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  • 01.01. Atmosphere  (3)
  • Life and Medical Sciences
  • Seismology
  • Elsevier  (4)
  • 2020-2024  (4)
  • 2020-2020
  • 1950-1954
  • 1935-1939
  • 1
    Publication Date: 2023-10-24
    Description: •Anthropogenic CO2 flux can be estimated by stable isotopic surveying. •Gas emissions from human activities force the atmospheric CO2. •The monitoring of stable isotopes allows identifying the CO2 sources in the air. •Several tons per day of CO2 flow through the geosphere in urban zones. •Transient in the air CO2 occurs owing to changes in weather variables.
    Description: Atmospheric carbon dioxide (CO2) concentrations increase due to volcanic emissions, diffuse degassing from fault zones, and various human-caused gas emissions, especially in densely populated urban zones, which play a pivotal role in the ongoing climate change. This study aims to examine changes in the concentration and stable isotopic composition of atmospheric CO2. A laser-based analyzer provided the δ13C and δ18O values based on concentration measurements for various CO2 isotopologues. Multiple linear regression (MLR) showed that almost 30% of the atmospheric CO2 changes are caused by weather variations, while ~70% of the changes involve CO2 from various gas sources related to human activities. The Keeling plot approach was used to identify the isotopic signature of the extra CO2, which points to the gas produced by hydrocarbon combustion. An isotopic mass balance model was designed to show the relation between excess atmospheric CO2 and the flux of human-related gas emissions. Calculating the CO2 flux in the atmosphere based on this isotopic mass balance model showed that several tons of CO2 move daily between geospheres. This study shows that surveying atmospheric CO2 in urban zones allows quantifying the CO2 emissions from various sources.
    Description: Published
    Description: 119302
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: 1TR. Georisorse
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Description: 2IT. Laboratori analitici e sperimentali
    Description: 6IT. Osservatori non satellitari
    Description: JCR Journal
    Keywords: CO2 flux ; Carbon stable isotopes ; Oxygen isotope composition ; Atmospheric CO2 ; Geochemical modeling ; Gas Hazard ; Stable isotopes ; Isotopes ; 01.01. Atmosphere ; 04.08. Volcanology ; environmental geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2023-02-20
    Description: Several regions around the globe are characterized by a seismically active lower crust, at depths where litho­logical and thermal conditions suggest stress release by ductile flow. The Gargano Promontory (GP, southern Italy) is an example where a recently installed seismic network has recorded an intense seismic activity at depths between 20 and 30 km, i.e. in the lower crust. The GP is located in proximity of the Gargano-Dubrovnik line­ament, a seismogenic zone separating the central and southern Adriatic basins. These two basins constitute sites of sediments accumulation since Tertiary times. Another important basin in the region is represented by the Apennine foredeep, that includes the Candelaro area. We analyze the possible mechanisms controlling the dis­tribution of seismicity in the GP to identify the factors that make the lower crust seismically active. To this aim, we construct a thermo-rheological model of a layered continental crust, calibrated on the basis of geometrical, lithological and thermal constraints. The model takes into account various crustal lithologies, the presence of fluids in the crystalline basement, lateral variations of geotherm and stress field. The numerical simulations show that the presence of fluids is a key factor controlling the cluster of seismicity in the lower crust. Moreover, the presence of water in the upper crystalline basement and sedimentary cover provides a plausible explanation for upper crustal seismicity in a zone of very high heat flow SW of the GP. The distribution of the seismicity is probably affected by the composition of the crystalline basement, with mafic bodies injected into the crust during the Paleocene magmatic phase that affected the Mediterranean region. In addition, fluid accumulation and overpressure may occur along detachment levels in the lower crust, leading to clustering of the earthquakes. Based on our findings, we hypothesize that the presence of hydrous diapiric upwelling(s) in the upper mantle can feed a deep fluid circulation system, inducing lower crustal seismicity.
    Description: Published
    Description: 103929
    Description: 4T. Sismicità dell'Italia
    Description: JCR Journal
    Keywords: Lower crust ; Rheology ; Seismology ; Geotherm ; Numerical modeling ; Gargano Promontory (southern Italy)
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2023-03-15
    Description: Volcanoes are currently to be regarded as natural sources of air pollutants. Climatic and environmental forcing of large volcanic eruptions are well known, although gases emitted through passive degassing during periods of quiescence or hydrothermal activity can also be highly dangerous for the environment and public health. Based on compositional and isotopic data, a survey on the spatial distribution in air of the main volatile compounds of carbon (CO2 and CH4) and sulfur (H2S and SO2) emitted from the fumarolic field of Pisciarelli (Campi Flegrei, Pozzuoli, Naples), a hydrothermal area where degassing activity has visibly increased since 2009, was carried out. The main goals of this study were (i) to evaluate the impact on air quality of these natural manifestations and (ii) inquire into the behavior of the selected chemical species once released in air, and their possible use as tracers to distinguish natural and anthropogenic sources. Keeling plot analysis of CO2 and CH4 isotopes revealed that the hydrothermal area acts as a net source of CO2 in air, whilst CH4 originated mainly from anthropogenic sources. Approaching the urban area, anthropogenic sources of CO2 increased and, at distances greater than 800 m from the Pisciarelli field, they prevailed over the hydrothermal signal. While hydrothermal CO2 simply mixed with that in the atmospheric background, H2S was possibly affected by oxidation processes. Therefore, SO2 measured in the air near the hydrothermal emissions had a secondary origin, i.e. generated by oxidation of hydrothermal H2S. Anthropogenic SO2 was recognized only in the furthest measurement site from Pisciarelli. Finally, in the proximity of a geothermal well, whose drilling was in progress during our field campaign, the H2S concentrations have reached values up to 3 orders of magnitude higher than the urban background, claiming the attention of the local authorities.
    Description: Published
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Air quality; Carbon and sulfur volatile compounds; Carbon isotopes; Hydrothermal systems; Natural sources of pollutants. ; 04.08. Volcanology ; 01.01. Atmosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2024-01-08
    Description: This study is focused on fluids characterization and circulations through the crust of the Irpinia region, an active seismic zone in Southern Italy, that has experienced several high-magnitude earthquakes, including a catastrophic one in 1980 (M = 6.9 Ms). Using isotopic geochemistry and the carbon‑helium system in free and dissolved volatiles in water, this study aims to explore the processes at depth that can alter pristine chemistry of these natural fluids. Gas-rock-water interactions and their impact on CO2 emissions and isotopic composition are evaluated using a multidisciplinary model that integrates geochemistry and regional geological data. By analyzing the He isotopic signature in the natural fluids, the release of mantle-derived He on a regional scale in Southern Italy is verified, along with significant emissions of deep-sourced CO2. The proposed model, supported by geological and geophysical constraints, is based on the interactions between gas, rock, and water within the crust and the degassing of deep-sourced CO2. Furthermore, this study reveals that the Total Dissolved Inorganic Carbon (TDIC) in cold waters results from mixing between a shallow and a deeper carbon endmember that is equilibrated with carbonate lithology. In addition, the geochemical signature of TDIC in thermal carbon-rich water is explained by supplementary secondary processes, including equilibrium fractionation between solid, gas, and aqueous phases, as well as sinks such as mineral precipitation and CO2 degassing. These findings have important implications for developing effective monitoring strategies for crustal fluids in different geological contexts and highlight the critical need to understand gas-water-rock interaction processes that control fluid chemistry at depths that can affect the assessment of the CO2 flux in atmosphere. Finally, this study highlights that the emissions of natural CO2 from the seismically active Irpinia area are up to 4.08·10+9 mol·y-1, which amounts is in the range of worldwide volcanic systems.
    Description: Published
    Description: 165367
    Description: OST3 Vicino alla faglia
    Description: OST5 Verso un nuovo Monitoraggio
    Description: JCR Journal
    Keywords: CO(2) output; Carbon isotopes; Degassing; Earthquakes; Noble gases; Precipitation ; 04.04 Solid Earth ; 01.01. Atmosphere ; 03.01. General ; 03.02. Hydrology ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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