ALBERT

Beschreibung: When cumulonimbus clouds aggregate, developing into a single entity with precipitation covering a horizontal scale of hundreds of kilometers, they are called mesoscale convective systems (MCSs). They account for much of Earth’s precipitation, generate severe weather events and flooding, produce prodigious cirriform anvil clouds, and affect the evolution of the larger-scale circulation. Understanding the inner workings of MCSs has resulted from developments in observational technology and modeling. Time–space conversion of ordinary surface and upper-air observations provided early insight into MCSs, but deeper understanding has followed field campaigns using increasingly sophisticated radars, better aircraft instrumentation, and an ever-widening range of satellite instruments, especially satellite-borne radars. High-resolution modeling and theoretical insights have shown that aggregated cumulonimbus clouds induce a mesoscale circulation consisting of air overturning on a scale larger than the scale of individual convective up- and downdrafts. These layers can be kilometers deep and decoupled from the boundary layer in elevated MCSs. Cooling in the lower troposphere and heating aloft characterize the stratiform regions of MCSs. As a result, long-lived MCSs with large stratiform regions have a top-heavy heating profile that generates potential vorticity in midlevels, thus influencing the larger-scale circulation within which the MCSs occur. Global satellite data show MCSs varying in structure, depending on the prevailing large-scale circulation and topography. These patterns are likely to change with global warming. In addition, environmental pollution affects MCS structure and dynamics subtly. Feedbacks of MCSs therefore need to be included or parameterized in climate models.

Beschreibung: The central change in understanding of the ocean circulation during the past 100 years has been its emergence as an intensely time-dependent, effectively turbulent and wave-dominated, flow. Early technologies for making the difficult observations were adequate only to depict large-scale, quasi-steady flows. With the electronic revolution of the past 50+ years, the emergence of geophysical fluid dynamics, the strongly inhomogeneous time-dependent nature of oceanic circulation physics finally emerged. Mesoscale (balanced), submesoscale oceanic eddies at 100-km horizontal scales and shorter, and internal waves are now known to be central to much of the behavior of the system. Ocean circulation is now recognized to involve both eddies and larger-scale flows with dominant elements and their interactions varying among the classical gyres, the boundary current regions, the Southern Ocean, and the tropics.

Beschreibung: Although atmospheric observing systems were already an important part of meteorology before the American Meteorological Society was established in 1919, the past 100 years have seen a steady increase in their numbers and types. Examples of how observing systems were developed and how they have enabled major scientific discoveries are presented. These examples include observing systems associated with the boundary layer, the upper air, clouds and precipitation, and solar and terrestrial radiation. Widely used specialized observing systems such as radar, lidar, and research aircraft are discussed, and examples of applications to weather forecasting and climate are given. Examples drawn from specific types of chemical measurements, such as ozone and carbon dioxide, are included. Sources of information on observing systems, including other chapters of this monograph, are also discussed. The past 100 years has been characterized by synergism between societal needs for weather observations and the needs of fundamental meteorological research into atmospheric processes. In the latter half of the period, observing system improvements have been driven by the increasing demands for higher-resolution data for numerical models, the need for long-term measurements, and for more global coverage. This has resulted in a growing demand for data access and for integrating data from an increasingly wide variety of observing system types and networks. These trends will likely continue.

Beschreibung: The polar regions present several unique challenges to meteorology, including remoteness and a harsh environment. We summarize the evolution of polar meteorology in both hemispheres, beginning with measurements made during early expeditions and concluding with the recent decades in which polar meteorology has been central to global challenges such as the ozone hole, weather prediction, and climate change. Whereas the 1800s and early 1900s provided data from expeditions and only a few subarctic stations, the past 100 years have seen great advances in the observational network and corresponding understanding of the meteorology of the polar regions. For example, a persistent view in the early twentieth century was of an Arctic Ocean dominated by a permanent high pressure cell, a glacial anticyclone. With increased observations, by the 1950s it became apparent that, while anticyclones are a common feature of the Arctic circulation, cyclones are frequent and may be found anywhere in the Arctic. Technology has benefited polar meteorology through advances in instrumentation, especially autonomously operated instruments. Moreover, satellite remote sensing and computer models revolutionized polar meteorology. We highlight the four International Polar Years and several high-latitude field programs of recent decades. We also note outstanding challenges, which include understanding of the role of the Arctic in variations of midlatitude weather and climate, the ability to model surface energy exchanges over a changing Arctic Ocean, assessments of ongoing and future trends in extreme events in polar regions, and the role of internal variability in multiyear-to-decadal variations of polar climate.

Beschreibung: The field of atmospheric science has been enhanced by its long-standing collaboration with entities with specific needs. This chapter and the two subsequent ones describe how applications have worked to advance the science at the same time that the science has served the needs of society. This chapter briefly reviews the synergy between the applications and advancing the science. It specifically describes progress in weather modification, aviation weather, and applications for security. Each of these applications has resulted in enhanced understanding of the physics and dynamics of the atmosphere, new and improved observing equipment, better models, and a push for greater computing power.

Beschreibung: Over the past century, the atmospheric and related sciences have seen incredible advances in our understanding of Earth’s environment and our ability to monitor and predict its behavior. These advances have had a profound impact on society and have been integrated into every aspect of daily life. The American Meteorological Society (AMS) has been instrumental in supporting these advances throughout its first 100 years of existence as a scientific and professional society serving the community of professionals in the atmospheric and related oceanic and hydrologic sciences. AMS has provided opportunities for researchers and practitioners to share their scientific findings and build fruitful collaborations to further the science and its application. Through strategic initiatives at key points in its history, AMS has pushed the science forward—highlighting areas ripe for development, creating frameworks for interdisciplinary interactions, and providing innovative approaches to the dissemination of research results. As a society made up of the scientific community and led by many of the most prominent scientists of their time, AMS has been able to respond to, and often anticipate, the needs of its community.

Beschreibung: A century ago, meteorologists regarded tropical cyclones as shallow vortices, extending upward only a few kilometers into the troposphere, and nothing was known about their physics save that convection was somehow involved. As recently as 1938, a major hurricane struck the densely populated northeastern United States with no warning whatsoever, killing hundreds. In the time since the American Meteorological Society was founded, however, tropical cyclone research blossomed into an endeavor of great breadth and depth, encompassing fields ranging from atmospheric and oceanic dynamics to biogeochemistry, and the precision and scope of forecasts and warnings have achieved a level of success that would have been regarded as impossible only a few decades ago. This chapter attempts to document the extraordinary progress in tropical cyclone research over the last century and to suggest some avenues for productive research over the next one.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): Alberto Pistocchi, Costanza Calzolari, Francesco Malucelli, Fabrizio Ungaro Study region The plains of Emilia Romagna, Italy. Study focus Urban expansion is among the main causes of increase in flood frequency and intensity in small rural catchments in Europe, and our study region is paradigmatic in this respect. We present here a regional screening-level assessment of soil sealing impacts in terms of increased flood peak discharges and flooding volumes on the secondary drainage network of the plains. We estimate flood peak discharges and flooding volumes through a simple kinematic model with runoff coefficients for the land use of 2008 and 1976. Additionally, we calculate an equivalent compensatory flood detention volume that would enable preserving flood peak discharges as prior to soil sealing (principle of “hydraulic invariance”). The proposed approach is simple and readily applicable to any region facing similar issues, for screening-level assessment of flood hazards over an extended stream network. New hydrological insights for the region The analysis highlights a significant increase in flood hazards throughout the secondary stream network. The impact. Widespread and relatively uniform, is more apparent in smaller catchments and in the case of more permeable soils. This demands retrofitting of the majority of the drainage network and/or significantly higher costs from flooding damages. The analysis suggests that costs of additional flooding after soil sealing may be higher than those of soil sealing impacts compensation through flood detention (hydraulic invariance).

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): M.A. Sarr, O. Seidou, Y. Tramblay, S. El Adlouni Study region The study considers six precipitation stations located in Senegal, West Africa. Senegal is located in the Sahel, an area that is threatened by climate variability and change. Both droughts and extreme rainfall have been an issue in recent years. Study focus Two different statistical downscaling techniques were applied to the outputs of four regional climate models at six selected precipitation stations in Senegal. First, the delta-change method was applied to the mean annual precipitation as well as the 5, 10, 20, 50 and 100-year return period daily precipitation events. Second, a quantile–quantile transformation (QQ) was used to downscale the monthly distributions of precipitation simulated by regional climate models (RCMs). The 5, 10, 20, 50 and 100-year daily precipitation events were afterward calculated. All extreme events were calculated assuming that maximum annual daily precipitations follow the generalized extreme value (GEV) distribution. The two-sided Kolmogorov–Smirnov (KS) test was finally used to assess the performance of the quantile–quantile transformation as well as the GEV distribution fit for the annual maximum daily precipitation. New hydrological insights for the region Results show that the two downscaling techniques generally agree on the direction of the change when applied to the outputs of same RCM, but some cases lead to very different projections of the direction and magnitude of the change. Projected changes indicate a decline in mean precipitation except for one RCM over one region in Senegal. Projected changes in extreme precipitations are not consistent across stations and return periods. The choice of the downscaling technique has more effect on the estimation of extreme daily precipitations of return period equal or greater than ten years than the choice of the climate models.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): J.S. Lessels, T.F.A. Bishop Study region South eastern Australia. Study focus This region is characterised with rainfall events that are associated with large exports of nutrients and sediments. Many water quality monitoring schemes use a form of event-based sampling to quantify these exports. Previous water quality studies that have evaluated different sampling schemes often rely on continuously monitored water quality data. However, many catchment authorities only have access to limited historical data which consists of event-based and monthly routine samples. Therefore there is a need to develop a method that assesses the importance of sampling events using information from limited historical data. This work presents a simulation based approach using unconditional simulation based on historical stream discharge. Such an approach offers site-specific information on optimal sampling schemes. A linear mixed model is used to model the relationship between total phosphorus and stream discharge and the auto-correlation of total phosphorus. New hydrological insights for the region The inclusion of event-based sampling improved annual load estimates of all sites with a maximum RMSE difference of 16.11 tonnes between event-based and routine sampling. Based on the accuracy of annual loads, event-based sampling was found to be more important in catchments with a large relief and high annual rainfall in this region. Using this approach, different sampling schemes can be compared based on limited historical data.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): Hayet Chihi, Ghislain de Marsily, Habib Belayouni, Houcine Yahyaoui Study region “Jeffara de Medenine” aquifer system in south-eastern Tunisia. Study focus This study investigates the role of fault structures in the distribution of hydrogeochemical facies and groundwater compartmentalization for the aquifer system. New hydrological insights for the region The proposed methodology, including seismic structural study, hierarchical cluster analysis and geostatistical methods, allowed an efficient multi-element characterization of the spatial patterns of the structural elements in the aquifers and of the hydrogeological parameters used in a spatial cross-correlation to explore the dependence of the geochemical properties in each “geochemical population” on the hosting structural compartment to delineate the different geochemical compartments. The tectonic studies showed that the lateral extent of the aquifers is controlled by normal faults. The multivariate statistical analysis revealed a strong spatial coherence between hydrogeochemical facies clustering and the reservoir compartments at both large and small scales. The kriged maps of major-ion concentrations and of total dissolved solids in the aquifers were then analyzed and compared with the reservoir facies distribution for each compartment, the geometric characteristics of the aquifer, and the piezometric level trends. This allowed to characterize the hydraulic behavior of the Medenine fault and to understand the underlying physical and chemical processes having led to the spatial distribution of the geochemical properties, and thus, the hydrogeochemical functioning of the aquifers.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): Marnie L. Atkins, Isaac R. Santos, Damien T. Maher Study region This study investigates dissolved methane distribution in groundwater from the Richmond River Catchment (New South Wales, Australia) before proposed coal seam gas (CSG, or coal bed methane) development. Study focus Unconventional gas exploration has rapidly expanded in recent years. However, the impact of these operations on groundwater systems is poorly understood. A total of 91 groundwater samples were analyzed from 6 geological units. Our observations act as regional baseline research prior to CSG extraction and may assist with long term impact assessment. New hydrological insights for the region Methane was found in all geological units ranging between 0.26 and 4427 μg L −1 (median 10.68 μg L −1 ). Median methane concentrations were highest in chloride-type groundwater (13.26 μg L −1 , n = 58) while bicarbonate-type groundwater had lower concentrations (3.71 μg L −1 ). Groundwater from alluvial sediments had significantly higher median methane concentrations (91.46 μg L −1 ) than groundwater from both the basalt aquifers (0.7 μg L −1 ) and bedrock aquifers (4.63 μg L −1 ); indicating geology was a major driver of methane distribution. Methane carbon stable isotope ratios ranged from –90.9‰ to –29.5‰, suggesting a biogenic origin with some methane oxidation. No significant correlations were observed between methane concentrations and redox indicators (nitrate, manganese, iron and sulphate) except between iron and methane in the Lismore Basalt ( r 2 = 0.66, p 〈 0.001), implying redox conditions were not the main predictor of methane distribution.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): Z. Zomlot, B. Verbeiren, M. Huysmans, O. Batelaan Study focus Groundwater is of strategic importance. The accurate estimation of groundwater recharge and assessing the fundamental controlling factors are therefore of utmost importance to protect groundwater systems. We used the spatially-distributed water-balance model WetSpass to estimate long-term average recharge in Flanders. We validated recharge rates with base flow estimates of 67 daily stream flow records using the hydrograph analyses. To this end we performed principal component analysis, multiple linear regression analysis and relative importance analysis to assess the controlling factors of the spatial variation of recharge and base flow with the influencing watershed characteristics. New hydrological insights for the region The average resulting recharge is 235 mm/year and occurs mainly in winter. The overall moderate correlation between base flow estimates and modeled recharge rates indicates that base flow is a reasonable proxy of recharge. Groundwater recharge variation was explained in order of importance by precipitation, soil texture and vegetation cover; while base flow variation was strongly controlled by vegetation cover and groundwater depth. The results of this study highlight the important role of spatial variables in estimation of recharge and base flow. In addition, the prominent role of vegetation makes clear the potential importance of land-use changes on recharge and hence the need to include a proper strategy for land-use change in sustainable management of groundwater resources.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): B. Ibrahim, D. Wisser, B. Barry, T. Fowe, A. Aduna Study region Hydrological observation networks in the West African region are not dense and reliable. Furthermore, the few available discharge data often present significant gaps. The Volta basin, the second largest transboundary basin in the region, is a typical example of a basin with inadequate hydrological networks. Study focus In this study, a prediction approach to determine monthly discharge in ungauged watersheds is developed. The approach is based on the calibration of two conceptual models for gauged watersheds and an estimation of models’ parameters from the physical and climatic characteristics of the watersheds. The models’ parameters were determined for each ungauged watershed through two different methods: the multiple linear regressions and the kriging method. The two methods were first validated on five gauged watersheds and then applied to the three ungauged watersheds. New hydrological insights for the region The application of the two hydrological models on the eight watersheds helped to produce relevant monthly runoff and to establish the annual hydrological balances from 1970 to 2000 for both gauged and ungauged watersheds. The developed method in this study could therefore help estimate runoff time series, which are of crucial importance when it comes to design hydraulic structures such as small reservoirs.

Beschreibung: Publication date: Available online 14 August 2015 Source: Journal of Hydrology: Regional Studies Author(s): Mayank Shekhar, Amalava Bhattacharyya Study region Zemu Chuu (river), Lachen, North Sikkim, Eastern Himalaya India. Study focus Using tree-ring data of fir ( Abies densa ) the temporal variation of 222 years January–April mean discharge of Zemu Chuu, upper reaches of the Teesta River at Lachen, North Sikkim Eastern Himalaya was investigated. This was based on linear regression reconstruction model which explained variance of 50.1% during calibration period (AD 1976–1996). The model was verified by reduction of error (RE), sign test (ST), product mean test (Pmt), root mean square error (RMSE) and Durbin–Watson test (DW). The RE never falls below zero suggesting the model had explanatory power over the entire period of reconstruction. New hydrological insights for the region The explored strong relationship between tree ring records and instrumental data enable to develop mean January–April months (premonsoon) river discharge of Zemu Chuu from remote area of Sikkim. Reconstructed data reveals high stream-flow when it is more than the mean plus one standard deviation and as low when flow is less than the mean minus one standard deviation. There were such 23 high discharge and 21 extremely low years over the past AD 1775–1996. This premonsoon reconstruction of river flow would be of great significance when scarcity of water is acute in the North East Himalaya.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): Jonathan A. Warrick, John M. Melack, Blair M. Goodridge Study region Coastal watersheds of southern California, United States. Study focus We sought to better understand the rates and variability of suspended-sediment discharge from small coastal watersheds (〈100 km 2 ) of California. Suspended-sediment concentrations and stream discharge were measured with automated samplers near the mouths of four small watersheds (10–56 km 2 ). New hydrological insights for the region The watersheds were found to have suspended-sediment concentrations that extended over five orders of magnitude (1 to over 100,000 mg L −1 ). Sediment concentrations were weakly correlated with discharge ( r 2 = 0.10–0.25), and four types of hysteresis patterns were observed during high flow events (clockwise, counterclockwise, no hysteresis, and complex). Annual sediment yields varied by 400-fold across the four watersheds (e.g., 5–2100 t km −2 yr −1 during the 2003–2006 water years), and sediment discharge was measurably elevated in one watershed that was partially burned by a late summer wildfire. Dozens of high flow events provided evidence that suspended-sediment yields were generally related to peak stream discharge and event-based precipitation, although these relationships were not consistent across the watersheds. This suggests that watersheds smaller than 100 km 2 can provide large – and therefore important – fluxes of sediment to the coast, but that simple techniques to estimate sediment loads, such as sediment rating curves, hydrologic regressions, and extrapolation using global sediment yield relationships that include watershed area as a primary factor, may provide poor results. Graphical abstract

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): Chris C. Gianfagna, Chris E. Johnson, David G. Chandler, Charlie Hofmann Study region The Catskills region of New York State is largely forested and dominated hydrologically by stream watersheds with few natural lakes. The area experiences intensive water resources management and ecosystem monitoring due to its strategic role as the principal water supply for New York City. Study focus We analyzed average daily flows in nested and non-nested pairs of gaged watersheds in the Catskills to assess whether daily flow in ungaged watersheds can be calculated based on watershed area ratios. New hydrological insights for the region Watershed area ratio was the most important basin parameter for estimating flow at upstream sites based on downstream flow. The area ratio alone explained 93% of the variance in the slopes of relationships between upstream and downstream flows. Regression analysis indicated that flow at any upstream point can be estimated by multiplying the flow at a downstream reference gage by the watershed area ratio. This method accurately predicted upstream flows at area ratios as low as 0.005. We also observed a very strong relationship ( R 2 = 0.79) between area ratio and flow–flow slopes in non-nested catchments. Our results indicate that a simple flow estimation method based on watershed area ratios is justifiable, and indeed preferred, for the estimation of daily streamflow in ungaged watersheds in the Catskills region.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): Alfonso Rivera Study region Canada–USA border. Study focus Since 2005, Canada has followed international developments in transboundary groundwater issues in cooperation with its southern neighbor the United States (USA) within the Internationally Shared Aquifer Resources Management Initiative (ISARM) of UNESCO. As a result, 10 Transboundary Aquifer Systems (TAS) were identified along the border between Canada and the USA. This study is an extensive review of the current state of the 10 TAS. Documentation of scientifically-based knowledge on TAS is an important step in identifying potential issues in policies that might be adopted to address shared water-resource issues. New hydrological insights for the region This analysis emphasizes the need for more scientific data, widespread education and training, and a more clearly defined governments’ role to manage groundwater at the international level. The study reviews the current legal framework and summarises the current scientific knowledge for the TAS with respect to the hydrologic and geologic framework as well as some of the major drivers for supply and demand. It also describes the links, approach and relevance of studies on the TAS to the UN Law of Transboundary Aquifers and on how these might fit in the regional strategy for the assessment and management of the TAS. Clear communication, shared knowledge and common objectives in the management of TAS will prepare the countries for future negotiations and cooperative binational programs.

Beschreibung: Publication date: September 2015 Source: Journal of Hydrology: Regional Studies, Volume 4, Part B Author(s): Brioch Hemmings, Daren Gooddy, Fiona Whitaker, W. George Darling, Alia Jasim, Joachim Gottsmann Study region Montserrat, Lesser Antilles, Caribbean. Study focus Analysis of δ 2 H and δ 18 O isotopes, and chlorofluorocarbon (CFC) anthropogenic tracers in Montserrat groundwater provides insights into the age and provenance of the spring waters. New hydrological insights δ 2 H and δ 18 O analysis indicates uniform recharge elevations for groundwaters on Montserrat. CFC-11 and CFC-12 analysis reveals age differences between isotopically similar, high elevation springs and low elevation aquifer waters. Low CFC concentrations within a confined low elevation aquifer suggest water ages of ∼45 years. High CFC concentrations in the northern and western springs are explained by rapid infiltration of cool (high CFC concentration) rainfall into saturated compartments, with flow through the vadose zone to the phreatic zone dominated by compartment flow. Lower CFC concentrations in a number of aligned warmer springs suggest a contribution from older, warmer waters from depth. Temperatures and CFC concentrations indicate older component supply rates of up to 8 L/s to the highest yielding spring on Centre Hills, with contributions of up to 75% in the warmest spring waters.

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1

Beschreibung: Publication date: Available online 3 April 2015 Source: Journal of Hydrology: Regional Studies Author(s): A. Shahul Hameed , T.R. Resmi , S. Suraj , C. Unnikrishnan Warrier , M. Sudheesh , R.D. Deshpande Study region The Chaliyar river basin, Kerala State, India. Study focus Detailed understanding about spatio-temporal variation in the interaction and exchange of water between surface and sub-surface reservoirs is important for effective watershed management. Spatio-temporal variations in the oxygen isotopic composition ( δ 18 O) were used to understand the interaction between groundwater and river water, and to estimate the groundwater recharge from river water in the Chaliyar river basin. New hydrological insights for the region Based on the spatio-temporal variation in δ 18 O values of river and groundwater and fluctuation in ground water levels, following important inferences are made: (1) estimated river water contribution to post-monsoon groundwater recharge is ∼16% in the lowland coastal area of the Chaliyar river basin and 29% in midland region; (2) northeast winter monsoon rains contribute to the groundwater of Chaliyar river basin only in an insignificant manner, and with a delayed response; (3) unlike river water samples which exhibit both seasonal and spatial variation of more than 3‰, the groundwater samples vary only marginally (∼1‰) between the seasons and across the physiographic zones; (4) groundwater samples exhibit inverse altitude gradient in δ 18 O values in the highland zone, in all the three seasons. This may be due to flow of the isotopically depleted groundwater down the gradient and evaporation of residual water in the upper reaches of the basin.

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1 Author(s): Ashish Sharma

Beschreibung: Publication date: Available online 16 May 2015 Source: Journal of Hydrology: Regional Studies Author(s): E.H. Elias , A. Rango , C.M. Steele , J.F. Mejia , R. Smith Study region Upper Rio Grande, Colorado and New Mexico, USA. Study focus Climate change is predicted to further limit the water availability of the arid southwestern U.S. We use the snowmelt runoff model to evaluate impacts of climate change on snow covered area (SCA), streamflow timing and runoff volume. Simulations investigate four future conditions using models downscaled to existing climate stations. Twenty-four subbasins of the Upper Rio Grande containing appreciable snowmelt and a long-term gauging station are simulated. New hydrological insights for the region Future annual volume is 193–204 million m 3 more to 448–476 million m 3 less than the pre-climate change value of 2688 million m 3 . There is disparity between increased volume in wetter simulations (+7%) and decreased volume (−18%) in drier simulations. SCA on 1 April reduced by approximately 50% in all but the warmer/wetter climate. Peak flow is 14–24 days early in the future climates. Among the 24 subbasins there is considerable range in mean melt season SCA (−40% to −100%), total volume change (−30% to +57%) and runoff timing advancement indicating that climate change is best evaluated at the subbasin scale. Daily hydrographs show higher streamflow in March and April, but less from mid-May until the end of the water year. The large decrease in volume in May, June and July will compound water management challenges in the region.

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1 Author(s): Mohammad Kamruzzaman

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3 Author(s): Jean-Michel Lemieux , Jalil Hassaoui , John Molson , René Therrien , Pierre Therrien , Michel Chouteau , Michel Ouellet Study region This study is conducted in the Magdalen Islands (Québec, Canada), a small archipelago located in the Gulf of St. Lawrence. Study focus This work was undertaken to support the design of a long-term groundwater monitoring network and for the sustainable management of groundwater resources. This study relies mostly on the compilation of existing data, but additional field work has also been carried out, allowing for the first time in the Magdalen Islands, direct observation of the depth and shape of the transition zone between freshwater and seawater under natural conditions. Simulations were conducted along a 2D cross-section on Grande Entrée Island in order to assess the individual and combined impacts of sea-level rise, coastal erosion and decreased groundwater recharge on the position of the saltwater–freshwater interface. The simulations were performed considering variable-density flow and solute transport under saturated-unsaturated conditions. The model was driven by observed and projected climate change scenarios to 2040 for the Magdalen Islands. New hydrological insights for the region The simulation results show that among the three impacts considered, the most important is sea-level rise, followed by decreasing groundwater recharge and coastal erosion. When combined, these impacts cause the saltwater–freshwater interface to migrate inland over a distance of 37 m and to rise by 6.5 m near the coast to 3.1 m further inland, over a 28-year period.

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3 Author(s): M.A. Pascolini-Campbell , Richard Seager , David S. Gutzler , Benjamin I. Cook , Daniel Griffin Study region The Gila River, New Mexico, is characterized by two peaks in streamflow: one in the winter–spring (December–May), and summer (August–September). The region is influenced both by Pacific SST variability as well as the North American Monsoon. Study focus The mechanisms responsible for the variability of the winter–spring and summer streamflow peaks are investigated by correlation of streamflow with precipitation and sea surface temperature for 1928–2012. Decadal variability in the flow record is examined for a longer term perspective on Gila River streamflow using tree ring-based reconstructions of the Palmer Drought Severity Index (PDSI) and the Standardized Precipitation Index (SPI). New hydrological insights for the region Results indicate a strong influence of winter–spring precipitation and Pacific SST anomalies on the winter–spring streamflow, with El Niño conditions in the Pacific causing increased precipitation and streamflow. Decadal Pacific variability helps explain the transition from high winter flow in the late 20th century to lower flows in the most recent decade. The summer streamflow has a somewhat weaker correlation with precipitation and Pacific SST than the winter–spring streamflow. Its variability is more likely influenced by local North American Monsoon precipitation variability. PDSI and SPI reconstructions indicate much more severe and extended periods of droughts and pluvials in past centuries as well as periods of concurrent winter and summer drought.

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3 Author(s): Tsou Jaw , Jialun Li , Kuo-lin Hsu , Soroosh Sorooshian , Fatima Driouech Study region Morocco (excluding Western Sahara). Study focus This study evaluated Moroccan precipitation, dynamically downscaled (0.18-degree) from three runs of the studied GCM ECHAM5/MPI-OM, under the present-day (1971–2000/20C3M) and future (2036–2065/A1B) climate scenarios. The spatial and quantitative properties of the downscaled precipitation were evaluated by a verified, fine-resolution reference. The effectiveness of the hydrologic responses, driven by the downscaled precipitation, was further evaluated for the study region over the upstream watershed of Oum er Rbia River located in Central Morocco. New hydrological insights for the region The raw downscaling runs reasonably featured the spatial properties but quantitatively misrepresented the mean and extreme intensities of present-day precipitation. Two proposed bias correction approaches, namely stationary Quantile-Mapping (QM) and non-stationary Equidistant CDF Matching model (EDCDFm), successfully reduced the system biases existing in the raw downscaling runs. However, both raw and corrected runs projected great diversity in terms of the quantity of future precipitation. Hydrologic simulations performed by a well-calibrated Variable Infiltration Capacity model successfully reproduced the present-day streamflow. The driven flows were identified highly correlated with the effectiveness of the downscaled precipitation. The future flows were projected to be markedly diverse, mainly due to the varied precipitation projections. Two of the three flow simulation runs projected slight to severe drying scenarios, while another projected an opposite trend for the evaluated future period.

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3 Author(s): Megersa Olumana Dinka , Willibald Loiskandl , Julius Musyoka Ndambuki Study region The Matahara region is located in the East Showa zone of Oromiya regional state (Ethiopia). Matahra Sugar Estate and Lake Basaka (highly saline, alkaline and sodic lake) are situated within the flat plains of Matahara region. The area is vulnerable to the occurrences of various tectonic and volcanic activities due to its location in the upper most part of the Main Ethiopian Rift Valley region. Study focus In this study, the hydrochemical properties of different surface water and groundwater bodies available at Matahara region have been characterized for quality compositions. Water samples were collected from different water sources and analyzed for important major quality parameters following standard test procedures. Other chemical indices were derived from the measured quality parameters. The potential sources of minerals were suggested for each of the considered water sources based on their quality characteristics. New hydrological insights for the region Overall, the study result elucidates that the chemical composition of different water bodies are due to natural processes and/or anthropogenic activities within the region. The local anthropogenic processes could be discharges from factory, domestic sewage and farming activities. Some of the water types are found to have relatively higher concentration of dissolved constituents. Irrigation waters have almost equal chemical compositions, indicating their hydrochemical sources are almost the same. Most of the concentrations are relatively high in Lake Basaka, groundwater and hot springs. It is easy to imagine the potential damaging effects of such quality waters on crop production, soil properties and environment of the region.

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3 Author(s): Julianne Hagarty , David Azanu , Bernadette Atosona , Ray Voegborlo , Erica A.H. Smithwick , Kamini Singha Study region Buruli ulcer, an emerging disease caused by Mycobacterium ulcerans , largely affects poor rural populations in tropical countries. The environmental niche that supports this necrotizing bacterium is unclear. Here, water samples were collected from five communities within Ghana in the rainy season in 2011: four in the southern part of Ghana (three disease-endemic communities: Pokukrom, Betenase, and Ayanfuri, and one control: Kedadwen) and one non-endemic community (Nangruma) in the north. Study focus Past studies of Buruli ulcer conclude that water quality is, in some way, closely related to the transmission of this disease. This work serves as a first step to explore links between Buruli ulcer incidence and water quality. More broadly, this research works toward identifying the environmental niche for M. ulcerans , providing characterization of water bodies hazardous to human health in at-risk communities. New hydrological insights Trace metals, thought to aid in the preferential growth of M. ulcerans , are present in higher concentrations in mining pits and stagnant pools than in other tested water bodies. Arsenic in particular could serve as a double threat for BU incidence: it could support the growth of M. ulcerans while suppressing immune systems, making the population more susceptible to disease. Few other differences between endemic and non-endemic communities exist, implying other variables such as human behavior may also control the onset of Buruli ulcer.

Beschreibung: Publication date: April–June 2015 Source: Geofísica Internacional, Volume 54, Issue 2 Author(s): Hugo G. Nami Paleomagnetic data from three sedimentary sections in Pichincha province -Quito City (QC), Mullimica (Mu) and El Tingo (ET)- Ecuador (northwestern South America) are reported. Analysis of natural remanent magnetization directions obtained from 109 oriented samples taken at 4 sites, shows that some samples recorded a magnetic component different from the normal present geomagnetic field (GMF). The characteristic remanent magnetization (ChRM) was determined by progressive AF demagnetization. The analysis shows that the sections recorded ChRM of normal, intermediate and reverse polarities during the Pleistocene-Holocene transition and Holocene. Normal directions were recorded in QC, while normal and intermediate polarity directions at Mu and, reverse VGPs at ET. QC and the upper portion of Mu correspond to the paleosecular variation Holocene record for Ecuador during the ∼≤4.7 ka BP. On the other hand, the lower portion of Mu logs represents the transition from normal to intermediate directions occurring at ∼≥5.6 ka BP. Sites from ET recorded two stable oblique reverse records with a large fluctuation far from the present GMF at ∼10.5 ka BP. The transitional virtual geomagnetic poles generally agree with those registered during the possible Pleistocene-Holocene excursion observed in other places of the planet. When plotted in a present world map, VGPs calculated from normal samples at QC are very well clustered in Northern North America, Greenland and Northern Europe; most VGP's calculated from Mu are situated between 30° and 60° northern latitude in Northern North America, Greenland, western Europe, Africa and North Pacific Ocean. Interestingly, the majority of the reverse directions from ET conforms a patch located in southern Africa, and a few ones are situated in central Africa, eastern Australia and Antarctica. An Ecuadorian paleopole was calculated with data resulting from QC and Mu. Also other paleopoles of the same age were processed from other North and South American sites. Remarkably they agree well, although they do not agree with the geographical pole showing ∼15 o angular difference in relation to the rotation's axis of the Earth. Finally, is discussed the hypothesis of the global excursional state of the GMF during the last ∼11.0 ka BP and the potential use as dating tool the excursion dated at 10.5 ka BP.

Beschreibung: Publication date: April–June 2015 Source: Geofísica Internacional, Volume 54, Issue 2 Author(s): Miguel Cervantes Solano , Avto Goguitchaichvili , Mabel Mena , Luis Alva-Valdivia , Juan Morales Contreras , Ruben Cejudo Ruiz , Héctor López Loera , Ana María Soler , Jaime Urrutia-Fucugauchi A detailed paleomagnetic and rock magnetic investigation has been carried out on the Early Cretaceous Ponta Grossa dike swarm in southern Brazil. This formation seems an excellent target for paleomagnetic study. The dikes are widely distributed over a large area, easy to access, and they record faithfully the geomagnetic field at the time of the eruption. Most of them are fresh and have been dated by K-Ar and Ar-Ar. Thermomagnetic experiments (low-field versus temperature curves) suggest low-Ti titanomagnetites as main remanence carriers, and their domain structure is characterised by a mixture of single-domain and multi-domain grains. Characteristic paleomagnetic directions are retrieved from 28 out of 29 sites (235 standard paleomagnetic cores). 17 sites show normal polarity, 10 sites show reverse polarity and one site shows an oblique direction, with negative inclination, separated 79° of the mean normal directions. The reversal test is positive at the 95% confidence level which ensures that the secondary remanent magnetizations were successfully removed and the sampling adequately averaged the palaeosecular variation. The paleosecular variation parameters values obtained in this study correlate with those determined for the Cretaceous Normal Superchron, between 125 to 84 Ma. The new paleomagnetic pole position (222.0° E, 88.1° S, N = 24, K = 35.68, A 95 = 5.0°) agrees well (within uncertainties) with the reference poles determined from Besse and Courtillot (2002) , and disagree with those reported in previous studies. The new results should be considered for estimating the Cretaceous paleomagnetic poles for stable South America.

Beschreibung: Publication date: January–March 2015 Source: Geofísica Internacional, Volume 54, Issue 1 Author(s): V. Chakravarthi , M. Pramod Kumar An inversion algorithm is developed to simultaneously estimate the fault plane geometry and the parameters pertaining to either densities or depths of multiple geologic formations within the hanging wall system of a strike-limited listric fault from the observed gravity anomalies. Fault planes of the structures are described by polynomial functions of arbitrary but specific degree. The applicability of the algorithm is demonstrated on both synthetic and real field gravity anomalies. In the synthetic example, pseudorandom noise is added to the gravity anomalies of the structure prior to inversion. From the inversion of gravity anomalies produced by a synthetic structure it was found that the estimated parameters more or less mimic the true parameters even in the presence of random noise. The estimated densities and depths of the formations from independent inversion of real-world gravity anomalies from the margin of the Chintalpudi sub-basin in India correlate well with the available drilling information.

Beschreibung: Publication date: January–March 2015 Source: Geofísica Internacional, Volume 54, Issue 1 Author(s): Efraín Ovando Shelley , Vanessa Mussio , Miguel Rodríguez , José G. Acosta Chang In this paper we describe how some techniques for estimating shallow shear wave velocity profilesobtainedfrommeasurementsofambient vibrations and from artificially generated waves can be used to assess sand liquefaction potential. The measurements are easy, quick and more economical than most other methods. The passive Microtremor Analysis Method (MAM) and the active Multichannel Analysis of Surface Waves (MASW) have only recently been adopted for liquefaction studies. We propose a method that was applied in the valley of Mexicali to characterize soil in terms of shear wave velocity to assess liquefaction potential; our results display its advantages.

Beschreibung: Publication date: January–March 2015 Source: Geofísica Internacional, Volume 54, Issue 1 Author(s): Akhtar Malik Muhammad , Tang Zhonghua , Ammar Salman Dawood , Bailey Earl Groundwater vulnerability assessment shows an extreme sensitivity to in situ anthropogenic pollutants. A dichotomous assessment of geological and hydrological (inter alia) characteristics makes it possible to determine the vulnerability of an aquifer. The natural carrying capacity of aquifer can be severely compromised by human activities. The physical structure and material composition of aquifers shows resistance to contaminants transport from surface to water-table. Currently, numerous methods have been posited evaluating aquifer's vulnerability. Similarly the DRASTIC model utilizes computer algorithms and hydro-geological data within a Geographical Information System (GIS) environment to compute aquifer vulnerability. The degree of vulnerability for each parameter can be evaluated by computing sensitivity analysis of DRASTIC index using GIS, showing the contribution of each parameter to vulnerability sensitivity. The GIS was used to developed map which showed high risk area of 28.8% and moderately vulnerable areas of 46.3% while areas of no risk were 10.4%. Central regions within the study area showed low vulnerability due to dense human settlement and low water level. However, pasture type lands and agricultural areas recorded high risk. Lahore's environmental and socio-economic development is dependent on policy makers and planner's ability to use information effectively for decision making. The resultant groundwater vulnerability map provides a basis for this aimed at protecting the aquifer from pollutants. Additionally, land use and development activities can be informed by mapping variables, showing that industrial and agriculture areas are highly vulnerable as compare to settlement areas.

Beschreibung: Publication date: Available online 18 April 2015 Source: Journal of Hydrology: Regional Studies Author(s): Fabrice Papa , Frédéric Frappart , Yoann Malbeteau , Mohammad Shamsudduha , Venugopal Vuruputur , Muddu Sekhar , Guillaume Ramillien , Catherine Prigent , Filipe Aires , Rajesh Kumar Pandey , Sujit Bala , Stephane Calmant Study region The Ganges–Brahmaputra (GB), a major river basin of the Indian Sub-Continent (ISC), is the host of more than 700 millions people. Study focus In addition to monsoons and strong climate variability, GB is facing growing demands for freshwater availability by a continually growing population and rapidly developing of agricultural and industrial sectors. The management of water resources is thus of highest priority and, in the context of current over-abstraction of groundwater, accurate estimates of terrestrial freshwater storage are essential. We propose a multi-satellite approach to estimate surface freshwater storage (SWS) and subsurface water storage (SSWS, groundwater + soil moisture) variations over GB. New hydrological insights Basin-scale monthly SWS variations for the period 2003–2007 show a mean annual amplitude of ∼410 km 3 , contributing to about 45% of the Gravity Recovery And Climate Experiment (GRACE)-derived total water storage variations (TWS). During the drought-like conditions in 2006, we estimate that the SWS deficit over the entire GB basin in July–August–September was about 30% as compared to other years. The SWS variations are then used to decompose the GB GRACE-derived TWS and isolate the variations of SSWS whose mean annual amplitude is estimated to be ∼550 km 3 . This new dataset of water storage variations represent an unprecedented source of information for hydrological and climate modeling studies of the ISC.

Beschreibung: Publication date: Available online 7 April 2015 Source: Journal of Hydrology: Regional Studies Author(s): Swati Verma , Abhijit Mukherjee , Runti Choudhury , Chandan Mahanta Study region Brahmaputra River basin, India. Study focus The present study deciphers the groundwater solute chemistry and arsenic (As) enrichment in the shallow aquifers of the study region. Four different geomorphologic units, e.g. piedmont (PD), older alluvium of river Brahmaputra and its tributaries (OA), active alluvium of river Brahmaputra and its tributaries (YA) and river channel deposits (RCD) were identified. More than 62% of all groundwater samples collected have dissolved As >0.01 mg/L, whereas about 87% of groundwater samples in OA terrain are enriched with As, which draws a distinct difference from the adjoining Gangetic aquifers. New hydrological insights for the region Most groundwater solutes of RCD and YA terrains were derived from both silicate weathering and carbonate dissolution, while silicate weathering process dominates the solute contribution in OA groundwater. Groundwater samples from all terrains are postoxic with mean pe values between Fe(III) and As(V)–As(III) reductive transition. While, reductive dissolution of (Fe–Mn)OOH is the dominant mechanism of As mobilization in RCD and YA aquifers, As in OA and PD aquifers could be mobilized by combined effect of pH dependent sorption and competitive ion exchange. The present study focuses on the major ion chemistry as well as the chemistry of the redox sensitive solutes of the groundwater in different geomorphic settings and their links to arsenic mobilization in groundwater.

Beschreibung: Publication date: Available online 11 March 2015 Source: Journal of Hydrology: Regional Studies Author(s): B.M. Hallett , H.A. Dharmagunawardhane , S. Atal , E. Valsami-Jones , S. Ahmed , W.G. Burgess Study region The Maheshwaram and Waipally catchments of Andhra Pradesh, India, and the Plonnaruwa catchment of north-central Sri Lanka. Study focus The distribution of F across eight crystalline phases and between the bedrock and the regolith at eleven sites in three catchments is documented. Mineral contributions to F release during weathering and regolith development are quantified. New hydrological insights for the region An estimate of weathering duration for the in situ regolith in Andhra Pradesh, 250–380 Ka, is close to a previous estimate for southern India. Partial or total destruction of the primary F-bearing bedrock minerals and consistent depletion of F in the remnant minerals result in a much reduced total F content in the regolith. Leaching experiments and field relationships, however, indicate a greater potential for F mobilisation to groundwater from the regolith than the bedrock. Schemes for managed aquifer recharge should beware the risk of mobilising additional F to groundwater.

Beschreibung: Publication date: March 2015 Source: Journal of Hydrology: Regional Studies, Volume 3, Supplement 1 Author(s): Salah Er-Raki

Beschreibung: Publication date: Available online 10 December 2015 Source: Journal of Hydrology: Regional Studies Author(s): Tatsuya Utsunomiya, Masaki Hata, Ryo Sugimoto, Hisami Honda, Shiho Kobayashi, Yoji Miyata, Makoto Yamada, Osamu Tominaga, Jun Shoji, Makoto Taniguchi Study focus There have been far more studies on how the variability in surface water discharge affects production of animal communities in aquatic ecosystems while less information has been accumulated on the mechanisms of how the groundwater supply works. Study region Physical and biological surveys were conducted to test the hypothesis that high level of submarine ground water discharge enhances species richness, abundance and biomass of fishes and invertebrates in coastal waters of Obama Bay, Japan, where a high contribution of nutrients (ca. 65% of phosphorus) to total provided through all freshwater has been reported. Survey for horizontal distribution of radon-222 ( 222 Rn) concentration showed high levels of submarine groundwater discharge in the west part of survey area. Fish and invertebrate communities were compared within a relatively small spatial scale (ca. 100 m) in relation to level of submarine groundwater discharge. New hydrological insights Species richness, abundance and biomass of fishes and abundance and biomass of turban snail and hermit crab were significantly higher in the area with high 222 Rn concentration. Abundance of gammarids, the most major prey item of the fishes, was 18 times higher in the area with high 222 Rn concentration. Since the turban snail, hermit crab and gammarids feed on producers (phytoplankton and benthic microalgae), submarine groundwater are concluded to increase species richness and production of fishes and invertebrates through providing nutrients and enhancing primary production.

Beschreibung: Publication date: March 2016 Source: Journal of Hydrology: Regional Studies, Volume 5 Author(s): A.C. de la Casa, G.G. Ovando Study region Changes in reference evapotranspiration (ET o ) may have important consequences for agricultural suitability in the central region of Argentina. Annual ET o variation was assessed, in terms of both territory and time, for the 7 decades between 1941 and 2010, analyzing the behavior of the 4 atmospheric variables which determine it: temperature, vapor pressure, wind speed and cloud cover. Study focus The influence of each variable on ET o was evaluated from a multiple regression model and a simple correlation analysis, using climate data from the observation network, and repeating this analysis using interpolated variables. In this grid scheme, linear relationships were determined between ET o and the different key atmospheric variables, plus precipitation (PP), and the t test was applied to establish the statistically significant sectors ( P 〈 0.1). Then, those areas with a significant trend change ( P 〈 0.1) were determined by the Mann–Kendall test. Finally, the interception of the grids was performed to establish their joint occurrence. New hydrological insights for the region Most of the region analyzed (>91%) presents a non-significant variation of ET o over time, with a mostly non-significant change of each driving variable, regarding both its relationship with ET o and its own trend of change. The beneficial change in agricultural suitability reported for this water-limited region was found to be produced almost exclusively by increasing PP. Graphical abstract

Beschreibung: Publication date: Available online 11 December 2015 Source: Journal of Hydrology: Regional Studies Author(s): Makoto Taniguchi, Naoki Masuhara, Kimberly Burnett Security measures of three resources; water, energy and food are analyzed for thirty two countries in the Asia Pacific region which are faced to Pacific Ocean, in terms of amounts of the resource, self-production, and diversity of sources of each resource. Diversity for all the three resources is also analyzed using surface water and groundwater for water sources; hydro power, geothermal power, solar, and biomass for energy; and cereals, vegetable, fruit, meat, and fish for food. We see high diversity of sources of water in the US and the Philippines, and a low diversity of sources of food in the US, Canada, and Indonesia. These security measures including water security show new hydrological insight for Asia-Pacific region.

Beschreibung: Publication date: Available online 10 December 2015 Source: Journal of Hydrology: Regional Studies Author(s): Aiko Endo, Izumi Tsurita, Kimberly Burnett, Pedcris M. Orencio Study region Asia, Europe, Oceania, North America, South America, Middle East and Africa. Study focus The purpose of this paper is to review and analyze the water, energy, and food nexus and regions of study, nexus keywords and stakeholders in order to understand the current state of nexus research. New hydrological insights Through selected 37 projects, four types of nexus research were identified including water–food, water–energy–food, water–energy, and climate related. Among them, six projects (16%) had a close linkage with water–food, 11 (30%) with water–energy–food, 12 (32%) with water–energy, and eight (22%) with climate. The regions were divided into Asia, Europe, Oceania, North America, South America, Middle East and Africa. North America and Oceania had a tendency to focus on a specific nexus type, water–energy (46%) and climate (43%), while Africa had less focus on water–energy (7%). Regarding keywords, out of 37 nexus projects, 16 projects listed keywords in their articles. There were 84 keywords in total, which were categorized by the author team depending on its relevance to water, food, energy, climate, and combination of water–food–energy–climate, and 40 out of 84 keywords were linked with water and only 4 were linked with climate. As for stakeholders, 77 out of 137 organizations were related to research and only two organizations had a role in media.

Beschreibung: Publication date: March 2016 Source: Journal of Hydrology: Regional Studies, Volume 5 Author(s): Shilpa M. Asokan, Peter Rogberg, Arvid Bring, Jerker Jarsjö, Georgia Destouni Study region The large semi-arid Aral Region in Central Asia and the smaller tropical Mahanadi River Basin (MRB) in India. Study focus Few studies have so far evaluated the performance of the latest generation of global climate models on hydrological basin scales. We here investigate the performance and projections of the global climate models in the Coupled Model Intercomparison Project, Phase 5 (CMIP5) for freshwater fluxes and their changes in two regional hydrological basins, which are both irrigated but of different scale and with different climate. New hydrological insights for the region For precipitation in both regions, model accuracy relative to observations has remained the same or decreased in successive climate model generations until and including CMIP5. No single climate model out-performs other models across all key freshwater variables in any of the investigated basins. Scale effects are not evident from global model application directly to freshwater assessment for the two basins of widely different size. Overall, model results are less accurate and more uncertain for freshwater fluxes than for temperature, and particularly so for model-implied water storage changes. Also, the monsoon-driven runoff seasonality in MRB is not accurately reproduced. Model projections agree on evapotranspiration increase in both regions until the climatic period 2070–2099. This increase is fed by precipitation increase in MRB and by runoff water (thereby decreasing runoff) in the Aral Region.

Beschreibung: Publication date: March 2016 Source: Journal of Hydrology: Regional Studies, Volume 5 Author(s): Justin A. Schulte, Raymond G. Najjar, Ming Li Study region The Mid-Atlantic region of the United States. Study focus An understanding of past streamflow variability is necessary for developing future management practices that will help mitigate the impacts of extreme events such as drought or floods on agriculture and other human activities. To better understand mechanisms driving streamflow variability at all timescales, annual to multi-decadal streamflow variability of three major rivers in the Mid-Atlantic region of the United States (the Susquehanna, Delaware, and Hudson Rivers) was studied in the context of climate modes using correlation and wavelet analyses. New hydrological insights for the region Results from the correlation analysis detected statistically significant relationships between climate indices and streamflow that were similar for the three rivers. The results from the wavelet analysis showed that 18- and 26-year periodicities were embedded in the streamflow time series. Decadal variability of streamflow was coherent with the El-Niño Southern Oscillation (SO) and the Pacific Decadal Oscillation (PDO). The time series for the PDO and SO indices and precipitation were found to be synchronized to the decadal variability of a global circulation pattern consisting of a Rossby wave train emanating from the North Pacific. The SO explained 37–54% of the 1960s drought, 33–49% of the 1970s pluvial, and 19–50% of the 2000s pluvial in the three river basins.

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Progress in Oceanography, Volume 170〈/p〉 〈p〉Author(s): Alba María Martínez–Pérez, Teresa S. Catalá, Mar Nieto–Cid, Jaime Otero, Marta Álvarez, Mikhail Emelianov, Isabel Reche, Xosé Antón Álvarez–Salgado, Javier Arístegui〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Fluorescent dissolved organic matter (FDOM) in the Mediterranean Sea was analysed by excitation–emission matrix (EEM) spectroscopy and parallel factor (PARAFAC) analysis during the cruise HOTMIX 2014. A 4–component model, including 3 humic–like and 1 protein–like compounds, was obtained. To decipher the environmental factors that dictate the distributions of these components, we run generalized additive models (GAMs) in the epipelagic layer and an optimum multiparametric (OMP) water masses analysis in the meso– and bathypelagic layers. In the epipelagic layer, apparent oxygen utilization (AOU) and temperature presented the most significant effects on the variability of the marine humic-like peak M fluorescence, suggesting that its distribution was controlled by the net community respiration of organic matter and photobleaching. On the contrary, the variability of the soil humic-like peak E and the protein–like peak T fluorescence was explained mainly by the prokaryotic heterotrophic abundance, which decreased eastwards. In the meso– and bathypelagic layers, water mass mixing and basin–scale mineralization processes explained 〉72% and 63% of the humic–like and protein–like fluorescence variability, respectively. When analysing the two basins separately, the OMP model offered a better explanation of the distribution of fluorescence in the eastern Mediterranean Sea, as expected from the reduced biological activity in this ultra–oligotrophic basin. Furthermore, while western Mediterranean deep waters display the usual trend in the global ocean (increase of humic–like fluorescence and decrease of protein–like fluorescence with higher AOU values), the eastern Mediterranean deep waters presented an opposite trend. Different initial fluorescence intensities of the water masses that mix in the eastern basin, with Adriatic and Aegean origins, seem to be behind this contrasting pattern. The analysis of the transect–scale mineralization processes corroborate this hypothesis, suggesting a production of humic–like and a consumption of protein–like fluorescence in parallel with water mass ageing. Remarkably, the transect–scale variability of the chromophoric dissolved organic matter (CDOM) absorbing at the excitation wavelength of the humic–like peak M indicates an unexpected loss with increasing AOU, which suggests that the consumption of the non–fluorescent fraction of CDOM absorbing at that wavelength exceeded the production of the fluorescent fraction observed here.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Biochimica et Biophysica Acta (BBA) - General Subjects, Volume 1863, Issue 2〈/p〉 〈p〉Author(s): Mathilde Ménard, Florent Meyer, Ksenia Parkhomenko, Cédric Leuvrey, Grégory Francius, Sylvie Bégin-Colin, Damien Mertz〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Human serum albumin (HSA) nanoparticles emerge as promising carriers for drug delivery. Among challenges, one important issue is the design of HSA nanoparticles with a low mean size of ca. 50 nm and having a high drug payload. The original strategy developed here is to use sacrificial mesoporous nanosilica templates having a diameter close to 30 nm to drive the protein nanocapsule formation. This new approach ensures first an efficient high drug loading (ca. 30%) of Doxorubicin (DOX) in the porous silica by functionalizing silica with an aminosiloxane layer and then allows the one-step adsorption and the physical cross-linking of HSA by modifying the silica surface with isobutyramide (IBAM) groups. After silica template removal, homogenous DOX-loaded HSA nanocapsules (30–60 nm size) with high drug loading capacity (ca. 88%) are thus formed. Such nanocapsules are shown efficient in multicellular tumor spheroid models (MCTS) of human hepatocarcinoma cells by their significant growth inhibition with respect to controls. Such a new synthesis approach paves the way toward new protein based nanocarriers for drug delivery.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0304416518303416-ga1.jpg" width="500" alt="Unlabelled Image" title="Unlabelled Image"〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Biochimica et Biophysica Acta (BBA) - Molecular Cell Research, Volume 1866, Issue 1〈/p〉 〈p〉Author(s): 〈/p〉

Beschreibung: 〈p〉Publication date: November 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Comptes Rendus Geoscience, Volume 350, Issue 7〈/p〉 〈p〉Author(s): Ilias Fountoulakis, Christos S. Zerefos, Alkiviadis F. Bais, John Kapsomenakis, Maria-Elissavet Koukouli, Nozomu Ohkawara, Vitali Fioletov, Hugo De Backer, Kaisa Lakkala, Tomi Karppinen, Ann R. Webb〈/p〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Spectral UV records of solar irradiance at stations over Europe, Canada, and Japan were used to study long-term trends at 307.5 nm for a 25-year period, from 1992 to 2016. Ground-based measurements of total ozone, as well as satellite measurements of the Aerosol Index, the Total Cloud Cover and the surface reflectivity were also used in order to attribute the estimated changes of the UV to the corresponding changes of these factors. The present study shows that over the Northern Hemisphere, the long-term changes in UV-B radiation reaching the Earth's surface vary significantly over different locations, and that the main drivers of these variations are changes in aerosols and total ozone. At high latitudes, part of the observed changes may also be attributed to changes in the surface reflectivity. Over Japan, the UV-B irradiance at 307.5 nm has increased significantly by ∼3%/decade during the past 25 years, possibly due to the corresponding significant decrease of its absorption by aerosols. It was found that the greatest part of this increase took place before the mid-2000s. The only European station, over which UV radiation increases significantly, is that of Thessaloniki, Greece. Analysis of the clear-sky irradiance for the particular station shows increasing irradiance at 307.5 nm by ∼3.5%/decade during the entire period of study, with an increasing rate of change during the last decade, possibly again due to the decreasing absorption by aerosols.〈/p〉〈/div〉

Beschreibung: 〈p〉Publication date: 1 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Solid State Ionics, Volume 327〈/p〉 〈p〉Author(s): W.G. Wang, X.Y. Li, T. Liu, G.L. Hao〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The electrical performances and relaxation behaviors of the Na〈sub〉0.525〈/sub〉Bi〈sub〉0.475〈/sub〉TiO〈sub〉2.975〈/sub〉 and Bi-deficient Na〈sub〉0.51〈/sub〉Bi〈sub〉0.48〈/sub〉TiO〈sub〉2.975〈/sub〉 sample were investigated. The grain conductivity of the Na〈sub〉0.525〈/sub〉Bi〈sub〉0.475〈/sub〉TiO〈sub〉2.975〈/sub〉 sample is able to reach 1.51 × 10〈sup〉−3〈/sup〉 S/cm at 673 K. In the temperature range of measurement, the grain conductivity of the Bi-deficient Na〈sub〉0.51〈/sub〉Bi〈sub〉0.48〈/sub〉TiO〈sub〉2.975〈/sub〉 sample is lower than that of the Na〈sub〉0.525〈/sub〉Bi〈sub〉0.475〈/sub〉TiO〈sub〉2.975〈/sub〉 sample. By the internal friction and dielectric relaxation spectrum, the activation energy and relaxation time at infinite temperature were determined as (0.82 eV, 2.47 × 10〈sup〉−14〈/sup〉 s), (0.67 eV, 5.82 × 10〈sup〉−12〈/sup〉 s) and (0.85 eV, 5.8 × 10〈sup〉−13〈/sup〉 s), (0.52 eV, 2.55 × 10〈sup〉−10〈/sup〉 s) for the Na〈sub〉0.525〈/sub〉Bi〈sub〉0.475〈/sub〉TiO〈sub〉2.975〈/sub〉 and Na〈sub〉0.51〈/sub〉Bi〈sub〉0.48〈/sub〉TiO〈sub〉2.975〈/sub〉 samples at the different temperature regions. In the Na〈sub〉0.525〈/sub〉Bi〈sub〉0.475〈/sub〉TiO〈sub〉2.975〈/sub〉 compound, there is larger specific free volume, higher mobile oxygen vacancy content and better oxygen vacancy mobility, which cause the higher grain conductivity in the Na〈sub〉0.525〈/sub〉Bi〈sub〉0.475〈/sub〉TiO〈sub〉2.975〈/sub〉 compound. To some extent, by the Bi-deficient method, oxygen vacancies can be introduced into the Na〈sub〉0.51〈/sub〉Bi〈sub〉0.48〈/sub〉TiO〈sub〉2.975〈/sub〉 compound and the grain conductivity may be improved, but the other side of Bi-deficiency harms the oxygen vacancy diffusion capacities in the Na〈sub〉0.5〈/sub〉Bi〈sub〉0.5〈/sub〉TiO〈sub〉3〈/sub〉 compound.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 1 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Solid State Ionics, Volume 327〈/p〉 〈p〉Author(s): Yonrapach Areerob, Ju Yong Cho, Won Kweon Jang, Kwang Youn Cho, Won-Chun Oh〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉A cost effective and efficient alternative counter electrode (CE) to replace commercially existing platinum (Pt)-based CEs for dye-sensitized solar cells (DSSCs) is necessary to make DSSCs competitive. Herein, we report the model-controllable synthesis of Graphene-La〈sub〉6〈/sub〉W〈sub〉2〈/sub〉O〈sub〉15〈/sub〉 doped NiSe-CoSe quantum dot (GLW-NiCoSe) nanosheets with various NiCoSe content via simple hydrothermal method and used as CE for DSSC application. Electrochemical impedance spectroscopy (EIS) results confirmed that the as-synthesized GLW-NiCoSe nanosheets quantum dot exhibited good electrocatalytic properties and a low charge transfer resistance at the electrolyte-electrode interface. In addition, Thermal images and Photocurrent also demonstrate stability effect of material with more exposed edge sites and appropriate NiCoSe ratio. GLW-NiCoSe nanosheets performed rough surfaces, well-defined interior voids, large specific surface areas and outstanding catalytic actives. Finally, the mechanism of this material has been reported. All of these results showed a high energy conversion efficiency of up to 8%, which was comparable to the Pt CE (7%). The simple fabricated and good electrocatalytic properties of GLW-NiCoSe nanosheets make them as an alternative CE for DSSCs.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0167273818304910-ga1.jpg" width="314" alt="Unlabelled Image" title="Unlabelled Image"〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 1 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Solid State Ionics, Volume 327〈/p〉 〈p〉Author(s): Ho-Young Jung, Geon-O Moon, T. Sadhasivam, Chang-Soo Jin, Won-Shik Park, Hee-Tak Kim, Sung-Hee Roh〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉To confirm the viability of a porous polyethylene (PE) separator for using in vanadium redox flow batteries (VRFBs), we conduct a comparative electroanalytical and chemical stability studies of the PE separator and Nafion 212 membrane. We characterize the physicochemical properties of the separator, such as water uptake, dimensional change, and ion conductivity, and analyze its structural and compositional features using thermogravimetric analysis, scanning electron microscopy, and X-ray photoelectron spectroscopy. We also test the chemical stability of the separator against highly oxidative V〈sup〉5+〈/sup〉 ions and the cell performance of VRFB using PE separator to assess practical applicability. In chemical stability, the change of VO〈sub〉2〈/sub〉〈sup〉+〈/sup〉 ion to VO〈sup〉2+〈/sup〉 ion is considerably lowered by the PE separator (0.01 mmol/L) than the Nafion 212 (0.27 mmol/L), which indicates that the PE separator possesses higher chemical stability. The energy efficiency of the VRFB with the PE separator is lower than that obtained with Nafion 212. However, the chemical stability of PE separator is 27 times higher than that of Nafion 212, indicating that its use will promote the long-term operation of the VRFB system. Hence, the PE separator can be considered a cost-effective option for VRFB operation, with appropriate modifications to its thickness, surface properties and pore structure.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: March 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Surface Science, Volume 681〈/p〉 〈p〉Author(s): Qingjun Chen, Ingeborg-Helene Svenum, Ljubisa Gavrilovic, De Chen, Edd A. Blekkan〈/p〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Trace amounts of potassium (K) have a significant influence on the activity and selectivity of cobalt-based catalysts in Fischer–Tropsch synthesis (FTS), in which hydrogen adsorption and dissociation is one of the initial and most important steps. In this work, hydrogen adsorption and dissociation behavior on typical facets ((0001), (10–11), (10–12), (10–15) and (11–20)) of hcp Co with and without adsorbed K were systematically studied. H〈sub〉2〈/sub〉 molecular adsorption results showed that H〈sub〉2〈/sub〉 mainly adsorbed in the perpendicular mode and close to the state of free H〈sub〉2〈/sub〉. Different facets and pre-adsorbed K did not show obvious effects on the H〈sub〉2〈/sub〉 adsorption energy. Atomic hydrogen adsorption was site and facet dependent, but the maximum hydrogen adsorption energy on the different facets of hcp Co were similar (-2.64 to -2.67 eV) with the exception on the (11–20) facet where the adsorption energy was significantly lower (-2.44 eV). K had a slight destabilizing effect on the H atom adsorption on the former Co surfaces due to a very weak repulsive interaction between K and H atoms. The initial H〈sub〉2〈/sub〉 dissociation had negligible energy barriers (0–0.07 eV) on the clean surface of hcp Co, suggesting the direct dissociative adsorption of H〈sub〉2〈/sub〉. The energy barriers for H〈sub〉2〈/sub〉 dissociation are mainly caused by the approach of molecular H〈sub〉2〈/sub〉 towards the Co surface and the rotation of the H〈sub〉2〈/sub〉 molecule from the perpendicular mode to the parallel mode. The H〈sub〉2〈/sub〉 dissociation energy barriers increase by 0.02–0.17 eV after the pre-adsorption of K, indicating a slight inhibition of H〈sub〉2〈/sub〉 dissociation by K. However, the energy barriers for H〈sub〉2〈/sub〉 dissociation in the presence of K were also small (0.05–0.21 eV). This indicates that H〈sub〉2〈/sub〉 dissociates readily at typical Co-based FTS reaction temperatures (210–240 °C), both in the absence and presence of K. Different K species (K and KOH) exhibit similar effects on H〈sub〉2〈/sub〉 dissociation on hcp Co. The B〈sub〉5〈/sub〉 sites on the stepped facets, the preferred sites for K adsorption are not the most favorable site for H〈sub〉2〈/sub〉 dissociation, and K slightly hinders H〈sub〉2〈/sub〉 dissociation at the B〈sub〉5〈/sub〉 site of hcp Co.〈/p〉〈/div〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0039602818305144-fx1.jpg" width="301" alt="Image, graphical abstract" title="Image, graphical abstract"〉〈/figure〉〈/p〉〈/div〉

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Technological Forecasting and Social Change, Volume 138〈/p〉 〈p〉Author(s): Jae-Woong Min, Nicholas S. Vonortas, YoungJun Kim〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉This study explores the factors that contribute to the commercialization of technologies transferred from universities and public research institutes (U&PRIs) to companies. We take a step further than the established literature focusing on technology transfer to examine factors that also affect the chances of the successful commercialization of the transferred technologies through an empirical analysis of 669 technology transfer cases in Korea. The study shows that the intensity of market competition is a key factor in moderating the effects of partnership and absorptive capacity on the successful commercialization of transferred technologies. While collaboration with U&PRIs exerts a positive effect on commercialization success, this effect is weakened by the intensity of market competition. The intensity of market competition boosts the importance of company absorptive capacity for the commercialization success of the transferred technology. We conclude that strategic management of the absorptive capacities of companies and their partnership with U&PRIs are necessary ingredients of the success of technology transfer in concordance with the intensity of competition that the company faces in the market.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 10 February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Electrochimica Acta, Volume 296〈/p〉 〈p〉Author(s): Saheed Bukola, Stephen E. Creager〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Transmission rates for protons and deuterons across single-layer graphene embedded in Nafion | graphene | Nafion sandwich structures are measured as a function of temperature in electrochemical hydrogen pump cells. Rates of ion transmission through graphene are obtained in the form of area-normalized ion-transfer resistances, and are interpreted in terms of ion-exchange current densities and standard heterogeneous ion-transfer rate constants. An encounter pre-equilibrium model for the ion-transfer step is then used to provide rate constants for the fundamental microscopic step of ion (proton or deuteron) transmission across graphene. Application of this rate model to interpret variable-temperature data on proton and deuteron transmission rates provides values for the activation energy and pre-exponential factor for the fundamental ion transmission step across graphene. Activation energies obtained from the Arrhenius plots for proton and deuteron transmission are as follows; for proton, E〈sub〉act〈/sub〉 = 48 ± 2 kJ/mole (0.50 ± 0.02 eV) and for deuteron, E〈sub〉act〈/sub〉 = 53 ± 5 kJ/mole (0.55 ± 0.05 eV). The difference between these two values of approximately 5 kJ/mole is in good agreement with the expected difference in vibrational zero-point energies for O〈img src="https://sdfestaticassets-eu-west-1.sciencedirectassets.com/shared-assets/16/entities/sbnd"〉H and O-D bonds, albeit with some uncertainty given the uncertainties in the activation energy values. Pre-exponential frequency factor values of 8.3 ± 0.4 × 10〈sup〉13〈/sup〉 s〈sup〉−1〈/sup〉 and is 4.7 ± 0.5 × 10〈sup〉13〈/sup〉 s〈sup〉−1〈/sup〉 were obtained for proton and deuteron transmission respectively across graphene. These pre-factor values are both quite large, on the order of the values predicted from the Eyring – Polanyi equation with a transmission coefficient near one. The ratio of 1.8 for the rate pre-factors (H/D) is in reasonable agreement with the value of 1.3 for the ratio of bond vibrational frequencies for O〈img src="https://sdfestaticassets-eu-west-1.sciencedirectassets.com/shared-assets/16/entities/sbnd"〉H and O-D stretching, respectively. Taken together, these data support a model in which proton and deuteron transmission across graphene are largely adiabatic processes for which the differences in transmission rate at room temperature are due largely to differences in activation energies.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: Available online 31 October 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 European Polymer Journal〈/p〉 〈p〉Author(s): Ali Behnood, Mahsa Modiri Gharehveran〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉 〈p〉Asphalt binders play an integral role in the performance and properties of asphalt mixtures. Increased traffic-related factors on the roadways such as heavier loads, higher traffic volume, and higher tire pressure combined with substantial variation in daily and seasonal temperatures of the pavement have been responsible for the asphalt pavements failure. To prevent or mitigate these failures, many attempts have been made by polymer scientists and civil engineers to improve the performance of asphalt pavements by modifying the properties of asphalt binders. A good modifier changes the failure properties such that binder yields more stresses and strains before failure. Modification of asphalt binders through the addition of a polymer to improve their rheological and physical properties has a long history in asphalt industry. Once the polymer is properly mixed with the asphalt binder, a swallowed polymer network is formed, which contributes to the changes in viscoelastic behavior. However, polymer-modified asphalt binders may have some drawbacks related to the poor solubility of polymers. Understanding the internal structure of polymer-modified asphalt binders has been the subject of numerous research studies.〈/p〉 〈p〉Available studies regarding the affecting parameters on the properties of the polymer-modified asphalt binders are reviewed here. Various types of polymers used in asphalt industry and their effects on the rheological, morphological, physical and mechanical properties of polymer-modified asphalt binders are also discussed in this paper. In addition, this paper provides a review on the techniques used to overcome/mitigate the shortcomings of conventional polymer-modified asphalt binders.〈/p〉 〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0014305718318019-ga1.jpg" width="341" alt="Graphical abstract for this article" title=""〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of the Mechanics and Physics of Solids, Volume 122〈/p〉 〈p〉Author(s): 〈/p〉

Beschreibung: 〈p〉Publication date: 1 January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Ocean & Coastal Management, Volume 167〈/p〉 〈p〉Author(s): Uxío Labarta, M〈sup〉a〈/sup〉 José Fernández-Reiriz〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉 〈p〉The mussels industry with a production that accounts for more than twenty five percent of the fresh product landings from the sea, and the full-time employment of more than 8000 people, is by far the largest productive activity of the Galician sea.〈/p〉 〈p〉In the 1980s was noticed an increase in productivity related to processes of innovation in the industry of mussel. Together with it, the first organizational forms of the Galician-based production sector was constituted, with a spatial and administrative reordering for mussel rafts and crops. A new reality of the sector was maintained in both the marketing guidelines and the fact of initiating a vertical integration between the mussel industry and the commercialization. Everything was accompanied by changes in markets and strong tensions: derived from red tides that limit the operating cycle and even its profitability and also from the conflicts between the producing and transforming organizations, added to the competition in the markets of other countries, mainly Chile.〈/p〉 〈p〉The reality of mussel culture and markets leads to a reformulation in the industry, with strategies for territorial diversification of suppliers, new technological improvements in production and even organizational, economic, and bioecological innovations.〈/p〉 〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 1 February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Electrochimica Acta, Volume 295〈/p〉 〈p〉Author(s): Kaili Jin, Man Zhou, Hong Zhao, Shixiong Zhai, Fengyan Ge, Yaping Zhao, Zaisheng Cai〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉With the large theoretical capacity and environmental benignity, copper sulfide (CuS) becomes a prospective candidate electrode material for supercapacitors. In this work, electroconductive mesoporous carbonized clothes (Cc) was obtained by carbonizing the waste cotton fabrics. Then the CuS was galvanostatic electrodeposited on 〈em〉Cc〈/em〉 to prepare the binder-free 〈em〉g〈/em〉-CuS/Cc electrode. In the galvanostatic electrodeposition process, CuS grew along the crystal surface to form regular nanosheets, and a part of Cu〈sup〉2+〈/sup〉 were reduced to Cu〈sup〉1.1+〈/sup〉. In addition, on account of the synergistic effect of electrochemical double layer capacitance with pseudocapacitance and the high specific surface area (450.76 m〈sup〉2〈/sup〉 g〈sup〉−1〈/sup〉), the 〈em〉g〈/em〉-CuS/Cc composite displayed not only outstanding areal specific capacitance (4676 mF cm〈sup〉−2〈/sup〉 at 2 mA cm〈sup〉−2〈/sup〉) but also excellent cycling performance (89.8% retention after 10000 cycles). Meanwhile, the symmetrical flexible supercapacitor (SC) based on 〈em〉g〈/em〉-CuS/Cc electrodes with PVA-KOH gel electrolyte (〈em〉g〈/em〉-CuS/Cc-SC) accomplished a high specific capacitance of 1333 mF cm〈sup〉−2〈/sup〉 at 2 mA cm〈sup〉−2〈/sup〉 as well as ultrahigh energy density of 0.96 Wh cm〈sup〉−2〈/sup〉 at the power density of 4.36 W cm〈sup〉−2〈/sup〉. Therefore, 〈em〉g〈/em〉-CuS/Cc shows a great potential for applications in the next generation of flexible energy storage devices.〈/p〉〈/div〉 〈/div〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0013468618324447-fx1.jpg" width="384" alt="Image 1" title="Image 1"〉〈/figure〉〈/p〉〈/div〉

Beschreibung: 〈p〉Publication date: 1 February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Electrochimica Acta, Volume 295〈/p〉 〈p〉Author(s): Kang Li, Zhanwei Xu, Xuetao Shen, Kai Yao, Jianshe Zhao, Ronglan Zhang, Jun Zhang, Li Wang, Jianfeng Zhu〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Commercial lithium/thionyl chloride (Li/SOCl〈sub〉2〈/sub〉) batteries cannot meet the 3.15 V platform required for most instruments. A 〈em〉hovenia acerba〈/em〉-like assembly constructed with cobalt tetrapyridinoporphyrazine of thickness of 5–15 nm is anchored on acid-functionalized multi-walled carbon nanotubes (CoTAP/MWCNTs), which were prepared using an 〈em〉in situ〈/em〉 solid synthesis process. The discharge time of Li/SOCl〈sub〉2〈/sub〉 batteries with a voltage greater than 3.15 V catalyzed by CoTAP/MWCNTs is found to be 11 min longer than batteries without catalysts and 4 min longer than those catalyzed by CoTAP alone. The energy of Li/SOCl〈sub〉2〈/sub〉 batteries with a voltage greater than 3.15 V catalyzed by CoTAP/MWCNTs is discovered to be 11.44-times higher than batteries with AF-MWCNTs and 6.17-times higher than those catalyzed by bulk CoTAP. This is due to the fact that more CoTAP ultrafine nanoparticulates are anchored on the AF-MWCNTs. These nanoparticulates provide more active sites for the catalytic reaction of SOCl〈sub〉2〈/sub〉. The assemblies are shown to have an adsorption-coordination effect on Li ions and to delay the deposition of lithium chloride passive films enhancing battery voltage platforms.〈/p〉〈/div〉 〈/div〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉A 〈em〉hovenia acerba〈/em〉-like assembly constructed with cobalt tetrapyridinoporphyrazine of thickness of 5–15 nm is anchored on acid-functionalized multi-walled carbon nanotubes (CoTAP/MWCNTs), which were prepared using an 〈em〉in situ〈/em〉 solid synthesis process. The discharge time of Li/SOCl〈sub〉2〈/sub〉 batteries with a voltage greater than 3.15 V catalyzed by CoTAP/MWCNTs is found to be 11 min longer than batteries without catalysts and 4 min longer than those catalyzed by CoTAP alone.〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0013468618324319-fx1.jpg" width="270" alt="Image 1" title="Image 1"〉〈/figure〉〈/p〉〈/div〉

Beschreibung: 〈p〉Publication date: December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Transport Geography, Volume 73〈/p〉 〈p〉Author(s): Chengxi Liu, Yusak O. Susilo, Dimas B.E. Dharmowijoyo〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The activity space of an individual is defined as the activity-travel environment which a traveller is using for his or her activities (Axhausen et al., 2002). It is limited by this individual's ability and resources, such as available time for travel as well as his or her anchor points. However, most existing studies have focused on single individual activity space, ignoring the fact that individuals' activities often interact with that of his or her family members'. In this paper a multivariate model is proposed where the correlation between travel time of fathers and mothers, and the correlation between the activity space and travel time are modelled explicitly. The estimated correlations from these joint distributions provide insights into both the intra-household interactions in daily travel and the intrinsic relationships of the hidden limits in the dimensions of space and time. The travel time limits are modelled using a stochastic frontier model component, which can estimate an unobserved upper or lower limit for travel time expenditure. This limit usually refers to the maximum travel time budget or minimum travel time need, which denotes the maximum or minimum amount of travel time that an individual is willing or able to allocate per day. The concept of the confidence ellipse is used as a measure of activity space constructed from the multi-day travel diary data. It is hypothesised that the unobserved travel time limits and activity space sizes of fathers and mothers are correlated with each other, due to a similar spatial knowledge and accessibility to various facilities. The daily variations in the travel time expenditure of parents are also assumed to be correlated because of daily household task allocation and joint household travel. Data collected from a three-week household travel diary in the Bandung Metropolitan Area in Indonesia are used for estimation in this study. The estimated frontier model component shows that neither parent has reached their maximum travel time budget and/or minimum travel time need that they inherently must spend. Compared with other attributes, the perceived accessibility attributes play the most important role in influencing the activity space limits. For households with fully employed fathers, a trade-off mechanism is found in travel time expenditure between parents, which is likely due to the redistribution of household tasks. On the other hand, for households with fathers who are not fully employed, a complementary effect is found, arising from the joint travel among household members. The travel time budget and activity space limits of fathers are positively correlated with those of mothers. These findings call for the formulation of transport policies that consider the household as a unit, especially in developing countries such as Indonesia, to fulfil the mobility needs of different market segments, e.g., households with fully employed fathers and those with fathers who are not fully employed.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): X.Y. Wang, S.L. Zhang, S.D. Feng, L. Qi, R.P. Liu〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The structures of the Ti〈sub〉75〈/sub〉Al〈sub〉25〈/sub〉 alloy during rapid-quenching with and without external pressure are investigated by using molecular dynamic techniques. The amorphous phase can be obtained at the cooling rate 10.0 K/ps without pressure. The alloy is composed of crystal and amorphous phase at the cooling rate 0.1 and 1.0 K/ps without pressure, but the pure amorphous phase can be formed when the pressure exceeds the critical value. The critical pressure is about 20 and 30 GPa when the cooling rate is 0.1 and 1.0 K/ps, respectively. H-A indices analysis indicates that high pressure favors the formation of the ideal icosahedral structures in the amorphous Ti〈sub〉75〈/sub〉Al〈sub〉25〈/sub〉 alloy, and the content of 1551 bond-type can reach near to 50% when the pressure is 30 GPa. The amorphous state can be maintained if the external pressure is removed from the alloy step-by-step. The content of 1551 bond-type decreases with the deceasing of the pressure, but the 1541 and 1431 bond-types increase in this process.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Physics and Chemistry of Solids, Volume 124〈/p〉 〈p〉Author(s): 〈/p〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): 〈/p〉

Beschreibung: 〈p〉Publication date: 15 February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Applied Surface Science, Volumes 467–468〈/p〉 〈p〉Author(s): S.P. Sun, J.L. Zhu, S. Gu, X.P. Li, W.N. Lei, Y. Jiang, D.Q. Yi, G.H. Chen〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The surface stability and equilibrium morphology of MoO〈sub〉3〈/sub〉 were investigated by the first principles calculations. The thermodynamic energies of the stoichiometric surfaces of MoO〈sub〉3〈/sub〉 are in the order (0 1 0) 〈 (1 0 1) 〈 (0 0 1) 〈 (1 0 0). It is found that the (0 1 0) surface has a lowest surface energy, which agrees well with the previous calculations. The energies of the non-stoichiometric surfaces were evaluated as functions of temperature and oxygen partial pressure. The results show that the energies of Mo-terminated surfaces decrease with temperatures, and increase with oxygen partial pressures, while the energies of O-terminated surfaces show the opposite rule. The equilibrium morphology of MoO〈sub〉3〈/sub〉 was predicted by using the Gibbs-Wulff model, and then was compared with the other’s experiments and theoretical results.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Applied Surface Science, Volumes 467–468〈/p〉 〈p〉Author(s): Sanju Gupta, Nicholas Dimakis〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The interfacial interactions between transition metal oxides (vanadium oxide VO〈sub〉2〈/sub〉, vanadium pentoxide V〈sub〉2〈/sub〉O〈sub〉5〈/sub〉, cobalt oxide CoO and Co〈sub〉3〈/sub〉O〈sub〉4〈/sub〉, manganese oxide MnO〈sub〉2〈/sub〉) and water adsorbates on graphene supports as solvated interfaces and influence of defects in graphene are studied using periodic density functional theory (DFT) calculations in view of their significance for applied electrochemistry. DFT complemented and synergized our experimental work. The optimized metal oxide adatom-graphene geometries identified the preferred adatom sites, whereas metal oxide-graphene strengths are correlated with the adatom distance from the graphene plane, the Metal-C overlap populations, and the adsorption energies. The presence of finite electronic density of states (DOS) near Fermi level and charge transfers between the adatom top layer and graphene supports reflect primarily covalent bonding nature. The presence of small orbital overlap integral of bonds between the s and p (and d) orbitals of the nearest carbon (graphene), carbon oxide (graphene oxide) and metal oxide atoms reveal localized orbital re-hybridization resulting in changes in DOS yielding high electrochemical activity. Moreover, for increased adatom coverage the extent of charge transfer reverses resulting in limited electroactivity. In fact, DFT calculations are corroborated with experimental findings, where graphene-based supports decorated with optimal mass loaded nanostructured Co〈sub〉3〈/sub〉O〈sub〉4〈/sub〉 and MnO〈sub〉2〈/sub〉 (as well as V〈sub〉2〈/sub〉O〈sub〉5〈/sub〉) were capable of delivering maximum specific energy storage capacity (C〈sub〉s〈/sub〉) 〉 550 F·g〈sup〉−1〈/sup〉 (Gupta et al. J. Mater. Res. 32, 301 (2017)) in contrast to higher or lower loading. The presence of defects in graphene materials results in new electronic states to endow unique functionalities that is not otherwise possible in the bulk and with adsorbed water molecules besides optimum C/O ratio in graphene oxide nanosheets that show redshift thus a decreasing bandgap and finite charge transfer from graphene to water molecules. The case examples studied in this work represent a first glimpse of what may become routine and integral step in materials design and discovery for alternative energy and sustainable environmental technologies.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): Anne-Isabelle Bidegaray, Andrea Ceglia, Maria Rita Cicconi, Van-Thai Pham, Amandine Crabbé, El Amine Mernissi Cherigui, Karin Nys, Herman Terryn, Daniel R. Neuville, Stéphane Godet〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The analysis of iron, manganese and antimony in silicate glass is of great interest in chemistry, materials science, earth sciences and archaeological sciences. Yet, conclusions from different fields appear to be contradictory and many questions about redox reactions in glass remain. The purpose of this study is thus to discuss whether and how these multivalent elements interact in glass. Soda-lime silicate melts containing iron along with manganese and/or antimony have been analysed at different high temperatures under argon atmosphere. Using 〈em〉in-situ〈/em〉 XANES at the Fe K-edge, redox thermodynamics, kinetics and diffusivities have been assessed for the different compositions. The data obtained show that antimony is more efficient at oxidising iron compared to manganese at all temperatures. The oxidising power trend would thus be Sb 〉 Sb + Mn 〉 Mn. Furthermore, hypotheses on the formation of Fe-Mn complexes are also reported in glasses with stoichiometric proportions of iron and manganese. Based on the determination of redox diffusivities, it appears that presence of other multivalent elements does not significantly affect the iron redox mechanisms and that diffusivity is essentially controlled by the mobility of calcium.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): Wentao Zhang, Feng He, Junlin Xie, Xiaoqing Liu, De Fang, Hu Yang, Zhihong Luo〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Glass ceramics from modified molten blast furnace (BF) slag were prepared. The crystallization behavior of the modified BF slag was characterized using differential thermal analysis (DTA), X-ray diffraction (XRD), and field emission scanning electron microscope (FESEM). The crystallization kinetics results indicated that the crystallization activation energy initially decreased and subsequently increased with increasing CaO/SiO〈sub〉2〈/sub〉. The crystallization temperature and the crystallization index (n) decreased from 916 to 867 °C, and 5.66–1.13, respectively. The crystallization mechanism transformed from bulk crystallization to surface crystallization. By XRD analyzing, Melilite was developed as the main crystal phase, and the transformation of crystal from akermanite to gehlenite was observed. The rapid surface crystallization was beneficial for maintaining the shape of glass ceramics. The complex replacement in melilite crystals resulted in the micro cracks in glass ceramics, therefore led to the decrease of flexural strength of glass ceramics〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): B.C. Jamalaiah〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Different amounts of GeO〈sub〉2〈/sub〉 activated tellurite tungstate glasses were prepared by melt quenching technique. Thermal stability and glass forming ability were studied using differential scanning calorimetry. The chemical composition, homogeneity and amorphous nature of studied glasses were investigated. The phonon energy was estimated to be 721.34 cm〈sup〉−1〈/sup〉. Experimentally determined refractive indices were compared with those determined from optical band gap (E〈sub〉g〈/sub〉) and optical electronegativity (Δ〈em〉χ〈/em〉〈sup〉∗〈/sup〉). The dielectric constant (K) and electronic polarizability (α) were determined using refractive index value. The presence of disorder was estimated in terms of Urbach energy (E〈sub〉U〈/sub〉). The average electronegativity (〈em〉χ〈/em〉〈sub〉〈em〉ave〈/em〉〈/sub〉), oxide ion polarizability (〈em〉α〈/em〉〈sub〉〈em〉O〈/em〉〈/sub〉〈sup〉2−〈/sup〉) and covalent character (C〈sub〉cov〈/sub〉) were determined. The content of GeO〈sub〉2〈/sub〉 was optimized to be 10.0 mol% to design a novel host material for solid state lasers and fiber devices.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): Chunhe Jiang, Kejiang Li, Jianliang Zhang, Qinghua Qin, Zhengjian Liu, Minmin Sun, Ziming Wang, Wang Liang〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉SiO〈sub〉2〈/sub〉-Al〈sub〉2〈/sub〉O〈sub〉3〈/sub〉-CaO-MgO is the most significant slag system in the blast furnace ironmaking process and it is very important to investigate the microstructure and viscosity of the system. In this paper, molecular dynamics simulations were carried out to explore the effects of MgO/Al〈sub〉2〈/sub〉O〈sub〉3〈/sub〉 ratio on structure and properties of the system. Based on the self-diffusion coefficients, the viscosities were calculated by Einstein-Stokes equation and compared with the experimental value and the Factsage value. The results showed that with the increase of MgO/Al〈sub〉2〈/sub〉O〈sub〉3〈/sub〉 ratio, the stability of [SiO〈sub〉4〈/sub〉]〈sup〉4−〈/sup〉 and [AlO〈sub〉4〈/sub〉]〈sup〉5−〈/sup〉 tetrahedron became weaken and the relative proportions of bridge and non-bridge oxygen showed a decrease. And due to the increase of MgO, more Mg〈sup〉2+〈/sup〉 ions are used as network modifiers to reduce the degree of polymerization of the system, resulting in a decrease in the viscosity, which is consistent with experimental results. Finally, based on the present study, in the case of increasing Al〈sub〉2〈/sub〉O〈sub〉3〈/sub〉 content of blast furnace slag, the fluidity of slag could be adjusted by controlling MgO/Al〈sub〉2〈/sub〉O〈sub〉3〈/sub〉 ratio, thereby providing a basis for stable operation of blast furnace ironmaking.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): A.I. Popov〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The definition of glassy state presented by the authors of the article “The glassy state of matter: Its definition and ultimate fate” E. Zanotto and J. Mauro is considered. The importance of the contribution to the glassy state problem made in the article is emphasized. At the same time consideration of the glassy state as unstable state of matter causes definite objections. It is more correctly to consider the glassy state as metastable state of matter.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): M.G. Syamala Rao, M.A. Pacheco-Zuñiga, L.A. Garcia-Cerda, G. Gutiérrez-Heredia, J.A. Torres Ochoa, M.A. Quevedo López, R. Ramírez-Bon〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉In this work, we developed a novel inorganic-organic hybrid gate dielectric by combining zirconium and hafnium components to form zirconium hafnium oxide strongly linked with polymethyl methacrylate (ZrHfO〈sub〉2〈/sub〉-PMMA) and deposited at low temperature (200 °C) by sol-gel method. The obtained 108 nm thick, high-quality hybrid gate dielectric showed an exceptionally low surface roughness (0.9-nm), a low leakage current density (7.7 × 10〈sup〉−6〈/sup〉 A/cm〈sup〉2〈/sup〉) and reasonable dielectric properties such as gate capacitance along with dielectric constant (77 nF/cm〈sup〉2〈/sup〉 & 9.4 @1 kHz) respectively. To examine the ZrHfO〈sub〉2〈/sub〉-PMMA hybrid dielectric electrical properties we constructed thin-film transistors (TFTs) with room temperature r.f sputtered n-type metal oxide semiconductors, a-IGZO and ZnO, as active channels. The bottom gate fabricated a-IGZO TFTs driving at as low as below 6 V, with extracted field effect mobility of 2.45 cm〈sup〉2〈/sup〉/V. s, a low threshold voltage of 1.2 V with large ON/OFF current ratio 10〈sup〉7〈/sup〉 respectively. On the other hand, for comparison we employed ZnO TFTs by applying same hybrid dielectric system, the obtained parameters of bottom gate ZnO TFTs were good field effect saturation mobility of 12.8 cm〈sup〉2〈/sup〉/V. s, threshold voltage of 1.8 V and ON/OFF current ratio of 10〈sup〉3〈/sup〉.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): Weidi Zhu, Mark Lockhart, Bruce Aitken, Sabyasachi Sen〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The viscoelastic properties of supercooled As〈sub〉x〈/sub〉Se〈sub〉100-x〈/sub〉 (0 ≤ x ≤ 30) and As〈sub〉x〈/sub〉Se〈sub〉100-x-y〈/sub〉I〈sub〉y〈/sub〉 (x = 20, 30 and y = 10, 20) liquids are studied using oscillatory parallel plate rheometry. In addition to the α-relaxation process, the shear relaxation of liquids with selenium chains longer than ~ 3 atoms is also characterized by a low-frequency polymeric mode. The temporal decoupling of this low-frequency soft/floppy relaxation mode from that of the α-relaxation mode is a unique function of the average selenium chain length. The floppy mode abruptly vanishes for liquids with average chain lengths shorter than ~ 3 Se atoms, thus implying a dynamical rigidity transition. When taken together, these results indicate that, contrary to the conventional wisdom, the pertinent structural variable associated with such transition in the viscoelastic behavior is not the average coordination number but instead the intermediate-range structural elements such as the average selenium chain length.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 502〈/p〉 〈p〉Author(s): M.S.A. Mohd Saidi, S.K. Ghoshal, K. Hamzah, R. Arifin, M.F. Omar, M.K. Roslan, E.S. Sazali〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉We report the influence of silver (Ag) and titania (TiO〈sub〉2〈/sub〉) nanoparticles (ATNPs) co-embedment on the photoluminescence (PL) properties of dysprosium ions (Dy〈sup〉3+〈/sup〉) doped zinc-magnesium tellurite glass system prepared using conventional melt quenching method. Both up- and down- converted PL spectra of glasses revealed three emission bands located at 482 (blue: 〈sup〉4〈/sup〉F〈sub〉9/2〈/sub〉 → 〈sup〉6〈/sup〉H〈sub〉15/2〈/sub〉), 574 (yellow: 〈sup〉4〈/sup〉F〈sub〉9/2〈/sub〉 → 〈sup〉6〈/sup〉H〈sub〉13/2〈/sub〉) and 664 nm (weak red: 〈sup〉4〈/sup〉F〈sub〉9/2〈/sub〉 → 〈sup〉6〈/sup〉H〈sub〉11/2〈/sub〉), where the band intensities were enhanced with the inclusion of ATNPs. Glasses with 0.2 mol% of ANPs and up to 0.3 mol% of TNPs disclosed highest PL intensity enhancement, which was majorly attributed to the ATNPs mediated localized surface plasmon resonance (LSPR) and large field enhancement (called hot spot) effects in the proximity of Dy〈sup〉3+〈/sup〉 ions. Absorption spectra of glasses displayed two plasmon bands characteristics of each type of nanoparticle. It was inferred that the superposition of localized SP modes from ATNPs could generate new hybridized modes (strong local field in the vicinity of Dy〈sup〉3+〈/sup〉 ions) shifted with respect to the single type of NPs resonance. HRTEM images showed the existence of both Ag and titania NPs inside the glass matrix. Glasses containing ATNPs exhibited anatase phase with (103) and (112) nanocrystalline lattice plane orientation. Proposed glass system may be useful for the development of solid state laser and photonic devices.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 March 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Magnetism and Magnetic Materials, Volume 474〈/p〉 〈p〉Author(s): Muhammad Arshad, M. Asghar, Muhammad Junaid, Muhammad Farooq Warsi, M. Naveed Rasheed, M. Hashim, M.A. Al-Maghrabi, Muhammad Azhar Khan〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉In this study Co-Ni co-doped nanocrystalline manganese ferrites were fabricated via co-precipitation method. The annealing of as prepared nanoferrites was done at 950 °C for 7 h. The powder X-ray diffraction (XRD) confirmed that all samples possessed cubic spinel structure. The crystallite size was determined by Scherrer’s equation that lies in the range of 27–35 nm. The spectral analysis confirmed bending and stretching of bonds at octahedral (B) and tetrahedral (A) sites. The spectral bands were shifted towards the longer wavelength side and these indicate the incorporation of dopants cations (Co-Ni). The magnetic parameters were measured from the M-H loops of nanoferrites. With the increase of Co-Ni contents, the saturation magnetization (Ms) increased up to x = 0.15 and then it decreased. The dielectric properties of all compositions were studied in 1 MHz–3 GHz range and were discussed in the light of Debye-type reduction phenomenon by following the Koop’s theory. The dielectric and magnetic behavior evaluation suggested that synthesized ferrites are suitable for microwave devices fabrication.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0304885318319127-ga1.jpg" width="282" alt="Graphical abstract for this article" title=""〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Infrared Physics & Technology, Volume 96〈/p〉 〈p〉Author(s): Chunyan Guo, Yaoyao Sun, Qingxuan Jia, Zhi Jiang, Dongwei Jiang, Guowei Wang, Yingqiang Xu, Tao Wang, Jinshou Tian, Zhaoxin Wu, Zhichuan Niu〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉A kind of wide spectrum infrared detectors based on InAs/GaSb type-II superlattices (T2SLs) operating from 0.5 μm to 5 μm wavelength range is reported. The materials were grown by Molecular Beam Epitaxy (MBE) on GaSb substrates. Diverse types and sizes microstructure are fabricated on the surface of the detector to form the photon traps (PTs) array. PTs decrease the reflectivity and increase the light absorption of epitaxial material. Compared with the planar mesa detectors without antireflection (AR) film, detectors with PTs array exhibits a high responsivity of 0.86 A/W at 1160 nm and maximum D* reaches to 10〈sup〉9〈/sup〉 cm Hz〈sup〉1/2〈/sup〉/W in visible wavelength. Also, the PTs processed on detector augment spectral response and QE in infrared wavelength. The peak responsivity of the detector with PTs is to 1.35 A/W and QE can exceed to 0.76 in the infrared wavelength. The infrared detector with PTs is attractive for numerous applications.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: November 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Solid State Sciences, Volume 85〈/p〉 〈p〉Author(s): 〈/p〉

Beschreibung: 〈p〉Publication date: November 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Solid State Sciences, Volume 85〈/p〉 〈p〉Author(s): 〈/p〉

Beschreibung: 〈p〉Publication date: November 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Solid State Sciences, Volume 85〈/p〉 〈p〉Author(s): 〈/p〉

Beschreibung: 〈p〉Publication date: 15 February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Applied Surface Science, Volumes 467–468〈/p〉 〈p〉Author(s): Xu Wu, Yalin Feng, Yali Du, Xuezhen Liu, Chunlei Zou, Zhe Li〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉LDHs templates (marked as CoAl-MnO〈sub〉2〈/sub〉-LDH and CoMnAl-CO〈sub〉3〈/sub〉-LDH) were fabricated via ion-exchange/redox reaction and hexamethylenetetramine (HMT) hydrolysis methods respectively. CoMnAl mixed metal oxides (marked as MnO〈sub〉2〈/sub〉/CoAl-LDO and CoMnAl-LDO) from the as-prepared LDHs templates were novelly prepared and tested as low-temperature NH〈sub〉3〈/sub〉-SCR catalysts. Catalytic evaluation pronouncedly affirmed that the catalytic performances of the as-acquired catalysts were vulnerable to the preparation method of precursor template, where MnO〈sub〉2〈/sub〉/CoAl-LDO presented preferable DeNOx activity (over 90% NOx conversion), N〈sub〉2〈/sub〉 selectivity and SO〈sub〉2〈/sub〉 resistance in much broader working temperature window (90–300 °C) than CoMnAl-LDO. Multiple characterizations revealed that the excellent catalytic performance of the MnO〈sub〉2〈/sub〉/CoAl-LDO could be attributed to its higher specific surface area which could promote dispersion of abundant Mn〈sup〉4+〈/sup〉 and Co〈sup〉3+〈/sup〉 species, and resultantly afforded stronger redox ability and more acid sites. Moreover, dynamic calculation confirmed that the relatively lower activation energy on MnO〈sub〉2〈/sub〉/CoAl-LDO for low-temperature NH〈sub〉3〈/sub〉-SCR reaction should be closely related to the occurrence of a more rapid redox cycle and in agreement with the excellent DeNOx performance.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0169433218329702-ga1.jpg" width="413" alt="Graphical abstract for this article" title=""〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 15 February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Applied Surface Science, Volumes 467–468〈/p〉 〈p〉Author(s): Sandra Jendrzej, Leonard Gondecki, Jörg Debus, Henning Moldenhauer, Peter Tenberge, Stephan Barcikowski, Bilal Gökce〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The lubricant is a central element in the transmission design. It primarily separates the two contact partners through a pressure-induced solidification in the lubrication gap, thus enabling the operation of heavily loaded sliding-rolling contacts. On the one hand, the quality and properties of a lubricant depend on the base oils, which differ by their viscosity and process-technological parameters. The addition of particulate additives gives the lubricants further functional properties that are not contained in the base oil. In this study, the influence of laser-synthesized yttria-stabilized zirconia nano- or submicrometer spheres as dispersed functional elements in the lubricant is studied, and their impact on wear and fatigue on the tooth flank is investigated. The work includes systematic investigations on the influence of the particle’s shape and size by running tests on a FZG gear test rig. Finally, the potential of the laser-generated particles as a lubricant additive is evaluated in a first conclusion.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Nuclear Materials, Volume 513〈/p〉 〈p〉Author(s): Matic Pečovnik, Sabina Markelj, Anže Založnik, Thomas Schwarz-Selinger〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The influence of grain size on deuterium transport and retention in tungsten was studied. For this purpose an experiment was carried out on three polycrystalline tungsten samples with different grain sizes and a single crystal sample with surface orientation 〈100〉. In order to increase deuterium retention and hence the sensitivity for detection, samples were first damaged by high energy W ions. After damaging, the samples were exposed to a flux of deuterium atoms at 600 K for 70 h. During the exposure the depth profile of the retained deuterium was measured by Nuclear Reaction Analysis using a 〈sup〉3〈/sup〉He ion beam. After the exposure the samples were also analysed by Thermal Desorption Spectroscopy. A clear difference in the time dependence of deuterium uptake was noticed between different samples. The experimental results were modeled using a rate-equation model. The influence of different grain size was modeled by changing the effective height of the potential barrier for deuterium atoms to enter into the bulk. We managed to successfully describe the transport of deuterium into the bulk of tungsten by reducing the potential barrier for samples with smaller grain sizes while the barrier for the sample with larger grain size was close to the value for the damaged single crystal sample.〈/p〉〈/div〉 〈/div〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0022311518307256-fx1.jpg" width="256" alt="Image 1" title="Image 1"〉〈/figure〉〈/p〉〈/div〉

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Nuclear Materials, Volume 513〈/p〉 〈p〉Author(s): P.A. Burr, E. Kardoulaki, R. Holmes, S.C. Middleburgh〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The stability, diffusivity and clustering behaviour of defects in uranium diboride (UB〈sub〉2〈/sub〉) was investigated in light of the potential application as a burnable absorber in nuclear fuel. UB〈sub〉2〈/sub〉 was found to accommodate limited deviations from stoichiometry, which should be a consideration when manufacturing and operating the material. Self-diffusivity of both U and B was found to be sluggish (10〈sup〉−14〈/sup〉 cm〈sup〉2〈/sup〉/s for B and 10〈sup〉−19〈/sup〉 cm〈sup〉2〈/sup〉/s for U at 2000K) and highly anisotropic, with migration along the basal planes being orders of magnitude faster than 〈em〉c〈/em〉-axis migration. The anisotropy of defect migration (both interstitials and vacancies) is predicted to hinder recombination of defects produced by collision cascades, thus limiting the radiation tolerance of the material. Boron and uranium vacancies exhibit a drive to cluster. Boron vacancies in particular, which are mobile on basal planes, are predicted to cluster into strongly bound di-vacancy, which in turn are less mobile. These are then predicted to grow into larger two-dimensional vacancy clusters on the B plane, leading to anisotropic swelling. We provide an analytical expression to predict the stability of these clusters based on purely geometrical considerations. Finally, the accommodation of Li, He and Xe onto vacancy clusters was considered. Li appears to stabilise the structure upon U depletion, while the retention of He and Xe appears to rise with increasing B depletion, through the formation of vacancy clusters.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 1 February 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Physica B: Condensed Matter, Volume 554〈/p〉 〈p〉Author(s): D. Bessas, I. Kantor, D. Bourazani, K. Georgalas, N. Biniskos, L. Zhang, A.I. Dugulan, E. Syskakis〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Bulk Sr〈sub〉2〈/sub〉PdO〈sub〉3〈/sub〉 was synthesized by a modified solid state reaction and a detailed characterization was carried out using both microscopic and macroscopic experimental techniques. Pd site exhibits an electric field gradient of 5.9(1) ⋅ 10〈sup〉17〈/sup〉 V/cm〈sup〉2〈/sup〉 due to the anisotropic local atomic configuration. A Curie - paramagnetic susceptibility indicating antiferromagnetic interactions superimposed to a core diamagnetic state is confirmed. A linear volume thermal expansion with a coefficient of 3.0(1) ⋅ 10〈sup〉−5〈/sup〉 K〈sup〉−1〈/sup〉 at room temperature is extracted. A collection of Einstein oscillators, with an Einstein temperature of about 115 K, is involved in the thermal transport. Large atomic displacements were observed in Sr vibrations. No Pd or Sr valence change is observed up to 900 K. A moderate anharmonicity is identified and quantified in a macroscopic Grüneisen parameter of 2.5(1) at room temperature. The electrical resistivity reveals a semiconducting behaviour. A systematic reduction in electrical resistivity and a change in the conduction mechanism is observed upon thermal cycling which indicates that a peculiar electronic mechanism is involved.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: Available online 1 November 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment〈/p〉 〈p〉Author(s): S. Monzani, A. Andreazza, M. Citterio, P. Fontana, M. Ianna, T. Lari, V. Liberali, F. Ragusa, C. Sbarra, A. Sidoti, A. Stabile〈/p〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Monochromatic X and gamma rays are a standard calibration tool for semiconductor detector. For finely segmented pixel detectors, like the ones foreseen for HL-LHC detector upgrades, the single pixel spectrum is affected by charge sharing across nearby pixels, due to diffusion and the finite range of photoelectrons, resulting in a low energy continuum below the photoelectric peak. In this paper a systematic simulation study will be presented. The shape of the transition between the photoelectric peak and the continuum is determined by diffusion and needs to be unfolded for a correct estimation of the energy resolution. Simulation results are compared with data collected with different high-resistivity CMOS devices with 50 × 250 〈math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll" altimg="si1.gif"〉〈mi mathvariant="normal"〉μ〈/mi〉〈/math〉m〈sup〉2〈/sup〉 pixel size and photon energies between 13 and 60 keV. They show a good agreement, highlighting the potential usage of the whole single pixel spectrum to derive device characteristics.〈/p〉〈/div〉

Beschreibung: 〈p〉Publication date: 1 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 501〈/p〉 〈p〉Author(s): G. Gorni, M.J. Pascual, A. Caballero, J.J. Velázquez, J. Mosa, Y. Castro, A. Durán〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The crystallization mechanism of LaF〈sub〉3〈/sub〉 in sol-gel oxyfluoride glass-ceramics in the system SiO〈sub〉2〈/sub〉-LaF〈sub〉3〈/sub〉 has been studied using DTA, XRD, FTIR, HRTEM and NMR. Based on classical calculations of non-isothermal DTA curves involving Ozawas's plots, a diffusion-controlled process should be responsible for the fluorides crystallization similarly to that obtained for melt-quenching oxyfluoride glass-ceramics. Therefore, an increase of the crystal size and fraction is expected when increasing the time and/or temperature of the treatment. Nevertheless, XRD, FIR, HRTEM and NMR demonstrated that neither bigger crystals nor higher crystal fraction are obtained for treatment times longer than 1 min at 550 °C. However, further heat treatment causes that the structural order of the crystals is lost. On the other hand, typical fluorides crystallization temperatures (~300 °C) in sol-gel materials are much lower than T〈sub〉g〈/sub〉 of the matrix (~1130 °C) thus being very different to what observed for oxyfluoride glasses prepared by melt-quenching. The proposed crystallization mechanism is a fast process that occurs when crystallization temperature is reached. This behavior is explained as a chemical reaction from the xerogels, followed by the fast precipitation of the nanocrystals without energy barrier. The nanocrystals are unstable in the surrounding SiO〈sub〉2〈/sub〉 matrix for aging at crystallization or higher temperatures. These treatments lead to a dissolution process, favored by the compositional gradient between matrix and crystals, which drive the material to reach the equilibrium.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: 1 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 501〈/p〉 〈p〉Author(s): Jürn W.P. Schmelzer, Alexander S. Abyzov, Vladimir M. Fokin, Christoph Schick〈/p〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉General relations for the dependence of the thermodynamic driving force of crystallization and the specific interfacial energy melt-crystal of critical crystal clusters on temperature and pressure are derived. Its application to the analysis of experimental data on crystal nucleation seems to support at a first glance a proposal by Kauzmann on the existence of a pseudo-spinodal curve in melt-crystallization. Provided this assumption is true, Kauzmann temperature (and for pressure-induced nucleation, the Kauzmann pressure) cannot be reached by a metastable liquid due to intensive crystallization processes occurring in its vicinity. However, such suggestion cannot be retained taking into account the kinetic terms (diffusion coefficients, viscosity) in the expression for the nucleation rate. The absence of a pseudo-spinodal in melt-crystallization can be verified also in an alternative way by considering the characteristic time scales of crystallization and relaxation. Finally, it is shown that the phenomenon denoted commonly as Kauzmann paradox is merely an untypical as compared to normal conditions type of behavior. Neither in its original formulation nor in its consequences it results in any contradictions with basic laws of nature. They are prevented either by normal (not associated with a pseudo-spinodal) crystallization or a conventional glass transition.〈/p〉〈/div〉

Beschreibung: 〈p〉Publication date: 1 December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Journal of Non-Crystalline Solids, Volume 501〈/p〉 〈p〉Author(s): J. Gilabert, M.P. Gómez-Tena, V. Sanz, S. Mestre〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉 〈p〉The effect of a post-synthesis thermal treatment on CoCr〈sub〉2−2Ψ〈/sub〉Al〈sub〉2Ψ〈/sub〉O〈sub〉4〈/sub〉 (0.0 ≤ Ψ ≤ 1.0) ceramic pigments synthesized by Solution Combustion Synthesis (SCS) has been studied. As-synthesized SCS pigments were treated at two different calcination temperatures (800 °C and 1000 °C) to study changes in mineralogy, microstructure and thermal behaviour, as well as their effect over the colouring power.〈/p〉 〈p〉Spinel-type 〈em〉Fd〈/em〉-3〈em〉m〈/em〉 crystalline structure was developed in all cases. Nevertheless, crystallinity parameters were highly affected by both analysed processing parameters: composition (Ψ) and post-synthesis calcination temperature (T〈sub〉c〈/sub〉). A Cr(III) enrichment along with T〈sub〉c〈/sub〉 increase favoured ion rearrangement to promote sample crystallization and crystallite growth. Fast kinetics of SCS makes Al-rich spinels with transition metals difficult to be synthesized. The application of a secondary thermal treatment resulted in a favourable evolution towards a well-crystallized structure. Lattice parameter did not seem to be affected by T〈sub〉c〈/sub〉, although it evolved indeed with composition. From a microstructural point of view, as-synthesized pigments were foamy, with a very low bulk density and nanometric grain size. After the thermal treatment, larger grain sizes were obtained, especially for the samples richer in Al and treated at higher T〈sub〉c〈/sub〉.〈/p〉 〈p〉All pigments developed intense colours in a transparent glaze without showing heterogeneities, indicating a stable behaviour against glazing process. Glaze colour evolved from green to perfectly blue shades, indicating an important dependence on composition. Nevertheless, colouring power seemed to be rather affected by calcination process.〈/p〉 〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: December 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Radiation Measurements, Volume 119〈/p〉 〈p〉Author(s): Alessio Parisi, Luana de Freitas Nascimento, Olivier Van Hoey, Patrice Mégret, Hisashi Kitamura, Satoshi Kodaira, Filip Vanhavere〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Lithium fluoride thermoluminescent radiation detectors with different dopant concentrations (〈sup〉7〈/sup〉LiF:Mg,Ti and 〈sup〉7〈/sup〉LiF:Mg,Cu,P) were exposed to 〈sup〉1〈/sup〉H and 〈sup〉4〈/sup〉He ions at the Heavy Ion Medical Accelerator in Chiba (HIMAC) in order to investigate their response to energetic light charged particles. Computer simulations with the Monte Carlo code PHITS were performed for a better interpretation of the experimental data. The results were compared with literature efficiency data and with the results of a recently developed microdosimetric efficiency model. In case of the main peak signal of 〈sup〉7〈/sup〉LiF:Mg,Ti detectors, the determined efficiency values are in good agreement with previous investigations. Discrepancies in the efficiency of high temperature signal due to well-known non-linearity effects are reported. For 〈sup〉7〈/sup〉LiF:Mg,Cu,P detectors, an anomalous thermoluminescence behavior in the low temperature part of the signal was found and discussed. Depending on the light quantification process, differences up to 30% in the dose assessment can be obtained, affecting also the relative efficiency determination process. An explanation of this phenomenon as a consequence of local migration of the charged carriers between the low temperature peaks and the main peak is presented. The implications of these findings on the use of LiF:Mg,Cu,P detectors in radiation environments characterized by the presence of 〈sup〉1〈/sup〉H and 〈sup〉4〈/sup〉He ions (i.e. space and proton therapy) are discussed. In order to avoid the occurrence of this anomalous behavior, it is advised to pre-heat the detectors after energetic light particle exposures.〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: Available online 31 October 2018〈/p〉 〈p〉〈b〉Source:〈/b〉 Soil Dynamics and Earthquake Engineering〈/p〉 〈p〉Author(s): Vladimir A. Osinov, Stylianos Chrisopoulos, Theodoros Triantafyllidis〈/p〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉The paper presents a numerical analysis of the dynamic deformation of the tunnel lining and the soil caused by a blast-induced pressure pulse of a moderate amplitude (several megapascals) inside the tunnel. The tunnel lining is circular and consists of individual concrete linearly elastic tubbings. The tunnel is located at a depth of 15 m in fully saturated granular soil. Effective-stress changes are described by a hypoplasticity model. The possibility of pore water cavitation at zero absolute pore pressure is taken into account. The problem is solved in a two-dimensional plane-strain formulation with the finite-element program Abaqus/Standard. Emphasis is placed on fine spatial discretization in order to obtain accurate solutions. Stresses and deformations in the lining and in the soil are analysed in detail. The solutions reveal an important role of the strong nonlinearity in the soil behaviour due to the pore water cavitation.〈/p〉〈/div〉

Beschreibung: 〈p〉Publication date: 15 January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Palaeogeography, Palaeoclimatology, Palaeoecology, Volume 514〈/p〉 〈p〉Author(s): Mahasin Ali Khan, Meghma Bera, Robert A. Spicer, Teresa E.V. Spicer, Subir Bera〈/p〉 〈div xml:lang="en"〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Fossil leaf floras, from the latest Miocene-Pliocene Siwalik Group exposed in Bhutan, sub-Himalaya, are subjected to a CLAMP (Climate Leaf Analysis Multivariate Program) analysis using a high-resolution gridded climate calibration. The CLAMP analysis of 27 different morphotypes of fossil leaves indicates a mean annual temperature (MAT) of 24.1 °C ± 2.8 °C; a cold month mean temperature (CMMT) of 18.9 °C ± 4 °C and a warm month mean temperature (WMMT) of 27.8 °C ± 3.3 °C. The analysis also suggests a weak monsoonal climate (the monsoon index, MSI 46.7; present MSI 52) with growing season precipitation (GSP) of 1819 ± 916 mm (present GSP 2490 mm). Here we also compare palaeoclimate estimates of the latest Miocene-Pliocene Siwalik Group flora from Bhutan (c. 6 to 3.8 Ma) with those of previously investigated Siwalik Group floras from the Miocene-Pleistocene of Arunachal, India and Miocene Siwalik floras of Darjeeling, India which characterise the monsoon signature at the time of deposition. Since all the Siwalik floras of the eastern Himalaya (Darjeeling and Arunachal Pradesh) spanning the mid-Miocene to Pleistocene yield almost the same values we suggest that overall the eastern Himalayan Siwalik climate appears to have been remarkably uniform over the past 15 million years. The MAT result of the Bhutan Siwalik flora differs by just 0.6 °C from Arunachal and 1.2 °C from Darjeeling Siwalik floras. For all Siwalik fossil assemblages, WMMTs, CMMTs and LGSs (length of the growing season) are similar and consistent (WMMTs around 28 °C, CMMTs around 18 °C and LGSs around 12 months). Similarly, the mean annual relative humidity (RH) and specific humidity (SH) appear to have been uniformly around 80% and 14 g/kg respectively throughout the Neogene of the eastern Himalayan Siwaliks. Changes in the monsoon index suggest that in both Bhutan and Arunachal sub-Himalaya, there has been little change in the intensity of the monsoon since mid-Miocene time, while further west in the Darjeeling area precipitation seasonality has increased since the mid-Miocene.〈/p〉〈/div〉 〈/div〉 〈div xml:lang="en"〉 〈h5〉Graphical abstract〈/h5〉 〈div〉〈p〉〈figure〉〈img src="https://ars.els-cdn.com/content/image/1-s2.0-S0031018218303523-ga1.jpg" width="327" alt="Unlabelled Image" title="Unlabelled Image"〉〈/figure〉〈/p〉〈/div〉 〈/div〉

Beschreibung: 〈p〉Publication date: January 2019〈/p〉 〈p〉〈b〉Source:〈/b〉 Remote Sensing of Environment, Volume 220〈/p〉 〈p〉Author(s): Xiyu Chen, Lin Liu, Annett Bartsch〈/p〉 〈h5〉Abstract〈/h5〉 〈div〉〈p〉Microwave remote sensing, both active or passive, can provide useful information about the freeze/thaw (F/T) state of soil near the surface. Here we apply an edge detection algorithm on time series of indicators derived from measurements of SMAP L-band radiometer and ASCAT C-band scatterometer to detect the freeze/thaw onsets of surface soil. Comparing these results against the onsets derived from in situ measurements in Alaska, we demonstrate that this algorithm is an effective approach to detect onsets of the soil F/T transition. More specifically, our results show that the thawing onsets estimated from the SMAP data occurred 5 to 13 days earlier than the onsets estimated from the in situ measurements, which is likely due to the influence of snowmelt on the radiometer signal. The thawing onsets estimated from the ASCAT data were about 6 days later than the in situ onsets. Our estimated freezing onsets from each microwave remote sensing dataset were close to the in situ onsets (1–5 days). We also compare our estimated onsets with those from the SMAP Level 3 F/T product and the mean biases for thawing and freezing onsets are 1 ± 2 and 1 ± 3 days, respectively. Furthermore, we illustrate the complementary nature of the SMAP and ASCAT measurements and the potential for combining these two to differentiate snowmelt from soil thawing events.〈/p〉〈/div〉