ALBERT

Beschreibung: Sea ice drift, surface temperature, and barometric pressure were measured by Surface Velocity Profiler 2015P21 drifting on Antarctic sea ice. The buoy was deployed on multi year ice without drogue during POLARSTERN cruise ANT-XXXI/2 (PS96). The time series describes the position and additional parameters of the buoy between 02 Sep 2015 and 12 Sep 2017 in sample intervals of 1 hour. The data set has been processed, including the removal of obvious inconsistencies (missing values).

Beschreibung: Sea ice drift was measured by Surface Velocity Profiler 2017P38 drifting on Arctic sea ice. The buoy was deployed without drogue during POLARSTERN cruise ARK-XXXI/1 (PS106). The time series describes the position of the buoy between 12 Jun 2017 and 26 Jun 2017 in sample intervals of 5 minutes. The data set has been processed, including the removal of obvious inconsistencies (missing values).

Beschreibung: Sea ice drift was measured by Surface Velocity Profiler 2017P39 drifting on Arctic sea ice. The buoy was deployed without drogue during POLARSTERN cruise ARK-XXXI/1 (PS106). The time series describes the position of the buoy between 12 Jun 2017 and 12 Jul 2017 in sample intervals of 5 minutes. The data set has been processed, including the removal of obvious inconsistencies (missing values).

Beschreibung: Sea ice drift was measured by Surface Velocity Profiler 2016P46 drifting on Arctic sea ice. The buoy was deployed on second year ice without drogue during POLARSTERN cruise ARK-XXX/3 (PS101). The time series describes the position of the buoy between 29 Sep 2016 and 30 May 2017 in sample intervals of 30 minutes. The data set has been processed, including the removal of obvious inconsistencies (missing values).

Beschreibung: In permafrost areas, seasonal freeze-thaw cycles of active layer result in upward and downward movements of the ground. Additionally, relatively uniform thawing of the ice-rich layer at the permafrost table can contribute to net long-term surface lowering. We use a simple method to quantify surface lowering (subsidence) and uplift in a yedoma area of the Lena River Delta, Siberian Arctic (Kurungnakh Island), using reference rods (metal pipes and fiberglass rods) installed deeply in permafrost. The metal pipes were 2 m long and 3 cm in diameter and were anchored at least 1 m below the typical active layer. The fiberglass rods were 2 m long and 1 cm in diameter and were anchored at least 70 m below the typical active layer. We assume, therefore, that the rods were motionless relative to the permafrost. The plexiglass plate with a size of 10 by 10 cm was fixed in its horizontal position by the rod but could move freely with the surface vertically along the rod. We repeatedly measured distance between the top of a rod and a plexiglass plate resting on the ground surface. Several distance measurements around each rod were taken at each visit and averaged. Altogether 12 metal pipes were installed at the study site in April 2013 and 19 fiberglass rods were installed in April 2014. Measurements were conducted during field campaigns from spring 2013 to summer 2017 with some gaps. We provide here the measured distances between the top of a rod and a plexiglass plate. To obtain the ground displacement, the user have to define the period of interest and calculate the displacement.

Beschreibung: In permafrost areas, seasonal freeze-thaw cycles of active layer result in upward and downward movements of the ground. Additionally, relatively uniform thawing of the ice-rich layer at the permafrost table can contribute to net long-term surface lowering. We use a simple method to quantify surface lowering (subsidence) and uplift in a yedoma area of the Lena River Delta, Siberian Arctic (Kurungnakh Island), using reference rods (metal pipes and fiberglass rods) installed deeply in permafrost. The metal pipes were 2 m long and 3 cm in diameter and were anchored at least 1 m below the typical active layer. The fiberglass rods were 2 m long and 1 cm in diameter and were anchored at least 70 m below the typical active layer. We assume, therefore, that the rods were motionless relative to the permafrost. The plexiglass plate with a size of 10 by 10 cm was fixed in its horizontal position by the rod but could move freely with the surface vertically along the rod. We repeatedly measured distance between the top of a rod and a plexiglass plate resting on the ground surface. Several distance measurements around each rod were taken at each visit and averaged. Altogether 12 metal pipes were installed at the study site in April 2013 and 19 fiberglass rods were installed in April 2014. Measurements were conducted during field campaigns from spring 2013 to summer 2017 with some gaps. We provide here the measured distances between the top of a rod and a plexiglass plate. To obtain the ground displacement, the user have to define the period of interest and calculate the displacement.

Beschreibung: Differential SAR interferometry (DInSAR) uses the phase difference between two SAR signals acquired on two dates over the same area to measure small-scale ground motion. During the last decade the method has been adapted for monitoring permafrost-related ground motion. Here we perform DInSAR on TerraSAR-X data to assess its viability for seasonal thaw subsidence detection in a yedoma landscape of the Lena River Delta. TerraSAR-X is a right-looking SAR satellite launched in 2007, operating in the X-band (wavelength 3.1 cm, frequency 9.6 GHz), with a revisit time of eleven days. All data that we used were acquired in StripMap mode with HH polarization from a descending orbit at 08:34 local acquisition time (22:34 UTC). The incidence angle of the track we use is approximately 31 degrees. The scene size covered an area of approximately 18 km x 56 km. The slant range and azimuth pixel spacing were approximately 0.9 m and 2.4 m, respectively. Based on the ground temperature data we roughly estimated the beginning and the end of thaw season in 2013. The corresponding TerraSAR-X time series used for this study includes nine Single-Look Slant Range Complex (SSC) images taken between 7 June and 14 September 2013. The time span between the acquisitions that we used for interferometry was 11 days, with one exception when the time span was 22 days due to a missing acquisition. The data were processed using the Gamma radar software. The SSC data were converted to Gamma Single Look Complex (SLC) format and the SLC data were then consecutively co-registered with subpixel accuracy (typically better than 0.2 pixels) in such a way that the co-registered slave image became the master for the next image. This way of co-registering also ensures subpixel co-registration accuracy for all interferometric combinations of the nine images. Multilooking was performed with the factor 4 in the range and factor 3 in the azimuth directions to reduce the noise and obtain roughly square ground range pixels. The ground size of the multilooked pixel is approximately 7 m. We removed the topographic phase term using ArcticDEM that is a freely available high-resolution (5 m) circum-Arctic DEM produced from optical stereographic WorldView imagery acquired from 2012–2016. Obtained differential interferograms were then filtered with an adaptive filter based on the local fringe spectrum with the filtering window size of 128 pixels and an alpha exponent of 0.4. Interferograms, featuring especially low coherence, were additionally filtered with a window size of 64 pixels. For the phase unwrapping we used a branch-cut algorithm with the seeding point located approximately in the middle of the study area with relatively high coherence. We did not attempt to unwrap the areas, separated from the main study area by the river channels. The influence of atmospheric phase delays was evident in the unwarpped interferograms. In order to enhance the displacement signal and reduce atmospheric noise, all eight unwrapped interferograms were summed up in a time-continuous stack. Phase rate per day was calculated from the stack. A strong linear ramp was present across the phase rate map. To remove the trend, a 2D linear function was fit to the data and then subtracted from the phase rate map. The phase rate was then converted to vertical displacement rate in meters, under the assumption that the ground movement is purely vertical. The resulting displacement rate map was geocoded using ArcticDEM to the Universal Transverse Mercator (UTM) projection, zone 52N WGS84 with a pixel size of 5 m. The map was finally converted to the displacement magnitude by multiplying the rate by 99 days (from 7 June to 14 September 2013) and converted to centimeters. As opposed to the results, published in the related paper, here we did not start the unwrapping from the known bedrock position, as it was partly affected by low coherence as well as rather remote from the main area of interest and only weakly connected to the rest of the map over a small and noisy area of valid pixels. It means that the displacement map published here, features only displacement values relative to each other, without a fixed reference point. The spatial pattern of the signal, however, did not change with this alteration in processing. The DInSAR map showed a distinct subsidence in most of the thermokarst basins relative to the upland. Moreover, the spatial pattern of DInSAR signal was in high agreement with the surface wetness in the basins, identified with the near infra-red band of a high-resolution optical image. Drier parts of the basins were clearly separated from wetter parts that showed a prominent subsidence. In general, low coherence in combination with atmospheric effects as well as remoteness of a reference ground point were severe obstacles for the retrieval of a wide-area seasonal thaw subsidence map with TerraSAR-X data.

Beschreibung: Sea ice drift, surface temperature, and barometric pressure were measured by Surface Velocity Profiler 2017P23 drifting on Arctic sea ice. The buoy was deployed on first year ice without drogue during POLARSTERN cruise ARK-XXXI/1 (PS106). The time series describes the position and additional parameters of the buoy between 07 Jun 2017 and 11 Jul 2018 in sample intervals of 1 hour. The data set has been processed, including the removal of obvious inconsistencies (missing values).

Beschreibung: The copepod Calanus finmarchicus plays a crucial role in the north Atlantic food web. Its seasonal life cycle involves reproduction and development in surface waters before overwintering in diapause at depth. Although diapause has been studied for more than a century, the factors responsible for the initiation and termination of it are still unclear. Endogenous clocks have been identified as potent tools for photoperiod measurement and seasonal rhythmicity in many terrestrial species, but knowledge of these remains scarce in the marine realm. Focusing on the dominant CV copepodid stage, we sampled a population of C. finmarchicus from a Scottish sea loch to characterize population dynamics, several physiological parameters, and diel and seasonal expression rhythms of 35 genes representing different metabolic pathways, including the circadian clock machinery. This generated a detailed overview of the seasonal cycle of C. finmarchicus including the most extensive field dataset on circadian clock gene expression in a marine species to date. Gene expression patterns revealed distinct gene clusters upregulated at different phases of the copepod's seasonal cycle. While diel clock cycling was restricted to the active spring/summer phase, many clock genes exhibited the highest expression during diapause. Our results provide new insights into diapause on physiological and genetic levels. We suggest that photoperiod, in interaction with internal and external factors (lipid content, temperature, food availability) and the endogenous clock mechanism, plays an important role in the timing of diapause in C. finmarchicus.

Beschreibung: Added are 5 seismic reflection data sets of Store Glacier, a tide water glacier in West Greenland Uummannaq Fjord. Two crossing profiles were recorded, 20140513, along the ice flow and 20140514, across the ice flow.

Beschreibung: Coastal ecosystems in the Arctic are affected by climate change. As summer rainfall frequency and intensity are projected to increase in the future, more organic matter, nutrients and sediment could be mobilized and transported into the coastal nearshore zones. However, knowledge of current processes and future changes is limited. We investigated streamflow dynamics and the impacts of summer rainfall on lateral fluxes in a small coastal catchment on Herschel Island in the western Canadian Arctic. For the summer monitoring periods of 2014-16, mean dissolved organic matter (DOM) flux over 17 days amounted to 82.7 ± 30.7 kg km**-2 and mean total dissolved solids flux to 5252 ± 1224 kg km-2. Flux of suspended sediment (SS) were 7245 kg km**-2 in 2015, and 369 kg km**-2 in 2016. We found that 2.0 % of SS was composed of particulate organic carbon. Data and hysteresis analysis suggests a limited supply of sediments; their interannual variability is most likely caused by short-lived localized disturbances. In contrast, our results imply that DOC is widely available throughout the catchment and exhibits positive linear relationship with runoff. We hypothesize that increased projected rainfall in the future will result in a similar increase of DOC fluxes.

Beschreibung: The late Miocene-early Pliocene was a time of global cooling and the development of modern meridional thermal gradients. Equatorial Pacific sea surface conditions potentially played an important role in this global climate transition, but their evolution is poorly understood. Here, we present the first continuous late Miocene-early Pliocene (8.0-4.4 Ma) planktic foraminiferal stable isotope records from eastern equatorial Pacific Integrated Ocean Drilling Program Site U1338, with a new astrochronology spanning 8.0-3.5 Ma. Mg/Ca analyses on surface dwelling foraminifera Trilobatus sacculifer from carefully selected samples suggest mean sea-surface-temperatures (SSTs) are ~27.8±1.1°C (1 Sigma) between 6.4-5.5 Ma. The planktic foraminiferal d18O record implies a 2°C cooling between 7.2-6.1 Ma and an up to 3°C warming between 6.1-4.4 Ma, consistent with observed tropical alkenone paleo-SSTs. Diverging fine-fraction-to-foraminiferal d13C gradients likely suggest increased upwelling from 7.1-6.0 and 5.8-4.6 Ma, concurrent with the globally recognized late Miocene Biogenic Bloom. This study shows that both warm and asymmetric mean states occurred in the equatorial Pacific during the late Miocene-early Pliocene. Between 8.0-6.5 and 5.2-4.4 Ma, low east-west d18O and SST gradients and generally warm conditions prevailed. However, an asymmetric mean climate state developed between 6.5-5.7 Ma, with larger east-west d18O and SST gradients and eastern equatorial Pacific cooling. The asymmetric mean state suggests stronger trade winds developed, driven by increased meridional thermal gradients associated with global cooling and declining atmospheric pCO2 concentrations. These oscillations in equatorial Pacific mean state are reinforced by Antarctic cryosphere expansion and related changes in oceanic gateways (e.g., Central American Seaway/Indonesian Throughflow restriction).

Beschreibung: Planktic foraminifera census data have been used to reconstruct past temperatures through transfer functions, as well as changes in ocean ecosystems, chemistry and circulation. Here we present new multinet, plankton net and core-top census data from 20 sites in the Subpolar North Pacific. We combine these with previous data to provide an up to date compilation of North Pacific planktic foraminifera assemblage data. Our compilation is used to define 6 faunal zones: the subpolar zone; transitional zone; upwelling zone; subtropical zone; east equatorial zone; west equatorial zone; based on the distribution of 10 major species of planktic foraminifera. Two species of planktic foraminifera Neogloboquadrina pachyderma and Globigerina bulloides provide the basis for many subpolar paleo-reconstructions. Through the analysis of new multinet and CTD data we find that G. bulloides and N. pachyderma are predominantly found within 0-50 m of the water column and coincide with high food availability. N. pachyderma also shows a strong temperature control and can thrive in food poor waters where temperatures are low. Both species bloom seasonally, particularly during the spring bloom of March to June, with G. bulloides exhibiting greater seasonal variation. We suggest that percentage abundance of N. pachyderma in paleo-assemblages can be used to assess relative changes in past temperature, with G. bulloides abundance more likely to reflect changes in food availability. By comparing our core-top and multinet data, we also find a dissolution bias of G. bulloides over N. pachyderma in the North Pacific, which may enrich assemblages in the latter species.

Beschreibung: Caminella Lendenfeld, 1894 is a poorly known Geodiidae genus with unclear phylogenetic relationships. In order to find new lines of evidence that could shed light on the evolutionary history of Caminella, we decided to revise type material and museum material, as well as examine new material from underwater caves and deep-sea ecosystems. In doing so, we formally show that Isops maculosus Vosmaer, 1894 and Caminella loricata Lendenfeld, 1894 are junior synonyms of Caminella intuta (Topsent, 1892). We discuss different spicule morphological phenotypes in C. intuta, which may be linked to silica availability. We also discovered two new species of deep-sea Caminella: 1) from Cape Verde (Caminella caboverdensis sp. nov.) and 2) from seamounts located south of the Azores archipelago and the North of Spain (Caminella pustula sp. nov.). We reveal that Caminella sterrasters have complex surface microstructures, unique amongst the Geodiidae, where actin tips are linked to each other. Molecular markers (COI, 28S (C1-D2) and 18S) sequenced for some specimens led to new phylogenetic analyses, which continue to suggest a close relationship of Caminella with the Erylinae and Calthropella; these affinities are discussed in light of morphological characters.

Beschreibung: The mobilization of carbon in degrading permafrost is a long-term process and an important feedback upon climate change. Under submarine conditions substantial permafrost warming occurs millennia before permafrost thaws, potentially stimulating microbial communities. How microbial community composition and abundance responded to millennial-scale permafrost warming remains, however, unkown. We measured the in situ development of bacterial community composition and abundance together with temperature, salinity and pore water chemistry along an onshore-offshore transect on the Siberian Arctic Shelf. Samples derived from ice-bonded terrestrial permafrost comparable in age and sedimentation history that had been warming by more than 10 °C over the last 2500 years. Bacterial assemblages identified through amplicon sequencing correlated only weakly with temperature but strongly with pore water stable isotope signatures. They showed a significant spatial variation. Bacterial 16S rRNA gene copies quantified through qPCR negatively correlated with rising temperature, while both gene copies and total cell counts negatively correlated with increasing pore water salinity. Correlations of microbial community composition and abundance to stable isotope signatures and pore water salinity imply that they still mainly reflect the sedimentation history. On time-scales of centuries, permafrost warming coincided with decreasing microbial abundances, whereas millennia after inundation, microbial cell abundance was similar to onshore permafrost. We suggest that, as long as permafrost remains frozen the effect of warming alone on the permafrost-carbon-feedback is marginally even on time-scales of millennia because it has an overall low-level effect on microbial community composition and abundance.

Beschreibung: Changes in species' distributions are classically projected based on their climate envelopes. For Siberian forests, which have a tremendous significance for vegetation-climate feedbacks, this implies future shifts of each of the forest-forming larch (Larix) species to the north-east. However, in addition to abiotic factors, reliable projections must assess the role of historical biogeography and biotic interactions. Here, we use sedimentary ancient DNA and individual-based modelling to investigate the distribution of larch species and mitochondrial haplotypes through space and time across the treeline ecotone on the southern Taymyr peninsula, which at the same time presents a boundary area of two larch species. We find spatial and temporal patterns, which suggest that forest density is the most influential driver determining the precise distribution of species and mitochondrial haplotypes. This suggests a strong influence of competition on the species' range shifts. These findings imply possible climate change outcomes that are directly opposed to projections based purely on climate envelopes. Investigations of such fine-scale processes of biodiversity change through time are possible using paleoenvironmental DNA, which is available much more readily than visible fossils and can provide information at a level of resolution that is not reached in classical palaeoecology.

Beschreibung: The NW Iberian continental margin is characterised by a complex morphology and by a sedimentary system which was highly dynamic over glacial to interglacial times. The sedimentary history of the continental slope was strongly influenced by the interaction of bottom currents with topographic highs of structural origin leading to the accumulation of several sediment drifts. A combined analysis of gravity cores from different water depth with hydroacoustic data reveals the vertical behaviour of the upper Mediterranean Outflow Water (MOW) core after the Last Glacial Maximum (LGM). A coarser grained interval during Deglacial and early Holocene times (17.2 to 9.9 cal ka BP) points to an increase in bottom current strength. This increase in velocity was probably related to oceanic density fronts, which migrated through the 300 m thick transition zone between the underlying Labrador Sea Water and the overlying MOW. Radiocarbon dates timed the current strengthening to 17.2 cal ka BP, and a following weakening of the bottom current to 13.3 cal ka BP at 1965 m water depth and to 9.9 cal ka BP at 1885 m water depth. The depth-dependent current weakening suggests an upward shifting of the transition zone by 80 m that was related either to an overall shallowing of MOW or a vertical contraction of this water mass. The upward movement happened over a time interval of approximately 3.4 thousand years. In addition sediment core analysis reveals significant lateral heterogeneities within cm to dm thick sediment layers in the contourite drift. These heterogeneities suggest a need of a detailed core coverage across current-influenced deposits for palaeoceanographic studies to minimize misinterpretations.

Beschreibung: North Atlantic Deep Water (NADW) currently redistributes heat and salt between Earth's ocean basins, and plays a vital role in the ocean-atmosphere CO2 exchange. Despite its crucial role in today's climate system, vigorous debate remains as to when deep-water formation in the North Atlantic started. Here, we present datasets from carbonate-rich middle Eocene sediments from the Newfoundland Ridge, revealing a unique archive of paleoceanographic change from the progressively cooling climate of the middle Eocene. Well-defined lithologic alternations between calcareous ooze and clay-rich intervals occur at the ~41-kyr beat of axial obliquity. Hence, we identify obliquity as the driver of middle Eocene (43.5-46 Ma) Northern Component Water (NCW, the predecessor of modern NADW) variability. High-resolution benthic foraminiferal d18O and d13C suggest that obliquity minima correspond to cold, nutrient-depleted, western North Atlantic deep waters. We thus link stronger NCW formation with obliquity minima. In contrast, during obliquity maxima, Deep Western Boundary Currents were weaker and warmer, while abyssal nutrients were more abundant. These aspects reflect a more sluggish NCW formation. This obliquity-paced paleoceanographic regime is in excellent agreement with results from an Earth system model, in which obliquity minima configurations enhance NCW formation.

Beschreibung: Mg/Ca and stable oxygen isotope compositions (d18O) of planktic foraminifera tests are commonly used as proxies to reconstruct past ocean conditions including variations in the vertical water column structure. Accurate proxy calibrations require thorough regional studies, since parameters such as calcification depth and temperature of planktic foraminifera depend on local environmental conditions. Here we present radiocarbon-dated, modern surface sediment samples and water column data (temperature, salinity, and seawater d18O) from the Western Pacific Warm Pool. Seawater d18O (d18OSW) and salinity are used to calculate individual regressions for western Pacific surface and thermocline waters (d18OSW = 0.37 × S-12.4 and d18OSW = 0.33 × S-11.0). We combine shell d18O and Mg/Ca with water column data to estimate calcification depths of several planktic foraminifera and establish regional Mg/Ca-temperature calibrations. Globigerinoides ruber, Globigerinoides elongatus, and Globigerinoides sacculifer reflect mixed layer conditions. Pulleniatina obliquiloculata and Neogloboquadrina dutertrei and Globorotalia tumida preserve upper and lower thermocline conditions, respectively. Our multispecies Mg/Ca-temperature calibration (Mg/Ca = 0.26exp0.097*T) matches published regressions. Assuming the same temperature sensitivity in all species, we propose species-specific calibrations that can be used to reconstruct upper water column temperatures. The Mg/Ca temperature dependencies of G. ruber, G. elongatus, and G. tumida are similar to published equations. However, our data imply that calcification temperatures of G. sacculifer, P. obliquiloculata, and N. dutertrei are exceptionally warm in the western tropical Pacific and thus underestimated by previously published calibrations. Regional Mg/Ca-temperature relations are best described by Mg/Ca = 0.24exp0.097*T for G. sacculifer and by Mg/Ca = 0.21exp0.097*T for P. obliquiloculata and N. dutertrei.

Beschreibung: The temporal succession of changes in Amazonian hydroclimate during Heinrich Stadial 1 (HS1) (ca. 18-14.7 cal ka BP) is currently poorly resolved. Here we present HS1 records based on isotope, inorganic and organic geochemistry from a marine sediment core influenced by the Amazon River discharge. Our records offer a detailed reconstruction of the changes in Amazonian hydroclimate during HS1, integrated over the basin. We reconstructed surface water hydrography using stable oxygen isotopes (d18O) and Mg/Ca-derived paleotemperatures from the planktonic foraminifera Globigerinoides ruber, as well as salinity changes based on stable hydrogen isotope (dD) of palmitic acid. We also analyzed branched and isoprenoid tetraether concentrations, and compared them to existing bulk sediment ln(Fe/Ca) data and vegetation reconstruction based on stable carbon isotopes from n-alkanes, in order to understand the relationship between continental precipitation, vegetation and sediment production. Our results indicate a two-phased HS1 (HS1a and HS1b). During HS1a (18-16.9 cal ka BP), a first sudden increase of sea surface temperatures (SST) in the western equatorial Atlantic correlated with the slowdown of the Atlantic Meridional Overturning Circulation (AMOC) and the associated southern hemisphere warming phase of the bipolar seesaw. This phase was also characterized by an increased delivery of terrestrial material. During HS1b (16.9-14.8 cal ka BP), a decrease in terrestrial input was, however, associated with a marked decline of seawater d18O and palmitic acid dD. Both isotopic proxies independently indicate a drop in sea surface salinity (SSS). A number of records under the influence of the North Brazil Current, in contrast, indicate increases in SST and SSS resulting from a weakened AMOC during HS1. Our records thus suggest that the expected increase in SSS due to the AMOC slowdown was overridden by a two-phased positive precipitation anomaly in Amazonian hydroclimate.

Beschreibung: Exceptionally high sedimentation rates in Arctic fjords provide the possibility to reconstruct environmental conditions in high temporal resolution during the (pre-)Holocene. The unique geographical location of Svalbard at the intersection of Arctic and Atlantic waters offers the opportunity to estimate local (mainly glacier-related) vs. regional (hydrographic) variabilities. Sedimentological, micropalaeontological and geochemical data from the very remote, glacier-surrounded Wahlenbergfjord in eastern Svalbard provides information on glacier dynamics, palaeoceanographic and sea ice conditions during the Holocene. The present study illustrates a high meltwater discharge during the summer insolation maximum (~11.3-7.7 ka) when the intrusion of upwelled relatively warm Atlantic-derived waters led to an almost open fjord situation with reduced sea ice in summer. Around 7.7 ka, a rapid hydrographic shift occurred: The dominance of inflowing Atlantic-derived waters was replaced by a stronger influence of Arctic Water reflecting regional palaeoceanographic conditions evident in the benthic foraminiferal fauna also at Svalbard's margins. Neoglacial conditions characterised the late Holocene (~3.1-0.2 ka), when glaciers likely advanced as cold atmospheric temperatures were decoupled from the advection of relatively warm intermediate waters probably caused by an extending sea ice coverage. Accordingly, our data show that even a remote, glacier-proximal study site reflects rapid as well as longer-term regional changes.

Beschreibung: Methylated amines and sulfides are ubiquitous organic nitrogen and sulfur compounds in the marine environment and could serve as important energy substrates to methanogens inhabiting anoxic sediments. However, their abundance and isotopic values remain largely unconstrained in marine sediments. In this study, we investigated the distribution of trimethylamine (TMA), dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) in Aarhus Bay, Denmark and provided the first report for their stable carbon isotopic composition. Simultaneous measurement of those two compounds in small volumes of pore waters and sediments was accomplished with gas chromatography in combination with either a purge and trap system for quantification or a headspace method for carbon isotopic analysis. TMA in the solid phase (exchangeable pool, 0.3-6.6 µmol/kg wet sediment; base-extractable pool, 2-18 µmol/kg) was much more abundant than the dissolved pool (〈 20 nM), indicating strong adsorption of TMA to sediments. Likewise, total base-hydrolyzable DMS(P)t (including DMS and base-released DMS from DMSP) in sediment was at least three orders of magnitude higher (11-65 µmol/kg) than the dissolved pool of DMS(P)d in the pore water (including DMS and dissolved DMSP; 1-12 nM). TMA and DMS(P) contents in the solid phase peaked in the surface sediment, consistent with their phytodetrital origin. TMA was more 13C-depleted than DMS(P) (TMA: -36.4 per mil to -39.2 per mil; DMS: -18.6 per mil to -23.4 per mil), presumably due to different biological or biosynthetic origins of the respective methyl groups. Both compounds showed a downcore decrease in their solid-phase concentration, a feature that was attributed to microbial degradation, but progressive enrichment in 13C (up to 4 per mil) with depth was observed only for DMS(P). The considerable pool size of TMA and DMS(P) outlined in this study and geochemical evidence of their degradability suggested these two compounds could be potentially important substrates for methane production in sulfate-reducing environments.

Beschreibung: The half sections for archive were used for core imaging and description on ship board (GeoB 17701-1, GeoB 17703-1, GeoB 17705-1, GeoB 17708-1, GeoB 17711-1, GeoB 17715-1) and onshore (all others). The images were made using a handheld Canon EOS 450D reflex camera under fluorescent light conditions. A true color chart was used for color control. The core description provides information about core section length and position, core section number, core image, color, graphic lithology, sedimentary structures, coring disturbance, grain size and description text. Sediment color was determined qualitatively for core intervals using Munsell soil color charts. Grain size of the sand fraction was determined using a sand ruler, ranging from 63-90 µm for very fine sand, 90-250 µm for fine sand, 250-710 µm for medium sand, and 710-2000 µm for coarse sand.

Beschreibung: The strontium (Sr), neodymium (Nd) and lead (Pb) isotope signatures of suspended particulate matter (SPM) in rivers reflect the radiogenic isotope signatures of the rivers' drainage basin. These signatures are not significantly affected by weathering, transport or depositional cycles, but document the sedimentary contributions of the respective sources. We report new Sr, Nd and Pb isotope ratios and element concentrations of modern SPM from the Brazilian Amazon River basin and document the past evolution of the basin by analyzing radiogenic isotopes of a marine sediment core from the slope off French Guiana archiving the last 40 kyr of Amazon River SPM, and the Holocene section of sediment cores raised between the Amazon River mouth and the slope off French Guiana. The composition of modern SPM confirms two main source areas, the Andes and the cratonic Shield. In the marine sediment core notable changes occurred during the second phase of Heinrich Stadial 1 (i.e. increased proportion of Shield rivers SPM) and during the last deglaciation (i.e. increased proportion of Madeira River SPM) together with elsewhere constant source contributions. Furthermore, we report a prominent offset in Sr and Nd isotopic composition between the average core value (εNd: −11.7 ± 0.9 (2SD), 87Sr/86Sr: 0.7229 ± 0.0016 (2SD)) and the average modern Amazon River SPM signal (εNd: −10.5 ± 0.5 (2SD), 87Sr/86Sr: 0.7213 ± 0.0036 (2SD)). We suggest that a permanent change in the Amazon River basin sediment supply during the late Holocene to a more Andean dominated SPM was responsible for the offset.

Beschreibung: Long-term changes in vegetation and climate of southern Brazil, as well as ocean dynamics of the adjacent South Atlantic, were studied by analyses of pollen, spores and organic-walled dinoflagellate cysts (dinocysts) in marine sediment core GeoB2107-3 collected offshore southern Brazil covering the last 73.5 cal kyr BP. The pollen record indicates that grasslands were much more frequent in the landscapes of southern Brazil during the last glacial period if compared to the late Holocene, reflecting relatively colder and/or less humid climatic conditions. Patches of forest occurred in the lowlands and probably also on the exposed continental shelf that was mainly covered by salt marshes. Interestingly, drought-susceptible Araucaria trees were frequent in the highlands (with a similar abundance as during the late Holocene) until 65 cal kyr BP, but were rare during the following glacial period. Atlantic rainforest was present in the northern lowlands of southern Brazil during the recorded last glacial period, but was strongly reduced from 38.5 until 13.0 cal kyr BP. The reduction was probably controlled by colder and/or less humid climatic conditions. Atlantic rainforest expanded to the south since the Lateglacial period, while Araucaria forests advanced in the highlands only during the late Holocene. Dinocysts data indicate that the Brazil Current (BC) with its warm, salty and nutrient-poor waters influenced the study area throughout the investigated period. However, variations in the proportion of dinocyst taxa indicating an eutrophic environment reflect the input of nutrients transported mainly by the Brazilian Coastal Current (BCC) and partly discharged by the Rio Itajaí (the major river closest to the core site). This was strongly related to changes in sea level. A stronger influence of the BCC with nutrient rich waters occurred during Marine Isotope Stage (MIS) 4 and in particular during the late MIS 3 and MIS 2 under low sea level. Evidence of Nothofagus pollen grains from the southern Andes during late MIS 3 and MIS 2 suggests an efficient transport by the southern westerlies and Argentinean rivers, then by the Malvinas Current and finally by the BCC to the study site. Major changes in the pollen/spore and dinocyst assemblages occur with similar pacing, indicating strongly interlinked continental and marine environmental changes. Proxy comparisons suggest that the changes were driven by similar overarching factors, of which the most important was orbital obliquity.

Beschreibung: Cycloclasticus bacteria are ubiquitous in oil-rich regions of the ocean and are known for their ability to degrade polycyclic aromatic hydrocarbons (PAHs). In this study, we describe Cycloclasticus that have established a symbiosis with Bathymodiolus heckerae mussels and poecilosclerid sponges from asphalt-rich, deep-sea oil seeps at Campeche Knolls in the southern Gulf of Mexico. Genomic and transcriptomic analyses revealed that, in contrast to all previously known Cycloclasticus, the symbiotic Cycloclasticus appears to lack the genes needed for PAH degradation. Instead, these symbionts use propane and other short-chain alkanes such as ethane and butane as carbon and energy sources, thus expanding the limited range of substrates known to power chemosynthetic symbioses. Analyses of short-chain alkanes in the environment of the Campeche Knolls symbioses revealed that these are present at high concentrations (in the μM to mM range). Comparative genomic analyses revealed high similarities between the genes used by the symbiotic Cycloclasticus to degrade short-chain alkanes and those of free-living Cycloclasticus that bloomed during the Deepwater Horizon oil spill. Our results indicate that the metabolic versatility of bacteria within the Cycloclasticus clade is higher than previously assumed, and highlight the expanded role of these keystone species in the degradation of marine hydrocarbons.

Beschreibung: Seafloor methane release can significantly affect the global carbon cycle and climate. Appreciable quantities of methane are stored in continental margin sediments as shallow gas and hydrate deposits, and changes in pressure, temperature and/or bottom-currents can liberate significant amounts of this greenhouse gas. Understanding the spatial and temporal dynamics of marine methane deposits and their relationships to environmental change are critical for assessing past and future carbon cycle and climate change. Here we present foraminiferal stable carbon isotope and sediment mineralogy records suggesting for the first time that seafloor methane release occurred along the southern Brazilian margin during the last glacial period (40–20 cal ka BP). Our results show that shallow gas deposits on the southern Brazilian margin responded to glacial−interglacial paleoceanographic changes releasing methane due to the synergy of sea level lowstand, warmer bottom waters and vigorous bottom currents during the last glacial period. High sea level during the Holocene resulted in an upslope shift of the Brazil Current, cooling the bottom waters and reducing bottom current strength, reducing methane emissions from the southern Brazilian margin.

Beschreibung: The climate of the Sahara and Arabian deserts during the Little Ice Age is not well known, due to a lack of annually resolved natural and documentary archives. We present an annual reconstruction of temperature and aridity derived from Sr/Ca and oxygen isotopes in a coral of the desert-surrounded northern Red Sea. Our data indicate that the eastern Sahara and Arabian Desert did not experience pronounced cooling during the late Little Ice Age (~1750-1850), but suggest an even more arid mean climate than in the following ~150 years. The mild temperatures are broadly in line with predominantly negative phases of the North Atlantic Oscillation during the Little Ice Age. The more arid climate is best explained by meridional advection of dry continental air from Eurasia. We find evidence for an abrupt termination of the more arid climate after 1850, coincident with a reorganization of the atmospheric circulation over Europe.

Beschreibung: The geochemistry of seep gases is useful for an understanding of the local petroleum system. Here it was tested whether individual light hydrocarbons in seep gases are representatively entrapped in authigenic carbonates that formed near active seep sites. If applicable, it would be possible to extract geochemical information not only on the origin but also on the thermal maturity of the hydrocarbon source rocks from the gases entrapped in carbonates in the past. Respective data could be used for a better understanding of paleoenvironments and might directly serve as calibration point for, amongst others, petroleum system modeling. For this approach, (sub)-recent seep carbonates from the Black Sea (Paleodnjepr region and Batumi seep area), two sites of the Campeche Knoll region in the Gulf of Mexico, and the Venere mud volcano (Mediterranean Sea) were selected. These seep carbonates derive from sites for which geochemical data on the currently seeping gases exist. During treatment with phosphoric acid, methane and higher hydrocarbons were released from all carbonates, but in low concentrations. Compositional studies demonstrate that the ratio of methane to the sum of higher hydrocarbons (C1/(C2+C3)) is (partly strongly) positively biased in the entrapped gas fraction. δ13C values of C1 were determined for all samples and, for the samples from the Gulf of Mexico and the Mediterranean Sea, also of C2 and C3. The present dataset from six seep sites indicates that information on the seeped methane can be—although with a scatter of several permil—recorded in seep carbonate matrices, but other valuable information like the composition and δ13C of ethane and propane appears to be modified or lost during, for example, enclosure or at an early stage of diagenesis.

Beschreibung: Eastern Canadian margin sediments bear testimony to several catastrophic deglacial meltwater discharges from the retreating Laurentide Ice Sheet. The reddish-brown plumite layers deposited on the levees of the Laurentian Fan valleys have been recognized as indications of multiple outburst floods between Heinrich events 2 and 1. Five event layers have been consistently recorded in three new gravity cores retrieved on the SW Grand Banks slope and comply with the previously published Laurentian Fan core MD95-2029. The apparently huge extent of these outburst plumes around the Laurentian Fan as well as their causes and consequences are investigated in this study using physical properties, rock magnetic and grain-size analyses, together with seismoacoustic profiling. We provide the first detailed 14C ages of the outburst event sequence and discuss their recurrence intervals in the context of regional ice retreat. Compared to the hemipelagic interlayers, event layers have overall uniform and systematic changes of rock-magnetic properties. Hematite contents increase over time and proximally while magnetite grain sizes fine upwards and spatially away from the fan. Based on the sediment composition and load, we argue that these plumites were formed by recurrent erosion of glacial mud deposits in the Laurentian Channel by meltwater outbursts. Three alternative glaciological scenarios are evaluated: in each case, the provenance of the transported sediment is not an indicator of the precise source of the meltwater.