ALBERT

Description: Analysis of individual laminae in Recent sediments from the slopes of the Guaymas Basin indicates an increased abundance of the larger sizes (〉60 µm) of Coscinodiscus nodulifer when upwelling conditions persist over the depositional site and an increase of the smaller sizes (〈60 µm) when nonupwelling conditions exist. The size distributions of C. nodulifer in 10-cm composite samples from Hole 480 show a greater abundance of the large sizes (〉60 µm) associated with well-laminated sections and more of the smaller sizes (〈60 µm) in samples from the homogeneous sections. We have tentatively correlated the pronounced homogeneous zones with late Pleistocene glacial periods. These results indicate a persistence of nonupwelling conditions over Hole 480 during glacial periods (homogeneous zones) and a predominance of upwelling conditions during interglacial periods (laminated zones). Other evidence from diatom and silicoflagellate floral analysis seems to support these preliminary conclusions.

Description: Analyses of stable isotopes of monospecific planktonic foraminifers (G. quadrilobatus group) and monogeneric benthic foraminifers (Cibicidoides spp.) from late Neogene Atlantic Site 502 and Pacific Site 503 were conducted in order to determine the paleoceanographic changes resulting from the late Neogene uplift of the Panama Isthmus and from climatic cooling. In general, results at each site are similar to those from previous studies for the late Miocene and late Pliocene time interval, documenting the late Miocene (6 Ma) shift in carbon isotopes and the inferred growth of permanent Northern Hemisphere continental ice sheets beginning about 3.2 Ma. Comparison of Atlantic-Pacific planktonic-benthic isotope data for four stratigraphic intervals (~6-8, ~5-6, ~3-5, and ~2-3 Ma) suggests that increasing isolation of Atlantic and Pacific low-latitude waters may be related to the emergence of the Panama Isthmus. The contrast between Atlantic and Pacific benthic foraminiferal d13C increased in two steps from 0.60 per mil to 1 per mil (the modern contrast) at about 6 Ma and 3 Ma. The first increase (0.15 per mil) may represent the end of previously limited deep-water communication between the Atlantic and Pacific at the present location of Panama. The second increase (0.25 per mil) may be due to increased production of North Atlantic Deep Water. This probably reflects the development of modern deep-sea circulation. The d18O of planktonic foraminifers begins to increase in Atlantic Site 502 at 4.2 Ma and may reflect the increasing salinity of the North Atlantic Ocean arising from diminishing surface-water exchange across Panama. This increase is clearly shown by contrasting the d18O of Atlantic and Pacific planktonic foraminifers, as well as the d18O of planktonic and benthic foraminifers at Site 502. This inferred increase in surface-water salinity begins at the time of increasing provinciality of Atlantic and Pacific planktonic foraminifers.

Description: Heavy and light minerals were examined in 29 samples from Sites 494, 498, 499, 500, and 495 on the Deep Sea Drilling Project Leg 67 Middle America Trench transect; these sites represent lower slope, trench, and oceanic crust environments off Guatemala. All samples are Quaternary except those from Hole 494A (Pliocene) and Hole 498A (Miocene). Heavy-mineral assemblages of the Quaternary sediments are characterized by an immature pyroxene-amphibole suite with small quantities of olivine and epidote. The Miocene sediments yielded an assemblage dominated by epidote and pyroxene but lacking olivine; the absence of olivine is attributed to selective removal of the most unstable components by intrastratal solution. Light-mineral assemblages of all samples are predominantly characterized by volcanic glass and plagioclase feldspar. The feldspar compositions are compatible with andesitic source rocks and frequently exhibit oscillatory zoning. The heavy- and light-mineral associations of these sediments suggest a proximal volcanic source, most probably the Neogene highland volcanic province of Guatemala. Sand-sized components from Site 495 are mainly biogenic skeletons and volcanic glass and, in one instance (Section 495-5-3), euhedral crystals of gypsum.

Description: Mineralogical and oxygen isotopic analyses of samples from Deep Sea Drilling Project Sites 477, 481, and 477 in the Guaymas Basin indicate the existence of two distinct hydrothermal systems. In the first, at Sites 481 and 478, hot dolerite sills intruded into highly porous hemipelagic siliceous mudstones that were moderately rich in organic matter, thermally altered the adjacent sediments, and expelled hydrothermal pore fluids. The second, at Site 477 and active at present, is most probably caused by a recent igneous intrusion forming a magma chamber at shallow depth. In the first hydrothermal system, the main thermal reactions above and below the sills are dissolution of opal-A and formation of quartz, either directly or through opal-CT; formation of smectite; formation of analcime only above the sills; dissolution and recrystallization of calcite and occasional formation of dolomite or protodolomite. The d18O values of the hydrothermally altered sediments range from 9.9 to 12.2 per mil (SMOW). The d18O values of recrystallized calcites above the first sill complex, Site 481, indicate temperatures of 140° to 170°C. No fluid recharge is required in this system. The thickness of the sill complexes and the sequence and depth of intrusion into the sediment column determine the thickness of the alteration zones, which ranges from 2 or 3 to approximately 50 meters. Generally, the hydrothermally altered zone is thicker above than below the sill. In the second type, the sediments are extensively recrystallized. The characteristic greenschist-facies mineral assemblage of quartz-albite-chlorite-epidote predominates. Considerable amounts of pyrite, pyrrhotite, and sphene are also present. The lowest d18O value of the greenschist facies rocks is 6.6 per mil, and the highest d18O value of the associated pore fluids is +1.38 per mil (SMOW). The paragenesis and the oxygen isotopes of individual phases indicate alteration temperatures of 300 ± 50°C. On the basis of the oxygen isotopes of the solids and associated fluids, it is concluded that recharge of fluids is required. The water/rock ratio in wt.% is moderate, approximately 2/1 to 3/1 - higher than the calculated water/rock ratio of the hydrothermal system at the East Pacific Rise, 21 °N.

Description: Nontronite, the main metalliferous phase of the Galapagos mounds, occurs at a subsurface depth of ~2–20 m; Mn-oxide material is limited to the upper 2 m of these mounds. The nontronite forms intervals of up to a few metres thickness, consisting essentially of 100% nontronite granules, which alternate with intervals of normal pelagic sediment. The metalliferous phases represent essentially authigenic precipitates, apparently formed in the presence of upwelling basement-derived hydrothermal solutions which dissolved pre-existent pelagic sediment. Electron microprobe analyses of nontronite granules from different core samples indicate that: (1) there is little difference in major-element composition between nontronitic material from varying locations within the mounds; and (2) adjacent granules from a given sample have very similar compositions and are internally homogeneous. This indicates that the granules are composed of a single mineral of essentially constant composition, consistent with relatively uniform conditions of solution Eh and composition during nontronite formation. The Pb-isotopic composition of the nontronite and Mn-oxide sediments indicates that they were formed from solutions which contained variable proportions of basaltic Pb, introduced into pore waters by basement-derived solutions, and of normal-seawater Pb. However, the Sr-isotopic composition of these sediments is essentially indistinguishable from the value for modern seawater. On the basis of 18O/16O ratios, formation temperatures of ~20–30°C have been estimated for the nontronites. By comparison, temperatures of up to 11.5°C at 9 m depth have been directly measured within the mounds and heat flow data suggest present basement-sediment interface temperatures of 15–25°C.

Description: The usefulness of cosmogenic beryllium-10 (half life = 2.5 Ma) for studying the rates of accumulation of ferromanganese nodules is reported based on its measured depth distribution in the top 20 mm of these deposits. Accumulation rates have been obtained in the range of 1 to 4 mm/Ma, which are in good agreement with rates determined using the 230Th method on the same nodules. The use of 10Be offers promise in extending the dating to the outer few cm of the nodules. This contrasts with conventional methods using 230Th and 231Pa isotopes which, due to their comparatively short half lives, are limited to a few mm at the surface of the nodules. Detailed studies of 10Be in the manganese deposits coupled with other trace element analyses should prove valuable in understanding the processes of formation of these deposits and the chronology of events recorded by them.

Description: Nodules occur in the siliceous calcareous ooze and siliceous marl at Site 503 in the eastern equatorial Pacific. They are present below a depth of about 11 meters throughout the green-colored reduced part of the section down to 228 meters, although they are most abundant between 30 and 85 meters. They are cylindrical or barrel-shaped, up to 70 mm long, and usually have an axial channel through them or are hollow. They appear to have formed around and/or within burrows. XRD studies and microprobe analyses show that they are homogeneous and consist of calcian rhododrosite and minor calcite; Mn is present to the extent of about 30%. Isotopic analyses of the carbonate give carbon values which range from -1.2 per mil to -3.8 per mil, and oxygen isotope compositions vary from +4.0 per mil to +6.0 per mil. These values are different from those for marine-derived carbonates as exemplified by the soft sediment filling of a burrow: d13C, -0.26 per mil; d18O, +1.05 per mil. The carbon isotope data indicate that carbonate derived (possibly indirectly) from seawater was mixed with some produced by organic diagenesis to form the nodules. The d18O values suggest that although they formed near the sediment surface, some modification or the introduction of additional diagenetic carbonate occurred during burial.

Description: The cores and dredges described in this report were taken on Cruise 128 of the R.R.S. "Discovery" in May 1982 by the National Institute of Oceanography, Wormley, United Kingdom. A total of 12 cores were recovered and are available through the British Oceanographic Data Centre for sampling and study.

Description: Deep-sea echinoderms of the Tongue of the Ocean, Bahama Islands, have been studied, using trawled collections made by the University of Miami together with observations from the deep submersible Alvin. Transect runs in the submersible permitted studies of population densities and behaviour of approximately 38 species of larger invertebrates, of which 27 were echinoderms. Several echinoderm species show a patchy distribution pattern which is apparently not related to available food resources. Some species are exclusively herbivores, feeding on fragments of turtle grass, Thalassia testudinata and sargassum weed, Sargassum spp. Feeding habits of some Tongue of the Ocean echinoderms are compared with those of the same species from further north, where supplies of plant material are not nearly so abundant.

Description: Scientists from the Woods Hole Oceanographic Institution, the U.S. Navy, the State University of New York at Albany, Wesleyan University, Nine dives in the research submersible ?Alvin? were made into Great Abaco Submarine Canyon to depths ranging from 1850 to 3666 m. Our observations indicate that the walls of this canyon are distinctly terraced, consisting of nearly vertical to overhanging rock cliffs and intervening, less steep sediment-covered slopes. The wall rock consists mostly of massive, shallow-water limestones and dolostones of Cretaceous age, coated on exposed surfaces with manganese oxides. These rocks are heavily jointed/fractured and thus very blocky to angular in appearance, with sponges and other sessile organisms commonly attached. Talus slopes and sedimentary breccia deposits containing angular boulders are present at the base of these steep escarpments. Short-term bottom current measurements in the axis of the eastern part of the canyon indicate that currents are relatively weak, reaching velocities of only 10 cm/sec. This relatively placid setting is further corroborated by the abundance of turtle grass (Thalassia) found along the canyon axis. However, abundant subdued, symmetrical ripple marks and large scour depressions at the base of boulders, indicate that high-energy events sporadically impact the canyon axis. Contemporary erosional activity along the axis of the western (headward) part of the canyon appears to be more significant, as evidenced by asymmetrical ripple marks, sand waves and bioerosion. Great Abaco Canyon has evolved with time via a variety of processes, including: (1) faulting: (2) subsidence; (3) defacement; and (4) erosional down-cutting. The location, orientation and initiation of this canyon appear to be structurally controlled by the Great Abaco Fracture Zone during pre-Santonian time. Regional subsidence during the Mesozoic allowed the walls of Great Abaco Canyon to build vertically by accretion of shallow-water limestones, whereas joint-controlled defacement has widened the canyon while maintaining steep walls. Erosional down-cutting in the canyon axis by carbonate sediment gravity flows also appears to have been important episodically, particularly during the Miocene and Pleistocene.

Description: Two consecutive drilling legs (Legs 59 and 60) were assigned to drill an east-west transect of sites along latitude 18°N, from the Mariana Basin of the Pacific Ocean to the oldest inactive island arcs and back-arc spreading basins of the Philippine Sea. The western (older, inactive) half of this transect (Philippine Sea, Palau-Kyushu Ridge, Parece Vela Basin, and the West Mariana Ridge-Sites 447-451) was drilled during Leg 59. The objective of Leg 60 was to sample the tectonically active eastern portion of the transect in a closely spaced series of holes across the presently opening back-arc basin (Mariana Trough, Site Survey Target SP-4: Sites 453-456), the Mariana arc itself (Site Survey Target SP-3b: Site 457), the Mariana fore-arc region (Site Survey Target SP-3, Sites 458 and 459), and deep within the Mariana Trench (Site Survey Target SP-2: Sites 460 and 461). In addition, one site (Site Survey Target SP-1: Site 452) was drilled on the Pacific plate seaward of the trench to obtain a reference section of sediments and oceanic crust being delivered to the trench.

Description: The origin and evolution of passive continental margins are of great scientific interest and economic importance. During DSDP Leg 64 the Glomar Challenger drilled at eight sites (474-481) in the Gulf of California region. The Gulf of California presented a singular example of tectonics and sedimentation in a very young ocean, being formed by translation and oblique rifting. The sedimentation of the region is hemipelagic, rapid, and largely dominated by siliceous microfossils.Sites 474, 475, and 476 form a transect from oceanic crust to continental crust at the southern tip of Baja California in order to define passive-margin subsidence during the early post-rifting phase. Sites 477, 478, and 481 investigate of the nature of young ocean crust in the Guaymas Basin, where high accumulation rates are common and variable high heat flow indicates active rifting and hydrothermal activity. Sites 479 and 480, are situated on the Guaymas Basin Slope above the proto-Gulf sequences. Interest focused on the paleoceanography of laminated, homogeneous diatom-rich, anoxic sediments within the zone of low oxygen.

Description: Leg 66 was part of two broader investigations of subduction complexes and convergent margin geology, one led by the Active Margin Panel (AMP) of the International Phase of Ocean Drilling (IPOD) to drill selected convergent margins to elucidate structure and evolution and the other, led by the University of Texas Marine Science Instituted (UTMSI) Galveston Geophysical Laboratory (GGL) to investigate the tectonics of the Middle America Trench from the Cocos Fracture Zone to the Riviera Fracture Zone. In this context, the specific objective at Site 487 was the coring of pelagic and hemipelagic sediment section and underlying oceanic basement. It is the farthest offshore site off the Cocos Fracture Zone.

Description: The Oaxaca transect, located off southern Mexico and drilled during Leg 66, sampled a truncated margin and subduction complex. In contrast, the Guatemala transect was selected because accretion was thought to have continued in this area during most of the Tertiary. Site surveys conducted by the University of Texas Marine Science Institute provided multichannel seismic records, among which profile GUA-13 was chosen as the location for Leg 67 drill holes. Selection of this transect arises in part from the fact that it includes a portion of the San José Canyon, thus layers of hemipelagic drape may have been stripped away by erosion, allowing quicker access to deep horizons. By studying the continental margin off Guatemala it was hoped to strengthen the tie between offshore and onshore geology, to describe the stratigraphic sequence from the continental slope to the subducting oceanic plate beneath, to recover in ash layers a record of Central American volcanism.

Description: The general objectives of this cruise were to use the newly developed HPC to recover two undisturbed, continuous records of the late Neogene and Quaternary, one from the western Caribbean and the other from the eastern equatorial Pacific, and to test the coring capabilities of the HPC. At site 502 in the Caribbean an hemipelagic facies with accumulation rates of about 3 cm/k.y near site 154 were a coarse-grained volcanogenic turbidite sequence had been recovered at a depth equivalent to a strong seismic reflector. Site 503 was located as close as possible to previously rotary-drilled Site 83 in the eastern equatorial Pacific.

Description: The recovery of hydrothermal sediments at depth beneath the mounds of hydrothermal origin during a brief period of drilling on Deep Sea Drilling Project (DSDP) Leg 54 provided some evidence suggesting that hydrothermal material may be pervasive over a relatively large region inclusive of the mounds but also incorporating adjacent seafloor presently covered by pelagic sediments. As a result of the incomplete recovery of sediments at some sites and the poor recovery of basement rocks during Leg 54, it was suggested that a more carefully planned program be designed to drill a broader range of sites in the Galapagos mounds field. The major objectives of the first part of Leg 70 were to collect data and sediment representative of the hydrothermal mounds and ridges located about 20 km south of the Galapagos spreading axis.

Description: he three-site Leg 64 Deep Sea Drilling transect at the tip of the Peninsula of Baja California straddled the transition from continental to oceanic crust. The outer site, 474, penetrated mainly mud turbidites and bottomed in "middle" Pliocene oceanic crust about 3 m.y. old. Two sites on the lower continental slope penetrated hemipelagic muddy sediments, a thin section of low-oxygen, phosphoritic, and glauconitic sediments, and a metamorphic cobble conglomerate; one of the sites, 476, bottomed in deeply weathered granite. The oldest marine sediments at this site are early Pliocene, about 4.5 m.y. old. Depth indicators in these holes suggest that all sites were in almost 1000 meters of water by the time oceanic crust was first generated and sea-floor spreading began. Block faulting, subsidence, and deposition of marine sediments on continental crust had preceded the start of sea-floor spreading. Close examination of lineated magnetic anomalies demonstrates that the transition from continental to oceanic crust in this region is diachronous, as early as 4.9 m.y. in some places, but as young as 3.2 m.y. along the line of the transect. We propose a geological history scenario which involves termination of subduction along the western margin of Baja California at 12.5 Ma, a period of transform motion between the Pacific and North American plates along the Tosco Abreojos Transform Fault zone along the west side of Baja California, and a jump of the Pacific-North American plate edge to the alignment of the Gulf at 5.5 Ma. Between 5.5 Ma and about 3.2 Ma, separation of the blocks occurred locally by sea-floor spreading, but elsewhere by "diffuse extension", largely involving listric normal faulting and thinning of the continental crust, accompanied by subsidence and marine inundation. Thus, the plate edge system in the mouth and southern part of the Gulf evolved as early as 5.5 Ma, but the transition from rifting to drifting was diachronous, starting only 3.2 Ma along the line of the transect.

Description: A detailed geophysical and geological survey of the Mariana Trough, an actively extensional back-arc basin, was conducted in 1976 and 1977 to provide data for selection of drilling sites for DSDP Leg 60. These surveys revealed large-scale bathymetric trends, sediment distribution, crustal seismic veolocity structure, and earthquake activity that suggest the basin is opening around an axial spreading center tectonically similar to the slowly spreading Mid-Atlantic Ridge. There are, however, significant differences in the character of the trough, such as poorly defined magnetic anomalies, extreme bathymetric relief, and the frequent occurrence of low-magnitude earthquakes but absence of larger seismic events. Seafloor spreading in the Mariana Trough may be characteristic of the initial opening stages of any oceanic rift system, whether or not it is in a back-arc setting.

Description: Mineralogical (microprobe) and geochemical (X-ray fluorescence, neutron activation analyses) data are given for 18 samples of volcanic rocks from the Guatemala Trench area (Deep Sea Drilling Project Leg 67). Typical fresh oceanic tholeiites occur in the trench itself (Hole 500) and in its immediate vicinity on the Cocos Plate (Site 495). Several samples (often reworked) of "spilitic" oceanic tholeiites are also described from the Trench: their mineralogy (greenschist facies association - actinolite + plagioclase + chlorite) and geochemistry (alteration, sometimes linked to manganese and zinc mineralization) are shown to result from high-temperature (300°-475°C) hydrothermal sea water-basalt interactions. The samples studied are depleted in light rare-earth elements (LREE), with the exception of the slightly LREE-enriched basalts from Hole 500. The occurrence of such different oceanic tholeiites in the same area is problematic. Volcanic rocks from the Guatemala continental slope (Hole 494A) are described as greenschist facies metabasites (actinolite + epidote + chlorite + plagioclase + calcite + quartz), mineralogically different from the spilites exposed on the Costa Rica coastal range (Nicoya Peninsula). Their primary magmatic affinity is uncertain: clinopyroxene and plagioclase compositions, together with titanium and other hygromagmaphile element contents, support an "active margin" affinity. The LREE-depleted patterns encountered in the present case, however, are not frequently found in orogenic samples but are typical of many oceanic tholeiites.

Description: Manganese nodules from 36 stations in the Cape Leeuwin field were analyzed for Mn, Fe, Ni, Cu and Co and the results were combined with earlier work to demonstrate quantitative and geographic variations. Nodules in this field are moderately enriched in Ni, moderately depleted in Cu, and contain intermediate values of Co. The sum of Ni + Cu vs. Mn/Fe plots along a hyperbolic regression line derived from nodules of the southeastern Pacific, suggesting that this relationship has general applicability. Regional variations in nodule grade (Ni + Cu + Co) assist in defining pathways of Antarctic Bottom Water between the Southeast Indian Ridge and the Wharton basin.

Description: The purpose of the expedition was to test new techniques to determine thickness, distribution and quality of mineral deposits on the Blake Plateau with special reference to manganese nodules and manganese-phosphate pavements.

Description: Sample preparation technique is critical for valid chemical analyses. A main source of error comes from the fact that the great specific surface area of crusts or nodules enhances their tendency to retain or attract hygroscopic moisture. Variable treatment of this moisture can in extreme cases lead to analytical value differences as great as 40-50 %. In order to quantify these influences, samples of ferromanganese oxide-phosphorite pavement from the Blake Plateau have been subjected to various drying techniques before analysis using X-ray fluorescence.

Description: Ferromanganese deposits, mostly manganese crusts, are common in elevations along the northeastern Brazilian continental margin. Association of the deposits with more or less altered basaltic rock can be observed. On the Pernambuco Plateau and Ceara Guyot, ferromanganese deposits occur associated with phosphatic material and nodules. The mineralogical composition of the ferromanganese deposits indicates a predominance of the manganese oxide phase dMnO2. Low contents of Mn and Cu are characteristic of their chemical composition. Fe and Mn in the deposits probably precipitated from the sea water.

Description: The report is divided into three sections: morphology, mineralogy and elemental composition. The nodule morphology section defines what is considered a nodule for the study, and details the external characteristics and internal structure. Nodule mineralogy is discussed in three sections: manganese minerals, iron oxide minerals, and accessory minerals. The major manganese minerals discussed are todorokite, birnessite, and vernadite. The iron oxide minerals are less well known and include feroxyhyte, goethite, and lepidocrocite. Accessory minerals present include quartz, clays, and other silicates and nonsilicates. A discussion on moisture content is also included. The elemental composition section presents data on 74 elements occurring as cations or anions. Summary data, histograms, and interelement correlation coefficients are presented.

Description: Isolation and analysis of the eolian component of late Cenozoic pelagic sediments from the North Pacific provides direct information concerning changes in atmospheric circulation. A 50% increase in intensity of both the prevailing westerlies and the tradewinds coincides with increasing pole-to-equator temperature gradients resulting from the onset of northern hemisphere glaciation. At the same time, the mass flux of dust from continents to the North Pacific increased by a factor of 4.5, apparently reflecting significantly increased continental aridity associated with the late Cenozoic glacial ages.

Description: We present here oxygen and carbon isotopic records of Eocene to Oligocene benthic foraminifera from two Bay of Biscay Deep Sea Drilling Project (DSDP) sites (119 and 401). d18O of benthic foraminifera increases 1.9 per mil from a middle Eocene minimum (Zones P10-P11) to an earliest Oligocene maximum (Zone NP21). Approximately 1.4 per mil of the increase in benthic foraminiferal d18O occurs during the late Eocene to earliest Oligocene (Zones P15/16-NP21). Previous results from other North Atlantic DSDP sites (400A and 398) have significantly lower d18O values of benthic foraminifera, some by as much as 2 per mil (Vergnaud-Grazzini et al., 1978; 1989, doi:10.2973/dsdp.proc.48.119.1979; Vergnaud-Grazzini, 1979, doi:10.2973/dsdp.proc.47-2.117.1979 ). We believe that these differences result from diagenetic alteration of the sediments in the deeper-buried Sites 400A and 398.

Description: Carbon-14 determinations on box cores of calcareous ooze from the western and eastern equatorial Pacific suggest that patterns of mixed-layer ages, sedimentation rates, and mixed-layer thicknesses are controlled by gradients of carbonate dissolution and fertility, and by small-scale redeposition processes. Mixed-layer ages range from 3000 to 7000 years, with a mode between 4000 and 5000 years. Sedimentation rates range from 0.8 to 2.4 cm/1000 years. Mixed-layer depths, calculated according to the box model of mixing, range from 7 cm to 16 cm. Observed thicknesses are about one-fourth smaller than calculated ones.

Description: Ferromanganese concretions cover large areas of the Gulf of Bothnia. They are flat to well-rounded, the rounded ones being richer in oxyhydroxides of iron and manganese. Rounded and ellipsoidal nodules, particularly those in the northern Gulf of Bothnia, are richest in Mn, Ni, Ba and Cu, which probably coexist in a Mn oxyhydroxide phase. Flat nodules are enriched in Fe, P, rare earths and As, probably associated with an Fe oxy-hydroxide component. Aluminum, V, Cr and Ti occur in still another phase. The sediments of the gulf generally consist of a 10-50 mm-thick layer of oxidized surface sediment, enriched in Mn, Ba, P and Ni lying on top of reduced sediments which are diagenetically depleted in these elements. The remobilized elements have redeposited in the nodules, but this process cannot explain the origin of all the nodular material. Some released Mn, Ba and Ni furthermore enter into suspended phases, which eventually leave the Baltic Sea. The economic value of the nodules in the Gulf of Bothnia is probably limited at present.

Description: Hydrothermal deposits of a wide variety of types are being found with increasing frequency on or near actively spreading mid-ocean ridges. However, they also have a potential to occur in other submarine volcanic settings, including island arcs. To follow up indications of mineralization associated with submarine hydrothermal activity in the south-west Pacific island arc, a joint New Zealand Oceanographic Institute/Imperial College research cruise was mounted in May 1981 aboard the RV Tangaroa. During this cruise, over 130 sampling stations were occupied, at one of which were dredged manganese deposits with strong hydrothermal affinities. This is the first report of such deposits from an island arc setting.

Description: Recent studies on marine ferromanganese nodules have suggested a relationship between their growth rate and their chemical composition. The suggestion is based on the hypothesis that the metals in nodules have two sources of supply: bottom seawater (hydrogenous) and sediment pore water (diagenetic). The diagenetic source calls for upward diffusion of Mn mobilized in a deeper, low Eh zone of the sediment column and its subsequent precipitation in an oxidized surface zone. Addition of the remobilized Mn to surface nodules would augment their accretion rate. It would also render the oxide layers to contain higher Mn/Fe ratios than layers resulting from hydrogenous precipitation. We report here a radiometrically determined accretion rate of 168±24 mm/Myr for a deep-sea manganese nodule from the Peru Basin in the Pacific. This rate is about two orders of magnitude higher than that frequently found in nodules of deep-sea origin, and emphasizes the importance of sediment diagenetic processes on the growth of manganese concretions.

Description: Drilling durin Deep Sea Drilling Project Legs 68, 69, and 70 on the southern limb of the Costa Rica Rift was used to study geothermal processes in the ocean crust. Two areas were drilled. One was a geothermally hot site on 6.2-m.y.-old crust, where topography is smooth, heat flow is close to that predicted by conductive cooling of the lithosphere (200 mWm**-2), and hydrothermal circulation may be sealed within the crust. The other was on 3.9-m.y.-old crust, where rough topography is associated with low heat flow (15 to 50 mWm**-2) and possible open convection of sea water. At both sites, about 250 m of siliceous-calcareous sediments overlies igneous basement. In the hot area, it blankets the topography, whereas in the cold area, basement outcrops still occur. Operations included numerous down-hole experiments in both areas and hydraulic piston coring of a 230-m sediment section in the hot area. Diagenesis of the sediments appears closely related to temperature. At the hot site, chert was found near basement, and the chemistry of pore fluids, sampled from both sediments and basement, is strongly influenced by reactions within the basement. Strong lateral gradients in the composition of pore fluids occur in the sediments. At the cold site, no chert was found, and bacterial processes within the sediment dominated the chemistry of the pore fluids. Basaltic basement in both areas consists mainly of pillow lavas and thin flows, with occasional more massive units. The basalt is relatively magnesian. The degree of alteration is very small in the cold area, but much more extensive in the hot area. Ease of drilling also shows a strong contrast. Basement penetration reached 562 m in the hot area and was halted because of lack of time; at the cold site, 43 m of basement was cored only with difficulty. The most intensive in-hole experiments were conducted in the hot area. Successful runs with the borehole televiewer allowed basement lithology to be determined and showed the presence of more and less fractured zones. Pulse tests using a single borehole packer gave values of basement permeability of about 2 to 40 millidarcies. Numerous temperature logs established a broadly conductive in situ temperature gradient, with temperatures reaching 120°C at 562 m into the basement. However, anomalously low temperatures in the upper part of the hole, which persisted after drilling disturbance had decayed away, showed that cold ocean water was flowing down the hole and into the basement at about 90 m below the base of the sediments, at rates of about 80 to 100 m/hr. The packer records indicate a pressure at this depth of 10 bars below hydrostatic.

Description: The Pliocene-Quaternary sediments that we drilled at eight sites in the Gulf of California consist of silty clays to clayey silts, diatomaceous oozes, and mixtures of both types. In this chapter I have summarized various measurements of their physical properties, relating this information to burial depth and effective overburden pressure. Rapid deposition and frequent intercalations of mud turbidites may cause underconsolidation in some cases; overconsolidation probably can be excluded. General lithification begins at depths between 200 and 300 meters sub-bottom, at porosities between 55 and 60% (for silty clays) and as high as 70% (for diatomaceous ooze). Diatom-rich sediments have low strength and very high porosities (70-90%) and can maintain this state to a depth of nearly 400 meters (where the overburden pressure = 1.4 MPa). The field compressibility curves of all sites are compared to data published earlier. Where sediments are affected by basaltic sills, these curves clearly show the effects of additional loading and thermal stress (diagenesis near the contacts). Strength measurements on well-preserved hydraulic piston cores yielded results similar to those obtained on selected samples from standard drilling. Volumetric shrinkage dropped to low values at 100 to 400 meters burial depth (0.3 to 2.0 MPa overburden pressure). Porosity after shrinkage depends on the composition of sediments.

Description: Geochemical analyses were carried out on Quaternary sediments from cores at Sites 479 and 480. The amount of organic matter indicates that these sediments have good to very good source-rock potential. Rock-Eval pyrolysis and microscopic examination show that many of the samples contain thermally immature, oil-prone, marine organic matter. Preliminary results show that Rock-Eval pyrolysis can distinguish oxic (bioturbated) and anoxic (laminated) organic facies in the cores. More than 10% of the organic carbon in these immature sediments is normally lost as hydrolysate during conventional acid treatment for the removal of carbonates. The protokerogen remaining after solvent extraction and acid maceration constitutes only a fraction of the total organic matter. Elemental analysis, pyrolysis, and vitrinite reflectance of the kerogenous residue show that it is considerably less oil prone than the total organic matter.