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  • Articles  (56,564)
  • MDPI  (56,564)
  • 2020-2024  (239)
  • 2020-2021
  • 2015-2019  (56,325)
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  • 1
    Publication Date: 2015-08-11
    Description: In the present work, the performance of carbon nanotubes (c-CNTs) functionalized polydimethylsiloxane (PDMS) based coatings as extractive phases for in-tube solid phase microextraction (IT-SPME) coupled to Capillary LC (CapLC) has been evaluated. Carboxylic-single walled carbon nanotubes (c-SWNTs) and carboxylic-multi walled carbon nanotubes (c-MWNTs) have been immobilized on the activated surface of PDMS capillary columns. The effect of different percentages of diphenyl groups in the PDMS extractive phase has also been evaluated. The extraction capability of the capillary columns has been tested for different organic pollutants, nitrogen heterocyclic compounds and polycyclic aromatic compounds (PAHs). The results indicated that the use of the c-CNTs-PDMS capillary columns improve pyriproxyfen and mainly PAH extraction. Triazines were better extracted by unmodified TRB-35 and modified c-CNTs-PDMSTRB-5. The results showed that the extraction capability of the c-CNT capillary columns depends not only on the polarity of the analytes (as it occurs with PDMS columns) but also on the interactions that the analytes can establish with the immobilized c-CNTs on the PDMS columns. The extraction efficiency has been evaluated on the basis of the preconcentration rate that can be achieved, and, in this sense, the best c-CNTs-PDMS capillary column for each group of compounds can be proposed.
    Electronic ISSN: 2227-9075
    Topics: Chemistry and Pharmacology
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  • 2
    Publication Date: 2015-08-14
    Description: Declines in Ogallala aquifer levels used for irrigation has prompted research to identify methods for optimizing water use efficiency (WUE) of cotton (Gossypium hirsutum L). In this experiment, conducted at Lubbock, TX, USA in 2014, our objective was to test two canopy temperature based stress indices, each at two different irrigation trigger set points: the Stress Time (ST) method with irrigation triggers set at 5.5 (ST_5.5) and 8.5 h (ST_8.5) and the Crop Water Stress Index (CWSI) method with irrigation triggers set at 0.3 (CWSI_0.3) and 0.6 (CWSI_0.6). When these irrigation triggers were exceeded on a given day, the crop was deficit irrigated with 5 mm of water via subsurface drip tape. Also included in the experimental design were a well-watered (WW) control irrigated at 110% of potential evapotranspiration and a dry land (DL) treatment that relied on rainfall only. Seasonal crop water use ranged from 353 to 625 mm across these six treatments. As expected, cotton lint yield increased with increasing crop water use but lint yield WUE displayed asignificant (p ≤ 0.05) peak near 3.6 to 3.7 kg ha−1 mm−1 for the ST_5.5 and CWSI_0.3 treatments, respectively. Our results suggest that WUE may be optimized in cotton with less water than that needed for maximum lint yield.
    Electronic ISSN: 2073-4395
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Economics
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  • 3
    Publication Date: 2015-08-13
    Description: The Saudi Arabia (SA) climate varies greatly, depending on the geography and the season. According to K ppen and Geiger, the climates of SA is “desert climate”. The analysis of the seasonal rainfall detects that spring and winter seasons have the highestrainfall incidence, respectively. Through the summer,small quantities of precipitation are observed, while autumn received more precipitation more than summer season considering the total annual rainfall. In all seasons, the SW area receives rainfall, with a maximum in spring, whereas in the summer season, the NE and NW areas receive very little quantities of precipitation. The Rub Al-Khali (the SE region) is almost totally dry. The maximum amount of annual rainfall does not always happen at the highest elevation. Therefore, the elevation is not the only factor in rainfall distribution.A great inter-annual change in the rainfall over the SA for the period (1978–2009) is observed. In addition, in the same period, a linear decreasing trend is found in the observed rainfall, whilst in the recent past (1994–2009) a statistically significant negative trend is observed. In the Southern part of the Arabian Peninsula (AP) and along the coast of the Red Sea, it is interesting to note that rainfall increased, whilst it decreased over most areas of SA during the 2000–2009 decade, compared to 1980–1989.Statistical and numerical models are used to predict rainfall over Saudi Arabia (SA). The statistical models based on stochastic models of ARIMA and numerical models based on Providing Regional Climates for Impact Studies of Hadley Centre (PRECIS). Climate and its qualitative character and quantified range of possible future changes are investigated. The annual total rainfall decreases in most regions of the SA and only increases in the south. The summertime precipitation will be the highest between other seasons over the southern, the southwestern provinces and Asir mountains, while the wintertime rainfall will remain the lowest.The climate in the SA is instructed by the El Niño Southern Oscillation (ENSO) and other circulations such as centers of high and low pressure, the North Atlantic Oscillation (NAO) and SOI. Strength and oscillation of subtropical jet stream play a big role in pulling hot, dry air masses of SA.
    Electronic ISSN: 2225-1154
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 4
    Publication Date: 2015-08-15
    Description: In the existing attribute-based encryption (ABE) scheme, the authority (i.e., private key generator (PKG)) is able to calculate and issue any user’s private key, which makes it completely trusted, which severely influences the applications of the ABE scheme. To mitigate this problem, we propose the black box traceable ciphertext policy attribute-based encryption (T-CP-ABE) scheme in which if the PKG re-distributes the users’ private keys for malicious uses, it might be caught and sued. We provide a construction to realize the T-CP-ABE scheme in a black box model. Our scheme is based on the decisional bilinear Diffie-Hellman (DBDH) assumption in the standard model. In our scheme, we employ a pair (ID, S) to identify a user, where ID denotes the identity of a user and S denotes the attribute set associated with her.
    Electronic ISSN: 2078-2489
    Topics: Computer Science
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  • 5
    Publication Date: 2015-08-15
    Description: Recently, non-standard Lagrangians have gained a growing importance in theoretical physics and in the theory of non-linear differential equations. However, their formulations and implications in general relativity are still in their infancies despite some advances in contemporary cosmology. The main aim of this paper is to fill the gap. Though non-standard Lagrangians may be defined by a multitude form, in this paper, we considered the exponential type. One basic feature of exponential non-standard Lagrangians concerns the modified Euler-Lagrange equation obtained from the standard variational analysis. Accordingly, when applied to spacetime geometries, one unsurprisingly expects modified geodesic equations. However, when taking into account the time-like paths parameterization constraint, remarkably, it was observed that mutually discrete gravity and discrete spacetime emerge in the theory. Two different independent cases were obtained: A geometrical manifold with new spacetime coordinates augmented by a metric signature change and a geometrical manifold characterized by a discretized spacetime metric. Both cases give raise to Einstein’s field equations yet the gravity is discretized and originated from “spacetime discreteness”. A number of mathematical and physical implications of these results were discussed though this paper and perspectives are given accordingly.
    Electronic ISSN: 2227-7390
    Topics: Mathematics
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  • 6
    Publication Date: 2015-08-04
    Description: The use of a novel micro pressurized liquid extraction (µPLE) method for the isolation of 16 priority pollutant polycyclic aromatic hydrocarbons (PAHs) from various solid samples is explored. The technique employs rapid heating in a single static extraction mode to remove analytes in a matter of seconds from 5–10 mg samples using only 125 µL of solvent. For example, results show that 30 s extractions with toluene at 200 °C produce respective PAH recovery ranges of 90%–130% and 88%–114% from samples of soil and smoked chicken. Comparatively, solids containing significant amounts of biochar were more challenging to extract from. For instance, when using a pure biochar sample matrix, recoveries for the 16 PAHs range from only 33%–66% after 60 s of extraction with toluene at 200 °C. Overall, these extraction results agree very well with those reported when using conventional methods on similar samples. Therefore, the findings indicate that µPLE can potentially provide an alternative sample preparation method for PAHs that is both very rapid and requires little solvent.
    Electronic ISSN: 2227-9075
    Topics: Chemistry and Pharmacology
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  • 7
    Publication Date: 2015-08-05
    Description: Digital publishing resources contain a lot of useful and authoritative knowledge. It may be necessary to reorganize the resources by concepts and recommend the related concepts for e-learning. A recommender system is presented in this paper based on the semantic relatedness of concepts computed by texts from digital publishing resources. Firstly, concepts are extracted from encyclopedias. Information in digital publishing resources is then reorganized by concepts. Secondly, concept vectors are generated by skip-gram model and semantic relatedness between concepts is measured according to the concept vectors. As a result, the related concepts and associated information can be recommended to users by the semantic relatedness for learning or reading. History data or users’ preferences data are not needed for recommendation in a specific domain. The technique may not be language-specific. The method shows potential usability for e-learning in a specific domain.
    Electronic ISSN: 2078-2489
    Topics: Computer Science
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  • 8
    Publication Date: 2015-08-05
    Description: Mangroves are found throughout the tropics, providing critical ecosystem goods and services to coastal communities and supporting rich biodiversity. Globally, mangroves are being rapidly degraded and deforested at rates exceeding loss in many tropical inland forests. Madagascar contains around 2% of the global distribution, >20% of which has been deforested since 1990, primarily from over-harvest for forest products and conversion for agriculture and aquaculture. While historically not prominent, mangrove loss in Madagascar’s Mahajamba Bay is increasing. Here, we focus on Mahajamba Bay, presenting long-term dynamics calculated using United States Geological Survey (USGS) national-level mangrove maps contextualized with socio-economic research and ground observations, and the results of contemporary (circa 2011) mapping of dominant mangrove types. The analysis of the USGS data indicated 1050 hectares (3.8%) lost from 2000 to 2010, which socio-economic research suggests is increasingly driven by commercial timber extraction. Contemporary mapping results permitted stratified sampling based on spectrally distinct and ecologically meaningful mangrove types, allowing for the first-ever vegetation carbon stock estimates for Mahajamba Bay. The overall mean carbon stock across all mangrove classes was estimated to be 100.97 ± 10.49 Mg C ha−1. High stature closed-canopy mangroves had the highest average carbon stock estimate (i.e., 166.82 ± 15.28 Mg C ha−1). These estimates are comparable to other published values in Madagascar and elsewhere in the Western Indian Ocean and demonstrate the ecological variability of Mahajamba Bay’s mangroves and their value towards climate change mitigation.
    Electronic ISSN: 2077-1312
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 9
    Publication Date: 2015-08-05
    Description: By recourse to tempered ultradistributions, we show here that the effect of a q-Fourier transform (qFT) is to map equivalence classes of functions into other classes in a one-to-one fashion. This suggests that Tsallis’ q-statistics may revolve around equivalence classes of distributions and not individual ones, as orthodox statistics does. We solve here the qFT’s non-invertibility issue, but discover a problem that remains open.
    Electronic ISSN: 2227-7390
    Topics: Mathematics
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  • 10
    Publication Date: 2015-08-05
    Description: Aquifers within the Columbia River Basalt Group (CRBG) provide a critical water supply throughout much of the Pacific Northwest of the United States. Increased pumping has resulted in water level declines in this region. Recharge into this aquifer system is generally not well understood. Recent suggestions of probable decades-long droughts in the 21st century add to this problem. We show that geophysical methods can provide useful parameters for improved modeling of aquifers in a primary CRBG aquifer located on the eastern edge of the Columbia Plateau. Groundwater models depend in part on the area, thickness, porosity, storativity, and nature of confinement of this aquifer, most of which are poorly constrained by existing well information and previous stress tests. We have made use of surface gravity measurements, borehole gravity measurements, barometric efficiency estimates, earth tidal response, and earthquake seismology observations to constrain these parameters. We show that the aquifer, despite its persistent drawdown, receives a great deal of recharge annually. Much of the recharge to the aquifer is due to leakage from overlying flows, ultimately tied to precipitation, an important result for future aquifer management in times of sustained drought.
    Electronic ISSN: 2079-9276
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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