ALBERT

Beschreibung: Impacts of beaver dams on hydrologic and temperature regimes in a mountain stream Hydrology and Earth System Sciences, 19, 3541-3556, 2015 Author(s): M. Majerova, B. T. Neilson, N. M. Schmadel, J. M. Wheaton, and C. J. Snow Beaver dams affect hydrologic processes, channel complexity, and stream temperature in part by inundating riparian areas, influencing groundwater–surface water interactions, and changing fluvial processes within stream systems. We explored the impacts of beaver dams on hydrologic and temperature regimes at different spatial and temporal scales within a mountain stream in northern Utah over a 3-year period spanning pre- and post-beaver colonization. Using continuous stream discharge, stream temperature, synoptic tracer experiments, and groundwater elevation measurements, we documented pre-beaver conditions in the first year of the study. In the second year, we captured the initial effects of three beaver dams, while the third year included the effects of ten dams. After beaver colonization, reach-scale (~ 750 m in length) discharge observations showed a shift from slightly losing to gaining. However, at the smaller sub-reach scale (ranging from 56 to 185 m in length), the discharge gains and losses increased in variability due to more complex flow pathways with beaver dams forcing overland flow, increasing surface and subsurface storage, and increasing groundwater elevations. At the reach scale, temperatures were found to increase by 0.38 °C (3.8 %), which in part is explained by a 230 % increase in mean reach residence time. At the smallest, beaver dam scale (including upstream ponded area, beaver dam structure, and immediate downstream section), there were notable increases in the thermal heterogeneity where warmer and cooler niches were created. Through the quantification of hydrologic and thermal changes at different spatial and temporal scales, we document increased variability during post-beaver colonization and highlight the need to understand the impacts of beaver dams on stream ecosystems and their potential role in stream restoration.

Beschreibung: Does the Budyko curve reflect a maximum power state of hydrological systems? A backward analysis Hydrology and Earth System Sciences Discussions, 12, 7821-7842, 2015 Author(s): M. Westhoff, E. Zehe, P. Archambeau, and B. Dewals Almost all catchments plot within a small envelope around the Budyko curve. This apparent behaviour suggests that organizing principles may play a role in the evolution of catchments. In this paper we applied the thermodynamic principle of maximum power as the organizing principle. In a top-down approach we derived mathematical formulations of the relation between relative wetness and gradients driving runoff and evaporation for a simple one-box model. We did this in such a way that when the conductances are optimized with the maximum power principle, the steady state behaviour of the model leads exactly to a point on the Budyko curve. Subsequently we derived gradients that, under constant forcing, resulted in a Budyko curve following the asymptotes closely. With these gradients we explored the sensitivity of dry spells and dynamics in actual evaporation. Despite the simplicity of the model, catchment observations compare reasonably well with the Budyko curves derived with dynamics in rainfall and evaporation. This indicates that the maximum power principle may be used (i) to derive the Budyko curve and (ii) to move away from the empiricism in free parameters present in many Budyko functions. Future work should focus on better representing the boundary conditions of real catchments and eventually adding more complexity to the model.

Beschreibung: As internet technologies make their way into developing areas, so too does the possibility of education and training being delivered to the people living in those previously unserved areas. The growing catalogue of free, high quality courseware, when combined with the newly acquired means of delivery, creates the potential for millions of people in the developing world to acquire a good education. Yet a good education obviously requires more than simply delivering information; students must also receive high quality feedback on their assessments. They must be told how their performance compares with the ideal, and be shown how to close the gap between the two. However, delivering high quality feedback is labor-intensive, and therefore expensive, and has long been recognized as a problematic issue by educators. This paper outlines a case study that uses a Learning Management System (LMS) to efficiently deliver detailed feedback that is informed by the principles of best practice. We make the case that the efficiencies of this method allow for large-scale courses with thousands of enrolments that are accessible to developing and developed areas alike. We explore the question; is computer-mediated feedback delivery efficient and effective and might it be applied to large-scale courses at low-cost?

Beschreibung: This paper provides an overview of the main manufacturing technologies of displays, focusing on those with low and ultra-low levels of power consumption, which make them suitable for current societal needs. Considering the typified value obtained from the manufacturer’s specifications, four technologies—Liquid Crystal Displays, electronic paper, Organic Light-Emitting Display and Electroluminescent Displays—were selected in a first iteration. For each of them, several features, including size and brightness, were assessed in order to ascertain possible proportional relationships with the rate of consumption. To normalize the comparison between different display types, relative units such as the surface power density and the display frontal intensity efficiency were proposed. Organic light-emitting display had the best results in terms of power density for small display sizes. For larger sizes, it performs less satisfactorily than Liquid Crystal Displays in terms of energy efficiency.

Beschreibung: Model selection is an integral, yet contentious, component of epidemiologic research. Unfortunately, there remains no consensus on how to identify a single, best model among multiple candidate models. Researchers may be prone to selecting the model that best supports their a priori, preferred result; a phenomenon referred to as “wish bias”. Directed acyclic graphs (DAGs), based on background causal and substantive knowledge, are a useful tool for specifying a subset of adjustment variables to obtain a causal effect estimate. In many cases, however, a DAG will support multiple, sufficient or minimally-sufficient adjustment sets. Even though all of these may theoretically produce unbiased effect estimates they may, in practice, yield somewhat distinct values, and the need to select between these models once again makes the research enterprise vulnerable to wish bias. In this work, we suggest combining adjustment sets with model averaging techniques to obtain causal estimates based on multiple, theoretically-unbiased models. We use three techniques for averaging the results among multiple candidate models: information criteria weighting, inverse variance weighting, and bootstrapping. We illustrate these approaches with an example from the Pregnancy, Infection, and Nutrition (PIN) study. We show that each averaging technique returns similar, model averaged causal estimates. An a priori strategy of model averaging provides a means of integrating uncertainty in selection among candidate, causal models, while also avoiding the temptation to report the most attractive estimate from a suite of equally valid alternatives.

Beschreibung: The widespread, intentional and increasingly frequent chemical emplacement in the troposphere has gone unidentified and unremarked in the scientific literature for years. The author presents evidence that toxic coal combustion fly ash is the most likely aerosolized particulate sprayed by tanker-jets for geoengineering, weather-modification and climate-modification purposes and describes some of the multifold consequences on public health. Two methods are employed: (1) Comparison of 8 elements analyzed in rainwater, leached from aerosolized particulates, with corresponding elements leached into water from coal fly ash in published laboratory experiments, and (2) Comparison of 14 elements analyzed in dust collected outdoors on a high-efficiency particulate air (HEPA) filter with corresponding elements analyzed in un-leached coal fly ash material. The results show: (1) the assemblage of elements in rainwater and in the corresponding experimental leachate are essentially identical. At a 99% confidence interval, they have identical means (T-test) and identical variances (F-test); and (2) the assemblage of elements in the HEPA dust and in the corresponding average un-leached coal fly ash are likewise essentially identical. The consequences on public health are profound, including exposure to a variety of toxic heavy metals, radioactive elements, and neurologically-implicated chemically mobile aluminum released by body moisture in situ after inhalation or through transdermal induction.

Beschreibung: Impacts of land use change and climate variations on annual inflow into Miyun Reservoir, Beijing, China Hydrology and Earth System Sciences Discussions, 12, 7785-7819, 2015 Author(s): J. K. Zheng, G. Sun, W. H. Li, X. X. Yu, C. Zhang, Y. B. Gong, and L. H. Tu Miyun reservoir, the only surface water source for Beijing city, has experienced water supply decline in recent decades. Previous studies suggest that both land use change and climate contributes the changes of water supply in this critical watershed. However, the specific causes of the decline in Miyun reservoir are debatable in a non-stationary climate in the past four decades. The central objective of this study was to quantify the separate and collective contributions of land use change and climate variability to the decreasing inflow into Miyun reservoir during 1961–2008. Different from previous studies, this work objectively identified breakpoints by analyzing the long-term historical hydrometeorology and land cover records. To effectively study the different impacts of the climate variation and land cover change during different sub-periods, annual water balance model (AWB), climate elasticity model (CEM), and rainfall–runoff model (RRM) were employed to conduct attribution analysis synthetically. We found a significant decrease in annual streamflow ( p 〈 0.01), a significant positive trend in annual potential evapotranspiration ( p 〈 0.01), and an insignificant negative trend in annual precipitation ( p 〉 0.1) during 1961–2008. Combined with historical records, we identified two breakpoints as in 1983 and 1999 for the period 1961–2008 by the sequential Mann–Kendall Test and Double Mass Curve. Climate variability alone did not explain the decrease in inflow to Miyun reservoir. Reduction of water yield was closely related to increase in evapotranspiration rates due to the expansion of forestlands and reduction in cropland and grassland, and was likely exacerbated by increased water consumption for domestic and industrial uses in the basin. Our study found that the contribution to the observed streamflow decline from land use change fell from 64–92 % during 1984–1999 to 36–58 % during 2000–2008, whereas the contribution from climate variation climbed from 8–36 % during the 1984–1999 to 42–64 % during 2000–2008. Model uncertainty analysis further demonstrated that climate warming played a dominant role in streamflow reduction in the 2000s. We conclude that future climate change and variability will further challenge the goal of water supply of Miyun reservoir to meet water demand. A comprehensive watershed management strategy needs to consider the climate variations besides vegetation management.

Beschreibung: The impacts of climate change on human health have been documented globally and in the United States. Numerous studies project greater morbidity and mortality as a result of extreme weather events and other climate-sensitive hazards. Public health impacts on the U.S. Gulf Coast may be severe as the region is expected to experience increases in extreme temperatures, sea level rise, and possibly fewer but more intense hurricanes. Through myriad pathways, climate change is likely to make the Gulf Coast less hospitable and more dangerous for its residents, and may prompt substantial migration from and into the region. Public health impacts may be further exacerbated by the concentration of people and infrastructure, as well as the region’s coastal geography. Vulnerable populations, including the very young, elderly, and socioeconomically disadvantaged may face particularly high threats to their health and well-being. This paper provides an overview of potential public health impacts of climate variability and change on the Gulf Coast, with a focus on the region’s unique vulnerabilities, and outlines recommendations for improving the region’s ability to minimize the impacts of climate-sensitive hazards. Public health adaptation aimed at improving individual, public health system, and infrastructure resilience is urgently needed to meet the challenges climate change may pose to the Gulf Coast in the coming decades.

Beschreibung: This study forecasts the liquidity gap in China’s pension scheme for urban workers in the context of an ageing population and the possible effects of recent governmental policies by constructing a basic pension model, including “old people”, “middle people” and “new people” and a simulation method. We find, firstly, that China’s liquidity gap of pension will reach its peak of approximately 13.11 trillion yuan in 2038. Subsequently, this gap will gradually decrease with growth in the mortality rate. Secondly, reasonable intervals for the replacement and contribution rates should be set at [0.417, 0.604] and [0.189, 0.262], respectively, to sustain China’s pension system. Thirdly, compared to increasing fiscal subsidies, an income doubling plan, raising the contribution rate, lowering the replacement rate and delaying the retirement age can significantly reduce the liquidity gap, although the policy costs are relatively high. A policy permitting families to have two children will increase the rate of reduction of the liquidity gap, but it cannot effectively narrow the gap at the peak moment.

Beschreibung: More and more hybrid electric vehicles are driven since they offer such advantages as energy savings and better active safety performance. Hybrid vehicles have two or more power driving systems and frequently switch working condition, so controlling stability is very important. In this work, a two-stage Kalman algorithm method is used to fuse data in hybrid vehicle stability testing. First, the RT3102 navigation system and Dewetron system are introduced. Second, a modeling of data fusion is proposed based on the Kalman filter. Then, this modeling is simulated and tested on a sample vehicle, using Carsim and Simulink software to test the results. The results showed the merits of this modeling.

Beschreibung: Strange VLF bursts in northern Scandinavia: case study of the afternoon "mushroom-like" hiss on 8 December 2013 Annales Geophysicae, 33, 991-995, 2015 Author(s): J. Manninen, N. G. Kleimenova, A. Kozlovsky, I. A. Kornilov, L. I. Gromova, Y. V. Fedorenko, and T. Turunen We investigate a non-typical very low frequency (VLF) 1–4 kHz hiss representing a sequence of separated noise bursts with a strange "mushroom-like" shape in the frequency–time domain, each one lasting several minutes. These strange afternoon VLF emissions were recorded at Kannuslehto (KAN, ϕ = 67.74° N, λ = 26.27° E; L ∼ 5.5) in northern Finland during the late recovery phase of the small magnetic storm on 8 December 2013. The left-hand (LH) polarized 2–3 kHz "mushroom caps" were clearly separated from the right-hand (RH) polarized "mushroom stems" at the frequency of about 1.8–1.9 kHz, which could match the lower ionosphere waveguide cutoff (the first transverse resonance of the Earth–ionosphere cavity). We hypothesize that this VLF burst sequence could be a result of the modulation of the VLF hiss electron–cyclotron instability from the strong Pc5 geomagnetic pulsations observed simultaneously at ground-based stations as well as in the inner magnetosphere by the Time History of Events and Macroscale Interactions during Substorms mission probe (THEMIS-E; ThE). This assumption is confirmed by a similar modulation of the intensity of the energetic (1–10 keV) electrons simultaneously observed by the same ThE spacecraft. In addition, the data of the European Incoherent Scatter Scientific Association (EISCAT) radar at Tromsø show a similar quasi-periodicity in the ratio of the Hall-to-Pedersen conductance, which may be used as a proxy for the energetic particle precipitation enhancement. Our findings suggest that this strange mushroom-like shape of the considered VLF hiss could be a combined mutual effect of the magnetospheric ULF–VLF (ultra low frequency–very low frequency) wave interaction and the ionosphere waveguide propagation.

Beschreibung: Radiative and climate impacts of a large volcanic eruption during stratospheric sulfur geoengineering Atmospheric Chemistry and Physics Discussions, 15, 21837-21881, 2015 Author(s): A. Laakso, H. Kokkola, A.-I. Partanen, U. Niemeier, C. Timmreck, K. E. J. Lehtinen, H. Hakkarainen, and H. Korhonen Both explosive volcanic eruptions, which emit sulfur dioxide into the stratosphere, and stratospheric geoengineering via sulfur injections can potentially cool the climate by increasing the amount of scattering particles in the atmosphere. Here we employ a global aerosol-climate model and an earth system model to study the radiative and climate impacts of an erupting volcano during solar radiation management (SRM). According to our simulations, the radiative impacts of an eruption and SRM are not additive: in the simulated case of concurrent eruption and SRM, the peak increase in global forcing is about 40 % lower compared to a corresponding eruption into a clean background atmosphere. In addition, the recovery of the stratospheric sulfate burden and forcing was significantly faster in the concurrent case since the sulfate particles grew larger and thus sedimented faster from the stratosphere. In our simulation where we assumed that SRM would be stopped immediately after a volcano eruption, stopping SRM decreased the overall stratospheric aerosol load. For the same reasons, a volcanic eruption during SRM lead to only about 1/3 of the peak global ensemble-mean cooling compared to an eruption under unperturbed atmospheric conditions. Furthermore, the global cooling signal was seen only for 12 months after the eruption in the former scenario compared to over 40 months in the latter. In terms of the global precipitation rate, we obtain a 36 % smaller decrease in the first year after the eruption and again a clearly faster recovery in the concurrent eruption and SRM scenario. We also found that an explosive eruption could lead to significantly different regional climate responses depending on whether it takes place during geoengineering or into an unperturbed background atmosphere. Our results imply that observations from previous large eruptions, such as Mt Pinatubo in 1991, are not directly applicable when estimating the potential consequences of a volcanic eruption during stratospheric geoengineering.

Beschreibung: New fire diurnal cycle characterizations to improve fire radiative energy assessments made from MODIS observations Atmospheric Chemistry and Physics, 15, 8831-8846, 2015 Author(s): N. Andela, J. W. Kaiser, G. R. van der Werf, and M. J. Wooster Accurate near real time fire emissions estimates are required for air quality forecasts. To date, most approaches are based on satellite-derived estimates of fire radiative power (FRP), which can be converted to fire radiative energy (FRE) which is directly related to fire emissions. Uncertainties in these FRE estimates are often substantial. This is for a large part because the most often used low-Earth orbit satellite-based instruments such as the Moderate Resolution Imaging Spectroradiometer (MODIS) have a relatively poor sampling of the usually pronounced fire diurnal cycle. In this paper we explore the spatial variation of this fire diurnal cycle and its drivers using data from the geostationary Meteosat Spinning Enhanced Visible and Infrared Imager (SEVIRI). In addition, we sampled data from the SEVIRI instrument at MODIS detection opportunities to develop two approaches to estimate hourly FRE based on MODIS active fire detections. The first approach ignored the fire diurnal cycle, assuming persistent fire activity between two MODIS observations, while the second approach combined knowledge on the climatology of the fire diurnal cycle with active fire detections to estimate hourly FRE. The full SEVIRI time series, providing full coverage of the fire diurnal cycle, were used to evaluate the results. Our study period comprised of 3 years (2010–2012), and we focused on Africa and the Mediterranean basin to avoid the use of potentially lower quality SEVIRI data obtained at very far off-nadir view angles. We found that the fire diurnal cycle varies substantially over the study region, and depends on both fuel and weather conditions. For example, more "intense" fires characterized by a fire diurnal cycle with high peak fire activity, long duration over the day, and with nighttime fire activity are most common in areas of large fire size (i.e., large burned area per fire event). These areas are most prevalent in relatively arid regions. Ignoring the fire diurnal cycle generally resulted in an overestimation of FRE, while including information on the climatology of the fire diurnal cycle improved FRE estimates. The approach based on knowledge of the climatology of the fire diurnal cycle also improved distribution of FRE over the day, although only when aggregating model results to coarser spatial and/or temporal scale good correlation was found with the full SEVIRI hourly reference data set. We recommend the use of regionally varying fire diurnal cycle information within the Global Fire Assimilation System (GFAS) used in the Copernicus Atmosphere Monitoring Services, which will improve FRE estimates and may allow for further reconciliation of biomass burning emission estimates from different inventories.

Beschreibung: The aim of this study was to investigate how atmospheric air pollutants and meteorological conditions affected atmospheric visibility in the largest Polish agglomeration. The correlation analysis, principal component analysis (PCA) and generalized regression models (GRMs) were used to accomplish this objective. The meteorological parameters (temperature, relative humidity, precipitation, wind speed and insolation) and concentrations of the air pollutants (PM10, SO2, NO2, CO and O3) were recorded in 2004–2013. The data came from the Ursynów-SGGW, MzWarszUrsynów and Okęcie monitoring stations, located in the south of Warsaw (Poland). It was shown that the PM10 concentration was the most important parameter affecting the visibility in Warsaw. The concentration, and indirectly the visibility, was mainly affected by the pollutant emission from the flat/building heating (combustion of various fuels). It changed intensively during the research period. There were also periods in which this emission type did not have a great influence on the pollutant concentrations (mainly PM10) and visibility. In such seasons, the research revealed the influence of the traffic emission and secondary aerosol formation processes on the visibility.

Beschreibung: Validation of farm-scale methane emissions using nocturnal boundary layer budgets Atmospheric Chemistry and Physics Discussions, 15, 21765-21802, 2015 Author(s): J. Stieger, I. Bamberger, N. Buchmann, and W. Eugster This study provides the first experimental validation of Swiss agricultural methane emission estimates at the farm scale. We measured CH 4 concentrations at a Swiss farmstead during two intensive field campaigns in August 2011 and July 2012 to (1) quantify the source strength of livestock methane emissions using a tethered balloon system, and (2) to validate inventory emission estimates via nocturnal boundary layer (NBL) budgets. Field measurements were performed at a distance of 150 m from the nearest farm buildings with a tethered balloon system in combination with gradient measurements at eight heights on a 10 m tower to better resolve the near-surface concentrations. Vertical profiles of air temperature, relative humidity, CH 4 concentration, wind speed and wind direction showed that the NBL was strongly influenced by local transport processes and by the valley wind system. Methane concentrations showed a pronounced time course, with highest concentrations in the second half of the night. NBL budget flux estimates were obtained via a time–space kriging approach. Main uncertainties of NBL budget flux estimates were associated with instationary atmospheric conditions and the estimate of the inversion height z i (top of volume integration). The mean NBL budget fluxes of 1.60 ± 0.31 μg CH 4 m -2 s -1 (1.40 ± 0.50 and 1.66 ± 0.20 μg CH 4 m -2 s -1 in 2011 and 2012, respectively) were in good agreement with local inventory estimates based on current livestock number and default emission factors, with 1.29 ± 0.47 and 1.74 ± 0.63 μg CH 4 m -2 s -1 for 2011 and 2012, respectively. This indicates that emission factors used for the national inventory reports are adequate, and we conclude that the NBL budget approach is a useful tool to validate emission inventory estimates.

Beschreibung: New and improved infrared absorption cross sections for dichlorodifluoromethane (CFC-12) Atmospheric Measurement Techniques, 8, 3197-3207, 2015 Author(s): J. J. Harrison Despite its widespread commercial use throughout the twentieth century, primarily in the refrigeration industry, dichlorodifluoromethane (CFC-12) is now known to have the undesirable effect of depleting stratospheric ozone. As this long-lived molecule slowly degrades in the atmosphere, monitoring its vertical concentration profile using infrared sounders on satellite platforms crucially requires accurate laboratory spectroscopic data. This work describes new high-resolution infrared absorption cross sections of dichlorodifluoromethane over the spectral range 800–1270 cm −1 , determined from spectra recorded using a high-resolution Fourier transform spectrometer (Bruker IFS 125HR) and a 26 cm pathlength cell. Spectra of dichlorodifluoromethane/dry synthetic air mixtures were recorded at resolutions between 0.01 and 0.03 cm −1 (calculated as 0.9/MOPD; MOPD = maximum optical path difference) over a range of temperatures and pressures (7.5–761 Torr and 190–294 K) appropriate for atmospheric conditions. This new cross-section dataset improves upon the one currently available in the HITRAN and GEISA databases.

Beschreibung: Seasonality of ultrafine and sub-micron aerosols and the inferences on particle formation processes Atmospheric Chemistry and Physics Discussions, 15, 21803-21835, 2015 Author(s): H. C. Cheung, C. C.-K. Chou, M.-J. Chen, W.-R. Huang, S.-H. Huang, C.-Y. Tsai, and C. S.-L. Lee The aim of this study is to investigate the seasonal variations in the physicochemical properties of atmospheric ultrafine particles (UFPs, d ≤ 100nm) and submicron particles (PM 1 , d ≤ 1 μm) in an East-Asian urban area, which are hypothesized to be affected by the interchange of summer and winter monsoons. An observation experiment was conducted at the TARO, an urban aerosol station in Taipei, Taiwan, from October 2012 to August 2013. The measurements included the mass concentration and chemical composition of UFPs and PM 1 , as well as the particle number concentration (PNC) and size distribution (PSD) with size range of 4–736 nm. The results indicate that the mass concentration of PM 1 was elevated during cold seasons with peak level of 18.5 μg m -3 in spring, whereas the highest UFPs concentration was measured in summertime with a seasonal mean of 1.62 μg m -3 . Moreover, chemical analysis revealed that the UFPs and PM 1 were characterized by distinct composition; UFPs were composed mostly of organics, whereas ammonium and sulfate were the major constituents in PM 1 . The seasonal median of total PNCs ranged from 13.9 × 10 3 cm -3 in autumn to 19.4 × 10 3 cm -3 in spring. The PSD information retrieved from the corresponding PNC measurements indicates that the nucleation mode PNC ( N 4–25 ) peaked at 11.6 × 10 3 cm -3 in winter, whereas the Aitken mode ( N 25–100 ) and accumulation mode ( N 100–736 ) exhibited summer maxima at 6.0 × 10 3 and 3.1 × 10 3 cm -3 , respectively. The shift in PSD during summertime is attributed to the enhancement in the photochemical production of condensable organic matter that, in turn, contributes to the growth of aerosol particles in the atmosphere. In addition, remarkable photochemical production of particles was observed in spring and summer seasons, which was characterized with averaged particle growth and formation rates of 4.3 ± 0.8 nm h -1 and 1.6 ± 0.8 cm -3 s -1 , respectively. The prevalence of new particle formation (NPF) in summer is suggested as a result of seasonally enhanced photochemical oxidation of SO 2 , which contributes to the production of H 2 SO 4 , and low level of PM 10 ( d ≤ 10 μm) that serves as the condensation sink. Regarding the sources of aerosol particles, correlation analysis upon the PNCs against NO x revealed that the local vehicular exhaust was the dominant contributor of the UFPs throughout a year. On the contrary, the Asian pollution outbreaks can have significant influence in the PNC of accumulation mode particles during the seasons of winter monsoons. The results of this study underline the significance of secondary organic aerosols in the seasonal variations of UFPs and the influences of continental pollution outbreaks in the downwind areas of Asian outflows.

Beschreibung: The anthropogenic contribution to atmospheric black carbon concentrations in southern Africa: a WRF-Chem modeling study Atmospheric Chemistry and Physics, 15, 8809-8830, 2015 Author(s): F. Kuik, A. Lauer, J. P. Beukes, P. G. Van Zyl, M. Josipovic, V. Vakkari, L. Laakso, and G. T. Feig South Africa has one of the largest industrialized economies in Africa. Emissions of air pollutants are particularly high in the Johannesburg-Pretoria metropolitan area, the Mpumalanga Highveld and the Vaal Triangle, resulting in local air pollution. This study presents and evaluates a setup for conducting modeling experiments over southern Africa with the Weather Research and Forecasting model including chemistry and aerosols (WRF-Chem), and analyzes the contribution of anthropogenic emissions to the total black carbon (BC) concentrations from September to December 2010. The modeled BC concentrations are compared with measurements obtained at the Welgegund station situated ca. 100 km southwest of Johannesburg. An evaluation of WRF-Chem with observational data from ground-based measurement stations, radiosondes, and satellites shows that the meteorology is modeled mostly reasonably well, but precipitation amounts are widely overestimated and the onset of the wet season is modeled approximately 1 month too early in 2010. Modeled daily mean BC concentrations show a temporal correlation of 0.66 with measurements, but the total BC concentration is underestimated in the model by up to 50 %. Sensitivity studies with anthropogenic emissions of BC and co-emitted species turned off show that anthropogenic sources can contribute up to 100 % to BC concentrations in the industrialized and urban areas, and anthropogenic BC and co-emitted species together can contribute up to 60 % to PM 1 levels. Particularly the co-emitted species contribute significantly to the aerosol optical depth (AOD). Furthermore, in areas of large-scale biomass-burning atmospheric heating rates are increased through absorption by BC up to an altitude of about 600hPa.

Beschreibung: Calibration of 3-D wind measurements on a single-engine research aircraft Atmospheric Measurement Techniques, 8, 3177-3196, 2015 Author(s): C. Mallaun, A. Giez, and R. Baumann An innovative calibration method for the wind speed measurement using a boom-mounted Rosemount model 858 AJ air velocity probe is introduced. The method is demonstrated for a sensor system installed on a medium-size research aircraft which is used for measurements in the atmospheric boundary layer. The method encounters a series of coordinated flight manoeuvres to directly estimate the aerodynamic influences on the probe and to calculate the measurement uncertainties. The introduction of a differential Global Positioning System (DGPS) combined with a high-accuracy inertial reference system (IRS) has brought major advances to airborne measurement techniques. The exact determination of geometrical height allows the use of the pressure signal as an independent parameter. Furthermore, the exact height information and the stepwise calibration process lead to maximum accuracy. The results show a measurement uncertainty for the aerodynamic influence of the dynamic and static pressures of 0.1 hPa. The applied parametrisation does not require any height dependencies or time shifts. After extensive flight tests a correction for the flow angles (attack and sideslip angles) was found, which is necessary for a successful wind calculation. A new method is demonstrated to correct for the aerodynamic influence on the sideslip angle. For the three-dimensional (3-D) wind vector (with 100 Hz resolution) a novel error propagation scheme is tested, which determines the measurement uncertainties to be 0.3 m s −1 for the horizontal and 0.2 m s −1 for the vertical wind components.

Beschreibung: Biomass burning emissions and potential air quality impacts of volatile organic compounds and other trace gases from temperate fuels common in the United States Atmospheric Chemistry and Physics Discussions, 15, 21713-21763, 2015 Author(s): J. B. Gilman, B. M. Lerner, W. C. Kuster, P. D. Goldan, C. Warneke, P. R. Veres, J. M. Roberts, J. A. de Gouw, I. R. Burling, and R. J. Yokelson A comprehensive suite of instruments was used to quantify the emissions of over 200 organic gases, including methane and volatile organic compounds (VOCs), and 9 inorganic gases from 56 laboratory burns of 18 different biomass fuel types common in the southeastern, southwestern, or northern United States. A gas chromatograph-mass spectrometer (GC-MS) provided extensive chemical detail of discrete air samples collected during a laboratory burn and was complemented by real-time measurements of organic and inorganic species via an open-path Fourier transform infrared spectrometer (OP-FTIR) and 3 different chemical ionization-mass spectrometers. These measurements were conducted in February 2009 at the U.S. Department of Agriculture's Fire Sciences Laboratory in Missoula, Montana. The relative magnitude and composition of the gases emitted varied by individual fuel type and, more broadly, by the 3 geographic fuel regions being simulated. Emission ratios relative to carbon monoxide (CO) were used to characterize the composition of gases emitted by mass; reactivity with the hydroxyl radical, OH; and potential secondary organic aerosol (SOA) precursors for the 3 different US fuel regions presented here. VOCs contributed less than 0.78 ± 0.12 % of emissions by mole and less than 0.95 ± 0.07 % of emissions by mass (on average) due to the predominance of CO 2 , CO, CH 4 , and NO x emissions; however, VOCs contributed 70–90 (±16) % to OH reactivity and were the only measured gas-phase source of SOA precursors from combustion of biomass. Over 82 % of the VOC emissions by mole were unsaturated compounds including highly reactive alkenes and aromatics and photolabile oxygenated VOCs (OVOCs) such as formaldehyde. OVOCs contributed 57–68 % of the VOC mass emitted, 42–57 % of VOC-OH reactivity, and aromatic-OVOCs such as benzenediols, phenols, and benzaldehyde were the dominant potential SOA precursors. In addition, ambient air measurements of emissions from the Fourmile Canyon Fire that affected Boulder, Colorado in September 2010 allowed us to investigate biomass burning (BB) emissions in the presence of other VOC sources (i.e., urban and biogenic emissions) and identify several promising BB markers including benzofuran, 2-furaldehyde, 2-methylfuran, furan, and benzonitrile.

Beschreibung: Stable isotope study of a new chondrichthyan fauna (Kimmeridgian, Porrentruy, Swiss Jura): an unusual freshwater-influenced isotopic composition for the hybodont shark Asteracanthus Biogeosciences Discussions, 12, 12899-12921, 2015 Author(s): L. Leuzinger, L. Kocsis, J.-P. Billon-Bruyat, S. Spezzaferri, and T. Vennemann Chondrichthyan teeth (sharks, rays and chimaeras) are mineralised in isotopic equilibrium with the surrounding water, and parameters such as water temperature and salinity can be inferred from the oxygen isotopic composition (δ 18 O p ) of their bioapatite. We analysed a new chondrichthyan assemblage, as well as teeth from bony fish (Pycnodontiformes). All specimens are from Kimmeridgian coastal marine deposits of the Swiss Jura (vicinity of Porrentruy, Ajoie district, NW Switzerland). While the overall faunal composition and the isotopic composition of bony fish are consistent with marine conditions, unusually low δ 18 O p values were measured for the hybodont shark Asteracanthus . These values are also lower compared to previously published data from older European Jurassic localities. Additional analyses on material from Solothurn (Kimmeridgian, NW Switzerland) also have comparable, low- 18 O isotopic compositions for Asteracanthus . The data are hence interpreted to represent a so far unique, freshwater-influenced isotopic composition for this shark that is classically considered as a marine genus. While reproduction in freshwater or brackish realms is established for other hybodonts, a similar behaviour for Asteracanthus is proposed here. Regular excursions into lower salinity waters can be linked to the age of the deposits and correspond to an ecological adaptation, most likely driven by the Kimmeridgian transgression and by the competition of the primitive shark Asteracanthus with the rapidly diversifying neoselachians (modern sharks).

Beschreibung: Climate change impacts on net primary production (NPP) and export production (EP) regulated by increasing stratification and phytoplankton community structure in CMIP5 models Biogeosciences Discussions, 12, 12851-12897, 2015 Author(s): W. Fu, J. Randerson, and J. K. Moore We examine climate change impacts on net primary production (NPP) and export production (sinking particulate flux; EP) with simulations from nine Earth System Models (ESMs) performed in the framework of the fifth Coupled Model Inter-comparison Project (CMIP5). Global NPP and EP are reduced considerably by the end of the century for the intense warming scenario of Representative Concentration Pathway (RCP) 8.5. Relative to the 1990s, global NPP in the 2090s is reduced by 2.3–16 % and EP by 7–18 %. The models with the largest increases in stratification (and largest relative reductions in NPP and EP) also show the largest positive biases in stratification for the contemporary period, suggesting some potential overestimation of climate impacts on NPP and EP. All of the CMIP5 models show an increase in stratification in response to surface ocean warming and freshening that is accompanied by decreases in NPP, EP, and surface macronutrient concentrations. There is considerable variability across models in the absolute magnitude of these fluxes, surface nutrient concentrations, and their perturbations by climate change, indicating large model uncertainties. The negative response of NPP and EP to stratification increases reflects a bottom-up control, as nutrient flux to the euphotic zone declines. Models with dynamic phytoplankton community structure show larger declines in EP than in NPP. This is driven by phytoplankton community composition shifts, with a reduced percentage of NPP by large phytoplankton under RCP 8.5, as smaller phytoplankton are favored under the increasing nutrient stress. Thus, projections of the NPP response to climate change in the CMIP5 models are critically dependent on the simulated phytoplankton community structure, the efficiency of the biological pump, and the resulting (highly variable) levels of regenerated production. Community composition is represented relatively simply in the CMIP5 models, and should be expanded to better capture the spatial patterns and the changes in export efficiency that are necessary for predicting climate impacts on NPP.

Beschreibung: Aquatic vegetation serves many important ecological and socioeconomic functions in lake ecosystems. The presence of floating algae poses difficulties for accurately estimating the distribution of aquatic vegetation in eutrophic lakes. We present an approach to map the distribution of aquatic vegetation in Lake Taihu (a large, shallow eutrophic lake in China) and reduce the influence of floating algae on aquatic vegetation mapping. Our approach involved a frequency analysis over a 2003–2013 time series of the floating algal index (FAI) based on moderate-resolution imaging spectroradiometer (MODIS) data. Three phenological periods were defined based on the vegetation presence frequency (VPF) and the growth of algae and aquatic vegetation: December and January composed the period of wintering aquatic vegetation; February and March composed the period of prolonged coexistence of algal blooms and wintering aquatic vegetation; and June to October was the peak period of the coexistence of algal blooms and aquatic vegetation. By comparing and analyzing the satellite-derived aquatic vegetation distribution and 244 in situ measurements made in 2013, we established a FAI threshold of −0.025 and VPF thresholds of 0.55, 0.45 and 0.85 for the three phenological periods. We validated the accuracy of our approach by comparing the results between the satellite-derived maps and the in situ results obtained from 2008–2012. The overall classification accuracy was 87%, 81%, 77%, 88% and 73% in the five years from 2008–2012, respectively. We then applied the approach to the MODIS images from 2003–2013 and obtained the total area of the aquatic vegetation, which varied from 265.94 km2 in 2007 to 503.38 km2 in 2008, with an average area of 359.62 ± 69.20 km2 over the 11 years. Our findings suggest that (1) the proposed approach can be used to map the distribution of aquatic vegetation in eutrophic algae-rich waters and (2) dramatic changes occurred in the distribution of aquatic vegetation in Lake Taihu during the 11-year study.

Beschreibung: Diffuse Correlation Spectroscopy (DCS) is a well-established optical technique that has been used for non-invasive measurement of blood flow in tissues. Instrumentation for DCS includes a correlation device that computes the temporal intensity autocorrelation of a coherent laser source after it has undergone diffuse scattering through a turbid medium. Typically, the signal acquisition and its autocorrelation are performed by a correlation board. These boards have dedicated hardware to acquire and compute intensity autocorrelations of rapidly varying input signal and usually are quite expensive. Here we show that a Raspberry Pi minicomputer can acquire and store a rapidly varying time-signal with high fidelity. We show that this signal collected by a Raspberry Pi device can be processed numerically to yield intensity autocorrelations well suited for DCS applications. DCS measurements made using the Raspberry Pi device were compared to those acquired using a commercial hardware autocorrelation board to investigate the stability, performance, and accuracy of the data acquired in controlled experiments. This paper represents a first step toward lowering the instrumentation cost of a DCS system and may offer the potential to make DCS become more widely used in biomedical applications.

Beschreibung: Wind tunnels are a key experimental tool for the analysis of airflow parameters in many fields of application. Despite their great potential impact on agricultural research, few contributions have dealt with the development of automatic control systems for wind tunnels in the field of greenhouse technology. The objective of this paper is to present an automatic control system that provides precision and speed of measurement, as well as efficient data processing in low-speed wind tunnel experiments for greenhouse engineering applications. The system is based on an algorithm that identifies the system model and calculates the optimum PI controller. The validation of the system was performed on a cellulose evaporative cooling pad and on insect-proof screens to assess its response to perturbations. The control system provided an accuracy of 〈0.06 m·s‾1 for airflow speed and 〈0.50 Pa for pressure drop, thus permitting the reproducibility and standardization of the tests. The proposed control system also incorporates a fully-integrated software unit that manages the tests in terms of airflow speed and pressure drop set points.

Beschreibung: A new application of utilizing ultra-wideband (UWB) technology to sense wind turbine blade deflections is introduced in this paper for wind energy cost reduction. The lower UWB band of 3.1–5.3 GHz is applied. On each blade, there will be one UWB blade deflection sensing system, which consists of two UWB antennas at the blade root and one UWB antenna at the blade tip. The detailed topology and challenges of this deflection sensing system are addressed. Due to the complexity of the problem, this paper will first realize the on-blade UWB radio link in the simplest case, where the tip antenna is situated outside (and on the surface of) a blade tip. To investigate this case, full-blade time-domain measurements are designed and conducted under different deflections. The detailed measurement setups and results are provided. If the root and tip antenna locations are properly selected, the first pulse is always of sufficient quality for accurate estimations under different deflections. The measured results reveal that the blade tip-root distance and blade deflection can be accurately estimated in the complicated and lossy wireless channels around a wind turbine blade. Some future research topics on this application are listed finally.

Beschreibung: A method for measuring shaft diameters is presented using structured light vision measurement. After calibrating a model of the structured light measurement, a virtual plane is established perpendicular to the measured shaft axis and the image of the light stripe on the shaft is projected to the virtual plane. On the virtual plane, the center of the measured shaft is determined by fitting the projected image under the geometrical constraints of the light stripe, and the shaft diameter is measured by the determined center and the projected image. Experiments evaluated the measuring accuracy of the method and the effects of some factors on the measurement are analyzed.

Beschreibung: Understanding the relationship between land use and surface water quality is necessary for effective water management. We estimated the impacts of catchment-wide land use on water quality during the dry and rainy seasons in the Dongjiang River basin, using remote sensing, geographic information systems and multivariate statistical techniques. The results showed that the 83 sites can be divided into three groups representing different land use types: forest, agriculture and urban. Water quality parameters exhibited significant variations between the urban-dominated and forest-dominated sites. The proportion of forested land was positively associated with dissolved oxygen concentration but negatively associated with water temperature, electrical conductivity, permanganate index, total phosphorus, total nitrogen, ammonia nitrogen, nitrate nitrogen and chlorophyll-a. The proportion of urban land was strongly positively associated with total nitrogen and ammonia nitrogen concentrations. Forested and urban land use had stronger impacts on water quality in the dry season than in the rainy season. However, agricultural land use did not have a significant impact on water quality. Our study indicates that urban land use was the key factor affecting water quality change, and limiting point-source waste discharge in urban areas during the dry season would be critical for improving water quality in the study area.

Beschreibung: The morphological properties of kaolin flocs were investigated in a Couette-flow experiment at the steady state under seven shear flow conditions (shear rates of 5.36, 9.17, 14, 24, 31, 41 and 53 s−1). These properties include a one-dimensional (1-D) fractal dimension (D1), a two-dimensional (2-D) fractal dimension (D2), a perimeter-based fractal dimension (Dpf) and an aspect ratio (AR). They were calculated based on the projected area (A), equivalent size, perimeter (P) and length (L) of the major axis of the floc determined through sample observation and an image analysis system. The parameter D2, which characterizes the relationship between the projected area and the length of the major axis using a power function, , increased from 1.73 ± 0.03, 1.72 ± 0.03, and 1.75 ± 0.04 in the low shear rate group (G = 5.36, 9.17, and 14 s−1) to 1.92 ± 0.03, 1.82 ± 0.02, 1.85 ± 0.02, and 1.81 ± 0.02 in the high shear rate group (24, 31, 41 and 53 s−1), respectively. The parameter D1 characterizes the relationship between the perimeter and length of the major axis by the function  and decreased from 1.52 ± 0.02, 1.48 ± 0.02, 1.55 ± 0.02, and 1.63 ± 0.02 in the low shear group (5.36, 9.17, 14 and 24 s−1) to 1.45 ± 0.02, 1.39 ± 0.02, and 1.39 ± 0.02 in the high shear group (31, 41 and 53 s−1), respectively. The results indicate that with increasing shear rates, the flocs become less elongated and that their boundary lines become tighter and more regular, caused by more breakages and possible restructurings of the flocs. The parameter Dpf, which is related to the perimeter and the projected area through the function , decreased as the shear rate increased almost linearly. The parameter AR, which is the ratio of the length of the major axis and equivalent diameter, decreased from 1.56, 1.59, 1.53 and 1.51 in the low shear rate group to 1.43, 1.47 and 1.48 in the high shear rate group. These changes in Dpf and AR show that the flocs become less convoluted and more symmetrical and that their boundaries become smoother and more regular in the high shear rate group than in the low shear rate group due to breakage and possible restructuring processes. To assess the effects of electrolyte and sediment concentration, 0.1 mol/L calcium chloride (CaCl2) and initial sediment concentration from 7.87 × 10−5 to 1.57 × 10−5 were used in this preliminary study. The addition of electrolyte and increasing sediment concentration could produce more symmetrical flocs with less convoluted and simpler boundaries. In addition, some new information on the temporal variation of the median size of the flocs during the flocculation process is presented.

Beschreibung: Examining the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol formation during the 2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee ground site Atmospheric Chemistry and Physics, 15, 8871-8888, 2015 Author(s): S. H. Budisulistiorini, X. Li, S. T. Bairai, J. Renfro, Y. Liu, Y. J. Liu, K. A. McKinney, S. T. Martin, V. F. McNeill, H. O. T. Pye, A. Nenes, M. E. Neff, E. A. Stone, S. Mueller, C. Knote, S. L. Shaw, Z. Zhang, A. Gold, and J. D. Surratt A suite of offline and real-time gas- and particle-phase measurements was deployed at Look Rock, Tennessee (TN), during the 2013 Southern Oxidant and Aerosol Study (SOAS) to examine the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol (SOA) formation. High- and low-time-resolution PM 2.5 samples were collected for analysis of known tracer compounds in isoprene-derived SOA by gas chromatography/electron ionization-mass spectrometry (GC/EI-MS) and ultra performance liquid chromatography/diode array detection-electrospray ionization-high-resolution quadrupole time-of-flight mass spectrometry (UPLC/DAD-ESI-HR-QTOFMS). Source apportionment of the organic aerosol (OA) was determined by positive matrix factorization (PMF) analysis of mass spectrometric data acquired on an Aerodyne Aerosol Chemical Speciation Monitor (ACSM). Campaign average mass concentrations of the sum of quantified isoprene-derived SOA tracers contributed to ~ 9 % (up to 28 %) of the total OA mass, with isoprene-epoxydiol (IEPOX) chemistry accounting for ~ 97 % of the quantified tracers. PMF analysis resolved a factor with a profile similar to the IEPOX-OA factor resolved in an Atlanta study and was therefore designated IEPOX-OA. This factor was strongly correlated ( r 2 〉 0.7) with 2-methyltetrols, C 5 -alkene triols, IEPOX-derived organosulfates, and dimers of organosulfates, confirming the role of IEPOX chemistry as the source. On average, IEPOX-derived SOA tracer mass was ~ 26 % (up to 49 %) of the IEPOX-OA factor mass, which accounted for 32 % of the total OA. A low-volatility oxygenated organic aerosol (LV-OOA) and an oxidized factor with a profile similar to 91Fac observed in areas where emissions are biogenic-dominated were also resolved by PMF analysis, whereas no primary organic aerosol (POA) sources could be resolved. These findings were consistent with low levels of primary pollutants, such as nitric oxide (NO ~ 0.03 ppb), carbon monoxide (CO ~ 116 ppb), and black carbon (BC ~ 0.2 μg m −3 ). Particle-phase sulfate is fairly correlated ( r 2 ~ 0.3) with both methacrylic acid epoxide (MAE)/hydroxymethyl-methyl-α-lactone (HMML)- (henceforth called methacrolein (MACR)-derived SOA tracers) and IEPOX-derived SOA tracers, and more strongly correlated ( r 2 ~ 0.6) with the IEPOX-OA factor, in sum suggesting an important role of sulfate in isoprene SOA formation. Moderate correlation between the MACR-derived SOA tracer 2-methylglyceric acid with sum of reactive and reservoir nitrogen oxides (NO y ; r 2 = 0.38) and nitrate ( r 2 = 0.45) indicates the potential influence of anthropogenic emissions through long-range transport. Despite the lack of a clear association of IEPOX-OA with locally estimated aerosol acidity and liquid water content (LWC), box model calculations of IEPOX uptake using the simpleGAMMA model, accounting for the role of acidity and aerosol water, predicted the abundance of the IEPOX-derived SOA tracers 2-methyltetrols and the corresponding sulfates with good accuracy ( r 2 ~ 0.5 and ~ 0.7, respectively). The modeling and data combined suggest an anthropogenic influence on isoprene-derived SOA formation through acid-catalyzed heterogeneous chemistry of IEPOX in the southeastern US. However, it appears that this process was not limited by aerosol acidity or LWC at Look Rock during SOAS. Future studies should further explore the extent to which acidity and LWC as well as aerosol viscosity and morphology becomes a limiting factor of IEPOX-derived SOA, and their modulation by anthropogenic emissions.

Beschreibung: Real-time measurements of secondary organic aerosol formation and aging from ambient air in an oxidation flow reactor in the Los Angeles area Atmospheric Chemistry and Physics Discussions, 15, 21907-21958, 2015 Author(s): A. M. Ortega, P. L. Hayes, Z. Peng, B. B. Palm, W. Hu, D. A. Day, R. Li, M. J. Cubison, W. H. Brune, M. Graus, C. Warneke, J. B. Gilman, W. C. Kuster, J. A. de Gouw, and J. L. Jimenez Field studies in polluted areas over the last decade have observed large formation of secondary organic aerosol (SOA) that is often poorly captured by models. The study of SOA formation using ambient data is often confounded by the effects of advection, vertical mixing, emissions, and variable degrees of photochemical aging. An Oxidation Flow Reactor (OFR) was deployed to study SOA formation in real-time during the CalNex campaign in Pasadena, CA, in 2010. A high-resolution aerosol mass spectrometer (AMS) and a scanning mobility particle sizer (SMPS) alternated sampling ambient and reactor-aged air. The reactor produced OH concentrations up to 4 orders of magnitude higher than in ambient air, achieving equivalent atmospheric aging from hours up to several weeks in 3 min of processing. OH radical concentration was continuously stepped, obtaining measurements of real-time SOA formation and oxidation at multiple equivalent ages from 0.8 days–6.4 weeks. Enhancement of OA from aging showed a maximum net SOA production between 0.8–6 days of aging with net OA mass loss beyond 2 weeks. Reactor SOA mass peaked at night, in the absence of ambient photochemistry, and correlated with trimethylbenzene concentrations. Reactor SOA formation was inversely correlated with ambient SOA and O x , which along with the short-lived VOC correlation, indicates the importance of relatively reactive (τ OH ∼ 0.3 day) SOA precursors in the LA-Basin. Evolution of the elemental composition in the reactor was similar to trends observed in the atmosphere (O : C vs. H : C slope ∼ -0.65). Oxidation state of carbon (OS C ) in reactor SOA increased steeply with age and remained elevated (OS C ∼ 2) at the highest photochemical ages probed. The ratio of OA in the reactor output to excess CO (ΔCO, ambient CO above regional background) vs. photochemical age is similar to previous studies at low to moderate ages and also extends to higher ages where OA loss dominates. The mass added at low-to-intermediate ages is due primarily to condensation of oxidized species, not heterogeneous oxidation. The OA decrease at high photochemical ages is dominated by heterogeneous oxidation followed by fragmentation/evaporation. A comparison of urban SOA formation in this study with a similar study of vehicle SOA in a tunnel supports the dominance of vehicle emissions in urban SOA. Pre-2007 SOA models underpredict SOA formation by an order of magnitude, while a more recent model performs better but overpredicts at higher ages. These results demonstrate the value of the reactor as a tool for in situ evaluation of the SOA formation potential and OA evolution from ambient air.

Beschreibung: On the consistency of 2-D video disdrometers in measuring microphysical parameters of solid precipitation Atmospheric Measurement Techniques, 8, 3251-3261, 2015 Author(s): F. Bernauer, K. Hürkamp, W. Rühm, and J. Tschiersch Detailed characterization and classification of precipitation is an important task in atmospheric research. Line scanning 2-D video disdrometer devices are well established for rain observations. The two orthogonal views taken of each hydrometeor passing the sensitive area of the instrument qualify these devices especially for detailed characterization of nonsymmetric solid hydrometeors. However, in case of solid precipitation, problems related to the matching algorithm have to be considered and the user must be aware of the limited spatial resolution when size and shape descriptors are analyzed. Clarifying the potential of 2-D video disdrometers in deriving size, velocity and shape parameters from single recorded pictures is the aim of this work. The need of implementing a matching algorithm suitable for mixed- and solid-phase precipitation is highlighted as an essential step in data evaluation. For this purpose simple reproducible experiments with solid steel spheres and irregularly shaped Styrofoam particles are conducted. Self-consistency of shape parameter measurements is tested in 38 cases of real snowfall. As a result, it was found that reliable size and shape characterization with a relative standard deviation of less than 5 % is only possible for particles larger than 1 mm. For particles between 0.5 and 1.0 mm the relative standard deviation can grow up to 22 % for the volume, 17 % for size parameters and 14 % for shape descriptors. Testing the adapted matching algorithm with a reproducible experiment with Styrofoam particles, a mismatch probability of less than 3 % was found. For shape parameter measurements in case of real solid-phase precipitation, the 2-DVD shows self-consistent behavior.

Beschreibung: Schneefernerhaus as a mountain research station for clouds and turbulence Atmospheric Measurement Techniques, 8, 3209-3218, 2015 Author(s): S. Risius, H. Xu, F. Di Lorenzo, H. Xi, H. Siebert, R. A. Shaw, and E. Bodenschatz Cloud measurements are usually carried out with airborne campaigns, which are expensive and are limited by temporal duration and weather conditions. Ground-based measurements at high-altitude research stations therefore play a complementary role in cloud study. Using the meteorological data (wind speed, direction, temperature, humidity, visibility, etc.) collected by the German Weather Service (DWD) from 2000 to 2012 and turbulence measurements recorded by multiple ultrasonic sensors (sampled at 10 Hz) in 2010, we show that the Umweltforschungsstation Schneefernerhaus (UFS) located just below the peak of Zugspitze in the German Alps, at a height of 2650 m, is a well-suited station for cloud–turbulence research. The wind at UFS is dominantly in the east–west direction and nearly horizontal. During the summertime (July and August) the UFS is immersed in warm clouds about 25 % of the time. The clouds are either from convection originating in the valley in the east, or associated with synoptic-scale weather systems typically advected from the west. Air turbulence, as measured from the second- and third-order velocity structure functions that exhibit well-developed inertial ranges, possesses Taylor microscale Reynolds numbers up to 10 4 , with the most probable value at ~ 3000. In spite of the complex topography, the turbulence appears to be nearly as isotropic as many laboratory flows when evaluated on the "Lumley triangle".

Beschreibung: Technical Note: A simple calculation algorithm to separate high-resolution CH 4 flux measurements into ebullition and diffusion-derived components Biogeosciences Discussions, 12, 12923-12945, 2015 Author(s): M. Hoffmann, M. Schulz-Hanke, J. Garcia Alba, N. Jurisch, U. Hagemann, T. Sachs, M. Sommer, and J. Augustin Processes driving the production, transformation and transport of methane (CH 4 ) in wetland ecosystems are highly complex. Thus, serious challenges are constitutes in terms of the mechanistic process understanding, the identification of potential environmental drivers and the calculation of reliable CH 4 emission estimates. We present a simple calculation algorithm to separate open-water CH 4 fluxes measured with automatic chambers into diffusion- and ebullition-derived components, which helps facilitating the identification of underlying dynamics and potential environmental drivers. Flux separation is based on ebullition related sudden concentration changes during single measurements. A variable ebullition filter is applied, using the lower and upper quartile and the interquartile range (IQR). Automation of data processing is achieved by using an established R-script, adjusted for the purpose of CH 4 flux calculation. The algorithm was tested using flux measurement data (July to September 2013) from a former fen grassland site, converted into a shallow lake as a result of rewetting ebullition and diffusion contributed 46 and 55 %, respectively, to total CH 4 emissions, which is comparable to those previously reported by literature. Moreover, the separation algorithm revealed a concealed shift in the diurnal trend of diffusive fluxes throughout the measurement period.

Beschreibung: Plume-based analysis of vehicle fleet air pollutant emissions and the contribution from high emitters Atmospheric Measurement Techniques, 8, 3263-3275, 2015 Author(s): J. M. Wang, C.-H. Jeong, N. Zimmerman, R. M. Healy, D. K. Wang, F. Ke, and G. J. Evans An automated identification and integration method has been developed for in-use vehicle emissions under real-world conditions. This technique was applied to high-time-resolution air pollutant measurements of in-use vehicle emissions performed under real-world conditions at a near-road monitoring station in Toronto, Canada, during four seasons, through month-long campaigns in 2013–2014. Based on carbon dioxide measurements, over 100 000 vehicle-related plumes were automatically identified and fuel-based emission factors for nitrogen oxides; carbon monoxide; particle number; black carbon; benzene, toluene, ethylbenzene, and xylenes (BTEX); and methanol were determined for each plume. Thus the automated identification enabled the measurement of an unprecedented number of plumes and pollutants over an extended duration. Emission factors for volatile organic compounds were also measured roadside for the first time using a proton transfer reaction time-of-flight mass spectrometer; this instrument provided the time resolution required for the plume capture technique. Mean emission factors were characteristic of the light-duty gasoline-dominated vehicle fleet present at the measurement site, with mean black carbon and particle number emission factors of 35 mg kg fuel −1 and 7.5 × 10 14 # kg fuel −1 , respectively. The use of the plume-by-plume analysis enabled isolation of vehicle emissions, and the elucidation of co-emitted pollutants from similar vehicle types, variability of emissions across the fleet, and the relative contribution from heavy emitters. It was found that a small proportion of the fleet ( 〈 25 %) contributed significantly to total fleet emissions: 100, 100, 81, and 77 % for black carbon, carbon monoxide, BTEX, and particle number, respectively. Emission factors of a single pollutant may help classify a vehicle as a high emitter; however, regulatory strategies to more efficiently target multi-pollutant mixtures may be better developed by considering the co-emitted pollutants as well.

Beschreibung: High-resolution measurement of cloud microphysics and turbulence at a mountaintop station Atmospheric Measurement Techniques, 8, 3219-3228, 2015 Author(s): H. Siebert, R. A. Shaw, J. Ditas, T. Schmeissner, S. P. Malinowski, E. Bodenschatz, and H. Xu Mountain research stations are advantageous not only for long-term sampling of cloud properties but also for measurements that are prohibitively difficult to perform on airborne platforms due to the large true air speed or adverse factors such as weight and complexity of the equipment necessary. Some cloud–turbulence measurements, especially Lagrangian in nature, fall into this category. We report results from simultaneous, high-resolution and collocated measurements of cloud microphysical and turbulence properties during several warm cloud events at the Umweltforschungsstation Schneefernerhaus (UFS) on Zugspitze in the German Alps. The data gathered were found to be representative of observations made with similar instrumentation in free clouds. The observed turbulence shared all features known for high-Reynolds-number flows: it exhibited approximately Gaussian fluctuations for all three velocity components, a clearly defined inertial subrange following Kolmogorov scaling (power spectrum, and second- and third-order Eulerian structure functions), and highly intermittent velocity gradients, as well as approximately lognormal kinetic energy dissipation rates. The clouds were observed to have liquid water contents on the order of 1 g m −3 and size distributions typical of continental clouds, sometimes exhibiting long positive tails indicative of large drop production through turbulent mixing or coalescence growth. Dimensionless parameters relevant to cloud–turbulence interactions, the Stokes number and settling parameter are in the range typically observed in atmospheric clouds. Observed fluctuations in droplet number concentration and diameter suggest a preference for inhomogeneous mixing. Finally, enhanced variance in liquid water content fluctuations is observed at high frequencies, and the scale break occurs at a value consistent with the independently estimated phase relaxation time from microphysical measurements.

Beschreibung: An adsorption theory of heterogeneous nucleation of water vapour on nanoparticles Atmospheric Chemistry and Physics Discussions, 15, 21883-21906, 2015 Author(s): A. Laaksonen and J. Malila Heterogeneous nucleation of water vapour on insoluble nuclei is a phenomenon that can induce atmospheric water and ice cloud formation. However, modelling of the phenomenon is hampered by the fact that the predictive capability of the classical heterogeneous nucleation theory is rather poor. A reliable theoretical description of the influence of different types of water-insoluble nuclei in triggering the water condensation or ice deposition would help to decrease uncertainty in large scale model simulations. In this paper we extend a recently formulated adsorption theory of heterogeneous nucleation to be applicable to highly curved surfaces, and test the theory against laboratory data for water vapour nucleation on silica, titanium dioxide and silver oxide nanoparticles. We show that unlike the classical heterogeneous nucleation theory, the new theory is able to quantitatively predict the experimental results.

Beschreibung: High-resolution daily gridded datasets of air temperature and wind speed for Europe Earth System Science Data Discussions, 8, 649-702, 2015 Author(s): S. Brinckmann, S. Krähenmann, and P. Bissolli New high-resolution datasets for near surface daily air temperature (minimum, maximum and mean) and daily mean wind speed for Europe (the CORDEX domain) are provided for the period 2001–2010 for the purpose of regional model validation in the framework of DecReg, a sub-project of the German MiKlip project, which aims to develop decadal climate predictions. The main input data sources are hourly SYNOP observations, partly supplemented by station data from the ECA&D dataset ( http://www.ecad.eu ). These data are quality tested to eliminate erroneous data and various kinds of inhomogeneities. Grids in a resolution of 0.044° (5 km) are derived by spatial interpolation of these station data into the CORDEX area. For temperature interpolation a modified version of a regression kriging method developed by Krähenmann et al. (2011) is used. At first, predictor fields of altitude, continentality and zonal mean temperature are chosen for a regression applied to monthly station data. The residuals of the monthly regression and the deviations of the daily data from the monthly averages are interpolated using simple kriging in a second and third step. For wind speed a new method based on the concept used for temperature was developed, involving predictor fields of exposure, roughness length, coastal distance and ERA Interim reanalysis wind speed at 850 hPa. Interpolation uncertainty is estimated by means of the kriging variance and regression uncertainties. Furthermore, to assess the quality of the final daily grid data, cross validation is performed. Explained variance ranges from 70 to 90 % for monthly temperature and from 50 to 60 % for monthly wind speed. The resulting RMSE for the final daily grid data amounts to 1–2 °C and 1–1.5 m s −1 (depending on season and parameter) for daily temperature parameters and daily mean wind speed, respectively. The datasets presented in this article are published at http://dx.doi.org/10.5676/DWD_CDC/DECREG0110v1 .

Beschreibung: Storm-triggered landslides in the Peruvian Andes and implications for topography, carbon cycles, and biodiversity Earth Surface Dynamics Discussions, 3, 631-688, 2015 Author(s): K. E. Clark, A. J. West, R. G. Hilton, G. P. Asner, C. A. Quesada, M. R. Silman, S. S. Saatchi, W. Farfan-Rios, R. E. Martin, A. B. Horwath, K. Halladay, M. New, and Y. Malhi In this study, we assess the geomorphic role of a rare, large-magnitude landslide event and consider the effect of this event on mountain forest ecosystems and the erosion of organic carbon in an Andean river catchment. Proximal triggers such as large rain storms are known to cause large numbers of landslides, but the relative effects of such low-frequency, high-magnitude events are not well known in the context of more regular, smaller events. We develop a 25 year duration, annual-resolution landslide inventory by mapping landslide occurrence in the Kosñipata Valley, Peru, from 1988 to 2012 using Landsat, Quickbird and Worldview satellite images. Catchment-wide landslide rates were high, at 0.076 % yr −1 by area, indicating landslides may completely turn over hillslopes every ~ 1320 years and strip 28 tC km −2 yr −1 of soil (73 %) and vegetation (27 %). A single rain storm in March 2010 accounted for 27 % of all landslide area observed during the 25 year study and removed 26 % of the organic carbon that was stripped from hillslopes by all landslides during the study. An approximately linear magnitude–frequency relationship for annual landslide areas suggests that large storms contribute an equivalent landslide failure area to the sum of smaller frequency landslides events occurring over the same period. However, the spatial distribution of landslides associated with the 2010 storm is distinct. On the basis of precipitation statistics and landscape morphology, we hypothesize that spatial focusing of storm-triggered landslide erosion at lower elevations in the Kosñipata catchment may be characteristic of longer-term patterns. These patterns may have implications for the source and composition of sediments and organic material supplied to river systems of the Amazon basin, and, through focusing of regular ecological disturbance, for the species composition of forested ecosystems in the region.

Beschreibung: A Late Pleistocene sea level stack Climate of the Past Discussions, 11, 3699-3728, 2015 Author(s): R. M. Spratt and L. E. Lisiecki Late Pleistocene sea level has been reconstructed from ocean sediment core data using a wide variety of proxies and models. However, the accuracy of individual reconstructions is limited by measurement error, local variations in salinity and temperature, and assumptions particular to each technique. Here we present a sea level stack (average) which increases the signal-to-noise ratio of individual reconstructions. Specifically, we perform principal component analysis (PCA) on seven records from 0–430 ka and five records from 0–798 ka. The first principal component, which we use as the stack, describes ~80 % of the variance in the data and is similar using either five or seven records. After scaling the stack based on Holocene and Last Glacial Maximum (LGM) sea level estimates, the stack agrees to within 5 m with isostatically adjusted coral sea level estimates for Marine Isotope Stages 5e and 11 (125 and 400 ka, respectively). When we compare the sea level stack with the δ 18 O of benthic foraminifera, we find that sea level change accounts for about ~40 % of the total orbital-band variance in benthic δ 18 O, compared to a 65 % contribution during the LGM-to-Holocene transition. Additionally, the second and third principal components of our analyses reflect differences between proxy records associated with spatial variations in the δ 18 O of seawater.

Beschreibung: Accurate state of charge (SoC) estimation of batteries plays an important role in promoting the commercialization of electric vehicles. The main work to be done in accurately determining battery SoC can be summarized in three parts. (1) In view of the model-based SoC estimation flow diagram, the n-order resistance-capacitance (RC) battery model is proposed and expected to accurately simulate the battery’s major time-variable, nonlinear characteristics. Then, the mathematical equations for model parameter identification and SoC estimation of this model are constructed. (2) The Akaike information criterion is used to determine an optimal tradeoff between battery model complexity and prediction precision for the n-order RC battery model. Results from a comparative analysis show that the first-order RC battery model is thought to be the best based on the Akaike information criterion (AIC) values. (3) The real-time joint estimator for the model parameter and SoC is constructed, and the application based on two battery types indicates that the proposed SoC estimator is a closed-loop identification system where the model parameter identification and SoC estimation are corrected mutually, adaptively and simultaneously according to the observer values. The maximum SoC estimation error is less than 1% for both battery types, even against the inaccurate initial SoC.

Beschreibung: This is the second part of a study conducted to model the aerothermodynamic impact of suction parameters and gas properties on a multi-stage centrifugal compressor’s performance. A new iterative method has been developed in the first part to derive the equivalent performance at various operating conditions. This approach has been validated to predict the compressor map at different suction pressures and temperatures using the design characteristics as reference values. A further case is included in this paper in order to emphasize the validity of the developed approach to obtain the performance characteristics at various gas compositions. The provided example shows that the performance parameters at different gas mixtures can be predicted to within ±1.34%. Furthermore, the conducted optimization in this paper reveals that the proposed method can be applied for the compressor design evaluation corresponding to the expected variation in suction conditions. Moreover, the examined case study demonstrates the effect of gas properties’ variation on the operating point and aerodynamic stability of the entire compression system. In order to achieve that, a simple approach has been established to assess the contribution of gas properties’ variation to the inefficient and unstable compressor performance based on the available operational data.

Beschreibung: The in-wheel electric vehicle is expected to be a popular next-generation vehicle because an in-wheel system can simplify the powertrain and improve driving performance. In addition, it also has an advantage in that it maximizes driving efficiency through independent torque control considering the motor efficiency. However, there is an instability problem if only the driving torque is controlled in consideration of only the motor efficiency. In this paper, integrated torque distribution strategies are proposed to overcome these problems. The control algorithm consists of various strategies for optimizing driving efficiency, satisfying driver demands, and considering tire slip and vehicle cornering. Fuzzy logic is used to determine the appropriate timing of intervention for each distribution strategy. A performance simulator for in-wheel electric vehicles was developed by using MATLAB/Simulink and CarSim to validate the control strategies. From simulation results under complex driving conditions, the proposed algorithm was verified to improve both the driving stability and fuel economy of the in-wheel vehicle.

Beschreibung: The knowledge of unsteady forces is necessary when designing vertical axis wind turbines (VAWTs). Measurement data for turbines operating at an open site are still very limited. The data obtained from wind tunnels or towing tanks can be used, but have limited applicability when designing large-scale VAWTs. This study presents experimental data on the normal forces of a 12-kW straight-bladed VAWT operated at an open site north of Uppsala, Sweden. The normal forces are measured with four single-axis load cells. The data are obtained for a wide range of tip speed ratios: from 1.7 to 4.6. The behavior of the normal forces is analyzed. The presented data can be used in validations of aerodynamic models and the mechanical design for VAWTs.

Beschreibung: This paper introduces a new iterative method to predict the equivalent centrifugal compressor performance at various operating conditions. The presented theoretical analysis and empirical correlations provide a novel approach to derive the entire compressor map corresponding to various suction conditions without a prior knowledge of the detailed geometry. The efficiency model was derived to reflect the impact of physical gas properties, Mach number, and flow and work coefficients. One of the main features of the developed technique is the fact that it considers the variation in the gas properties and stage efficiency which makes it appropriate with hydrocarbons. This method has been tested to predict the performance of two multistage centrifugal compressors and the estimated characteristics are compared with the measured data. The carried comparison revealed a good matching with the actual values, including the stable operation region limits. Furthermore, an optimization study was conducted to investigate the influences of suction conditions on the stage efficiency and surge margin. Moreover, a new sort of presentation has been generated to obtain the equivalent performance characteristics for a constant discharge pressure operation at variable suction pressure and temperature working conditions. A further validation is included in part two of this study in order to evaluate the prediction capability of the derived model at various gas compositions.

Beschreibung: This paper presents an investigation of sewage sludge gasification in a fixed bed gasifier. Experiments were conducted on a laboratory scale fixed bed gasifier. In the experiments, two types of dried sewage sludge were tested and their properties were analysed. Parameters such as air ratio λ = 0.12 to 0.27, gasification agent temperature t = 50 to 250 °C and gasification agent composition ( = 0.21 and  > 0.21) were found to influence on temperature distribution, syngas Lower Heating Value (LHV) and syngas composition. The results indicate that the syngas LHV was found to decrease with increased air ratio for all analyzed cases: cold and preheated air and cold enriched air. The increase in the percentage of the main combustible components was accompanied by a decrease in the concentration of carbon dioxide. Increasing oxygen concentration increased the temperature, which tended to favor the formation of smaller molecules in the gas mixture. Thus, the enriched air medium produced a gas with a higher LHV. In contrast to conventional gasification, gasification process with gasification agent preheating causes that the flux of heat necessary to support endothermic gasification reactions is producing more effective. Air preheating causes increases hydrogen and carbon monoxide production.

Beschreibung: Aiming at the combined power quality +disturbance recognition, an automated recognition method based on wavelet packet entropy (WPE) and modified incomplete S-transform (MIST) is proposed in this paper. By combining wavelet packet Tsallis singular entropy, energy entropy and MIST, a 13-dimension vector of different power quality (PQ) disturbances including single disturbances and combined disturbances is extracted. Then, a ruled decision tree is designed to recognize the combined disturbances. The proposed method is tested and evaluated using a large number of simulated PQ disturbances and some real-life signals, which include voltage sag, swell, interruption, oscillation transient, impulsive transient, harmonics, voltage fluctuation and their combinations. In addition, the comparison of the proposed recognition approach with some existing techniques is made. The experimental results show that the proposed method can effectively recognize the single and combined PQ disturbances.

Beschreibung: For general metric theories of gravity, we compare the approach that describes/derives the field equations of gravity as a thermodynamic identity with the one which looks at them from entropy bounds. The comparison is made through the consideration of the matter entropy flux across (Rindler) horizons, studied by making use of the notion of a limiting thermodynamic scale l* of matter, previously introduced in the context of entropy bounds. In doing this: (i) a bound for the entropy of any lump of matter with a given energy-momentum tensor Tab is considered, in terms of a quantity, which is independent of the theory of gravity that we use; this quantity is the variation of the Clausius entropy of a suitable horizon when the element of matter crosses it; (ii) by making use of the equations of motion of the theory, the same quantity is then expressed as the variation of Wald’s entropy of that horizon (and this leads to a generalized form of the generalized covariant entropy bound, applicable to general diffeomorphism-invariant theories of gravity); and (iii) a notion of l* for horizons, as well as an expression for it, is given.

Beschreibung: Controlling competing vegetation during early growth is one of the most important practices for the successful establishment of poplar plantations. Today, most poplar plantations in temperate regions are established on abandoned marginal agricultural land where competing vegetation is usually present during the first years after planting. Thus, the objective of this study was to examine how the growth of two kinds of poplar planting materials, un-rooted cuttings and bare-rooted seedlings was influenced by different vegetation control and soil preparation practices. Across treatments, un-rooted cuttings grew more rapidly than the bare-rooted seedlings. Our results also show that mulching with a degradable carpet or permanent polyethylene plastic increased seedling growth to a similar extent and more strongly in the cases of no treatment (in control plots). In addition, the results suggest that soil preparation in the mulched area favored seedling growth, but this effect was restricted to the first year after planting. These findings indicate that optimal practices for establishing poplar plantations on former agricultural land include planting un-rooted cuttings in prepared soil and mulching.

Beschreibung: Recent disasters, such as the 2010 Haiti earthquake, have drawn attention to the potential role of citizens as active information producers. By using location-aware devices such as smartphones to collect geographic information in the form of geo-tagged text, photos, or videos, and sharing this information through online social media, such as Twitter, citizens create Volunteered Geographic Information (VGI). To effectively use this information for disaster management, we developed a VGI framework for the discovery of VGI. This framework consists of four components: (i) a VGI brokering module to provide a standard service interface to retrieve VGI from multiple resources based on spatial, temporal, and semantic parameters; (ii) a VGI quality control component, which employs semantic filtering and cross-referencing techniques to evaluate VGI; (iii) a VGI publisher module, which uses a service-based delivery mechanism to disseminate VGI, and (iv) a VGI discovery component to locate, browse, and query metadata about available VGI datasets. In a case study we employed a FOSS (Free and Open Source Software) strategy, open standards/specifications, and free/open data to show the utility of the framework. We demonstrate that the framework can facilitate data discovery for disaster management. The addition of quality metrics and a single aggregated source of relevant crisis VGI will allow users to make informed policy choices that could save lives, meet basic humanitarian needs earlier, and perhaps limit environmental and economic damage.

Beschreibung: Background and Purpose: The aim of the present study was to assess a relationship between readiness to quit and post-stroke smoking behavior. Methods: Eighty-six active smokers with first-ever ischemic stroke were recruited in a tertiary-care stroke unit. The question “Are you ready to quit smoking within the next month?” with yes/no responses and the 10-cm readiness visual analog scale (VAS) was administered during the anti-smoking intervention. Smoking status was verified at the 3- and 12-month follow-up. Results: The readiness VAS score at hospitalization was significantly lower in patients classified as smokers as compared to patients classified as non-smokers. The readiness score 〈5 cm was a significant predictor of smoking at the 3-month (OR, 7.3) and 12-month follow-up (OR, 4.9). Conclusions: The present results suggest that the readiness VAS can be used as a simple and inexpensive instrument for early identification of patients who continue to smoke after stroke.

Beschreibung: In this work, the plastic deformation mechanisms responsible for mechanical properties and fracture toughness in  nanotwinned (NT) magnesium is studied by molecular dynamics (MD) simulation. The influence of twin boundary (TBs) spacing and crack position on deformation behaviors are investigated. The microstructure evolution at the crack tip are not exactly the same for the left edge crack (LEC) and the right edge crack (REC) models according to calculations of the energy release rate for dislocation nucleation at the crack tip. The LEC growth initiates in a ductile pattern and then turns into a brittle cleavage. In the REC model, the atomic decohesion occurs at the crack tip to create a new free surface which directly induces a brittle cleavage. A ductile to brittle transition is observed which mainly depends on the competition between dislocation motion and crack growth. This competition mechanism is found to be correlated with the TB spacing. The critical values are 10 nm and 13.5 nm for this transition in LEC and REC models, respectively. Essentially, the dislocation densities affected by the TB spacing play a crucial role in the ductile to brittle transition.

Beschreibung: Plant factories have attracted increasing attention because they can produce fresh fruits and vegetables free from pesticides in all weather. However, the emission spectra from current light sources significantly mismatch the spectra absorbed by plants. We demonstrate a concept of using multiple broad-band as well as narrow-band solid-state lighting technologies to design plant-growth light sources. Take an organic light-emitting diode (OLED), for example; the resulting light source shows an 84% resemblance with the photosynthetic action spectrum as a twin-peak blue dye and a diffused mono-peak red dye are employed. This OLED can also show a greater than 90% resemblance as an additional deeper red emitter is added. For a typical LED, the resemblance can be improved to 91% if two additional blue and red LEDs are incorporated. The approach may facilitate either an ideal use of the energy applied for plant growth and/or the design of better light sources for growing different plants.

Beschreibung: Reliable data transmission over lossy communication link is expensive due to overheads for error protection. For signals that have inherent sparse structures, compressive sensing (CS) is applied to facilitate efficient sparse signal transmissions over lossy communication links without data compression or error protection. The natural packet loss in the lossy link is modeled as a random sampling process of the transmitted data, and the original signal will be reconstructed from the lossy transmission results using the CS-based reconstruction method at the receiving end. The impacts of packet lengths on transmission efficiency under different channel conditions have been discussed, and interleaving is incorporated to mitigate the impact of burst data loss. Extensive simulations and experiments have been conducted and compared to the traditional automatic repeat request (ARQ) interpolation technique, and very favorable results have been observed in terms of both accuracy of the reconstructed signals and the transmission energy consumption. Furthermore, the packet length effect provides useful insights for using compressed sensing for efficient sparse signal transmission via lossy links.

Beschreibung: A model for simulating vertical water level fluctuations with coupled liquid and gas phases is presented. The Preissmann implicit scheme is used to linearize the governing equations for one-dimensional transient flow for both liquid and gas phases, and the linear system is solved using the chasing method. Some classical cases for single liquid and gas phase transients in pipelines and networks are studied to verify that the proposed methods are accurate and reliable. The implicit scheme is extended using a dynamic mesh to simulate the water level fluctuations in a U-tube and an open surge tank without consideration of the gas phase. Methods of coupling liquid and gas phases are presented and used for studying the transient process and interaction between the phases, for gas phase limited in a chamber and gas phase transported in a pipeline. In particular, two other simplified models, one neglecting the effect of the gas phase on the liquid phase and the other one coupling the liquid and gas phases asynchronously, are proposed. The numerical results indicate that the asynchronous model performs better, and are finally applied to a hydropower station with surge tanks and air shafts to simulate the water level fluctuations and air speed.

Beschreibung: Secondary organic aerosol formation from photochemical aging of light-duty gasoline vehicle exhausts in a smog chamber Atmospheric Chemistry and Physics, 15, 9049-9062, 2015 Author(s): T. Liu, X. Wang, W. Deng, Q. Hu, X. Ding, Y. Zhang, Q. He, Z. Zhang, S. Lü, X. Bi, J. Chen, and J. Yu In China, a rapid increase in passenger vehicles has led to the growing concern of vehicle exhaust as an important source of anthropogenic secondary organic aerosol (SOA) in megacities hard hit by haze. In this study, the SOA formation of emissions from two idling light-duty gasoline vehicles (LDGVs) (Euro 1 and Euro 4) operated in China was investigated in a 30 m 3 smog chamber. Five photo-oxidation experiments were carried out at 25 °C with relative humidity at around 50 %. After aging at an OH exposure of 5 × 10 6 molecules cm −3 h, the formed SOA was 12–259 times as high as primary organic aerosol (POA). The SOA production factors (PF) were 0.001–0.044 g kg −1 fuel, comparable with those from the previous studies at comparable OH exposure. This quite lower OH exposure than that in typical atmospheric conditions might however lead to the underestimation of the SOA formation potential from LDGVs. Effective SOA yields in this study were well fit by a one-product gas-particle partitioning model but quite lower than those of a previous study investigating SOA formation from three idling passenger vehicles (Euro 2–4). Traditional single-ring aromatic precursors and naphthalene could explain 51–90 % of the formed SOA. Unspeciated species such as branched and cyclic alkanes might be the possible precursors for the unexplained SOA. A high-resolution time-of-flight aerosol mass spectrometer was used to characterize the chemical composition of SOA. The relationship between f 43 (ratio of m/z 43, mostly C 2 H 3 O + , to the total signal in mass spectrum) and f 44 (mostly CO 2 + ) of the gasoline vehicle exhaust SOA is similar to the ambient semi-volatile oxygenated organic aerosol (SV-OOA). We plot the O : C and H : C molar ratios of SOA in a Van Krevelen diagram. The slopes of ΔH : C / ΔO : C ranged from −0.59 to −0.36, suggesting that the oxidation chemistry in these experiments was a combination of carboxylic acid and alcohol/peroxide formation.

Beschreibung: Patients with a polyherbal prescription are more likely to receive duplicate medications and thus suffer from adverse drug reactions. We conducted a population-based retrospective study to examine the items of Chinese herbal medicine (CHM) per prescription in the ambulatory care of traditional Chinese medicine (TCM) in Taiwan. We retrieved complete TCM ambulatory visit datasets for 2010 from the National Health Insurance database in Taiwan. A total of 59,790 patients who received 313,482 CHM prescriptions were analyzed. Drug prescriptions containing more than five drugs were classified as polyherbal prescriptions; 41.6% of patients were given a polyherbal prescription. There were on average 5.2 ± 2.5 CHMs: 2.3 ± 1.1 compound herbal formula items, and 3.0 ± 2.5 single Chinese herb items in a single prescription. Approximately 4.6% of patients were prescribed 10 CHMs or more. Men had a lower odds ratio (OR) among polyherbal prescriptions (OR = 0.96, 95% confidence interval [CI] 0.92–0.99), and middle-aged patients (35–49 years) had the highest frequency of polyherbal prescription (OR = 1.19, 95% CI = 1.13–1.26). Patients with neoplasm, skin and subcutaneous tissue disease, or genitourinary system disease were more likely to have a polyherbal prescription; OR = 2.20 (1.81–2.67), 1.65 (1.50–1.80), and 1.52 (1.40–1.64), respectively. Polyherbal prescription is widespread in TCM in Taiwan. Potential herb interactions and iatrogenic risks associated with polyherbal prescriptions should be monitored.

Beschreibung: Atmospheric concentrations of carbon dioxide (CO2), a major cause of global warming, have been rising due to industrial development. Carbon capture and storage (CCS), which is regarded as the most effective way to reduce such atmospheric CO2 concentrations, has several environmental and technical disadvantages. Carbon capture and utilization (CCU), which has been introduced to cover such disadvantages, makes it possible to capture CO2, recycling byproducts as resources. However, CCU also requires large amounts of energy in order to induce reactions. Among existing CCU technologies, the process for converting CO2 into CaCO3 requires high temperature and high pressure as reaction conditions. This study proposes a method to fixate CaCO3 stably by using relatively less energy than existing methods. After forming NaOH absorbent solution through electrolysis of NaCl in seawater, CaCO3 was precipitated at room temperature and pressure. Following the experiment, the resulting product CaCO3 was analyzed with Fourier transform infrared spectroscopy (FT-IR); field emission scanning electron microscopy (FE-SEM) image and X-ray diffraction (XRD) patterns were also analyzed. The results showed that the CaCO3 crystal product was high-purity calcite. The study shows a successful method for fixating CO2 by reducing carbon dioxide released into the atmosphere while forming high-purity CaCO3.

Beschreibung: Bone substitute materials have witnessed tremendous development over the past decades and autogenous bone may still be considered the gold standard for many clinicians and clinical approaches in order to rebuild and restore bone defects. However, a plethora of novel xenogenic and synthetic bone substitute materials have been introduced in recent years in the field of bone regeneration. As the development of bone is actually a calcification process within a collagen fiber arrangement, the use of scaffolds in the formation of fibers may offer some advantages, along with additional handling characteristics. This review focuses on material characteristics and degradation behavior of electrospun biodegradable polyester scaffolds. Furthermore, we concentrated on the preclinical in vivo performance with regard to bone regeneration in preclinical studies. The major findings are as follows: Scaffold composition and architecture determine its biological behavior and degradation characteristics; The incorporation of inorganic substances and/or organic substances within composite scaffolds enhances new bone formation; L-poly(lactic acid) and poly(lactic-co-glycolic acid) composite scaffolds, especially when combined with basic substances like hydroxyapatite, tricalcium phosphate or demineralized bone powder, seem not to induce inflammatory tissue reactions in vivo.

Beschreibung: Semi-conducting poly(n-methylaniline) (PNMA)-coated poly(methyl methacrylate) (PMMA) composite nanoparticles were synthesized using cross-linked and grafted PMMA particles as a core, and then, the PNMA shell was coated via chemical oxidative polymerization on the surface of modified PMMA nanoparticles. Their electroresponsive electrorheological characteristics when dispersed in silicone were confirmed under applied electric fields using a rotational rheometer, focusing on their viscoelastic response. Using a frequency sweep test, the frequency dependence of both the storage and loss moduli was confirmed to increase upon increasing the electric field, with a stable plateau regime over the entire angular frequency range.

Beschreibung: Nitrogen export from a boreal stream network following forest harvesting: seasonal nitrate removal and conservative export of organic forms Biogeosciences Discussions, 12, 12061-12089, 2015 Author(s): J. Schelker, R. Sponseller, E. Ring, L. Högbom, S. Löfgren, and H. Laudon Boreal streams are under pressure from large scale disturbance by forestry. Recent scenarios predict an increase in forest production in Scandinavia to meet market demands and to mitigate higher anthropogenic CO 2 emissions. Increased fertilization and shorter forest rotations are anticipated which will likely enhance the pressure on boreal streams in the near future. Among the major environmental impacts of forest harvesting is the increased mobilization of inorganic nitrogen (N), primarily as nitrate (NO 3 - ) into surface waters. But whereas NO 3 - inputs to first-order streams have been previously described, their downstream fate and impact is not well understood. We evaluated the downstream fate of N inputs in a boreal landscape that has been altered by forest harvests over a 10 year period to estimate the effects of multiple clear-cuts on aquatic N export in a boreal stream network. Small streams showed substantial leaching of NO 3 - in response to harvests with concentrations increasing by ~ 15 fold. NO 3 - concentrations at two sampling stations further downstream in the network were strongly seasonal and increased significantly in response to harvesting at the medium size, but not at the larger stream. Nitrate removal efficiency, E r , calculated as the percentage of "forestry derived" NO 3 - that was retained within the landscape using a mass balance model was highest during the snow melt season followed by the growing season, but declined continuously throughout the dormant season. In contrast, export of organic N from the landscape indicated little removal and was essentially conservative. Overall, net removal of NO 3 - between 2008 and 2011 accounted for ~ 70 % of the total NO 3 - mass exported from harvested patches distributed across the landscape. These results highlight the capacity and limitation of N-limited terrestrial and aquatic ecosystems to buffer inorganic N mobilization that arises from multiple clear-cuts within meso-scale boreal watersheds.

Beschreibung: Uncertainties in global aerosols and climate effects due to biofuel emissions Atmospheric Chemistry and Physics, 15, 8577-8596, 2015 Author(s): J. K. Kodros, C. E. Scott, S. C. Farina, Y. H. Lee, C. L'Orange, J. Volckens, and J. R. Pierce Aerosol emissions from biofuel combustion impact both health and climate; however, while reducing emissions through improvements to combustion technologies will improve health, the net effect on climate is largely unconstrained. In this study, we examine sensitivities in global aerosol concentration, direct radiative climate effect, and cloud-albedo aerosol indirect climate effect to uncertainties in biofuel emission factors, optical mixing state, and model nucleation and background secondary organic aerosol (SOA). We use the Goddard Earth Observing System global chemical-transport model (GEOS-Chem) with TwO Moment Aerosol Sectional (TOMAS) microphysics. The emission factors include amount, composition, size, and hygroscopicity, as well as optical mixing-state properties. We also evaluate emissions from domestic coal use, which is not biofuel but is also frequently emitted from homes. We estimate the direct radiative effect assuming different mixing states (homogeneous, core-shell, and external) with and without absorptive organic aerosol (brown carbon). We find the global-mean direct radiative effect of biofuel emissions ranges from −0.02 to +0.06 W m −2 across all simulation/mixing-state combinations with regional effects in source regions ranging from −0.2 to +0.8 W m −2 . The global-mean cloud-albedo aerosol indirect effect (AIE) ranges from +0.01 to −0.02 W m −2 with regional effects in source regions ranging from −1.0 to −0.05 W m −2 . The direct radiative effect is strongly dependent on uncertainties in emissions mass, composition, emissions aerosol size distributions, and assumed optical mixing state, while the indirect effect is dependent on the emissions mass, emissions aerosol size distribution, and the choice of model nucleation and secondary organic aerosol schemes. The sign and magnitude of these effects have a strong regional dependence. We conclude that the climate effects of biofuel aerosols are largely unconstrained, and the overall sign of the aerosol effects is unclear due to uncertainties in model inputs. This uncertainty limits our ability to introduce mitigation strategies aimed at reducing biofuel black carbon emissions in order to counter warming effects from greenhouse gases. To better understand the climate impact of particle emissions from biofuel combustion, we recommend field/laboratory measurements to narrow constraints on (1) emissions mass, (2) emission size distribution, (3) mixing state, and (4) ratio of black carbon to organic aerosol.

Beschreibung: The Ice Selective Inlet: a novel technique for exclusive extraction of pristine ice crystals in mixed-phase clouds Atmospheric Measurement Techniques, 8, 3087-3106, 2015 Author(s): P. Kupiszewski, E. Weingartner, P. Vochezer, M. Schnaiter, A. Bigi, M. Gysel, B. Rosati, E. Toprak, S. Mertes, and U. Baltensperger Climate predictions are affected by high uncertainties partially due to an insufficient knowledge of aerosol–cloud interactions. One of the poorly understood processes is formation of mixed-phase clouds (MPCs) via heterogeneous ice nucleation. Field measurements of the atmospheric ice phase in MPCs are challenging due to the presence of much more numerous liquid droplets. The Ice Selective Inlet (ISI), presented in this paper, is a novel inlet designed to selectively sample pristine ice crystals in mixed-phase clouds and extract the ice residual particles contained within the crystals for physical and chemical characterization. Using a modular setup composed of a cyclone impactor, droplet evaporation unit and pumped counterflow virtual impactor (PCVI), the ISI segregates particles based on their inertia and phase, exclusively extracting small ice particles between 5 and 20 μm in diameter. The setup also includes optical particle spectrometers for analysis of the number size distribution and shape of the sampled hydrometeors. The novelty of the ISI is a droplet evaporation unit, which separates liquid droplets and ice crystals in the airborne state, thus avoiding physical impaction of the hydrometeors and limiting potential artefacts. The design and validation of the droplet evaporation unit is based on modelling studies of droplet evaporation rates and computational fluid dynamics simulations of gas and particle flows through the unit. Prior to deployment in the field, an inter-comparison of the optical particle size spectrometers and a characterization of the transmission efficiency of the PCVI was conducted in the laboratory. The ISI was subsequently deployed during the Cloud and Aerosol Characterization Experiment (CLACE) 2013 and 2014 – two extensive international field campaigns encompassing comprehensive measurements of cloud microphysics, as well as bulk aerosol, ice residual and ice nuclei properties. The campaigns provided an important opportunity for a proof of concept of the inlet design. In this work we present the setup of the ISI, including the modelling and laboratory characterization of its components, as well as field measurements demonstrating the ISI performance and validating the working principle of the inlet. Finally, measurements of biological aerosol during a Saharan dust event (SDE) are presented, showing a first indication of enrichment of bio-material in sub-2 μm ice residuals.

Beschreibung: Impacts on wave-driven harbour agitation due to climate change in Catalan ports Natural Hazards and Earth System Science, 15, 1695-1709, 2015 Author(s): J. P. Sierra, M. Casas-Prat, M. Virgili, C. Mösso, and A. Sánchez-Arcilla The objective of the present work is to analyse how changes in wave patterns due to the effect of climate change can affect harbour agitation (oscillations within the port due to wind waves). The study focuses on 13 harbours located on the Catalan coast (NW Mediterranean) using a methodology with general applicability. To obtain the patterns of agitation, a Boussinesq-type model is used, which is forced at the boundaries by present/future offshore wave conditions extracted from recently developed high-resolution wave projections in the NW Mediterranean. These wave projections were obtained with the SWAN model forced by present/future surface wind fields projected, respectively, by five different combinations of global and regional circulation models (GCMs and RCMs) for the A1B scenario. The results show a general slight reduction in the annual average agitation for most of the ports, except for the northernmost and southernmost areas of the region, where a slight increase is obtained. A seasonal analysis reveals that the tendency to decrease is accentuated in winter. However, the inter-model variability is large for both the winter and the annual analysis. Conversely, a general increase with a larger agreement among models is found during summer, which is the period with greater activity in most of the studied ports (marinas). A qualitative assessment of the factors of variability seems to indicate that the choice of GCM tends to affect the spatial pattern, whereas the choice of RCM induces a more homogeneous bias over the regional domain.

Beschreibung: The effect of fuel composition on gasification process performance was investigated by performing mass and energy balances on a pre-pilot scale bubbling fluidized bed reactor fed with mixtures of plastic waste, wood, and coal. The fuels containing plastic waste produced less H2, CO, and CO2 and more light hydrocarbons than the fuels including biomass. The lower heating value (LHV) progressively increased from 5.1 to 7.9 MJ/Nm3 when the plastic waste fraction was moved from 0% to 100%. Higher carbonaceous fines production was associated with the fuel containing a large fraction of coal (60%), producing 87.5 g/kgFuel compared to only 1.0 g/kgFuel obtained during the gasification test with just plastic waste. Conversely, plastic waste gasification produced the highest tar yield, 161.9 g/kgFuel, while woody biomass generated only 13.4 g/kgFuel. Wood gasification showed a carbon conversion efficiency (CCE) of 0.93, while the tests with two fuels containing coal showed lowest CCE values (0.78 and 0.70, respectively). Plastic waste and wood gasification presented similar cold gas efficiency (CGE) values (0.75 and 0.76, respectively), while that obtained during the co-gasification tests varied from 0.53 to 0.73.

Beschreibung: This paper introduces a new simple system with a butterfly chaotic attractor. This system has rich and complex dynamics. With some typical parameters, its Lyapunov dimension is greater than other known three dimensional chaotic systems. It exhibits chaotic behavior over a large range of parameters, and the divergence of flow of this system is not a constant. The dynamics of this new system are analyzed via Lyapunov exponent spectrum, bifurcation diagrams, phase portraits and the Poincaré map. The compound structures of this new system are also analyzed. By means of topological horseshoe theory and numerical computation, the Poincaré map defined for the system is proved to be semi-conjugate to 3-shift map, and thus the system has positive topological entropy.

Beschreibung: In this paper, the problem of robust control of nonlinear fractional-order systems in the presence of uncertainties and external disturbance is investigated. Fuzzy logic systems are used for estimating the unknown nonlinear functions. Based on the fractional Lyapunov direct method and some proposed Lemmas, an adaptive fuzzy controller is designed. The proposed method can guarantee all the signals in the closed-loop systems remain bounded and the tracking errors converge to an arbitrary small region of the origin. Lastly, an illustrative example is given to demonstrate the effectiveness of the proposed results.

Beschreibung: This paper proposes a resonant electric cradle design with infant cries recognition, employing an Arduino UNO as the core processor. For most commercially available electric cradles, the drive motor is closely combined with the bearing on the top, resulting in a lot of energy consumption. In this proposal, a ball bearing design was adopted and the driving force is under the cradle to increase the distance from the object to fulcrum and torque. The sensors are designed to detect the oscillation state, and then the force is driven at the critical time to achieve the maximum output response while saving energy according to the principle of resonance. As for the driving forces, the winding power and motors are carefully placed under the cradle. The sensors, including the three-axis accelerometer and infrared sensor, are tested and applied under swinging amplitude control. In addition, infant cry recognition technology was incorporated in the design to further develop its functionality, which is a rare feature in this kind of hardware. The proposed nonlinear operator of fundamental frequency ( ) analysis is able to identify different types of infant cries. In conclusion, this paper proposes an energy-saving electric cradle with infant cries recognition and the experimental results demonstrate the effectiveness of this approach.

Beschreibung: Many people find that their sleep is restricted or disturbed by social obligations, including work. Sleep phase delays can affect an individual’s circadian rhythms on the following day and cause daytime sleepiness and/or poor performance. In this study, to examine weekly variations in sleep patterns, we analyzed sleep data for seven-day periods (from Sunday to Saturday) that had been collected from 2914 subjects (aged 20–79 years) over a total of 24,899 subject-weeks using contactless biomotion sensors. On the weekend, the subjects’ mean sleep midpoint, bedtime, and wake-up time were delayed by 40, 26 and 53 min, respectively, compared with those seen on weekdays. In addition, on weekdays, the mean difference between the maximum and median sleep midpoint ranged from 35 to 47 min among the subjects in their 20 s–70 s. The weekend delay and weekday variation in the subjects’ sleep patterns tended to decrease with age. This study detected sleep pattern disturbances on both weekdays and weekends. The serial changes in weekday bedtimes detected in this study suggest that sleep habits are influenced by changes in the temporal patterns of social activities/duties. We need further study the advantages of getting extra sleep and the disadvantages of sleep pattern disturbances in daily lifestyle.

Beschreibung: Free acidity of aqueous solutions was initially defined in 1909 by Søren Peter Lauritz Sørensen as pH = −lgcH+ (c/mol·dm−3 or m/mol·kg−1 of the free hydrogen ions in solution, H+) soon (1910) was changed to pH = paH+ = −lgaH+, integrating the new concepts of activity, ai and activity coefficient γi, for the ionic species i under concern, H+ in this case; it is ai = −lg(miγi). Since individual ions do not exist alone in solution, primary pH values cannot be assigned solely by experimental measurements, requiring extra thermodynamic model assumptions for the activity coefficient, γH+, which has put pH in a unique situation of not being fully traceable to the International System of Units (SI). Also the concept of activity is often not felt to be as perceptible as that of concentration which may present difficulties, namely with the interpretation of data. pH measurements on unknown samples rely on calibration of the measuring setup with adequate reference pH buffers. In this work, the assignment of pH values to buffers closely matching the samples, e.g., seawater, is revisited. An approach is presented to assess the quantity pmH+ = −lgmH+ profiting from the fact that, contrary to single ion activity coefficients, mean activity coefficients,   can be assessed based on experimentally assessed quantities alone, γExp ±, thus ensuring traceability to the mole, the SI base unit for amount of substance. Compatibility between γExp ± and mean activity coefficient calculated by means of Pitzer model equations, γPtz ±, validates the model for its intended use.

Beschreibung: Utilisation of CryoSat-2 SAR altimeter in operational ice charting The Cryosphere Discussions, 9, 4117-4145, 2015 Author(s): E. Rinne and M. Similä We present methods to utilise Cryosat-2 (CS-2) Synthetic Aperture (SAR) mode data in operational ice charting. We compare CS-2 data qualitatively to Synthetic Aperture Radar (SAR) mosaics over Barents and Kara seas. Furthermore, we compare the CS-2 to archived operational ice charts. We present distributions of four CS-2 waveform parameters for different ice types as presented in the ice charts. We go on to present an automatic classification method for CS-2 data which, after training with operational ice charts, is capable of determining open water from ice with a hit rate of 〉 90 %. The training data is dynamically updated every five days using the most recent 15 days CS-2 data and operative ice charts. This helps the adaption of the classifier to the evolving ice/snow conditions throughout winter. The classifier is also capable of detecting three different ice classes (thin and thick first year ice as well as old ice) with success rates good enough for the output to be usable to support operational ice charting. Finally, we present a near real time CS-2 product just plotting the waveform characteristics and conclude that even such a simple product is usable for some of the needs of ice charting.

Beschreibung: Currently deep learning has made great breakthroughs in visual and speech processing, mainly because it draws lessons from the hierarchical mode that brain deals with images and speech. In the field of NLP, a topic model is one of the important ways for modeling documents. Topic models are built on a generative model that clearly does not match the way humans write. In this paper, we propose Event Model, which is unsupervised and based on the language processing mechanism of neurolinguistics, to model documents. In Event Model, documents are descriptions of concrete or abstract events seen, heard, or sensed by people and words are objects in the events. Event Model has two stages: word learning and dimensionality reduction. Word learning is to learn semantics of words based on deep learning. Dimensionality reduction is the process that representing a document as a low dimensional vector by a linear mode that is completely different from topic models. Event Model achieves state-of-the-art results on document retrieval tasks.

Beschreibung: Inverse modeling of black carbon emissions over China using ensemble data assimilation Atmospheric Chemistry and Physics Discussions, 15, 20851-20879, 2015 Author(s): P. Wang, H. Wang, Y. Q. Wang, X. Y. Zhang, S. L. Gong, M. Xue, C. H. Zhou, H. L. Liu, X. Q. An, T. Niu, and Y. L. Chen Emissions inventories of black carbon (BC), which are traditionally constructed using a "bottom-up" approach based on activity data and emissions factors, are considered to contain a large level of uncertainty. In this paper, an ensemble optimal interpolation (EnOI) data assimilation technique is used to investigate the possibility of optimally recovering the spatially resolved emissions bias of BC. An inverse modeling system for emissions is established for an atmospheric chemistry aerosol model and two key problems related to ensemble data assimilation in the top-down emissions estimation are discussed: (1) how to obtain reasonable ensembles of prior emissions; and (2) establishing a scheme to localize the background-error matrix. An experiment involving a one month simulation cycle with EnOI inversion of BC emissions is performed for January 2008. The bias of the BC emissions intensity in China at each grid point is corrected by this inverse system. The inversed emission over China in January is 240.1 Gg, and annual emission is about 2750 Gg, which is over 1.8 times of bottom-up emission inventory. The results show that, even though only monthly mean BC measurements are employed to inverse the emissions, the accuracy of the daily model simulation improves. Using top-down emissions, the average root-mean-square error of simulated daily BC is decreased by nearly 30 %. These results are valuable and promising for a better understanding of aerosol emissions and distributions, as well as aerosol forecasting.

Beschreibung: Metrology of ground-based satellite validation: co-location mismatch and smoothing issues of total ozone comparisons Atmospheric Measurement Techniques Discussions, 8, 8023-8082, 2015 Author(s): T. Verhoelst, J. Granville, F. Hendrick, U. Köhler, C. Lerot, J.-P. Pommereau, A. Redondas, M. Van Roozendael, and J.-C. Lambert Comparisons with ground-based correlative measurements constitute a key component in the validation of satellite data on atmospheric composition. The error budget of these comparisons contains not only the measurement uncertainties but also several terms related to differences in sampling and smoothing of the inhomogeneous and variable atmospheric field. A versatile system for Observing System Simulation Experiments (OSSEs), named OSSSMOSE, is used here to quantify these terms. Based on the application of pragmatic observation operators onto high-resolution atmospheric fields, it allows a simulation of each individual measurement, and consequently also of the differences to be expected from spatial and temporal field variations between both measurements making up a comparison pair. As a topical case study, the system is used to evaluate the error budget of total ozone column (TOC) comparisons between on the one hand GOME-type direct fitting (GODFITv3) satellite retrievals from GOME/ERS2, SCIAMACHY/Envisat, and GOME-2/MetOp-A, and on the other hand direct-sun and zenith-sky reference measurements such as from Dobsons, Brewers, and zenith scattered light (ZSL-)DOAS instruments respectively. In particular, the focus is placed on the GODFITv3 reprocessed GOME-2A data record vs. the ground-based instruments contributing to the Network for the Detection of Atmospheric Composition Change (NDACC). The simulations are found to reproduce the actual measurements almost to within the measurement uncertainties, confirming that the OSSE approach and its technical implementation are appropriate. This work reveals that many features of the comparison spread and median difference can be understood as due to metrological differences, even when using strict co-location criteria. In particular, sampling difference errors exceed measurement uncertainties regularly at most mid- and high-latitude stations, with values up to 10 % and more in extreme cases. Smoothing difference errors only play a role in the comparisons with ZSL-DOAS instruments at high latitudes, especially in the presence of a polar vortex. At tropical latitudes, where TOC variability is lower, both types of errors remain below about 1 % and consequently do not contribute significantly to the comparison error budget. The detailed analysis of the comparison results, including now the metrological errors, suggests that the published random measurement uncertainties for GODFITv3 reprocessed satellite data are potentially overestimated, and adjustments are proposed here. This successful application of the OSSSMOSE sytem to close for the first time the error budget of TOC comparisons, bodes well for potential future applications, which are briefly touched upon.

Beschreibung: Relating seasonal dynamics of enhanced vegetation index to the recycling of water in two endorheic river basins in north-west China Hydrology and Earth System Sciences, 19, 3387-3403, 2015 Author(s): M. A. Matin and C. P.-A. Bourque This study associates the dynamics of enhanced vegetation index in lowland desert oases to the recycling of water in two endorheic (hydrologically closed) river basins in Gansu Province, north-west China, along a gradient of elevation zones and land cover types. Each river basin was subdivided into four elevation zones representative of (i) oasis plains and foothills, and (ii) low-, (iii) mid-, and (iv) high-mountain elevations. Comparison of monthly vegetation phenology with precipitation and snowmelt dynamics within the same basins over a 10-year period (2000–2009) suggested that the onset of the precipitation season (cumulative % precipitation 〉 7–8 %) in the mountains, typically in late April to early May, was triggered by the greening of vegetation and increased production of water vapour at the base of the mountains. Seasonal evolution of in-mountain precipitation correlated fairly well with the temporal variation in oasis-vegetation coverage and phenology characterised by monthly enhanced vegetation index, yielding coefficients of determination of 0.65 and 0.85 for the two basins. Convergent cross-mapping of related time series indicated bi-directional causality (feedback) between the two variables. Comparisons between same-zone monthly precipitation amounts and enhanced vegetation index provided weaker correlations. Start of the growing season in the oases was shown to coincide with favourable spring warming and discharge of meltwater from low- to mid-elevations of the Qilian Mountains (zones 1 and 2) in mid-to-late March. In terms of plant requirement for water, mid-seasonal development of oasis vegetation was seen to be controlled to a greater extent by the production of rain in the mountains. Comparison of water volumes associated with in-basin production of rainfall and snowmelt with that associated with evaporation seemed to suggest that about 90 % of the available liquid water (i.e. mostly in the form of direct rainfall and snowmelt in the mountains) was recycled locally.

Beschreibung: Investigating suspended sediment dynamics in contrasting agricultural catchments using ex situ turbidity-based suspended sediment monitoring Hydrology and Earth System Sciences, 19, 3349-3363, 2015 Author(s): S. C. Sherriff, J. S. Rowan, A. R. Melland, P. Jordan, O. Fenton, and D. Ó hUallacháin Soil erosion and suspended sediment (SS) pose risks to chemical and ecological water quality. Agricultural activities may accelerate erosional fluxes from bare, poached or compacted soils, and enhance connectivity through modified channels and artificial drainage networks. Storm-event fluxes dominate SS transport in agricultural catchments; therefore, high temporal-resolution monitoring approaches are required, but can be expensive and technically challenging. Here, the performance of in situ turbidity sensors, conventionally installed submerged at the river bankside, is compared with installations where river water is delivered to sensors ex situ, i.e. within instrument kiosks on the riverbank, at two experimental catchments (Grassland B and Arable B). The in situ and ex situ installations gave comparable results when calibrated against storm-period, depth-integrated SS data, with total loads at Grassland B estimated at 12 800 and 15 400 t, and 22 600 and 24 900 t at Arable B, respectively. The absence of spurious turbidity readings relating to bankside debris around the in situ sensor and its greater security make the ex situ sensor more robust. The ex situ approach was then used to characterise SS dynamics and fluxes in five intensively managed agricultural catchments in Ireland which feature a range of landscape characteristics and land use pressures. Average annual suspended sediment concentration (SSC) was below the Freshwater Fish Directive (78/659/EEC) guideline of 25 mg L −1 , and the continuous hourly record demonstrated that exceedance occurred less than 12 % of the observation year. Soil drainage class and proportion of arable land were key controls determining flux rates, but all catchments reported a high degree of inter-annual variability associated with variable precipitation patterns compared to the long-term average. Poorly drained soils had greater sensitivity to runoff and soil erosion, particularly in catchments with periods of bare soils. Well drained soils were less sensitive to erosion even on arable land; however, under extreme rainfall conditions, all bare soils remain a high sediment loss risk. Analysis of storm-period and seasonal dynamics (over the long term) using high-resolution monitoring would be beneficial to further explore the impact of landscape, climate and land use characteristics on SS export.

Beschreibung: Landscape heterogeneity drives contrasting concentration–discharge relationships in shale headwater catchments Hydrology and Earth System Sciences, 19, 3333-3347, 2015 Author(s): E. M. Herndon, A. L. Dere, P. L. Sullivan, D. Norris, B. Reynolds, and S. L. Brantley Solute concentrations in stream water vary with discharge in patterns that record complex feedbacks between hydrologic and biogeochemical processes. In a comparison of three shale-underlain headwater catchments located in Pennsylvania, USA (the forested Shale Hills Critical Zone Observatory), and Wales, UK (the peatland-dominated Upper Hafren and forest-dominated Upper Hore catchments in the Plynlimon forest), dissimilar concentration–discharge ( C – Q ) behaviors are best explained by contrasting landscape distributions of soil solution chemistry – especially dissolved organic carbon (DOC) – that have been established by patterns of vegetation and soil organic matter (SOM). Specifically, elements that are concentrated in organic-rich soils due to biotic cycling (Mn, Ca, K) or that form strong complexes with DOC (Fe, Al) are spatially heterogeneous in pore waters because organic matter is heterogeneously distributed across the catchments. These solutes exhibit non-chemostatic behavior in the streams, and solute concentrations either decrease (Shale Hills) or increase (Plynlimon) with increasing discharge. In contrast, solutes that are concentrated in soil minerals and form only weak complexes with DOC (Na, Mg, Si) are spatially homogeneous in pore waters across each catchment. These solutes are chemostatic in that their stream concentrations vary little with stream discharge, likely because these solutes are released quickly from exchange sites in the soils during rainfall events. Furthermore, concentration–discharge relationships of non-chemostatic solutes changed following tree harvest in the Upper Hore catchment in Plynlimon, while no changes were observed for chemostatic solutes, underscoring the role of vegetation in regulating the concentrations of certain elements in the stream. These results indicate that differences in the hydrologic connectivity of organic-rich soils to the stream drive differences in concentration behavior between catchments. As such, in catchments where SOM is dominantly in lowlands (e.g., Shale Hills), we infer that non-chemostatic elements associated with organic matter are released to the stream early during rainfall events, whereas in catchments where SOM is dominantly in uplands (e.g., Plynlimon), these non-chemostatic elements are released later during rainfall events. The distribution of SOM across the landscape is thus a key component for predictive models of solute transport in headwater catchments.

Beschreibung: Future changes in flash flood frequency and intensity of the Tha Di River (Thailand) based on rainfall–runoff modeling and advanced delta change scaling Hydrology and Earth System Sciences Discussions, 12, 7327-7352, 2015 Author(s): S. Hilgert, A. Wagner, and S. Fuchs As a consequence of climate change, extreme and flood-causing precipitation events are expected to increase in magnitude and frequency, especially in today's high-precipitation areas. During the north-east monsoon seasons, Nakhon Si Thammarat in southern Thailand is flash-flooded every 2.22 years on average. This study investigates frequency and intensity of harmful discharges of the Tha Di River regarding the IPCC emission scenarios A2 and B2. The regional climate model (RCM) PRECIS was transformed using the advanced delta change (ADC) method. The hydrologic response model HBV-Light was calibrated to the catchment and supplied with ADC-scaled daily precipitation and temperature data for 2010–2089. Under the A2 (B2) scenario, the flood threshold exceedance frequency on average increases by 133 % (decreases by 10 %), average flood intensity increases by 3 % (decreases by 2 %) and the annual top five discharge peaks intensities increase by 46 % (decrease by 5 %). Yearly precipitation sums increase by 30 % (10 %) towards the end of the century. The A2 scenario predicts a precipitation increase during the rainy season, which intensifies flood events; while increases projected exclusively for the dry season are not expected to cause floods. Retention volume demand of past events was calculated to be up to 12 × 10 6 m 3 . Flood risks are staying at high levels under the B2 scenario or increase dramatically under the A2 scenario. Results show that the RCM scaling process is inflicted with systematic biases but is crucial to investigate small, mountainous catchments. Improvement of scaling techniques should therefore accompany the development towards high-resolution climate models.

Beschreibung: A pan-African medium-range ensemble flood forecast system Hydrology and Earth System Sciences, 19, 3365-3385, 2015 Author(s): V. Thiemig, B. Bisselink, F. Pappenberger, and J. Thielen The African Flood Forecasting System (AFFS) is a probabilistic flood forecast system for medium- to large-scale African river basins, with lead times of up to 15 days. The key components are the hydrological model LISFLOOD, the African GIS database, the meteorological ensemble predictions by the ECMWF (European Centre for Medium-Ranged Weather Forecasts) and critical hydrological thresholds. In this paper, the predictive capability is investigated in a hindcast mode, by reproducing hydrological predictions for the year 2003 when important floods were observed. Results were verified by ground measurements of 36 sub-catchments as well as by reports of various flood archives. Results showed that AFFS detected around 70 % of the reported flood events correctly. In particular, the system showed good performance in predicting riverine flood events of long duration (〉 1 week) and large affected areas (〉 10 000 km 2 ) well in advance, whereas AFFS showed limitations for small-scale and short duration flood events. The case study for the flood event in March 2003 in the Sabi Basin (Zimbabwe) illustrated the good performance of AFFS in forecasting timing and severity of the floods, gave an example of the clear and concise output products, and showed that the system is capable of producing flood warnings even in ungauged river basins. Hence, from a technical perspective, AFFS shows a large potential as an operational pan-African flood forecasting system, although issues related to the practical implication will still need to be investigated.

Beschreibung: Gas adsorption and desorption effects on cylinders and their importance for long-term gas records Atmospheric Measurement Techniques Discussions, 8, 8083-8112, 2015 Author(s): M. C. Leuenberger, M. F. Schibig, and P. Nyfeler It is well known that gases adsorb on many surfaces, in particular metal surfaces. There are two main forms responsible for these effects (i) physisorption and (ii) chemisorption. Physisorption is associated with lower binding energies in the order of 1–10 kJ mol −1 compared to chemisorption ranging from 100 to 1000 kJ mol −1 . Furthermore, chemisorption forms only monolayers, contrasting physisorption that can form multilayer adsorption. The reverse process is called desorption and follows similar mathematical laws, however, it can be influenced by hysteresis effects. In the present experiment we investigated the adsorption/desorption phenomena on three steel and three aluminium cylinders containing compressed air in our laboratory and under controlled conditions in a climate chamber, respectively. We proved the pressure effect on physisorption for CO 2 , CH 4 and H 2 O by decanting one steel and two aluminium cylinders completely. The CO 2 results for both cylinders are in excellent agreement with the pressure dependence of a monolayer adsorption model. However, adsorption on aluminium ( 〈 0.05 and 0 ppm for CO 2 and H 2 O) was about 10 times less than on steel ( 〈 0.41 ppm and about 〈 2.5 ppm, respectively). The CO 2 amounts adsorbed (5.8 × 10 19 CO 2 molecules) corresponds to about the five-fold monolayer adsorption indicating that the effective surface exposed for adsorption is significantly larger than the geometric surface area. Adsorption/desorption effects were minimal for CH 4 and for CO. However, the latter dependence requires further attention since it was only studied on one aluminium cylinder with a very low mole fraction. In the climate chamber the cylinders were exposed to temperatures between −10 and +50 °C to determine the corresponding temperature coefficients of adsorption. Again, we found distinctly different values for CO 2 ranging from 0.0014 to 0.0184 ppm °C −1 for steel cylinders and −0.0002 to −0.0003 ppm °C −1 for aluminium cylinders. The reversed temperature dependence for aluminium cylinders point to significantly lower desorption energies than for steel cylinders and might at least partly be due to temperature and gas consumption induced pressure changes. Temperature coefficients for CH 4 , CO and H 2 O adsorption were, within their error bands, insignificant. These results do indicate the need for careful selection and usage of gas cylinders for high precision calibration purposes such as requested in trace gas applications.

Beschreibung: A two-layer canopy model with thermal inertia for an improved snowpack energy balance below needleleaf forest (model SNOWPACK, version 3.2.1, revision 741) Geoscientific Model Development, 8, 2379-2398, 2015 Author(s): I. Gouttevin, M. Lehning, T. Jonas, D. Gustafsson, and M. Mölder A new, two-layer canopy module with thermal inertia as part of the detailed snow model SNOWPACK (version 3.2.1) is presented and evaluated. As a by-product of these new developments, an exhaustive description of the canopy module of the SNOWPACK model is provided, thereby filling a gap in the existing literature. In its current form, the two-layer canopy module is suited for evergreen needleleaf forest, with or without snow cover. It is designed to reproduce the difference in thermal response between leafy and woody canopy elements, and their impact on the underlying snowpack or ground surface energy balance. Given the number of processes resolved, the SNOWPACK model with its enhanced canopy module constitutes a sophisticated physics-based modeling chain of the continuum going from atmosphere to soil through the canopy and snow. Comparisons of modeled sub-canopy thermal radiation to stand-scale observations at an Alpine site (Alptal, Switzerland) demonstrate improvements induced by the new canopy module. Both thermal heat mass and the two-layer canopy formulation contribute to reduce the daily amplitude of the modeled canopy temperature signal, in agreement with observations. Particularly striking is the attenuation of the nighttime drop in canopy temperature, which was a key model bias. We specifically show that a single-layered canopy model is unable to produce this limited temperature drop correctly. The impact of the new parameterizations on the modeled dynamics of the sub-canopy snowpack is analyzed. The new canopy module yields consistent results but the frequent occurrence of mixed-precipitation events at Alptal prevents a conclusive assessment of model performance against snow data. The new model is also successfully tested without specific tuning against measured tree temperature and biomass heat-storage fluxes at the boreal site of Norunda (Sweden). This provides an independent assessment of its physical consistency and stresses the robustness and transferability of the chosen parameterizations. The SNOWPACK code including the new canopy module, is available under Gnu General Public License (GPL) license and upon creation of an account at https://models.slf.ch/ .

Beschreibung: A comprehensive filtering scheme for high-resolution estimation of the water balance components from high-precision lysimeters Hydrology and Earth System Sciences, 19, 3405-3418, 2015 Author(s): M. Hannes, U. Wollschläger, F. Schrader, W. Durner, S. Gebler, T. Pütz, J. Fank, G. von Unold, and H.-J. Vogel Large weighing lysimeters are currently the most precise method to directly measure all components of the terrestrial water balance in parallel via the built-in weighing system. As lysimeters are exposed to several external forces such as management practices or wind influencing the weighing data, the calculated fluxes of precipitation and evapotranspiration can be altered considerably without having applied appropriate corrections to the raw data. Therefore, adequate filtering schemes for obtaining most accurate estimates of the water balance components are required. In this study, we use data from the TERENO (TERrestrial ENvironmental Observatories) SoilCan research site in Bad Lauchstädt to develop a comprehensive filtering procedure for high-precision lysimeter data, which is designed to deal with various kinds of possible errors starting from the elimination of large disturbances in the raw data resulting e.g., from management practices all the way to the reduction of noise caused e.g., by moderate wind. Furthermore, we analyze the influence of averaging times and thresholds required by some of the filtering steps on the calculated water balance and investigate the ability of two adaptive filtering methods (the adaptive window and adaptive threshold filter (AWAT filter; Peters et al., 2014), and a new synchro filter applicable to the data from a set of several lysimeters) to further reduce the filtering error. Finally, we take advantage of the data sets of all 18 lysimeters running in parallel at the Bad Lauchstädt site to evaluate the performance and accuracy of the proposed filtering scheme. For the tested time interval of 2 months, we show that the estimation of the water balance with high temporal resolution and good accuracy is possible. The filtering code can be downloaded from the journal website as Supplement to this publication.

Beschreibung: The multi-parameter character of supersymmetric dark-matter models implies the combination of their experimental studies with astrophysical and cosmological probes. The physics of the early Universe provides nontrivial effects of non-equilibrium particles and primordial cosmological structures. Primordial black holes (PBHs) are a profound signature of such structures that may arise as a cosmological consequence of supersymmetric (SUSY) models. SUSY-based mechanisms of baryosynthesis can lead to the possibility of antimatter domains in a baryon asymmetric Universe. In the context of cosmoparticle physics, which studies the fundamental relationship of the micro- and macro-worlds, the development of SUSY illustrates the main principles of this approach, as the physical basis of the modern cosmology provides cross-disciplinary tests in physical and astronomical studies.

Beschreibung: In this paper, we study a generalized Zakharov–Kuznetsov equation in three variables, which has applications in the nonlinear development of ion-acoustic waves in a magnetized plasma. Conservation laws for this equation are constructed for the first time by using the new conservation theorem of Ibragimov. Furthermore, new exact solutions are obtained by employing the Lie symmetry method along with the simplest equation method.

Beschreibung: At the center of core technologies for a future cyber world, such as Internet of Things (IoT) or big data, is a context-rich system that offers services by using situational information. The field where context-rich systems were first introduced is near-field communication (NFC)-based electronic payments. Near-field Communication (NFC) integrated payment services collect the payment information of the credit card and the location information to generate patterns in the user’s consumption or movement through big data technology. Based on such pattern information, tailored services, such as advertisement, are offered to users. However, there is difficulty in controlling access to personal information, as there is a collaborative relationship focused on the trusted service manager (TSM) that is close knit to shared personal information. Moreover, in the case of Hadoop, among the many big data analytical technologies, it offers access control functions, but not a way to authorize the processing of personal information, making it impossible to grant authority between service providers to process information. As such, this paper proposes a key generation and distribution method, as well as a secure communication protocol. The analysis has shown that the efficiency was greater for security and performance compared to relation works.

Beschreibung: Assimilation of Antarctic velocity observations provides evidence for uncharted pinning points The Cryosphere, 9, 1427-1443, 2015 Author(s): J. J. Fürst, G. Durand, F. Gillet-Chaulet, N. Merino, L. Tavard, J. Mouginot, N. Gourmelen, and O. Gagliardini In ice flow modelling, the use of control methods to assimilate the dynamic and geometric state of an ice body has become common practice. These methods have primarily focussed on inverting for one of the two least known properties in glaciology, namely the basal friction coefficient or the ice viscosity parameter. Here, we present an approach to infer both properties simultaneously for the whole of the Antarctic ice sheet. After the assimilation, the root-mean-square deviation between modelled and observed surface velocities attains 8.7 m a −1 for the entire domain, with a slightly higher value of 14.0 m a −1 for the ice shelves. An exception in terms of the velocity mismatch is the Thwaites Glacier Ice Shelf, where the RMS value is almost 70 m a −1 . The reason is that the underlying Bedmap2 geometry ignores the presence of an ice rise, which exerts major control on the dynamics of the eastern part of the ice shelf. On these grounds, we suggest an approach to account for pinning points not included in Bedmap2 by locally allowing an optimisation of basal friction during the inversion. In this way, the velocity mismatch on the ice shelf of Thwaites Glacier is more than halved. A characteristic velocity mismatch pattern emerges for unaccounted pinning points close to the marine shelf front. This pattern is exploited to manually identify seven uncharted features around Antarctica that exert significant resistance to the shelf flow. Potential pinning points are detected on Fimbul, West, Shackleton, Nickerson and Venable ice shelves. As pinning points can provide substantial resistance to shelf flow, with considerable consequences if they became ungrounded in the future, the model community is in need of detailed bathymetry there. Our data assimilation points to some of these dynamically important features not present in Bedmap2 and implicitly quantifies their relevance.

Beschreibung: We introduced an analysis to identify structural characterization of two-dimensional regular and amorphous networks. The analysis was shown to be reliable to determine the global network rigidity and can also identify local floppy regions in the mixture of rigid and floppy regions. The eigenmode analysis explores the structural properties of various networks determined by eigenvalue spectra. It is useful to determine the general structural stability of networks that the traditional Maxwell counting scheme based on the statistics of nodes (degrees of freedom) and bonds (constraints) does not provide. A visual characterization scheme was introduced to examine the local structure characterization of the networks. The eigenmode analysis is under development for various practical applications on more general network structures characterized by coordination numbers and nodal connectivity such as graphenes and proteins.

Beschreibung: Atomic force microscope with applicable types of operation in a liquid environment is widely used to scan the contours of biological specimens. The contact mode of operation allows a tip to touch a specimen directly but sometimes it damages the specimen; thus, a tapping mode of operation may replace the contact mode. The tapping mode triggers the cantilever of the microscope approximately at resonance frequencies, and so the tip periodically knocks the specimen. It is well known that the cantilever induces extra liquid pressure that leads to drift in the resonance frequency. Studies have noted that the heights of protein surfaces measured via the tapping mode of an atomic force microscope are ~25% smaller than those measured by other methods. This discrepancy may be attributable to the induced superficial hydrodynamic pressure, which is worth investigating. In this paper, we introduce a semi-analytical method to analyze the pressure distribution of various tip geometries. According to our analysis, the maximum hydrodynamic pressure on the specimen caused by a cone-shaped tip is ~0.5 Pa, which can, for example, pre-deform a cell by several nanometers in compression before the tip taps it. Moreover, the pressure calculated on the surface of the specimen is 20 times larger than the pressure without considering the tip effect; these results have not been motioned in other papers. Dominating factors, such as surface heights of protein surface, mechanical stiffness of protein increasing with loading velocity, and radius of tip affecting the local pressure of specimen, are also addressed in this study.

Beschreibung: This study explores the potential of Synthetic Aperture Radar (SAR) to aid Unmanned Aerial Vehicle (UAV) navigation when Inertial Navigation System (INS) measurements are not accurate enough to eliminate drifts from a planned trajectory. This problem can affect medium-altitude long-endurance (MALE) UAV class, which permits heavy and wide payloads (as required by SAR) and flights for thousands of kilometres accumulating large drifts. The basic idea is to infer position and attitude of an aerial platform by inspecting both amplitude and phase of SAR images acquired onboard. For the amplitude-based approach, the system navigation corrections are obtained by matching the actual coordinates of ground landmarks with those automatically extracted from the SAR image. When the use of SAR amplitude is unfeasible, the phase content can be exploited through SAR interferometry by using a reference Digital Terrain Model (DTM). A feasibility analysis was carried out to derive system requirements by exploring both radiometric and geometric parameters of the acquisition setting. We showed that MALE UAV, specific commercial navigation sensors and SAR systems, typical landmark position accuracy and classes, and available DTMs lead to estimated UAV coordinates with errors bounded within ±12 m, thus making feasible the proposed SAR-based backup system.

Beschreibung: This paper demonstrates an automated computer vision system for outdoor tree crop enumeration in a seedling nursery. The complete system incorporates both hardware components (including an embedded microcontroller, an odometry encoder, and an uncalibrated digital color camera) and software algorithms (including microcontroller algorithms and the proposed algorithm for tree crop enumeration) required to obtain robust performance in a natural outdoor environment. The enumeration system uses a three-step image analysis process based upon: (1) an orthographic plant projection method integrating a perspective transform with automatic parameter estimation; (2) a plant counting method based on projection histograms; and (3) a double-counting avoidance method based on a homography transform. Experimental results demonstrate the ability to count large numbers of plants automatically with no human effort. Results show that, for tree seedlings having a height up to 40 cm and a within-row tree spacing of approximately 10 cm, the algorithms successfully estimated the number of plants with an average accuracy of 95.2% for trees within a single image and 98% for counting of the whole plant population in a large sequence of images.

Beschreibung: Long-term coastal-polynya dynamics in the Southern Weddell Sea from MODIS thermal-infrared imagery The Cryosphere Discussions, 9, 3959-3993, 2015 Author(s): S. Paul, S. Willmes, and G. Heinemann Based upon high-resolution thermal-infrared Moderate-Resolution Imaging Spectroradiometer (MODIS) satellite imagery in combination with ERA-Interim atmospheric reanalysis data, we derived long-term polynya parameters such as polynya area, thin-ice thickness distribution and ice-production rates from daily cloud-cover corrected thin-ice thickness composites. Our study is based on a thirteen year investigation period (2002–2014) for the austral winter (1 April to 30 September) in the Antarctic Southern Weddell Sea. The focus lies on coastal polynyas which are important hot spots for new-ice formation, bottom-water formation and heat/moisture release into the atmosphere. MODIS has the capability to resolve even very narrow coastal polynyas. Its major disadvantage is the sensor limitation due to cloud cover. We make use of a newly developed and adapted spatial feature reconstruction scheme to account for cloud-covered areas. We find the sea-ice areas in front of Ronne and Brunt Ice Shelf to be the most active with an annual average polynya area of 3018 ± 1298 and 3516 ± 1420 km 2 as well as an accumulated volume ice production of 31 ± 13 and 31 ± 12 km 3 , respectively. For the remaining four regions, estimates amount to 421 ± 294 km 2 and 4 ± 3 km 3 (Antarctic Peninsula), 1148 ± 432 km 2 and 12 ± 5 km 3 (Iceberg A23A), 901 ± 703 km 2 and 10 ± 8 km 3 (Filchner Ice Shelf) as well as 499 ± 277 km 2 and 5 ± 2 km 3 (Coats Land). Our findings are discussed in comparison to recent studies based on coupled sea-ice/ocean models and passive-microwave satellite imagery, each investigating different parts of the Southern Weddell Sea.

Beschreibung: Climatic controls and climate proxy potential of Lewis Glacier, Mt Kenya The Cryosphere Discussions, 9, 3887-3924, 2015 Author(s): R. Prinz, L. I. Nicholson, T. Mölg, W. Gurgiser, and G. Kaser The Lewis Glacier on Mt Kenya is one of the best studied tropical glaciers and has experienced considerable retreat since a maximum extent in the late 19th century (L19). From distributed mass and energy balance modelling, this study evaluates the current sensitivity of the surface mass and energy balance to climatic drivers, explores climate conditions under which the L19 maximum extent might have sustained, and discusses the potential for using the glacier retreat to quantify climate change. Multiyear meteorological measurements at 4828 m provide data for input, optimization and evaluation of a spatially distributed glacier mass balance model to quantify the exchanges of energy and mass at the glacier–atmosphere interface. Currently the glacier loses mass due to the imbalance between insufficient accumulation and enhanced melt, because radiative energy gains cannot be compensated by turbulent energy sinks. Exchanging model input data with synthetic climate scenarios, which were sampled from the meteorological measurements and account for coupled climatic variable perturbations, reveal that the current mass balance is most sensitive to changes in atmospheric moisture (via its impact on solid precipitation, cloudiness and surface albedo). Positive mass balances result from scenarios with an increase of annual (seasonal) accumulation of 30 % (100 %), compared to values observed today, without significant changes in air temperature required. Scenarios with lower air temperatures are drier and associated with lower accumulation and increased net radiation due to reduced cloudiness and albedo. If the scenarios currently producing positive mass balances are applied to the L19 extent, negative mass balances are the result, meaning that the conditions required to sustain the glacier in its L19 extent are not reflected in today's observations. Alternatively, a balanced mass budget for the L19 extent can be explained by changing model parameters that imply a distinctly different coupling between the glacier's local surface-air layer and its surrounding boundary-layer. This result underlines the difficulty of deriving paleoclimates for larger glacier extents on the basis of modern measurements of small glaciers.

Beschreibung: Drainage networks are essential compartments in an urban infrastructure system for the efficient collection and prompt drainage of flood water. In addition to the advances in numerical techniques on urban flood simulation, the topological characteristics of urban drainage networks and their impacts on flooding have not been investigated thoroughly despite their importance. This study evaluated the urban drainage networks in Seoul, South Korea, in terms of the network configuration and its implication for peak flows and flood mitigation. Gibbs’ model was used to analyze the network configuration of 31 urban catchments with various slope ranges. The results showed that urban drainage networks can be less efficient than river in nature in terms of the drainage time, which is counter-intuitive. On the other hand, the analysis showed that efficient networks have risks of flood concentration and, hence, increase potential flood risks. This study showed that efficient networks tend to have higher peak flows at the outlet and vice versa. Therefore, an alternative drainage network layout, which is less efficient and more sinuous, was introduced and it resulted in reduced peak flows and flooding. This result shows managing a proper drainage network layout can contribute to flood mitigation in urban catchments.

Beschreibung: A Web-based spatial decision supporting system for land management and soil conservation Solid Earth, 6, 903-928, 2015 Author(s): F. Terribile, A. Agrillo, A. Bonfante, G. Buscemi, M. Colandrea, A. D'Antonio, R. De Mascellis, C. De Michele, G. Langella, P. Manna, L. Marotta, F. A. Mileti, L. Minieri, N. Orefice, S. Valentini, S. Vingiani, and A. Basile Today it is evident that there are many contrasting demands on our landscape (e.g. food security, more sustainable agriculture, higher income in rural areas, etc.) as well as many land degradation problems. It has been proved that providing operational answers to these demands and problems is extremely difficult. Here we aim to demonstrate that a spatial decision support system based on geospatial cyberinfrastructure (GCI) can address all of the above, so producing a smart system for supporting decision making for agriculture, forestry, and urban planning with respect to the landscape. In this paper, we discuss methods and results of a special kind of GCI architecture, one that is highly focused on land management and soil conservation. The system allows us to obtain dynamic, multidisciplinary, multiscale, and multifunctional answers to agriculture, forestry, and urban planning issues through the Web. The system has been applied to and tested in an area of about 20 000 ha in the south of Italy, within the framework of a European LIFE+ project (SOILCONSWEB). The paper reports – as a case study – results from two different applications dealing with agriculture (olive growth tool) and environmental protection (soil capability to protect groundwater). Developed with the help of end users, the system is starting to be adopted by local communities. The system indirectly explores a change of paradigm for soil and landscape scientists. Indeed, the potential benefit is shown of overcoming current disciplinary fragmentation over landscape issues by offering – through a smart Web-based system – truly integrated geospatial knowledge that may be directly and freely used by any end user ( www.landconsultingweb.eu ). This may help bridge the last very important divide between scientists working on the landscape and end users.

Beschreibung: Towards predictive data-driven simulations of wildfire spread – Part II: Ensemble Kalman Filter for the state estimation of a front-tracking simulator of wildfire spread Natural Hazards and Earth System Science, 15, 1721-1739, 2015 Author(s): M. C. Rochoux, C. Emery, S. Ricci, B. Cuenot, and A. Trouvé This paper is the second part in a series of two articles, which aims at presenting a data-driven modeling strategy for forecasting wildfire spread scenarios based on the assimilation of the observed fire front location and on the sequential correction of model parameters or model state. This model relies on an estimation of the local rate of fire spread (ROS) as a function of environmental conditions based on Rothermel's semi-empirical formulation, in order to propagate the fire front with an Eulerian front-tracking simulator. In Part I, a data assimilation (DA) system based on an ensemble Kalman filter (EnKF) was implemented to provide a spatially uniform correction of biomass fuel and wind parameters and thereby, produce an improved forecast of the wildfire behavior (addressing uncertainties in the input parameters of the ROS model only). In Part II, the objective of the EnKF algorithm is to sequentially update the two-dimensional coordinates of the markers along the discretized fire front, in order to provide a spatially distributed correction of the fire front location and thereby, a more reliable initial condition for further model time-integration (addressing all sources of uncertainties in the ROS model). The resulting prototype data-driven wildfire spread simulator is first evaluated in a series of verification tests using synthetically generated observations; tests include representative cases with spatially varying biomass properties and temporally varying wind conditions. In order to properly account for uncertainties during the EnKF update step and to accurately represent error correlations along the fireline, it is shown that members of the EnKF ensemble must be generated through variations in estimates of the fire's initial location as well as through variations in the parameters of the ROS model. The performance of the prototype simulator based on state estimation (SE) or parameter estimation (PE) is then evaluated by comparison with data taken from a reduced-scale controlled grassland fire experiment. Results indicate that data-driven simulations are capable of correcting inaccurate predictions of the fire front location and of subsequently providing an optimized forecast of the wildfire behavior at future lead times. The complementary benefits of both PE and SE approaches, in terms of analysis and forecast performance, are also emphasized. In particular, it is found that the size of the assimilation window must be specified adequately with the persistence of the model initial condition and/or with the temporal and spatial variability of the environmental conditions in order to track sudden changes in wildfire behavior. The present prototype data-driven forecast system is still at an early stage of development. In this regard, this preliminary investigation provides valuable information on how to combine observations with a fire spread model in an efficient way, as well as guidelines to design the future system evolution in order to meet the operational requirements of wildfire spread monitoring.

Beschreibung: High resolution satellite turbidity and sea surface temperature observations of river plume interactions during a significant flood event Ocean Science Discussions, 12, 1669-1692, 2015 Author(s): V. E. Brando, F. Braga, L. Zaggia, C. Giardino, M. Bresciani, D. Bellafiore, C. Ferrarin, F. Maicu, A. Benetazzo, D. Bonaldo, F. M. Falcieri, A. Coluccelli, A. Russo, and S. Carniel Sea surface temperature (SST) and turbidity ( T ) derived from Landsat-8 (L8) imagery were used to characterize river plumes in the Northern Adriatic Sea (NAS) during a significant flood event in November 2014. Sea surface salinity (SSS) from an operational coupled ocean-wave model supported the interpretation of the plumes interaction with the receiving waters and among them. There was a good agreement of the SSS, T , and SST fields at the sub-mesoscale and mesoscale delineation of the major river plumes. L8 30 m resolution enabled also the description of smaller plume structures. Sharp fronts in T and SST delimited each single river plume. The isotherms and turbidity isolines coupling varied among the plumes due to differences in particle loads and surface temperatures in the discharged waters. The different plumes reflectance spectra were related to the lithological fingerprint of the sediments in the river catchments.

Beschreibung: Sea level trend and variability around Peninsular Malaysia Ocean Science, 11, 617-628, 2015 Author(s): Q. H. Luu, P. Tkalich, and T. W. Tay Sea level rise due to climate change is non-uniform globally, necessitating regional estimates. Peninsular Malaysia is located in the middle of Southeast Asia, bounded from the west by the Malacca Strait, from the east by the South China Sea (SCS), and from the south by the Singapore Strait. The sea level along the peninsula may be influenced by various regional phenomena native to the adjacent parts of the Indian and Pacific oceans. To examine the variability and trend of sea level around the peninsula, tide gauge records and satellite altimetry are analyzed taking into account vertical land movements (VLMs). At annual scale, sea level anomalies (SLAs) around Peninsular Malaysia on the order of 5–25 cm are mainly monsoon driven. Sea levels at eastern and western coasts respond differently to the Asian monsoon: two peaks per year in the Malacca Strait due to South Asian–Indian monsoon; an annual cycle in the remaining region mostly due to the East Asian–western Pacific monsoon. At interannual scale, regional sea level variability in the range of ±6 cm is correlated with El Niño–Southern Oscillation (ENSO). SLAs in the Malacca Strait side are further correlated with the Indian Ocean Dipole (IOD) in the range of ±5 cm. Interannual regional sea level falls are associated with El Niño events and positive phases of IOD, whilst rises are correlated with La Niña episodes and negative values of the IOD index. At seasonal to interannual scales, we observe the separation of the sea level patterns in the Singapore Strait, between the Raffles Lighthouse and Tanjong Pagar tide stations, likely caused by a dynamic constriction in the narrowest part. During the observation period 1986–2013, average relative rates of sea level rise derived from tide gauges in Malacca Strait and along the east coast of the peninsula are 3.6±1.6 and 3.7±1.1 mm yr −1 , respectively. Correcting for respective VLMs (0.8±2.6 and 0.9±2.2 mm yr −1 ), their corresponding geocentric sea level rise rates are estimated at 4.4±3.1 and 4.6±2.5 mm yr −1 . The geocentric rates are about 25 % faster than those measured at tide gauges around the peninsula; however, the level of uncertainty associated with VLM data is relatively high. For the common period between 1993 and 2009, geocentric sea level rise values along the Malaysian coast are similar from tide gauge records and satellite altimetry (3.1 and 2.7 mm yr −1 , respectively), and arguably correspond to the global trend.

Beschreibung: Yield and quality estimations provide vital information to fruit growers, yet require accurate monitoring throughout the growing season. To this end, the temporal dependency of fruit yield and quality estimations through spectral vegetation indices was investigated in irrigated and rainfed pear orchards. Both orchards were monitored throughout three consecutive growing seasons, including spectral measurements (i.e., hyperspectral canopy reflectance measurements) as well as yield determination (i.e., total yield and number of fruits per tree) and quality assessment (i.e., fruit firmness, total soluble solids and fruit color). The results illustrated a clear association between spectral vegetation indices and both fruit yield and fruit quality (|r| > 0.75; p 〈 0.001). However, the correlations between vegetation indices and production variables varied throughout the growing season, depending on the phenological stage of fruit development. In the irrigated orchard, index values showed a strong association with production variables near time of harvest (|r| > 0.6; p 〈 0.001), while in the rainfed orchard, index values acquired during vegetative growth periods presented stronger correlations with fruit parameters (|r| > 0.6; p 〈 0.001). The improved planning of remote sensing missions during (rainfed orchards) and after (irrigated orchards) vegetative growth periods could enable growers to more accurately predict production outcomes and improve the production process.

Beschreibung: The combination of optical trapping with Raman spectroscopy provides a powerful method for the study, characterization, and identification of biological micro-particles. In essence, optical trapping helps to overcome the limitation imposed by the relative inefficiency of the Raman scattering process. This allows Raman spectroscopy to be applied to individual biological particles in air and in liquid, providing the potential for particle identification with high specificity, longitudinal studies of changes in particle composition, and characterization of the heterogeneity of individual particles in a population. In this review, we introduce the techniques used to integrate Raman spectroscopy with optical trapping in order to study individual biological particles in liquid and air. We then provide an overview of some of the most promising applications of this technique, highlighting the unique types of measurements enabled by the combination of Raman spectroscopy with optical trapping. Finally, we present a brief discussion of future research directions in the field.

Beschreibung: In this paper, we propose a novel extrinsic calibration method for camera networks using a sphere as the calibration object. First of all, we propose an easy and accurate method to estimate the 3D positions of the sphere center w.r.t. the local camera coordinate system. Then, we propose to use orthogonal procrustes analysis to pairwise estimate the initial camera relative extrinsic parameters based on the aforementioned estimation of 3D positions. Finally, an optimization routine is applied to jointly refine the extrinsic parameters for all cameras. Compared to existing sphere-based 3D position estimators which need to trace and analyse the outline of the sphere projection in the image, the proposed method requires only very simple image processing: estimating the area and the center of mass of the sphere projection. Our results demonstrate that we can get a more accurate estimate of the extrinsic parameters compared to other sphere-based methods. While existing state-of-the-art calibration methods use point like features and epipolar geometry, the proposed method uses the sphere-based 3D position estimate. This results in simpler computations and a more flexible and accurate calibration method. Experimental results show that the proposed approach is accurate, robust, flexible and easy to use.