a condensable (steam), a noncondensable and nonabsorbable (air), and a third component which is noncondensable but absorbable (Elemental Iodine, for example). The dispersed and the continuous phases have been treated simultaneously. Results obtained here show excellent agreement with experimental results where available. An important conclusion is that for laminar condensation on a freely falling droplet, for a given thermal driving force and noncondensable gas concentration in the bulk, the dimensionless heat transfer decreases with increasing saturation temperature of the outside medium.
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    AIChE Journal 27 (1981), S. 396-403 
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    Notes: Simultaneous biological and activated-carbon treatment of organic wastewaters appears promising. The effects of bacterial film growth on adsorbent particles is investigated by laboratory work and mathematical modelling. Regeneration of the adsorbent due to film growth does occur, but faster than predicted. The discrepancy reflects uncertainty about the structure of bacterial films.
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    AIChE Journal 27 (1981), S. 429-442 
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    Notes: The development of processes requires the consideration of a wide variety of reactions which are required to transform raw materials into desired products, solve separation problems, and heat or cool process streams. These reactions have to be evaluated on the basis of raw material costs, kinetics, potential separation difficulties, catalyst costs, safety and reliability, as well as other factors that would arise in their industrial implementation. In this paper, the current status of research in reaction path synthesis has been reviewed. Details have been presented on the REACT program that has been developed for the synthesis of reaction paths for industrial organic chemicals.
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    AIChE Journal 27 (1981), S. 277-284 
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    Notes: A calculational method is proposed for the simulation of steady-state, multisolute, countercurrent extraction with axial dispersion. The method provides for complex chemical-equilibrium and phase-equilibrium relationships, and accounts for the individual resistances of the liquid phases in the calculation of mass-transfer rates. The solution procedure follows that developed by Newman (1967, 1968) for systems of simultaneous, second-order difference equations.Three example problems are solved to demonstrate the efficiency and flexibility of the method. These include (1) an example from McSwain and Durbin (1966), (2) calculation of axial-dispersion and mass-transfer parameters from experimental data for the extraction of acetic acid from water by a tertiary amine in an RDC extractor, and (3) simultaneous extraction of solutes that interact in an acid-base complexing reaction at the liquid-liquid interface. The examples all assume that extraction is governed by interphase mass-transfer rates and cell-wise backmixing; however, the method is also applicable to equilibrium-stage separators, separators described by the diffusional model of axial dispersion, and other countercurrent separation processes.
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    AIChE Journal 27 (1981), S. 312-315 
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    AIChE Journal 27 (1981), S. 588-592 
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    Notes: Quantitative measurements of the effect of a third phase of buoyant solid particles on the settling rates of suspensions of heavy particles are reported. It is found that for a wide range of concentration of both buoyant and heavy particles, the settling rates of both solid phases are greatly increased. If the phases are dilute, the settling velocities of both are retarded. The total settling time of heavy particles can be halved, but only under conditions that the light phase is unaccelerated. This suggests that small gas bubbles would form a more satisfactory buoyant phase. The high concentrations of thickened suspensions which result from the acceleration process are also reported.
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    AIChE Journal 27 (1981), S. 632-636 
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    AIChE Journal 27 (1981), S. 673-679 
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    Notes: A procedure for inserting vapor pressure data in the equations of state is presented. It provides a straightforward scheme for the extension of direct methods to the study of phase equilibria of polar mixtures and of solutions containing nonvolatile electrolytes. Some examples of application are also given.
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    AIChE Journal 27 (1981), S. 861-863 
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    Notes: Experimental data and theory both support the contention that there is a maximum solubility in solid-fluid equilibria. An example system, naphthalene-ethylene, at temperatures between the upper and lower critical end points and at pressures from 1 to 1000 bar is considered. There is also a solubility minimum in this system.
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    AIChE Journal 28 (1982), S. 91-96 
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    Notes: A model based on extension and secondary motions of striations in a deforming flow is used to predict details of the mixing and dispersion of viscous liquids. Generally, extension of intermaterial area and interfacial surface occurs in stagnation regions, and breakup ensues when the striated flow has left such a region or has time to form unmixing regions of smaller scale in the stretching flow. Complex criteria for the types of mixing anticipated are based on differences in viscosity, differences in density, striation scale, rate of stretch, and, for various degrees of immiscibility, interfacial tension.
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    Notes: A new process for purification of phenolic wastewaters by parametric pumping is presented.An equilibrium (linear) model for nonmixed dead volumes thermal direct mode parametric pumping is developed and the influence of bottom and top dead volume magnitudes on transient separation is analyzed.Analytical solutions for batch, continuous and semicontinuous operations are presented.Experimental data on the system phenol/water-Duolite ES861 include equilibrium isotherms at 20°C and 60°C and parapump runs for the cases mentioned above.
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    AIChE Journal 28 (1982), S. 134-138 
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    Notes: The volumetric and phase behavior of propane-perfluorocyclobutane mixtures has been determined in the critical region. This system exhibits a minimum temperature point in its critical locus curve and forms a positive critical azeotrope. The measured critical points in this system and their correlation using an extended corresponding states principle are reported in this paper.
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    AIChE Journal 27 (1981), S. 829-836 
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    Notes: A general analysis of a cascade of identical recycle units is presented by means of studying the fluid history inside the system. This is an extension of Part I (Mann et al., 1979) in which a single recycle unit was analyzed. The history of a fluid element is expressed in terms of the number of cycles it completes, the time it resides in the system and the total time it resides in a specific section of the system - all are random variables. Concepts from probability theory and stochastic processes are used to derive the number of cycles distribution (NCD), residence time distribution (RTD) and various total regional residence time distributions (TRRTDs) as well as their means and variances. Expressions for the joint distributions of pairs of these random variables are also derived as well as explicit expressions for their covariances and correlation coefficients. Two applications of the results are illustrated: one in analyzing a continuous spouted-bed coating unit and the second in using the cascade as a flexible, physically based multi-parameter flow model.
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    AIChE Journal 28 (1982), S. 245-250 
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    Notes: Both equilibrium and rate studies were made for the adsorption and desorption of Bovine Serum Albumin (B.S.A.), Fraction V, from dilute solutions using a new cellulose based ion exchange resin. Using the equilibrium data and a simple two-film theory to describe the rate data it was shown that during the initial perioid of adsorption the rate was controlled by film diffusion, after which it was controlled by intraparticle diffusion. The desorption was largely intraparticle diffusion controlled except for a very short surface desorption step. It is suggested that the model could be used to describe other protein adsorption/ion exchange processes.
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    AIChE Journal 28 (1982), S. 266-273 
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    Notes: A new reactor configuration, the annular bed reactor, is mathematically modeled to assess its capabilities as a CO methanation reactor. The results show that the reactor offers excellent temperature control characteristics and negligible pressure drop, and that it is a promising configuration for this as well as other reaction systems.
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    AIChE Journal 28 (1982), S. 294-301 
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    Notes: Approximate analytical solutions of the local temperature variations, due to viscous heating, in channel flows of non-Newtonian fluids with small Nahme-Griffith numbers were obtained by the WKB-J method. The results are general and easy to use so that extensive numerical computations are not required. Comparisons between the approximate analytical solution and complete numerical solution showed that the relative differences were very small.
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    AIChE Journal 28 (1982), S. 338-341 
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    AIChE Journal 27 (1981), S. 928-937 
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    Notes: The Isotherm Migration Method of numerically analyzing conduction with phase change is modified to handle surface and external resistances, appearance, and propagation of successive fronts into slabs of composite material of one or more constituents finely dispersed in a matrix, different components transforming at different temperatures. Procedures are developed for selecting temperature intervals between isotherms, initially locating isotherms by means of analytical approximations to the earliest stages, and thereafter inserting and removing isotherms as appropriate, particularly when each component gives rise to a separate front.
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    AIChE Journal 27 (1981), S. 968-974 
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    Notes: An improved model and solution procedure for nonequilibrium, multicomponent, two-phase, steady-state mass transfer problems are developed. Processes as diverse as packed column operation and the drying of porous solids are included. Ideas such as “HETP,” “HTU” or “mass transfer section” are avoided. “Stiff” systems appear to be handled well.
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    AIChE Journal 27 (1981), S. 1002-1008 
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    Notes: Our purpose is to give the physical conditions under which transfer of a surfactant through a fluid interface between two immiscible liquids may induce aperiodic convective motion.Adsorption-desorption rates are considered together with diffusional exchanges. New kinds of surface instabilities are then predicted.
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    AIChE Journal 27 (1981), S. 1017-1020 
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    AIChE Journal 27 (1981), S. 1026-1028 
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    AIChE Journal 27 (1981), S. 1039-1041 
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    AIChE Journal 28 (1982), S. 492-500 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis of a batch, dispersed-emulsion (liquid membrane), separation system results in simple models that describe the concentrations and masses of each phase as functions of time. Comparisons with a limited set of experimental data are offered. One of these models allows a set of pilot studies to be extended to performance predictions and comparative studies of different feed-membrane-solvent combinations, which could lead to an optimally designed separation process.
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 181
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    AIChE Journal 26 (1980), S. 9-15 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Tracer gas dispersion was measured for laminar flow through three different tube constrictions, at orifice Reynolds numbers between 10 and 5000 and Schmidt numbers of 0.213 and 0.769. Each constriction generates a confined jet which significantly enhances axial dispersion at intermediate Reynolds numbers ranging from 100 to 1000.
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    AIChE Journal 28 (1982), S. 514-515 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 28 (1982), S. 515-517 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 26 (1980), S. 16-23 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model is developed to describe non-isothermal sorption kinetics and used to interpret experimental uptake curves for CO2 in 4A zeolite and for CO2 and in C5H12 in 5A zeolite. The model assumes that the dominant mass transfer resistance is intracrystalline diffusion while the major resistance to heat transfer is the external heat transfer between the adsorbent sample and the surroundings. It gives a good representation of the kinetic behavior over a wide range of conditions. Both the extreme cases of isothermal diffusion and complete heat transfer control are demonstrated experimentally. Intermediate situations, in which the uptake rate is controlled by the combined effects of diffusion and heat transfer, are demonstrated as well. The parameters derived from the model are consistent, reproducible, and agree well with a priori estimates. The model provides a useful theoretical basis for the analysis of rapid sorption processes for which the non-isothermal approximation is invalid.
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    AIChE Journal 28 (1982), S. 166-168 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 28 (1982), S. 173-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 187
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    AIChE Journal 28 (1982), S. 610-616 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The governing equations for the laminar fully developed flow and heat transfer in curved tubes are solved numerically for a power-law fluid. Results for the velocity and temperature fields, the friction factor, and the Nusselt number are presented for different values of the Dean number, the Prandtl number, and the power-law index. The friction factor results are compared with available experimental data.
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    AIChE Journal 28 (1982), S. 626-637 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A multiparameter corresponding-states correlation is applied to describe fossil-fluid vapor/liquid-equilibrium behavior needed to design separation and other process units in coal-liquefaction plants. Data for both defined and undefined fluids pertinent to coal liquefaction are utilized in correlation development. The procurement of these data requires a thorough evaluation and study of the needs for additional data to improve correlations. These needs are systematically outlined in the context of the level of predication capability that can be achieved using the currently available data base.A conformal-solution model is applied to describe the behavior of many defined binary and ternary coal-solvent systems. The correlation is then extended to undefined systems such as those encountered in the Exxon Donor Solvent process. Correlation results are reported and correlation limits are assessed.
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    AIChE Journal 28 (1982), S. 671-676 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Tait equation has been extended and generalized to permit the calculation of densities of compressed liquids and their mixtures to a pressure of 68,950 kPa (10,000 psia) using only critical temperature, critical pressure, Soave-Redlich-Kwong acentric factor, saturation pressure, and saturated volume for a pure liquid or the corresponding mixture parameters for a liquid mixture. This correlation, together with the correlation developed by Hankinson and Thomson (1979) for saturated liquid densities, comprise COSTALD (COrresponding STAtes Liquid Density), an integrated method for estimating densities of nonpolar and slightly polar liquids and mixtures. The new correlation gave 0.446 average absolute percent error for 6,338 data points for nonpolar liquids, 2.57% error for 1352 data points for polar and quantum liquids, 0.369% error for 319 data points for LNG/LPG mixtures, and 1.61% error for all mixtures tested.
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    AIChE Journal 28 (1982), S. 702-702 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 191
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    Keywords: Chemistry ; Chemical Engineering
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  • 192
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Crystallization kinetics of sodium chloride have been studied in a Continuous Mixed Suspension Mixed Product Removal evaporative crystallizer at 50°C. A marine propeller was found to give a substantially lower nucleation rate than a pitched blade impeller under identical conditions. The crystal turnover time did not affect the effective nucleation rate.
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    AIChE Journal 28 (1982), S. 765-772 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized mathematical model is developed to describe the process of multicomponent adsorption on activated carbon in fixed beds. Numerical, finite difference, solutions for the adsorption of binary, and ternary organic mixtures are shown to satisfactorily match previously published experimental data.
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    AIChE Journal 28 (1982), S. 786-792 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When a small drop or bubble approaches a fluid-fluid interface, a thin liquid film forms between them, drains, until an instability forms and coalescence occurs. A hydrodynamic theory is developed for the first portion of this coalescence process: the drainage of the thin liquid film while it is still sufficiently thick that the effects of London-van der Waals forces and electrostatic forces can be ignored. The time rate of change of the film profile is predicted, given only the drop radius and the required physical properties. Comparisons are offered with the limited experimental data available.
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    AIChE Journal 28 (1982), S. 830-833 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 28 (1982), S. 840-841 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 28 (1982), S. 325-333 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Chemical solution theory has been shown to be particularly well-suited for certain classes of liquid metal mixtures. A generalized formulation of this approach is presented and it eliminates the need for mechanistic information. The results are in good agreement with many data, and could lead to a variety of industrial applications of liquid metal solvents.
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    AIChE Journal 28 (1982), S. 341-343 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 28 (1982), S. 349-349 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 28 (1982), S. 869-869 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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