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  • Wiley-Blackwell  (11,969)
  • 1985-1989  (11,969)
  • 1989  (11,969)
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  • 1985-1989  (11,969)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 279-286 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In order to describe the translational diffusion of polymers in dilute solution, an elastic dumbbell model is used for which the effects of both hydrodynamic interaction and a nonlinear connector force are treated in a self-consistently averaged form. For this model, the diffusion tensor in the presence of a homogeneous flow field is obtained from (i) the mass flux caused by concentration gradients, (ii) the average polymer velocity caused by external forces, and (iii) the mean-square displacement of a polymer caused by the Brownian forces. From the second and third approaches the same expression for the diffusion tensor is found, whereas a different expression is obtained from the first approach. This means that the Nernst-Einstein equation cannot be generalized to the case of flowing solutions. The model predictions for the diffusion tensors in steady shear flow are discussed in detail.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 311-313 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 373-384 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady states with different flow rates and temperature profiles may exist in different tubes of a multitube packed-bed reactor due to the coupling among the species, energy and momentum balances, and the change of physical properties with temperature and pressure. Under typical operating conditions if no axial conduction of heat occurs thermoflow multiplicity can be found only for unrealistically high heats of reaction and/or over a very narrow range of exit pressures. However, accounting for the finite but small heat conduction in the reactor tubes leads to multiplicity for typical parameters and a reasonable range of exit pressures. Cooling tends to decrease the region of parameters for which the multiplicity occurs.
    Additional Material: 16 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 385-392 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is developed for fluid-solid reaction kinetics in a porous solid. The model is based on a convergent-divergent pore structure and accounts for pore blockage and inside cavities. A numerical study applied the model to the process of coke removal for catalyst regeneration. The calculated results show that in the presence of pore occlusion, the reaction rates are significantly reduced at the beginning of reaction. At higher levels of coke loading the reaction behavior can be especially affected by the volume fraction of the divergent pores. This behavior can be used to select catalysts with pore structures that improve control of the regeneration process.
    Additional Material: 11 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 365-372 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The approximate equations of Hassler and Brunner and of van Domselaar are often used to deduce the capillary pressure curve of a porous medium from centrifuge data. The use of these equations restricts the centrifuge method to short samples. Also, these equations require differentiation of data. We report here methods to determine the capillary pressure curve by the midpoint and least-squares solution of the fundamental equation, relating the average saturation S1 of liquid in the porous medium to the capillary pressure Pc1 at the end of the sample nearest the axis of rotation. The methods do not require differentiation of data and are not restricted to short samples. We introduce and evaluate an approximation based on an exact result derived by Rajan. This new approximation requires the same inputs as do the Hassler-Brunner and the van Domselaar approximations, but it is accurate over a wider range of sample sizes. In addition, an approximate solution which can be used to estimate capillary pressure curves for long cores is developed.
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 423-428 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A technique based upon transmission FTIR to obtain rate constants for adsorption and desorption over supported metal catalysts has been developed and tested. The technique requires the use of a sinusoidal perturbation function imposed on steady state linearized adsorption-desorption kinetics. The measurement of a phase lag between the sinusoidal inlet gas phase forcing concentration and the response of surface coverage, together with a measurement of the maximum amplitudes of the forcing function and surface response enable the calculation of the relevant adsorption and desorption rate constants.The technique has been successfully applied to the measurement of both adsorption and desorption rate constants for CO adsorbed on a 1% Pt/SiO2 catalyst. The values obtained for these rate constants at 343 K were: Ka = 0.147 s-1 and Kd = 7.28 × 10-3 s-1. A sticking coefficient corresponding to the adsorption of weakly bonded CO on Pt under conditions of high CO surface coverage was obtained.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 490-499 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Orthogonal collocation is used to analyze the dispersion and chemical conversion of a multicomponent fluid pulse in a laminar isothermal flow in a catalytic tube. Homogeneous and heterogeneous first-order chemical reactions are included, and a full matrix diffusion law is used. The collocation method represents the dynamics well over wide ranges of system parameters and reaction time. Radial averaging approaches prove less convenient, since the dispersion coefficients thus introduced are complicated functions of time, transport properties and chemical kinetics.
    Additional Material: 4 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 514-518 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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