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  • Chemistry  (11,435)
  • Inorganic Chemistry  (1,488)
  • Cell & Developmental Biology  (531)
  • 1975-1979  (11,966)
  • 1978  (6,229)
  • 1975  (5,737)
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  • 1975-1979  (11,966)
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  • 1
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1978-10-13
    Description: Picosecond spectroscopy is a relatively new field of science that utilizes ultrashort laser pulses to monitor events taking place in the 10(-12) second regime. The continuing development of picosecond spectroscopy has made possible the detection and measurement of the primary events in many physical and tiological processes. This article describes a currently used picosecond spectroscopy system that is capable of reliably recording picosecond events. Two areas of picosecond research are discussed; one concerns the interaction of electrons in fluids, and the second the primary events in vision.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Rentzepis, P M -- New York, N.Y. -- Science. 1978 Oct 13;202(4364):174-82.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/694523" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; Electrons ; *Kinetics ; Lasers ; Protons ; *Retinal Pigments ; *Rhodopsin ; Spectrum Analysis/*methods ; Temperature ; *Vision, Ocular
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1978-03-17
    Description: The history of U.S. foreign aid support of science and technology in Latin America is examined and an attempt is made to evaluate the scientific and economic growth of that area in relation to the total foreign aid effort.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Szmant, H H -- New York, N.Y. -- Science. 1978 Mar 17;199(4334):1173-82.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/415363" target="_blank"〉PubMed〈/a〉
    Keywords: Chemistry ; Cost-Benefit Analysis ; Education ; History, 20th Century ; International Educational Exchange ; Latin America ; *Research Support as Topic ; *Science/history ; United States
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 1978-04-07
    Description: Glucose reacts nonenzymatically with the NH2-terminal amino acid of the beta chain of human hemoglobin by way of a ketoamine linkage, resulting in the formation of hemoglobin AIc. Other minor components appear to be adducts of glucose 6-phosphate and fructose 1,6-diphosphate. These hemoglobins are formed slowly and continuously throughout the 120-day life-span of the red cell. There is a two- to threefold increase in hemoglobin AIc in the red cells of patients with diabetes mellitus. By providing an integrated measurement of blood glucose, hemoglobin AIc is useful in assessing the degree of diabetic control. Furthermore, this hemoglobin is a useful model of nonenzymatic glycosylation of other proteins that may be involved in the long-term complications of the disease.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Bunn, H F -- Gabbay, K H -- Gallop, P M -- New York, N.Y. -- Science. 1978 Apr 7;200(4337):21-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/635569" target="_blank"〉PubMed〈/a〉
    Keywords: Blood Glucose/metabolism ; Chemical Phenomena ; Chemistry ; Diabetes Complications ; Diabetes Mellitus/*blood/diagnosis ; Diphosphoglyceric Acids/blood ; Glycosides/blood ; Glycosuria/etiology ; Hemoglobin A/*metabolism ; Hemoglobins/*analysis/*metabolism ; Humans ; Kinetics ; Oxygen/blood ; Structure-Activity Relationship
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 9 (1978) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 5
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A2 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 6
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A5 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 7
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A6 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 8
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A7 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 9
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Knowledge about stress corrosion cracking and corrosion fatigue until 1970; specific aggressive media to cause stress corrosion cracking: alkali solution, nitrates, ammonia salts - meaning of the constant strain rate technique and stress corrosion cracking in bicarbonate solutions - dependence of tensile stress, strain and strain rate upon time; significance of strain rate - investigations in bicarbonate, carbonate and hydroxide solutions - critical potential ranges - relation between strain rate and low cycle fatigue - theoretical differences between stress corrosion cracking and corrosion fatigue in spite of gradual transient in physical appearances.
    Notes: Stand des Wissens über Spannungsriß- und Schwingungsrißkorrosion bis um 1970; spezifische Medien für Spannungsrißkorrosion: Alkalilauge, Nitrate, Ammoniumsalze - Bedeutung der constant-strain-rate-Technik und Bikarbonat-Spannungsrißkorrosion - Zeitabhängigkeit von Zugspannung, Dehnung und Dehngeschwindigkeit; Bedeutung der Dehngeschwindigkeit - Untersuchungen in Bikarbonat-, Karbonat- und Hydroxidlösungen - kritische Potentialbereiche - Zusammenhang zwischen Dehngeschwindigkeit und langsamer Ermüdung - theoretischer Unterschied zwischen Spannungsrißkorrosion und Korrosionsermüdung trotz phänomenologisch gleitender Übergänge.
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  • 10
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 27-30 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigation of Steel Fiber Reinforced Aluminium under Torsional and Compressive LoadingA fiber-shaped composite material which, due to its fabrication process and internal structure may be called a double fiber composite, and whose strength behaviour is significantly influenced by boundary layers and porosity has been tested by means of two test methods: 1The possibility is demonstrated to determine by a non-destructive elastic torsional test the useful cross section for the utilization of the material, taking the quality-reducing factors into consideration.2Pressure tests have shown good agreement with Timoshenko and Gere's wave theory extended in this particular case. .
    Notes: Die Erprobung eines faserförmigen Verbundwerkstoffes, der durch Herstellungsverfahren und inneren Aufbau als Doppelfaserverbund zu bezeichnen ist und dessen Festigkeitsverhalten durch Grenzschichten und Porosität wesentlich beeinflußt wird, wurde mittels zweier Prüfverfahren durchgeführt: 1Es wird die Möglichkeit aufgezeigt, den nutzbaren Querschnitt für den Einsatz des Materials unter Berücksichtigung der qualitätsmindernden Faktoren im elastischen Torsionsversuch zerstörungsfrei zu ermitteln.2Durch Druckversuche wurde eine gute Übereinstimmung mit der hier erweiterten Wellentheorie von Timoshenko und Gere erzielt. .
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  • 11
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Mechanical and Technological Properties of Nickel Containing SuperferritesHigh chromium ferritic stainless steels with molybdenum and nickel additions, containing low amounts of interstitials, show remarkably good mechanical properties besides their excellent corrosion behaviour. Yield strengths of these materials can be more than the twofold, compared with that of austenitic stainless steels. In contrary to commercial ferritic stainless chromium steels, the Superferrites exhibit remarkable notch impact toughness also at temperatures below 0 °C. These properties as well as their permanent toughness after a welding process permit a good technological workability and, because of the high strength properties, the application of thinner dimensions in construction.
    Notes: Hochlegierte ferritische Chromstähle mit Molybdän- und Nickelzusätzen sowie niedrigen Kohlenstoff- und Stickstoffgehalten weisen neben ihrer hervorragenden Korrosionsbeständigkeit auffallend gute mechanisch-technologische Eigenschaften auf. Diese Werkstoffe können im Vergleich mit austenitischen chemisch beständigen Stählen mehr als doppelt so hohe 0,2%-Dehngrenzen erreichen. Im Gegensatz zu den herkömmlichen ferritischen Chromstählen besitzen sie auch bei Temperaturen unter 0 °C eine bemerkenswerte Kerbschlagzähigkeit. Diese Eigenschaften sowie das bleibende Verformungsvermögen nach einem Schweißvorgang lassen eine gute Verarbeitbarkeit der Stähle im Apparatebau zu, wobei wegen des Festigkeitsvorteils wesentlich dünnere Abmessungen benötigt werden.
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  • 12
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 19-27 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The growing interest in the use of graphite as a material for chemical equipment is occasioned by the highly corrosion resistant properties of this low-cost material.Economic and safety specifications require a thorough knowledge of the material's properties and performance and also of the effect of these factors on a particular unit. It is to be considered for instance that the material's compressive strength is 3 to 5 times higher than its tensile strength.Another important characteristic is its static strength: the smaller the stressed volume, the higher the breaking strength. This comparatively good performance is of advantage in cases of high voltage gradients as encountered as edge stresses at the openings of tube plates and nozzles. In such cases the breaking strength may reach twice the value of the rupturing strength.A third characteristic to be mentioned is the high dependence of strength on the parameters of production; the strength decreases, for technological reasons, with increasing size.The following design principles are based on the specific properties and performance of the material: units to be preferably subjected to compressive stressuse of the smallest possible stockmaterial of higher strength to be used in hightension zones (smaller semiproduct dimensions)No cemented joints in highly stressed zones .
    Notes: Graphit zeichnet seine “breite” Korrosionsbeständigkeit bei verhältnismäßig niederen Kosten aus. Er wird deshalb in zunehmendem Maße für hochkorrosionsfeste Apparate eingesetzt. Wirtschaftliche und sicherheitstechnische Forderungen machen eine genaue Kenntnis des Werkstoffverhaltens und dessen Auswirkungen auf ein Bauteil zur Voraussetzung. So ist z. B. die gegenüber der Zugfestigkeit um den Faktor 3 bis 5 höhere Druckfestigkeit zu berücksichtigen. Ein weiteres wichtiges Merkmal ist die statistische Natur der Festigkeit. Je geringer das beanspruchte Volumen ist, desto höher ist die Bruchfestigkeit. Das bedeutet gerade bei hohen Spannungsgradienten, wie sie als Lochrandspannungen an Rohrplatten oder Stutzen auftreten, ein vergleichsweise günstiges Verhalten. In derartigen Fällen kann die Bruchfestigkeit den doppelten Wert der Zug-Bruchfestigkeit erreichen. Als drittes hervorzuhebendes Merkmal ist die starke Abhängigkeit der Festigkeit von den Herstellungsparametern zu nennen; technologisch bedingt nimmt die Festigkeit mit zunehmenden Abmessungen ab.Aus dem Werkstoffverhalten leiten sich folgende Konstruktionsprinzipien ab: Bauteile bevorzugt auf Druck beanspruchen.Stets das kleinstmögliche Halbzeug verwenden.In Zonen hoher Spannung Material höherer Festigkeit einsetzen (kleinere Halbzeugabmessungen).Kittverbindungen nicht in hochbeanspruchte Zonen legen.
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  • 13
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 31-36 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 14
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 36-36 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 15
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 16
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A9 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 17
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 18
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A12 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 19
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    Materialwissenschaft und Werkstofftechnik 9 (1978) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 20
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: ESCA - Investigations of the Passive Films Formed on Austenitic Stainless Steels in Nitric AcidBy means of ESCA the composition and the thickness of passive films formed on austenitic stainless steels were investigated after the attack of nitric acid at various temperatures and acid concentrations.The outermost layers of the oxide film consist of SiO2, then a layer rich of Cr-oxid follows, containing also some Mo in the four- and six-valent state. Ni does not contribute to the oxide film. Cr is also enriched in the metal just below the oxide film.
    Notes: Mittels ESCA wurden Zusammensetzung und Dicke der Oxidschichten ermittelt, die bei der Beanspruchung verschiedener austenitischer Chrom-Nickel-(Molybdän)-Stähle in Salpetersäuren unterschiedlicher Konzentration und Temperatur gebildet werden.Die äußere Schicht besteht aus SiO2; darunter befindet sich eine chromreiche, molybdänhaltige Oxidschicht. Nickel ist am Aufbau der Oxidschichten nicht beteiligt.In der metallischen Matrix unterhalb der Oxidschicht wurde eine Chromanreicherung nachgewiesen.
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  • 21
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Testing of plastic pipes and fittings
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  • 22
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The Improvement of Fatigue Limit as a Result of Hardening and Macrostresses Due to a Surface TreatmentSurface treatments, that increase the hardness as well as induce surface residual macrostresses, are universaly able to improve the fatigue limit. It is shown, that depending on the shape of specimens both effects together are responsible for the raise of the fatigue strength, which is in contrast to former opinions. The increase of hardness increases the stress required for crack initiation and is thus decident for unnotched specimens, whereas in this case the influence of permanent residual stresses is relatively smaller. Notched specimens of sufficient stress concentration factor kt are determined by the crack propagation conditions, which can be controlled decisively by mean loads. The increase of hardness improves the resistance against crack initiation proportional to the 1/kt portion of the unnotched fatigue limit, but cracks remain nonpropagating as long as a certain minimum alternative stress, which can be raised by compressive residual stresses, is not exceeded. Depending upon concentration factor, mean compressive load and hardness the transition from crack initiation to crack propagation as the criterion for fatigue fracture can be estimated by several fatigue-strength-diagrams, which are evaluated for specimens of constant hardness but are valid for surface hardened specimens as well.
    Notes: Eine universelle Möglichkeit, die Dauerhaltbarkeit von Bauteilen zu verbessern, bieten Oberflächenbehandlungsverfahren, die sowohl die Werkstoffhärte erhöhen als auch Druckeigenspannungen 1. Art in der Randschicht erzeugen. Im Gegensatz zu der im älteren Schrifttum oft vertreten Ansicht, nach der entweder der eine oder der andere Einfluß für den Mechanismus der Wechselfestigkeitssteigerung verantwortlich sein soll, zeigt sich, daß in Abhängigkeit von der Bauteilgeometrie beide Faktoren zusammenwirken. Die Härtesteigerung beeinflußt vornehmlich die Anrißdauerfestigkeit und bestimmt damit das Verhalten glatter Teile; Druckeigenspannungen, sofern sie nicht abgebaut werden, leisten einen geringeren Beitrag. Bei gekerbten Proben ausreichend hoher Formzahl wird der Dauerbruch durch die Rißausbreitungsbedingungen festgelegt, die in entscheidender Weise von Mittelspannungen abhängen. Die Härtesteigerung erhöht zwar proportional zum 1/αk-fachen Teil der Wechselfestigkeit glatter Proben die Beständigkeit gegen die Bildung von Anrissen, diese bleiben aber stehen, sofern nicht eine durch Druckmittelspannungen heraufsetzbare Mindestwechselspannung überschritten wird. Der von Formzahl, Höhe der Druckeigenspannungen und Härte abhängige Übergang von Anrißbildung zu Rißfortschritt als Kriterium für die zum Bruch führende Wechselspannung kann in Dauerfestigkeitsschaubildern abgelesen werden, die für Werkstoffe homogener Festigkeit aufgestellt werden, die aber ebenso für oberflächenverfestigte Proben gelten.
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  • 23
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A17 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 24
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Influence of Microstructure on Mechanical Properties of (α + β)-Ti-AlloysThe amount of α- and β-phase in (α + β)-Titanium alloys for example in the alloy TiAl6 V4 may be altered to a large extend by annealing procedures. In the alloy TiAl6 V4 each temperature corresponds to a certain amount of each of these phases, the composition of which is also dependent on annealing temperature. Above about 970 °C the homogeneous β-phase appears. Additions of Iron, Oxygen, Nitrogen and Hydrogen have a great influence on the transition temperature and the distribution of the α- and β-phase. There is a great influence of the distribution of the phases on the mechanical properties. The β-phase and the α-solid solution can be quenched from high temperature and decomposed at a lower temperature, so that intermediate phases as ω from β and α2 from α may be precipitated. The α-solid solution is anisotropic so that texturized samples have different properties in various directions. Based on these fundamental aspects it is shown to what extend these microstructures may influence the mechanical properties especially the fatigue behaviour of (α + β)-Ti-alloys.
    Notes: Die Anteile des α- und β-Titanmischkristalls in (α + β)-Titanlegierungen können z. B. bei der Legierung TiAl6 V4 in großen Bereichen durch Wärmebehandlung variiert werden. Bei jeder Temperatur stellt sich z. B. bei TiAl6 V4 ein bestimmtes Verhältnis zwischen α und β ein, wobei sich die Legierungskonzentration in den einzelnen Phasenanteilen ändert, bis oberhalb etwa 970 °C die reine β-Phase vorliegt. Beimengungen wie Eisen, Sauerstoff, Stickstoff und Wasserstoff verändern die Umwandlungstemperatur und auch die Anteile der jeweiligen Phasen. Die mechanischen Eigenschaften werden durch das Gefüge entscheidend beeinflußt. Sowohl der β-Mischkristall wie auch der α-Mischkristall können von hoher Temperatur abgeschreckt und bei tiefen Temperaturen zum Zerfall gebracht werden, so daß dadurch weitere Zwischenphasen, wie die ω-Phase im β-Mischkristall und die α2-Phase im α-Mischkristall ausgeschieden werden. Der α-Mischkristall weist eine starke Anisotropie auf, so daß mit Textur behaftete Proben eine Richtungsabhängigkeit der mechanischen Eigenschaften aufweisen. Ausgehend von diesen Grundlagen wird gezeigt, wie sich diese Gefügezustände auf die mechanischen Eigenschaften insbesondere bei schwingender Beanspruchung auswirken.
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  • 25
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 73-76 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Ähnlich wie zum Taschentext 55 (Eisenwerkstoffe), der im Jahr 1977 im Verlag dieser Zeitschrift erschienen ist, wird mit dem Abdruck einiger Abschnitte aus dem Taschentext 56 (Metallische Nichteisenwerkstoffe) auf die Bedeutung dieser Werkstoffgruppe hingewiesen. Die Taschentexte der Reihe „Werkstoffkunde“ sollen den Studierenden der Ingenieurtechnik und ebenso den Ingenieur der Praxis mit Wesen und Eigenschaften technischer Werkstoffe bekannt machen. Dabei werden weniger die metallkundlichen als vielmehr die anwendungstechnischen Fragen in den Vordergrund gestellt.
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  • 26
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    Materialwissenschaft und Werkstofftechnik 9 (1978) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A20 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A24 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 86-92 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: On the Interaction of CracksStress intensity factors for multiple cracks in a plate under tension are reviewed. In addition to the known results for symmetrically arranged cracks the interaction effects due to rotation of one of the cracks relative to the load direction are calculated and in some cases examined experimentally. The results are discussed with reference to the safety assessment of structural components.
    Notes: Spannungsfaktoren von Mehrfachrissen in einer Scheibe unter Zug werden gesichtet. Erweiternd zu den bekannten Ergebnissen für symmetrische Rißanordnungen werden die Wechselwirkungseffekte, die bei der Drehung eines der Risse gegen die angelegte Spannung auftreten, numerisch und zum Teil experimentell untersucht. Die Ergebnisse werden im Hinblick auf Sicherheitsbeurteilung von Bauteilen diskutiert.
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    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
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    Description / Table of Contents: The State of the Art in the Fatigue Live Evaluation of ComponentsFor fatigue life estimations of components many compromises must be entered in the utilization of available fatigue design data. The parameters of the chosen design data which do not fit the component to be evaluated are in most cases taken into consideration by very global factors. These factors and the inaccuracies of Miner's Rule provide only a rough estimate of the fatigue life of a component. When the component is allready available, these uncertainties can be reduced by performing a fatigue test with service like load-time histories and a relative Miner's Calculation. For the same reason the total knowledge about the service fatigue behaviour of similar components should be taken into account in the life estimation.
    Notes: Bei praktisch allen Abschätzungen der Schwingfestigkeit eines Bauteils müssen Kompromisse bei der Auswahl der Bemessungs-Diagramme eingegangen werden. Die für das Bauteil nicht zutreffenden Parameter der Bemessungsunterlagen müssen recht pauschal durch Abschlagfaktoren berücksichtigt werden. Zusammen mit den Ungenauigkeiten der Miner-Regel können sich daraus recht erhebliche Fehleinschätzungen der Betriebslebensdauer eines Bauteiles ergeben. Wenn das Bauteil zur Verfügung steht, können diese Unsicherheiten durch einen Versuch mit betriebsähnlichem Kollektiv, verbunden mit einer Relativ-Miner Rechnung zum größten Teil vermieden werden. Aus dem gleichen Grunde sollten alle Kenntnisse über das Schwingfestigkeitsverhalten des Bauteils im Betrieb bei der Berechnung der Lebensdauer berücksichtigt werden.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 96-100 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: On the relationship between the properties and the microstructure of multiphase materials. Part III: Microstructure and Youngs Modulus of Elasticity
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 92-95 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Ultrasonic Attenuation Measurements of a Maraging SteelThe objective of this study was to investigate the influence of nm-precipitation of a precipitation hardening steel on the ultrasonic attenuation. The applied steel X 2 NiCoMo 1885 was solution annealed and subsequently precipitation hardened at 480 °C at different holding times. A clear correlation between ultrasonic attenuation coefficient for 4 Mc and hardness values measured in the range of the hardness increase can be seen. The particle density of the microstructure given is considered as the common cause of the influence of both parameters. The increase in the particle density leads to a decrease in the ultrasonic attenuation coefficient. The reneward increase in the US-attenuation coefficient may additionally be influenced by the beginning austenit reformation and has not been investigated in more details here.
    Notes: Im Rahmen der hier durchgeführten Untersuchungen wurde der Einfluß von Ausscheidungen im nm-Bereich auf die Ultraschallschwächung an einem ausscheidungshärtenden Stahl untersucht. Der verwendete Stahl X 2 NiCoMo 1885 wurde lösungsgeglüht und anschließend bei 480 °C bei verschiedenen Zeiten ausgehärtet. Die gemessenen Härtewerte im Bereich des Härteanstiegs und der Ultraschall-Schwächungskoeffizient für 4 MHz zeigen eine eindeutige Korrelation. Als gemeinsame Ursache für die Beeinflussung beider Parameter wird die im Gefüge vorliegende Teilchendichte angesehen. Die Zunahme der Teilchendichte führt zu einer Abnahme des US-Schwächungskoeffizienten. Der erneute Anstieg des US-Schwächungskoeffizienten kann zusätzlich durch die einsetzende Austenitrückbildung beeinflußt werden und wurde daher hier nicht näher untersucht.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 101-109 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A25 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 109-112 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A28 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A32 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 113-120 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations on the Effect of Microstructure on Crack Propagation during Unidirectional Loading of TiAl6V4Fracture mechanics tests were performed with the titanium alloy Ti-6 Al-4 V between -196°C and room temperatur. Crack propagation behaviour was characterized by the K-Δa-curve, KIo at the onset of stable crack extension and by KQ, determined with the 5% secant method. KQ is strongly dependent on the microstructure, whereas there is a less effect on KIo. For a material with a microstructure with a low fracture toughness the value KQ can be increased considerably by vaccum annealing at 750°C. There is only a small decrease of the yield strength.
    Notes: An der Titanlegierung TiAl6V4 wurden Bruchmechanikversuche zwischen -196°C und Raumtemperatur durchgeführt. Die Charakterisierung des Rißausbreitungsverhaltens erfolgte durch die K-Δa-Kurve bzw. durch KIobeim Einsetzen der stabilen Rißverlängerung und KQ, bestimmt mit dem 5% Sekantenverfahren. Die Gefügeausbildung hat einen großen Einfluß auf KQ, der Einfluß auf KIo ist geringer. Bei einem Material mit Gefüge mit niedriger Rißzähigkeit kann KQ durch eine Glühbehandlung bei 750°C im Vakuum beträchtlich erhöht werden. Die Streckgrenze sinkt dabei nur unwesentlich ab.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 176-179 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Shift vectors for the comparison of Cv-T-curvesIt is shown in this paper that a shift in the Cv-T-curves caused by mechanical or thermal treatment, or by irradiation with particles of high energy can be better described by a shift vector given by the inversion points of a functionally determined curve than with the currently used empirical criteria. Moreover, the shift of a whole curve can be described by a vector whose components are the shifts of all parameters used for the calculation of the curve.The resulting vector of a Cv-T-curve may, for instance, be connected functionally with the neutron fluence. This makes it possible to compute shift vectors.
    Notes: In dieser Arbeit wird gezeigt, daß die durch mechanische oder thermische Einwirkung oder durch Bestrahlung mit hochenergetischen Teilchen hervorgerufene Verschiebung von AvT-Kurven durch die Verschiebung des funktionell bestimmten Wendepunktes mit einem Verschiebungsvektor besser beschrieben werden kann als mit den bisher üblichen empirischen Kriterien. Darüber hinaus kann die Verschiebung der gesamten Kurve durch einen Vektor beschrieben werden, dessen Komponenten die Verschiebungen aller zur Berechnung der Kurven verwendeten Parameter sind.Der Ergebnisvektor einer Av-T-Kurve kann z. B. mit der Neutronenfluenz funktionell verknüpft werden. Dies ermöglicht die Berechnung von Verschiebungsvektoren.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 164-171 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Progresses in the application of plastic compound materialsPlastics possess a number of various properties one cannot find in another material in this combination. Beyond that the desired properties can be reached by compounding several different materials. The best known example is the glass reinforced plastic. The arguments for the application of compound materials are very different: increase of strength and stiffness, cheaper injection moulded parts due to shorter cycle times, thinner wall-thicknesses and therefore less raw material consumption, lower distortion and thermal elongation for technical parts and excellent thermal insulation of the foams.Research on the topic of the bonding between the plastic and the carbon, glass and organic fibres led the way to an ever spreading field of the application of reinforced plastics.
    Notes: Kunststoffe weisen eine Reihe von Eigenschaften auf, die sich in diesen Kombinationen bei keinem anderen Werkstoff finden. Darüber hinaus können durch chemische oder mechanische Verbindungsvorgänge die gewünschten Eigenschaften mehrerer Materialien in einem Werkstoff vereinigt werden. Das bekannteste Beispiel für die mechanischen Verbundwerkstoffe auf Kunststoffbasis ist der glasfaserverstärkte Kunststoff. Die wesentlichen Argumente für den Einsatz von Verbundwerkstoffen sind ganz unterschiedlicher Art: Festigkeits- und Steifigkeitssteigerung, Fertigungskostensenkung durch kürzere Zykluszeiten für das Spritzgußverfahren, größere Formtreue bei Spritzgußteilen aus teilkristallinen Thermoplasten, geringere Wärmedehnung für Maschinenteile, bessere Wärmeisolation z. B. bei Schäumen, geringerer Verbrauch an Kunststoffen durch kleinere Bauteilwanddicken.Durch intensive Forschung und gute Fortschritte auf den Gebieten Haftung zwischen Faser und Kunststoff, Verarbeitbarkeit hochmoduliger Kohle- und Chemiefasern, Festigkeit, Temperatur- und Chemikalienbeständigkeit der Kunststoffe, Verarbeitungstechnologie für Spritzguß, Prepeg- und Naßverarbeitung hat sich der Anwendungsbereich der faserverstärkten Kunststoffe erheblich erweitert.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 180-181 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 181-188 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Seit 1949 hat die industrielle Herstellung von Titan ausgehend von den USA in Europa, Japan und den UdSSR zunehmende Bedeutung gewonnen. Heute zählt der Werkstoff mit einer Erzeugung an Schmelzblöcken von rd. 30 000 jato in der westlichen Welt zu den Konstruktionswerkstoffen, die in weiten Bereichen der Technik angewandt werden.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A54 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 263-263 
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A65 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A68 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Description / Table of Contents: Thermally Induced Structural Changes in Nickel Composite Coatings
    Notes: Dispersionsschichten werden durch Mitabscheidung von im Elektrolyten suspendierten Feststoffteilchen in eine galvanisch oder chemisch erzeugte Metallmatrix hergestellt. Derartige Teilchenverbundwerkstoffe werden in verschiedenen technischen Anwendungsfällen eingesetzt und haben sich bewährt. Die wohl am häufigsten verwendete Schicht besteht aus Ni-SiC. Beim Einsatz dieser Schicht im Bereich höherer Temperaturen ist mit Veränderungen der Schichteigenschaften zu rechnen. Bei der Auswahl der Ni-SiC-Schicht für bestimmte Anwendungen müssen derartige thermisch bedingte Eigenschaftsänderungen berücksichtigt werden.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 316-321 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Dynamic strength variationThe Weibull probability function or the arcsin √P distribution suffices for description purposes provided that considerations are confined to failure or survival probabilities between 20 and 80%. Beyond these limits more sophisticated analysis of the test results - as too in the case of the design engineer when estimating the statistically induced component of the safety margin - must make use of more realistic distribution functions.
    Notes: Zu ihrer Beschreibung genügt die Weibullsche Wahrscheinlichkeitsfunktion oder auch die arcsin P-Verteilung nur, solange man sich auf Ausfall- oder Überlebenswahrscheinlichkeiten zwischen 20 und 80% beschränkt. Jenseits dieser Grenzen muß sich die anspruchsvollere Analyse der Versuchsergebnisse - wie auch der Konstrukteur bei der Abschätzung der statistisch bedingten Komponente der Sicherheitsspanne - wirklichkeitsnäherer Verteilungsfunktionen bedienen.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 310-315 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Carbon Fibre Reinforced Al2O3 and MulliteThe hydrolysis process from metalalkoxides has been investigated to prepare carbon fibre reinforced Al2O3 and mullite composites. Carbon fibres (SIGRAFIL HF with 10,000 monofilaments) were im pregnated with metalalkoxides (Al-tri-sec-butylate to form Al(OH)3, mixtures of tetramethoxy-silan and Al-tri-sec-butylate to form mullite), hydrated in air and hot-pressed in a graphite mold at about 1700 °C, 10 min. Beside this also the preparation of composites with chopped fibres is described. The mechanical properties were measured in a three point bending test. Composite material with more than 10 vol% fibres show plastic deformation with matrix cracking during testing. For Al2O3 an additional SiC-interlayer (0.5-1 μm SiC by a CVD-process from CH3SiCl3 and H2 at 1280 °C) is necessary to obtain a bonding between fibre and matrix. Only in this case with fibre content higher 10% it is possible to increase the fexural strength of Al2O3. The strength values lie on a line with 60% of the fibre strength. The rule of mixture cannot be applied for Al2O3 as matrix. Low fibre contents decrease the flexural strength. It appeares that in this case the Al2O3 matrix is damaged before testing. But with mullite as matrix the measured values of flexural strength lie on a line which is 65% of the rule of mixture. This is caused by a relative good bonding between fibre and matrix and is independend of an additional SiC-interlayer. The Young-modulus of Al2O3 is drastically decreased with 10% carbon fibre content (for mullite matrix: 28 vol%). It was possible to calculate the beginning of the formation of cracks in the Al2O3 matrix caused by the mismatch of the components. This value does agree with the measured decrease of Young-modulus. The toughness of both materials measured by the critical intensity factor KICV (for a composite material) with notched speciments (0.1 mm notch width) is increased with fibre content. (These KICV-values are a function of notch length and width in a range of the probable error and therefore the uncorrected values are considered). For Al2O3 matrix the KICV-values increase only if SiC-scoated fibres are used. For mullite as a matrix KICV increases with fibre content for both of the SiC coated and uncoated fibre composites. With higher fibre volume than 50% the values decrease because the interspace between the fibres is not filled with matrix. The increased KICV for these composites compared to that of the matrix alone can be explaned by energy absorption at the fibre-matrix interface. In the case of mullite matrix this mechanical behaviour is caused by a good bonding between the components. Therefore the fracture energy of these mullite composites is drastically increased with fibre content. This means that a strong mullite material with good toughness is formed. These properties are a function of the preparation method. The hydrolysis process formes a very fine grain starting material, which formes a relative dense mullite by reaction sintering between the carbon fibre monofilaments. During this reaction also a good bonding between the fibres and the matrix is formed.
    Notes: Die Hydrolyse von Metallalkoxyden (Al-tri-sec-butylat und Methylsilanester) läßt sich zur Herstellung von kohlenstoffaserverstärkten Al2O3- und Mullit-Verbundwerkstoffen heranziehen. Hierbei zeigte es sich, daß für Al2O3-Matrix eine zusätzliche SiC-Zwischenschicht die Haftung zwischen Faser und Matrix verbessert. Die hergestellten Verbundwerkstoffe zeigen deutlich verbesserte Werte für die Bruchzähigkeit.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 332-336 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Material - Design - Production
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 460-460 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Journal of High Resolution Chromatography 1 (1978), S. 71-72 
    ISSN: 0935-6304
    Keywords: Gas Chromatography ; Capillary, glass ; Separation of the four 10,12-Hexadecadiene-1-ol isomers ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Complete gas-liquid chromatographic separation of the four 10, 12-hexadecadiene-l-ol isomers using a FFAPcoated glass capillary column is described.These measurements are of importance for the analysis of pheromones from biological sources and for the control of material from stereospecific syntheses.
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    Journal of High Resolution Chromatography 1 (1978), S. 69-71 
    ISSN: 0935-6304
    Keywords: Gas Chromatography Mass Spectrometry ; Capillary, glass/Varian, MAT 311A ; Separation and detection (El, Cl) of some roast coffee constituents ; Three new phenolic compounds found ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A roast coffee infusion (nicaragua arabica) was acidified (pH 1,5) with hydrochloric acid and extracted with diethyl ether in a perforator. After evaporation of the solvent the residue was treated with N-methyl-N-trimethylsilyl trifluoroacetamide and analyzed by glass capillary GC/MS. The main components were identified by their electron impact and isobutane chemical ionization mass spectra. 1,2,4-trihydroxy benzene, 1-ethyl-3, 4-dihydroxy benzene and 2,3-dihydroxy toluene were identified as new constituents of roast coffee with possible emetic properties.
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    Journal of High Resolution Chromatography 1 (1978), S. 73-73 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 74-79 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 80-80 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 80-80 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 109-110 
    ISSN: 0935-6304
    Keywords: Gas Chromatography ; Capillary, glass ; Computer reconstruction of chromatograms without distortion of peak shape ; Vertical/horizontal scaling to almost any paper size ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper describes two programs that are used to plot digital area slice data from glass capillary gas chromatograms. The programs are written in H/P LAB BASIC II, and can be executed on Hewlett-Packard 3354A Laboratory Data Systems using digital plotting devices. The programs are designed to plot high resolution chromatograms, allow horizontal and vertical scaling, and the plots can be numbered and labelled.
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    Journal of High Resolution Chromatography 1 (1978), S. 121-122 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 156-160 
    ISSN: 0935-6304
    Keywords: Thin Layer Chromatography, TLC and HPTLC ; Quantitative evaluation ; Errors, systematic and statistical, error propagation by graphical methods ; Peak height gives better results (slow scanning) ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The paper discusses errors and error propagation in respect of graphic methods in quantitative in situ measurements in TLC. An error of 0.3% is possible by measuring only peak height if optimal conditions are chosen. This is in good agreement with analysis done practically which gives errors in the order of 0.3-0.6%. If the peak area is evaluated using the approximation peak height × half width, the error is in the order of 0.6%, but in real experiments only 1.5% had been found. Systematic errors in determining peak heights are introduced by the time constant of the amplifiers and the recorder.
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    Journal of High Resolution Chromatography 1 (1978), S. 275-276 
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    Keywords: Gas Chromatography ; Capillary ; Splitless injection ; Theoretical basis for reconcetration by solvent effects ; Guidelines for an effective solvent effect, in literature citation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal of High Resolution Chromatography 1 (1978), S. 277-278 
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    Keywords: Gas Chromatography ; Capillary, glass ; Static coating technique for columns up to 50 m ; Degassing solvents, closing procedure ; Extraordinary requirements for water bath ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal of High Resolution Chromatography 1 (1978), S. 279-280 
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    Keywords: Gas Chromatography ; Capillary, glass ; Static coating technique ; A standard procedure, 7 critical points ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal of High Resolution Chromatography 1 (1978), S. 281-281 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 307-308 
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    Keywords: Gas Chromatography ; capillary, glass, diagnosis of damage ; repair by partial washing ; partial reimpregnation/deactivation ; repair test ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal of High Resolution Chromatography 1 (1978), S. 169-170 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 164-168 
    ISSN: 0935-6304
    Keywords: Thin Layer Chromatography, HPTLC ; Fastest possible analytical mode: Anticircular separation ; First principal analytical details ; Most economical TLC/HPTLC technique, quantitative comparison with linear and circular mode ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The principal analytical details for the third of three possible modes in high performance thin-layer chromatography are given, namely the anticircular mode. Separation is achieved by allowing the mobile phase to enter the plate layer on a precise outer circle line, from where it flows towards the centre with nearly constant speed. This technique is theoretically and practically the fastest of all three possible in HPTLC. It permits maximum sample capacity with a minimum of time, layer and mobile phase consumption. It is therefore the most economical HPTLC technique.A new carrier-free mobile phase transfer principle is used. The conditions for qualitative and quantitative analysis are good: repeatability, reproducibility and accuracy of routine TLC analyses are superior to those achieved by the classical trough technique. The specially narrow spot-path in anticircular HPTLC facilitates automated quantitation. Compared with the linear and circular modes, the anticircular mode shows better separation and significantly increased sensitivity at higher Rf-values. The drawback, however, is that the separation power (expressed by the separation number) is lower compared with the other two modes.
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    Journal of High Resolution Chromatography 1 (1978), S. 173-174 
    ISSN: 0935-6304
    Keywords: Instrumentation in GC ; Pressure regulators in capillary GC ; Diffusion free, optimal with 0.03 mm thick steel foil ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal of High Resolution Chromatography 1 (1978), S. 209-210 
    ISSN: 0935-6304
    Keywords: Gas Chromatography ; Capillary, glass, surface modified, preparation ; Pesticides, separation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Filamentary crystal growth on the inner surface of a glass analytical capillary column using a modified ammonium hydrogen difiuoride procedure, produced highly efficient wall coated open tubular columns.Baseline separation of the acetate derivatives of 2,3,4,6- and 2,3,5,6-tetrachlorophenol was achieved and was instrumental in determining pentachlorophenol loadings along a watershed. The application of capillary columns, related to the analyses of organochlorine pesticide residues is also demonstrated. Parent and degradation products of twenty-five commonly monitored residues were effectively resolved on a 20 MOV-101 column.
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    Journal of High Resolution Chromatography 1 (1978), S. 214-215 
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    Keywords: Thin layer chromatography TLC ; Ammoniacal silver ion plates for polyunsaturated fatty acid methyl esters separation ; Rf-data versus number of double bonds ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal of High Resolution Chromatography 1 (1978), S. 226-226 
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    Keywords: Liquid chromatography, medium or high-pressure ; Coupling, general purpose ; 1/8" brass union, adapted by drilling ; Connection of different kinds of tubing (1/16" and 1/8") ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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    Journal of High Resolution Chromatography 1 (1978), S. 229-229 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 229-230 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978) 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 236-237 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 237-237 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 235-235 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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    Journal of High Resolution Chromatography 1 (1978), S. 239-244 
    ISSN: 0935-6304
    Keywords: Liquid Chromatography HPLC ; Antibiotics analysis ; Ion-exchange chrom. separation of acyltetramic acids (streptolydigin et al) on tetraethylaminoethyl cellulose ; Method of choice for crude and purified fermentation samples ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two new acyltetramic acids related to streptolydigin have been isolated from fermentations of Streptomyces lydicus. The principal members of this complex were resolved by TLC on silica gel. However, the methods of detection, permanganate spray or bioautography, were not suitable for both crude fermentation broths and purified extracts. Gas chromatography is unsuitable for the detection of either underivatized or silylated streptolydigins. High performance liquid chromatography (HPLC) particularly on triethylaminoethyl cellulose is rapid and sensitive and is the method of choice for the analysis of both crude and purified samples. Using high performance liquid chromatography, two components were detected in the complex, which are not observed using any of the other chromatographic procedures.
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    Journal of High Resolution Chromatography 1 (1978), S. 245-249 
    ISSN: 0935-6304
    Keywords: Thin Layer Chromatography, TLC ; Equations for gradient elution technique ; TLC as pilot technique for gradient HPLC ; Possibilities to determine optimal gradient programmes ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Equations describing gradient elution in TLC, with a mobile phase of a constant composition in each step, have been derived. These equations are useful for calculating retention volumes from isocratic TLC data. Equations originally derived for gradient HPLC were adapted for TLC. The validity of the equations has been experimentally verified. The satisfactory agreement between experiment and theory for binary mobile phase composed of methyl ethyl ketone and n-heptane suggests that TLC can be used as a pilot technique for gradient HPLC.
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    Journal of High Resolution Chromatography 1 (1978), S. 253-256 
    ISSN: 0935-6304
    Keywords: Gas Chromatography ; Thermodynamic data determination ; Diffusivity and activation energy, measured and calculated for selected polypropylene solvent systems ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A thorough survey of the past and current available literature shows that the diffusion of the solvents toluene, ethylbenzene, ortho-, meta-, and para-xylenes in polypropylene has not been studied so far, although such studies find practical applications in various industrial problems. Diffusitives and the activation energies of the above mentioned solvents in polypropylene were determined in the temperature range of 45-120°C by gas chromatography. The values obtained in this communication compare fairly with those determined by conventional techniques for analogous systems, confirming the reliability of the gas chromatography as a powerful tool for diffusion measurement and the authenticity of the data presented herein.
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    Journal of High Resolution Chromatography 1 (1978), S. 250-252 
    ISSN: 0935-6304
    Keywords: Thin Layer Chromatography, TLC, HPTLC ; Quantitative evaluation ; Errors, systematic and statistical ; Error propagation for routine analysis with internal or external standards ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The error propagation is given for routine analysis by in situ evaluation in TLC using the methods with internal or external standard. The internal standard method will need four different measurements of peak height or area, while the external standard method uses only two measurements. Therefore in the latter case the error of the spotting volume will cause errors in the determined concentration. By error propagation it can be shown, that the internal standard method gives better results, if the error in measuring peak height or area is less than the error of the spotting volume.
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    Journal of High Resolution Chromatography 1 (1978), S. 257-262 
    ISSN: 0935-6304
    Keywords: Gas Chromatography ; Theory in qualitative analysis ; Retention index in isothermal and temperature programmed analysis (part 1) ; Simple dead volume calculations with three known compounds ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A definition for an absolute retention index is given. This index is independent of whether the process is isothermal or temperature programmed. The relation between this index and Kovats's index is discussed. General equations are derived for the retention times of homologous series, from which the position of the air peak or missing members can be determined. Methods used in the literature for air peak determination are improved and extended to other cases of interest. The retention index in temperature programmed chromatography is reexamined in the light of recent publications on temperature programming.
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    Journal of High Resolution Chromatography 1 (1978), S. 273-275 
    ISSN: 0935-6304
    Keywords: Liquid Chromatography ; Size exclusion columns ; Comparison of rigid (silica) and semirigid (microstyragel) packings by variation of flow, injection volume, concentration ; Elution volumes, plate numbers, calibration curves ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Systematic studies on operation variables affecting GPC separations using the semirigid Microstyragel (Waters Associates) and the rigid silica packings (DuPont) of about equivalent porosity are reported. The dependence of (a) flow rate, (b) injection volume, and (c) concentration on elution volume and theoretical plates are examined.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A40 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 140-147 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: On the relationship between the properties and the microstructure of multiphase materials. Part IV: Microstructure and thermal expansion coefficient. The properties of multiphase materials depend on the properties as well as on the geometry and geometrical arrangement (microstructure) of their phases. In many cases, where the material exists under extreme conditions (e. g. high temperatures, radioactive irradiation) not admitting direct property measurements or making them difficult and less accurate two dimensional pictures (micrographs) are available as the only reliable source of information.A stereologic image analysis then provides the tool to characterize the microstructure of multiphase materials quantitatively from their micrographs. Knowing equations describing the dependence of the properties on the microstructure characterized by appropriate parameters direct property measurements would become substitutable by stereologic analyses of the microstructure. Due to the fact, that this holds not only under extreme conditions the stereological microstructure analysis could also be used in conventional quality control to obtain properties without measuring them directly. Furthermore quantitative relationships between properties and microstructural parameters provide a better insight into the property-microstructuredependence thus enabling theoretically the pre-calculation of property improvements by optimalisation of the microstructure (“taylormade- materials”).This paper - subdivided in four articles - considers the derivation and the experimental proof of quantitative relationships between the microstructure and the conductivity, elastic modulus and thermal expansion coefficient of two phase matrix materials.In the present fourth part of this paper the derivation of the equations is considered which describe the dependence of the linear thermal expansion coefficient on the microstructure of two phase matrix materials quantitatively, the phases of which show linear elastic and isotropic behaviour. Calculated and measured thermal expansion coefficients of two phase materials from about 15 binary systems are compared agreeing sufficiently well. The general equation describing mathematically the relationship between the microstructure and the linear thermal expansion coefficient of two phase materials confirms theoretically, that closed pores do not affect the thermal expansion coefficient of porous materials. - At the end of the present article an engineering statement is made summarizing and judging the results obtained in the alltogether four parts of this publication.
    Notes: Die Eigenschaften mehrphasiger Werkstoffe hängen von den Eigenschaften ihrer Phasen und deren Geometric und geometrischer Anordnung (Gefügestruktur) ab. Mikroskopische Gefügebilder mehrphasiger Werkstoffe sind vielfach auch dann verfügbar, wenn der Werkstoff extremen Zustandsbedingungen ausgesetzt war (z. B. hohe Temperaturen, radioaktive Strahlung), unter denen direkte Eigenschaftsmessungen unmöglich oder schwierig und daher aufwendig und/oder ungenau sind. Durch stereologische Gefügeanalyse kann aus solchen Gefügebildern die Gefügestruktur ermittelt werden. Die Kenntnis des quantitativen Zusammenhangs zwischen Gefügestruktur und Eigenschaften würde dann die direkte Messung vin Eigenschaftskenngrößen ersetzbar machen durch eine stereologische Gefügeanalyse. Da dies nicht nur für extreme Zustandsbedingungen gilt, würde die stereologische Gefügeanalyse in der konventionellen Qualitätskontrolle - ebenfalls ohne direkte Eigenschaftsmessung - Aussagen über Eigenschaftskenngrößen erlauben. Außerdem vertiefen solche Gefüge-Eigenschafts-Beziehungen das physikalische Verständnis für den Zusammenhang zwischen Eigenschaften und Gefügestruktur von Werkstoffen und ermöglichen damit die Vorausberechnung von Eigenschaftsverbesserungen durch Gefügeoptimierung. Diese Arbeit behandelt in 4 Teilen die Ableitung und experimentelle Prüfung quantitativer Beziehungen zwischen der Gefügestruktur und der Leifähigkeit, dem Elastizitätsmodul sowie dem thermischen Ausdehnungskoeffizienten zweiphasiger Werkstoffe.Im vorliegenden 4. Teil dieser Abhandlung wird die Ableitung der Gleichungen beschrieben, die den quantitativen Zusammenhang zwischen dem linearen thermischen Ausdehnungskoeffizienten und der Gefügestruktur zweiphasiger Werkstoffe mit Einlagerungsgefüge und linearelastischen, isotropen Werkstoffphasen erfassen. Berechnete und gemessene Ausdehnugskoeffizienten von zweiphasigen Werkstoffen aus:etwa 15 binären Systemen werden verglichen und zeigen befriedigende Übereinstimmung. Die allgemeine Gleichung zum Zusammenhang zwischen dem linearen, thermischen Ausdehnungskoeffizienten und der Gefügestruktur zweiphasiger Matrix-Werkstoffe liefert das experimentell bestätigte Ergebnis, daß geschlossene Poren den Ausdehnungskoeffizienten poröser Werkstoffe nicht beeinflussen. Der vorliegende letzte Teil der Abhandlung schließt ab mit einer ingenieurmäßigen Einschätzung der in allen vier Abschnitten gewonnenen Ergebnisse.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 172-176 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Wear testing and wear behaviour of cemented carbidesWear resistance is not a mater constant but a quantity of a system. For the judgement of a case of wear or for the choice of the suitable grade of cemented carbide it is necessary to investigate exactly the limiting conditions and the appearance of wear.The wear test can only be considered with exactly defined limiting conditions and only be compared with application of similar limiting conditions.
    Notes: Die Verschleißfestigkeit ist keine Materialeigenschaft, sondern eine Systemgröße. Zur Beurteilung eines Verschleißfalles bzw. zur richtigen Auswahl des geeigneten Hartmetalles müssen zum einen die Randbedingungen; d. h. die Einflußgrössen, zum anderen die sich hieraus ergebenden Verschleißarten und Erscheinungsformen genauestens untersucht werden.Ein Laborverschleißversuch kann nur im Zusammenhang mit genau definierten Randbedingungen gesehen werden und kann nur mit Anwendungsfällen verglichen werden, die gleiche oder sehr ähnliche Randbedingungen besitzen.
    Additional Material: 20 Ill.
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A41 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 218-223 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Material - Design - Production
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    Keywords: Chemistry ; Polymer and Materials Science
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. 263-263 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 9 (1978), S. A60 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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