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  • Books
  • Articles  (3)
  • 04.08. Volcanology  (2)
  • Dynamics and mechanics of faulting  (1)
  • Oxford University Press  (2)
  • Agu  (1)
  • Cell Press
  • 2020-2022  (3)
  • 1960-1964
  • 1
    Publication Date: 2021-06-21
    Description: Sulphur behaviour and variations in redox conditions during magma differentiation and degassing in the Mt Etna (Italy) volcanic system have been explored by integrating the study of olivine-hosted melt inclusions (MIs) with an experimental survey of sulphur solubility in hydrous basaltic magmas. Sulphur solubility experiments were performed at conditions relevant to the Etnean plumbing system (1200 C, 200MPa and oxygen fugacity between NNOþ0 2 and NNOþ1 7, with NNO being the nickel–nickel oxide buffer), and their results confirm the important control of oxygen fugacity (fO2) on S abundance in mafic magmas and on S partitioning between fluid and melt phases (DSfluid/melt). The observed DSfluid/melt value increases from 5164 to 14666 when fO2 decreases from NNOþ1 760 5 to NNOþ0 3. Based on the calculated DSfluid/melt and a careful selection of previously published data, an empirical model is proposed for basaltic magmas to predict the variation of DSfluid/melt values with variations in P (25–300 MPa), T (1030–1200 C) and fO2 (between NNO– 0 8 and NNOþ2 4). Olivine-hosted melt inclusions (Fo89-91) from tephra of the prehistoric (4 ka BP) sub-plinian picritic eruption, named FS (‘Fall Stratified’), have been investigated for their major element compositions, volatile contents and iron speciation (expressed as Fe3þ/PFe ratio). These primitive MIs present S content from 235677 to 34456168 ppm, and oxygen fugacity values, estimated from Fe3þ/PFe ratios, range from NNOþ0 760 2 to NNOþ1 660 2. Iron speciation has also been investigated in more evolved and volatile-poorer Etnean MIs. The only primitive melt inclusion from the Mt Spagnolo eruption (4–15 ka BP) presents a S content of 1515649ppm and an estimated fO2 of NNOþ1 460 1. The more evolved MIs (from 2002–2003, 2006, 2008–2009 and 2013 eruptions) have S content lower than 500 ppm, and their Fe3þ/RFe ratios result in fO2 between NNO– 0 960 1 and NNOþ0 460 1. Redox conditions and S behaviour in Etnean magmas during degassing and fractional crystallization were modelled coupling MELTS code with our empirical DSfluid/melt model. Starting from an FS-type magma composition and upon decrease of T and P, fractional crystallization of olivine, clinopyroxene, spinel and plagioclase causes a significant fO2 decrease. The fO2 reduction, in turn, causes a decrease in sulphur solubility and an increase in DSfluid/melt, promoting S exsolution during magma ascent, which further enhances the reduction of fO2. For the evolved MIs of 2002–2013 eruptions, magma differentiation may therefore have played a crucial role in decreasing redox conditions and favouring efficient S degassing. Differently, during the unusual FS eruption, only limited melt evolution is observed and S exsolution seems to have been triggered by a major pressure decrease accompanied by H2O and CO2 exsolution during fast magmatic ascent.
    Description: Published
    Description: egaa095
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: melt inclusions ; sulphur solubility experiments ; XANES ; Mt. Etna ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-04-14
    Description: The scaling of earthquake parameters with seismic moment and its interpretation in terms of self- similarity is still debated in the literature. We address this question by examining a worldwide compilation of corner frequency-based and elastic rebound theory (ERT)-based fault slip, area and stress drop values for earthquakes ranging in magnitude from -0.7 to 7.8. We find that corner frequency estimates of slip (and stress drop) scale differently than those inferred from the ERT approach, where the latter deviates from the generally accepted constant stress drop behavior of so- called self-similar scaling models. We also find that average slips from finite-source models are consistent with corner frequency scaling, whereas peak slip values are more consistent with the ERT scaling. The different scaling of corner frequency- and ERT-based estimates of slip and stress drop with earthquake size is interpreted in terms of heterogeneity of the rupture process. ERT-based estimates of stress drop decrease with seismic moment suggesting a self-affine behavior. Despite the inferred heterogeneity at all scales, we do not observe a clear effect on the Brune stress drop scaling with earthquake size.
    Description: Published
    Description: 1771–1781
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Earthquake dynamics ; Earthquake source observations ; Dynamics and mechanics of faulting ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2020-03-24
    Description: An edited version of this paper was published by AGU. Copyright (2019) American Geophysical Union
    Description: Tectonic and magmatic activity may couple at volcanic arcs, even though any relationship is less defined in smaller arcs, experiencing limited activity. Here we use gas geochemistry data collected during the 2011–2012 unrest at Santorini (Greece) to understand better the dynamics of the Aegean Volcanic Arc with regard to its tectonic setting. Since the most recent eruption in 1950 and before the unrest, minor seismicity and CO2 degassing (mainly from the fumaroles of Nea Kameni islet) were observed at Santorini. On January 2011, anomalous seismicity along the NE‐SW trending Kameni Line was accompanied by an inflation north of Nea Kameni. Fumarolic gas composition changed and gas release notably increased. We carried out geochemical study on both Kameni and Thera islands from January 2012 to June 2013. We repeated surveys of diffuse soil CO2 degassing and of in‐soil gas concentration, and we analyzed fumaroles and gas dissolved in thermal waters for chemical and isotopic composition. In agreement with previous studies, our geochemical data, particularly the diffuse soil CO2 flux increase, the increase of H2 content, and of CO2/CH4 and 3He/4He ratios in fumarolic gases, support geophysical data in indicating that unrest was associated with the emplacement of new mafic magma. This unrest had limited effect on the regional setting, with gas emissions focusing along the regional NE‐SW structures, without triggering by any seismic event, conversely to the 1950 eruption, which probably occurred in a frame of general tectonic reorganization of the Aegean microplate.
    Description: Published
    Description: 1033-1049
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: Extensive and systematic geochemical surveys followed the anomalous degassing during Santorini unrest, both in the caldera center and on the inner caldera walls; ; Gas ratios and isotopic composition indicate deep mafic magma refilling into the shallow dacitic plumbing system; ; Unrest has limited apparent relations with the longer-term tectonic evolution of the Arc, conversely to the 1950 eruption ; 04.08. Volcanology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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