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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases  (2)
  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (1)
  • Elsevier Science  (2)
  • Nature Publishing Group  (1)
  • Blackwell Publishing Ltd
  • Copernicus
  • 2015-2019  (3)
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Years
Year
  • 1
    Publication Date: 2020-12-09
    Description: We report a new case of methane (CH4) of apparent abiotic origin in continental serpentinized ultramafic rocks. Multiple analytical techniques, on-site and in the laboratory, revealed methane and ethane degassing from hyperalkaline (pH 〉 11) Ca2þ eOH mineral waters in boreholes drilled in the Alter-do- Chão igneous intrusion, at Cabeço de Vide, in mainland Portugal. The C and H isotopic composition of CH4 (d13C w 20&; d2H: 283&) suggests a dominant abiotic origin, although minor thermogenic contributions cannot be excluded. Similarly, low methane-to-ethane ratios suggest a predominantly nonmicrobial source, consistent with previous microbiological data showing the lack of methanogenic archaea in these waters. Heavier hydrocarbons, CO2 and H2 are below detection limits. This case study confirms that CH4 from serpentinized ultramafic rocks can be transported by hyperalkaline fluids linked to deep circulation of meteoric waters. Maximum depth of Cabeço de Vide serpentinized rocks is less than 1 km, and present temperatures are likely lower than 50 C. Serpentinization and related gas formation may have occurred at any time during thermal evolution of the igneous intrusion, so gas formation temperature cannot be easily determined. This case is an opportunity to test thermometry provided by CH4 isotopologue analyses. The existence of methane in continental serpentinized igneous rocks is more widespread than previously thought and petroleum systems with similar serpentinized ultramafics in reservoir rocks may have traces of the observed 13C-enriched CH4
    Description: Published
    Description: 12-16
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: Abiotic methane, serpentinization ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-12-22
    Description: Natural hydrocarbon gas seeps are surface expressions of Petroleum Seepage Systems, whereby gas is ascending through faults from pressurized reservoirs that are typically associated with sandstones or limestones. A spectacular “eternal flame” in western New York State marks a gas macroseep of dominantly thermogenic origin emanating directly from deep shale source rocks, which makes this a rare case in contrast to most Petroleum Seepage Systems where gas derives from conventional reservoirs. The main flaming seep releases about 1 kg of methane per day and may feature the highest ethane and propane (C2 þ C3) concentration ever reported for a natural gas seep (w35 vol. %). The same gas is also released to the atmosphere through nearby invisible and diffuse seepages from the ground. The synopsis of our data with available gas-geochemical data of reservoir gases in the region and the stratigraphy of underlying shales suggests that the thermogenic gas originates from Upper Devonian shales without intermediation of a conventional reservoir. A similar investigation on a second “eternal flame” in Pennsylvania suggests that gas is migrating from a conventional sandstone pool and that the seep is probably not natural but results from an undocumented and abandoned gas or oil well. The large flux of the emitted shale gas in New York State implies the existence of a pressurized gas pool at depth. Tectonically fractured shales seem to express “naturally fracked” characteristics and may provide convenient targets for hydrocarbon exploration. Gas production from “tectonically fracked” systems might not require extensive artificial fracking.
    Description: Published
    Description: 178-186
    Description: 7A. Geofisica di esplorazione
    Description: JCR Journal
    Description: restricted
    Keywords: gas seep, methane, shale-gas, hydrocarbons ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: In open conduit volcanoes, volatile-rich magma continuously enters into the feeding system nevertheless the eruptive activity occurs intermittently. From a practical perspective, the continuous steady input of magma in the feeding system is not able to produce eruptive events alone, but rather surplus of magma inputs are required to trigger the eruptive activity. The greater the amount of surplus of magma within the feeding system, the higher is the eruptive probability.Despite this observation, eruptive potential evaluations are commonly based on the regular magma supply, and in eruptive probability evaluations, generally any magma input has the same weight. Conversely, herein we present a novel approach based on the quantification of surplus of magma progressively intruded in the feeding system. To quantify the surplus of magma, we suggest to process temporal series of measurable parameters linked to the magma supply. We successfully performed a practical application on Mt Etna using the soil CO2 flux recorded over ten years.
    Description: Published
    Description: 30471
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: eruptive potential ; eruptive probability ; open conduit volcanoes ; Etna ; Soil CO2 flux ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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