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  • 04.01. Earth Interior  (3)
  • Elsevier  (3)
  • American Association for the Advancement of Science
  • American Institute of Physics (AIP)
  • International Union of Crystallography
  • 2020-2024  (3)
  • 1960-1964
  • 2020  (3)
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  • Elsevier  (3)
  • American Association for the Advancement of Science
  • American Institute of Physics (AIP)
  • International Union of Crystallography
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Year
  • 1
    Publication Date: 2023-10-25
    Description: Calc-alkaline and alkaline magmatic activity is generally separated in space and/or in time. The Eastern Transylvanian Basin in Romania is one of the few places where, during Pleistocene, alkaline eruptions occurred contemporaneously with the calc-alkaline activity. Mantle xenoliths entrained in Perşani Mts. alkaline volcanic products have been studied in order to investigate the interaction of metasomatic agents of different magmatic affinities with the mantle wedge. Based on mineral major and trace element and noble gases in fluid inclusions, two main events have been recognized. The first was a pervasive, complete re-fertilization of a previously depleted mantle by a calc-alkaline subduction-related melt, causing the formation of very fertile, amphibole-bearing lithotypes. This is shown by the a) increased amounts of modal clinopyroxene up to 21.9 % with Al2O3 contents up to 8.16 wt%, higher than what is expected for clinopyroxene in Primordial Mantle; b) 4He/40Ar* ratios up to 1.2, within the reported range for mantle production; c) 3He/4He in olivine, opx and cpx of 5.8 ± 0.2 Ra, among the most radiogenic values of European mantle, below the typical MORB mantle value (8 ± 1 Ra), reflecting recycling of crustal material in the local lithosphere. The second event is related to later interaction with an alkaline metasomatic agent similar to the host basalts that caused slight LREE enrichment in pyroxenes and disseminated amphiboles and precipitation of vein amphiboles with a composition similar to amphiboles megacrysts also found in the Perşani Mts. volcanic deposits. This is highlighted by the 4He/40Ar* and 3He/4He values found in some opx and cpx, up to 2.5 and 6.6 Ra, respectively, more typical of magmatic fluids.
    Description: Published
    Description: 105516
    Description: 1T. Struttura della Terra
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Keywords: Mantle refertilisation ; Eastern Transylvanian Basin ; Noble gases ; Post-collisional ; Subduction-related metasomatism ; Solid Earth ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2023-11-16
    Description: Lascar (5592 m a.s.l.) and Lastarria (5697 m a.s.l.) are Chilean active stratovolcanoes located in the Central Volcanic Zone (CVZ; 16°S to 28°S) that have developed on top of a 71 km thick continental crust. Independently of the similarities in their Plinian/Vulcanian eruptive styles, their complex magmatic feeding structures and the origins of their magmatic fluids still necessitate constraints in order to improve the reliability of geochemical monitoring. Here we investigate the petrography, bulk-rock chemistry, and mineral chemistry in products from the 1986–1993 explosive eruptive cycle at Lascar and from several Holocene eruptive sequences at Lastarria. These data are integratedwith measurements of the noble gas isotopes in fluid inclusions (FIs) of minerals fromthe same products as well as in fumarole gases. The geochemistry ofminerals and rocks shows that the studied products belong to high-K–calc-alkaline series typical of subduction-related settings, and provide evidence of differentiation,mixing, and crustal assimilation that are higher at Lastarria. The contribution of slab sediments and fluids to magma genesis in thewedge is limited, suggesting a homogeneous mantle beneath CVZ. The deepest crystallization processes occurred at variable levels of the plumbing systems according to the lithostatic equivalent depths estimated with mineral equilibrium geobarometers at Lascar (15–29 km) and Lastarria (~20–40 km). The 40Ar/36Ar and 4He/20Ne ratios in FIs and fumarole gases indicate the presence of some degree of air contamination in the fluids from both volcanoes. The 3He/4He values at Lascar (6.9–7.3 Ra) are relatively homogeneous and comparable to those of fumaroles, suggesting a main zone of magma crystallization and degassing. In contrast, the 3He/4He values at Lastarria (5.31–8.01 Ra) vary over a wide range, suggesting various magma storage levels and providing evidence of crustal contamination, as indicated by the rock chemistry.We argue thatmantle beneath the two volcanoes has a MORB-like signature of 3He/4He, while local crustal contamination explains the lower ratios measured at Lascar.
    Description: Published
    Description: 105615
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Lascar ; Lastarria ; noble gases ; Fluid inclusions ; Crustal contamination ; Mantle wedge ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2023-11-21
    Description: Trace volatile elements like He are key for understanding the mantle source signature of magmas and to better constrain the relative roles of subduction and crustal processes to the variability of along-arc chemical and isotopic signatures of magmatic fluids. Here we report on noble gas abundances and isotopic data of Fluid Inclusions (FIs) in eruptive products and/or fumarolic gases from the Colombia-Ecuador segment of Andean Northern Volcanic Zone (NVZ). FIs in olivine phenocrysts from Ecuador (El Reventador, Cotopaxi and Tungurahua) yield air-normalized corrected 3He/4He ratios of 7.0–7.4 RA, within the MORB range (8 ± 1 RA). With exception of the Cotopaxi lavas (opx 〈 〈oliv.), these are indistinguishable of those obtained for their cogenetic orthopyroxene pairs and of gas emissions previously reported in literature. Olivine phenocrysts from Nevado del Ruiz fissure lavas also yield the highest 3He/4He (8.5 ± 0.3 RA) for this volcanic system, which is in the range of fumarolic gases for Galeras (previously reported as high as 8.8 RA and here measured to a maximum of 8.3 ± 0.1 RA). Our dataset highlights disparities between isotope signatures of eruptive products from Ecuador (avg. ~7.2 RA) and those reported for the Colombian portion of the NVZ (avg. ~8.5 RA). Previous studies on the geochemistry of erupted products put in evidence significant along-arc variations ascribed either to the involvement of different slab components, or to variable depths of evolution of arc magmas within the continental crust. However, the same variation is not discernible in the signature of noble gases, especially helium, from FIs and gas emissions analyzed in this study, with little inter-variation between Cotopaxi, Reventador and Tungurahua (all within 0.2 RA from the Ecuador average of 7.2) and Galeras and Nevado del Ruiz, whose maximum values differ by ~0.3 RA. We therefore suggest a homogenous MORB-like 3He/4He signature for the mantle wedge beneath this arc segment, whereby along-arc variations in crustal thickness (from 〈35 km at the northernmost part of the segment to ≥50 km at the Ecuadorian arc segment) may factor largely into the variability recorded on our data set. The first CO2/3He ratios obtained in FIs from Andean rocks support the hypothesis of increasing crustal contamination from Colombia to Ecuador, concomitant with increasing crustal thicknesses under the respective arc regions.
    Description: Published
    Description: 119966
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Andean Volcanic Belt ; Northern Volcanic Zone ; Fluid inclusions ; Noble gases ; Helium ; Crustal thickness ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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