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  • Articles  (2)
  • Fluid geochemistry  (2)
  • Elsevier  (2)
  • 2020-2022  (2)
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  • 1
    Publication Date: 2021-06-15
    Description: Sicily hosts many natural manifestations that include thermal waters, gas discharges and mud volcanoes. Due to the significant geodynamic and geological differences, the fluid discharges along a NE-WS–oriented transect that run from the Peloritani Mts. to the Sciacca Plain shows a large variability in water and gas chemical and isotopic compositions. The studied waters are characterized by Ca-HCO3, Ca(Mg)-SO4, Ca-Cl and Na-Cl compositions produced by distinct geochemical processes such as water-rock-gas interactions, mixing between deep and shallow aquifers and seawater and direct and reverse ion exchanges. The gas chemistry is dominated by CO2 to the east and CO2-N2 to the west of the study area, whereas the central part shows mud volcanoes discharging CH4-rich gases. Water isotopes suggest that the thermal waters are fed by a meteoric recharge, although isotopic exchange processes between thermal fluids and host rocks at temperature 〉150°C are recognized. Accordingly, liquid geothermometry suggests equilibrium temperatures up to 220°C. The carbon in CO2 and helium isotopes of the emissions from the westernmost sector of Sicily indicate that these two gases consists of up to 40 % of a mantle component, the latter decreasing to the east down to 10% where CO2 of thermometamorphic origin dominates. Accordingly, conceptual models of the fluid circulation for the western, central and eastern sectors are proposed. The regional geothermal reservoir, hosted in carbonates in the western sector and locally outcropping, is of low to medium temperature. Higher temperature conditions (up to 200-220°C) are suggested by geothermometry and probably related to deeper levels of the system. Sicily can be regarded as a potentially suitable area for future investigations to evaluate specific activities aimed at exploiting the geothermal resource.
    Description: Published
    Description: 102120
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Fluid geochemistry ; Stable isotopes ; Geothermal exploration ; Dissolved gases ; Tectonics ; 03. Hydrosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-05-21
    Description: Fluid primary source(s) and chemical-physical processes controlling water and gas chemistry of thermal springs from Eastern Cordillera, sub-Andean Ranges and Santa Bárbara (Jujuy Province, northern Argentina) were investigated to provide information for a preliminary evaluation of the geothermal potential in these areas. Thermal manifestations in Eastern Cordillera (Reyes) and part of those in the western sector of sub-Andean Range (Aguas Calientes) are fed by shallow aquifers, interacting with Quaternary- Neogene rocks and the upper portion of Pliocene-Miocene formations (Orán Group), whereas the meteoric water recharge area is located at〉2500 m a.s.l., corresponding to Chañi hill. Differently, El Jordán thermal spring in the sub-Andean Range is fed by a hydrothermal aquifer hosted within highly porous and fractured formations of the Salta Group (Yacoraite Formation) and recharged by meteoric water from Sierra de Calilegua (∼1500m a.s.l.). The latter is the recharge area of the La Quinta geothermal waters as well, but these have been fed at higher altitudes (〉 2500 m a.s.l.) in the range. The hydrothermal reservoir feeding the other thermal springs from the Santa Barbara system (Caimancito, El Palmar, and Siete Aguas) is recharged by meteoric water from Zapla Ranges and Santa Barbara Hill at〈2500m a.s.l. The high-TDS (〉 16,000 mg/L) Na+-Cl- La Quinta thermal springs are produced by interaction with the evaporite deposits of Salta Group, including halite, whereas the chemistry of El Palmar, El Jordán and Caimancito thermal springs, showing a Na+-SO4 2-(Cl−) composition, depends on mixing with shallower SO4 2--rich waters interacting with gypsum deposits of Anta Formation. Dissolved and bubbling gases from all the investigated provinces are related to CO2- and CH4-rich crustal fluids produced by both thermogenic processes occurring within the hydrothermal systems and microbial activity at relatively low depth, with low to negligible mantle contribution, as indicated by the 3He/4He values ≤ 0.21 Ra. The fluid reservoir feeding the Quinta thermal springs shows the highest estimated temperatures (〉 200 °C), which, considering the depth of Salta Group in the Santa Barbara system (~2000 m), support the idea, suggested by previous authors, of an anomalous geothermal gradient for this area, a promising pre-requisite for future exploitation of the geothermal resource.
    Description: Published
    Description: 102627
    Description: 1TR. Georisorse
    Description: JCR Journal
    Keywords: Hydrothermal systems ; Fluid geochemistry ; Jujuy province ; Geothermal resource
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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