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  • doped ceriadisorderpair distribution functionhigh-resolution X-ray powder diffractionpercolationhierarchysolid electrolyteselectron spin resonance  (2)
  • 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes  (1)
  • International Union of Crystallography (IUCr)  (2)
  • Molecular Diversity Preservation International  (1)
  • American Chemical Society
  • Edizioni Nuova Cultura
  • 2015-2019  (3)
Collection
Keywords
Publisher
Years
Year
  • 1
    Publication Date: 2017-04-04
    Description: We study land subsidence processes and the associated ground fissuring, affecting an active graben filled by thick unconsolidated deposits by means of InSAR techniques and fieldwork. On 21 September 2012, Ciudad Guzmán (Jalisco, Mexico) was struck by ground fissures of about 1.5 km of length, causing the deformation of the roads and the propagation of fissures in adjacent buildings. The field survey showed that fissures alignment is coincident with the escarpments produced on 19 September 1985, when a strong earthquake with magnitude 8.1 struck central Mexico. In order to detect and map the spatio-temporal features of the processes that led to the 2012 ground fissures, we applied InSAR multitemporal techniques to process ENVISAT-ASAR and RADARSAT-2 satellite SAR images acquired between 2003 and 2012. We detect up to 20 mm/year of subsidence of the northwestern part of Ciudad Guzmán. These incremental movements are consistent with the ground fissures observed in 2012. Based on interferometric results, field data and 2D numerical model, we suggest that ground deformations and fissuring are due to the presence of areal subsidence correlated with variable sediment thickness and differential compaction, partly driven by the exploitation of the aquifers and controlled by the distribution and position of buried faults.
    Description: Published
    Description: 8610-8630
    Description: 6A. Monitoraggio ambientale, sicurezza e territorio
    Description: JCR Journal
    Description: open
    Keywords: InSAR ; ground subsidence ; buried faults ; ground fissuring ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2015-08-01
    Description: A new hierarchical approach is presented for elucidating the structural disorder in Ce1−xGdxO2−x/2 solid solutions on different scale lengths. The primary goal of this investigation is to shed light on the relations between the short-range and the average structure of these materials via an analysis of disorder on the mesocopic scale. Real-space (pair distribution function) and reciprocal-space (Rietveld refinement and microstructure probing) analysis of X-ray powder diffraction data and electron spin resonance (ESR) investigations were carried out following this approach. On the local scale, Gd- and Ce-rich droplets (i.e. small regions a few ångströms wide) form, exhibiting either a distorted fluorite (CeO2) or a C-type (Gd2O3) structure in the whole compositional range. These droplets can then form C-type nanodomains which, for Gd concentrations xGd ≤ 0.25, are embedded in the fluorite matrix. At the site percolation threshold pC for a cubic lattice (xGd = pC ≃ 0.311), C-type nanodomains percolate inside each crystallite and a structural phase transformation is observed. When this occurs, the peak-to-peak ESR line width ΔHpp shows a step-like behaviour, which can be associated with the increase in Gd–Gd dipolar interactions. A general crystallographic rationale is presented to explain the fluorite-to-C-type phase transformation. The approach shown here could be adopted more generally in the analysis of disorder in other highly doped materials.
    Keywords: doped ceriadisorderpair distribution functionhigh-resolution X-ray powder diffractionpercolationhierarchysolid electrolyteselectron spin resonance
    Electronic ISSN: 2052-2525
    Topics: Geosciences , Physics
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  • 3
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    International Union of Crystallography (IUCr)
    In: IUCrJ
    Publication Date: 2015-08-23
    Keywords: doped ceriadisorderpair distribution functionhigh-resolution X-ray powder diffractionpercolationhierarchysolid electrolyteselectron spin resonance
    Electronic ISSN: 2052-2525
    Topics: Geosciences , Physics
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