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  • 1
    Publication Date: 2021-06-15
    Description: Sicily hosts many natural manifestations that include thermal waters, gas discharges and mud volcanoes. Due to the significant geodynamic and geological differences, the fluid discharges along a NE-WS–oriented transect that run from the Peloritani Mts. to the Sciacca Plain shows a large variability in water and gas chemical and isotopic compositions. The studied waters are characterized by Ca-HCO3, Ca(Mg)-SO4, Ca-Cl and Na-Cl compositions produced by distinct geochemical processes such as water-rock-gas interactions, mixing between deep and shallow aquifers and seawater and direct and reverse ion exchanges. The gas chemistry is dominated by CO2 to the east and CO2-N2 to the west of the study area, whereas the central part shows mud volcanoes discharging CH4-rich gases. Water isotopes suggest that the thermal waters are fed by a meteoric recharge, although isotopic exchange processes between thermal fluids and host rocks at temperature 〉150°C are recognized. Accordingly, liquid geothermometry suggests equilibrium temperatures up to 220°C. The carbon in CO2 and helium isotopes of the emissions from the westernmost sector of Sicily indicate that these two gases consists of up to 40 % of a mantle component, the latter decreasing to the east down to 10% where CO2 of thermometamorphic origin dominates. Accordingly, conceptual models of the fluid circulation for the western, central and eastern sectors are proposed. The regional geothermal reservoir, hosted in carbonates in the western sector and locally outcropping, is of low to medium temperature. Higher temperature conditions (up to 200-220°C) are suggested by geothermometry and probably related to deeper levels of the system. Sicily can be regarded as a potentially suitable area for future investigations to evaluate specific activities aimed at exploiting the geothermal resource.
    Description: Published
    Description: 102120
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Fluid geochemistry ; Stable isotopes ; Geothermal exploration ; Dissolved gases ; Tectonics ; 03. Hydrosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2020-05-21
    Description: Fluid primary source(s) and chemical-physical processes controlling water and gas chemistry of thermal springs from Eastern Cordillera, sub-Andean Ranges and Santa Bárbara (Jujuy Province, northern Argentina) were investigated to provide information for a preliminary evaluation of the geothermal potential in these areas. Thermal manifestations in Eastern Cordillera (Reyes) and part of those in the western sector of sub-Andean Range (Aguas Calientes) are fed by shallow aquifers, interacting with Quaternary- Neogene rocks and the upper portion of Pliocene-Miocene formations (Orán Group), whereas the meteoric water recharge area is located at〉2500 m a.s.l., corresponding to Chañi hill. Differently, El Jordán thermal spring in the sub-Andean Range is fed by a hydrothermal aquifer hosted within highly porous and fractured formations of the Salta Group (Yacoraite Formation) and recharged by meteoric water from Sierra de Calilegua (∼1500m a.s.l.). The latter is the recharge area of the La Quinta geothermal waters as well, but these have been fed at higher altitudes (〉 2500 m a.s.l.) in the range. The hydrothermal reservoir feeding the other thermal springs from the Santa Barbara system (Caimancito, El Palmar, and Siete Aguas) is recharged by meteoric water from Zapla Ranges and Santa Barbara Hill at〈2500m a.s.l. The high-TDS (〉 16,000 mg/L) Na+-Cl- La Quinta thermal springs are produced by interaction with the evaporite deposits of Salta Group, including halite, whereas the chemistry of El Palmar, El Jordán and Caimancito thermal springs, showing a Na+-SO4 2-(Cl−) composition, depends on mixing with shallower SO4 2--rich waters interacting with gypsum deposits of Anta Formation. Dissolved and bubbling gases from all the investigated provinces are related to CO2- and CH4-rich crustal fluids produced by both thermogenic processes occurring within the hydrothermal systems and microbial activity at relatively low depth, with low to negligible mantle contribution, as indicated by the 3He/4He values ≤ 0.21 Ra. The fluid reservoir feeding the Quinta thermal springs shows the highest estimated temperatures (〉 200 °C), which, considering the depth of Salta Group in the Santa Barbara system (~2000 m), support the idea, suggested by previous authors, of an anomalous geothermal gradient for this area, a promising pre-requisite for future exploitation of the geothermal resource.
    Description: Published
    Description: 102627
    Description: 1TR. Georisorse
    Description: JCR Journal
    Keywords: Hydrothermal systems ; Fluid geochemistry ; Jujuy province ; Geothermal resource
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2018-03-26
    Description: At Vulcano (Aeolian Islands, Italy), different measurement methods have been developed for more than 30 years and models were formulated to account for the real time evolution of the actual solphataric activity. The results of a long term monitoring of surface temperature and of CO2 flux from soil, reviewed in a multidisciplinary framework, are presented here. These two parameters, monitored at the ground surface, highlighted local variations of the hydrothermal release and the time series of data showed in several instances, different range of values. The background and anomalous ranges defined by this long term monitoring are robust by a statistical point of view. The long term data-series offered a useful tool to verify conceptual framework and to better define the natural hazard evaluation integrating “classical” and “new” investigation techniques. Moreover, La Fossa area lays in a geodynamic context with active seismo- tectonic processes, frequently perturbing the pressure field of the hydrothermal system under investigation. Any perturbation in the pressure state variable (P) of the system, results in an excited state of its components and a relevant transfer of energy and mass towards the surface starts to counterbalance the perturbation. The continuous monitoring of surface temperature reveals the effects of the forces guiding the heat flows whereas the space variation of temperature indicates the rising paths of hydrothermal and magmatic fluids. The occurrence of new fumaroles and mofetes, or even changing emission rates of fluids by these vents, rises questions about the evolution of the equilibrium state of buried hydrothermal system, or about changing physical condition of overburden rocks. The conceptual framework suggesting the potential of our time series of field data is that a rock body, can be seen as a multiphase geochemical system where the fluid phases play a crucial role in defining the physical changes of the body and its response to the different forces acting on it. The changes of pore pressure depend on the balance between gas phases production and gas leaked out from a geochemical system. Analyses of fluxes at the system boundaries can give information on the equilibrium of the interacting geospheres. Even if playing variables are too many, some specific compounds and parameters can be selected as indicators of the state of the system.#
    Description: Published
    Description: Yokohama, Japan
    Description: 4V. Dinamica dei processi pre-eruttivi
    Keywords: Long term monitoring ; Vulcano ; Fluid geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 4
    Publication Date: 2018-03-26
    Description: We present soil temperature data from a peripheral fumarole emission of Mt Etna at the top end of a radial fracture called Bottoniera. This area lies in the northern flank of the volcano (2,500m a.s.l.), and was interested by fissure eruption during 2002/2003. In the steam heated soil lying around the fumarole release, a shallow vertical profile has been monitored from October 2009 to September 2012. We estimated the local surface heat flux and compared its time variations to the eruptive activity occurred during the monitoring period. The eruptive vents were located on the opposite flank, (〉3200m a.s.l.), far about 4km. The heat flux from this peripheral emission has been highly influenced by the eruptive activity. Its time variations are correlated to the variable rates of products emitted from January 2011 to April 2012. Different ranges of heat flux values have been associated to the pre-eruptive phase, to the productive eruption period and to the end of this eruptive cycle. The decrease of heat flux was registered before the end of the eruptive cycle. The continuous thermal monitoring revealed in real time that ascending magma through the active conduits is the heating bottom source of the heat flux dispersed by a complex network of active fractures present in this area. The recorded data suggest the steam heated soil around fumaroles vents as a possible new investigation field for a low cost monitoring of the local variation in the structural weakness of the apparatus. Extending this thermal monitoring to the other steaming grounds of this complex volcanic system we could also follow variations of the fluid circulation paths and obtain direct information about local pore pressure changes. A multivariate analysis of recorded data could suggest, which part of this complex apparatus is being involved, time by time, with the ongoing evolution. It would contribute to the evaluation of flank instability caused by physical changes occurring on the network of active fractures, and inferred by multidisciplinary investigations (such as deformation patterns, tectonic lineaments and geochemical features of underground waters and diffuse gas emissions).
    Description: Published
    Description: Yokohama, Japan
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Keywords: Fumaroles ; Steam heated Soil ; Thermal monitoring ; Eruptive cycle ; Fluid geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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