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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (3)
  • Copernicus  (2)
  • Copernicus GmbH  (1)
  • 2010-2014  (3)
  • 1985-1989
  • 1980-1984
  • 1955-1959
  • 1925-1929
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  • 2010-2014  (3)
  • 1985-1989
  • 1980-1984
  • 1955-1959
  • 1925-1929
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  • 1
    Publication Date: 2017-04-04
    Description: Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after carbon dioxide. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former (IPCC, 2007). It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere (Etiope, 2004). Active or recent volcanic/geothermal areas represent one of these sources of geological methane. But due to the fact that methane flux measurements are laboratory intensive, very few data have been collected until now and the contribution of this source has been generally indirectly estimated (Etiope et al., 2007). The Greek territory is geodynamically very active and has many volcanic and geothermal areas. Here we report on methane flux measurements made at two volcanic/geothermal systems along the South Aegean volcanic arc: Sousaki and Nisyros. The former is an extinct volcanic area of Plio-Pleistocene age hosting nowadays a low enthalpy geothermal field. The latter is a currently quiescent active volcanic system with strong fumarolic activity due to the presence of a high enthalpy geothermal system. Both systems have gas manifestations that emit significant amounts of hydrothermal methane and display important diffuse carbon dioxide emissions from the soils. New data on methane isotopic composition and higher hydrocarbon contents point to an abiogenic origin of the hydrothermal methane in the studied systems. Measured methane flux values range from –48 to 29,000 (38 sites) and from –20 to 1100 mg/mˆ2/d (35 sites) at Sousaki and Nisyros respectively. At Sousaki measurement sites covered almost all the degassing area and the diffuse methane output can be estimated in about 20 t/a from a surface of about 10,000 mˆ2. At Nisyros measurements covered the Stephanos and Kaminakia areas, which represent only a part of the entire degassing area. The two areas show very different methane degassing pattern with latter showing much higher flux values. Methane output can be estimated in about 0.25 t/a from an area of about 30,000 mˆ2 at Stephanos and about 1 t/a from an area of about 20,000 mˆ2 at Kaminakia. The total output from the entire geothermal system of Nisyros probably should not exceed 2 t/a.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: methane output ; diffuse degassing ; volcanic/hydrothermal systems ; Greece ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 2
    Publication Date: 2017-04-04
    Description: A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis) was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500- 3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the most impacted by volcanic emissions. Leaves collected along two radial transects from the active vents on the eastern flank, highlight that the levels of metals decrease one or two orders of magnitude with increasing distance from the source. This variability is higher for volatile elements (As, Bi, Cd, Cs, Pb, Sb, Tl) than for more refractory elements (Al, Ba, Sc, Si, Sr, Th, U). The two different species of plants do not show significant differences in the bioaccumulation of most of the analyzed elements, except for lanthanides, which are systematically enriched in Rumex leaves. The high concentrations of many toxic elements in the leaves allow us to consider these plants as highly tolerant species to the volcanic emissions, and suitable for biomonitoring researches in the Mt. Etna area.
    Description: Published
    Description: Vienna, Austria
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Mt. Etna ; biomonitoring ; Trace elements ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 3
    Publication Date: 2017-04-04
    Description: In this paper, spectral and detrended fluctuation analyses, as well as time reversibility and magnitude-sign decomposition, have been applied to the 10-year time-series data resulting from geochemical monitoring of gas emissions on the flanks of Mt. Etna, and gases from a CO2 exploitation well located tens of kilometers from the volcano. The analysis of the time series which showed main effects of fractionation between gases due to selective dissolution in aquifers (e.g., the CO2 concentration series), revealed the occurrence of random fluctuations in time, typical of systems where several processes combine linearly. In contrast, the series of He isotopic composition exhibited power-law behavior of the second-order fluctuation statistics, with values of the scaling exponent close to 0.9. When related to the spectral exponent, this value indicates that the isotopic series closely resemble fractal flicker-noise signals having persistent long-range correlations. The isotopic signals also displayed asymmetry under time reversal and long-range correlation of the associated magnitude series, therefore it was statistically proved the presence of nonlinearity. Both long-range correlation and nonlinearity in time series have been generally considered as distinctive features of dynamic systems where numerous processes interact by feedback mechanisms, in accordance with the paradigm of self-organized criticality (SOC). Thus, it is here proposed that the system that generated the isotope series worked under conditions of SOC. Since the fluctuations of the isotope series have been related to magma degassing, the previous results place constraints on the dynamics of such process, and suggest that nonequilibrium conditions must be dominant. It remains unclear whether the signature of SOC is directly due to volatile degassing from magma, or if it derives from the interaction between melt and the stress field, which certainly influences magma decompression. The strength of scaling appears to increase after 2002 ( values from 0.8 up to 1.2), focusing on transition of the Etnean system from typical SOC toward conditions of lower criticality. By comparing this transition with those of geophysical observables, it can be suggested that the drop in the rate of magma supply, subsequent to the paroxysms of 2001 and 2002–2003, was the main cause of the scaling change.
    Description: Published
    Description: 733-751
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: gas geochemistry ; self-organized criticality ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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