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  • American Chemical Society  (130,601)
  • Oxford University Press  (23,294)
  • American Geophysical Union  (14,307)
  • 1985-1989  (168,202)
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  • 1
    Publication Date: 2022-04-12
    Description: Petrographic, mineralogic, and geochemical data are reported for lavas from two of the major shield volcanoes of the Santorini volcanic complex (Skaros and Micro Profitis Ilias), both of which were active prior to the well-known Minoan eruption with associated caldera collapse. Field work and whole-rock chemical analyses indicate four cycles of eruptive activity within the Skaros sequence and three within the Micro Profitis Ilias (M P1) sequence. SiO2 and LIL-element contents decrease from the base to the top of all cycles except for the uppermost cycle of Skaros. Chemical variations within cycles are interpreted to result from eruption from compositionally and thermally zoned magma chambers. Major oxide data and the results of least-squares, mass balance modeling indicate that fractional crystallization played an important role in the development of the observed chemical variations. However, observed systematic variations in groundmass compositions within each cycle, observed irregular variations in total phenocryst content and the results of density calculations require that generation of the chemical zonation did not involve crystal settling but reflects unstable density stratification, probably resulting from sidewall crystallization. Some of the primitive lavas erupted on Santorini preserve phenocryst and xenocryst evidence for a stage of high-pressure fractional crystallization (involving removal of olivine, clinopyroxene, orthopyroxene, and Cr-spinel). Trace element data combined with petrographic data (i.e. the occurrence of abundant phenocrysts with resorption textures) is taken as evidence that magma mixing was also important in the development of cyclic variations. Most basaltic andesites from Skaros appear to be hybrids derived by mixing of basalt and andesite/dacite. Mineralogic data demonstrate that mixing was also important in the development of zonation in the chambers beneath MPI, but trace element data cannot be explained by combined fractionation and mixing alone. Specifically, incompatible, and compatible element abundances are lower than predicted if fractionation and mixing occurred and it is suggested that the anomalous trace element behaviour of especially LIL elements reflects the simultaneous operation of assimilation, for which there is support from isotopic studies. It is concluded that inter- cyclic chemical variations are explicable in terms of fractionation, mixing and assimilation. The LIL element and highly compatible element concentrations in the most primitive lavas erupted in each cycle of Skaros and MPI increase with time, indicating that mixing became more important with time.
    Type: Article , PeerReviewed
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  • 2
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    Oxford University Press
    In:  Journal of Molluscan Studies, 52 . pp. 81-82.
    Publication Date: 2021-01-19
    Type: Article , PeerReviewed
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  • 3
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    American Geophysical Union
    In:  Journal of Geophysical Research, 93 (C12). pp. 15473-15483.
    Publication Date: 2020-11-18
    Description: The southern section of the Agulhas western boundary current system exhibits unique characteristics as regards ocean/atmosphere heat flux processes. The Agulhas Retroflection region's high heat flux core from 37°S to 41°S, 16°E to 22°E does not demonstrate a distinct annual cycle of turbulent heat fluxes (latent and sensible) as is characteristic of its northern hemisphere counterparts. Rather, a weak semiannual heat flux cycle is found with maximum average losses during winter and summer (200 and 211 W/m2 ) and minimum losses during spring and autumn (185 and 162 W/m2 ). Upstream where the Agulhas Current is closer to land, winter heat losses exceed those of summer, but the differences are small. This behavior contrasts with that encountered at the poleward ends of northern hemisphere western boundary currents where winter heat fluxes are several times those of summer. The main reason for this difference is persistent westerly and southwesterly wind flow over the Agulhas Retroflection region throughout the year which ensures that cold, unsaturated maritime air repeatedly forces loss of heat from the ocean's surface. Spatial heat flux gradients associated with the Agulhas‐Subtropical Convergence surface temperature front are more pronounced in summer than in winter, indicating that cyclogenesis locally may be less seasonally dependent than in the northern hemisphere situation. Average oceanic cooling rates in the core region of the Retroflection, based on net heat flux calculations and a mixed surface layer of 75 m, range from 1.35°C/month during winter to 0.25°C/month during summer. Interannual variability in ocean/atmosphere heat fluxes within the Agulhas Retroflection region often exceeds the variability illustrated by the annual cycle. West of the Agulhas Retroflection core region, interannual sea surface temperature (SST) anomalies are more influential in the generation of heat flux anomalies by virtue of their large temporal variability. This high SST variability is primarily attributed to interannual changes in flux of Agulhas Current water into the southeast Atlantic Ocean. Oceanic heat loss within this warm water zone is an important modifying influence to both ocean and atmosphere, thus meriting further research.
    Type: Article , PeerReviewed
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  • 4
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    Oxford University Press
    In:  Fems Microbiology Reviews, 39 . pp. 57-66.
    Publication Date: 2020-07-31
    Description: Osmotic adaption by halophilic and halotolerant bacteria is generally achieved by the accumulation or synthesis of several organic solutes. Accumulation by uptake from the medium is preferred over biosynthesis. The chemical nature of the major solute is important in determining the degree of osmotolerance of the organism. Glycine betaine accumulation confers a greater degree of osmotolerance than proline, which in turn confers more osmotolerance than glutamate accumulation. The occurrence and uptake of these solutes in a variety of eubacteria is reviewed.
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  • 5
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    American Geophysical Union
    In:  Journal of Geophysical Research, 94 (B5). pp. 5585-5602.
    Publication Date: 2019-10-14
    Description: We examine the closure of the current plate motion circuit between the African, North American, and Eurasian plates to test whether these plates are rigid and whether the Gloria fault is an active transform fault. We also investigate the possible existence of microplates that have been previously proposed to lie along these plate boundaries, and compare the predicted direction of motion along the African‐Eurasian plate boundary in the Mediterranean with the direction of slip observed in earthquakes. From marine geophysical data we obtain 13 transform fault azimuths and 40 3‐m.y.‐average spreading rates, 34 of which are determined from comparison of synthetic magnetic anomaly profiles to ∼140 observed profiles. Slip vectors from 32 earthquake focal mechanisms further describe plate motion. Detailed magnetic surveys north of Iceland provide 11 rates in a region where prior plate motion models had few data. Magnetic profiles north of the Azores triple junction record a rate of 24 mm/yr, 4 mm/yr slower than used by prior models. Gloria and Sea Beam surveys accurately measure the azimuths of seven transform faults; our plate motion model fits six of the seven within 2°. Two transform faults surveyed by Gloria side scan sonar lie near FAMOUS area transform faults A and B and give azimuths 13° clockwise of them. Because recent studies show that short‐offset transforms, such as transforms A and B, are in many places oblique to the direction of plate motion, we exclude azimuths from transforms with less than 35‐km offset. The best fitting and closure‐enforced vectors fit the data well, except for a small systematic misfit to the slip vectors: On right‐lateral slipping transforms, slip vectors tend to be a few degrees clockwise of plate motion and mapped fault azimuths, whereas on left‐lateral slipping transforms, slip vectors tend to be a few degrees counterclockwise of plate motion and mapped fault azimuths. We search the long Eurasia‐North America boundary for evidence of an additional plate, but find no systematic misfits to the data. In particular, if a Spitsbergen plate exists and moves relative to Eurasia, its motion is less than 3 mm/yr. An Africa‐Eurasia Euler vector determined by adding the Eurasia‐North America and Africa‐North America Euler vectors is consistent with the Gloria fault trend and with slip vectors from eastern Azores‐Gibraltar Ridge focal mechanisms. A small circle, centered at the Africa‐Eurasia closure‐enforced pole, fits the trace of the Gloria fault. The model in which closure was enforced predicts ∼4 mm/yr slip across the Azores‐Gibraltar Ridge, and west‐northwest convergence near Gibraltar, ∼45° more oblique than suggested by a recent model based on compressive axes of focal mechanisms. Moreover, our model predicts directions of plate motion that agree well with northwest trending slip vectors from thrust earthquakes between Gibraltar and Sicily. Because closure‐enforced vectors fit the data nearly as well as the best fitting vectors, we conclude that the data are consistent with a rigid plate model and with the Gloria fault being a transform fault.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 1989-12-18
    Print ISSN: 0009-2347
    Electronic ISSN: 1520-605X
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 7
    Publication Date: 1989-12-18
    Print ISSN: 0009-2347
    Electronic ISSN: 1520-605X
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 8
    Publication Date: 1989-12-18
    Print ISSN: 0009-2347
    Electronic ISSN: 1520-605X
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 9
    Publication Date: 1989-12-18
    Print ISSN: 0009-2347
    Electronic ISSN: 1520-605X
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 10
    Publication Date: 1989-12-18
    Print ISSN: 0009-2347
    Electronic ISSN: 1520-605X
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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