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  • Articles  (46)
  • Chemical Engineering  (46)
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  • 1960-1964  (46)
  • 1961  (46)
  • Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics  (46)
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  • Articles  (46)
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  • 1960-1964  (46)
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  • 1
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: If temperature variations of forces in both directions are observed simultaneously at constant simple dimensions, internal energy and entropy changes on elongation in those directions may be calculated at constant volume and in the more common experimental condition of constant pressure. Thermodynamic derivatives at constant volume are important for fundamental molecular interpretation being related to configuration change. Constant pressure quantities were therefore changed into constant volume ones by the use of an evaluated correction term, involving average Young Moduli and thermal expansion coefficient.
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  • 2
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 180-180 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 3
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    Polymer Engineering and Science 1 (1961), S. 191-198 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Interfacial reactions between organosilane-treated fiberglass and styrene, and bond conditions in these and in polymerized ethylene oxide and epichlorhydrin-E-glass systems were investigated. The vinyl functionality of some alkenylsilanes showed little effect on the polymerization of styrene on E-glass. The polymerization of this aromatic monomer on vinyltrichlorosilane-reacted fiberglass did not result in interfacial bond formation. Sorption of water on organosilane-coated glass at different temperatures suggested that permeation of the adsorbate into the bulk of the substrate was determined by diffusive transfer of water molecules.
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  • 4
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    Polymer Engineering and Science 1 (1961), S. 214-223 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A solution of substituted alkyl alkoxy silanes was applied to E-glass filament strands before forming glass-resin composite hoops, which were tested to relate changes in hoop physical properties to the nature of the coupling agent-size application. Continuously heat cleaning E-glass in oxygen-enriched air gives a strand that, when properly coated with size and laminated, makes a hoop with superior strength and modulus properties.
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  • 5
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    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 6
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    Polymer Engineering and Science 1 (1961), S. 2-2 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 7
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    Polymer Engineering and Science 1 (1961), S. 14-20 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A description is given of the procedure and equipment used for the purpose of studying the effect of hydrostatic pressure upon the capillary flow properties of polymer melts. Flow properties are reported for a low density polyethylene over a wide range of temperatures, die sizes, different pressures and hydrostatic pressures.
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  • 8
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    Polymer Engineering and Science 1 (1961), S. 21-25 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The degradation of plastics by ultraviolet energy and the use of protective ultraviolet absorbers to improve stability necessitate studies along several lines. These include (a) the measurement of the ultraviolet spectral energy distribution of sunlight and of the indoor accelerated test sources, (b) the measurement of the extent of degradation as a function of the wavelength of the incident radiation, (c) an estimate of the absorbing effectiveness of the added protective agents, and (d) the stability of the protective ultraviolet absorbers themselves.
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  • 9
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    Polymer Engineering and Science 1 (1961), S. 31-39 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study was designed to show the nature of weathering of an elastomer poly(ester-urethane), and to indicate methods of overcoming the deficiency. Unprotected polymer, when exposed to UV radiation in a Weatherometer, showed deterioration which is characterized by loss of tensile strength, some increase in modulus, and a decreased extensibility of surface skin.
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  • 10
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    Polymer Engineering and Science 1 (1961), S. 26-30 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effectiveness of ultraviolet stabilizers of various types of polyolefin, cellulose ester, and poly (vinyl chloride) plastics was investigated. Most of these stabilizers were of the ultraviolet-absorbing type but two were of the nonabsorbing type. Exposures were made both outdoors and indoors in a Twin-Arc Weatherometer. The latter was modified by the addition of ten 20-watt fluorescent sun lamps to remedy the short-ultraviolet deficiency of the enclosed carbon arcs.
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  • 11
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    Polymer Engineering and Science 1 (1961), S. 40-46 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The non-Newtonian flow behavior of polyethylene has been investigated with respect to the effects of molecular weight and molecular weight distribution. Effects of die geometry on melt fracture as well as preliminary extrudate orientation studies are discussed.
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  • 12
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    Polymer Engineering and Science 1 (1961), S. 47-51 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new curing system which yields room temperature curing epoxy adhesives with high bond strength and softening point has been developed for service in contact with high explosives. Bisphenol A type resins cured with hydroxyl alkyl phosphate acid esters are used. Short pot life and relatively low alkali resistance are drawbacks of the system.
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  • 13
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    Polymer Engineering and Science 1 (1961), S. 133-138 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Twelve plastics representing various chemical structures were studied as part of a program to determine the utility of plastics as packaging materials in the high radiation presentation of food. The plastics were exposed to selected dosages of Cobalt-60 gamma radiation in vacuum and in air. Gas evolution and changes in infrared spectra as a result of irradiation were used to hypothesize the relative stability of these plastics to irradiation. Based on these facts it was found that plastics containing conjugated ring systems, ionic linkages, and chlorine in side groups were the most stable.
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  • 14
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    Polymer Engineering and Science 1 (1961), S. 139-142 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new series of inorganic-organic high polymers have been synthesized namely; the metaloxene polymers of phenolaldehyde. Titanium (IV), Zirconium (IV) and Hafnium (IV) phenolaldehyde have been prepared and other metals especially the refractory type metals may merit further development as calorobic plastic materials. The hafnium resin has been compression molded into a rocket-nozzle insert shape with satisfactory rocket-firing results.
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  • 15
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    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 16
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    Polymer Engineering and Science 1 (1961), S. 152-152 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 17
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    Polymer Engineering and Science 1 (1961), S. 169-176 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Mobile ions can be introduced thereby increasing the conductivity, with a limiting operating temperature range of 200°-250°C. Conductivity can be increased with the formation of conjugatd double bonds. Polymeric compounds may be synthesized with metallocyclic groups, where an atom of metal is bound to nitrogen atoms in a heterocyclic system in the basic chain of conjugation of the macromolecule. Here phtalocyanimes possess the greatest thermal stability. Lastly there are semiconducting polymers with conjugated double bonds containing hetero-atoms in the principle chain, having unpaired electrons of oxygen and nitrogen.
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  • 18
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    Polymer Engineering and Science 1 (1961), S. 52-52 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 19
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    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 20
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    Polymer Engineering and Science 1 (1961), S. 54-55 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 21
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    Polymer Engineering and Science 1 (1961), S. 109-112 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Griffith theory for brittle fracture predicts that the tensile strength should be inversely proportional to the square root of the size of a defect or flaw in the sample tested. The validity of this relation has been investigated for the glassy polymers, poly(methyl methacrylate) and polystrene. The results indicate that the strength of the polymers depends on two factors: (1) the surface energy, and (2) the inherent flaw size. The surface energy is primarily that dissipated in a viscous flow process and the inherent flaw size is related to the tendency of the polymer to craze under stress.
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  • 22
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    Polymer Engineering and Science 1 (1961), S. 113-120 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow patterns in the channel of a screw extruder have been investigated in a study utilizing a model extruder with stationary screw and a rotating, transparent barrel. Photographs of flow streamlines at conditions over the full range of output restriction are presented for a non-Newtonian fluid. A technique employing photographs of particle tracers was used with the same apparatus to permit quantitative measurement of velocity profiles with both a Newtonian and a non-Newtonian fluid.
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  • 23
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    Polymer Engineering and Science 1 (1961), S. 121-132 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanism of formation of tubular polythene film is a complicated process, and extensive studies have shown that the properties of the film made are influenced profoundly and in a complex way both by the processing conditions used by certain design features of the equipment. Studies of the effect of the extrusion variables on the more important film properties, both optical and mechanical, are reviewed in this paper. The results are discussed in terms of the fundamental nature of polythene film, its surface, its crystalline structure and its orientation.
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  • 24
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    Polymer Engineering and Science 1 (1961), S. 147-148 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 25
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    Polymer Engineering and Science 1 (1961), S. 9-13 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Translated from: Vysokomolekuliarnye Soedineniia 2, 778-84 (May 1960). A thermomechanical study was made of the softening of crystalline polymers during uniform, uniaxial stretch and also of the effect of the rate of heating upon the softening or amorphous polymers. The effect of the tensile force on the thermo-mechanical behavior of various polymers was measured over the range 20 to 100 kg/cm2 and within wide temperature limits (-150° to 250°C). Ribbons 50 mm long, 2-4 mm wide and 0.05 to 0.5 mm thick served as specimens.
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  • 26
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    Polymer Engineering and Science 1 (1961), S. 3-8 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study was designed to show the nature of weathering of an elastomer poly( ester-urethane), and to indicate methods of overcoining the deficiency. Unprotected polymer, when exposed to UV radiation in a Weatherometer, showed deterioration which is characterized by loss of tensile strength, some increase in modulus, and a decreased extensibility of surface skin.
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  • 27
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    Polymer Engineering and Science 1 (1961), S. 56-56 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 28
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    Polymer Engineering and Science 1 (1961), S. 63-67 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method for measuring heat stability and temperature of degradation of thermosetting plastics is described, as well as an improved method for the determination of transition temperature into glassy or viscous state for thermosetting resins. Magnitude of elastic deformation is tied in with length of polymer chain and lattice density.
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  • 29
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    Polymer Engineering and Science 1 (1961), S. 80-85 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The magnitude and temperature dependence of the electrical resistivities of a number of thermoplastic and thermosetting high polymers have been determined. Activation energies for the electrical conduction process Ee have been calculated and found to vary from 12 to 60 Kcal/mole depending upon the structure of the polymer. Results are interpreted in terms of an ionic diffusion process and discussed in terms of the structure of the polymers.
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  • 30
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    Polymer Engineering and Science 1 (1961), S. 57-62 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Derivatives of 2-hydroxybenzophenone are well-known stabilizers for such polymers as cellulose acetate butyrate and polyesters. Their stabilization effectiveness is commonly associated with their ability to screen a polymer from the harmful ultraviolet radiation found in sunlight. They also satisfy other requirements for effective stabilizers, namely, compatibility with many polymers and an inherent stability to ultraviolet light. Several other functions of 2 hydroxybenzophenones in stabilizing a polymer to ultraviolet light have been postulated, but little experimental data related to them are available. This paper deals with some of the additional functions of 2-hydroxybenzophenones in weathering stabilization as investigated by nuclear magnetic resonance spectroscopy (NMR) and electron paramagnetic resonance spectroscopy (EPR).
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  • 31
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    Polymer Engineering and Science 1 (1961), S. 68-72 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: During the last thrity years, dielectric measurements have been employed extensively to provide a better understanding of the interactions between polymer and plasticizer in various thermoplastic formulations. Recently, a series of melamine resins, plasticized to the extent that shrinkage and internal stress were modified, became available. Since there is little information in the literature concerning the dielectric properties of such thermosetting resins, a study was made of the variation of dielectric constant and loss as a function of frequency and temperature.
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  • 32
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    Polymer Engineering and Science 1 (1961), S. 73-79 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This article includes a comparison of the adhesive properties of bisphenol-A expoxides at 300°K and 76°K with respect to the molecular weight of the uncured resins. Joints of 2024 aluminum were tested at 300°K and 76°K in tensile-shear and in impact-shear, and total linear thermal contraction of the cured resins was measured between the two temperatures. Results are discussed with respect to residual joint stresses and adsorptive properties of the resins.
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  • 33
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    Polymer Engineering and Science 1 (1961), S. 86-92 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For broad ranges of operating conditions and a wide variety of high pressure polyethylenes, the flow data obtained from a high shear viscometer and a commercial extruder are identical. Discrepancies between flow data can result from non steady state viscosities in the high shear viscometer, or from cooled screw extruder operation. In the broad regions in which the flow data concur, the readily obtained viscometer data are suitable for predictions of extruder performance. The principle is illustrated by the good correlation of a viscometer flow curve parameter and the screw power consumption in the extruder. Principles outlined for flow data identity and extruder performance prediction are believed to be general, but the quantitative limits defined are specific to the extrusion devices involved.
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  • 34
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    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 35
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    Polymer Engineering and Science 1 (1961), S. 93-100 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Recent technology has evolved a number of dissimilar thermoplastics which under conditions of ambient temperature and impact loading show both the high modulus, which is mainly a property of brittle polymers in the glassy state, and also the impact resistance, such as may be expected of polymers in the rubbery state. Several of these special plastics were examined by electronmicroscopy and also with respect to several aspects of their mechanical behavior to establish by direct observation and inference whether or not different types of plastics exhibit some common features of structure which promote impact resistance. These observations suggest the hypothesis that special circumstances of domain heterogeneity can override many other variables of composition or molecular structures in controlling the fracture mechanism.
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  • 36
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    Polymer Engineering and Science 1 (1961), S. 102-103 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 104-104 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 38
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 105-108 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For resins of room temperature density 0.91 to 0.96 g/cc, enthaply and internal energy diagrams have been developed from 0 to 200°C and up to 1000 atmospheres. These diagrams can be used for estimating properties for which data are not available, and provide unified view of many properties of polyethylene under conditions of fabrication and use. Extent of crystallinity estimates can be made from enthalpy, internal energy, specific volume, compressibility and melting point data provided for hypothetical amorphous, crystalline and actual resins.
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  • 39
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 143-146 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This article describes preparation of resins as described in the title above, and the effect of concentration of the diepoxide, dimer acid, and initiator (stannous octoate). Proportion of dimer acid and diepoxide has a marked influence on hardness and tensile properties of resins. Change in tensile properties upon aging correlates very well with change in hardness. Higher proportions of dimer acid produce softer, more flexible resins. The resins have unique electrical properties at temperature up to 175°C, apparently because of the high proportion of hydrocarbon in the resin.
    Additional Material: 1 Ill.
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  • 40
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 150-151 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 41
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 153-163 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Permeability properties depend on the size, shape and polarity of the permeating molecule. Permeability of organic liquids, polar or non-polar, can be quite accurately predicted if the chemical composition of the permeant is known. By the choice of an arbitrary value (unity) as an indicator for the carbon atom, numbers specific to each structural element of the permeating molecule can be computed from previous experimental data. These numbers, herein called “Permachor” values (π), then combine by simple addition to relate the logarithm of a liquid's permeation in polyethylene.
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  • 42
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 177-179 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Equipment is described for measurement of Young's and shear modulus on the same identical polymer sample, by a free-vibration method. Strain gauges are used as sensors in an automatic recorder. Young's modulus and damping, shear modulus and damping and Poisson's ratio are reported over a range of temperature for polypropylene, Nylon 66 and poly (methylmethacrylate). It is found that Poisson's ratio shows a dip in the glass transition region and that values greater than the infinitesimal strain limit of 0.5 are obtained in the rubbery region.
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 181-190 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Adsorption studies on powdered and planar surfaces yield significant information regarding the rate and degree of interaction between the substrate and the organic adsorbate. Investigative tools include contact angle measurement, radiotracer methods, ellipsometry, x-ray diffraction, electron diffraction, elegant infrared techniques, dynamic desorption techniques, and film balance applications.
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  • 44
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 199-213 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The chromium complex is chemically bonded by ion exchange with alkali cations to strongly acidic sites in the glass surface. These sites are formed by the isomorphous replacement of silicon by boron and aluminum in the network structure. Polymerized complexes are better bonding agents than monomeric ones. Specific interactions between organic groups on the chrome complex and the bonding resins also determine laminate strength and water resistance.
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  • 45
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 224-233 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Theoretically a monolayer or insignificant weight per cent of coupling agent should give optimum properties for fiber glass-resin composites, contrary to commercial practice. Studies of variation of chemical bonding between the coupling agent and the resin and the study of the degree of bonding of the coupling agents to the glass by extraction techniques have not explained this effect. However, new techniques of electron microscopy have revealed details of loading distribution and agglomeration on the glass fiber which tend to explain this effect.
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  • 46
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 234-244 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Evidence indicates that there is a chemical bond between the coupling agent of either silane or chrome complex type and the glass substrate, but that this chemical bond may be strong or weak, depending on the elements making up the bond and the other elements in the immediate area surrounding the bond. These elements can exert either a beneficial or detrimental effect on the strength of that bond. Other evidence is given to show that a vapor phase treatment that applies silane coupling agents like A-1100 to “E” glass gives the highest known strength retention values. A mechanism is advanced to explain the bridging of unreactive sites on glass surfaces by silane coupling agents applied from solution.
    Additional Material: 17 Ill.
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