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  • Other Sources  (11)
  • American Chemical Society (ACS)
  • American Institute of Physics
  • 2015-2019  (9)
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  • 1
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    American Institute of Physics
    In:  The Journal of the Acoustical Society of America, 138 (3). pp. 1253-1267.
    Publication Date: 2020-05-11
    Description: Responses obtained in consonant perception experiments typically show a large variability across stimuli of the same phonetic identity. The present study investigated the influence of different potential sources of this response variability. It was distinguished between source-induced variability, referring to perceptual differences caused by acoustical differences in the speech tokens and/or the masking noise tokens, and receiver-related variability, referring to perceptual differences caused by within- and across-listener uncertainty. Consonant-vowel combinations consisting of 15 consonants followed by the vowel /i/ were spoken by two talkers and presented to eight normal-hearing listeners both in quiet and in white noise at six different signal-to-noise ratios. The obtained responses were analyzed with respect to the different sources of variability using a measure of the perceptual distance between responses. The speech-induced variability across and within talkers and the across-listener variability were substantial and of similar magnitude. The noise-induced variability, obtained with time-shifted realizations of the same random process, was smaller but significantly larger than the amount of within-listener variability, which represented the smallest effect. The results have implications for the design of consonant perception experiments and provide constraints for future models of consonant perception.
    Type: Article , PeerReviewed
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  • 2
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    American Institute of Physics
    In:  The Journal of the Acoustical Society of America, 78 (6). pp. 2115-2121.
    Publication Date: 2020-05-11
    Description: The acoustic backscatter of eight well‐curated ferromanganese nodules has been measured in 1 °C seawater at frequencies from 45 to 167 kHz. The nodules have diameters from 37 to 121 mm and are thought to be representative of the Cu–Ni–Co‐rich nodules from the area around 14° 40’ N, 125° 25’ W (DOMES site C). They had been collected in box cores on the Echo 1 expedition and were kept refrigerated and water soaked in air‐tight plastic bags. Acoustic backscatter variations of over 10 dB were observed while the nodule was rotated 10° to 30° about one of its principal axes. The complicated fine structure, as well as the target strength, makes it clear that nodules cannot be modeled as simple spheres.
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  • 3
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    American Chemical Society (ACS)
    In:  Industrial & Engineering Chemistry Research, 56 (44). pp. 12755-12762.
    Publication Date: 2020-02-06
    Description: The discharges from industrial processes constitute the main source of copper contamination in aqueous ecosystems. In this study we investigated the capacity of different types of biochar (derived from chicken manure, eucalyptus, corncob, olive mill and pine sawdust) to remove copper from aqueous solution in a continuous-flow system. The flow rate of the system strongly influenced the amount of copper retained. The adsorption to the corncob biochar varied from 5.51 to 3.48 mg Cu g-1 as the flux decreased from 13 to 2.5 mL min-1. The physicochemical characteristics of biochar determine the copper retention capacity and the underlying immobilization mechanisms. Biochars with high inorganic contents retain the largest amounts of copper and may be suitable for using in water treatment systems to remove heavy metals. The copper retention capacity of the biochars ranged between ~1.3 and 26 mg g-1 and varied in the following order: chicken manure 〉 olive mill 〉〉 corncob 〉 eucalyptus 〉 sawdust pine.
    Type: Article , PeerReviewed
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  • 4
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    American Institute of Physics
    In:  Journal of the Acoustical Society of America, 78 (4). pp. 1348-1355.
    Publication Date: 2020-07-16
    Description: Additional data from sonobuoys and the Deep Sea Drilling Project (DSDP) justify separating sound‐velocity‐depth functions and velocity gradients (in the first layer of soft marine sediments) into some geographic areas and sediment types. Based on sonobuoy and core measurements (where V is sound velocity in km/s, and h is depth in sediments in km), the following data are obtained: continental shelf basins off Sumatra and Java—V=1.484+0.710h−0.085h2; U. S. Atlantic continental rise—V=1.513+0.828h−0.138h2; deep‐sea terrigenous sediments—V=1.519+1.227h−0.473h2; and siliceous sediments of the Bering Sea— V=1.509+0.869h−0.267h2. Selected DSDP data (through leg 74) in similar areas yield: continental terrace silt–clays—V=1.505+0.712h; deep‐sea terrigenous sediments—V=1.510+1.019h; and deep‐sea siliceous sediments—V=1.533+0.761h. Computed velocity gradients from sonobuoy measurements are generally supported by the DSDP gradients. Only DSDP data give the following: hemipelagic sediments—V=1.501+1.151h; deep‐sea calcareous sediments—V=1.541+0.928h; and deep‐sea pelagic clay—V=1.526+1.046h. Where fast sediment accumulation occurs, there has not been enough time to reduce sediment pore spaces under overburden pressure; areas of slow accumulation may have relatively high sediment structural strength. Both cases have lower velocity gradients because higher porosities and consequent lower velocities persist to deeper depths.
    Type: Article , PeerReviewed
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  • 5
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    American Institute of Physics
    In:  Journal of the Acoustical Society of America, 140 (4). pp. 2695-2702.
    Publication Date: 2020-07-16
    Description: The Green's function (GF) for the scalar wave equation is numerically constructed by an advanced geometric ray-tracing method based on the eikonal approximation related to the semiclassical propagator. The underlying theory is first briefly introduced, and then it is applied to acoustics and implemented in a ray-tracing-type numerical simulation. The so constructed numerical method is systematically used to calculate the sound field in a rectangular (cuboid) room, yielding also the acoustic modes of the room. The simulated GF is rigorously compared to its analytic approximation. Good agreement is found, which proves the devised numerical approach potentially useful also for low frequency acoustic modeling, which is in practice not covered by geometrical methods.
    Type: Article , PeerReviewed
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  • 6
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    American Chemical Society (ACS)
    In:  Environmental Science & Technolog, 51 (23). pp. 13733-13739.
    Publication Date: 2020-02-06
    Description: The majority of methane produced in many anoxic sediments is released via ebullition. These bubbles are subject to dissolution as they rise, and dissolution rates are strongly influenced by bubble size. Current understanding of natural methane bubble size distributions is limited by the difficulty in measuring bubble sizes over wide spatial or temporal scales. Our custom optical bubble size sensors recorded bubble sizes and release timing at 8 locations in Upper Mystic Lake, MA continuously for 3 months. Bubble size distributions were spatially heterogeneous even over relatively small areas experiencing similar flux, suggesting that localized sediment conditions are important to controlling bubble size. There was no change in bubble size distributions over the 3 month sampling period, but mean bubble size was positively correlated with daily ebullition flux. Bubble data was used to verify the performance of a widely used bubble dissolution model, and the model was then used to estimate that bubble dissolution accounts for approximately 10% of methane accumulated in the hypolimnion during summer stratification, and at most 15% of the diffusive air–water–methane flux from the epilimnion.
    Type: Article , PeerReviewed
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  • 7
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    American Chemical Society (ACS)
    In:  Environmental Science & Technology, 49 (22). pp. 13121-13129.
    Publication Date: 2019-10-24
    Description: Laboratory sediment incubations and continuous ebullition monitoring over an annual cycle in the temperate Saar River, Germany confirm that impounded river zones can produce and emit methane at high rates (7 to 30 (g CH4 m–3 d–1) at 25 °C and 270 to 700 (g CH4 m–2 yr–1), respectively). Summer methane ebullition (ME) peaks were a factor of 4 to 10 times the winter minima, and sediment methane formation was dominated by the upper sediment (depths of 0.14 to 0.2 m). The key driver of the seasonal ME dynamics was temperature. An empirical model relating methane formation to temperature and sediment depth, derived from the laboratory incubations, reproduced the measured daily ebullition from winter to midsummer, although late summer and autumn simulated ME exceeded the observed ME. A possible explanation for this was substrate limitation. We recommend measurements of methanogenically available carbon sources to identify substrate limitation and help characterize variation in methane formation with depth and from site to site.
    Type: Article , PeerReviewed
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  • 8
    Publication Date: 2020-01-02
    Description: Microplastics (MPs, 〈5 mm) have been reported as emerging environmental contaminants, but reliable data are still lacking. We compared the two most promising techniques for MP analysis, namely, Raman and Fourier transform infrared (FTIR) spectroscopy, by analyzing MPs extracted from North Sea surface waters. Microplastics 〉500 μm were visually sorted and manually analyzed by μ-Raman and attenuated total reflection (ATR)-FTIR spectroscopy. Microplastics ≤500 μm were concentrated on gold-coated filters and analyzed by automated single-particle exploration coupled to μ-Raman (ASPEx-μ-Raman) and FTIR imaging (reflection mode). The number of identified MPs 〉500 μm was slightly higher for μ-Raman (+23%) than ATR-FTIR analysis. Concerning MPs ≤500 μm, ASPEx-μ-Raman quantified two-times higher MP numbers but required a four-times higher analysis time compared to FTIR imaging. Because ASPEx-μ-Raman revealed far higher MP concentrations (38–2621 particles m–3) compared to the results of previous water studies (0–559 particles m–3), the environmental concentration of MPs ≤500 μm may have been underestimated until now. This may be attributed to the exceptional increase in concentration with decreasing MP size found in this work. Our results demonstrate the need for further research to enable time-efficient routine application of ASPEx-μ-Raman for reliable MP counting down to 1 μm.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2019-01-02
    Description: High-resolution 3D (HR3D) seismic data are important for hydrocarbon exploration of shallow reservoirs, site characterization, and geohazard assessments. The goal of this contribution is to identify and quantify the parameters to increase the resolution of HR3D seismic data to meter scale. The main acquisition parameters controlling the resolution of the collected data are the spectrum of the seismic source, source-receiver offset range, and trace density. An evolution to one-meter-scale resolution of 3D seismic will rely on combining a reproducible seismic source with high frequencies up to at least 600 Hz, a high uniform trace density of more than 4 million traces per square kilometer, and an offset range shorter than approximately 200 m. The resulting 3D seismic data volume will reach meter-scale resolution for water and target depths of less than 600 m. The proposed HR3D system will be suitable for 3D and 4D characterization of seabed properties and shallow stratigraphy, the identification of geohazards and hydrocarbon leakage, and monitoring the environmental impact of offshore activities. The P-Cable 3D system is an excellent starting point for achieving one-meter-scale resolution due to its flexible and tight meter-scale shot and receiver spacing.
    Type: Article , PeerReviewed
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  • 10
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    American Institute of Physics
    In:  Review of Scientific Instruments, 90 (12). p. 124504.
    Publication Date: 2021-01-08
    Description: Understanding mechanical interactions between hydrate and hosting sediments is critical for evaluating formation stability and associated environmental impacts of hydrate-bearing sediments during gas production. While core-scale studies of hydrate-bearing sediments are readily available and some explanations of observed results rely on pore-scale behavior of hydrate, actual pore-scale observations supporting the larger-scale phenomena are rarely available for hydrate-bearing sediments, especially with methane as guest molecules. The primary reasons for the scarcity include the challenge of developing tools for small-scale testing apparatus and pore-scale visualization capability. We present a testing assembly that combines pore-scale visualization and triaxial test capability of methane hydrate-bearing sediments. This testing assembly allows temperature regulation and independent control of four pressures: influent and effluent pore pressure, confining pressure, and axial pressure. Axial and lateral effective stresses can be applied independently to a 9.5 mm diameter and 19 mm long specimen while the pore pressure and temperature are controlled to maintain the stability of methane hydrate. The testing assembly also includes an X-ray transparent beryllium core holder so that 3D computed tomography scanning can be conducted during the triaxial loading. This testing assembly permits pore-scale exploration of hydrate-sediment interaction in addition to the traditional stress-strain relationship. Exemplary outcomes are presented to demonstrate applications of the testing assembly on geomechanical property estimations of methane-hydrate bearing sediments.
    Type: Article , PeerReviewed
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