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  • Articles  (601,717)
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  • Articles  (601,717)
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  • 1
    Publication Date: 2014-12-31
    Print ISSN: 1936-0851
    Electronic ISSN: 1936-086X
    Topics: Chemistry and Pharmacology , Physics
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  • 2
    Publication Date: 2014-12-31
    Print ISSN: 1936-0851
    Electronic ISSN: 1936-086X
    Topics: Chemistry and Pharmacology , Physics
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  • 3
    Publication Date: 2014-12-31
    Print ISSN: 1936-0851
    Electronic ISSN: 1936-086X
    Topics: Chemistry and Pharmacology , Physics
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  • 4
    Publication Date: 2014-12-31
    Description: We report on the realization of a quartz-enhanced photoacoustic (QEPAS) sensor for measurement of H 2 S gas traces. A distributed feedback diode laser working at 2.64 µm wavelength has been coupled to an acoustic detection module composed of a quartz tuning fork and a micro-resonator system, and the QEPAS signal has been optimized in terms of gas sample pressure and laser frequency modulation depth. The sensor shows a very good linearity with respect to the H 2 S concentration. We performed an Allan–Werle variance analysis to investigate the sensor long-term stability, and we reached a detection limit of four parts per million for 1-s integration time and 500 parts per billion in 60-s integration time. The realized QEPAS sensor represents a good compromise between performance and handiness, in view of a fully portable device.
    Print ISSN: 0946-2171
    Electronic ISSN: 1432-0649
    Topics: Physics
    Published by Springer
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  • 5
    Publication Date: 2014-12-31
    Description: We present a detailed design principle and propagation characteristics of a channel plasmon-photonic–crystal-coupled-waveguide (PPCCW) for realizing terahertz (THz) waveguides and waveguide-based devices. The avoided-crossing behavior exhibited by dispersion curves of the supermodes due to modal interference leads to a sharp change in group velocity close to the phase-matching wavelength. As a consequence, the group-velocity dispersion (GVD) peaks to a maxima (~1.40 × 10 5  ps/km·μm) and dips to a minima (~−1.60 × 10 5  ps/km·μm), thus exhibiting extremely large GVD. The propagation length is obtained in the order of a few centimeters. The analysis is substantiated by the frequency dependence of mode field distribution and propagation loss suffered by the supermodes of PPCCW geometry. Also, the obtained result is in good agreement with FEM-based study. The proposed waveguide is aimed at facilitating enhanced performance THz-waveguide sensors and GVD compensation modules.
    Print ISSN: 0946-2171
    Electronic ISSN: 1432-0649
    Topics: Physics
    Published by Springer
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  • 6
    Publication Date: 2014-12-31
    Description: By experiments and theory, we investigate the influence of heat transfer across a gas–solid interface on the nodule height of microstructured silicon fabricated under femtosecond laser pulses. By changing the pressure of the vacuum system, a fast-changing spread in height is found. This is determined by the different heat-transfer flux across the gas–solid interface for different Knudsen-number regimes. Heat transfer affects the energy remaining in the bulk silicon, which determines nodule formation and corresponding height. The rate of change in the heat-transfer flux induces a negative rate of change in the nodule height. These results are important when optimizing the surface microstructure for silicon-based photoelectron devices.
    Print ISSN: 0946-2171
    Electronic ISSN: 1432-0649
    Topics: Physics
    Published by Springer
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  • 7
    Publication Date: 2014-12-31
    Description: Two-line atomic fluorescence (TLAF) thermometry is based on the consecutive excitation of two nearby atomic ground states to a common excited state, and ratioing the ensuing fluorescence yields. TLAF is one of the few methods that hold promise for thermometry in sooting environments. We extend the method to the regime of fully saturated excitation and introduce a new seeding system that also allows the method to be used in lean flames. We compare results for saturated TLAF to those of linear TLAF and to thermocouple measurements, and find good correspondence. The saturated version introduced here maximizes fluorescence yields while simultaneously suppressing the dependence on excitation laser irradiance.
    Print ISSN: 0946-2171
    Electronic ISSN: 1432-0649
    Topics: Physics
    Published by Springer
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  • 8
    Publication Date: 2014-12-31
    Description: In this paper, the mechanical and long-term durability behaviour of structural lightweight concrete (LWC) produced with natural lightweight scoria aggregate (LWSA) from the Azores is analysed. Among the properties studied are the compressive and tensile strength, modulus of elasticity, shrinkage, capillary absorption, carbonation and chloride resistance. To this end, a comprehensive experimental study was carried out on different concrete compositions involving common and high-performance structural concrete produced with coarse or coarse and fine volcanic scoria aggregate. Generally, all the mechanical properties worsened with the incorporation of LWSA. It is concluded that the most efficient LWC with LWSA can attain compressive strength up to about 35 MPa. On the other hand, the production of LWC of more than 50 MPa implies a marked reduction in compressive strength for a small reduction in density. The long-term shrinkage increased with the replacement of normal-weight aggregate by LWA and was higher when coarse and fine scoria were used. However, the early age shrinkage can be counterbalanced by the internal curing effect provided by LWSA. The capillary absorption, chloride and carbonation resistance were affected by the high porosity of LWSA. The absence of the outer shell in scoria aggregate and the surface effects during tests can partly explain the lower performance of the LWC. Nevertheless, it is shown that LWC with scoria can be durable, and even for low- to moderate-strength LWC the corrosion induced by carbonation may not be relevant.
    Print ISSN: 1319-8025
    Electronic ISSN: 2191-4281
    Topics: Natural Sciences in General , Technology
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  • 9
    Publication Date: 2014-12-31
    Description: Urban areas with rapid industrial development have major impacts on environmental soil quality. This study was carried out to determine contamination assessment of heavy metal concentration of urban soil from Klang district (Malaysia). Health risk assessment was used to determine potential health risks (carcinogenic and non-carcinogenic risks) in both adults and children. Moreover, this study was also used to identify the most significant contaminant and exposure pathway with regard to Klang urban soil. Mean bioavailability of heavy metal concentrations were found in the order of Fe (6.65 mg/kg) 〉 Zn (5.61 mg/kg) 〉 Cu (2.96 mg/kg) 〉 Co (0.22 mg/kg) 〉 Cd (0.14 mg/kg) 〉 Pb (0.11 mg/kg) 〉 Cr (0.10 mg/kg). Maximum values of Cd (0.64 mg/kg), Cu (52.14 mg/kg) and Pb (9.18 mg/kg) have exceeded some guidelines and standard values. Study findings showed that total carcinogenic risks values of Cd, Cr and Pb are more than incremental lifetime (1.0E-05). This indicates the likehood of having cancer threat for adults and children. While for total non-carcinogenic risk, none of the heavy metals (Co, Cr, Cu, Pb and Zn) showed Hazard Index values more than one indicating there is no any potential non-carcinogenic risks for adults and children in study area. From this study, Cd is the most significant contaminant as maximum concentration value has exceeded soil guidelines and potential to have carcinogenic risks to adults and children. Pathway order for both carcinogenic and non-carcinogenic risks is ingestion 〉 dermal 〉 inhalation where ingestion pathway contributed the most to potential health risks involving urban soil of Klang.
    Print ISSN: 1866-6280
    Electronic ISSN: 1866-6299
    Topics: Geosciences
    Published by Springer
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  • 10
    Publication Date: 2014-12-31
    Description: Restoration efforts in Florida’s Everglades focus on preserving and restoring this unique wetland’s natural landscape. Because most of the Everglades is a freshwater peatland, it requires surplus rainfall to remain a peatland. Restoration plans generally assume a stable climate, yet projections of altered climate over a 50-year time horizon suggest that this assumption may be inappropriate. Using a legacy regional hydrological model, we simulated combinations of a temperature rise of 1.5 °C, a ± 10 % change in rainfall, and a 0.46 m sea level rise relative to base conditions. The scenario of increased evapotranspiration and increased rainfall produced a slight increase in available water. In contrast, the more likely scenario of increased evapotranspiration and decreased rainfall lowered median water depths by 5–114 cm and shortened inundation duration periods by 5–45 %. Sea level rise increased stages and inundation duration in southern Everglades National Park. These ecologically significant decreases in water depths and inundation duration periods would greatly alter current ecosystems through severe droughts, peat loss and carbon emissions, wildfires, loss of the unique ridge and slough patterns, large shifts in plant and animal communities, and increased exotic species invasions. These results suggest using adaptive restoration planning, a method that explicitly incorporates large climatic and environmental uncertainties into long-term ecosystem restoration plans, structural design, and management. Anticipated water constraints necessitate alternative approaches to restoration, including maintaining critical landscapes and facilitating transitions in others. Accommodating these uncertainties may improve the likelihood of restoration success.
    Print ISSN: 0364-152X
    Electronic ISSN: 1432-1009
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Springer
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