ALBERT

Description: Modeling of fluid flow in naturally fractured reservoirs is often done through modeling and upscaling of discrete fracture networks (DFNs). The two-dimensional fracture geometry required for DFNs is obtained from subsurface and outcropping analog data. However, these data provide little information on subsurface fracture aperture, which is essential for quantifying porosity and permeability. Apertures are difficult to obtain from either outcropping or subsurface data and are therefore often based on fracture size or scaling relationships, but these do not consider the orientation and spatial distribution of fractures with respect to the in situ stress field. Using finite-element simulations, mechanical aperture can be modeled explicitly, but because changes in fracture geometry require renewed meshing and simulating, this approach is not easily integrated into subsurface DFN modeling workflows. We present a geometrically based method for calculating the shear-induced hydraulic aperture, that is, an aperture of up to 0.5 mm (0.02 in.) that can result from shear displacement along irregular fracture walls. The geometrically based method does not require numerical simulations, but it can instead be directly applied to DFNs using the fracture orientation and spacing distributions in combination with an estimate of the regional stress tensor and orientation. The frequency distribution of hydraulic aperture from the geometrically based method is compared with finite-element models constructed from five real fracture networks, digitized from outcropping pavements. These networks cover a wide range of possible geometries and spatial distributions. The geometrically based method predicts the average hydraulic aperture and equivalent permeability of fractured porous media with error margins of less than 5%.

Description: Numerical geochemical modeling was used to study the effects on pore-water composition and mineralogy from carbon dioxide (CO 2 ) injection into the Pennsylvanian Morrow B Sandstone in the Farnsworth Unit in northern Texas to evaluate its potential for long-term CO 2 sequestration. Speciation modeling showed the present Morrow B formation water to be supersaturated with respect to an assemblage of zeolite, clay, carbonate, mica, and aluminum hydroxide minerals and quartz. The principal accessory minerals in the Morrow B, feldspars and chlorite, were predicted to dissolve. A reaction-path model in which CO 2 was progressively added up to its solubility limit into the Morrow B formation water showed a decrease in pH from its initial value of 7 to approximately 4.1 to 4.2, accompanied by the precipitation of small amounts of quartz, diaspore, and witherite. As the resultant CO 2 -charged fluid reacted with more of the Morrow B mineral matrix, the model predicted a rise in pH, reaching a maximum of 5.1 to 5.2 at a water–rock ratio of 10:1. At a higher water–rock ratio of 100:1, the pH rose to only 4.6 to 4.7. Diaspore, quartz, and nontronite precipitated consistently regardless of the water–rock ratio, but the carbonate minerals siderite, witherite, dolomite, and calcite precipitated at higher pH values only. As a result, CO 2 sequestration by mineral trapping was predicted to be important only at low water–rock ratios, accounting for a maximum of 2% of the added CO 2 at the lowest water–rock ratio investigated of 10:1, which corresponds to a small porosity increase of approximately 0.14% to 0.15%.

Description: Substrate relief is a common characteristic of hard-bottom offshore banks and is associated with benthic biodiversity. Earlier studies revealed varying relief associated with offshore mesophotic communities. Correlations may exist between relief and benthic biodiversity, which in turn may be useful in determining drill sites. Such drill site determination requires obtaining an estimate of variability in relief on these banks and its associated geographic patterns. We performed fine-scale surveys of relief on 14 banks in the Gulf of Mexico to examine variation between them, geographic patterns, and possible processes influencing them: 28 Fathom, 29 Fathom, Alderdice, Bouma, Bright, Elvers, Geyer, Horseshoe, McGrail, Parker, Rankin, Rezak, Sidner, and Sonnier Banks. We used a multibeam sensor on a remotely operated vehicle, with resolution of approximately 0.5 m (2 ft). Average and standard deviation of relief were calculated at the transect, drop site, and bank levels of resolution. Sidner and McGrail Banks had the highest relief, and 29 Fathom and Sonnier had the lowest. Sidner Bank had relief averaging up to 11 m (36 ft) in height, whereas 29 Fathom Bank exhibited the lowest relief (range 1 to 2 m [3 to 7 ft]). Bright Bank and all others exhibited intermediate and variable relief at both the transect and drop site levels. Relief is not predictable on many banks because of high variability between drop sites. Some low-relief banks are predictable in their relief, lending themselves to predictions of benthic diversity and suitable drill sites. Relief decreased significantly as one moved northward in the study region. Relief exhibited a significant sinusoidal pattern from west to east. Banks with low relief occurred off Lake Calcasieu and Lafayette, Louisiana.

Description: The Lower Cretaceous presalt section in the Kwanza Basin contains an excellent petroleum system that includes "synrift" strata (Barremian) overlain by a "sag" interval (Aptian) and capped by the Loeme Salt. The upper synrift is generally limestone with widespread mollusk packstones and grainstones (coquinas) deposited in a fresh-to–moderately saline (alkaline) lake. The sag interval is characterized by carbonate platforms and silica-rich isolated buildups formed in highly evaporated, highly alkaline lakes. Shrubby (dendritic), microbially influenced boundstones and intraclast–spherulite grainstones accumulated in shallow water on platform tops. Microbial cherts were deposited as organic buildups on large, isolated structural highs basinward (west) of platforms, and they apparently formed at low temperatures in very alkaline lake water. Shrubby boundstones and microbial cherts have vuggy pores that are primary and result in high permeability. Wackestones and packstones with calcitic grains (mainly spherulites) in dolomite or argillaceous dolomite were deposited in slightly deeper, low-energy sag environments. In addition, clays (especially stevensite) precipitated out of the silica-rich, highly alkaline lake waters. During sag deposition, calcite precipitated on the shallow lake floor with morphologies that ranged from spherulites to shrubs and included a continuum of intermediate forms. Spherulites probably precipitated just below the sediment–water interface. Spherulites and shrubby calcites are commonly recrystallized. Spherulites floating in stevensite probably formed in deeper lacustrine environments. Organic-rich mudstones were deposited in even deeper lacustrine environments in synrift and sag intervals, and they are likely the source of most hydrocarbons in this system. These interpretations are supported by seismic, core, petrographic, and stable isotope data.

Description: The natural fracture system developed in the Cardium sandstone is examined in four outcropping structures that represent different stages of fold development. At the incipient stage of folding, the fracture system is dominated by large, widely spaced hybrid fractures that have very small displacements and are aligned in the regional shortening direction (type I orientation). These fractures are naturally propped open by asperities along the fracture surfaces. A lesser number of small thrust faults (type III orientation) are also developed. Extension fractures aligned parallel to the fold axis (type II orientation) begin to develop in the early stage of folding. Through the intermediate stage of folding, there is a progressive increase in the intensity of both type I and type II orientation fractures. Incremental increases in shear displacement on new or reactivated fractures create a gouge of comminuted sandstone grains along the fracture interface. As folding progresses to an advanced stage, there is major increase in the amount of shear displacement on both type I and type II orientation fractures. Many existing fractures coalesce into connected fracture zones and small faults that have shear offsets ranging from several centimeters to several meters. A breccia can result from intense fracturing in the rock within and marginal to these shear features. Slickensides on type I orientation features consistently indicate slip in a subhorizontal direction, even as bed dip increases. Multiple slickenside patterns record reactivation of these features. Type II orientation fractures and small faults consistently undergo bed-perpendicular slip. Type I and type II features both serve to stretch the Cardium sandstone beds but in different directions. Only type III features, which are a minor component of the fracture population, result in bed thickening.

Description: CONFLICT OF INTEREST AND OTHER RELEVANT INFORMATION: Conflict of interest information is provided below for the authors of this paper. Chesapeake Energy Corporation (Chesapeake) funded the authors of this paper through their organizations of employment and, in the case of the senior author, privately, to do basic research to evaluate this very large data set and prepare the paper. Data were collected on behalf of Chesapeake by paid third-party consultants to comply with regulatory programs. The analyses and interpretations, and report writing, were done by the authors of the paper. The decision to submit the paper was that of the authors. The opinions and conclusions expressed in this paper are those of the authors and do not necessarily reflect those of Chesapeake. During the preparation of this paper, all authors worked for the organizations noted in authorship. Mark Hollingsworth is a current employee of Chesapeake, having worked there from February 2011 to the present. Prior to Mr. Hollingsworth’s employment by Chesapeake, he worked for TestAmerica Laboratories, Inc., which provided laboratory analytical consulting services to Chesapeake. Bert Smith is a former employee of Chesapeake, having worked there from May 2012 to September 2013, and has been employed by Enviro Clean Cardinal from November 2013 to the present. Enviro Clean Cardinal also does consulting work for Chesapeake. Prior to May 2013, Mr. Smith worked for Science Applications International Corporation, which did consulting work for Chesapeake. Elizabeth Perry works for AECOM, who provides energy consulting services to government and private industry, including Chesapeake. Rikka Bothun also worked for AECOM during most of the time this paper was under preparation but left AECOM in December 2014 and now works for a private consulting company that does not do consulting work for Chesapeake. None of the following authors (Don Siegel, Bert Smith, Elizabeth Perry, or Rikka Bothun) have competing corporate financial interests exceeding guidelines presented by AAPG Environmental Geosciences Journal. Mark Hollingsworth is a current employee of Chesapeake and owns stock in the company in an amount in excess of $5000. Donald Siegel is the lead author and contributor to the manuscript’s preparation, technical interpretations, and review of these data and the manuscript. Bert Smith contributed to the manuscript preparation, technical interpretations, and review of these data and the manuscript. Elizabeth Perry and Rikka Bothun contributed to the manuscript preparation, technical interpretations, and review. Mark Hollingsworth maintains the Chesapeake baseline data set and contributed to the manuscript preparation and review of these data and the manuscript. Due to confidentiality agreements with landowners whose wells were sampled, latitude and longitude cannot be shown on maps.

Description: CONFLICT OF INTEREST AND OTHER RELEVANT INFORMATION: Chesapeake Energy Corporation funded consultants and the authors of this paper through their organizations of employment and, in the case of Donald Siegel, privately to do basic research on this temporal data set and prepare the paper. The authors of this report did all analysis and writing. The opinions and conclusions expressed in this paper are those of the authors and do not necessarily reflect those of Chesapeake Energy Corporation. During the preparation of this paper, all authors worked for the organizations noted in authorship. Bert Smith is a former employee of Chesapeake Energy Corporation, having worked there from May 2012 to September 2013, and has been employed by Enviro Clean Cardinal since November 2013. While employed at Chesapeake Energy Corporation, he managed this temporal study, which was completed shortly after he left Chesapeake Energy Corporation. Enviro Clean Cardinal also does consulting work for Chesapeake Energy Corporation. Prior to May 2012, Bert Smith worked for Science Applications International Corporation, which consulted for Chesapeake Energy Corporation. Mark Becker has worked for Chesapeake Energy Corporation since March 2012; prior to that, he worked for the US Geological Survey for 24 yr. Donald Siegel works for Syracuse University, but he was funded privately for this work. Neither Bert Smith nor Donald Siegel have competing corporate financial interests exceeding guidelines presented by AAPG Environmental Geosciences . Mark Becker is a current employee of Chesapeake Energy Corporation and owns stock in the company in an amount in excess of $5000. Bert Smith is the lead author and contributed to the paper preparation, technical interpretations, and review of these data and paper. Mark Becker contributed to the paper preparation, technical interpretations, and review of these data and paper. Donald Siegel contributed to the paper preparation, technical interpretations, and review of these data and paper.

Description: As the largest active strike-slip fault zone of east Asia, the Tan-Lu fault zone is the most significant tectonic feature controlling the hydrocarbon accumulation in Bohai Bay. The Penglai 19-3 and Penglai 25-6 fields are the most typical examples among the fields found in the Tan-Lu fault zone. The structures related to the two fields are fault restraining bends produced by dextral strike-slip movement on faults within the Tan-Lu fault zone. The structures initiated at the late depositional stage of the third member of the Eocene Shahejie Formation (ca. 40 Ma) after the deposition of the main source rocks of the basin. They then experienced a main development stage during deposition of the second and first members of the Eocene Shahejie Formation and the Oligocene Dongying Formation (40–25 Ma). During the Neogene, the structures continued to be enhanced slightly because of continued strike-slip until the early to middle Pleistocene. These structures were characterized by the absence of the preponderance of the reverse separations on faults and might represent the restraining bends in a divergent wrench deformation zone. This study shows that restraining bend structures along intrabasinal strike-slip systems formed after the deposition of the source rocks are very favorable for hydrocarbon accumulation.

Description: The distribution of porosity was examined on seven drill cores from west–central Alberta encompassing the Belle Fourche and Second White Specks Formations. These Cenomanian–Turonian mudrocks from the Western Canada Sedimentary Basin exhibit good organic richness (〉2 wt. % total organic carbon) and marine kerogen type II with limited kerogen type III. With the increasing thermal maturity from approximately 0.43% vitrinite reflectance ( R o ) to approximately 0.90% R o , the total porosity decreases from approximately 9 to approximately 1 vol. %. This change translates to a reduction in total pore volume from approximately 0.05 to approximately 0.005 cm 3 /g and is accompanied by changes in relative proportions of micropore, mesopore, and macropore volumes. Variations in total porosity for the seven cores with different thermal maturities across Alberta are mainly related to mesoporosity and macroporosity, although the in-core variations in total porosity are mainly related to microporosity. In general, organic matter micropores contribute to the overall microporosity in the seven cores across the study area. The increase in the total pore volumes is in accordance with an increasing concentration of quartz, although increasing concentrations of chlorite and kaolinite may contribute to greater abundance of micropores in the seven cores. The in-core variations suggest that greater contents of kaolinite and illite may contribute to increasing mesopore volumes. Variations in pore volumes and pore size distribution with depth within individual cores (representing specific thermal maturity level) differ from what is observed laterally, when cores of various thermal maturity levels across Alberta are compared, indicating complex controls on porosity systems.

Description: The stratigraphic organization of early synrift clastic successions is controlled by the rates of tectonic subsidence and the growth of the master faults, which, coupled with eustatic base level change, control the generation of accommodation. The 100- to 300-m (328- to 984.2-ft)-thick, highly heterolithic Lower Jurassic upper Åre and Tilje succession (Halten terrace, offshore Norway) represents an example of ancient synrift deposits that accumulated within a north–northeast-south–southwest-oriented structurally controlled embayment where sedimentation was strongly influenced by tidal currents but with significant river influence and minor wave action, except in exposed distal locations. The shallowing-upward, deltaic Tilje succession was deposited near the lowstand shoreline. The Tilje Formation consists of two tabular second-order sequences, each of which overlies structurally influenced sequence boundaries (SB2 and SB3 in local terminology) associated with rift-related tectonic pulses. The first pulse led to formation of SB2 (shallow incision into the Åre Formation) and caused a regional geomorphological change of the basin from an open, wave-dominated setting (upper Åre Formation) to a funnel-shaped, tide-dominated setting (Tilje Formation), in which the lower sequence 2 accumulated. Sequence 3 rests erosively on sequence 2 and is characterized by proximal tidal deposits showing at least two main oblique to axial fluvial input points (north–northwest and northeast), with an increase in wave influence and deepening toward the south. Local rapid subsidence of elongated, narrow hanging wall basins exerted a subtle control on the succession thickness and distribution of tidal–fluvial distributary channels. The overall tabular geometry and internal architecture of the Tilje Formation is less complex than that of other tidal successions worldwide, showing lateral and vertical compartmentalization of the best tidal–fluvial sandstone reservoirs.

Description: Carbonate reservoir rocks exhibit a great variability in texture that directly impacts petrophysical parameters. Many exhibit bi- and multimodal pore networks, with pores ranging from less than 1 μm to several millimeters in diameter. Furthermore, many pore systems are too large to be captured by routine core analysis, and well logs average total porosity over different volumes. Consequently, prediction of carbonate properties from seismic data and log interpretation is still a challenge. In particular, amplitude versus offset classification systems developed for clastic rocks, which are dominated by connected, intergranular, unimodal pore networks, are not applicable to carbonate rocks. Pore geometrical parameters derived from digital image analysis (DIA) of thin sections were recently used to improve the coefficient of determination of velocity and permeability versus porosity. Although this substantially improved the coefficient of determination, no spatial information of the pore space was considered, because DIA parameters were obtained from two-dimensional analyses. Here, we propose a methodology to link local and global pore-space parameters, obtained from three-dimensional (3-D) images, to experimental physical properties of carbonate rocks to improve P-wave velocity and permeability predictions. Results show that applying a combination of porosity, microporosity, and 3-D geometrical parameters to P-wave velocity significantly improves the adjusted coefficient of determination from 0.490 to 0.962. A substantial improvement is also observed in permeability prediction (from 0.668 to 0.948). Both results can be interpreted to reflect a pore geometrical control and pore size control on P-wave velocity and permeability.

Description: With the booming exploration and development of unconventional hydrocarbon resources in source rocks, the estimation of total organic carbon (TOC) content from well logs has become increasingly important because of the significance of TOC in the formation evaluation of those resources. In this paper, a new log overlay method is developed to estimate the TOC content of source rocks with excess radioactivity, but containing little or no potassium feldspar. Specifically, on the basis of previous results of log responses of source rocks, it is believed that the natural gamma ray (GR) log responses of source rocks in the applicable conditions are predominantly contributed by clay minerals and organic matter. A practical clay indicator is established to reflect the clay content using density and neutron logs. The indicator is effective not only in nonsource rocks that contain oil or water but also in source rocks. Furthermore, a new method was developed by overlaying the properly scaled clay indicator curve on the GR curve. In nonsource rocks, including clay-rich rocks and reservoirs saturated with oil or water, the two curves overlie each other, whereas a separation between the curves occurs in organic-rich source rocks. The separation between the curves was defined and expressed and can be used to calculate the TOC consecutively after careful calibration with core data. This method has been successfully applied to two shale gas plays with high-maturity kerogen in the Sichuan Basin, China. In addition, a source rock with low-maturity kerogen was used to verify the new method for its effectiveness, reliability, and widespread adaptability.

Description: Geochemical fingerprinting of produced water from hydraulic fracturing projects is an essential tool to trace their provenance during the postfracturing period, to quantify recovery rates and volumes of fracturing fluids, and to visualize the geodynamic structure of natural or induced fracture networks. A total of 41 produced water samples from an exploration well in the Northern Arabia Exploration Area in Saudi Arabia were collected daily from the fracture-stimulated Qusaiba hot shale and analyzed for major ions and trace elements and partially for environmental isotopes. The postfracturing period shows an initial return of supply water and potassium chloride brine, subsequently replaced by the inflow of sodium chloride–type formation water with a stable plateau salinity of 50,000 mg/L. Less than 10% of the total injected fracturing fluids were recovered during postfracturing, whereas 78.8 vol. % of the total recovered fluid is composed of formation water (20,843 out of 26,446 bbls) during the study period. Coinciding values between logged reservoir temperature and calculated geothermometers confirm the provenance of pore water from the Qusaiba hot shale or from nearby units. The recharge of the Silurian sequence with meteoric surface water occurred during the early Holocene (6–6.7 ka), as evidenced by geochronological dating with the 14 C method and 18 O/ 2 H values close to the global meteoric water line. The inflow of formation water into the stimulated shale layer in the postfracturing stage could be originated by the natural occurrence of pore water within a naturally fractured, black shale layer or, more likely, by the rise of groundwater from the underlying Sarah sandstones via migration pathways of natural or newly formed, vertically induced hydraulic fractures. For this particular well site and the specific hydraulic fracturing project, chemical and isotopic fingerprinting confirms the absence of ascending migration pathways from the Silurian Qusaiba hot shale toward a shallower groundwater system, which are isolated through a lithological set of more than 900 m (3000 ft) of impermeable mudstone from the Qusaiba Member.

Description: Oxygen isotope ( 18 O) zonation in carbonate mineral cements is often employed as a proxy record (typically with millimeter-scale resolution) of changing temperature regimes during different stages of sediment diagenesis. Recent advances in secondary ion mass spectrometry allow for highly precise and accurate determinations of cement 18 O values to be made in situ on a micrometer scale, thus significantly increasing the spatial resolution available to studies of diagenesis in sandstone–shale and carbonate systems. Chemo-isotopically zoned dolomite–ankerite cements within shaly sandstone beds of the predominantly silty–shaly Eau Claire Formation (Cambrian, Illinois Basin) were investigated, revealing the following: with increasing depth of burial (from 〈0.5 to ~2 km [〈1500 to 6500 ft]), cement 18 O values decrease from a high of approximately 24 down to approximately 14 (on the Vienna standard mean ocean water [VSMOW] scale, equivalent to –6.5 to –16.5 on the Vienna Peedee belemnite [VPDB] scale). The observed cross-basin trend is largely consistent with cements having formed in response to progressive sediment burial and heating. Within the context of independent burial and thermal history models for the Illinois Basin, cementation began soon after deposition and continued intermittently into the mid-Permian. However, temperatures in excess of burial model predictions are inferred at the time of latest ankerite cement precipitation, which we propose overlapped in time with conductive heating of the Eau Claire Formation (a closed system) from under- and overlying sandstone aquifers that channeled the flow of hot, Mississippi Valley–type mineralizing brines during the mid-Permian (ca. 270 Ma).

Description: The Bohai Sea area, offshore of the Bohai Bay Basin, is one of the most petroliferous regions in China, with proven original oil in place of approximately 2.4 x 10 9 m 3 (150.94 x 10 8 bbl) and proven original gas in place of over 5 x 10 12 m 3 (1.76 x 10 13 ft 3 ). Cumulative oil production is over 50 million tons (3.5 x 10 8 bbl). In this study, using the limited data on source rock thickness, core samples, and Rock-Eval pyrolysis along with sedimentary facies analysis, source rock characteristics of different depositional settings were identified, and the thickness, richness, organic matter type, and thermal evolution of four sets of source rocks in the Bohai Sea area— the second member of Dongying Formation (E 3 d 2 ), the third member of Dongying Formation (E 3 d 3 ), the first and second members of Shahejie Formation (E 2 s 1-2 ), and the third member of Shahejie Formation (E 2 s 3 )—were predicted and evaluated. Subsequently, the intensity and history of hydrocarbon expulsion for different sags was systematically compared and analyzed. The greatest thickness of the four sets of source rocks in the Bohai Sea area is 400–800 m (1300–2600 ft). The average richness of the organic matter of these source rocks is 1.74%–2.87%. The E 2 s 3 set has the highest organic matter abundance; E 2 s 1-2 has the lowest. The organic matter of these source rocks is mainly type I and type II, but their evolutions differ. The vitrinite reflectance of E 3 d 2 is 0.5%–1.0%, that of E 3 d 3 is 0.7%–1.25%, that of E 2 s 1-2 is 0.75%–1.75%, and that of E 2 s 3 is 0.75%–2.0%. The cumulative hydrocarbon expulsion of the four sets of rocks is 4.14 x 10 10 t (2.90 x 10 11 bbl). The E 2 s 1-2 set has the greatest expulsion amount: 1.75 x 10 10 t (1.22 x 10 11 bbl). The peak stages of hydrocarbon expulsion of the four sets of source rocks were during Neogene Minghuazhen Formation (12.2–2.0 Ma) and Neogene Guantao Formation (16.6–12.0 Ma). The Bozhong sag expelled the most hydrocarbons, followed by the Liaozhong, Qikou, and Huanghekou sags.

Description: Schlumberger’s modular dynamics tester (MDT) tool was used to test 10 Miocene sands in the Tubular Bells deep water oil field, offshore Gulf of Mexico, United States. Nine sands from true vertical depths of 19,999–26,464 ft (6096–8066 m) were sampled from a single well and another deeper sand (29,075 ft [8,862 m]) from a second well. Using ion and strontium, oxygen, and hydrogen isotopic analysis, the nine MDT water samples were demonstrated to be mostly formation water. The sample in the second well from 29,075 ft (8862 m) is filtrate, based on its oxygen and hydrogen isotopic composition (–4.10 and –26.3, standard mean ocean water [SMOW]). Insufficient water was recovered for ionic analysis, which made the isotopic analysis even more important to help document the origin of the water in what appears to be a hydrocarbon-charged interval. Using a combination of chemical and isotopic analyses, it is concluded that only two of the sands are possibly in fluid communication or separated by baffles. The other sands are each in separate fluid compartments. The salinity (total dissolved solids) of the formation waters decreases with depth and distance from the salt and ranges from approximately 39,000 to more than 288,000 mg/L. The formation waters have oxygen and hydrogen isotopic compositions ranging from +3.19 to +4.52 and –16.1 to –19.4, respectively (SMOW). Bromide–chloride systematics indicate that the formation waters are mixtures of normal seawater and seawater that was evaporated to and probably beyond halite saturation. The evaporite water is sourced from the deeper Jurassic section (Louann Salt) and likely came up along the salt–sediment interface along faults and fractures associated with emplacement of the salt stock and canopy. The formation waters were subsequently enriched in chloride and sodium to varying degrees by dissolution of the diapiric salt. Strontium isotopes are compatible with mixing of highly concentrated (evaporative) Jurassic seawater with relatively low 87 Sr/ 86 Sr ratios and much less concentrated (almost seawater salinity) pore water with more radiogenic strontium, the latter derived from silicate reactions during burial diagenesis. Short-chain organic acids are present in high concentrations (〉1000 mg/L) along with the organophilic ions boron and iodide. The concentrations of boron, iodide, and organic acids do not correlate with salinity. Boron and iodide show a strong positive relationship with each other and a less strong, but positive, relationship with organic acid concentrations. Boron and iodide are nearly twice as concentrated in waters of oil-bearing sands than in water-bearing sands and appear to be indicators of hydrocarbon proximity. One water-bearing sand has concentrations of boron and iodide as high as those seen in oil-bearing sands, possibly suggesting an updip oil accumulation.

Description: Huge, high gas–oil ratio, hydrogen sulfide (H 2 S)-bearing gas condensate accumulations were recently discovered in the Ordovician carbonate reservoirs of the Tazhong uplift in the Tarim Basin, northwest China. Distinct differences exist between the eastern and western condensates in terms of chemical and isotopic compositions. Condensates from the western part of the uplift were characterized by high dibenzothiophenes (generally 〉500 μg/g), a high H 2 S concentration (~7%, vol./vol.), and relatively depleted 13 C methane ( 13 C 1 = –55.5 to –36). The H 2 S concentration in the Tazhong gas condensates shows a positive correlation to Mg 2+ concentration in the formation water. Formation water in Lower Ordovician–Cambrian strata in the Tazhong uplift is rich in Mg 2+ , which facilitates the thermochemical sulfate reduction (TSR) of sulfate contact ion pairs (CIPs) to produce H 2 S and dibenzothiophenes. A detailed comparison of the chemical compositions of the formation waters in different strata indicates that a high H 2 S concentration in the Tazhong gas condensates originates from the TSR of sulfate CIPs in the Lower Ordovician–Cambrian strata, where a primary oil accumulation may have existed. The concentrations of 3- and 4-methyldiamantanes in the western condensates (80 to 150 μg/g) are relatively lower than those from the eastern part of the uplift. Also, the 13 C 1 in the western H 2 S-bearing gas condensates was more negative, and the 13 C 2 – 13 C 1 value was larger than that from typical TSR-altered gases. These features indicate that the western Tazhong samples had just entered the initial stage of TSR. According to the pressure, volume, temperature (PVT) phase diagram, the lower Paleozoic section was quickly buried after the Tortonian. High-H 2 S hydrocarbon inclusions formed during the last 10 m.y. when paleotemperatures reached 140°C (284°F). Because the reaction rate of the sulfate CIPs oxidation was relatively slower than that of H 2 S autocatalysis during the entire TSR process, advanced TSR has not been accomplished yet. It is also inferred that the Tortonian was the key period for accumulation of secondary H 2 S-bearing gas condensates, resulting from abundant gas washing along deep fractures and charging in the early reservoirs. An increased aromaticity parameter (toluene/n-heptane) and an increased fractionation index from east to west indicate an intensified degree of gas washing. Different gas-washing intensities in the eastern and western gas condensates led to diverse PVT states as well. Deep strata in the Tazhong uplift were characterized by multiple charges and mixing, coupled with periodic TSR, leading to the occurrence of variable H 2 S-bearing gas condensates.

Description: Anomalous carbonate horizons with intercrystalline hydrocarbon residue, cone-in-cone structures, and calcite "beef" veins in adjacent sandstone beds record potential evidence for hydrocarbon generation and seepage in the middle to upper Turonian Frontier Formation from the Uinta Basin, Utah and Colorado. Eight carbonate occurrences, all encountered within distal delta-front facies (thin-bedded sandstones and siltstones), were sampled at outcrop locations from the southern and eastern margins of Dinosaur National Monument. Seven petrographic facies (PF1–PF7) were identified using standard petrographic and cathodoluminescence microscopy: PF1, large and small botryoids and fans; PF2, yellow-brown spherules; PF3, microcrystalline spar cement; PF4, blocky spar; PF5, prismatic spar; PF6, drusy mosaic spar; and PF7, dolomite. Facies PF1–PF3 are synsedimentary phases comprising a large percentage of carbonate horizon volume, whereas PF4–PF7 are late-stage fabrics. The 13 C values of PF1–PF3 (–9.9 to –20.0) are consistent with contributions from biogenic methane seepage during deposition and early diagenesis. Brecciated PF1 fabrics and blowout depressions within sandstone horizons further indicate significant methane generation during deposition and early burial. Late-stage fabrics contain 13 C (–8.0 to –17.3) and 18 O (–6.5 to –13.5) values consistent with progressive burial, during which intercrystalline hydrocarbon residue, cone-in-cone structures, and calcite beef veins were formed by the thermal maturation of organic matter from enclosing distal delta-front facies. Together, these features reveal the potential for the thin-bedded facies of the Frontier Formation distal delta front to serve as a potentially viable petroleum subsystem previously unrecognized in the Uinta–Piceance petroleum province.

Description: Reliable modeling of meandering fluvial reservoirs is challenging because of the heterogeneity in magnitude and pattern of porosity and permeability related to depositional and diagenetic features. Early mechanical and chemical alterations proceed along different pathways directly related to depositionally governed differences in textural and compositional parameters. In a well-constrained sedimentological framework and with relatively homogeneous conditions of detrital composition, this study aims to determine the effect of depositional fabric on early diagenetic processes and their collective effect on petrophysical properties (pore size distribution, open porosity, and permeability). A high-resolution qualitative and quantitative petrographic analysis is conducted on 22 fine- to very fine–grained sandstones from the main meandering fluvial facies of the channel (center and margin), point bar (lower, middle, and upper), scroll bar, and chute channel of a Triassic outcrop analog. The occurrence of small-scale internal heterogeneity associated with detrital matrix and suspension-settling laminae favors the compaction process and hinders early pore-filling cement precipitation that helps the preservation of primary porosity. Multivariate statistical treatment of data demonstrates that large (〉1 µm) and well-connected primary intergranular pores are the main contributors to permeability in the more heterogeneous samples. The distribution of the finer-grained sediment fraction is strongly facies related as a result of hydraulic sorting. Better understanding of linkages between depositionally predictable features and diagenetically induced heterogeneity may lead to realistic reservoir models and enhanced effectiveness of exploitation and bypassed-oil recovery strategies.

Description: Fractures are the main fluid-flow pathways in tight-oil sandstones, and they have a significant influence on tight-oil distribution, exploration, and development. Cores and image logs are commonly unavailable because of their high costs, so employing conventional logs for fracture detection is imperative for tight-oil sandstones. We compared the fracture-response characteristics of conventional logs based on two data sets, one from 8 cored wells with fracture intensities greater than 1 m –1 (3.3 ft –1 ) and the other from 11 cored wells with fracture intensities less than 0.5 m –1 (1.6 ft –1 ), with a case study of the Upper Triassic Yanchang Formation in southwest Ordos Basin, China. The results indicate that when tight-oil sandstones are more intensely fractured, the caliper log, acoustic log, compensated neutron log, density log, dual induction logs, and laterolog 8 present fracture responses to some extent. However, it is difficult to make a distinction between fractured and nonfractured zones using conventional logs in sandstones with smaller fracture intensities. The fracture-response intensities of conventional logs are weak, and they are influenced by fracture abundance, fracture occurrence, fracture scale, and mineral-filling degree. Moreover, lithology, fluids, and rock physical properties can cause fracturelike responses. Hence, some ambiguity exists when using conventional logs to directly identify fractures. Accompanying fracture-sensitive conventional logs with some methods to enhance fracture-response intensity and eliminate nonfracture influence could enable fracture identification in tight-oil sandstones.

Description: Accurate definition of structural style in subsurface interpretation is critically important for understanding the deformation history of fold-and-thrust belts, as well as assessing the petroleum prospectivity of structural traps. Using two- and three-dimensional seismic reflection surveys, well data, field mapping, forward models, and balanced cross sections, we describe the structural styles across the actively deforming southern Junggar fold-and-thrust belt in northwestern China, a basin undergoing petroleum exploration and development operations. Subsurface interpretations indicate several folds in the basin overlie Jurassic normal faults that were tectonically inverted in the Late Jurassic to Early Cretaceous. Following inversion, multiple detachment levels propagated northward from the Tian Shan and formed a series of imbricated fault-related folds. The most prominent fold trend in southern Junggar consists of the Tugulu, Manas, and Huoerguosi anticlines, which trap hydrocarbons in clastic Eocene reservoirs. These structures exhibit complex internal geometries, with coeval forethrusts and backthrusts forming imbricated structural wedges. In the latest stages of deformation, and continuing at present, the uppermost thrust sheet, the Southern Junggar Thrust (SJT), truncated the backlimbs of these structural traps, implying the SJT is a tectonically active, out-of-sequence thrust. From these interpretations, we present a model for how the southern Junggar fold-and-thrust belt developed from Jurassic to present. Moreover, we detail how fold growth, fault activity, and structural style affected charge histories, trap formation, and reservoir compartmentalization. Our results have direct implications for assessment of the southern Junggar petroleum system as well as other complex fold-and-thrust belts.

Description: Distinguishing axial and lateral sedimentary systems in rift basins is crucial for predicting reservoir distribution and quality, particularly where synrift strata are interrupted by mass transport complexes (MTCs). Upper Jurassic deep-marine synrift successions in the central North Sea have been studied to assess the temporal and spatial relationships of sediments and controls on reservoir quality. In the Late Jurassic, the central graben experienced erosion at rift margins, whereas adjacent grabens were starved and underfilled with marine sediments, supplied by axial and transverse systems. This study focused on sediments adjacent to a major intrabasinal high, the Josephine ridge. Data included seismic, wireline logs from 16 wells, and biostratigraphic and sedimentological analysis of 144 m (472 ft) of core. Synrift strata are dominated by mudstones but include MTCs interbedded with coarse sandstones at the rift margin and fine-grained turbidite sandstones in basinal depocenters. Petrographic and heavy mineral data indicate different provenance between MTCs and basinal turbidites. Turbidites correlate with periods of lowered relative sea level, during the initial rift phase, and record axial sediment supply. The composition of the MTCs corresponds to in situ strata on the adjacent Jade and Judy horsts. The distribution of MTCs implies formation by crestal collapse horsts during the rift climax and represents a transverse system, with no genetic relationship to axial turbidites. In starved deep-marine basins, fine-grained, well-sorted axial systems may provide the most extensive reservoirs. Transverse systems derived from isolated horsts are typically coarse-grained, poorly sorted, and spatially restricted, being unlikely to provide significant reservoir material.

Description: Petroleum (oil and gas) forms from the bacterial or thermal breakdown of kerogen during progressive burial in sedimentary basins. During times of petroleum generation, kerogens in organic-rich source rocks expel petroleum to form a fluid phase in the pore system, capable of migrating under hydrodynamic and buoyancy forces to ultimately escape to the surface or accumulate within petroleum traps in the subsurface. The relative timing of petroleum charge and trap formation is a vital component in the accumulation of petroleum deposits. Exhumed basins have been historically viewed as higher-risk targets for conventional petroleum exploration because of, inter alia, the switch-off of petroleum generation in the source rock at the commencement of cooling during exhumation. However, even at the switch-off point, the source rock may retain a significant volume of petroleum sorbed in kerogen and within its pore system. Herein we demonstrate that if the source rock is exhumed to shallower depths after peak burial, pore pressure reduction and the associated volumetric expansion of the petroleum—particularly of the gaseous—phase in the pore system will result in the discharge of additional petroleum into the adjacent carrier bed or reservoir formations. Because most onshore sedimentary basins are characterized by major exhumation events at some point in their history, this represents an additional and underappreciated mechanism for a late-stage petroleum charge in exhumed sedimentary basins. The modeling also indicates that both the initial, pre-exhumation, total gas storage capacity and the exhumation gas charge are likely to be volumetrically more significant for gas-bearing source rocks that have been exposed to higher initial pressures and lower thermal gradients. The concepts presented here also have implications for petroleum resources retained within unconventional shale reservoirs because high-graded shale plays may be associated with systems where the magnitude or rate of relative overpressure dissipation has limited exhumation charge from the unconventional to conventional reservoirs within the basin.

Description: An estimate or measurement of organic matter density is required for converting between the weight percent of total organic carbon (TOC) and the volume percent of organic matter for wireline log calibration; it is therefore important to recognize when significant changes in organic matter density occur. A method is presented for calculating organic matter density from measurements of crushed-rock dry grain density and Soxhlet-extracted TOC. I have investigated the thermal evolution of organic matter by tracking changes in the intrinsic density of organic matter as a function of thermal maturity. Organic matter density shows two step increases that correspond to the generation of liquid hydrocarbons in the oil window (up to ~1.2% vitrinite reflectance [ R o ]) and the conversion of organic matter to graphitelike carbon (more correctly, "turbostratic carbon") at high thermal maturity (〉4% R o ). Profound structural changes of organic matter may, in part, determine the maturity limits of source-rock tight liquids and shale-gas plays, particularly at high thermal maturity, where gas is hosted within the organic matter–hosted pore system.

Description: Apatite fission track (AFT) and vitrinite reflectance data from five exploration wells and three seafloor cores illuminate the thermal history of the underexplored United States Chukchi shelf. On the northeastern shelf, Triassic strata in the Chevron 1 Diamond well record apatite annealing followed by cooling, possibly during the Triassic to Middle Jurassic, which is a thermal history likely related to Canada Basin rifting. Jurassic strata exhumed in the hanging wall of the frontal Herald Arch thrust fault record a history of probable Late Jurassic to Early Cretaceous structural burial in the Chukotka fold and thrust belt, followed by rapid exhumation to near-surface temperatures at 104 ± 30 Ma. This history of contractional tectonism is in good agreement with inherited fission track ages in low-thermal-maturity, Cretaceous–Cenozoic strata in the Chukchi foreland, providing complementary evidence for the timing of exhumation and suggesting a source-to-sink relationship. In the central Chukchi foreland, inverse modeling of reset AFT samples from the Shell 1 Klondike and Shell 1 Crackerjack wells reveals several tens of degrees of cooling from maximum paleo-temperatures, with maximum heating permissible at any time from about 100 to 50 Ma, and cooling persisting to as recent as 30 Ma. Similar histories are compatible with partially reset AFT samples from other Chukchi wells (Shell 1 Popcorn, Shell 1 Burger, and Chevron 1 Diamond) and are probable in light of regional geologic evidence. Given geologic context provided by regional seismic reflection data, we interpret these inverse models to reveal a Late Cretaceous episode of cyclical burial and erosion across the central Chukchi shelf, possibly partially overprinted by Cenozoic cooling related to decreasing surface temperatures. Regionally, we interpret this kinematic history to be reflective of moderate, transpressional deformation of the Chukchi shelf during the final phases of contractional tectonism in the Chukotkan orogen (lasting until ~70 Ma), followed by renewed subsidence of the Chukchi shelf in the latest Cretaceous and Cenozoic. This history maintained modest thermal maturities at the base of the Brookian sequence across the Chukchi shelf, because large sediment volumes bypassed to adjacent depocenters. Therefore, the Chukchi shelf appears to be an area with the potential for widespread preservation of petroleum systems in the oil window.

Description: Advances in virtual outcrop technologies and their introduction to fracture characterization allow extraction of fracture data from very large and inaccessible areas. The recent development of automated or semiautomated methods for fracture extraction aims to reduce or avoid tedious, time-consuming, and biased manual interpretation of fractures from virtual outcrops. We present a benchmarking exercise between a previously proposed automated fracture picking method, manual picking, and fieldwork methods. Comparison between the three methods highlighted their relative advantages and limitations. The automated fracture picking method provided excellent results in terms of fracture orientation, size, spatial distribution, and density. Fieldwork is complementary to fracture extraction from virtual outcrops, and it should focus on quality control of remote sensing data, poorly exposed areas, small-scale observations, diagenesis, timing of fracture development, building conceptual models, and linking fracture stratigraphy to rock properties. We propose a best practice for the use and integration of manual and/or automated fracture extraction from virtual outcrop and fieldwork data for fracture characterization and modeling from outcrop analogs. We consider integration of different methods as the best way to improve the modeling exercise while reducing operational costs and risks.

Description: Because of its significant impact on relative permeability, capillary pressure, stimulation methods, and ultimate recovery, the wettability of reservoir rocks is a critical factor of the petroleum recovery process. However, characterizing the wettability of shale with extremely low matrix permeabilities is a challenging task because of the dominant presence of nanopores in shale and high heterogeneity of shale compositions at multiple scales. From spontaneous imbibition behavior that uses two types of imbibing fluid (water and n-decane), the present study examines the wettability characteristics of gas-window Barnett Shale samples taken from four different depths of Texas United 1 Blakely core in Wise County in Texas. Imbibition experiments were conducted in two directions: parallel and transverse to the lamination of the samples. A scaling method was used to analyze imbibition data, and observed imbibition behaviors were interpreted to infer the different wettability conditions of four samples with different mineralogy, total organic carbon content, and pore-throat size distribution. Our results show that wettability significantly affects fluid imbibition behavior and that four tested samples can be divided into three wettability categories: more water wet, mixed wet, and more oil wet. Overall, the variable wettability of Barnett samples will affect hydrocarbon storage, distribution, and production.

Description: The prolific Los Angeles basin in California may be the most petroliferous province on Earth per volume of sedimentary fill. However, because most exploration in the basin occurred prior to the advent of modern geochemical methods, genetic relationships among the various petroleum accumulations and their source rocks have remained speculative. A training set of 24 source-related biomarker and stable carbon isotope ratios for 111 non- or mildly biodegraded oil samples from the basin was used to construct a chemometric (multivariate statistics) decision tree. The decision tree allows genetic classification of additional oil or source-rock extract samples that might be collected. The decision tree identifies 6 tribes and a total of 12 genetically distinct oil families. The families have different bulk properties, such as API gravity and sulfur content, which were previously explained as resulting from secondary processes, including thermal maturity or biodegradation. However, the chemometric assignments are based on genetic properties that reflect distinct organofacies. The oil families occur in different locations and reservoir intervals in the basin, consistent with their origins from different organofacies of active source rock. The source-rock depositional environment for each oil family can be inferred using biomarker and isotope ratios. The samples show stable carbon isotope ratios for saturate and aromatic hydrocarbons that indicate different organofacies of Miocene marine source rocks. Tribes 1 and 2 straddle the central trough, mainly occur east of the Newport-Inglewood fault zone (NIFZ), and show evidence of proximal, clay-rich source rock deposited under suboxic conditions with elevated angiosperm input. Tribes 3–6 occur west of the NIFZ and show evidence of more distal, clay-poor source rock deposited under anoxic conditions. Geochemistry and stratigraphy of the oil tribes (1–6 below) suggest the following source-rock organofacies:

Description: The origin of the overpressure in the northern Qaidam Basin has not been clearly understood, which has caused some difficulties in hydrocarbon exploration. Using a compaction study, we applied a modified acoustic-velocity and effective-stress diagram to identify the overpressure transfer in the study area. This phenomenon has not been discussed in previous studies. For the present study, we approximately calculated the magnitude of the transfer overpressure and analyzed the cause of the overpressured aquifer at the crest of the anticline in the study area. Our study indicates that the effect of overpressure transfer is very distinct, and the largest contribution to the total overpressure is 57%. The main media of overpressure transfer include vertical faults and lateral conducting layers. The vertical faults can connect deep overpressured strata, and the lateral conducting layers can connect overpressured strata at the top and wing of the anticline. During anticline formation, the crest fractures, and then the overpressured water in the anticline wing flows into the fractured crest and forms the overpressure compartment that prevents the charging of deeper natural gas.

Description: Tidal heterolithic sandstones are commonly characterized by millimeter- to centimeter-scale intercalations of mudstone and sandstone. Consequently, their effective flow properties are poorly predicted by (1) data that do not sample a representative volume or (2) models that fail to capture the complex three-dimensional architecture of sandstone and mudstone layers. We present a modeling approach in which surfaces are used to represent all geologic heterogeneities that control the spatial distribution of reservoir rock properties (surface-based modeling). The workflow uses template surfaces to represent heterogeneities classified by geometry instead of length scale. The topology of the template surfaces is described mathematically by a small number of geometric input parameters, and models are constructed stochastically. The methodology has been applied to generate generic, three-dimensional minimodels (9 m 3 [~318 ft 3 ] volume) of cross-bedded heterolithic sandstones representing trough and tabular cross bedding with differing proportions of sandstone and mudstone, using conditioning data from two outcrop analogs from a tide-dominated deltaic deposit. The minimodels capture the cross-stratified architectures observed in outcrop and are suitable for flow simulation, allowing computation of effective permeability values for use in larger-scale models. We show that mudstone drapes in cross-bedded heterolithic sandstones significantly reduce effective permeability and also impart permeability anisotropy in the horizontal as well as vertical flow directions. The workflow can be used with subsurface data, supplemented by outcrop analog observations, to generate effective permeability values to be derived for use in larger-scale reservoir models. The methodology could be applied to the characterization and modeling of heterogeneities in other types of sandstone reservoirs.

Description: Tidal heterolithic sandstone reservoirs are heterogeneous at the submeter scale because of the ubiquitous presence of intercalated sandstone and mudstone laminae. Core-plug permeability measurements fail to sample a representative volume of this heterogeneity. Here, we investigate the impact of mudstone drape distribution on the effective permeability of heterolithic, cross-bedded tidal sandstones using three-dimensional, surface-based "minimodels" that capture the geometry of cross beds at an appropriate scale. The impact of seven geometric parameters has been determined: (1) mudstone fraction, (2) sandstone laminae thickness, (3) mudstone drape continuity, (4) toeset dip, (5) climb angle of foreset–toeset surfaces, (6) proportion of foresets to toesets, and (7) trough or tabular geometry of the cross beds. We begin by identifying a representative elementary volume of 1 m 3 (~35 ft 3 ), confirming that the model volume of 9 m 3 (~318 ft 3 ) yields representative permeability values. Effective permeability decreases as the mudstone fraction increases, and it is highly anisotropic: vertical permeability falls to approximately 0.5% of the sandstone permeability at a mudstone fraction of 25%, whereas the horizontal permeability falls to approximately 5% and approximately 50% of the sandstone value in the dip (across mudstone drapes) and strike (parallel to mudstone drapes) directions, respectively. Considerable spread exists around these values, because each parameter investigated can significantly impact effective permeability, with the impact depending upon the flow direction and mudstone fraction. The results yield improved estimates of effective permeability in heterolithic, cross-bedded sandstones, which can be used to populate reservoir-scale model grid blocks using estimates of mudstone fraction and geometrical parameters obtained from core and outcrop-analog data.

Description: Fault damage zones in porous sandstones commonly exhibit networks of deformation bands reflecting crushing and reorganization of grains associated with small-scale, localized displacement. Deformation bands introduce anisotropic, order-of-magnitude reduction of effective permeability, which will affect fluid flow in reservoir rocks. We here present a method for incorporating these features in industrial-type reservoir models. The method involves the use of a three-dimensional fault zone grid generation technique that allows property modeling on a discrete high-resolution fault zone grid without refining the entire reservoir model. Deformation band data from 106 outcrop scan lines of fault damage zones were classified into discrete fault facies defined according to deformation band density. The distributional pattern of fault facies in the data exhibits recurrent spatial relationships, which could be reproduced using truncated Gaussian simulation in the modeling process. The frequency distribution of deformation band density for each facies was analyzed, and average density values were assigned to each facies for calculating cell permeability. Permeability anisotropy was handled by approximating the relationship between deformation band densities in different directions based on published high-resolution fault zone maps and cross sections. Fluid-flow simulations were carried out on several damage zones models, and results were benchmarked against models with conventional fault rendering without damage zones. Simulation results show that flow paths, remaining oil distribution, and reservoir responses in models incorporating damage zones deviate from models employing conventional fault representation without damage zones, and these differences increase as deformation band permeability decreases.

Description: Rock-based studies of the Eagle Ford Group of Central Texas demonstrate that mudrock deposition is more complicated than previously supposed. X-ray diffraction, x-ray fluorescence, total organic carbon (TOC), and log data collected from eight cores and two outcrops demonstrate that bottom-current reworking and planktonic productivity are primary depositional controls, acting independently from eustatic forcing. Central Texas Eagle Ford facies include (1) massive argillaceous mudrock, (2) massive foraminiferal calcareous mudrock, (3) laminated calcareous foraminiferal lime mudstone, (4) laminated foraminiferal wackestone, (5) cross-laminated foraminiferal packstone–grainstone, (6) massive bentonitic claystone, and (7) nodular foraminiferal packstone–grainstone. High degrees of lateral facies variability, characterized by pinching and swelling of units, lateral facies changes, truncations, and locally restricted units, are observed even at small lateral scales (50 ft [15 m]). At 10 mi (16 km) and greater lateral spacings, core and geochemical data significantly underestimate intraformational facies variability. Approximately 73% of units can be successfully correlated across a distance of 500 ft (152 m), 35% are traceable across 1 mi (1.6 km), and only 16% of beds are correlative across 10 mi (16 km). Geochemical proxies (enrichment in molybdenum and other trace elements) indicate that maximum anoxia occurred within the Bouldin Member despite being composed of the most calcareous and high-energy facies. Comparison of total gamma ray (GR) logs to computed GR logs is requisite, because GR alone may provide misleading determination of facies, TOC content, depositional environment, and sequence stratigraphic implications.

Description: Studies suggest that nanometer-scale pores exist in organic matter as a result of thermal decomposition of kerogen. Depending on the host rock lithology, organic pores could be the primary storage for hydrocarbon accumulation in unconventional petroleum plays. Although various methods are publicly available, estimation of organic porosity remains a challenge because the procedures involve certain simplification or some implicit assumptions on the calculation of initial total organic carbon (TOC). In this study, we propose a revised method to address some of these issues. A model of estimating hydrocarbon expulsion efficiency is developed and incorporated into the calculation of initial TOC, thus producing an estimate of organic porosity with an improved mass balance. The method has been tested and compared with estimates using other methods based on a Rock-Eval data set in the literature. An application of the method to a large data set from the Upper Devonian Duvernay Formation petroleum system in the Western Canada Sedimentary Basin reveals that the modification has a significant effect on the estimated organic porosity. This study also indicates that organic porosity in the Duvernay Formation ranges greatly from none in immature intervals to 〉6% in highly mature and organic-rich shale intervals. Scanning electron microscope images of immature and mature organic-rich shale samples of the Duvernay Formation show a progressive increase in organic porosity with increasing thermal maturity, supporting the proposed model calculation. The presence of a large volume of organic porosity in mature shale intervals suggests a significant amount of hydrocarbon may be stored in the organic nanopores in the Duvernay Formation.

Description: Hydrocarbon exploration in the Berkine–Ghadames Basin in southern Tunisia has generally followed global economic trends. In recent years, improvements in seismic data acquisition combined with experience gained in log interpretation in low-resistivity reservoirs have resulted in oil and gas discoveries in the Upper Silurian Acacus Formation, enriching the hydrocarbon potential of the Berkine–Ghadames Basin in southern Tunisia. Presently, the Tunisian daily oil production is approximately 43,000 bbl, about half of which comes from the fields located in southern Tunisia and is produced from the Acacus Formation. The Berkine–Ghadames Basin is an intracratonic basin formed during the Pan-African Orogeny. It covers an area of approximately 350,000 km 2 (135,135 mi 2 ) and extends into Algeria, Libya, and Tunisia. The sedimentary section within the basin ranges from Cambrian to present and is approximately 7000 m (23,000 ft) thick in the depocenter. The basin has experienced several tectonic events, which have modified its architecture and affected the petroleum systems and hydrocarbon pathways. In this study, the main elements of the petroleum geology systems are described. With the geochemical modeling results, the petroleum potential, hydrocarbon generation, expulsion time, and quantity of hydrocarbon are assessed. The main petroleum systems are also defined. They are represented by the Silurian Tannezuft hot shale source rock with Ordovician Djeffara and Silurian Acacus reservoirs, by Silurian Tannezuft hot shale with Kirchaou reservoirs, and by the Devonian Aouinette Ouinine Formation Member III source rock with Kirchaou reservoirs. The hydrocarbon traps in the area are mainly structural types. The study describes and emphasizes the hydrocarbon migration pathway mechanism from source rocks to traps. To predict and derisk future drilling locations, fairway maps are generated for the three plays: Ordovician, Silurian, and Triassic. Although the paper focuses on southern Tunisia, an attempt is made to introduce Libyan and Algerian knowledge to evaluate the basin in a regional context.

Description: The recognition, correlation, and quantification of oil mixtures remain challenging in petroleum system studies. Most prolific basins have multiple source rocks that generate petroleum over wide ranges of maturity. Compound-specific isotopic analyses of alkanes (CSIA-A) and diamondoids (CSIA-D) are very effective for determining hydrocarbon mixtures. Quantitative diamondoid analysis (QDA) and CSIA-D provide a unique advantage for source correlation of thermally altered liquids or condensates and for condensate mixtures with black oil. Biomarker fingerprints, QDA, and various CSIA methods were applied to 37 oil and condensate samples to investigate the existence of deep sources and to identify and deconvolute cosourced oil mixtures. The data were used to unravel the components of mixed oil having widely diverse levels of maturity in the north–central West Siberian basin. Three oil families and their locations are recognized in the basin. One of the families appears to be composed of oil mixtures derived from two end-member families that originated from the Upper Jurassic Bazhenov and Lower to Middle Jurassic Tyumen source rocks. Our results suggest that a significant part of the gas in the giant gas fields of north–central western Siberia (e.g., Urengoi and Yamburg) is of thermogenic origin. The source of this thermal gas, which was formerly assigned to various source origins, was determined to be the Tyumen Formation. Some samples in the basin also show mixtures of noncracked Bazhenov oil with cracked Tyumen condensate. The area where prevalent oil cracking has occurred was determined from QDA.

Description: The elemental chemostratigraphy of the Upper Cretaceous Niobrara Member of the Mancos Shale shows that six chemostratigraphic zones can be identified in the Piceance Basin, Colorado, based on geochemical data. Chemostratigraphic correlations of nine wells spaced 20 mi (~32 km) apart closely match lithostratigraphic correlations made using gamma-ray and deep-resistivity wireline logs. Lithologic interpretations made from wireline logs indicate that the Niobrara Member and equivalent strata consist primarily of interbedded calcareous shale and shaley limestone facies that increase in thickness to the northwest in the basin. The geochemical data suggest that during deposition of the Niobrara Member, anoxia and calcium enrichment increased to the east of the basin, whereas terrestrial input and clay enrichment increased to the northwest. Element crossplots suggest that a large part of the silicon is detrital and that the Niobrara Member becomes an increasingly more clastic than carbonate system to the west and northwest. The log R –derived total organic carbon (TOC) calculated using a sonic-resistivity overlay analysis technique shows that the Niobrara Member comprises organic-rich and organic-poor deposits. Average TOC values range between 1 wt. % (in organic-poor deposits) and 2.37 wt. % (in organic-rich deposits), with higher TOC values recorded in the southern and eastern parts of the basin. Relative-rock brittleness estimates from element and TOC data show the stratigraphic variability of alternating ductile (TOC rich, Ca and Si/Al poor) and brittle (TOC poor, Ca and Si/Al rich) intervals for the Niobrara Member.

Description: The purpose of this work was to study the depositional mechanisms and significance of the Longmaxi shale in the Sichuan Basin in southern China. Seven lithofacies were identified based on the detailed observation of outcrops and cores using petrographic and scanning electron microscope examination of thin sections and other data analyses: (1) laminated calcareous mudstone, (2) laminated carbonaceous mudstone, (3) laminated silty mudstone, (4) laminated claystone, (5) laminated siliceous shale, (6) siltstone, and (7) massive mudstone. The laminated mudstone and laminated claystone originated from suspension deposition, and siliceous shale is associated with ocean upwelling, whereas massive mudstone and siltstone were primarily deposited by turbidity currents. The depositional mechanisms have a great effect on the source rock and reservoir properties. Suspension deposition near oceanic upwelling zones can provide favorable conditions for the production and preservation of organic matter and are thus conducive to the formation of high-quality source rocks (total organic carbon content up to 5.4%). The reservoir storage spaces are primarily interlaminated fractures and organic pores with good physical reservoir properties (high porosity, permeability, and brittle mineral content). Turbidity currents may carry a large quantity of oxygen to the seafloor, resulting in the oxidation of organic matter, which is unfavorable for its preservation. The lithofacies formed by turbidity currents have relatively low total organic carbon contents (average: 〈1%). Structural fractures and intergranular pores are the primary storage spaces that are present in the reservoir. In summary, organic-rich shale and siliceous shale that was deposited from suspension near upwelling zones are key exploration targets for shale oil and gas. The widely distributed, multilayer, tight sandstone is important in the exploration for tight oil. A better understanding of the deposition mechanism and its effect on oil reservoirs may assist in identification of favorable areas for exploration.

Description: The Vaca Muerta–Quintuco system (uppermost lower Tithonian–lower Valanginian) is a thick shallowing-upward sedimentary cycle consisting of dark bituminous shales, marlstones, limestones, and sandstones, cropping out in the Neuquén Basin, west–central Argentina. This paper analyzes three outcrop sections in Chos Malal area, northem Neuquén province. Detailed facies analysis allows us to differentiate six facies associations, representing basinal to proximal outer ramp facies of a homoclinal carbonate ramp system (Vaca Muerta Formation) and basinal to shoreface facies of a mixed carbonate–siliciclastic shelf system (Quintuco Formation), prograding westward from the eastern margin of the basin. Two sequence hierarchies were recognized: 5 composite depositional sequences (third order) and 15 high-frequency sequences (fourth order). Fluctuations in organic matter content within the Vaca Muerta Formation suggest a relationship with depositional sequences, finding the highest values associated with transgressive systems tract, whereas the transition to the Quintuco Formation shows a strong decrease in total organic carbon. The x-ray diffraction studies show an increase of clay minerals and quartz in the transgressive systems tract of the Vaca Muerta Formation and an increase in the content of calcite in highstand systems tracts. This pattern is reversed in the Quintuco Formation. Our sequence stratigraphic approach contributes to the understanding of the relationship between organic matter, clay minerals, facies, stacking pattern, and relative sea level changes in this exceptional shale oil and shale gas unconventional reservoir. This study may be helpful for a better postulate of petrophysical and geomechanical models for unconventional exploration.

Description: Conduit fault zones and fault zones that can accommodate long-distance along-fault flow are well-documented phenomena. In reservoir simulation models, flow within these features is more correctly captured using volumetric representations of fault zones instead of employing standard two-dimensional fault planes. The present study demonstrates a method for generating fault envelope grids on full-field reservoir models, within which fault cores (i.e., regions where most of fault zone displacement is accommodated) are modeled. The modeled fault core elements are lenses and slip zones. They are defined as facies units and populated in the fault envelope grids using combined object-based simulation and deterministic techniques. Using the facies property, four reservoir simulation models are generated by modulating fault core thickness and slip zone type and permeability. Membrane slip zones (slip zones that act as partial barriers to fluid flow) cause the fault cores to form baffle–conduit systems. Along-strike positioned injector–producer pairs focus flow into the fault cores, decreasing sweep efficiency. In contrast, injected fluids of injector–producer pairs positioned to drain perpendicular to the fault cores are partitioned and distributed by the fault cores and therefore increase overall sweep efficiency. In reservoir models with conduit slip zones (slip zones that enhance flow along them and act as partial barriers to flow across them), the fault cores act as thief zones. Fluids preferentially move through the fault cores toward the nearby producers instead of through sedimentary layers with high permeability. Sweep efficiency in the reservoir models with conduit fault cores has less dependency on injector–producer configuration. Our study suggests that the improved realism added by incorporating volumetrically expressed fault cores substantially influences forecasts of field behavior and consequently should be considered during oil and gas production planning.

Description: Hydrocarbons have recently been discovered in Upper Triassic to Middle Jurassic siliciclastic reservoirs in the Rub' Al-Khali basin in Saudi Arabia. The reservoirs fill accommodation space created by Triassic and early Jurassic crustal-scale basins on the order of 100 km (62 mi) in wavelength and hundreds of meters in depth. These basins are separated by highs that are interpreted as crustal-scale epeirogenic folds. Lithologies include well-sorted quartz arenites deposited in shallow-marine, shoreface, and fluviodeltaic settings. These sequences can be correlated across the basin to extensive escarpment outcrops south of Riyadh and beyond Saudi Arabia into well-documented equivalents elsewhere in the Middle East and East Africa. The gross architecture of the interval is imaged on reflection seismic, showing clinoformal geometries and onlap onto the Triassic structured surface. Geochemistry of tested fluids indicates a type III kerogen source. The simplest interpretation is that the system is self-sourcing hydrocarbons from interbedded coaly material that is observed in the wells and at outcrop. Reservoir pressures are anomalously low relative to the overlying carbonate reservoir systems. These low pressures are interpreted to indicate lateral communication from the Rub' Al-Khali basin westward to outcrop, in contrast with the overlying carbonate fairways that are known to contain facies boundaries that trend across the regional dip. Onlapping geometries in the siliciclastic fairway combine with Cretaceous and Cenozoic compressional structures to create combined structural-stratigraphic traps.

Description: A novel hydrogeochemical modeling approach is developed to unravel thermochemical sulfate reduction (TSR) in hydrocarbon reservoirs. Our numerical model couples a web of interconnected hydrogeochemical reactions to three-dimensional (3-D) and reservoir-wide diffusive mass transport. Our modeling approach simulates a semigeneric gas reservoir sealed by anhydrite. The calculated diagenetic processes fit the observations in reservoirs affected by TSR: formation of water, precipitation of calcite, metal (di-)sulfides, and elemental sulfur as replacements of dissolved anhydrite at the expense of CH 4(g) , as well as formation of hydrogen sulfide (H 2 S). By varying input parameters, the crucial factors controlling TSR have been identified. Our results highlight that reservoir-wide diffusive mass transport is one prerequisite for TSR. An increase in the rate constant of abiotic sulfate reduction (ASR) and in diffusive mass fluxes, as well as lack of precursor minerals for metal (di-)sulfide precipitation, can increase the souring intensity and accelerate H 2 S outgassing. In contrast, precipitation of elemental sulfur, which is stable according to the chemical thermodynamics, weakens H 2 S formation. Our modeling shows that TSR is complex and cannot be represented by the single reaction ASR and by simple correlations between the rate constant of ASR and the H 2 S gas content. The application of 3-D reactive transport modeling presented here, despite its semigeneric nature, provides a good example of how such an approach can be used ahead of drilling. Our modeling helps to investigate TSR in time and space to quantify the mass conversion of all reactants involved within this web and to predict the souring level.

Description: The Sichuan Basin is a prime gas-producing basin in China. Besides the giant Neoproterozoic Weiyuan gas field discovered in the central paleo-uplift, an extra giant gas reservoir in the Cambrian in this area has been confirmed in recent years. Although the lower Paleozoic in the southwest (Weiyuan area) is normally pressured, it is overpressured in the central area (Moxi–Gaoshiti area). Combined with the seal distribution, five pressure systems, including three overpressure systems, can be divided based on drill-stem test, mud weight, and sonic transit time data. Overpressures appear at depth interval of 1500 to 4900 m (4921 to 16,076 ft), approximately. Benefiting from the good sealing capacity of the gypsum in the Upper and Middle Triassic, high overpressure (pressure coefficient [ r ] 〉 2.0) has been preserved in the Lower Triassic, and the Upper Triassic and Cambrian are moderately overpressured (1.3 〈 r 〈 1.7). Mechanisms for various overpressure systems are different. Abnormally high sonic transit time in the Permian indicates disequilibrium compaction overpressure. The analyses of sonic transit time–effective stress suggest that disequilibrium compaction is the primary mechanism for the overpressure in the Upper Triassic Xujiahe Formation, but the Cambrian overpressure system is predominantly associated with fluid expansion, which mainly resulted from gas generation. Furthermore, we consider that the late thermal cracking of oil to gas is a key factor for gas and overpressure preservation in old strata. The high overpressure in the Lower Triassic marine carbonate rocks was caused by oil cracking and gypsum dehydration mechanisms. Combining the origin analysis with the burial and hydrocarbon generation histories, we constructed the Cambrian pore pressure evolution model, which is characterized by roughly normal pressure before 200 Ma, overpressuring from 200 to 90 Ma, and overpressure releasing since 90 Ma.

Description: During the Pliocene–Quaternary, the Bonaparte Basin is characterized by a very wide (〉600 km [〉370 mi]) carbonate platform and 200-km-wide (125-mi-wide) Malita intrashelf basin (ISB). Using three-dimensional and two-dimensional seismic data combined with exploration well data, this study characterizes the stratigraphic evolution of the Malita ISB during the last 3.5 m.y. Two third-order transgressive sequences can be distinguished. A late Pliocene transgression occurred over an irregular topography resulting from the flexural reactivation of the Malita graben. In the center of the ISB, carbonate aggradation resulted in the formation of isolated carbonate platforms separated by deeper water seaways and interplatform areas. Wider and more numerous carbonate platforms developed on the edges of the ISB. During the late Quaternary, renewed flexural deformation initiated a second transgressive cycle marked by higher subsidence rates in the ISB center than along its edges. High rates of accommodation creation (at third order) combined with higher-frequency (fourth-order), high-amplitude fluctuating sea levels and increased clastic input resulted in the progressive demise and burial of the carbonate platforms in the ISB center. Thus, the Pliocene–Quaternary stratigraphic architecture of the Malita ISB is strongly controlled by differential subsidence that controls spatial distribution of accommodation and ultimately platform architectures. The Malita ISB constitutes a rare recent analogue for Paleozoic and Mesozoic hydrocarbon-bearing ISBs.

Description: The role of deep-burial dissolution in the creation of porosity in carbonates has been discussed controversially in the recent past. We present a case study from the Upper Permian Zechstein 2 carbonate reservoirs of the Lower Saxony Basin in northwest Germany. These reservoirs are locally characterized by high amounts of carbon dioxide (CO 2 ) and variable amounts of hydrogen sulfide (H 2 S), which are derived from thermochemical sulfate reduction (TSR) and inorganic sources. To study the contribution of these effects on porosity development, we combine petrography, stable isotope, and rare earth and yttrium (REY) analyses of fracture cements with Raman spectroscopy and 13 C analyses of fluid inclusions. It is shown that fluid migration along deep fault zones created and redistributed porosity. Fluid inclusion analyses of vein cements demonstrate that hydrothermal fluids transported inorganic CO 2 into the reservoir, where it mixed with minor amounts of TSR-derived organic CO 2 . The likely source of inorganic CO 2 is the thermal decomposition of deeply buried Devonian carbonates. The REY distribution patterns support a hydrothermal origin of ascending iron- and CO 2 -rich fluids causing dolomitization of calcite and increasing porosity by 10%–16% along fractures. This porosity increase results from hydrothermal dolomitization and dissolution by acids generated from the reaction of Fe 2+ with H 2 S to precipitate pyrite. In contrast, hydrothermal dolomite cements reduced early diagenetic porosity in dolomitic intervals by approximately 17%. However, the carbonate dissolution in the predominantly calcitic host rock results in a net increase in porosity and permeability in the vicinity of the fracture walls, which has to be considered for modeling reservoir properties and fluid migration pathways.

Description: In this paper we use three-dimensional seismic attribute imaging and well data to reveal the previously unknown quantitative measures, directionality, and spatial locations of the Oligocene middle Frio fluvial channel systems within an area of 254 km 2 (98 mi 2 ) that covers two oil and gas fields in the Texas Gulf Coast Basin of the United States. The objective of this study is to apply quantitative seismic geomorphology techniques to quantify the morphometric parameters important to building predictive geologic models for fluvial reservoirs. Three categories of channel systems are differentiated based on their geomorphology, seismic signature, and the mode of transport. The first, category 1, includes channel systems of high-amplitude, moderate- to high-sinuosity, mixed load channels. Category 2 channel systems are high-amplitude, straight to low-sinuosity, bed load channels with both category 1 and 2 channels filled with coarse-grained sandstone deposits. Category 3 crevasse channel systems are low-amplitude, highly sinuous, suspended load channels filled with fine-grained deposits. These fluvial system categories were found to show unique morphometric characteristics such as channel width, meander belt width, and meander length. Analysis of the middle Frio channel systems imaged in the south Texas study area revealed a significant downstream decrease of channel belt width along the length of the channel belts. The creation of a quantitative morphometric database for the middle Frio fluvial reservoirs in the basin would be very useful for exploration and development purposes. The results of this study may have general applicability to the Texas Gulf Coast Basin and to similar fluvial reservoirs worldwide.

Description: A decision to proceed with risk ventures, such as exploration wells, requires three basic estimates: the cost, if the venture fails; the reward, if the venture succeeds; and the chance of success (risk). These three estimates are combined to derive the expected value and expected rate of return, which are critical to decisions to proceed or not to proceed with the risk venture. However, although cost and reward are seen as relatively "hard" numbers, based on measurable quantities and established price forecasts, risk is commonly seen as a "soft" number, an opinion based on incomplete knowledge. Decisions may be deferred, seeking more constraint on the risk estimate; this delay can be counterproductive. An alternative approach is used by professional poker players to make an equivalent decision. In that business, too, the chance of winning is harder to constrain than the cost and reward. Instead of seeking to fine-tune the risk, players compare a rough estimate of chance with "pot odds," an easily calculated number (the chance of winning needed to break even), and use this comparison to make the right decision efficiently. This approach can also be used in the exploration business. Pot odds of a prospect can be calculated using expected dry hole costs and the predicted value of a discovery. Comparison with the estimated chance of success may indicate whether we already have enough information to make the appropriate decision or whether further work is justified. This may improve business decision-making efficiency or provide a sense check on decisions already made.

Description: Intracratonic sag basins commonly have relatively simple tectonic histories; however, later tectonic activity involving exhumation can make reconstructing the burial history a challenging task. This is important because the relative timing of hydrocarbon generation and trap formation can be a key factor in risk assessment. If trap formation postdates peak hydrocarbon generation, exploration plays are typically downgraded. Mechanisms for charge in such exhumed basins are critical factors for understanding exploration risk. This study uses data collected from an Ordovician gas-condensate field in the Illizi Basin of Algeria to document the charging of a trap formed, or modified, during exhumation of the basin following maximum burial. Integrated analysis of sonic compaction data, thermal history indicators, and stratigraphic well data was used to constrain the burial and thermal history of the region. Hydrocarbon generation in the lower Silurian source rock is interpreted to have occurred during the Carboniferous (prior to Hercynian exhumation) and during the Late Cretaceous–early Eocene maximum burial (prior to Eocene exhumation). Structural reconstructions indicate that the field was initially located on the southern flank of a long-lived, intrabasinal, Paleozoic paleohigh. The large, low-relief structural closure that defines the present-day accumulation formed as a result of northward tilting of the Illizi Basin during Eocene uplift of the Hoggar massif. The study demonstrates that the timing of trap formation at the Ordovician field postdates the main local hydrocarbon generation events within the basin, suggesting that alternative hydrocarbon charge mechanisms are required. This study indicates considerable potential to charge updip traps on the flanks of exhumed petroliferous basins via redistribution of the preexisting hydrocarbons within the basin.

Description: A detailed sedimentological study of the middle Eagle Ford/Boquillas (outcrop analog of subsurface producing strata) units was conducted on numerous roads cut along US Highway 90 in Val Verde County and on outcrops in Big Bend National Park, Brewster County, Texas, using field-based petrographical and high-resolution image capture methods (light detection and ranging and GigaPans). This study demonstrates that vertical and lateral facies distribution is controlled by the interaction of sediment productivity under the influence of bottom currents below storm wave base. Vertical cyclicity is the result of alternating periods of lower primary productivity and relatively low sediment accumulation rates (globigerinid argillaceous wackestones) and shorter periods of high primary productivity and higher accumulation rates (pelagic grainstones), driven by the absence or presence of iron from volcanic ash deposition. Lateral variations are controlled by the deposition and reworking of pelagic sediment under the influence of below–storm wave base bottom currents. Pelagic grainstones accumulated in the form of isolated barchanoid hydraulic dunes, sand ridges, coalesced sand ridges, and sand sheets and less commonly as continuous beds. Detailed measurements show that pelagic grainstones have no more than 50% continuity, and ash beds have 72% continuity. Application of sequence stratigraphic principles needs to be done with caution because the deeper-water depositional setting is affected not by sediment input from a shallow-water benthic carbonate factory but by pelagic sediment from the open-marine environment subject to bottom current reworking. Packages of strata may be more reliable for longer-distance correlations.

Description: Statistical data documenting past exploration success and failure can be used to inform the estimate of future chance of success, but this is not appropriate to every situation. Even where appropriate, past frequency is not numerically equivalent to future expectation unless the sample size is very large. Using the rule of succession, we calculate the appropriate predicted chance of future success that can be used for smaller sample numbers, typical of exploration data sets, which include both successes and failures. The results, presented as a simple look-up table, show that the error that would result from using simple frequency instead of the appropriately calculated value is particularly severe for small samples (〉10% error arising if N 〈 9). This error is least if the past success rate is close to 0.5, but it increases markedly if the past data consist of mostly failure or mostly success. We review the conditions in which past frequency can be used as a guide and the circumstances in which it does not reflect future chance. Past success frequency should only be used as a guide to future chance if the past tests and future opportunities belong to the same play and are similar as far as the available data allow. They should not be used if the historical tests have selectively sampled the "cream" of the pool of opportunities.

Description: We illustrate recently developed techniques of three-dimensional (3-D) geomechanical structural restoration applied to resolve the kinematics of deformation in the sedimentary cover above mobile salt. Our study area is one of the hydrocarbon-bearing domes in eastern Arabia. We used 3-D seismic reflection and well data to build a 3-D structural geomodel for the well-imaged part of the sedimentary cover. The geomodel includes faults and a 3.2-km (2-mi) thick section of Permian to Cenozoic sediments and is restored from the Jurassic to the present day. The development of the structures is characterized by stages of normal faulting in the Jurassic and Cretaceous and a subsequent stage of low-amplitude folding in the Late Cretaceous. We interpret that the development of the structures in the sediment cover is caused by the movement of a deep, nonpiercing salt pillow. The structures grew under the control of gradually changing deforming mechanisms, from dominantly faulting to folding. The transition from normal faulting to domal folding is indicative of a reactive salt diapir. These restoration results improve our understanding about the kinematic history of the structures developed within the Jurassic and Cretaceous sedimentary section, which contains most of the hydrocarbon resources in Arabia. Moreover, they illustrate the potential of geomechanical restoration methods to investigate structures above mobile salt systems.

Description: To date, most condensates and gases found in the Hammerfest Basin exist in distal, central basin settings, in traps with tight cap rocks of class 1 traps, whereas low-gas–oil-ratio (GOR) oils occur systematically in proximal basin settings, where cap rocks of class 3 traps prevail. Multiple fill-spill events resulted in the redistribution of oils toward structurally higher basin margins. In a systematic evaluation of light hydrocarbon parameters from condensates and oils, it was found that oils in general exhibit more traceable alteration effects than do condensates. Whereas 75% of condensate and 13.3% of oil samples are fractionated, 6.25% and 10%, respectively, show signs of biodegradation. Long-distance migration is indicated for 12.5% of condensate and 50% of oil samples. In addition, clear evidence is shown for the mixing of recently migrated high-GOR petroleum phases with older, low-GOR paleo oils. In general, variation in source-specific parameters is surprisingly less pronounced. Decreasing thermal maturity of entrapped petroleum from the eastern part of the Tromsø Basin toward the Måsøy-Nysleppen Fault Complex is observed, whereas high maturities are shown for the Nordkapp Basin and the Finnmark Platform in the eastern part of the study area. Low-to-medium maturities are recorded for oils from the basin margins of the Hammerfest Basin. Alterations in the composition of the petroleums by physiochemical processes and distribution patterns of the petroleums are closely associated with uplift and erosion.

Description: Kela-2 is a giant gas field with a proven reserve of 597 tcf in the Kuqa depression, northern Tarim Basin. Widespread overpressures have been encountered in the Eocene and Cretaceous sandstone reservoirs of the field, with pressure coefficients up to 2.1 from drill-stem tests and well-log data analysis. Disequilibrium compaction associated with horizontal tectonic compression may be the dominant overpressure mechanism in the sandstone reservoirs, because the overpressured sandstone with a maximum burial depth over 6000 m (19,685 ft) displays anomalously high porosity and low density. The causes for sandstone reservoirs with anomalously high porosity in the Kela-2 gas field were studied based on an integrated investigation of sandstone reservoir characteristics, paleo oil–water contact, petroleum charge history, and overpressure evolution. Collective evidence indicates that early oil charge had retarded the porosity reduction of the reservoir sandstone and resulted in disequilibrium compaction from overburden rocks, and overpressure from disequilibrium compaction and horizontal tectonic compression at the beginning of the rapid subsidence and deposition in the Kela-2 gas field again contributed to the preservation of the reservoir porosity: (1) overpressured mudstones in the Kela-2 gas field are characteristic of normal compaction, and overpressure was generated by horizontal tectonic compression instead of disequilibrium compaction; (2) the reservoir sandstones with high porosity and permeability are associated with high paleo oil saturation, as indicated by quantitative grain fluorescence (QGF) responses and anomalous QGF on extract intensity; (3) sandstone units below the paleo oil–water contact have very low porosity and permeability; and (4) three episodes of oil and one episode of gas charge are identified in the sandstone reservoirs of the Kela-2 gas field, and the later two episodes of oil charge occurred circa 5.5–4.5 Ma, which corresponds to the beginning of the rapid tectonic subsidence and deposition in the Kuqa depression. The initially charged oil in the sandstone reservoirs was subsequently displaced by gas at circa 3–2 Ma through fault activation at the edge of the anticline trap. The overpressure evolution for the K 1 bs reservoir sandstone in the Kela-2 gas field indicates that the apparent overpressure development in the sandstone reservoir began at 5 Ma following the major oil charge and has been maintained to the present. Overpressure development from 5 Ma in the sandstone reservoirs of the Kela-2 gas field is believed to be the dominant cause of the porosity preservation.

Description: Mass-transport events are virtually ubiquitous on the modern continental slope and are also frequent in the stratigraphic record, but the potential they create for stratigraphic trapping within the sea-floor topography is not generally appreciated. Given the abundance of mass-transport deposits (MTDs), we should expect that many turbidite systems are so affected. The MTDs may be very large (volumes 〉 10 3 km 3 [~250 mi 3 ], areas 〉 10 4 km 2 [~6250 mi 2 ], thicknesses 〉 10 2 m [~330 ft]), and they extensively remold sea-floor topography on the continental slope and rise. Turbidity currents are highly sensitive to topography; thus, turbidite reservoir distribution and geometry on the slope and rise are often significantly affected by subjacent MTDs or their slide scars. Turbidites may be captured within slide scars and on the trailing edges, margins, and rugose upper surfaces of MTDs; developed in accommodation when the mass movement comes to rest; or subsequently resulting from compaction or creep. The filling of such accommodation depends on the properties of the turbidity currents, their depositional gradient, and how they interact with basin floor topography. The scale of accommodation on top of MTDs is determined largely by the dynamics of the initial mass flow and internal structure of the final deposit, and it typically has a limited range of length scales. We present interpretations of a range of previously published and original case studies to illustrate the range of accommodation styles associated with MTD-related topography within the evacuated space of the slide scar, around and on top of the deposits themselves. In fact, several well-known deep-water outcrops probably represent examples of sedimentation influenced by MTDs. Hydrocarbon reservoirs in many slope settings may be controlled by the accommodation related to MTD topography. At the exploration scale, entire shelf margin and slope depositional systems may be contained within the scars evacuated on the upper slope by mass failure, whereas at the production scale, the rugosity on the top of MTDs creates widespread potential for stratigraphic trapping. The location, geometry, and property distribution of such reservoirs are closely controlled by the interaction of turbidity currents with the topography; thus, an understanding of these processes and their impact on slope stratigraphy is vital to reservoir prediction.

Description: Outcrop analogs are routinely used to constrain models of subsurface fluvial sedimentary architecture built through stochastic modeling or interwell sand-body correlations. Correlability models are analog-based quantitative templates for guiding the well-to-well correlation of sand bodies, whereas indicator variograms used as input to reservoir models can be parameterized from data collected from analogs, using existing empirical relationships. This study tests the value and limitations of adopting analog-informed correlability models and indicator variogram models and assesses the effect and significance of analog choice in subsurface workflows for characterizing fluvial reservoirs. A 3.2-km (2-mi)-long architectural panel based on a virtual outcrop from the Cretaceous Blackhawk Formation (Wasatch Plateau, Utah) has been used to test the methodologies. Vertical dummy wells have been constructed across the panel, and the intervening fluvial architecture has been predicted using correlability models and sequential indicator simulations. The correlability and indicator variogram models employed to predict the outcrop architecture have been compiled using information drawn from an architectural database. These models relate to (1) analogs that partially match with the Blackhawk Formation in terms of depositional setting and (2) empirical relationships relating statistics on depositional element geometries and spatial relations to net-to-gross ratio, based on data from multiple fluvial systems of a variety of forms. The forecasting methods are assessed by quantifying the mismatch between predicted architecture and outcrop observations in terms of the correlability of channel complexes and static connectivity of channel deposits. Results highlight the effectiveness of correlability models as a check for the geologic realism of correlation panels and the value of analog-informed indicator variograms as a valid alternative to variogram model parameterization through geostatistical analysis of well data. This work has application in the definition of best-practice use of analogs in subsurface workflows; it provides insight into the typical degree of realism of analog-based predictions of reservoir architecture, as well as the effect of analog choice, and draws attention to associated pitfalls.

Description: The Lower Cretaceous McMurray Formation of northeastern Alberta hosts most of the bitumen resources of the Athabasca Oil Sands. Despite its importance, the sedimentary provenance and corresponding Early Cretaceous paleodrainage system associated with these fluvial deposits remain poorly understood. We collected 18 sandstone samples from five cored wells drilled in the McMurray Formation and analyzed these for detrital zircon uranium–lead (U–Pb) geochronology. Together, these samples yield detrital zircon U–Pb age populations of less than 250, 300–600, 1000–1200, 1800–1900, and 2600–2800 Ma. Almost all of the samples contain detrital zircons with ages of 300–600 and 1000–1200 Ma, which were originally derived from the Appalachian and Grenville provinces, respectively, of eastern North America. Lowermost strata of the McMurray Formation are characterized by relatively small fluvial channel deposits and detrital zircon ages of 1800–1900 and 2600–2800 Ma, which suggest a limited paleodrainage area that includes the adjacent Canadian shield. In contrast, channel deposits in the middle–upper part of the formation are relatively large and contain abundant Appalachian- and Grenville-derived detrital zircons. These data suggest that the paleodrainage system of the McMurray Formation evolved over time, increasing in size between deposition of the lowermost units and the middle–upper deposits. Detrital zircons from the Appalachian and Grenville regions may have been transported directly to western Canada during the Cretaceous or recycled multiple times prior to their deposition. Detrital zircons from the Cordillera (〈250 Ma) are restricted to the northern part of the study area, which suggests that a tributary may have joined the main trunk fluvial system in this area.

Description: The Tan-Lu fault system in the central Liaodong Bay subbasin, Bohai Bay Basin, has complex structural characteristics, and its tectonism during the Cenozoic is an important factor in oil accumulation. Three-dimensional seismic data were used to document the structural features and evolution of the system. Variations in source rock occurrence, oil catchment area, and faulting intensity were comprehensively evaluated to discuss the heterogeneity of oil occurrence along the system. Detailed analysis of the seismic data indicates a right-lateral slip for the Tan-Lu fault system. Transpression and transtension occur on two branches of the Tan-Lu fault with different orientations, indicating a likely slip azimuth that is between the two orientations, i.e., 30°–35°. The strike-slip began at the middle stage of deposition of the Shahejie Formation and reached its climax during deposition of the first and second members of the Dongying Formation. To date, the slip is still continuing. In the transpressional system, the lower strata on opposite sides of the strike-slip fault were shortened and folded, whereby the upper strata were stretched and normal faulted. As a result, a negative flower structure developed immediately above a positive flower structure. Strain distribution in this system is similar to that in a classic fold. Moderate tectonic deformation could enlarge the oil catchment area, benefiting oil accumulation. Weak or intense deformation is unfavorable for commercial oil accumulation because of a small oil catchment area and poor oil preservation, respectively.

Description: A megaflap, or an overturned, folded, sedimentary-basin edge, is a classic feature of salt-controlled basins, formed during the inception of salt allochthony. To illustrate the relative importance of the balance between salt and sediment inputs, basin rheology, and tectonism resulting from basin interactions in the development of megaflaps, a set of analog experiments were performed in a computed tomography scanner. Sediments are modeled using both granular material and a mix of granular and viscous material and salt as purely viscous material. Uneven sedimentary loading and associated salt flow localize primary minibasins, which then migrate and expand laterally until sufficient thickness is reached to pin the downbuilding phase. The encasement of minibasins into the mother-salt layer is followed by secondary minibasin development above the canopy, the inception and localization of which appear to be more locally controlled by the primary salt feeders, salt glaciers, and canopies. Enhanced salt extrusion along basin edges is responsible for (1) classic halokinetic sequences, (2) major wedging and basin-edge erosion, and (3) basin-edge backfolding onto the basin centers, forming megaflaps. Basin interactions during differential subsidence and secondary minibasin development above the allochthonous salt canopy result in the formation of salt welds and tectonic deformation at basin boundaries, including broken and transported basin edges. The major controlling factor in megaflap development is salt allochthony, which allows the local salt extrusion rate to be higher than the sedimentation rate. Enhanced allochthony is the result of enhanced pressure related to local salt stock squeezing, regional shortening, or basin tilting.

Description: The Dabei Gas Field is a recently discovered giant tight-gas field in the Kuqa Subbasin, western China. The reservoir porosity and permeability mainly range from 1% to 8% and from 0.01 to 1 md, respectively. The hydrocarbon (both gas and light oil) accumulation processes in the tight-sandstone reservoirs were studied based on detailed reservoir characterization, thermal maturity of both gas and light oil, hydrocarbon charge history, regional tectonic compression, and thrusting. Two episodes of oil and one episode of natural-gas charge were delineated in the tight-sandstone reservoir, as evidenced by (1) similar sources but different maturities for the gas and light oil, (2) the presence of abundant bitumen in the tight-sandstone reservoir, (3) the presence of both hydrocarbon gas inclusions and oil inclusions with two distinct fluorescence colors, and (4) the presence of two groups of aqueous inclusions (coeval with the petroleum inclusions) with contrasting homogenization temperatures and salinities. The oil inclusions with the blue-white fluorescence color were determined to have been trapped at 5–4 Ma, whereas the gas charge may have occurred at circa 3–2 Ma, corresponding to a salinity change recorded in the aqueous inclusions. The hydrocarbon accumulation processes appeared to be controlled by the tectonic compression of the South Tianshan Mountains. Intense tectonic compression caused thrust fault reactivation, which provided pathways for hydrocarbon migration. Overpressure evolution of the reservoir indicates that an intense tectonic compression began at circa 5 Ma, which caused thrust activation and concomitant oil charge into the relatively porous part of the reservoir. Subsequent tectonic compression caused uplift and erosion associated with thrusting at the end of the Kuqa Formation deposition (ca. 3 Ma), with thrust faults and fractures acting as major migration pathways for the gas accumulation in the already-tight sandstone reservoir resulting from both compaction and tectonic compression.

Description: Porous siliciclastic reservoirs are known to contain structural heterogeneities such as deformation bands, which fall below current seismic resolution and which generally cannot be explicitly represented in reservoir models because of the prohibitively high computational cost. In this study, we built a reservoir model to evaluate fluid flow across a contractionally folded unit containing deformation bands (the Navajo Sandstone in the San Rafael Reef monocline, Utah). Using field data, geometric relationships, and auxiliary computational techniques, we upscale deformation bands to capture flow effects in the large-scale structure, running simulations with variable scenarios of permeability contrast between host rock and deformation bands. Our simulations show that pervasive deformation band arrays (such as the ones present in the monocline) have effects when the contrast of permeability between them and the host rock is of at least three orders of magnitude, delaying water breakthrough and enhancing sweep; in long-term production, this results in larger final produced volumes and higher total recovery. Because of the wide range of deformation band permeabilities used in this study, our findings can be of importance for the prediction of flow and optimization of production strategies in comparable traps and reservoirs. Additionally, auxiliary computational techniques and geometric relationships such as the ones presented in this study can significantly improve the incorporation of small-scale features with strong scale gap into conventional sized reservoirs.

Description: Volcanic hydrocarbon reservoirs are rare and may be overlooked. The Carboniferous volcanic rocks of the Kebai fault zone in the western Junggar Basin contain hydrocarbon (HC) reservoirs in volcanic rock with proven oil reserves of 9.76 x 10 8 bbl that have a complex filling history. We have investigated the lithology and properties of these volcanic rock HC reservoirs as well as diagenesis and control of faults and fractures in oil reservoirs. The lithology of these Carboniferous volcanic rocks is primarily andesite and tuff. Also present were volcanic breccia and metamorphic rock in addition to rhyolite, felsite, diabase, and granite in the volcanic lava. On the basis of microscopic examination, five types of pores and fractures were observed: (1) fracture–dissolved phenocrystal pore, (2) fracture–intergranular pore, (3) fracture–gas pore, (4) fracture–dissolved intragranular pore, and (5) fracture–dissolved matrix pore. The fractures in these rocks are a significant factor in connecting the pores. Diagenetic processes that control reservoir quality include compaction, filling of pores and fractures, cementation, metasomatism, and grain dissolution. The volcanic reservoirs show a variety of lithologies, and oil has been discovered in all types of Carboniferous rocks. The controlling factors for oil distribution in these Carboniferous volcanic rocks are faulting, fracture development, and degree of weathering when they were subaerially exposed in the Permian. The area in which these faults and fractures developed is the primary area of oil enrichment with high yields. The objectives of this study were to (1) describe the characteristics of different types of volcanic rocks and reservoirs found in this basin and (2) characterize the diagenetic history of these rocks and document how diagenesis controls porosity and permeability.

Description: Karstification positively and negatively affects the quality of carbonate reservoirs; for example, dissolution and brecciation can increase porosity and permeability, whereas cavern collapse or cementation driven by postkarstification fluid flow may occlude porosity and reduce permeability. Karst may also pose challenges to drilling because of the unpredictable and highly variable porosity and permeability structure of the rock and the corresponding difficulty in predicting drilling mud weight. When combined, outcrop, petrographic, and geochemical data can constrain the style, distribution, and origin of seismic-scale karst, which may provide an improved understanding of carbonate reservoir architecture and allow development of safer drilling programs. However, relatively few studies have used seismic reflection data to characterize the regional development of seismic-scale karst features. In this study we use time-migrated two-dimensional seismic reflection data to determine the distribution, scale, and genesis of karst in a 3-km-thick (9800-ft-thick), Jurassic–Miocene carbonate-dominated succession in the Persian Gulf. We map 43 seismic-scale karst features, which are expressed as vertical pipe columns of chaotic reflections capped by downward-deflected depressions that are onlapped by overlying strata. The columns are up to 2 km (6500 ft) tall, spanning the Upper Jurassic to Upper Cretaceous succession, and are up to 5.5 km (18,000 ft) in diameter. We interpret these pipes to have formed in response to hypogene karstification by fluids focused along preexisting faults, with hypogene-generated depressions enhanced by epigene processes during key intervals of exposure. Our study indicates that seismic reflection data can and should be used in conjunction with petrographic and geochemical techniques to determine the presence of hypogene karst plays and to help improve the characterization of carbonate reservoirs and associated drilling hazards.

Description: The reservoir sedimentology and depositional environment of the Lower Cretaceous Alam El Bueib Formation in the Betty-1 well, Shoushan Basin, were investigated by studying lithofacies, petrography, and calcareous nannofossils. The sedimentary lithofacies indicate a fluvial to shallow-marine depositional environment. We have lithologically identified and described five lithofacies assemblages (massive-sandstone facies; cherty massive-sandstone facies; argillaceous-sandstone facies; heterolithic, laminated sandstone/shale facies; and sandy/silty–shale facies); we have petrographically identified and described seven microfacies (laminated claystone and siltstone; ferruginous quartz–arenite; feldspathic ferruginous quartz–wacke; quartz–arenite; anhydritic quartz–arenite; biomicrite; and sandy-limestone microfacies). Calcareous nannofossils were used to determine the age of the investigated deposits. The calcareous-nannofossil species led to the recognition of two nannofossil zones of the Early Cretaceous ( Nannoconus bermudezi zone of the Hauterivian and Nannoconus colomi zone of the Barremian). The studied sandstone reservoirs can be classified as compositionally immature feldspathic arenite and wacke. The main diagenetic minerals of the sandstones include authigenetic clay minerals, calcite cement, quartz overgrowth, and later ferroan carbonate. Wide porosity variations in sandstones correlate with an abundance of grain-coating clays and consequent inhibition of quartz cementation. Secondary porosity has been created mainly by feldspar, rock-fragment dissolution, and clay-matrix dissolution.

Description: Upward migration of brine because of pressurization resulting from injection is a risk of disposal of water produced with oil and geologic carbon storage. Analysis of the net production in each zone associated with oil production activities in the southern San Joaquin Valley, California, determined that net injection caused by disposal of water produced with oil occurred in zones above the shallowest zone with net production in several oil fields. The zones with net injection are also variously at depths just greater than the shallowest depths for geologic carbon storage or at depths intermediate between more typical geologic carbon storage depths and overlying groundwater with a total dissolved solids concentration appropriate for domestic use. As such, these net injections provide analogs for brine pressurization caused by geologic carbon storage, either in the injection zone around the CO 2 plume or in overlying zones caused by vertical leakage of brine or CO 2 . Hundreds of newspaper articles regarding groundwater contamination in the main newspaper in the southern San Joaquin area collectively reported on effects on groundwater from tens of sources at tens of locations. These effects resulted in the closure of about 100 water supply wells. However, no effects caused by upward migration of brine were reported. Of the shallowest zones with oil production–related activity in each field, the Fruitvale field, Main area, Etchegoin pool had the largest cumulative net injection volume. This pool is also intersected by numerous faults and approximately 900 wells related to oil production, each providing a potential pathway for upward fluid migration. Total dissolved solids and nitrate concentration data are available from greater than 100 water supply wells overlying this pool. Analysis of these data determined there was no significant groundwater quality change likely attributable to upward migration of brine ( p 〈 0.05). It is not known if this is because the application of current underground injection control regulations is effective or because upward migration of brine, which is a dense phase, to groundwater is unlikely. The different engineering and economic implications of these two hypotheses suggest the need for future work to ascertain which is correct under different conditions.

Description: In the Qinhuangdao 29 (QHD29) oil field, oil generated from the first member of the Shahejie source rocks is mainly contained in Paleogene reservoirs, whereas deeper oil sourced from the third member of the Shahejie (Es 3 ) source rocks is generally accumulated in Neogene reservoirs. The present study was undertaken to better understand the differences in petroleum accumulation in the QHD29 oil field and to provide suggestions for future petroleum exploration on the Shijiutuo uplift. Laser Raman spectroscopy reveals that carbon dioxide (CO 2 ) exists with hydrocarbon gas in the same fluid inclusions. Measured homogenization temperatures of aqueous inclusions range from 80°C to 160°C (176°F to 320°F), indicating late-stage rapid petroleum accumulation with a charging time of no earlier than 5.1 Ma. The results of grains containing oil inclusions measurements reveal the presence of paleo-oil accumulation in the current natural gas column. In terms of the boundary fault activity rate (FAR), CO 2 distribution is quite relevant to the late-stage activity of boundary faults, with high content of CO 2 corresponding to the section of the F1 fault with high-intensity activity (higher FAR values). Both Neogene and Paleogene reservoirs in well A1 contained predominantly Es 3 -derived oil and were accompanied by abundant mantle CO 2 . This reveals the segmented vertical transport of petroleum in the fault: both the mantle-derived CO 2 and hydrocarbons vertically migrated and accumulated in shallower reservoirs in the high-activity intensity section of the boundary fault. This may account for the occurrence of predominantly Es 3 -derived oil in the reservoirs near the section of the fault with high activity intensity. In the eastern part of the QHD29 oil field, vertical migration may have been limited because of the relatively low intensity of fault activity, and the distribution of sandstones seems to dominate the petroleum accumulation. Our research reveals that lithologic traps in the Es 3 stratum may still have great potential for exploration along the slope of the Shijiutuo uplift.

Description: Brine samples were collected from 30 conventional oil wells producing mostly from the Charles Formation of the Madison Group in the East and Northwest Poplar oil fields on the Fort Peck Indian Reservation, Montana. Dissolved concentrations of major ions, trace metals, Sr isotopes, and stable isotopes (oxygen and hydrogen) were analyzed to compare with a brine contaminant that affected groundwater northeast of the town of Poplar. Two groups of brine compositions, designated group I and group II, are identified on the basis of chemistry and 87 Sr/ 86 Sr ratios. The solute chemistry and Sr isotopic composition of group I brines are consistent with long-term residency in Mississippian carbonate rocks, and brines similar to these contaminated the groundwater. Group II brines probably resided in clastic rocks younger than the Mississippian limestones before moving into the Poplar dome to replenish the long-term fluid extraction from the Charles Formation. Collapse of strata at the crest of the Poplar dome resulting from dissolution of Charles salt in the early Paleogene probably developed pathways for the ingress of group II brines from overlying clastic aquifers into the Charles reservoir. Such changes in brine chemistry associated with long-term oil production may be a widespread phenomenon in the Williston Basin.

Description: The purpose of this paper is to relate diagenetic processes in deeply buried sandstones in the fourth member of the Eocene Shahejie Formation interval, Bohai Bay Basin, China, to pore-fluid flow changes with progressive burial. Based on petrographic, mineralogical, and geochemical analysis, distribution patterns of authigenic minerals are recognized that reflect (1) the sources and patterns of fluid flow and (2) fluid flow in an evolving open-to-closed system. Partial to extensive precipitation of calcite and dolomite at or near mudstone–sandstone contacts during eogenesis was a result of large-scale mass transfer between sandstones and adjacent mudstones. This process was driven by steep diffusion gradients from adjacent mudstones in a relatively open geochemical system on the local scale. Support for this model is provided by large sulfur isotope fractionation between framboidal pyrite and precursor gypsum. Dissolution of feldspar grains and dissolution of nonferroan carbonate cements during early mesogenesis are spatially associated with quartz and ferroan carbonate cementation, respectively. This process was related to organic carbon dioxide expelled from adjacent source rocks and indicates a relatively open system. During late mesogenesis, dissolution of evaporitic cements related to thermochemical sulfate reduction (TSR) generated ankerite and nodular pyrite cements in adjacent pores. A lack of sulfur isotope fractionation between parent anhydrite and late-stage, nodular pyrite during TSR supports a relatively closed fluid-flow system. Because the velocities of pore-fluid flow were low during mesogenesis, large-scale thermal convection and advection probably did not occur. Instead, diffusion over short distances is inferred as the predominant transport mechanism for dissolved solids that were precipitated as other phases either in situ or in adjacent pores.

Description: Paleogene Umm Er Radhuma and Ghaydah and Neogene Sarar source rocks from Sayhut subbasin in the Gulf of Aden Basin were studied to provide information such as organic-matter types, paleoenvironmental conditions, and petroleum-generation potential. This study is based on whole-rock organic-geochemical analyses and organic petrology. The total organic carbon (TOC) contents of the Paleogene to Neogene source rocks range from 0.43% to 6.11%, with an average TOC value of 1.00%, indicating fair to very good source-rock potential. The Paleogene Ghaydah and Umm Er Radhuma source rocks are relatively higher in genetic petroleum potential than Neogene Sarar source rocks. Mainly oil and gas are anticipated from the Ghaydah and Umm Er Radhuma source rocks with hydrogen index (HI) values ranging from 95 to 715 mg hydrocarbon (HC)/g TOC. This is supported by the presence of significant amounts of liptinite macerals in the Ghaydah and Umm Er Radhuma source rocks. The Sarar source rocks are dominated by vitrinitic type III kerogen (HI 〈 200 mg HC/g TOC) and are thus considered to be gas source rocks. The Paleogene to Neogene source rocks have vitrinite reflectance ( R o ) values in the range between 0.30% and 0.77% R o , and pyrolysis maximum temperature values range from 412°C to 444°C (774°F to 831°F), consistent with the immature to early mature oil window. Therefore, the present-day kerogen type in the Paleogene to Neogene source rocks is original and should not have been altered by thermal maturity. The biomarker of organic matter suggests that the Paleogene to Neogene source rocks were deposited in a marine environment under suboxic to anoxic conditions. The biomarkers also indicate that the Paleogene to Neogene source rocks contain a mixture of aquatic organic matter (planktonic and bacterial) and terrigenous organic matter, with increasing terrigenous influence to Sarar source-rock samples. Highly hypersaline reducing conditions are also evidenced in Ghaydah and Umm Er Radhuma source rocks, as indicated by the presence of the gammacerane biomarker, low pristane to phytane ratios, and homohopane distribution patterns.

Description: Low-maturity Boquillas Formation (Eagle Ford Formation–equivalent) organic-lean calcareous mudrock samples collected from outcrop were heated in gold tubes under confining pressure to investigate the evolution of organic matter (OM) pores and mineral pores. The majority of OM in the Boquillas samples was migrated petroleum (bitumen) based on evidence from geochemical analyses, solvent extraction, and scanning electron microscopy (SEM) petrography. The SEM images showed several diagenetic events—including framboidal pyrite precipitation and euhedral calcite, quartz, kaolinite, and chlorite cementation—that were all interpreted to have occurred prior to petroleum expulsion and pore-scale to bed-scale petroleum (bitumen) migration. Two major pore types were present prior to heating: primary mineral pores and modified mineral pores with migrated relic OM. From heating experiments, pores were found to be associated with stages of OM maturation. During the bitumen generation stage, modified mineral pores were dominant, and primary interparticle and intraparticle pores were present. During the oil generation stage, modified mineral pores with isopachous OM rim were observed to be the most abundant pore type. During the gas generation stage, both modified mineral pores and nanometer-sized spongy OM pores were predominant. We interpreted the occurrence of modified mineral pores to be the result of (1) oil and gas filled or partially filled voids that developed during petroleum migration and water expulsion; (2) voids after removing of oil, gas, and water during sample preparation; and (3) trapping of water molecules. The formation of these nanopores was interpreted to be related to gas generation and structural rearrangement of OM.

Description: Megaflaps are steep stratal panels that extend far up the sides of diapirs or their equivalent welds. They have multiple-kilometer fold widths and structural relief and are thus distinct from smaller-scale composite halokinetic sequences. Maximum dips range from near-vertical to completely overturned. Although overturned megaflaps are associated with flaring salt, there is no direct link between megaflap formation and the initiation of salt sheets. Strata within a megaflap are usually convergent, and the lower boundary is typically concordant with the top salt. The upper boundary ranges between a prominent onlap surface and a more diffuse zone of gradual rotation and thinning, and growth strata likewise display both onlap and stacked wedge geometries. We use quantitative cross-section restoration to elucidate the origin and development of megaflaps. Megaflaps typically represent the relatively thin roofs of early salt structures that include single-flap active diapirs, passive diapirs, salt pillows, and salt sheets. They develop during halokinetic drape folding as the minibasin sinks, during contractional squeezing of the diapir and its roof, or during some combination of the two. The kinematics are dominated by either limb rotation or kink-band migration, in which roof strata move through a fold hinge into a lengthening steep megaflap. Both restoration results and direct field evidence suggest that internal strain is minor, with little bed lengthening and thinning. Recognition and understanding of megaflaps are critical to successful petroleum exploration of three-way truncation traps against salt. Megaflaps also have implications for the lateral seal of stratigraphic traps and fluid pressures in minibasins.

Description: The morphological evolution of submarine channel systems can be documented using high-resolution three-dimensional seismic data sets. However, these studies provide limited information on the distribution of sedimentary facies within channel fills, channel-scale stacking patterns, or the detailed stratigraphic relationship with adjacent levee-overbank deposits. Seismic-scale outcrops of unit C2 in the Permian Fort Brown Formation, Karoo Basin, South Africa, on two subparallel fold limbs comprise thin-bedded successions, interpreted as external levee deposits, which are adjacent to channel complexes, with constituent channels filled with thick-bedded structureless sandstones, thinner-bedded channel margin facies, and internal levee deposits. Research boreholes intersect all these deposits, to link sedimentary facies and channel stacking patterns identified in core and on image logs and detailed outcrop correlation panels. Key characteristics, including depth of erosion, stacking patterns, and cross-cutting relationships, have been constrained, allowing paleogeographic reconstruction of six channel complexes in a 36-km 2 (14-mi 2 ) area. The system evolved from an early, deeply incised channel complex, through a series of external levee-confined and laterally stepping channel complexes culminating in an aggradational channel complex confined by both internal and external levees. Down-dip divergence of six channel complexes from the same location suggests the presence of a unique example of an exhumed deep-water avulsion node. Down-dip, external levees are supplied by flows that escaped from channel complexes of different ages and spatial positions and are partly confined and share affinities with internal levee successions. The absence of frontal lobes suggests that the channels remained in sand bypass mode immediately after avulsion.

Description: In contrast to the high-frequency and high-amplitude sea level changes of icehouse times, eustatic sea level changes in greenhouse times are now generally accepted as significantly lower frequency and amplitude. As a corollary of this, frequency and extent of cross-shelf shoreline transits in greenhouse times are also likely to have been modest by comparison, and it has been suggested that greenhouse deltas may have been docked at the shelf edge for long periods, thus delivering sediment to deep-water areas more frequently. A revisit of upper Paleocene–lower Eocene Wilcox data across south Texas shows repeated regressive–transgressive shoreline migrations longer than 50 km (31 mi) at a time scale of some 300 k.y. This style of repeated shoreline transits is documented from well logs and is supported by the repeated presence of transgressive estuarine deposits with strong tidal evidence as interpreted from core. We argue, therefore, that Wilcox paleogeography was more varied than commonly portrayed and that the greenhouse shoreline transits were caused by greenhouse sea level change but severely modulated by variable sediment discharge caused by Paleogene hyperthermals. Periodic climate warming during Wilcox deposition and Laramide relief generation in the drainage areas were also responsible for unusually high sediment flux into the Gulf of Mexico. The factor of sediment supply in shoreline growth and retreat has been understated in the literature, partly because of an overemphasis on accommodation as the main driver of stratigraphic sequences.

Description: Statistical classification methods consisting of the k -nearest neighbor algorithm ( k -NN), a probabilistic clustering procedure (PCP), and a novel method that incorporates outcrop-based thickness criteria through the use of well log indicator flags are evaluated for their ability to distinguish fluvial architectural elements of the upper Mesaverde Group of the Piceance and Uinta Basins as distinct electrofacies classes. Data used in training and testing of the classification methods come from paired cores and well logs consisting of 1626 wireline log curve samples each associated with a known architectural element classification as determined from detailed sedimentologic analysis of cores ( N = 9). Thickness criteria are derived from outcrop-based architectural element measurements of the upper Mesaverde Group. Through an approach that integrates select classifier results with thickness criteria, an overall accuracy (number of correctly predicted samples/total testing samples) of 83.6% was achieved for a four-class fluvial architectural element realization. Architectural elements were predicted with user’s accuracies (accuracy of an individual class) of 0.891, 0.376, 0.735, and 0.985 for the floodplain, crevasse splay, single-story channel body, and multistory channel body classes, respectively. Without the additional refinement by incorporation of thickness criteria, the k -NN and PCP classifiers produced similar results. In both the k -NN and PCP techniques, the combination of gamma ray and bulk density wireline log curves proved to be the most useful assemblage tested.

Description: Abnormal pressures are encountered during exploration drilling in different parts of Krishna–Godavari Basin on the east coast of India. The nature and stratigraphic occurrences of the overpressure zones vary across the basin. Three different clusters of wells, covering a large part of the basin encompassing both onshore- and offshore-drilled wells, are analyzed to capture this variation. A wide range of pore-pressure gradients from normal to as high as 18 MPa/km was observed in the present data set. The tops of overpressure zones demonstrate a large range from 2200 to 3000 m (6562 to 9842 ft). These depths generally correspond to either a Miocene deltaic sequence or Cretaceous synrift and postrift sequences. Available well data reveal two main reasons for the development of overpressure. Considerably high pore-pressure regimes in the Cretaceous sequence in the eastern corner of the basin are found to be mainly caused by gas generation, whereas disequilibrium compaction is proposed as the main cause for overpressure in the other parts of the basin. The outcome of this analysis provides a fair idea of the nature, magnitude, and distribution of the overpressure, and this will also help to strategize further exploration activities in the basin.