ALBERT

Description: Few studies have focused on the relationship between the various causes of groundwater level fluctuations and the seawater intrusion process, due to the complexity of this relationship, being the aim of this paper. Piezometric fluctuations in coastal aquifers are determined by a number of processes and their characterization depends on the complexity of the aquifer stratigraphy, as well as many other hydrodynamic factors. The precipitation regime, tides, wave setup and storm surges, as well as atmospheric pressure are the most relevant of these processes. By means of a series of observations made at an experimental site in south-eastern Spain, this study demonstrates the complexity of water table fluctuations in coastal zones. The study employed two piezometers situated very close to the shoreline, excavated in detritic deposits with highly variable hydraulic conductivity (semi-confined aquifer). Continuous measurements were taken of hydraulic head, tide height, electrical conductivity and water temperature. The study concludes that precipitation has the greatest effect on piezometric level, followed by atmospheric pressure and wave action, while the semi-diurnal and fortnightly tidal cycles caused variations of smaller amplitude in the piezometric logs. All these oscillations affect the position of the fresh water-seawater interface. The attenuation of the tidal amplitude observed at the two monitoring points was lower than the value calculated using analytical solutions, and this is due to the semi-confined nature of the aquifer. The calculated tidal efficiency is around 0.4-0.5, giving a t lag of about 3 h, with a 10–15 min delay between monitoring boreholes, P-II and PI. We also identified that the response of water conductivity and temperature to tidal cycles is not synchronized with the variations in the piezometric level influenced by tidal fluctuations.

Description: This final reply responds to Honohan’s invitation to articulate the Arendtian tone of the key-note paper. It spells out the philosophical intuition that the political life of citizens, at least potentially, is capable of making visible what makes human life worthwhile and fully meaningful, and the philosophical curiosity to see whether traces of this deep political awareness can be retrieved in dialogues with volunteers. In response to Dekker’s critical doubts, this final reply clarifies the central stakes of Claes’s paper. The core argument was not to show that the biographical model of meaningfulness is the prevailing approach of meaning in/of volunteering, but to assess the potentials and limits of the model’s interpretive power. Moreover, the paper argues for an alternative, existential model of meaningfulness. This approach refers to deep experiences of meaning that emerge from the practice of volunteering and that shift into powerful political experiences of hope, and a lived sense of equality.

Description: The authors propose a measurement method that divides the depth of the soil sample in discrete regions to investigate soil water propagation dynamics using soil impedance measurements. Experiments were conducted on a cylindrical phantom using a clay loam soil sample (60 % clay, 21 % loam and 19 % sand). The resulting impedance changes represent the wetting front (WF) propagation process at the different measurement depths. The measured impedance data is used to A) show graphically the wetting front propagation process, obtain B) a 1st order model, C) an ARX1821 model of the impedance change as a function of the irrigation volume applied and D) estimating changes in water content using a neural network. The results indicate that the proposed measurement technique can be used to detect and predict the movement of liquid trough the soil sample. The neural network permits inferring the water content from impedance and soil-water mixture temperature values. Changes in soil impedance in each segment, due to the water propagating downwards through the soil sample, can be used to study the dynamics of the wetting front, irrigation scheduling and model improvement from physical data.

Description: The paper presents an approach to the modelling of watercourses or their sections according to and in order to determine their suitability for hydropower water use on a large scale. The method is based on a multi-criteria analysis approach which in addition to existing guidelines defines and describes in detail the main stages for model establishment and hydropower suitability analysis. Since hydropower planning stands in direct conflict with other ecological water-related objectives, evaluation of suitability is based on two main criteria, which are supported with the belonging criteria. The first main criterion is based on evaluation of watercourses by their attractiveness for hydropower water use; the second one on evaluation of watercourses according to their ecological state or value. To support proper determination of unknown model parameters (e.g. weights of selected criteria) the paper also presents an upgrade of general multi-criteria analysis process with a calibration stage, which can efficiently upgrade in cases when calibration data is available. The proposed method was tested and discussed on a real case study with three dislocated Slovenian Alpine watercourses, where weights of preselected criteria and some thresholds of performance functions were selected as model variables and calibrated.

Description: Various scientific and technological based solutions such as virtual water trading, desalination, groundwater extraction and wastewater reuse have been proposed and implemented in many parts of Asia and Africa to relieve water scarcity. This paper applies SWOT (strengths, weaknesses, opportunities and threats) analysis to examine the suitability of these alternative water solutions to alleviate water scarcity. SWOT analysis proves to be a useful decision making tool as it provides a qualitative approach to simplify multilayer and interdisciplinary problems. The main input for the SWOT analysis consists of knowledge gathered from seven experts in the field of water and environmental sciences. The results show that compared to other solutions, wastewater reuse offers the most desirable qualities as a viable water solution for sustainable water management in Asia and Africa.

Description: Groundwater withdrawals can reduce aquifer-to-stream flow and induce stream-to-aquifer flow. These effects involve potential threats over surface water and groundwater quantity and quality. As a result, the description of stream-aquifer flow in space and time is of high interest for water managers. In this study, the EauDyssée platform, an integrated groundwater/surface water model is extended to provide the distribution of stream-aquifer flow at the regional scale. The methodology is implemented over long periods (17 years) in the Seine river basin (76 375 km 2 , France) with a 6 481 km long simulated river network. The study scale is compatible with the scale of interest of water authorities, which is often larger than study scales of research projects. Net and gross stream-aquifer exchange flow are computed at the daily time step over the whole river network at a resolution of 1 km. Simulation results highlight that a major proportion of the main stream network (82 %) is supplied by groundwater. Groundwater withdrawals induce a reduction of net aquifer-to-stream flow (−19 %) at the basin scale and flow reversals in the vicinity of pumping locations. Such an integrated model provided at the appropriate regional scale is an essential tool provided to water managers for the implementation of the EU Water Framework Directive.

Description: This paper presents the comparison of two hybrid methodologies for the two-objective (cost and resilience) design of water distribution systems. The first method is a low-level hybrid algorithm (LLHA), in which a main controller (the non-dominated sorting genetic algorithm II, NSGA-II) coordinates various subordinate algorithms. The second method is a high-level hybrid algorithm (HLHA), in which various sub-algorithms collaborate in parallel. Applications to four case studies of increasing complexity enable the performances of the hybrid algorithms to be compared with each other and with the performance of the NSGA-II. In the case study featuring low/intermediate complexity, the hybrid algorithms (especially the HLHA) successfully capture a more diversified Pareto front, although the NSGA-II shows the best convergence. When network complexity increases, instead, the hybrid algorithms (especially the LLHA) turn out to be superior in terms of both convergence and diversity. With respect to both the HLHA and the NSGA-II, the LLHA is capable of detecting the final front in a single run with a lower computation burden. In contrast, the HLHA and the NSGA-II, which are more affected by the initial random seed, require numerous runs with an attempt to reach the definitive Pareto front. On the other hand, a drawback of the LLHA lies in its reduced ability to deal with general problem formulations, i.e., those not relating to water distribution optimal design.

Description: Intensification of heavy precipitation as discussed in climate change studies has become a public concern, but it has not yet been examined well with observed data, particularly with data at short temporal scale like hourly and sub-hourly data. The original data set was retrieved by using an automated recovery approach. We chose four stations, namely, Vercelli (since 1927), Bra (since 1933), Lombriasco (since 1939) and Pallanza (since 1950) which are located in the northwest of Italy. We assessed trends for durations from 5 min to 12 h in seasonal, annual maxima, and number and magnitude of exceedances of the 95th percentile. Split sample tests have been undertaken to assess differences in quantile estimates derived using a Generalised Pareto distribution fitted to Peaks-Over-Threshold series. The statistical analyses performed include parametric and non-parametric tests. Mostly, we cannot reject the trend stationarity hypothesis. There is no uniform trend on extreme events in the whole area. However, some trends are evident and significant for specific stations and specific indices. Specifically, it is obvious that extreme rainfall events have risen in the last 20 years only for short durations.

Description: A novel quantitative risk assessment for residential properties at risk of pluvial flooding in Eindhoven, The Netherlands, is presented. A hydraulic model belonging to Eindhoven was forced with low return period rainfall events (2, 5 and 10-year design rainfalls). Three scenarios were analysed for each event: a baseline and two risk-reduction scenarios. GIS analysis identified areas where risk-reduction measures had the greatest impact. Financial loss calculations were carried out using fixed-threshold and probabilistic approaches. Under fixed-threshold assessment, per-event Expected Annual Damage (EAD) reached €38.2 m, with reductions of up to €454,000 resulting from risk-reduction measures. Present costs of flooding reach €1.43bn when calculated over a 50-year period. All net-present value figures for the risk-reduction measures are negative. Probabilistic assessment yielded EAD values up to more than double those of the fixed-threshold analysis which suggested positive net-present value. To the best of our knowledge, the probabilistic method based on the distribution of doorstep heights has never before been introduced for pluvial flood risk assessment. Although this work suggests poor net-present value of risk-reduction measures, indirect impacts of flooding, damage to infrastructure and the potential impacts of climate change were omitted. This work represents a useful first step in helping Eindhoven prepare for future pluvial flooding. The analysis is based on software and tools already available at the municipality, eliminating the need for software upgrading or training. The approach is generally applicable to similar cities.

Description: The use of inverse modeling techniques has greatly increased during the past several years because the advances in numerical modeling and increased computing power. Most of these methods require an a priori definition of the stochastic structure of conductivity ( K ) fields that is inferred only from K measurements. Therefore, the additional conditioning data, that implicitly integrate information not captured by K data, might lead to changes in the a priori model. Different inverse methods allow different degrees of structure adaptation to the whole set of data during the conditioning procedure. This paper illustrates the application of a powerful stochastic inverse method, the Gradual Conditioning (GC) method, to two different sets of data, both non-multiGaussian. One is based on a 2D synthetic aquifer and another on a real-complex case study, the Macrodispersion Experiment (MADE-2), site on Columbus Air Force Base in Mississippi (USA). We have analyzed how additional data change the a priori model on account of the perturbations performed when constraining stochastic simulations to data. Results show how the GC method tends to honour the a priori model in the synthetic case, showing fluctuations around it for the different simulated fields. However, in the 3D real case study, it is shown how the a priori structure is slightly modified not obeying just to fluctuations but possibly to the effect of the additional information on K, implicit in piezometric and concentration data. We conclude that implementing inversion methods able to yield a posteriori structure that incorporate more data might be of great importance in real cases in order to reduce uncertainty and to deal with risk assessment projects.

Description: In this comment-response Mikael Lindfelt makes some suggestions to how one could develop the argument for wit(h)nessing as experiencing meaningfulness in life as put forward by Nicole Note and Emilie Van Deale. While being positive to the main phenomenological approach, and especially the dialectical relational aspect of the phenomenological argument, Lindfelt uses Alain Badiou’s talk of Event in trying both to develop the phenomenological argument and to point out some idealistic tendencies in the line of the argument. Lindfelt suggests that the aspect of uniqueness in the relational experience of the other should be taken to more radically than suggested by Note and Van Deale. By pointing out the dialectical fragility of the Event of wit(h)nessing Lindfelt is arguing for that the concept of respect could be more utilized in arguing for the experience of meaning seen as a gift.

Description: The goal of our study is to determine accurate time series of geophysical Earth rotation excitations to learn more about global dynamic processes in the Earth system. For this purpose, we developed an adjustment model which allows to combine precise observations from space geodetic observation systems, such as Satellite Laser Ranging (SLR), Global Navigation Satellite Systems, Very Long Baseline Interferometry, Doppler Orbit determination and Radiopositioning Integrated on Satellite, satellite altimetry and satellite gravimetry in order to separate geophysical excitation mechanisms of Earth rotation. Three polar motion time series are applied to derive the polar motion excitation functions (integral effect). Furthermore we use five time variable gravity field solutions from Gravity Recovery and Climate Experiment to determine not only the integral mass effect but also the oceanic and hydrological mass effects by applying suitable filter techniques and a land–ocean mask. For comparison the integral mass effect is also derived from degree 2 potential coefficients that are estimated from SLR observations. The oceanic mass effect is also determined from sea level anomalies observed by satellite altimetry by reducing the steric sea level anomalies derived from temperature and salinity fields of the oceans. Due to the combination of all geodetic estimated excitations the weaknesses of the individual processing strategies can be reduced and the technique-specific strengths can be accounted for. The formal errors of the adjusted geodetic solutions are smaller than the RMS differences of the geophysical model solutions. The improved excitation time series can be used to improve the geophysical modeling.

Description: This paper introduces a new approach for modeling solar radiation pressure (SRP) effects on Global Navigation Satellite Systems (GNSSs). It focuses on the Galileo In-Orbit Validation (IOV) satellites, for which obvious SRP modeling deficits can be identified in presently available precise orbit products. To overcome these problems, the estimation of empirical accelerations in the Sun direction (D), solar panel axis (Y) and the orthogonal (B) axis is complemented by an a priori model accounting for the contribution of the rectangular spacecraft body. Other than the GPS satellites, which comprise an almost cubic body, the Galileo IOV satellites exhibit a notably rectangular shape with a ratio of about 2:1 for the main body axes. Use of the a priori box model allows to properly model the varying cross section exposed to the Sun during yaw-steering attitude mode and helps to remove systematic once-per-revolution orbit errors that have so far affected the Galileo orbit determination. Parameters of a simple a priori cuboid model suitable for the IOV satellites are established from the analysis of a long-term set of GNSS observations collected with the global network of the Multi-GNSS Experiment of the International GNSS Service. The model is finally demonstrated to reduce the peak magnitude of radial orbit errors from presently 20 cm down to 5 cm outside eclipse phases.

Description: Analyzing the effects of urban development on dynamic and spatial patterns of land use is vital to establish more efficient land management policies. However, in Malaysia, such effects are usually explained without quantitative metrics. This research quantified the future impact of urban expansion on the dynamic of land use by developing the area-independent dynamic metric. The metric was calculated based on summarizing the cross tabulation matrices of change in an urbanizing area at west coast of Peninsular Malaysia. Another two land use measures involving vulnerability to gain and vulnerability to loss were used to evaluate tendency of land classes to transition. The effects of urban development on spatial patterns of land use were quantified using two landscape metrics involving the Edge Density (ED) and Area-Weighted Mean Patch Fractal Dimension (AWMPFD). Analyses were carried out on a set of spatial land use data including observed 1997, 2002, and 2008, as well as a simulated near future land change for the year 2020 under a spatio-temporal land use model. Results showed that urban development practices would influence the dynamic of land transition in the near future. Urban growth would experience a fast-growing dynamic and high vulnerability to gain than loss while the dynamic and vulnerability of forest/wetland covers would decrease in terms of loss. Moreover, agriculture practices tend to be hindered by further urban development in the coming years. Another important finding was that urban development process would influence the spatial patterns of land use in the near future.

Description: Motion control of a single molecule through a solid-state nanopore offers a new perspective on detecting and analyzing single biomolecules. Repeat recapture of a single DNA molecule reveals the dynamics in DNA translocation through a nanopore and may significantly increase the signal-to-noise ratio for DNA base distinguishing. However, the transient current at the moment of voltage reversal prevents the observation of instantly recaptured molecules and invalidates the continuous DNA ping-pong control. We performed and analyzed the DNA translocation and recapture experiment in a silicon nitride solid-state nanopore. Numerical calculation of molecular motion clearly shows the recapture dynamics with different delay times. The prohibited time when the data acquisition system is saturated by the transient current is derived by equivalent circuit analysis and finite element simulation. The COMSOL simulation reveals that the membrane capacitance plays an important role in determining the electric field distribution during the charging process. As a result of the transient charging process, a non-constant driving force pulls the DNA back to nanopores faster than theoretically predicted. The observed long time constant in the transient current trace is explained by the dielectric absorption of the membrane capacitor.

Description: Plants have considerable hydrological and mechanical impacts on soil. However, there are lack of documentation and limited understanding on the hydrological and mechanical impacts of tropical legume trees. Therefore, this study was aimed to investigate the hydrological and mechanical properties of three selected legume plants, Leucaena leucocephala , Adenanthera pavonina and Peltophorum pterocarpum . Regarding hydrological aspect, the study results indicated that soil on which the L. leucocephala was grown had the highest transpiration rate, water absorption rate (WAR) and soil matric suction (SMS). In terms of mechanical characteristics, L. leucocephala exhibited the highest root tensile strength and cellulosic components in the root. Interestingly, L. leucocephala also showed a higher root biomass, root length and fine roots than A . pavonina and P. pterocarpum. The leaf area index (LAI) strongly correlated with SMS ( R 2  = 0.74), indicating that high LAI improved SMS. The high root tensile strength and fine roots of L. leucocephala make this species special for growing as a soil reinforcing plant. Overall results suggested that L. leucocephala exhibited outstanding hydrological and mechanical properties and can be a potential plant for the soil reinforcement program.

Description: We presented an integrated software system for analyzing nanopore data. This self-developed software provided rapid processes for accurate location, classification, and evaluation of every individual blockade. Using the proposed software, statistical analysis could be achieved easily and conveniently. The results of β -Amyloid 42 demonstrated that our data process could rapidly extract duration time and current amplitudes. In addition, our data process could accurately carry out statistical fittings.

Description: We study the influences of new-firm start-ups on growth at the regional and macroeconomic level in France using a quarterly database over the 1993–2011 period. We find that fluctuations in GDP are an early indicator of new-firm start-ups. Nevertheless, the most important relationships are found between the unemployment rate and new-firm start-ups. Entrepreneurship is mainly driven by an unemployment “push” effect that have consequences upon the potential of growth of new-firm start-ups in most of the French regions. The Île-de France region is an exception since the “Schumpeter” effect prevails in the long term.

Description: Expanding entrepreneurial enterprises move from high-cost (congestion, wages and rent) locations where they innovated to low-cost (smaller, less agglomerated) places suitable for standardised production. Net inter-regional relocations of British SMEs are predicted in part by this development pattern. SMEs that relocate are more productive, relatively larger and younger, as well as more probably initially located in London and the South East (core locations). These fast-growing businesses become even more productive and employ even more workers after moving than regionally immobile SMEs. In this respect, the UK regional core supports the periphery through a market process. Relocation is also a strategy for contracting enterprises, but not necessarily a helpful for smaller companies.

Description: A novel phenol-linked bis(imidazolium) salt, H 3 LCl 2 (L =  O -4-C(CH 3 ) 3 -C 6 H 2 -2,6-di[CH 2 {C(NCHCHNAr)}] 2 , Ar = 2,6-diisopropylphenyl, 1 ), was designed and used to prepare an ionic iron(III) complex [H 2 L][FeCl 4 ] ( 2 ). Complex 2 was a highly efficient catalyst for aryl Grignard cross-coupling of alkyl chlorides bearing β-hydrogens. Furthermore, complex 2 was reusable and could be reused in at least eight times without significant loss in catalytic activity.

Description: Vertically aligned TiO 2 nanotube arrays (~8 μm long, ~110 nm wide) have been fabricated through anodic oxidation of Ti-metal sheet in fluoride-containing electrolyte. By changing the volume ratio of ethylene glycol and diethylene glycol in the electrolyte, TiO 2 nanotube arrays with different tube-to-tube lateral spacing, i.e., closely packed, just separated, and fully separated, have been synthesized and applied as photoanodes for dye-sensitized solar cells (DSSCs). Photovoltaic efficiency of 2.99 %, 3.34 %, and 3.44 % has been obtained for DSSCs based on the closely packed, just separated, and fully separated TiO 2 nanotube arrays, respectively, illustrating the effect of tube-to-tube lateral spacing of TiO 2 nanotube arrays on the performances of DSSCs. It is suggested that fully separated TiO 2 nanotube arrays are beneficial to the conversion efficiency of DSSCs due to higher dye loading and faster electron transfer.

Description: Vegetation phenology is an important indicator of climate change impacts on the seasonal dynamics of the biosphere. However, little is known about the influence of elevation on spring phenological sensitivity to temperature in an alpine ecosystem. Based on remotely sensed land surface phenology and temperature data from 2001 to 2010, this study investigated the rate of spring phenological change of the Tibetan Plateau (TP) grasslands in response to interannual temperature variations at different elevations. Results suggest that spring phenology in the TP grasslands exhibits a stronger response to changes in temperature at higher elevations than at lower ones. In particular, spring phenology advanced by 1–2 days in response to a 1 °C increase in May average temperature at elevations from 3,000 to 3,500 m, while the rate was up to 8–9 days/°C at 5,000–5,500 m. Analysis using accumulated growing degree days (AGDD) from January 1 through May 31 showed the same general trend with increased elevation associated with increased sensitivity (as measured by phenological change per unit of AGDD change). Such temperature sensitivity gradients in the TP grasslands could be partly explained by the growth efficiency hypothesis which suggests that vegetation adapted to colder climates likely requires less heat energy for the onset of growing season and vice versa in warmer climates. Furthermore, accumulated growing degree days from January 1 to the greenup date were found to decrease with increasing elevations, which provided evidence to support the applicability of the growth efficiency hypothesis in an alpine grassland ecosystem.

Description: A gravity network with 302 observation points has been established in the western Sichuan Foreland Basin (SFB) to explore Bouguer gravity anomalies (BGAs). Our observational results reveal that the BGAs are negative as a whole, with a maximum value of −220 mGal (10 −5 m s −2 ) at the northwest region of the study area. The real Moho depths beneath the SFB revealed by BGA data change smoothly from 39.5 km in the southeast to 43.7 km in the northwest of the monitoring region. However, the isostatic ones deduced from Airy isostatic model and topographical data vary approximately 39.5–42.0 km. The maximum differences of 2.7 km between the real and isostatic Moho depths are found near the seismic gap between the M 8.0 Wenchuan and M 7.0 Lushan earthquakes, where the crust is in the greatest isostatic imbalance of the monitoring region. Analysis of the isostatic state indicates that the deep dynamic environment near the seismic gap between these two earthquakes indicates an M  ≥ 7.0 earthquake in the future. This study indicates that we can use isostasy as a potential approach to study the dynamic process of crustal material movement and to analyze regional potential seismic risks.

Description: Climate change is considered a top threat to biodiversity, but the relative roles of contemporary climate versus the rate of climate change in determining spatial patterns of biodiversity are far from clear. China has a very diverse flora and harbors a high percentage of endemic species, but the mechanisms underlying spatial patterns of plant endemism are poorly understood. This study explores the geographical patterns of a representative sample of 555 endemic seed plant species at the scale of 0.5° latitude × 0.5° longitude. Ordinary least squares and spatial autoregressive models were compared to assess the relationship between richness of endemics and the rate of climate change in the past century, as well as a group of contemporary climate variables. In China, a high level of endemism was associated with high elevation and low rate of climate change. However, contemporary climate had a stronger impact than climate change velocity in the past century on endemic species richness patterns. Specifically, mean annual precipitation and annual range of temperature were important contemporary climatic factors. The rate of change of annual mean temperature, but not that of annual precipitation, also significantly contributed to the spatial pattern of plant endemic species richness. We found no significant relationship between topographic variation and endemic species richness, while temperature variability at multiple time scales was strongly correlated with the species richness pattern. Future work should consider the direction of climate change and incorporate higher-resolution data.

Description: Widespread lakes on the Tibetan Plateau (TP) are valuable archives for investigating climate and environment changes, which could provide essential information on the mechanisms of past climate changes on the TP and their interaction with the global climate systems. However, there is a lack of in-depth investigation of modern limnological processes in the Tibetan lakes, which hampers the understanding of paleolimnological records and lake ecosystem succession. In this study, we performed continuous temperature monitoring at two lakes, Bangong Co, a freshwater lake in the western TP, and Dagze Co, a brackish lake in the central TP, in order to characterize the patterns of seasonal temperature variability, stratification, and mixing. Temperature data for an entire hydrological year demonstrate that Bangong Co is a dimictic lake and that Dagze Co is a meromictic lake. The higher salinity in the deep water at Dagze Co prevents the lake from overturning completely, and this finding is supported by simulations using a physical limnological model Lake Analyzer. Continuous lake water temperature monitoring provides fundamental data for classifying Tibetan lakes, as well as the hydrological basis for understanding their paleolimnological records and ecosystem succession.

Description: An 18-year long (1993–2011) comprehensive dataset of snow and meteorological variables from Col de Porte, France is used to analyze the variation of shortwave broadband albedo with elapsed time after snowfalls (snow aging) during each snow season. The effects of air temperature, snow surface temperature and snow depth on snow albedo are investigated. An index based on the accumulation of air temperature over several consecutive days with daily mean higher than 2.5 °C is proposed to divide each snow-covered period into a dry and the following wet snow season when this index reaches 18 °C. The results indicate that snow surface albedo decreases exponentially with time in both dry and wet snow seasons. Snow albedo reduction with snow aging is small at low surface temperature and the reduction rate increases with the rise of surface temperature. However, the reduction rate is widely scattered within the observed range of temperature, implying a loose relationship between snow albedo and snow surface temperature. Snow albedo in wet snow season is generally smaller and decreases faster than in dry snow season. For Col de Porte site, snow depths to effectively mask the underlying surface are 21 and 33 cm in dry and wet snow season respectively.

Description: The rareness and inhomogeneity of the data points cause difficulties in the reconstruction of past average temperature. Optimal regional averaging is a method that can overcome these difficulties and obtain the average temperature of target area by means of optimal weights using limited temperature data. In this paper, the average temperature in the Northern Hemisphere is calculated by the optimal regional averaging method using two types of data: temperature data from Climatic Research Unit from 1901 to 2000 and maximum latewood density dataset of tree from 1500 to 1949. Five, ten, fifteen data points from CRU and forty data points from MXD are used in our research. The results show that even with the relatively less data used in this reconstruction, the method allows the reconstruction of the average temperature of the Northern Hemisphere more accurately, which provides the temperature information for palaeoclimate reconstruction.

Description: Using in situ observations from THEMIS A, D and E during the 2008–2011 tail season, we present a statistical study of the evolution of pressure gradients in the near-Earth tail during bursty bulk flow (BBF) convection. We identified 138 substorm BBFs and 2,197 non-substorm BBFs for this study. We found that both the pressure and the B Z component of the magnetic field were enhanced at the arrival of BBFs at the spacecraft locations. We suggest that the increase of B Z during non-substorm BBFs is associated with flux pile-up. However, the much stronger enhancement of B Z during substorm BBFs implies the occurrence of magnetic field dipolarization which is caused by both the flux pile-up process and near-Earth current disruption. Furthermore, a bow-wave-like high pressure appears to be formed at the arrival of substorm BBFs, which is responsible for the formation of region-1-sense FACs. The azimuthal pressure gradient associated with the arrival of substorm BBFs lasts for about 5 min. The enhanced pressure gradient associated with the bow wave is caused by the braking and diversion of the Earthward flow in the inner plasma sheet. The results from this statistical study suggest that the braking and azimuthal diversion of BBFs may commonly create azimuthal pressure gradients, which are related to the formation of the FAC of the substorm current wedge.

Description: A series of novel imidazolium oxidative-thermoregulated bifunctional ionic liquids (ILs) have been synthesized by introducing the thermoregulated structural unit into imidazolium cation and using heteropolyanion as the anion of ILs. The structures of these new type of task-specific ionic liquids (TSILs) are characterized by FT-IR and 1 H NMR. The thermostability of ILs is analyzed by thermogravimetry. The thermoregulated properties of ILs in aqueous and organic solvents are mainly investigated. These ILs have the corresponding cloud points (CPs) in aqueous. The effects of IL concentration, polymerization degree, inorganic additives and organic additives on the CP are studied. IL/DMF/ n -heptane or n -octane biphasic system has the corresponding critical solution temperature (CST), and has the feature of “homogeneous at high temperature, heterogeneous at low temperature”. The effects of IL dosage and polymerization degree on the CST are given. IL/DMF/ n -octane thermoregulated biphasic system has been successfully applied for catalytic oxidative desulfurization of model fuels. This study opens up a new way for catalytic oxidation to achieve an integration of homogeneous catalysis and heterogeneous separation.

Description: High-rate GPS data from the United States continuously operating reference stations in the Alaska region are processed using the recently developed precise point positioning (PPP) technique. The traditional PPP technique does not fix ambiguities into their integers because these ambiguities do not have an integer nature when data from a single receiver, as well as precise orbit and clock corrections, are used. Additional corrections, i.e., uncalibrated phase delay (UPD), are needed to fix integer ambiguities and consequently improve positioning accuracy. This study proposes a methodology to compute for wide-lane and L2 (the second L-band frequency) UPDs using the geometry-based model and subsequently applies these parameters to the computation for ambiguity-fixed solutions. The instantaneous displacements of near-field sites, as well as the permanent deformations after the earthquake, are therefore obtained for the January 5, 2013, Alaska earthquake. The real-time performance of PPP solutions are assessed by considering realistic data latency and data interval of corrections. Ambiguity-fixed solutions are compared with ambiguity-float ones. The comparison shows that the positioning accuracy can be improved significantly when the ambiguities are fixed correctly. The solutions using the real-time corrections are also compared with those using post-processing corrections, i.e., Center for Orbit Determination in Europe final orbit and clock. Although the accuracy is somehow degraded because of the data latency and data interval, the real-time results are satisfactory for use in monitoring the small-scale deformation (1–2 cm) caused by the Alaska earthquake. In addition, the kinematic ambiguity-fixed PPP solutions for 7 days around the earthquake are calculated to obtain permanent pre- and post-earthquake deformations. The deformations computed from real-time and post-processing corrections do not appear to be significantly different.

Description: Investigation of temporal variations in the stable δ 18 O and δ D isotopes from Kathmandu’s precipitation events shows that the relatively enriched δ 18 O and δ D values in the winter (the dry season, dominated by the westerlies) were positively correlated with temperature, indicating a temperature effect controlling the changes of δ 18 O and δ D. However, the δ 18 O and δ D values were depleted in the summer (the wet season, dominated by the Indian monsoon), which were negatively correlated with precipitation amount, indicating an amount effect. In addition, the comparison of stable isotopes in precipitation from Kathmandu and Mawlong (near the Bay of Bengal) shows that the overall trends of δ 18 O and δ D values at Kathmandu generally approximate those at Mawlong. However, there remain many differences between the details of the isotopic changes at Kathmandu versus those at Mawlong. Compared with those at Mawlong, the further rainout effect and the more intense lift effect of the oceanic moisture by the high mountains resulted in the more depleted δ 18 O and δ D values in summer precipitation at Kathmandu. A deuterium excess and the local meteoric water lines reveal that evaporation at Kathmandu exceeds that at Mawlong. The data also show that the Indian monsoon activities at Mawlong are more intense than those at Kathmandu.

Description: Occlusion of carbon (C) within phytoliths (PhytOC) is becoming one of the most promising terrestrial C sequestration mechanisms. This study explored the production of PhytOC within 35 bamboo species belonging to three ecotypes using methods of microwave digestion. The aim of this study is to explore the present and potential C sequestration rate within phytoliths of bamboo species from three ecotypes. PhytOC content in bamboos of three ecotypes ranges from 0.07 % to 0.42 %. The mean PhytOC production flux decreases as: clustered bamboo (0.050 ± 0.016 t CO 2 ha −1  a −1 ) ≈ mixed bamboo (0.049 ± 0.016 t CO 2 ha −1  a −1 ) 〉 scattered bamboo (0.038 ± 0.020 t CO 2 ha −1  a −1 ). The phytolith carbon sequestration in Chinese bamboo is estimated to be 0.293 ± 0.127 Tg (1 Tg = 10 12  g) CO 2 a −1 ; approximately 75 %, 3 %, and 22 % of which is contributed from scattered, mixed and clustered bamboo, respectively. Taking the PhytOC production flux of 0.18 ± 0.12 t CO 2 ha −1  a −1 and current annual area increasing rate of 3 %, global bamboo phytoliths would sequester 11.9 ± 7.9 Tg CO 2 a −1 by 2050. Consequently, bamboo forests have significant potential to mitigate the increasing concentration of atmospheric CO 2 by maximizing PhytOC production flux and expanding bamboos.

Description: N-type Si (111) wafers have been processed by high-current pulsed electron beam (HCPEB) treatment with an increasing number of irradiation (1, 10 and 20 pulses). The results of this work show that a highly porous nanostructure was formed after irradiation. Moreover, the high-density Si nanocrystals (Si-ncs) about 3 nm were distributed on the surface of Si wafers and exhibited 3.02 eV Photoluminescence (PL) emission in blue band. The PL intensity increases with the increase in the Si-ncs’ density in accordance with the quantum confinement model, which can be ascribed to the different pulse time of HCPEB treatment. The possible formation mechanisms of micropores and Si-ncs are discussed.

Description: The effective adsorption capability of a hydrogenated graphene (H-Gr) was demonstrated. The H-Gr was firstly prepared by heating graphene (Gr) in a hydrogen flow at 1,000 °C. The specific surface area, layer number, zeta potential, surface defects, surface compounds groups and elemental ratio of H-Gr were investigated. Taking 2,4-dichlorophenol as a target pollutant, the adsorption ability of H-Gr was evaluated. The results showed that the adsorption kinetics followed the pseudo-second-order equation well. For the adsorption isotherms, the equilibrium data of H-Gr were found to fit to Langmuir model, which was different from the Freundlich model of Gr. The adsorption capacity of H-Gr was high to 287.01 mg/g, almost three times as much as that of Gr, which was benefit from the increase of specific surface area and zeta potential. This work suggests that H-Gr may be a potential candidate for the adsorption of aromatic compounds from water and has great prospect for practical application.

Description: Two consecutive magnetic flux ropes, separated by less than 30 s ( Δt  〈 30 s), are observed within one magnetic reconnection diffusion region without strong guide field in the Earth’s magnetotail by Cluster multi-spacecraft. The flux ropes are characterized by bipolar signatures of the south–north magnetic field component B z accompanied with strong core magnetic field B y , intense current J and density depletions inside of them. In spite of the small but non-trivial global scale negative guide field (– B y ), there exists a directional change of the core fields of two flux ropes, i.e., − B y for the first one, and + B y for the second one. The directions of the core fields are the same as the ambient cross-tail magnetic field component ( B y ) just outside of flux ropes. Therefore, we suggest that the core field of flux ropes is formed by compression of the local preexisting B y and that the directional change of core field is due to the change of local preexisting B y . Such a change in ambient B y might be caused by some microscale physics.

Description: In this work, a series of new metal phosphonates were hydrothermally synthesized and structurally characterized based on m -xylylenediphosphonic acids (H 4 L), including [M(H 2 L)(bpy)] (M = Mn 1 , Co 2 ), [MH 2 L)(phen)] (M = Co 3 , Cu 4 ), and [Cu 2 (H 2 L) 2 (bpy″) 2 ] 5 (bpy = 2,2′-bipyridine, phen = 1,10-phenanthroline, bpy″ = 4,4′-dimethyl-2,2′-bipyridine). X-ray diffraction indicated that compounds 1 and 2 were isomorphic. Complexes 3 and 4 were shown to crystallize in different space groups but had similar crystallographic units. In the complexes, H 4 L was seen to partially deprotonate to afford H 2 L 2− . The H 2 L 2− ligands in 1 – 4 functioned as tetradentate ligands with each phosphonate group adopting bidentate coordination mode with two M centers to generate a 2D layer. In addition, the H 2 L 2− anions in 5 functioned as tridentate ligands with one phosphonate group adopting the bidentate mode and another phosphonate group adopti ng the monodentate mode, thus linking three Cu atoms to provide a 1D chain. The IR and thermal stabilities of these compounds were subsequently examined.

Description: Identifying melts of thickened lower continental crust from high Sr/Y rocks is very important to trace deep crustal processes. Recent studies on Dabie Early Cretaceous granitoids have revealed that melts derived from thickened lower continental crust have higher Sr/CaO ratios and define a high Sr evolution trend compared with normal granitoids. Fractional crystallization of plagioclase can significantly change Sr and CaO contents of melts, but its role in controlling the Sr/CaO ratios of the melts is still unclear. This study gives a direct comparison of plagioclase compositions between normal granitoids and low-Mg adakitic rocks. On the basis of Sr–Ca exchange partition coefficient, discussions on effect of plagioclase crystallization on Sr/CaO ratios of melts show that fractional crystallization of abundant plagioclase cannot significantly change Sr/CaO ratios of granitic melts, which are inherited from their individual initial melts. High Sr/CaO ratios indicate the absence of plagioclase in sources of granitic melts. Therefore, high Sr/CaO correlation can be an important indicator to identify melts derived from thickened lower continental crust.

Description: We present a comprehensive numerical analysis of spherical, spheroidal, and ellipsoidal harmonic series for gravitational field modeling near small moderately irregular bodies, such as the Martian moons. The comparison of model performances for these bodies is less intuitive and distinct than for a highly irregular object, such as Eros. The harmonic series models are each associated with a distinct surface, i.e., the Brillouin sphere, spheroid, or ellipsoid, which separates the regions of convergence and possible divergence for the parent infinite series. In their convergence regions, the models are subject only to omission errors representing the residual field variations not accounted for by the finite degree expansions. In the regions inside their respective Brillouin surfaces, the models are susceptible to amplification of omission errors and possible divergence effects, where the latter can be discerned if the error increases with an increase in the maximum degree of the model. We test the harmonic series models on the Martian moons, Phobos and Deimos, with moderate oblateness of \(〈\) 0.4. The possible divergence effects and amplified omission errors of the models are illustrated and quantified. The three models yield consistent results on a bounding sphere of Phobos in their common convergence region, with relative errors in potential of \(\sim \) 0.01 and \(\sim \) 0.001 % for expansions up to degree 10 and degree 20 respectively. On the surface of Phobos, the spherical and spheroidal models up to degree 10 both have maximum relative errors of \(\sim \) 1 % in potential and \(\sim \) 100 % in acceleration due ostensibly to divergence effect. Their performances deteriorate more severely on the more irregular Deimos. The ellipsoidal model exhibits much less distinct divergence behavior and proves more reliable in modeling both potential and acceleration, with respective maximum relative errors of \(\sim \) 1 and \(\sim \) 10 %, on both bodies. Our results show that for the Martian moons and other such moderately irregular bodies, the ellipsoidal harmonic series should be considered preferentially for gravitational field modeling.

Description: The fluctuation of the water level in a reservoir may induce various types of slope movements. Some of these movements are new, whereas others are old but reactivated. Many ancient landslide accumulations are distributed in the deep valleys of the eastern Qinghai–Tibet Plateau margin in China and will likely be reactivated after the completion of reservoirs and pose a risk to reservoirs, dams, facilities, and towns near mountainous areas. The Shuangjiaping ancient landslide, located in the Dadu River, Sichuan Province, China, is an example of this case. Since August 2010, the western part of the accumulation body has seen the gradual appearance of deformations. The Pubugou reservoir water level rises and inundates the front edge of the accumulation body, thus threatening the safety of the national highway G108 and 37 houses on it. This study is based on field work investigation, drilling work, aerial photography, and profile survey. The site-scale investigation shows that the deformation area is only a part of an ancient landslide accumulation, with an area of approximately 50.4 × 10 4  m 2 and a volume of ca. 956 × 10 4  m 3 . Boundary and deposit characteristics of landslide accumulation are specified, which could be divided into four zones, namely, zones A and C, which are an avalanche accumulation area mainly composed of large blocks with diameter ranging from 1 to 3 m (some blocks have a diameter ranging from 5 to 10 m), zone B, a residual integrated rock mass accumulation area with “fake bedrock,” and zone D, a fine material accumulation area. A conceptual model is proposed to explain the mechanism and sliding process of this ancient landslide. The model includes translational sliding, stopping and hanging in air, avalanche accumulating, and transforming. The saltation of topography, material structure, and kinematic characteristics is the evidence used to identify the ancient landslide in deeply incised mountain areas. The current activity is found to be a surficial deposit displacement, and the whole landslide accumulation is stable or quasi-stable.

Description: The initiation of debris flows is commonly attributed either to fluidization as a result of rainfall-induced landslides or to gully erosion induced by concentrated runoffs. A series of flume tests have been performed to show how the initial soil moisture influences the initiation of debris flows. At the start of each experiment, surface runoff was generated over loose granular deposits, triggering debris flows. These experimental debris flows enacted different scenarios according to the small variations among the initial soil moistures. In the loose granular deposits with initial soil moistures ranging from 1 to 5 %, most runoff water could infiltrate and trigger a landslide, which accelerated within 1 s to speed over 1 ms −1 and then transformed into a debris flow. In the same soil deposits with initial moistures 〉5 or 〈1 %, the debris flow was initiated by slow gully erosion with episodic events of damming and breaching due to small-scale landslides occurring on the side-slopes of the erosion valley. The slope failures were not triggered by positive pore pressure but by a decrease in suction due to the wetting of the soil. This suction decrease in initially unsaturated slopes explains why the transformation of these slope failures into debris flows are due not only to an increase of pore pressure leading to soil liquefaction, which is one of the expected triggering mechanisms, but also to a loss of the cohesive strength of the soil.

Description: This paper presents a methodology for constructing fragility functions to characterise slope stability under a range of catastrophic earthquakes and rainfalls. The procedures for creating fragility functions, including the first-order reliability method (FORM) and the copula-based sampling method (CBSM), are demonstrated using a selection of typical slopes. The most common failure modes are included, such as the shallow sliding of an infinite slope, circular slip surface of a homogeneous slope, and tetrahedral wedge failure in a rock slope. Owing to the proposed approach, the fragility function can be applied to quantify the failure probabilities over a range of loading conditions with ease, as these are attributed to a function, rather than a design point. The advantage of these definitions is that the uncertainties of correlated soil shear strengths can be incorporated into the reliability models. The established procedure can provide a basis for describing vulnerable behaviour of a slope under various loading conditions and geometries.

Description: Early warning systems (EWSs) rely on the capacity to forecast a dangerous event with a certain amount of advance by defining warning criteria on which the safety of the population will depend. Monitoring of landslides is facilitated by new technologies, decreasing prices and easier data processing. At the same time, predicting the onset of a rapid failure or the sudden transition from slow to rapid failure and subsequent collapse, and its consequences is challenging for scientists that must deal with uncertainties and have limited tools to do so. Furthermore, EWS and warning criteria are becoming more and more a subject of concern between technical experts, researchers, stakeholders and decision makers responsible for the activation, enforcement and approval of civil protection actions. EWSs imply also a sharing of responsibilities which is often averted by technical staff, managers of technical offices and governing institutions. We organized the First International Workshop on Warning Criteria for Active Slides (IWWCAS) to promote sharing and networking among members from specialized institutions and relevant experts of EWS. In this paper, we summarize the event to stimulate discussion and collaboration between organizations dealing with the complex task of managing hazard and risk related to active slides.

Description: Recent studies have extensively discussed total least squares (TLS) algorithms for solving the errors-in-variables (EIV) model with equality constraints but rarely investigated the inequality-constrained EIV model. The most existing inequality-constrained TLS algorithms assume that all the elements in the coefficient matrix are random and independent and that their numerical efficiency is significantly limited due to combinatorial difficulty. To solve the above issues, we formulate a partial EIV model with inequality constraints of both unknown parameters and the random elements of the coefficient matrix. Based on the formulated EIV model, the inequality-constrained TLS problem is transformed into a linear complementarity problem through linearization. In this way, the inequality-constrained TLS method remains applicable even when the elements of the coefficient matrix are subject to inequality constraints. Furthermore, the precision of the constrained estimates is put forward from a frequentist point of view. Three numerical examples are presented to demonstrate the efficiency and superiority of the proposed algorithm. The application is accomplished by preserving the structure of random coefficient matrix and satisfying the constraints simultaneously, without any combinatorial difficulty.

Description: Desalination has proven to be a reliable and efficient water supply option in many countries, especially in times of water scarcity. However, high desalination costs and high prices for desalinated water (twice or three times higher than those from traditional water sources) have been hindering an uptake and the development of desalination in many countries. Applied desalination technology, capital and operational costs, production capacity, water salinity are just a few factors determining the final cost of desalinated water that varies considerably between $1.7–9.5/kgal ($0.45–2.51/m 3 ). The final prices for desalinated water and the related costs for local municipalities are among the most crucial determinants of the overall short- and long-term effectiveness of desalination processes. This paper provides an in-depth analysis on economics of desalination with country specific examples. It depicts a comprehensive picture of cost variability of desalinated water and points out challenges for cost-effective desalination in the future.

Description: In the present study, the Ti-in-biotite geothermometer was revised using more than 300 natural rutile- or ilmenite-bearing metapelites collected worldwide. The formulation was empirically calibrated as \( \ln [T\,(^\circ {\text{C}})] = 6.313 + 0.224\ln (X_{\text{Ti}} ) - 0.288\ln (X_{\text{Fe}} ) - 0.449\ln (X_{\text{Mg}} ) + 0.15P\,({\text{GPa}}) \) , with \( X_{j} = {{j}}/({\text{Fe}} + {\text{Mg}} + {\text{Al}}^{\text{VI}} + {\text{Ti}}) \) in biotite, assuming ferric iron content of 11.6 mol% of the total iron in biotite. This thermometer is consistent with the well-calibrated garnet–biotite thermometer within error of ±50 °C for most of the calibrant samples and can successfully distinguish systematic temperature changes of different metamorphic zones in both prograde and inverted metamorphic terranes as well as thermal contact aureoles. Thus, the thermometer truthfully reflects real geologic conditions and can be applied to TiO 2 -saturated metapelites metamorphosed at the crustal level within the calibration ranges (450–840 °C, 0.1–1.9 GPa, X Ti  = 0.02–0.14 in biotite).

Description: Drought situations can have significant impacts, affecting large areas and imposing relevant restrictions on multiple economic activities. The severity of those impacts is, normally, assessed through meteorological, agricultural and/or hydrological indices or even through estimation of water deficits or reduction of production yields (for agriculture). However, those assessments usually do not represent the socioeconomic importance of the impacts and the results are not comparable for different types of impacts or distinct regions. In this context, the present work enunciates the main principles to be considered and a methodological approach for socioeconomic evaluation of drought effects, regarding the main supply and demand characteristics of a region (water sources and associated uses), and the hydrological interlinked effects of drought situations. Moreover it describes the methodology process application to Portuguese reality and existing data as the basis of drought’s severity assessment, focusing on two drought prone areas in Portugal: the Guadiana and the Ribeiras do Algarve river basin case studies. Regarding the main specificities of the referred case studies, the economic activities (and water dependent sectors) considered for this methodology were the agricultural and the urban water supply sectors. For each of those sectors, specific assessment procedures where developed in order to estimate the respective economic impacts caused by the drought situation in the area of analysis. A global assessment of the socioeconomic relevance of drought impacts in a region is ensured through comparison of the estimated total economic impacts to the region’s annual average of the Gross Domestic Product (GDP), that enabling the comparison of results for different regions of analysis. The methodology may be applicable to any region with common hydrological and water use data and was developed to be of support for drought management and application on a drought early warning system.

Description: This introductory article starts by describing the genesis of this special issue and the interconnection of its topics. The editors offer a variety of reading entries into the key-note articles and responses. The article reconstructs the research interests underpinning the idea of integrating meaningfulness, volunteers and citizenship. It highlights the explicit interdisciplinary design of the special issue, and shows how the key-note authors, and their respondents, weave connections between meaningfulness, volunteering and citizenship. And, finally, the editors bring the background understandings of the key-note papers to the foreground, and reconstruct a non-intentional meta-level discussion on two fundamental concepts and their interplay: self and world.

Description: This article argues, firstly, that voluntary civic practices are not doomed to fall prey to a Big Society rhetoric and a cynical politics of cuts in social spending. It all depends on how these civic practices are promoted and what kind of civic discourse is communicated through the channels of social media and public opinion. Secondly, the author highlights the political importance of connecting meaningfulness with citizenship.

Description: This paper draws on an in-depth phenomenological analysis of some interviews taken from volunteers, inviting them to reflect on their lived experiences of meaningfulness in the context of volunteering and citizenship. It is found that while some testimonies reinforce the standard conceptions of meaningfulness, other testimonies vary from it. The main challenge of this contribution consists in phenomenologically describing this alternative picture of meaningfulness, depicted as the event of wit(h)nessing. In a final part, the authors consider how volunteering is at times especially prone to further experiences of wit(h)nessing.

Description: The Vértes Hills are one of the most active seismic regions in Hungary. An \(\hbox {M}_\mathrm{L}~=~4.5\) magnitude earthquake shocked this area near to Oroszlány on January 29, 2011. The mainshock was followed by about four hundred aftershocks, and their magnitude varied from \(\hbox {M}_\mathrm{L}~=~-0.6\) to \(\hbox {M}_\mathrm{L}~=~3.5\) . Despite of the large number of aftershocks, the seismotectonic interpretation is very difficult because these earthquakes occurred in the vicinity of quarries. The waveform similarity analysis was proven a successful method to separate earthquakes and explosions, and revealed plus information about the aftershock sequence.

Description: Biodiesel production from non-edible feedstocks is currently drawing much attention due to legitimate concerns about the effects of using edible oil for fuel. Pangium edule Reinw is a non-edible feedstock. Pangium is a tall tree native to the Micronesia, Melanesia and the mangrove swamps of South-East Asia. In this study, biodiesel production and characterization from P. edule oil was reported. The seeds were obtained from Bogor, Indonesia. The oil was found to have an acid value of 19.62 mg KOH/g oil. Therefore, a two-step acid–base-catalysed transesterification was used to produce biodiesel. This was followed by evaluating the physical and chemical properties of biodiesel and its blends with diesel. It has been found that the determined properties of P. edule methyl ester indicate that the oil can be considered as a future biodiesel source. The most remarkable feature of P. edule is its cloud, pour and cold filter plugging points. This biodiesel yielded cloud, pour and cold filter plugging points of –6, –4 and –8 °C, respectively. This indicates the viability of using this biodiesel in cold countries. Therefore, it is suggested that more research should be conducted on P. edule for future biodiesel production.

Description: The paper presents a new Kernel-based monitoring algorithm compared with statistical process control methods, such as DISSIM and MS-PCA and some others methods widely used in process control applications. The proposed algorithm is a modified version of the well known support vector domain description (SVDD). The last one is commonly used for one-classification problems, named also novelty detection. In this paper, we have used a modified SVDD endowed with useful tools to manage multi-classification problems. The proposed classifier is also able to deal with stationary as well as non-stationary data. The principle is based on the dynamic update of the training set through a recursive deletion/insertion procedure according to adequate rules. In order to reduce the computational complexity and improve the rapidity of convergence, the algorithm considers in each run a limited frame of samples for the training process. To prove its effectiveness, the approach is assessed at first on artificially generated data. Then, we have performed a case study applied on chemical process.

Description: A series of nonionic surfactants were synthesized from gallic acid and polyethylene glycols with different molecular weights. Chemical structures of the surfactants were confirmed using elemental analysis, infrared and nuclear magnetic resonance ( 1 H-NMR) spectroscopy. Surface activities of the surfactants in their solutions were determined by surface tension measurements. Increasing the polyethylene glycol chain length increased the surface activity of the surfactants in solutions. Measurements of interfacial tension between surfactants solutions and substrates with different polarity showed that the type of substrates plays functioning role on the interfacial properties. Thermodynamic properties of adsorption and micellization processes showed their tendency towards adsorption at solution interface and micellization in their solutions. Results showed reasonable surface activities compared to conventional nonionic surfactants.

Description: The Fukushima nuclear catastrophe has led to a wide-spread international discussion on how seismic and tsunami hazards can be better predicted and adverse consequences be prevented. In some countries the event led to the complete phase-out of nuclear energy. The lessons drawn by different organisations including earth scientists, earthquake engineers, non-governmental and governmental organisations will be reviewed from an independent position. This review captures the following areas: (1) Hazard assessment, (2) Engineering design and defence in depth concepts, (3) Emergency preparedness. It is shown that not all important lessons from the catastrophe have been drawn, because some of the root causes of the accident are not yet addressed. Especially the need of a holistic approach towards hazard assessment and the implementation of defence in depth and diversity of design principles for critical infrastructures like nuclear power plants hast to be stronger emphasized to prevent similar disasters.

Description: Providing warning notification several seconds before dangerous earthquake waves arrive at a target site reduces the property damages and human casualties. Most earthquake early warning systems (EEWS) developed are either regional (“network based”) or on-site (“stand alone”) systems. The recent upgrade of the seismic network in Romania with high dynamic range accelerometers allows recording of moderate to large magnitude earthquakes at very close epicentral distances (less than 10–20 km). This allows an increase of the warning lead-time (the time difference between the alert notification time and the arrival time of potentially destructive waves at a given target). The seismicity of Romania is significantly affected by earthquakes produced by the Vrancea seismic source with intermediate depth events (three shocks/century with magnitude Mw greater than 7.0). In this paper we present the performance of the seismic network in rapidly locate events occurring in the Vrancea area. Since rapid location of earthquakes is the first step in issuing early warning notifications, by reducing the time of the first valid location will lead to an increase the lead-time interval. Also rapid location of events will allow a future upgrade of EEWS to cover the entire Romanian territory.

Description: Physical characterization study is carried out on the Mansehra Granite, Hakale Granite, quartzite and dolerite from Mansehra area to explore their potential for utilization as construction materials. Laboratory tests reveal specific gravity (2.65–3.02), water absorption (0.32–0.38 %), Aggregate Impact and Aggregate Crushing values (17.26–27.01 % and 15.59–21.21 %), Flakiness and Elongation Index (6.01–7.80 % and 5.95–9.39 %), sulphate soundness (2.19–4.07 %) and Los Angeles abrasion value (28.13–35.70 %) of these rocks. Values of these parameters were compared with the ASTM and BS standards which indicate that Mansehra Granite, Hakale Granite, quartzite and dolerite can be the potential source for dimension stone, road and concrete aggregate. Stripping test indicates suitability of these rocks as aggregate for asphalt wearing course. Unconfined compressive strength of gneissic and massive Mansehra Granites varies from 61.50 to 66.20 MPa. Owing to lower unconfined compressive strength, higher flakiness and elongation index, aggregate impact and crushing values, the gneissic Mansehra Granite is not recommended as dimension stones, road and cement concrete. Petrographic studies indicate presence of strained quartz in Mansehra Granite, Hakale Granite and quartzite which suggest that these rocks are prone to alkali-silica reactivity potential and may not be used as cement concrete aggregate.