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  • Wiley-Blackwell  (10,888)
  • 1985-1989  (10,888)
  • 1988  (10,888)
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  • 1985-1989  (10,888)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1-8 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Results of a computer study are reported applying data reconciliation and interpretation techniques to a single-stage flash operation. Measured errors in the process variables are significantly reduced. The techniques are successfully extended to estimate flash efficiency. The flash efficiency is estimated using two methods: (1) a statistically rigorous simultaneous data reconciliation and efficiency estimation procedure, and (2), a faster, nonrigorous sequential procedure. It is found that the simultaneous procedure provides better measured variable and flash efficiency estimates.
    Additional Material: 8 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 37-44 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady states with different flow rates and temperature profiles may exist in a monolith or multitube packed-bed reactor operating under a prescribed pressure drop, due to the coupling among the species, energy, and momentum balances, and the change of physical properties with temperature and pressure. Criteria are derived predicting the conditions under which thermoflow multiplicity can occur for a gaseous reaction involving a change in the number of moles. In general, a reaction-induced volume increase enables thermoflow multiplicity to occur for reactions with a lower adiabatic temperature rise. A surprising finding is that thermoflow multiplicity may be found for an isothermal reaction involving a volume decrease. This point emphasizes the difference in the feedback mechanism leading to thermoflow and thermokinetic multiplicity.
    Additional Material: 8 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 123-129 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A light-extinction principle was used to measure the fall speeds of the interfaces that develop during gravity sedimentation of monodisperse, bidisperse, and tridisperse suspensions of noncolloidal particles with small particle Reynolds numbers in the semidilute total particle volume fraction range 0.0003 ≤ c0 ≤ 0.15. For monodisperse suspensions, the hindered settling velocity of the interface at the top of the suspension was found to be well represented by the correlation of Richardson and Zaki, provided that the isolated particle fall speed was chosen by linear extrapolation of the data to c0 = 0, with 90% confidence intervals on the exponent of n = 5.0 ± 0.1. For dilute monodisperse, bidisperse, and tridisperse suspensions, the hindered settling velocities of the interfaces showed agreement within experimental uncertainty with the theory of Batchelor, which predicts that the settling velocity decreases linearly with increasing particle concentration and which is based upon pairwise particle interactions.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 144-146 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 158-162 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 209-222 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is presented for convection and chemical reacton in porous media. An irreversible chemical reaction of arbitrary order is considered. Reactant depletion allows for basic solutions in either the kinetic or the diffusion regime. The cases of forced flow parallel to the lateral walls of the cavity and a closed system are addressed. A linear stability analysis of the basic states is performed and critical values of the thermal Rayleigh number for the onset of natural convection are determined. A dispersion relation is derived and a graphical representation of the linear stability analysis results is provided for typical values of the system parameters. Analytical predictions are verified by results obtained by numerical integration of the complete set of nonlinear partial differential equations. The effect of natural convection is discussed when the basic state is either in the kinetic or in the diffusion regime. For large gradients, associated with the diffusion regime, chemical reaction can drive free convection even for low values of the Rayleigh number. In forced flow systems, natural convection can change substantially the flow pattern of the system.
    Additional Material: 12 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 253-262 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Aerosol deposition in model filters composed of layers of parallel fibers with the orientation of the fiber of each layer kept arbitrary was simulated stochastically. Particle positions at the inlet of the filter were assumed to be randomly distributed over the inlet plane with the trajectory assumed to be rectilinear because of the particles' high inertia. In the simulation, the track of each particle through the filter was monitored and the possible bounce-off from collision surfaces was allowed for. Deposition behavior and the structure of deposits were studied with various aerosol flow conditions and filter characteristics.
    Additional Material: 19 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 45-54 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical and experimental study on the dissolution of porous media by flowing acid has been carried out. Dissolution of the media results in an evolution of the pore geometry and the formation of random flow channels. The goal is to predict the range of conditions under which channels will form, and the effects of various parameters on the structure of the channels and on their rate of propagation through the media. A random network model is used to describe the behavior of the stochastic, rootlike channels that form during flow and dissolution in carbonate rock and in other systems. The structure of the flow channels that form as a result of acid attack are characterized and studied using a Wood's metal casting technique. A comparison of model results shows that the rates of channel formation and growth are intimately related to the developing structure of the channels (size of branches and degree of branching), which in turn is controlled by factors such as the fluid velocity and the rate of reaction. Depending on the experimental conditions, the channels range from a single conduit with a minimum of branching to a highly branched, spongy network of channels. The dependence of permeability increase and channel branchedness on injection rates and acid diffusion rates is described by the Damkohler number for flow and reaction.
    Additional Material: 18 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 329-332 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 341-346 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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