Publication Date:
2022-03-07
Description:
The investigation of the role played by CO2 circulating within the mantle during partial melting and metasomatic/refertilization processes, together with a re-consideration of its storage capability and re-cycling in the lithospheric mantle, is crucial to unravel the Earth's main geodynamic processes. In this study, the combination of petrology, CO2 content trapped in bulk rock- and mineral-hosted fluid inclusions (FI), and 3D textural and volumetric characterization of intra- and inter-granular microstructures was used to investigate the extent and modality of CO2 storage in depleted and fertile (or refertilized) Sub-Continental Lithospheric Mantle (SCLM) beneath northern Victoria Land (NVL, Antarctica). Prior to xenoliths entrainment by the host basalt, the Antarctic SCLM may have stored 0.2 vol% melt and 1.1 vol% fluids, mostly as FI trails inside mineral phases but also as inter-granular fluids. The amount of CO2 stored in FI varies from 0.1 μg(CO2)/g(sample) in olivine from the anhydrous mantle xenoliths at Greene Point and Handler Ridge, up to 187.3 μg/g in orthopyroxene from the highly metasomatized amphibole-bearing lherzolites at Baker Rocks, while the corresponding bulk CO2 contents range from 0.3 to 57.2 μg/g.
Irrespective of the lithology, CO2 partitioning is favoured in orthopyroxene and clinopyroxene-hosted FI (olivine: orthopyroxene = 0.10 ± 0.06 to 0.26 ± 0.09; olivine: clinopyroxene = 0.10 ± 0.05 to 0.27 ± 0.14). The H2O/(H2O + CO2) molar ratios obtained by comparing the CO2 contents of FI to the H2O amount retained in pyroxene lattices vary between 0.72 ± 0.17 and 0.97 ± 0.03, which is well comparable with the values measured in olivine-hosted melt inclusions from Antarctic primary lavas and assumed as representative of the partition of volatiles at the local mantle conditions. From the relationships between mineral chemistry, thermo-, oxybarometric results and CO2 contents in mantle xenoliths, we speculate that relicts of CO2-depleted mantle are present at Greene Point, representing memory of a CO2-poor tholeiitic refertilization related to the development of the Jurassic Ferrar large magmatic event. On the other hand, a massive mobilization of CO2 took place before the (melt-related) formation of amphibole veins during the alkaline metasomatic event associated with the Cenozoic rift-related magmatism, in response to the storage and recycling of CO2-bearing materials into the Antarctica mantle likely induced by the prolonged Ross subduction.
Description:
Published
Description:
106643
Description:
2V. Struttura e sistema di alimentazione dei vulcani
Description:
3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
Description:
4V. Processi pre-eruttivi
Description:
2TR. Ricostruzione e modellazione della struttura crostale
Description:
JCR Journal
Keywords:
CO2 storage
;
Sub-Continental Lithospheric Mantle
;
Alkaline metasomatism
;
Fluid inclusions
;
Synchrotron X-ray microtomography
;
Inter-granular fluids
;
04.01. Earth Interior
;
04.08. Volcanology
Repository Name:
Istituto Nazionale di Geofisica e Vulcanologia (INGV)
Type:
article
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