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  • Methane  (3)
  • American Geophysical Union  (3)
  • American Chemical Society
  • Annual Reviews
  • Springer
  • 2020-2023  (3)
  • 1980-1984
  • 2020  (3)
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  • 2020-2023  (3)
  • 1980-1984
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  • 1
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Solid Earth 124(8), (2019): 7525-7537, doi: 10.1029/2019JB018186.
    Description: The proliferation of drilling expeditions focused on characterizing natural gas hydrate as a potential energy resource has spawned widespread interest in gas hydrate reservoir properties and associated porous media phenomena. Between 2017 and 2019, a Special Section of this journal compiled contributed papers elucidating interactions between gas hydrate and sediment based on laboratory, numerical modeling, and field studies. Motivated mostly by field observations in the northern Gulf of Mexico and offshore Japan, several papers focus on the mechanisms for gas hydrate formation and accumulation, particularly with vapor phase gas, not dissolved gas, as the precursor to hydrate. These studies rely on numerical modeling or laboratory experiments using sediment packs or benchtop micromodels. A second focus of the Special Section is the role of fines in inhibiting production of gas from methane hydrate, controlling the distribution of hydrate at a pore scale, and influencing the bulk behavior of seafloor sediments. Other papers fill knowledge gaps related to the physical properties of hydrate‐bearing sediments and advance new approaches in coupled thermal‐mechanical modeling of these sediments during hydrate dissociation. Finally, one study addresses the long‐standing question about the fate of methane hydrate at the molecular level when CO2 is injected into natural reservoirs under hydrate‐forming conditions.
    Description: C. R. was supported by the U.S. Geological Survey's Energy Resources Program and the Coastal/Marine Hazards and Resources Program, as well as by DOE Interagency Agreement DE‐FE0023495. C. R. thanks W. Waite and J. Jang for discussions and suggestions that improved this paper and L. Stern for a helpful review. J. Y. Lee was supported by the Ministry of Trade, Industry, and Energy (MOTIE) through the Project “Gas Hydrate Exploration and Production Study (19‐1143)” under the management of the Gas Hydrate Research and Development Organization (GHDO) of Korea and the Korea Institute of Geoscience and Mineral Resources (KIGAM). Any use of trade, firm, or product name is for descriptive purposes only and does not imply endorsement by the U.S. Government.
    Keywords: Gas hydrate ; Methane ; Reservoir properties ; Multiphase flow
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015989, doi:10.1029/2019JC015989.
    Description: Relatively minor amounts of methane, a potent greenhouse gas, are currently emitted from the oceans to the atmosphere, but such methane emissions have been hypothesized to increase as oceans warm. Here, we investigate the source, distribution, and fate of methane released from the upper continental slope of the U.S. Mid‐Atlantic Bight, where hundreds of gas seeps have been discovered between the shelf break and ~1,600 m water depth. Using physical, chemical, and isotopic analyses, we identify two main sources of methane in the water column: seafloor gas seeps and in situ aerobic methanogenesis which primarily occurs at 100–200 m depth in the water column. Stable isotopic analyses reveal that water samples collected at all depths were significantly impacted by aerobic methane oxidation, the dominant methane sink in this region, with the average fraction of methane oxidized being 50%. Due to methane oxidation in the deeper water column, below 200 m depth, surface concentrations of methane are influenced more by methane sources found near the surface (0–10 m depth) and in the subsurface (10–200 m depth), rather than seafloor emissions at greater depths.
    Description: This research was supported by DOE Grant (DE‐FE0028980) to J. K. and by DOE‐USGS Interagency Agreement DE‐FE0026195.
    Description: 2020-10-04
    Keywords: Methane ; Ocean ; Isotopes ; Gas seeps ; Mid Atlantic bight ; Oxidation
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-10-20
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 47 (2020): e2020GL087669, doi:10.1029/2020GL087669.
    Description: We present a year‐round time series of dissolved methane (CH4), along with targeted observations during ice melt of CH4 and carbon dioxide (CO2) in a river and estuary adjacent to Cambridge Bay, Nunavut, Canada. During the freshet, CH4 concentrations in the river and ice‐covered estuary were up to 240,000% saturation and 19,000% saturation, respectively, but quickly dropped by 〉100‐fold following ice melt. Observations with a robotic kayak revealed that river‐derived CH4 and CO2 were transported to the estuary and rapidly ventilated to the atmosphere once ice cover retreated. We estimate that river discharge accounts for 〉95% of annual CH4 sea‐to‐air emissions from the estuary. These results demonstrate the importance of resolving seasonal dynamics in order to estimate greenhouse gas emissions from polar systems.
    Description: All data generated by the authors that were used in this article are available on PANGAEA (https://doi.org/10.1594/PANGAEA.907159) and model code for estimating CH4 transport is available on GitHub (https://doi.org/10.5281/zenodo.3785893). We acknowledge the use of imagery from the NASA Worldview application (https://worldview.earthdata.nasa.gov), part of the NASA Earth Observing System Data and Information System (EOSDIS), and data from Ocean Networks Canada, and Environment Canada. We thank everyone involved in the fieldwork including C. Amegainik, Y. Bernard, A. Cranch, F. Emingak, S. Marriott, and A. Pedersen. Laboratory analysis and experiments were performed by A. Cranch, R. McCulloch, A. Morrison, and Z. Zheng. We thank J. Brinckerhoff, the Arctic Research Foundation, and the staff of the Canadian High Arctic Research Station for support with field logistics. Funding for the work was provided by MEOPAR NCE funding to B. Else, a WHOI Interdisciplinary Award to A. Michel., D. Nicholson. and S. Wankel, and Canadian NSERC grants to P. Tortell. and B. Else. Authors received fellowships, scholarships, and travel grants including an NSERC postdoctoral fellowship to C. Manning, an NDSEG fellowship to V. Preston, NSERC PGS‐D and Izaak Walton Killam Pre‐Doctoral scholarships to S. Jones, and Northern Scientific Training Program funds (Polar Knowledge Canada, administered by the Arctic Institute of North America, University of Calgary) to S. Jones and P. Duke. We also thank Polar Knowledge Canada (POLAR) and Nunavut Arctic College for laboratory space and field logistics support.
    Description: 2020-10-23
    Keywords: Greenhouse gases ; Biogeochemistry ; Arctic coastal waters ; Biogeochemical sensing ; Seasonal cycles ; Methane
    Repository Name: Woods Hole Open Access Server
    Type: Article
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