ALBERT

Description: The photochemistry of diacetylene (C4H2), the largest hydrocarbon to be unambiguously identified in planetary atmospheres, is of considerable importance to understanding the mechanisms by which complex molecules are formed in the solar system. In this work, the primary products of C4H2's ultraviolet photochemistry were determined in a two-laser pump-probe scheme in which the products of C4H2 photoexcitation are detected by vacuum ultraviolet photoionization in a time-of-flight mass spectrometer. Three larger hydrocarbon primary products were observed with good yield in the C4H2 + C4H2 reaction: C6H2, C8H2, and C8H3. Neither C6H2 or C8H3 is anticipated by current photochemical models of the atmospheres of Titan, Uranus, Neptune, Pluto, and Triton. The free hydrogen atoms that are released during the formation of the C8H3 and C8H2 products also may partially offset the role of C4H2 in catalyzing the recombination of free hydrogen atoms in the planetary atmospheres.

Description: The study reviews the historical perspective of the Martian climate, beginning with the early view of inexorable climate change on an older, but otherwise very earthlike, planet and continuing through the period when earth-based spectroscopy and the Mariner 4, 6, and 7 flyby missions portrayed a moonlike body, heavily cratered and almost airless by comparison with earth. The most general features of the earth and Mars are discussed and compared, with consideration given to the standard atmospheres, atmospheric circulation, seasonal cycles of carbon dioxide, water, and dust, and coupling between cycles.

Description: The Pressure Modulator Infrared Radiometer (PMIRR) is an atmospheric sounder designed to observe temporal and spatial variations of water vapor and of dust suspended in the Mars atmosphere, to characterize the planetary-scale thermal structure and circulation of the atmosphere, and to quantify the polar radiative balance. These measurements are fundamental to understanding the seasonal cycles of dust, of water, and of CO2 on Mars and, in particular, to determining the role of atmospheric transport. Using measurements in eight narrow-band infrared spectral regions and one broadband visible channel, the PMIRR investigation teams at JPL and Oxford University will derive vertical profiles of atmospheric temperature, extinction due to suspended dust, and water vapor concentration, as well as locations of CO2 and H2O ice clouds. These data will be used in a variety of ways to address issues of atmospheric dynamics and transport. Three topics will be emphasized here: (1) the expected precision of the retrieved profiles of temperature, dust extinction, and water vapor, including plans for validating the profiles; (2) the observation strategy, designed to best use PMIRR's two-axis scan mirror, as deployed in the Mars Observer mapping orbit; and (3) approaches to mapping the atmospheric fields globally and the derivation of key meteorological fields related to estimating atmospheric transport.

Description: It has been known since the early Mariner 6, 7, and 9 missions that dust loading of the lower atmosphere and the subsequent aerosol heating during dusty periods impacts the martian middle and upper atmospheres. A quantitative measure of this lower atmosphere forcing was obtained by the Viking 1 and 2 landers, from which observed amplitudes of semidiurnal surface-pressure oscillations were correlated with normal-incidence dust optical depths. It appears that the dominant semidiurnal mode is a good indicator of global dust content or mean dust optical depth, especially during dust storm events. A classical tidal model that reproduces the surface pressure oscillations measured by these Viking landers in 1977 was used to calculate tidal amplitudes and phases up to approximately 43 km. These tidal characteristics were calculated for various dust optical depth conditions ranging from typical dusty periods to global dust storm times. Reasonable extrapolations can be made to higher altitudes if one assumes that the vertically propagating tidal modes continue to grow without dissipation or breaking. It is very likely that gravity waves also play an important role in the structure and dynamics of the middle atmosphere of Mars, since the large topographical relief should produce vigorous gravity wave fluxes. Semidiurnal tidal modes, significantly enhanced by lower atmosphere dust-induced heating, may indeed propagate to the Mars thermosphere (approximately less than 100 km) before breaking and generating turbulence. The preferential enhancement of the semidiurnal tides during dust storm onset is primarily due to the elevation of the tidal heating source in a very dusty atmosphere. The (2,2) semidiurnal tidal tidal mode was shown to have the largest variation with dust optical depth, as measured by Viking lander instruments. Also, the (2,2) mode has the largest vertical wavelength of all the semidiurnal tidal modes, and thus is most likely to penetrate into the thermosphere before breaking and to modify the largely in situ solar-driven behavior otherwise expected. The tides may also be partially responsible for determining the height of the martian homopause (approximately 125 km).

Description: The historical interest in the weather and climate of Mars and current understanding of aspects of the present climate are addressed. Scientific research into the weather and climate of Mars in the next century is examined. The impact of the Martian weather of the 21st century on humans that may then be inhabiting the planet is considered.

Description: Classical atmospheric tidal theory is extended to include the effects of large-amplitude planetary-scale variations of the terrain height. Utilizing simple models of the thermotidal forcing, the resulting technique is used to compute the diurnal tide in both the dust-free and the dust-laden Martian atmosphere. The main effect of the Martian variable terrain is to drive topographic tidal modes which can propagate vertically and to excite the possibly resonant diurnal Kelvin mode. The resulting surface wind can exceed 20 m/sec and may determine the preferred location for the initiation of global dust storms. In the middle Martian atmosphere (30-80 km) static and shear instabilities embedded within the tidal fields will generate extensive, though variable, regions of turbulence. Vertical mixing by this turbulence and transport by the tide itself may help to stabilize the middle Martian atmosphere against photolysis.

Description: Of the several size and nomenclature groupings of Martian dust storms, it is the plane-encircling or truly runaway dust storms that are of most concern to both the theoreticians and mission planners. Once believed to be regularly seasonal, it is now known that they are not annual occurrences and that the few we know about occurred within at least one-third of Mars' seasonal cycle. We cannot confirm that any were observed before 1956, and not one has been observed since 1982 (the classification of that event as 'encircling' is an interpretation of observation from a single point on the planet's surface). If these storms occur in cycles, we do not know the lengths or causes of the cycles. Regional and local dust storms occur more frequently and throughout the Martian year, but the underlying question is how do some become runaways, encircling the planet, while the others die out, usually within a few days. An investigation of this topic is presented.

Description: The complex refractive index in the solar spectral region is estimated. With this index and the size distribution estimated from the UVS data Mie theory is used to compute the radiative parameters required for including radiative scattering in simplified radiative transfer approximations. These approximations then enable the wavelength-integrated solar heating to be computed for various dust-laden Martian atmospheres. The calculations presented in the main body of the paper were computer using the delta-Eddington approximation.

Description: This paper examines the solar heating of the Martian atmosphere during the 1971 global dust storm observed by Mariner 9. Radiative scattering as well as absorption is included by utilizing the delta-Eddington approximation to the full radiative transfer equation. The necessary optical parameters are generated by a Mie program which uses a size distribution and a complex refractive index inferred from a number of sources, particularly from recent analyses of Mariner 9 UVS and TV observations. When uniform mixing of the dust is assumed, the solar heating per unit mass during a Martian global dust storm is remarkably uniform with height for small solar zenith angles. Heating rates may reach 80 K/day for overhead sunlight. Overall, 20% of the direct insolation is absorbed by the dust-laden atmosphere. Even optically thin widespread dust hazes may produce heating rates of several degrees Kelvin per day.

Description: The mass budget is detailed for system architectures that use rocket fuels of propellants derived from Deimos and Phobos to transport 10000 ton payloads of exofuel (exoatmospheric fuels) or exomass (exoatmospheric mass) to earth orbits. A point design for the system architecture is used that includes a self-sustaining cycle, which requires no materials from earth, and an infrastructure, which must be emplaced to start the cycle. Both the use of steam rockets and the use of liquid oxygen and liquid hydrogen is examined. It is shown that a system delivering 10000 tons of payload to a highly elliptical earth orbit requires approximately 23000 tons of water for use by nuclear heated steam rockets to effect completely propulsive, round trip maneuvers. It is also shown that about 8000 tons will be available for sale at low earth orbit, each cycle, and that the number of cycles can number in the tens before critical components are replaced.