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  • Ocean  (6)
  • In situ oceanic observations
  • Mesoscale processes
  • Massachusetts Institute of Technology and Woods Hole Oceanographic Institution  (5)
  • American Geophysical Union  (1)
  • American Association for the Advancement of Science
  • 2015-2019  (6)
  • 1980-1984
  • 1970-1974
  • 1
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2017
    Description: This thesis investigates the formation and subsequent motion of oceanic lithospheric plates through geophysical and petrological methods. Ocean crust and lithosphere forms at mid-ocean ridges as the underlying asthenosphere rises, melts, and flows away from the ridge axis. In Chapters 2 and 3, I present the results from partial melting experiments of mantle peridotite that were conducted in order to examine the mantle melting point, or solidus, beneath a mid-ocean ridge. Chapter 2 determines the peridotite solidus at a single pressure of 1.5 GPa and concludes that the oceanic mantle potential temperature must be ~60ºC hotter than current estimates. Chapter 3 goes further to provide a more accurate parameterization of the anhydrous mantle solidus from experiments over a range of pressures. This chapter concludes that the range of potential temperatures of the mantle beneath mid-ocean ridges and plumes is smaller than currently estimated. Once formed, the oceanic plate moves atop the underlying asthenosphere away from the ridge axis. Chapter 4 uses seafloor magnetotelluric data to investigate the mechanism responsible for plate motion at the lithosphere-asthenosphere boundary. The resulting two dimensional conductivity model shows a simple layered structure. By applying petrological constraints, I conclude that the upper asthenosphere does not contain substantial melt, which suggests that either a thermal or hydration mechanism supports plate motion. Oceanic plate motion has dramatically changed the surface of the Earth over time, and evidence for ancient plate motion is obvious from detailed studies of the longer lived continental lithosphere. In Chapter 5, I investigate past plate motion by inverting magnetotelluric data collected over eastern Zambia. The conductivity model probes the Zambian lithosphere and reveals an ancient subduction zone previously suspected from surface studies. This chapter elucidates the complex lithospheric structure of eastern Zambia and the geometry of the tectonic elements in the region, which collided as a result of past oceanic plate motion. Combined, the chapters of this thesis provide critical constraints on ocean plate dynamics.
    Description: Funding for this research was provided by the National Science Foundation Division of Earth Sciences (EAR) grant number 1010432, Division of Ocean Sciences (OCE) grant numbers 1459649 and 0928663, WHOI Deep Ocean Exploration Institute, and the WHOI Academic Programs Office.
    Keywords: Lithosphere ; Ocean ; Temperature ; Mid-Atlantic Ridge
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 2
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-26
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution September 2019.
    Description: The Earth's oceans holds a wealth of information currently hidden from us. Effective measurement of its properties could provide a better understanding of our changing climate and insights into the creatures that inhabit its waters. Autonomous underwater vehicles (AUVs) hold the promise of penetrating the ocean environment and uncovering its mysteries; and progress in underwater robotics research over the past three decades has resulted in vehicles that can navigate reliably and operate consistently, providing oceanographers with an additional tool for studying the ocean. Unfortunately, the high cost of these vehicles has stifled the democratization of this technology. We believe that this is a consequence of two factors. Firstly, reliable navigation on conventional AUVs has been achieved through the use of a sophisticated sensor system, namely the Doppler velocity log (DVL)-aided inertial navigation system (INS), which drives up vehicle cost, power use and size. Secondly, deployment of these vehicles is expensive and unwieldy due to their complexity, size and cost, resulting in the need for specialized personnel for vehicle operation and maintenance. The recent development of simpler, low-cost, miniature underwater robots provides a solution that mitigates both these factors; however, removing the expensive DVL-aided INS means that they perform poorly in terms of navigation accuracy. We address this by introducing a novel acoustic system that enables AUV self-localization without requiring a DVL-aided INS or on-board active acoustic transmitters. We term this approach Passive Inverted Ultra-Short Baseline (piUSBL) positioning. The system uses a single acoustic beacon and a time-synchronized, vehicle-mounted, passive receiver array to localize the vehicle relative to this beacon. Our approach has two unique advantages: first, a single beacon lowers cost and enables easy deployment; second, a passive receiver allows the vehicle to be low-power, low-cost and small, and enables multi-vehicle scalability. Providing this new generation of small and inexpensive vehicles with accurate navigation can potentially lower the cost of entry into underwater robotics research and further its widespread use for ocean science. We hope that these contributions in low-cost underwater navigation will enable the ubiquitous and coordinated use of robots to explore and understand the underwater domain.
    Description: This research was funded and supported by a number of sponsors; we gratefully acknowledge them below. Defense Advanced Research Projects Agency (DARPA) and SSC Pacific via Applied Physical Sciences Corp. (APS) under contract number N66001-11-C-4115. SSC Pacific via Applied Physical Sciences Corp. (APS) under award number N66001-14-C-4031. Air Force via Lincoln Laboratory under award number FA8721-05-C-0002. Office of Naval Research (ONR) via University of California-San Diego under award number N00014-13-1-0632. Defense Advanced Research Projects Agency (DARPA) via Applied Physical Sciences Corp. (APS) under award number HR0011-18-C-0008. Office of Naval Research (ONR) under award number N00014-17-1-2474.
    Keywords: Ocean ; Submersibles ; Robotics ; Sound ; Navigation
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 3
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-26
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2018.
    Description: The biological carbon pump (BCP) helps to moderate atmospheric carbon dioxide levels by bringing carbon to the deep ocean, where it can be sequestered on timescales of centuries to millennia. Climate change is predicted to decrease the efficiency of the global BCP, however, the magnitude and timescale of this shift is largely uncertain and will likely impact some areas of the global ocean more significantly than others. Therefore, it is imperative that we (1) accurately quantify surface export and remineralization of particulate organic carbon (POC) via the BCP over large regions of the global ocean, (2) examine the factors controlling these POC fluxes and their variability, which includes the cycling of biologically-relevant trace metals, and (3) establish if and how the BCP is changing over time. This thesis focuses on addressing various aspects of these objectives using the 234Th-238U method across basin-scale GEOTRACES transects. First, the export and remineralization of POC were examined across large gradients in productivity, upwelling, community structure, and dissolved oxygen in the southeastern tropical Pacific Ocean. Although low oxygen zones are traditionally thought to have decreased POC flux attenuation relative to other regions of the global ocean and the low oxygen Pacific locations followed this pattern, regions that were functionally anoxic had enhanced attenuation in the upper 400 m. Second, trace metal export and remineralization were quantified across the Pacific transect. Because many trace metals are necessary for the metabolic functions of marine organisms and can co-limit marine productivity, the controls on the cycling of trace metals in the upper ocean were examined. Lastly, POC export was determined across two transects in the Western Arctic Ocean, where light and nutrient availability drive the biological pump. Upper ocean export estimates in the central basin did not reflect a substantial change in the biological pump compared to studies from the last three decades, however, an extensive maximum in 234Th relative to 238U deeper in the water column indicated that rapid vertical transport had occurred, which could suggest a more efficient biological pump in the Arctic Ocean.
    Description: I was funded under the NASA Earth and Space Science Fellowship Program grant (NNX13AP31H) for three years. I was also funded for work on the U.S. Pacific and Arctic GEOTRACES campaigns under two National Science Foundation grants (OCE-1232669 and OCE- 1458305). The MIT Henry G. Houghton Fund provided support for the purchase of computers and textbooks and the MIT Scurlock Fund allowed for my travel to Bermuda for cruise training. WHOI Academic Programs supplemented the aforementioned funding and also provided additional support for travel to conferences.
    Keywords: Carbon ; Climatic changes ; Ocean ; Thomas G. Thompson (Ship) Cruise TN303
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 4
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-26
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution February 2018
    Description: In the ocean, chromium (Cr) is a redox-sensitive trace metal. The reduction of Cr(VI) to Cr(III) occurs in oxygen deficient zones (ODZs), and Cr reduction in general has been identified as a significant Cr isotope fractionation mechanism. This thesis presents the first Cr isotope variations (d53Cr) in ODZs of the ocean and adds to the sparse Cr isotope data published for modern seawater. I developed a precise and accurate Cr isotope method for seawater samples. Seawater acidification converts total Cr to Cr(III) which is preconcentrated by Mg(OH)2 coprecipitation. A three-column anion exchange chromatography scheme separates Cr from isobaric and polyatomic interferences present in the seawater and reagent matrixes. Isotope analysis is performed on a MC-ICP-MS IsoProbe. The addition of a 50Cr-54Cr double spike allows for accurate correction of procedural and instrumental Cr mass fractionations. The first Cr isotope ratio data for a full water column profile in the Pacific Ocean is presented. This station serves as a fully oxic counterpart to stations located within the ODZ of the Eastern Tropical North Pacific. At one station, Cr concentrations are lower and d53Cr values are heavier within the ODZ. This is consistent with Cr reduction resulting in isotopically lighter, particlereactive Cr(III), which is scavenged and exported from the water column. A strong correlation of d53Cr and d15NNO3- at this station suggests that Cr reduction may be microbially mediated instead of simply being a product of thermodynamic equilibrium. Alternatively, Cr may be reduced by Fe(II). In the anoxic bottom waters of the Santa Barbara Basin a strong Cr reduction signal (lower [Cr], heavier d53Cr) is observed, which may result from the same aforementioned Cr reduction mechanisms. A shift to the heaviest seawater Cr isotope signatures yet observed was detected in the oxic bottom waters of the shallow Arctic Chukchi shelf, while Cr concentrations decreased. This extreme isotope signal may result from Cr reduction by a reduced species (e.g. Fe(II)), which was released from the underlying anoxic shelf sediments. Cr in the Atlantic layer and in the bottom water of a central Arctic station appears to be shaped by a novel, unidentified process.
    Description: This research was supported by the US National Science Foundation (NSF Award No. OCE- 0926197, OCE-1233749, OCE-1357224), the Singapore National Research Foundation through the Singapore-MIT Alliance for Research and Technology (Award No. WBS 6916070), and the Center for Microbial Research and Education (NSF-OIA Award No. EF-0424599). In the last year of my studies, I was supported by a MIT-WHOI Joint Program Science Fellowship.
    Keywords: Ocean ; Chromium ; Seawater ; Isotopes
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 5
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-26
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Physical Oceanography at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2019.
    Description: Global patterns of ocean salinity arise from the exchange of freshwater between the sea surface and the atmosphere. For a quasi-steady state system, these surface fluxes are balanced by compensating transports of salt in the ocean interior. In a warming climate, the atmosphere holds additional water vapor which acts to intensify the global water cycle. Amplified freshwater fluxes are then absorbed at the surface and propagate along ocean circulation pathways. Here, we use coupled model results from the CMIP5 experiment to identify coherent responses in the atmospheric water cycle and in ocean salinity patterns. Some aspects of the response are consistent across models, while other regions show large inter-model spread. In particular, the salinity response in the North Atlantic subpolar gyre, where the mean salinity plays a role in maintaining high surface density for deep-water formation, has low confidence in CMIP5 models. To understand how differences in ocean circulation may affect this response, we use two techniques to diagnose the role of salt transports in the present-day climate. The first is a salt budget within the surface mixed layer, which identifies major transport processes. The second is a Lagrangian particle tracking tool, used to understand the regional connectivity of water masses. From this analysis, we find that anomalous freshwater signals become well mixed within the ocean gyres, but can be isolated on larger scales. The subpolar Atlantic salinity response generally shows freshening at the surface, but is sensitive to the transport of anomalously salty water from the subtropics, a largely eddy-driven process. As CMIP5 models use a range of eddy parameterizations, this is likely a source of uncertainty in the salinity response. Finally, we investigate the effect of salinity changes on the deep overturning cells and other circulations, and find a complex influence that also depends on the details of advective pathways. In a warming scenario, water cycle amplification actually works to strengthen the Atlantic meridional overturning circulation due to the influence of enhanced subtropical evaporation.
    Description: Funding for this thesis was provided by NASA grant NNX12AF59GS03, a NASA Earth and Space Science Fellowship award 80NSSC17K0372, and the WHOI Academic Programs Office.
    Keywords: Salinity ; Climatic changes ; Ocean ; Dissertations, Academic ; North Atlantic Ocean
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
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  • 6
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Earth and Space Science, 6(7), (2019): 1220-1233, doi:10.1029/2018EA000436.
    Description: Ocean evaporative fluxes are a critical component of the Earth's energy and water cycle, but their estimation remains uncertain. Near‐surface humidity is a required input to bulk flux algorithms that relate mean surface values to the turbulent fluxes. Several satellite‐derived turbulent flux products have been developed over the last decade that utilize passive microwave imager observations to estimate the surface humidity. It is known, however, that these estimates tend to diverge from one another and from in situ observations. Analysis of current state‐of‐the‐art satellite estimates provided herein reveals that regional‐scale biases in these products remain significant. Investigations reveal a link between the spatial coherency of the observed biases to atmospheric dynamical controls of water vapor vertical stratification, cloud liquid water, and sea surface temperature. This information is used to develop a simple state‐dependent bias correction that results in more consistent ocean surface humidity estimates. A principal conclusion is that further improvements to ocean near‐surface humidity estimation using microwave radiometers requires incorporation of prior information on water vapor stratification and sea surface temperature.
    Description: Data products used in this study are made publicly available via multiple repositories hosted by individual data product producers. JOFUROv2 and JOFUROv3 data are available online (https://j‐ofuro.scc.u‐tokai.ac.jp/en/). IFREMERv4 and NOCS surface data are available through the OceanHeatFlux project (https://www.ifremer.fr/oceanheatflux/Data). GSSTFv3 (doi:10.5067/MEASURES/GSSTF/DATA301) and MERRA‐2 data are obtained from the Goddard Earth Sciences Data and Information Services Center. HOAPSv3.2 data are available from Satellite Application Facility on Climate Monitoring (https://doi.org/10.5676/EUM_SAF_CM/HOAPS/V001). SEAFLUXv2 data are accessed through the National Centers for Environmental Information (http://doi.org/10.7289/V59K4885). Daily surface observations were provided by David Berry and Elizabeth Kent. This work is supported under the NASA Physical Oceanography Program Grant NNX14AK48A.
    Keywords: Humidity ; Passive microwave ; Ocean ; Turbulent fluxes ; Evaporation ; Remote sensing
    Repository Name: Woods Hole Open Access Server
    Type: Article
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