ALBERT

Beschreibung: The uppermost Middle Triassic Leikoupo Formation in the western Sichuan Basin of China has recently been shown to host as much as 5.3 tcf (1.5 × 1012 m3) of natural gas resources. The reservoir rocks, composed mainly of microbially derived dolomudstone (e.g., thrombolites and stromatolites), are characterized by low porosity (

Beschreibung: The present contribution aims for a characterization of microstructure and pore-space distribution of upper Visean Rudov beds, considered the main source rock for conventional oil deposits in the Ukrainian Dneiper–Donets Basin and a prospect for unconventional hydrocarbon production in recent years. Broad ion beam–scanning electron microscopy (SEM) mapping revealed a remarkably heterogeneous microstructure controlled by diagenetic precipitates (Fe/Mg carbonates, albite). Formation of these precipitates is likely triggered by organic matter decomposition and represents an important influencing factor for overall porosity and permeability. Furthermore, shale diagenesis also influences mechanical properties, as suggested by nanoindentation tests. The SEM-visible organic matter porosity is restricted to solid bitumen; although pores less than 2–3 nm in vitrinites of overmature samples are indicated by focused ion beam–SEM results, they cannot be resolved clearly by this method. Pore generation in solid bitumen that likely formed in situ in primary amorphous organic matter already starts at the early oil window in samples from the basinal oil-prone organofacies, whereas most porous solid bitumen at peak oil maturity was interpreted as relicts of primary oil migration, representing an earlier oil phase that predominantly accumulated in quartz-rich layers and became nanoporous during secondary cracking. In the terrestrially dominated transitional to marginal organofacies, pore generation in pyrobitumen resulting from gas generation occurs significantly later and is less intense. Formation of authigenic clay and carbonate minerals within pyrobitumen is likely related to organic acids formed during bitumen decomposition and implies the presence of an aqueous phase even in pores that are apparently filled exclusively with solid bitumen.

Beschreibung: Studies of lacustrine carbonate rocks in continental rifts have received huge interest in recent years because of their great economic value in the South Atlantic. However, most existing facies and tectonosedimentary models for carbonate platforms are based on marine carbonate systems, whereas models for nonmarine systems are scarce. The main aim of this paper is to establish such models and to further our understanding of the hydrocarbon-bearing late synrift Lower Cretaceous carbonate successions of the Campos Basin, Brazil. This paper is based on a proximal to distal industrial data set of three-dimensional (3-D) seismic, cores, and well logs from the Coqueiros Formation (Coquina), southern Campos Basin. The dominant carbonate facies in the Coqueiros Formation are mollusk-rich grainstones, rudstones, and floatstones, which form the main reservoir facies. The 3-D seismic interpretations show an oblique extensional rift system, characterized by a series of grabens, half grabens, accommodation zones, and horsts oriented northeast–southwest to north–northeast-south–southwest. Three tectonic domains are recognized based on structural style, stretching factors, and subsidence rates as well as facies and different types of lacustrine carbonate platforms. Proximal rift margin areas are characterized by a series of half grabens with footwall and hanging-wall dip slopes of shallow lacustrine carbonates and fluviodeltaic mixed carbonate and siliciclastic deposits in marginal, hanging-wall basins. Central areas are carbonate rich with platforms established over horst blocks surrounded by deeper-water carbonate facies. Distal areas have the highest amount of stretching and subsidence and accumulate the thickest carbonate successions over a template of buried horsts and grabens. The entire carbonate succession underlies a thick layer of Aptian salt, which forms the seal to this prolific hydrocarbon system.

Beschreibung: The Ahdeb oil field is located in the Mesopotamian Basin of central Iraq within a northwest–southeast-trending anticline. Seven oil-bearing layers exist in the eastern area in the field, but there is only one oil-bearing layer in the western area. This study reveals that the reservoir filling process resulted from the difference in the elements in the petroleum system, the oil generation and migration process, and the formation of the structural trap. Most oils in the field, with pristane/phytane 〈 1 and a high relative abundance of hopanes exceeding C30, were generated from the Upper Jurassic–Lower Cretaceous Chia Gara Formation, whereas some oils were generated from the Lower Cretaceous Ratawi and Zubair Formations. The mid-Upper Cretaceous reservoirs in the field are composed of lime grainstones, packstones, and wackestones.The main oil accumulation occurred during the Maastrichtian, coinciding with peak oil generation from the Chia Gara Formation with a 50% transformation ratio from organic matter to oil. The reservoirs of the eastern structural trap in the field were filled with large amounts of medium to heavy oils. After the formation of two structural traps in the western area in the mid-Miocene, oils pre-existing in the second layer of the Khasib Formation in the east began migrating toward the structural traps in the west during the late Miocene, as verified by relatively higher 1-/4-methylcarbazole and 1,8-/2,7-dimethycarbazole ratios of oils in the west than that in the east and residual solid bitumen in the east. The strike-slip fault might also have restricted oil or gas migration during the Miocene, limiting oil accumulation in the west.

Beschreibung: Predicting the lateral distribution of petroleum play elements (reservoirs, source rocks, and seals) requires basic understanding of regional basin evolution and depositional history. In remote areas where little data are available or where the basins have undergone episodes of tectonic deformation, this understanding relies on integrated analysis of the plate tectonic framework and the resulting paleogeography. The Arctic has experienced several episodes of tectonic deformation, which fundamentally changed the basin configuration and patterns of sediment routing. Here, we present a set of paleogeographic maps highlighting these changes during the Triassic–Paleogene. In the Triassic, the Arctic was characterized by a central restricted basin, which predominantly received clastic input from the Polar Urals and Arctic Canada. The Alaskan and Siberian passive margins received clastics from continent-scale drainage systems extending into the North American craton and the central Asian fold belt, respectively. In the Jurassic, the region was dominated by rifting as the central Arctic landmass rifted away from Laurentia. In the Early Cretaceous, the northern margin of the Barents Sea underwent regional uplift resulting in new provenance areas shedding sediments southward. Compression along the Pacific margin formed continuous topography and high sediment input to the Canada Basin during the Late Cretaceous. Regression in the Canada Basin continued in the Paleogene when major rift–tip deltas formed. This overview of Arctic paleogeography demonstrates the complexity of this overall data-poor area and shows the need for integrated, regional models to understand sediment routing and stratigraphic development in such areas.

Beschreibung: Clinoforms, the basic large-scale architectural form within which sediments are stored and eventually fed down depositional dip in clastic wedges, exist in many shapes and sizes. Understanding how they form, evolve, and degrade is critical to understanding how transport mechanisms affect the shelf margin and sediment partitioning and distribution, and their implications on the presence of a working petroleum system. The Neogene stratigraphic succession of the Taranaki Basin in New Zealand contains clinoform packages that display a variety of architectures well imaged on seismic data. Quantitative characterization of this interval was performed to unravel the processes by which clinoforms evolve under the influence of tectonic- and isostatic-driven subsidence, sea-level change, and sediment supply fluctuations. Nine different clinoform packages were identified on the basis of changes in their seismic stratigraphic characteristics. Two-dimensional stratigraphic forward modeling was used to conduct a sensitivity analysis and determine the relative importance of different geologic controls on their genesis. Our results show that during the early to late Pliocene, clinoform architectures were influenced by the opening of a back-arc rifting structure in the Taranaki Basin (northern graben), which controlled sediment redistribution and partitioning. At the same time, a drop in global sea level allowed sediment bypass to distal parts of the basin. During the late Pliocene, changes in the Australian–Pacific subduction zone forced rapid uplifting of the Southern Alps, generating a significant increase in sediment supply. Model simulations suggest that clinoform architectures during the late Pliocene were controlled by this increase in sediment supply and associated loading.

Beschreibung: The success of hydraulic fracturing and increasing use of basin-modeling packages drive the need to understand the effects of hydrocarbon (HC) generation on the mechanical properties of source rocks. A better understanding of relationships among geological, geochemical, and geomechanical parameters can potentially reduce the uncertainties associated with conventional and unconventional prospect evaluation.We present a simulation of microcrack growth based on a three-dimensional source-rock system. Upon thermal maturation, the kerogen transforms into lighter products, most of which are HCs. The generated products exert excessive pore pressure to the system resulting from the effect of volume expansion; this pressure is released through the expansion of pore space and formation of microcracks. Using linear elasticity and linear elastic fracture mechanics, our model calculates microcrack sizes (surface areas, lengths, apertures, and volumes) and the amount of overpressure throughout the maturation process. We validated this model with experimental data from Kobchenko et al. (2011), and performed sensitivity analysis for both laboratory and geological settings. Much larger microcracks are generated in laboratory settings compared to the subsurface because of the lack of overburden, resulting in secondary porosity over 100 times larger than the original organic porosity and crack lengths obtaining millimeter scale. In contrast, microcracks are much smaller in geological settings because of the presence of significant overburden and stiffer rock frames: the crack apertures are in the submicron regime with a crack length ranging from 100 to 300 μm. The formation of microcracks connects isolated microscale HC pockets, providing pathways for primary migration.

Beschreibung: A detailed, rock-based investigation of three Upper Cretaceous Eagle Ford Group cores situated behind, at, and downdip of the Lower Cretaceous Stuart City paleoreef-shelf margin in south Texas was conducted to understand stratigraphic, sedimentological, and geochemical relationships across this buried shelf margin. An understanding of how the Eagle Ford Group lithofacies vary across the paleoreef-shelf margin is currently lacking. We therefore examined a dip section of three cores across the antecedent shelf margin and delineated seven Eagle Ford lithofacies: (1) massive argillaceous mudstone, (2) massive to laminated foraminiferal lime wackestone, (3) radiolarian and foraminiferal dolomitic to lime packstone, (4) massive to bioturbated skeletal lime wackestone, (5) laminated foraminiferal lime packstone, (6) laminated inoceramid and foraminiferal lime grainstone, and (7) massive to bioturbated claystone. A basinward decrease in calcite from 60% to 48% is accompanied by an increase in clay minerals from 12% to 20%. The low-relief raised rim of the older, buried Stuart City paleoshelf margin may have acted as a barrier, dividing the Eagle Ford Group into two sedimentological systems: (1) a restricted drowned shelf to the north, and (2) an open-marine basinal setting to the south. The lower to upper Cenomanian Eagle Ford strata on the drowned shelf are cyclic and enriched in molybdenum, suggesting anoxic to euxinic water masses. The anoxic, open-marine, basinward strata are less cyclical and have a lower molybdenum (compared with the drowned shelf) content. Ash beds and gravity-flow deposits are rare south of the margin. A depositional model was constructed of the lower and upper Eagle Ford formations.