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  • superconductivity  (17)
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  • Electrical Engineering, Measurement and Control Technology  (17)
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  • Articles  (17)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 6 (1993), S. 107-109 
    ISSN: 1572-9605
    Keywords: BiSrCaCuO ; superconductivity ; phase structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract With XRD,R-T curves, and a.cϰ measurements, the doping and codoping effects of Sb and V to a Cu-deficient Pb-doped Bi system have been studied. A sample singly doped with V possesses aT c about 2 K lower than that of a sample singly doped with Sb. This is attributed to the different sites of their substitution. It was observed that for promoting 2223 phase formation, Sb and V works cooperatively, and the codoping of Sb may enhance the 2223 phase formed. With a low doping level of Sb, the optimum doping amount of V is 0.3, i.e., with a nominal composition of Bi1.5Pb0.3Sb0.06Sr2Ca2Cu2.4V0.3O y . A sample in which the 2223 phase is the dominant phase and which has a zero resistance transition temperature of 105 K has been obtained.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 7 (1994), S. 427-428 
    ISSN: 1572-9605
    Keywords: Thermal expansion ; dielectric ; metal ; superconductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract A negative thermal expansion was measured for Ba1−x K x BiO3. This anomaly decreases with increasingx, still exists atx=0.4, and disappears atx=0.5.
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  • 3
    ISSN: 1572-9605
    Keywords: Bismuth ; lead substitution ; superconductivity ; Raman spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Raman spectroscopy and X-ray diffraction were used to follow structure and phase formation at various stages in order to study the effect of Pb substitution in (Bi1−x Pb x Sr3Ca3Cu4O y samples. We found that major reactions involving Bi2O3 occurred at around 700°C and that reactions with Ca, Cu, and Pb started at a lower temperature. The amount of Ca2PbO4 formed increases as a function of lead concentration and annealing temperature (up to 800°C), but excess lead substitution (50%) destroys the superconductivity. The high-temperature superconducting phase (2223) is only observed in the 15% and 20% leaded samples. These two samples exhibit a higher amount of Ca2PbO4 during intermediate processing stages, which suggests that the presence of the Ca2PbO4 is important for the formation of the high-T c phase. It was found that theT c increases with lead concentration (up to 20% Pb).
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 5 (1992), S. 1-3 
    ISSN: 1572-9605
    Keywords: Bi-Sr-Ca-Cu-O ; superconductivity ; phase structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The effect of oxygen content on superconductivity of the 2212 and 2223 phase has been studied. By comparing the excess oxygen, the modulation vector, the XRD patterns, and the electric resistivity of 2212 and 2223 phase samples obtained with different post-annealing conditions, i.e., annealing at 600°C or quenching from 860°C, it was found that the super-conductivity is markedly influenced by both the defect distribution in non-Bi layers and the interstitial oxygens incorporated in the Bi-O layers. A tentative explanation for this is given.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 5 (1992), S. 25-27 
    ISSN: 1572-9605
    Keywords: YBa2Cu3O7(Ag) ; superconductivity ; ac losses
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract 60-Hz ac lossesP were measured at temperature 77 K for sintered powder (YBa2Cu3O7)1-x Ag x samples as a function of applied magnetic fieldh. Rod-shaped samples were cut from pellets forx= 0 and 0.05. The losses were measured in a uniform ac magnetic fieldh applied parallel to the sample surface. Measurements were made in fields up toh= 1000 A/cm rms at temperature 4.2 K and up toh=600 A/cm rms at temperature 77 K. The results may indicate an increase of the intergranular current density and are discussed in relation to the grain size.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 5 (1992), S. 301-311 
    ISSN: 1572-9605
    Keywords: Ag substitution ; BPSCCO ; bismuth ; Raman spectroscopy ; superconductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The effects of Ag substitution on the formation of the superconducting phases in the BPSCCO system have been investigated by Raman spectroscopy and XRD. The silver was found either to accelerate the formation of the 2212 phase or to reduce the formation temperature of the 2212 phase. Moreover, addition of even a small amount of silver (Bi∶Pb∶Ag=8∶2∶1) poisons or inhibits the formation of the 2223 phase. However, there is no apparent effect on theT c of both the 2212 and 2223 phases. In addition, the presence of silver does not alter the mechanism for the formation of the PBSCCO superconducting phases.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 7 (1994), S. 243-249 
    ISSN: 1572-9605
    Keywords: Electronic specific heat ; superconductivity ; pseudogap ; Fermi statistics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We have determined for the first time the electronic specific heatγ(x, T) of YBa2Cu3O6+x for 0.16≤x≤0.97 from 1.8 to 300 K. Weakly superconducting behavior betweenx=0.4 and 0.8 progresses rapidly to strong coupling BCS-like superconducting and metallic normal state behavior forx〉 0.9. However, the continuous development of the entropyS(x, T) withx andT across the entire series suggests a progressive modification of the low-energy spin spectrum with hole doping rather than a simple band model. Fermi statistics andk-space pairing for allx is indicated by the magnitude andT-dependence ofS(x, T). Pseudogap behavior inS(x, T) is observed over a temperature region aboveT c , which increases rapidly with oxygen depletion to around 200 K forx∼0.7. This loss of entropy reflects normal-state correlations apparently unrelated to the superconducting pairing.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 4 (1991), S. 357-360 
    ISSN: 1572-9605
    Keywords: Excitonic mechanism ; superconductivity ; John Bardeen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 5 (1992), S. 83-94 
    ISSN: 1572-9605
    Keywords: Theory ; superconductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Based on a generalized BCS Hamiltonian in which the interaction strengths (V 11,V 22,V 12) among and between “electron” (1) and “hole” (2) Cooper pairs are differentiated, the thermodynamic properties of a type-I superconductor below the critical temperatureT c are investigated. An expression for the ground-state energy,W-W 0, relative to the unperturbed Bloch system is obtained:W-W 0=−1/4[N 1(0)Δ 1 2 +N 2(0)Δ 2 2 ], whereN j(0) represent the electron and hole densities of states at the Fermi energy εF, and Δj are the solutions of the simultaneous equations, $$\Delta _j = \tfrac{1}{2}V_{j1} N_1 (0)\Delta _1 {\text{ sinh}}^{ - {\text{1}}} (\hbar \omega _D /\Delta _1 ) + \tfrac{1}{2}V_{j2} N_2 (0)\Delta 2_2 {\text{ sinh}}^{ - {\text{1}}} (\hbar \omega _D /\Delta _2 )$$ with ωD denoting the Debye frequency. The usual BCS formulas are obtained in the limits: (all)V jl=V0,N 1(0) =N 2(0). Any excitations generated through the BCS interaction Hamiltonian containingV jl must involve Cooper pairs of antiparallel spins and nearly opposite momenta. The nonzero momentum orexcited Cooper pairs belowT c are shown to have an excitation energy band minimum lower than the quasi-electrons, which were regarded as the elementary excitations in the original BCS theory. The energy gapε g(T) defined relative to excited and zero-momentum Cooper pairs (whenV jl〉0) decreases fromε g(0) to 0 as the temperatureT is raised from 0 toT c. If “electrons” only are available as in a monovalent metal like sodium (V 12=0), the energy constant Δ1 is finite but the energy gap vanishes identically for allT. In agreement with the BCS theory, the present theory predicts that a pure nonmagnetic metal in any dimensions should have a Cooper-pair ground state whose energy is lower than that of the Bloch ground state. Additionally it predicts that a monovalent metal should remain normal down to 0K, and that there should be no strictly one-dimensional superconductor.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 5 (1992), S. 203-217 
    ISSN: 1572-9605
    Keywords: Cuprates ; superconductivity ; review
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Different ways to optimizeT c 's and the magnetic properties of high-T c superconductive cuprates are described and discussed. Oxygen intercalation-desintercalation phenomena and cationic substitutions (M3+ for M2+ or vice versa) lead to a variation of the hole carrier density and can have a drastic influence onT c 's, as shown for bismuth, thallium, and lead-based cuprates, as well as for La2CuO4 and “123”-type superconductors. In the former, the role of hole reservoirs for the rock salt type layers is outlined. The modification of the hybridization of orbitals can also explain the variations ofT c 's observed in some systems like Y1−x Ca x Ba2Cu3−x :Fe x O7 in which the oxidation state of copper remains constant. A critical current density enhancement can be realized by irradiating high-T c materials by high-energy heavy ions because of the peculiar columnar structure of the heavy ion-induced tracks. The effects of such columnar defects, 70 Å in diameter, on flux pinning, magnetic relaxation, and location of the irreversibility line of bismuth-based 2212 crystals irradiated by 6-GeV Pb ions are reported. We observe a strong shift of the irreversibility line toward high fields and temperatures, indicating that pinning effects must be taken into account in the vortex lattice motion. Such induced changes are accompanied by a strong enhancement of the critical current density and a significant enlargement of the irreversibility region in theH,T plane.
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  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 6 (1993), S. 185-189 
    ISSN: 1572-9605
    Keywords: Thallium cuprates ; superconductivity ; magnetic hysteresis ; irreversibility ; flux pinning
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract dc magnetic hysteresis as well as flux penetration and flux expulsion were investigated in Tl2−y Ba2CaCu2O8−x polycrystals and monocrystals. All measurements were performed at 35 K and in the 0–5 T field range. Hysteresis measurements revealed an irreversibility field of about 2 T. Existing models predict identical field-cooled (fc) and zero-field-cooled (zfc) magnetizations and vanishing time dependence above this field. Although the identical fc and zfc magnetizations are in fact observed, the time dependence vanishes only for flux penetration after zero-field cooling; a remanence is preserved after field cooling and decays with a finite relaxation rate. Activation energies calculated on the basis of the thermal activation model display a pronounced field dependence, and arelower for flux penetration than for flux expulsion in high fields (H≥3 T) for all orientations. This behavior of extreme layered superconductors contradicts classical theoretical models and questions the original definition of the irreversibility line as well. All of our results are consistent with the recent theory of lock-in transition, and can be well interpreted by using those principles.
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  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 7 (1994), S. 547-553 
    ISSN: 1572-9605
    Keywords: van Hove singularities ; superconductivity ; cuprates ; doped fullerenes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract We review the main results of the van Hove scenario applied to superconducting cuprates. It is based on the assumption that in these materials, the Fermi level lies near a singularity in the density of states (DOS). This hypothesis has recently been confirmed experimentally. We show that this model explains many properties of the high-T c superconductors. We show that an anaogous model with a peak in the DOS may also be applied to the superconducting doped fullerenes. A general feature of the model is a very short coherence length.
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 7 (1994), S. 589-591 
    ISSN: 1572-9605
    Keywords: Two-band ; pair transfer ; superconductivity ; dimer ; Hubbard model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract In the two-chain Hubbard model the on-site Coulomb repulsion generates a remarkably large pair-transfer coupling constant between bonding and antibonding orbitals of a dimer made of the two sites lying on the opposite chains and linked by a transfer energy. It leads to a pair-transfer interaction between two bands composed of these orbitals, promoting superconductivity (SC). Since it is found to be as large as intraband Coulomb coupling constants, our previous work suggests that SC can occur in this model. In fact we have obtained a clear indication of SC in restricted-size systems carrying out the exact-diagonalization with 6 electrons and a variational diagonalization with up to 14. The SC occurs in suitable band situations for a wide range of on-site Coulomb energies. We also obtained such an SC indication in a two-dimensional Hubbard model. We mention some candidate materials substantiating the present mechanism and suggest it to be quite general.
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 7 (1994), S. 921-924 
    ISSN: 1572-9605
    Keywords: Iodine ; superconductivity ; high pressure ; low temperature ; monatomic phase
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The superconductivity of metallic iodine is observed at temperatures below 1.2 K under pressures above 28 GPa by magnetization and electrical resistance measurements. The pressure dependence of the superconducting transition temperature is studied up to 74 GPa. This is the first observation of the superconductivity of the molecular-dissociated monatomic metal.
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  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 7 (1994), S. 175-180 
    ISSN: 1572-9605
    Keywords: Proximity effect ; superconductivity ; pair echoes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Recent experiments on N′-N-S junctions with high-temperature cuprate superconductors have shown that superconductivity can be induced in the adjacent, normal metal at distances many times greater than the few hundred Ångstroms range of the conventional proximity effect. We show that this arises in the particular geometry used in these experiments through the constructive interference of the tails of the de Gennes-Saint-James bound and quasi-bound states of the normal metal N that penetrate into the third metal, N′. This constructive interference results in the re-appearance of a pair amplitude in this metal which is analogous to the “spin echo” of NMR and which we name a “pair echo.”
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  • 16
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 7 (1994), S. 643-645 
    ISSN: 1572-9605
    Keywords: Pure and doped C60 ; inelastic neutron scattering ; superconductivity ; phonon density of states
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Via inelastic neutron scattering (INS) generalized phonon densities of states are obtained for C60 and superconducting A3C60 (A=K, Rb). Changes in the intramolecular modes agree with and augment recent Raman (RA), infrared (IR), and INS measurements, i.e., in the vicinity of the high-frequency modes of C60 [H g (8),A g (2),H g (7)] we find a pronounced shift of about 10 meV toward smaller energy transfers upon intercalating with potassium. Separated from these vibrations by a gap are the intermolecular spectra which for the doped samples display well-defined optic modes at 11 and 14 meV due to the vibrations of Rb and K ions. Indications of a weak anomalous temperature dependence of low-energy phonons (ħω 〈3 meV) nearT c are observed for K3C60.
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  • 17
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 7 (1994), S. 639-642 
    ISSN: 1572-9605
    Keywords: Alkali-metal-doped fullerenes ; normal-state transport ; superconductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The normal-state transport properties of alkali-metal-doped fullerene crystals are explored. The Hall effect has been measured in KxC60 from room temperature toT c . The electrical resistivityρ for K3C60 and Rb3C60 has been measured over a wide temperature range (20–650 K), and notable differences are observed for the materials at both low and high temperatures. The electrical resistivity of Rb3C60 has been measured in hydrostatic pressures up to 9 kbar. The resistivity is highly pressure sensitive. The transport results give an insight into the normal-state conduction mechanism and thus have consequences for the superconductivity mechanism.
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