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  • 1
    Publication Date: 2021-04-25
    Keywords: 551 ; VKB 350 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 186-209
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  • 2
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    Springer | Berlin [u.a.]
    Publication Date: 2021-04-25
    Description: Colonial non-zooxanthellate corals from deep-water coral reefs, Lophelia pertusa and Madrepora oculata, produce large amounts of extracellular mucus (EMS). This mucus has various functions, e.g., an antifouling capability protecting the coral skeleton from attacks of endolithic and boring organisms. Both corals show thick epithecal and exothecal skeletal parts with a clear lamellar growth pattern. The formation of the epitheca is unclear. It is supposed that the EMS play a central role during the calcification process of the epithecal skeletal parts. Staining with the fluorochrome tetracycline has shown an enrichment of Ca2+ ions in the mucus. In order to investigate this hypothesis, the protein content of the mucus and the intracrystalline organic matter from newly formed epithecal aragonite of Madrepora oculata was determined via sodium dodecyl sulfate (SDS) gel electrophoresis. Identical band patterns within both substances could be detected, one around 45 kDa molecular weight and a cluster around 30-35 kDa molecular weight. The occurrence of identical protein patterns within the mucus and in the newly formed aragonite confirms the idea that the mucus plays an important role during the organomineralization of the coral epitheca.
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 731-744
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  • 3
    Publication Date: 2021-03-29
    Description: The Satonda crater lake is up to now the only known "marine" lake with an increased alkalinity compared to seawater. Therefore, the lake contains a decreased amount of Ca2 +. Its pH values about 8.5-8.6. The lake was originally filled with freshwater, which is evident from peat deposits (3,150 14C_yrs BP). Shortly after the lake was rapidly filled with seawater and a marine fauna had established. Large input of organic matter has caused an intense oxygen consumption and, as a result, the bottom water of the lake became anaerobic. Thus, an intense sulfate reduction occurred producing high amounts of bicarbonate ions. The lake became stratified into three water bodies with various salinities separated by two pycnoclines. The surfaces water body is oxygenated and exhibits brackish conditions. The algae/microbialite reefs exhibit avertical development which started with a serpulid framework, followed by loose crusts of the calcified red alga Peyssonnelia and thalli of the green alga Cladophoropsis calcified by cyanobacteria (microstromatolites). The top calcified layer is formed by a network of Lithoporella, Peyssonnelia and microbialites. On the top layer the living reef community is located.
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 59-63
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  • 4
    Publication Date: 2021-03-29
    Description: The incorporation of hydrogen in enstatite in a hydrous system containing various amounts of NaCl was investigated at 25 kbar. The hydrogen content in enstatite shows a clear negative correlation to the NaCl-concentration in the system. The most favourable explanation is the reduction of water fugacity due to dilution. Other reasons for the limited hydrogen incorporation at high NaCl levels, such as a significant influence of Na+ on the defect chemistry or an exchange between OH- and Cl-in enstatite, appear much less important. A partition coefficient D Na En/Fluid = 0.0013 could be determined, demonstrating that Na is less incompatible in enstatite than H. The new results support the idea that dissolved components have to be considered when the total hydrogen storage capacity in nominally anhydrous minerals is estimated, especially in geological settings with high levels of halogens, such as subduction zones.
    Keywords: KEnstatite; Hydrogen incorporation;Water activity; Sodium; Chlorine ; 551
    Language: English
    Type: article , publishedVersion
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  • 5
    Publication Date: 2021-03-29
    Description: The coprecipitation of U (VI) with iron corrosion products from aqueous solutions by zero valent iron was investigated. The evidence of coprecipitation was demonstrated by conducting experiments with well characterized scrap iron,pyrite and a mixture of both materials with experimental durations of up to four months. Results indicate that under anoxic conditions only less than one tenth of the immobilized U(VI) was associated with the surface of scrap iron, whereas theremaining amount is entrapped in aging corrosion products.
    Keywords: 551
    Language: English
    Type: anthologyArticle , acceptedVersion
    Format: 577-586
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  • 6
    Publication Date: 2021-03-29
    Description: Five volcanic tuffs ranging from dacitic tuffs of Hungary to rhyolite, phonolite and basaltic tuffs of Germany were consolidated under laboratory conditions. Prior to consolidation an anti-hygro, a hydrous consolidant, which reduces the swelling ability of clay minerals, was applied. The three consolidants, a silicic acid ester (SAE), an elastic silicic acid ester (eSAE) and an acrylate resin (PMMA) were applied on test specimens under vacuum. Petrographic characterisation (polarizing microscopy, XRD, SEM) provided data for fabric analyses and the mineral composition of the tuffs. Changes in fabric, effective porosity, density, tensile strength, ultrasonic wave velocity were evaluated after the treatment. Weathering simulation tests such as hygric dilatation and thermal dilatation aimed to prove the effectiveness of consolidation and the durability of consolidated tuff samples. More than 500 samples were analysed. The tests showed that SAE caused the highest increase in indirect tensile strength. The water absorption and the pore size distribution of the tuffs were modified by consolidation. The PMMA reduced the water absorption the most, whereas SAE modified it the least. All the tested consolidants increased the thermal dilatation of the tuffs. The changes in hygric dilatation were not uniform: for most tuffs SAE increased and PMMA decreased the hygric dilatation, although the clay-rich Habichtswald tuff showed the opposite trend. The changes in hygric and thermal behaviour of consolidated tuff require special care when specific consolidants are chosen. These products modify the physical properties of consolidated tuffs and change the behaviour of weathering.
    Keywords: Strengthening agents; Tuff; Silicic acid ester; PMMA; Durability ; 551
    Language: English
    Type: article , publishedVersion
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  • 7
    Publication Date: 2021-03-29
    Keywords: Albrecht-von-Haller-Institut für Pflanzenwissenschaften / Abteilung für Palynologie und Klimadynamik ; Palaeolimnology; Holocene climate; Diatoms; Green algae; Pollen; Karst ; 551
    Language: English
    Type: article , publishedVersion
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  • 8
    Publication Date: 2021-03-29
    Description: A 782 d solubilization study using not shaken batch experiments and involving one uranium-bearing rock and three natural carbonate minerals was conducted to characterize uranium (U) leaching under oxic conditions. Results showed that aqueous U concentration increased continuously with a solubilization rate of 0.16 mgm-2h-1 for the first 564 d (1.5 y). After 1.5 y, U concentration reached a maximum value (saturation) and decreased afterwards. The saturation concentration of 54 mgL-1 (mean value) was influenced to various extent by the presence of carbonate minerals. Dissolution/precipitation, adsorption or ion exchange processes appear to control U solubilization.
    Keywords: 551
    Language: English
    Type: anthologyArticle , acceptedVersion
    Format: 425-435
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  • 9
    Publication Date: 2021-04-25
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 179-211
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  • 10
    Publication Date: 2021-04-25
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 102-120
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  • 11
    Publication Date: 2021-04-25
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 121-133
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  • 12
    Publication Date: 2021-03-29
    Description: The veneer cladding of the Oeconomicum (OEC, Göttingen), the State Theatre of Darmstadt (STD, Darmstadt) and of the State and University Library (SUB, Göttingen) is characterised by pronounced bowing after a short time of exposure. Direct comparison of bowing data related to measurements from 2000 to 2003 at the SUB clearly show that the amplitude in bowing had significantly increased. The bowing is different in intensity and orientation (concave, convex). The cladding material (Peccia marble, Rosa Estremoz marble and Carrara marble) are different in lattice preferred orientation, grain size distribution and grain interlocking. Depending on the bowing, panels may show cracks mostly initiated at the dowels. The percentage of visible cracks and breakouts increases with the amplitude of bowing except for the STD. Repetitive heatingcooling under dry conditions leads to considerable inelastic residual strain only after the first or second thermal cycle. The residual strain continuously increases again if water is present, whereby the moisture content after a thermal cycle has a certain impact on the decay rate. The water-enhanced thermal dilatation strongly correlates with the deterioration rate obtained from the laboratory bow test. Detailed petrophysical investigations provide evidence that with increasing bowing a decrease of mechanical properties (flexural strength or breaking load at dowel hole) occur. Marble degradation is also connected with the increase in porosity and a general shift of the maximum pore radii to larger pore sizes...
    Keywords: Bowing; Marble; Building mapping;Residual strain;Thermal expansion; Bowing potential ; 551
    Language: English
    Type: article , publishedVersion
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  • 13
    Publication Date: 2021-04-25
    Description: Protein components found in freeze-dried specimens of the coralline sponge Spirastrella (Acanthochaetetes) wellsi were separated and characterized . Proteins extracted from skeleton crystals (matrix proteins) contained high concentrations of glycin (16 %) as weil as enhanced amounts of asparagin/aspartic acid (11 %) and glutamin/glutamic acid (10 %). At least 10 proteins could be separated by SDSPAGE. Six of them, with molecular weights between 30 and 45 kDa, may be considered as distinct matrix proteins. The bulk of total soluble proteins as weil as all soluble matrix proteins are acidic with pH values below 5. Our results indicate that at least in one stage crystal growth is matrix mediated, i.e. controlled by the sponge.
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 9-12
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