ALBERT

Description: PI3K biology; lymphoma; cancer

Description: oncogenic drivers; signaling; pathways; hematologic malignancies; cancer

Description: The Pomici di Avellino eruption is the Plinian event of Vesuvius with the highest territorial impact. It affected an area densely inhabited by Early Bronze Age human communities and resulted in the long- term abandonment of an extensive zone surrounding the volcano. Traces of human life beneath the eruption products are very common throughout the Campania Region. A systematic review of the available archaeological data, the study of geological and archaeological sequences exposed in excava- tions, and the reconstruction of the volcanic phenomena affecting single sites has yielded an under- standing of local effects and their duration. The archaeological and volcanological analyses have shown that the territory was rapidly abandoned before and during the eruption, with rare post-eruption at- tempts at resettlement of the same sites inhabited previously. The definition of the distribution and stratigraphy of alluvial deposits in many of the studied sequences leads us to hypothesise that the scarce presence of humans during phases 1 and 2 of the Middle Bronze Age in the wide area affected by the eruption was due to diffuse phenomena of remobilisation of the eruption products, generating long- lasting alluvial processes. These were favoured by the deposition of loose fine pyroclastic material on the slopes of the volcano and the Apennines, and by climatic conditions. A significant resettlement of the territory occurred only hundreds of years after the Pomici di Avellino eruption, during phase 3 of the Middle Bronze Age. This study show the role of volcanic and related phenomena from a Plinian event in the settlement dynamics of a complex territory like Campania.

Description: Published

Description: 231-244

Description: 1V. Storia eruttiva

Description: 5V. Dinamica dei processi eruttivi e post-eruttivi

Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio

Description: JCR Journal

Description: Ground deformations are among the main volcanic phenomena occurring within the caldera system and pres- ently recorded at different volcanoes worldwide including the Campi Flegrei active caldera (southern Italy). A new stratigraphic, sedimentological and paleontological survey carried out in the central sector of the Campi Flegrei caldera both along the already known La Starza succession and through a new excavated tunnel provided new insights into the ground movement episodes occurred in the last 15 kyr. This study, which has also benefited of unpublished boreholes stratigraphic data, shows that the most uplifted sector of the Campi Flegrei caldera, presently marked by the morphological structure of the La Starza cliff close to the Pozzuoli coastline, was charac- terized by a complex sedimentary evolution. It results from different phases of alternating marine transgressions and regressions, the latter marked by both continental volcanic and/or palustrine/lacustrine sediments. These al- ternations result from the interplay between (i) subsidence and uplift episodes of the caldera floor and (ii) sea level variations during the Holocene. A rest period of volcanism accompanied by a sea level rise determined a sig- nificant submersion phase in about 3000 years between 8.59 and 5.5 ka. This phase was defined by a sea level with a maximum water depth value of 60–80 m and a late stage recording significant episodes of ground move- ments. Subsequently, between 5.5 and 3.5 ka, a ground uplift of about 100 m occurred, with short subsidence around 4.5 ka following the Plinian Agnano-Monte Spina eruption. The net vertical displacement represents the recorded deformation linked with a volcanism period in which ~2.5 km3 of magma were erupted by different vents within the caldera. It is worth to note as the general trend of ground movement through the time indicates a similarity in the pattern, beyond its scale.

Description: Published

Description: 143-158

Description: 1V. Storia eruttiva

Description: JCR Journal

Description: In this study we combine seismological and GOCE satellite gravity information by using a Bayesian-like technique, with the aim of inferring the density structure of the Pacific (90°N 90°S) (121°E 60°W) lithosphere and upper mantle. We recover a 1° × 1° 3-D density model, down to 300 km depth, which explains gravity observations with a variance reduction of 67.41%. The model, with an associated a posteriori standard deviation, provides a significant contribution to understanding the evolution of the Pacific lithosphere and answers to some debated geodynamic questions. Our methodology enables us to combine the recovery of density parameters with the optimum density-vSV scalings. The latter account for both seismological and gravity observations in order to identify the regions characterized by chemically-induced density heterogeneities which add to the thermally-induced anoma- lies. Chemically-modified structures are found west of the East Pacific Rise (EPR) and are of relevant amplitude both below the north-western side of the Pacific Plate, at the base of the lithosphere, and up to 100 km depth beneath the Hawaiian and Super Swell regions, thus explaining the anomalous shallow regions without invoking the thermal buoyancy as the sole justification. Coherently with the chemically modified structures, our results a) support a lighter and more buoyant lithosphere than that predicted by the cooling models and b) are in favor of the hypothesized crustal underplating beneath the Hawaiian chain and be- neath the volcanic units in the southern branch of the Super Swell region. The comparison between calculated mantle gravity residuals and residual topography a) suggests a lateral viscosity growth associated with the increasing thickness and density of the Plate and b) correlates well with sub-lithospheric mantle flow from the EPR towards west, up to the Kermadec and Tonga Trench in the south and the Kuril-Kamchatka Trench in the north.

Description: Published

Description: 101-115

Description: 7T. Struttura della Terra e geodinamica

Description: JCR Journal

Description: In this study, Mg/Ca, Sr/Ca and Ba/Ca ratios in a Lateglacial to Holocene stalagmite (CC26) from Corchia Cave (central Italy) are compared with stable isotope data to define palaeohydrological changes. For most of the record, the trace element ratios show small absolute variability but similar patterns, which are also consistent with stable isotope variations. Higher trace element-to-calcium values are interpreted as responses to decreasing moisture, inducing changes in the residence time of percolation, producing prior calcite precipitation and/or variations in the hydrological routing. Statistically meaningful levels of covariability were determined using anomalies of Mg/Ca, d18O and d13C. Combining these three time series into a single ‘palaeomoisture-trend’ parameter, we highlight several events of reduced moisture (ca. 8.9–8.4, 6.2, 4.2, 3.1 and 2.0 ka), a humid period between ca. 7.9 and 8.3 ka and other shorter-term wet events at ca. 5.8, 5.3 and 3.7 ka. Most of these events can be correlated with climate changes inferred from other regional studies. For both extremities of the record (i.e. before ca. 12.4 ka and after ca. 0.5 ka) Mg/Ca and Sr/Ca are anti-correlated and show the greatest amplitude of values, a likely explanation for which involves aragonite and/or gypsum precipitation (the latter derived from pyrite oxidation) above the CC26 drip point.

Description: Published

Description: 381–392

Description: 4A. Clima e Oceani

Description: JCR Journal

Description: restricted

Description: This study is focused on the (micro)biogeochemical features of two close geothermal sites (FAV1 and FAV2), both selected at the main exhalative area of Pantelleria Island, Italy. A previous biogeochemical survey revealed high CH4 consumption and the presence of a diverse community of methanotrophs at FAV2 site, whereas the close site FAV1 was apparently devoid of methanotrophs and recorded no CH4 consumption. Next-Generation Sequencing (NGS) techniques were applied to describe the bacterial and archaeal communities which have been linked to the physicochemical conditions and the geothermal sources of energy available at the two sites. Both sites are dominated by Bacteria and host a negligible component of ammonia-oxidizing Archaea (phylum Thaumarchaeota). The FAV2 bacterial community is characterized by an extraordinary diversity of methanotrophs, with 40% of the sequences assigned to Methylocaldum, Methylobacter (Gammaproteobacteria) and Bejerickia (Alphaproteobacteria); conversely, a community of thermo-acidophilic chemolithotrophs (Acidithiobacillus, Nitrosococcus) or putative chemolithotrophs (Ktedonobacter) dominates the FAV1 community, in the absence of methanotrophs. Since physical andchemical factors of FAV1, such as temperature and pH, cannot be considered limiting for methanotrophy, it is hypothesized that the main limiting factor for methanotrophs could be high NH4+ concentration. At the same time, abundant availability of NH4+ and other high energy electron donors and acceptors determined by the hydrothermal flux in this site create more energetically favourable conditions for chemolithotrophs that outcompete methanotrophs in non-nitrogen-limited soils.

Description: Published

Description: 150–162

Description: 4V. Vulcani e ambiente

Description: JCR Journal

Description: restricted

Description: During the last few decades, 4D volcano gravimetry has shown great potential for illuminating subsurface processes at active volcanoes (including some that might otherwise remain “hidden”), especially when combined with other methods (e.g., ground deformation, seismicity, and gas emissions). By supplying information on changes in the distribution of bulk mass over time, gravimetry can provide unique information regarding such processes as magma accumulation in void space, gas segregation at shallow depths, and mechanisms driving volcanic uplift and subsidence. Despite its potential, 4D volcano gravimetry is an underexploited method, not widely adopted by volcano researchers or observatories. The cost of instrumentation and the difficulty in using it under harsh environmental conditions is a significant impediment to the exploitation of gravity at many volcanoes. In addition, retrieving useful information from gravity changes in noisy volcanic environments is a major challenge. While these difficulties are not trivial, neither are they insurmountable; indeed, creative efforts in a variety of volcanic settings highlight the value of 4D gravimetry for understanding hazards as well as revealing fundamental insights into how volcanoes work. Building on previous work, we provide a comprehensive review of 4D volcano gravimetry, including discussions of instrumentation, modeling and analysis techniques, and case studies that emphasize what can be learned from, campaign, continuous, and hybrid gravity observations. We are hopeful that this exploration of 4D volcano gravimetry will excite more scientists about the potential of the method, spurring further application, development, and innovation.

Description: Published

Description: 146-179

Description: 4V. Dinamica dei processi pre-eruttivi

Description: JCR Journal

Description: San Cristóbal volcano in northwest Nicaragua is one of the most active basaltic–andesitic stratovolcanoes of the Central American Volcanic Arc (CAVA). Here we provide novel constraints on the volcano's magmatic plumbing system, by presenting the first direct measurements of major volatile contents in mafic-to-intermediate glass inclusions from Holocene and historic-present volcanic activity. Olivine-hosted (forsterite [Fo] b80; Fob80) glass inclusions from Holocene tephra layers contain moderate amounts of H2O (0.1–3.3 wt%) and S and Cl up to 2500 μg/g, and define the mafic (basaltic) endmember component. Historic-present scoriae and tephra layers exhibit more-evolved olivines (Fo69–72) that contain distinctly lower volatile contents (0.1–2.2 wt% H2O, 760–1675 μg/g S, and 1021–1970 μg/g Cl), and represent a more-evolved basaltic–andesitic magma. All glass inclusions are relatively poor in CO2, with contents reaching 527 μg/g (as measured by nanoscale secondary ion mass spectrometry), suggesting pre- to postentrapment CO2 loss to a magmatic vapor. We use results of Raman spectroscopy obtained in a population of small (b50 μm) inclusions with CO2-bearing shrinkage bubbles (3–12 μm) to correct for postentrapment CO2 loss to bubbles, and to estimate the original minimumCO2 content in San Cristóbal parental melts at ~1889 μg/g, which is consistent with the less-CO2-degassed melt inclusions (MI) (N1500 μg/g) found in Nicaragua at Cerro Negro, Nejapa, and Granada. Models of H2O and CO2 solubilities constrain the degassing pathway of magmas up to 425 MPa (~16 km depth), which includes a deep CO2 degassing step (only partially preserved in the MI record), followed by coupled degassing of H2O and S plus crystal fractionation at magma volatile saturation pressures from ∼195 to b10 MPa. The variation in volatile contents from San Cristóbal MI is interpreted to reflect (1) Holocene eruptive cycles characterized by the rapid emplacement of basaltic magma batches, saturated in volatiles, at depths of 3.8–7.4 km, and (2) the ascent of more-differentiated and cogenetic volatile-poor basaltic andesites during historic-present eruptions, having longer residence times in the shallowest (b3.4 km) and hence coolest regions of the magmatic plumbing system. We also report the first measurements of the compositions of noble-gas isotopes (He, Ne, and Ar) in fluid inclusions in olivine and pyroxene crystals. While the measured 40Ar/36Ar ratios (300–304) and 4He/20Ne ratios (9–373) indicate some degree of air contamination, the 3He/4He ratios (7.01–7.20 Ra) support a common mantle source for Holocene basalts and historic-present basaltic andesites. The magmatic source is interpreted as generated by a primitive MORB-like mantle, that is influenced to variable extents by distinct slab fluid components for basalts (Ba/La ~ 76 and U/Th ~ 0.8) and basaltic andesites (Ba/La ~ 86 and U/Th ~ 1.0) in addition to effects of magma differentiation. These values for the geochemical markers are particularly high, and their correlation with strong plume CO2/S ratios from San Cristóbal is highly consistent with volatile recycling at the CAVA subduction zone, where sediment involvement in mantle fluids influences the typical relatively C-rich signature of volcanic gases in Nicaragua.

Description: Published

Description: 131-148

Description: 1V. Storia eruttiva

Description: JCR Journal

Description: The Nevado del Ruiz volcano is considered one of the most active volcanoes in Colombia, which can potentially threaten approximately 600,000 inhabitants. The existence of a glacier and several streams channelling in some main rivers, flowing downslope, increases the risk for the population living on the flank of the volcano in case of unrest, because of the generation of lahars and mudflows. Indeed, during the November 1985 subplinian eruption, a lahar generated by the sudden melting of the glacier killed twenty thousand people in the town of Armero. Moreover, the involvement of the local hydrothermal system has produced in the past phreatic and phreatomagmatic activity, as occurred in 1989. Therefore, the physico-chemical conditions of the hydrothermal system as well as its contribution to the shallow thermal groundwater and freshwater in terms of enthalpy and chemicals require a close monitoring. The phase of unrest occurred since 2010 and culminated with an eruption in 2012, after several years of relative stability, stillmaintains amoderate alert, as required by the high seismicity and SO2 degassing. In October 2013, a sampling campaign has been performed on thermal springs and stream water, located at 2600–5000 m of elevation on the slope of Nevado del Ruiz, analyzed for water chemistry and stable isotopes. Some of these waters are typically steam-heated (low pH and high sulfate content) by the vapour probably separating from a zoned hydrothermal system. By applying a model of steam-heating, based on mass and enthalpy balances, we have estimated themass rate of hydrothermal steam discharging in the different springs. The composition of the hottest thermal spring (Botero Londono) is probably representative of a marginal part of the hydrothermal system, having a temperature of 250 °C and low salinity (Cl ~1500 mg/l), which suggest, along with the retrieved isotope composition, a chiefly meteoric origin. The vapour discharged at the steam vent “Nereidas” (3600 m asl) is hypothesized to be separated from a high temperature hydrothermal system. Based on its composition and on literature data on fluid inclusions, we have retrieved the P-T-X conditions of the deep hydrothermal system, aswell as its pH and fO2. The vapour feeding Nereidas would separate from a biphasic hydrothermal system characterized by the following parameters: t= 315 °C, P= 15 MPa, NaCl = 10 wt%, CO2=5 wt%, and similar proportion between liquid and vapour. Considering also the equilibria involving S-bearing gases and HCl, pH would approach the value of 1.5 while fO2 would correspond to the FeO-Fe2O3 buffer. Chlorine content is estimated at 10,300mg/l. Changes in the magmatic input into the hydrothermal system couldmodify its degree of vapourization and/or P-T-X conditions, thus inducing corresponding variations in vapour discharges and thermal waters. These findings, paralleled by contemporary measurements of water flow rates, could give significant clues on risk evaluation.

Description: Published

Description: 40-53

Description: 2V. Struttura e sistema di alimentazione dei vulcani

Description: JCR Journal