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  • American Chemical Society  (93,239)
  • Wiley-Blackwell
  • 2020-2024
  • 2015-2019  (93,259)
  • 1950-1954
  • 2017  (48,949)
  • 2016  (44,310)
Collection
Years
  • 2020-2024
  • 2015-2019  (93,259)
  • 1950-1954
Year
  • 1
    Publication Date: 2021-06-14
    Description: This study is focused on the (micro)biogeochemical features of two close geothermal sites (FAV1 and FAV2), both selected at the main exhalative area of Pantelleria Island, Italy. A previous biogeochemical survey revealed high CH4 consumption and the presence of a diverse community of methanotrophs at FAV2 site, whereas the close site FAV1 was apparently devoid of methanotrophs and recorded no CH4 consumption. Next-Generation Sequencing (NGS) techniques were applied to describe the bacterial and archaeal communities which have been linked to the physicochemical conditions and the geothermal sources of energy available at the two sites. Both sites are dominated by Bacteria and host a negligible component of ammonia-oxidizing Archaea (phylum Thaumarchaeota). The FAV2 bacterial community is characterized by an extraordinary diversity of methanotrophs, with 40% of the sequences assigned to Methylocaldum, Methylobacter (Gammaproteobacteria) and Bejerickia (Alphaproteobacteria); conversely, a community of thermo-acidophilic chemolithotrophs (Acidithiobacillus, Nitrosococcus) or putative chemolithotrophs (Ktedonobacter) dominates the FAV1 community, in the absence of methanotrophs. Since physical andchemical factors of FAV1, such as temperature and pH, cannot be considered limiting for methanotrophy, it is hypothesized that the main limiting factor for methanotrophs could be high NH4+ concentration. At the same time, abundant availability of NH4+ and other high energy electron donors and acceptors determined by the hydrothermal flux in this site create more energetically favourable conditions for chemolithotrophs that outcompete methanotrophs in non-nitrogen-limited soils.
    Description: Published
    Description: 150–162
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: geothermal soils ; geomicrobiology ; chemolithotrophs ; methanotrophs ; Pantelleria ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-04-07
    Description: Stable isotopes were measured in the carbonate and organic matter of palaeosols in the Somma–Vesuvius area, southern Italy in order to test whether they are suitable proxy records for climatic and ecological changes in this area during the past 18000 yr. The ages of the soils span from ca. 18 to ca. 3 kyr BP. Surprisingly, the Last Glacial to Holocene climate transition was not accompanied by significant change in d18O of pedogenic carbonate. This could be explained by changes in evaporation rate and in isotope fractionation between water and precipitated carbonate with temperature, which counterbalanced the expected change in isotope composition of meteoric water. Because of the rise in temperature and humidity and the progressive increase in tree cover during the Holocene, the Holocene soil carbonates closely reflect the isotopic composition of meteoric water. A cooling of about 2°C after the Avellino eruption (3.8 ka) accounts for a sudden decrease of about 1‰ in d18O of pedogenic carbonate recorded after this eruption. The d13C values of organic matter and pedogenic carbonate covary, indicating an effective isotope equilibrium between the organic matter, as the source of CO2, and the pedogenic carbonate. Carbon isotopes suggest prevailing C3 vegetation and negligible mixing with volcanogenic or atmospheric CO2.
    Description: Published
    Description: 813-824
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: restricted
    Keywords: stable isotope ; palaeosols ; Somma–Vesuvius ; palaeoclimate ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    American Chemical Society
    In:  EPIC3Environmental Science and Technology, American Chemical Society, 50(13), pp. 7066-7073, ISSN: 0013936X
    Publication Date: 2016-10-12
    Description: Atmospheric nuclear weapons testing (NWT) resulted in the injection of plutonium (Pu) into the atmosphere and subsequent global deposition. We present a new method for continuous semiquantitative measurement of 239Pu in ice cores, which was used to develop annual records of fallout from NWT in ten ice cores from Greenland and Antarctica. The 239Pu was measured directly using an inductively coupled plasma-sector field mass spectrometer, thereby reducing analysis time and increasing depth-resolution with respect to previous methods. To validate this method, we compared our one year averaged results to published 239Pu records and other records of NWT. The 239Pu profiles from the Arctic ice cores reflected global trends in NWT and were in agreement with discrete Pu profiles from lower latitude ice cores. The 239Pu measurements in the Antarctic ice cores tracked low latitude NWT, consistent with previously published discrete records from Antarctica. Advantages of the continuous 239Pu measurement method are (1) reduced sample preparation and analysis time; (2) no requirement for additional ice samples for NWT fallout determinations; (3) measurements are exactly coregistered with all other chemical, elemental, isotopic, and gas measurements from the continuous analytical system; and (4) the long half-life means the 239Pu record is stable through time.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
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    Wiley-Blackwell
    In:  EPIC3Climate Change Impacts on Fisheries and Aquaculture: A Global Analysis, Climate Change Impacts on Fisheries and Aquaculture: A Global Analysis, Wiley-Blackwell, pp. 663-701, ISBN: 978-1-119-15404-4
    Publication Date: 2017-10-09
    Description: Exploitation of Southern Ocean marine resources began more than 200 years ago with the massive hunt for seals and whales. In the 1960s/70s, fisheries for finfish and krill entered Southern Ocean waters. Within a few years many fish populations were heavily overfished and dramatically depleted, and some of these stocks still did not recover. Today, fish stocks and fisheries activities are managed and monitored by the Commission for the Conservation of Antarctic Marine Living Resources (CCAMLR) which was established in 1982 to ensure sustainable exploitation and protection of the delicate marine ecosystem. Current target species include Mackerel icefish (Champsocephalus gunnari), Patagonian as well as Antarctic toothfish (Dissostichus eleginoides and D. mawsoni) and Antarctic krill (Euphausia superba). Most of these species are vulnerable to overfishing due to slow growth, late age at maturity, and rather low fecundity. This vulnerability might increase, as Southern Ocean living communities are currently also faced with alterations of their environment due to climate change, such as increasing water temperatures and decreasing sea ice. Species, including the ones targetted by fisheries, are well-adapted to their particular environmental conditions and are believed to be highly sensitive to changes because of their cold-adapted physiology, their life history traits, and their direct or indirect dependence on sea ice. The species will be exposed to several stressors at the same time, and fishing pressure, direct abiotic forcing and changes mediated via the food web might act synergistically and result in significant population declines. In particular the strongly sea ice-dependent Antarctic krill, a key species in the food web, might be adversely affected. Fish species seems to have low tolerance towards higher water temperatures and may thus, in the long run, be replaced by lower latitude species.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 5
    Publication Date: 2017-04-04
    Description: We present a strategy to thoroughly investigate the effects of prominent topography on the surface tilt due to a spherical pressure source. We use Etna's topography as a case of study and, for different source positions, we compare the tilt fields calculated through (i) a 3-D boundary element method and (ii) analytical half-space solutions. We systematically determine (i) the source positions leading to the strongest tilt misfits when numerical and analytical results are compared and (ii) the surface areas where the strongest distortions in the tilt field are most likely to be observed. We also demonstrate that, under critical circumstances, in terms of respective positions of pressure source and observation points, results of inversion procedures aimed at retrieving the source parameters can be misleading, if tilt data are analysed using models that do not account for topography.
    Description: Published
    Description: 1471–1481
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Numerical approximations and analysis ; Transient deformation ; Volcano monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-12-11
    Description: In this study we applied a multidisciplinary approach, coupling geophysical and geochemical measurements, to unveil the provenance of 170 obsidian flakes, collected on the volcanic island of Ustica (Sicily). On this island there are some prehistoric settlements dated from the Neolithic to the Middle Bronze Age. Despite not having geological outcrops of obsidian rocks, the countryside of Ustica is rich in fragments of this volcanic glass, imported from other source areas. The study of obsidian findings was carried out first through visual observations and density measurements. At least two different obsidian families have been distinguished, probably imported from Lipari and Pantelleria islands. Analysing the magnetic properties of the samples, these two main sources were confirmed, but the possibility of other provenances was inferred. Finally, we characterized the geochemical signature of the Ustica obsidians by performing microchemical analyses through electron microprobe (EMPA) and laser ablation (LA–ICP–MS). The results were compared with literature data, confirming the presence of the Lipari and Pantelleria sources (Sicily) and indicating for the first time in this part of Italy a third provenance from Palmarola island (Latium). Our results shed new light on the commercial exchanges in the peri-Tyrrhenian area during the prehistoric age.
    Description: Published
    Description: 435–454
    Description: 1SR. TERREMOTI - Servizi e ricerca per la Società
    Description: 2SR. VULCANI - Servizi e ricerca per la Società
    Description: 3SR. AMBIENTE - Servizi e ricerca per la Società
    Description: JCR Journal
    Description: restricted
    Keywords: obsdian provenance ; LA-ICPMS ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2020-02-05
    Description: In this paper, we present a method for handling uncertainties in the determination of the source parameters of earthquakes from spectral data. We propose a robust framework for estimating earthquake source parameters and relative uncertainties, which are propagated down to the estimation of basic seismic parameters of interest such as the seismic moment, the moment magnitude, the source size and the static stress drop. In practice, we put together a Bayesian approach for model parameter estimation and a weighted statistical mixing of multiple solutions obtained from a network of instruments, providing a useful framework for extracting meaningful data from intrinsically uncertain data sets. The Bayesian approach used to estimate the source spectra parameters is a simple but powerful mechanism for non-linear model fitting, providing also the opportunity to naturally propagate uncertainties and to assess the quality and uniqueness of the solution. Another important added value of such an approach is the possibility of integrating information from the expertise of seismologists. Such data can be encoded in a prior state of information that is then updated with the information provided by seismological data. The performance of the proposed approach is demonstrated analysing data from the 1909 April 23 earthquake occurred near Benavente (Portugal).
    Description: Published
    Description: 691-701
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: open
    Keywords: Fourier analysis ; Probability distributions ; Earthquake source observations ; Seismicity and tectonics ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2022-05-25
    Description: © American Chemical Society, 2015. This article is posted here by permission of American Chemical Society; copying and redistribution for non-commercial research and education purposes only. The definitive version was published in ACS Nano 10 (2016): 6-37, doi:10.1021/acsnano.5b07826.
    Description: The microbiome presents great opportunities for understanding and improving the world around us and elucidating the interactions that compose it. The microbiome also poses tremendous challenges for mapping and manipulating the entangled networks of interactions among myriad diverse organisms. Here, we describe the opportunities, technical needs, and potential approaches to address these challenges, based on recent and upcoming advances in measurement and control at the nanoscale and beyond. These technical needs will provide the basis for advancing the largely descriptive studies of the microbiome to the theoretical and mechanistic understandings that will underpin the discipline of microbiome engineering. We anticipate that the new tools and methods developed will also be more broadly useful in environmental monitoring, medicine, forensics, and other areas.
    Description: This research was supported by the Office of Naval Research Grant #N000141410051 (P.S.W., G.C.L.W., and T.Y.), the Genomic Science Program of the U.S. DOE-OBER,
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 9
    Publication Date: 2022-05-26
    Description: © The American Chemical Society, 2016. This is an open access article published under an ACS AuthorChoice License. The definitive version was published in Analytical Chemistry 88 (2016): 7154–7162, doi:10.1021/acs.analchem.6b01260.
    Description: Discovery and identification of molecular biomarkers in large LC/MS data sets requires significant automation without loss of accuracy in the compound screening and annotation process. Here, we describe a lipidomics workflow and open-source software package for high-throughput annotation and putative identification of lipid, oxidized lipid, and oxylipin biomarkers in high-mass-accuracy HPLC-MS data. Lipid and oxylipin biomarker screening through adduct hierarchy sequences, or LOBSTAHS, uses orthogonal screening criteria based on adduct ion formation patterns and other properties to identify thousands of compounds while providing the user with a confidence score for each assignment. Assignments are made from one of two customizable databases; the default databases contain 14 068 unique entries. To demonstrate the software’s functionality, we screened more than 340 000 mass spectral features from an experiment in which hydrogen peroxide was used to induce oxidative stress in the marine diatom Phaeodactylum tricornutum. LOBSTAHS putatively identified 1969 unique parent compounds in 21 869 features that survived the multistage screening process. While P. tricornutum maintained more than 92% of its core lipidome under oxidative stress, patterns in biomarker distribution and abundance indicated remodeling was both subtle and pervasive. Treatment with 150 μM H2O2 promoted statistically significant carbon-chain elongation across lipid classes, with the strongest elongation accompanying oxidation in moieties of monogalactosyldiacylglycerol, a lipid typically localized to the chloroplast. Oxidative stress also induced a pronounced reallocation of lipidome peak area to triacylglycerols. LOBSTAHS can be used with environmental or experimental data from a variety of systems and is freely available at https://github.com/vanmooylipidomics/LOBSTAHS.
    Description: This research was supported by the Gordon and Betty Moore Foundation through Grant GBMF3301 to B.A.S.V.M. This research was also funded in part by a grant to B.A.S.V.M. from the Simons Foundation and is a contribution of the Simons Collaboration on Ocean Processes and Ecology (SCOPE). J.R.C. acknowledges support from a U.S. Environmental Protection Agency (EPA) STAR Graduate Fellowship (Fellowship Assistance Agreement No. FP-91744301-0).
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 10
    Publication Date: 2022-05-24
    Description: Pico, the youngest island of the Azores Archipelago (Portugal), is characterized by a central volcano and a 30-km-long fissure zone. Its eruption rate is the highest of the Azores islands, with more than 35 eruptions in the last 2000 years. Here, we estimate the lava-flow hazard for Pico Island by combining the vent opening probability derived from the spatial distribution of eruptive fissures, the classes of expected eruptions inferred from the physical and chemical characteristics of historical eruptions, and the lava-flow paths simulated by the MAGFLOW model. The most likely area to host new eruptions is along a WNW–ESE trend centred on the central volcano, with the highest hazard affecting the two main residential zones of Lajes do Pico and Madalena. Our analysis is the first attempt to assess the lava-flow hazard for Pico Island, and may have important implications for decision-making in territorial management and future land-use planning.
    Description: Published
    Description: 156-161
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: lava flow hazard ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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