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  • Articles  (343,360)
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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The great potential of high-energy X-ray diffraction to determine fine details in the atomic scale structure is discussed and illustrated with an example of a successful study on GeSe2 glass.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Transparent magnetic glass-ceramics were produced by infiltrating nano-porous glass with nitrate salts and firing. The resultant glass-ceramics contained spinel ferrite nanocrystals that exhibited ferromagnetic and superparamagnetic behavior depending on composition and firing temperature. Transparency in the near infrared was obtained when oxidizing conditions were used to prevent Fe2+ formation, while the porous matrix ensured nano-sized crystallites to limit scattering losses. MnFe2O4 glass-ceramics treated at 1000°C offered the best combination of magnetic and optical properties with a saturation magnetization of 5.6 emu/g, a Verdet constant of 16.5°/cm, and losses below 3 dB/mm at 1550 nm.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A 50 mW 325 nm He:Cd laser was used to irradiate the fracture surface of a commercial alkaline-earth boroaluminosilicate display glass (Corning Code 1737) held at temperatures above 800 K. After this treatment, the surface of the glass was found to be conductive for several hours in a temperature range between room temperature and 850 K. The conductivity shows an activation energy of 0.18 eV. Scanning tunneling spectroscopy measurements indicate that the glass surface is semiconducting with a bandgap of ∼4.4 eV. It is possible to form topographical images of the surface of the glass using the electron tunneling current; the observed topography corresponds to that acquired using atomic force imaging from the same area.
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Single crystal CaF2 is the material of choice for optics in the vacuum UV, due in part to its high transmission at these wavelengths. Unfortunately, as the wavelengths decrease, intrinsic birefringence (also referred to as spatial dispersion) can become larger than the target birefringence for precision optics at 157 nm, even for a cubic material such as CaF2. One elegant solution to this problem is to capitalize on opposite signs for this intrinsic birefringence, such as mixing SrF2 or BaF2 with CaF2. If the proper fluorides are mixed with the correct concentration, the intrinsic birefringence of the mixed single crystals can be minimized. It is also important that the resulting mixed single crystal maintain the high symmetry of CaF2, which requires that the cations mix randomly in the CaF2 structure. We show through Raman and NMR spectroscopic studies that this random mixing of cations can be achieved for mixed (Ca,Sr)F2 single crystals. A single Raman band is observed for all mixed crystals, which changes in both position and width upon addition of SrF2 to CaF2. 19F NMR spectra also reflect a random distribution of cations around the different fluorine environments in the mixed crystals.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Over the past decade, we have carried out a comprehensive development program to produce high-purity Ga:La:S and Ge:S glasses and further process these glasses into thin films. In this paper, we discuss the general properties of these glass systems and the techniques used to obtain thin films. We demonstrate the ability to deposit high-quality films ranging in thickness from nanometers to several millimeters by several methods, including chemical vapor deposition technique, a technique not usually applied to chalcogenide glasses.
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The surface structure of silica glasses has been simulated using molecular dynamics. The surface hydroxyl concentration was estimated to be 4.5/nm2, based on surface defect statistics. Hydroxyl-silica potentials were developed and used to study the hydroxylation of silica surface. It is found that the energy of chemisorption of water declines in the sequence: three coordinated silicon (Si3) and non-bridging oxygen (NBO) on separate sites, Si3 and NBO on combined sites, two- and three-membered rings. Partial hydroxylation of the most reactive sites, which leads to an OH coverage of 2.5/nm2, was studied. Structural relaxation after hydroxylation was observed.
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It is generally accepted that MgO additions enhance the sintering of alumina. The distribution of the low concentration required is, however, difficult to attain and critical to the final properties and microstructures. To improve the MgO distributions in ceramic injection-molded (CIM) alumina, Mg-containing precursors, Mg-stearate and Mg-acetate, were added during the kneading step of the CIM process, and the results were compared with those from adding MgO particles. Of the three additives, the Mg-stearate showed the highest sintered density and bending strength. This was attributed to its high molecular weight and it being able to mix with other binder components homogeneously in the liquid state, which leads to a better distribution of the MgO. In contrast, the MgO powder was kneaded in the solid particle form, and its distribution was not uniform. The Mg-acetate also imparted poorer MgO distribution because the liquid Mg-acetate dehydrated in the early stage of the kneading and formed solid lumps before it was well mixed into the binder system. The resulting sintered densities and bending strength using these two additives were, therefore, inferior to those for specimens in which Mg-stearate was used.
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Silicon nitride bulk ceramics with varying compositions of the grain boundary phase but similar grain sizes were developed, which allows to analyze the influence of the grain boundary chemistry on mechanical properties. Micrographs of the crack path reveal a much weaker interface when the rare-earth element in the grain boundary phase changes from a small to a large rare-earth cation (RE3+). Room temperature measurements of toughness and bending strength show that weaker grain boundaries result in a higher toughness, but in a decreased strength of the bulk material. This investigation demonstrates that the mechanical behavior of silicon nitride can be readily tuned by chemical composition changes of the grain boundary phase, but that a compromise between toughness and strength has to be found when designing the material.
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In a geopolymer matrix prepared by mixing a metakaolinite precursor with a solution of potassium hydroxide and silicate, 1 wt% Pb as the nitrate has been immobilized. Under the United States Environmental Protection Agency test protocol the Pb release was less than 5 ppm, the acceptable limit for landfills in the U.S.A. Electron microscopy showed Pb was present in the major amorphous phase and a minor (∼1 vol%) Ca-rich potassium silicate phase. Heating cured samples to several hundred degrees Centigrade was not significantly advantageous for immobilizing Pb.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Electrically induced fatigue crack growth is an important degradation mechanism for ferroelectric devices. Reliability concerns for ferroelectric devices place stringent demands for ferroelectric materials. In situ observation of electrically induced fatigue crack growth was carried out for ferroelectric single crystals under alternating electric field. Electrically induced fatigue crack growth was observed both below and above the coercive field. Crack closure and open behavior were observed together with 90° ferroelectric domain switching during the electric cycling. The crack propagation behavior is a repeated process of continuous but small increments followed by a sudden increase in the crack length. It was suggested that the electric boundary condition along the crack face, from its mouth to its tip, is a variation from the impermeable to the permeable state. The gradual attainment of an impermeable crack tip after an incubation period of field cycling causes the observed jump in crack propagation.
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