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  • Articles  (1,086)
  • Hindawi  (1,032)
  • American Association for the Advancement of Science
  • Copernicus
  • 2010-2014  (1,086)
  • 1965-1969
  • 1925-1929
  • 2013  (1,086)
  • Energy, Environment Protection, Nuclear Power Engineering  (1,086)
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  • Articles  (1,086)
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  • 2010-2014  (1,086)
  • 1965-1969
  • 1925-1929
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  • 1
    Publication Date: 2013-09-11
    Description: We used a one-dimensional simulation program Solar Cell Capacitance Simulator in 1 Dimension (SCAPS-1D) to investigate Copper-Indium-Gallium-Diselenide- (CIGS-) based solar cells properties. Starting with a conventional ZnO-B/i-ZnO/CdS/CIGS structure, we simulated the parameters of current-voltage characteristics and showed how the absorber layer thickness, hole density, and band gap influence the short-circuit current density (), open-circuit voltage (), fill factor (FF), and efficiency of solar cell. Our simulation results showed that all electrical parameters are greatly affected by the absorber thickness (w) below 1000 nm, due to the increase of back-contact recombination and very poor absorption. Increasing hole density (p) or absorber band gap () improves and leads to high efficiency, which equals value of 16.1% when p = 1016 cm−3 and  eV. In order to reduce back-contact recombination, the effect of a very thin layer with high band gap inserted near the back contact and acting as electrons reflector, the so-called back-electron reflector (EBR), has been investigated. The performances of the solar cells are significantly improved, when ultrathin absorbers (w 〈 500 nm) are used; the corresponding gain of due to the EBR is 3 mA/cm2. Our results are in good agreement with those reported in the literature from experiments.
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  • 2
    Publication Date: 2013-09-11
    Description: The work presents comparisons of the flame stabilization characteristics of axisymmetric disk and 2D slender bluff-body burner configurations, operating with inlet mixture stratification, under ultralean conditions. A double cavity propane air premixer formed along three concentric disks, supplied with a radial equivalence ratio gradient the afterbody disk recirculation, where the first flame configuration is stabilized. Planar fuel injection along the center plane of the leading face of a slender square cylinder against the approach cross-flow results in a stratified flame configuration stabilized alongside the wake formation region in the second setup. Measurements of velocities, temperatures, and chemiluminescence, local extinction criteria, and large-eddy simulations are employed to examine a range of ultralean and close to extinction flame conditions. The variations of the reacting front disposition within these diverse reacting wake topologies, the effect of the successive suppression of heat release on the near flame region characteristics, and the reemergence of large-scale vortical activity on approach to lean blowoff (LBO) are investigated. The cross-correlation of the performance of these two popular flame holders that are at the opposite ends of current applications might offer helpful insights into more effective control measures for expanding the operational margin of a wider range of stabilization configurations.
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    Electronic ISSN: 2090-1976
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  • 3
    Publication Date: 2013-09-11
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  • 4
    Publication Date: 2013-09-12
    Description: Changes of antioxidant properties of -lipoic acid (LA) after UV irradiation were studied. LA is the typical drug used in diabetic neuropathy. Quenching of free radicals is an important factor of therapy by using this substance. -Lipoic acid is exposed to UV irradiation during the storage. The aim of our studies was to examine the effect of UV irradiation on the interactions of LA with free radicals. The -lipoic acid was irradiated by UVA 315–400 nm light during 10 to 110 minutes by intervals of 10 minutes. The electron paramagnetic resonance spectroscopy was used as the experimental technique. The antioxidant properties of LA were spectroscopically confirmed. The strong effect of UV irradiation on interactions of -lipoic acid with free radicals was observed. It was pointed out that interactions of LA with free radicals decrease after its exposition on UV. The interactions of LA with free radicals were higher after the sample irradiation during 10 minutes than for the samples irradiated longer (20–110 minutes). The results are important for problems connected with photomedicine; they pointed out that -lipoic acid should not be stored on UV exposition. Application of electron paramagnetic resonance spectroscopy to characterize interactions of pharmacological substance with free radicals was confirmed.
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  • 5
    Publication Date: 2013-09-12
    Description: Copper antimony sulfide (CAS) is a relatively new class of sustainable absorber material, utilizing cost effective and abundant elements. Band gap engineered, modified CAS thin films were synthesized using electrodeposition and elevated temperature sulfurization approach. A testing analog of copper zinc antimony sulfide (CZAS) film-electrolyte interface was created in order to evaluate photoelectrochemical performance of the thin film of absorber materials. Eu3+/Eu2+ redox couple was selected for this purpose, based on its relative band offset with copper antimony sulfide. It was observed that zinc has a significant effect on CAS film properties. An enhanced photocurrent was observed for CAS film, modified with zinc addition. A detailed investigation has been carried out by changing stoichiometry, and corresponding surface and optical characterization results have been evaluated. A summary of favorable processing parameters of the films showing enhanced photoelectrochemical response is presented.
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  • 6
    Publication Date: 2013-09-12
    Description: In CdS/CdTe solar cells, chemical interdiffusion at the interface gives rise to the formation of an interlayer of the ternary compound . In this work, we evaluate the effects of this interlayer in CdS/CdTe photovoltaic cells in order to improve theoretical results describing experimental - (capacitance versus voltage) characteristics. We extended our previous theoretical methodology developed on the basis of three cardinal equations (Castillo-Alvarado et al., 2010). The present results provide a better fit to experimental data obtained from CdS/CdTe solar cells grown in our laboratory by the chemical bath deposition (for CdS film) and the close-spaced vapor transport (for CdTe film) techniques.
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  • 7
    Publication Date: 2013-09-12
    Description: In a silicon wafer-based photovoltaic (PV) module, significant power is lost due to current transport through the ribbons interconnecting neighbour cells. Using halved cells in PV modules is an effective method to reduce the resistive power loss which has already been applied by some major PV manufacturers (Mitsubishi, BP Solar) in their commercial available PV modules. As a consequence, quantitative analysis of PV modules using halved cells is needed. In this paper we investigate theoretically and experimentally the difference between modules made with halved and full-size solar cells. Theoretically, we find an improvement in fill factor of 1.8% absolute and output power of 90 mW for the halved cell minimodule. Experimentally, we find an improvement in fill factor of 1.3% absolute and output power of 60 mW for the halved cell module. Also, we investigate theoretically how this effect confers to the case of large-size modules. It is found that the performance increment of halved cell PV modules is even higher for high-efficiency solar cells. After that, the resistive loss of large-size modules with different interconnection schemes is analysed. Finally, factors influencing the performance and cost of industrial halved cell PV modules are discussed.
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  • 8
    Publication Date: 2013-09-12
    Description: In three-phase photovoltaic (PV) system, three-phase filter inductors are important part for the output electrical power quality. The comparison analyses of three-phase discrete filter inductors and two kinds of three-phase integrated filter inductors in three-phase PV inverter are proposed. Firstly, the three-phase PV inverter operation with discrete filter inductors is analyzed, and the design of discrete filter inductors is given; then operation of the three-phase PV inverter with three-phase integrated five-limb magnetic core filter inductors is analyzed, the design of integrated filter inductors with five-limb magnetic core is given, then the operation of three-phase PV inverter with three-phase integrated three-limb magnetic core filter inductors is analyzed, and the design of integrated filter inductors with three limbs magnetic core is given. The conclusion of comparison between three-phase discrete filter inductors and two kinds of three-phase integrated filter inductors is done; it means that the three-phase discrete filter inductors can achieve better output electrical power quality with lower power density and three-phase integrated filter inductors can achieve higher power density with lower output electrical power quality. Finally, the experiment results are given to compare the volume and filter effect of three kinds of filter inductors in three-phase PV inverter.
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  • 9
    Publication Date: 2013-09-13
    Description: Composite silicon dioxide-titanium dioxide (SiO2-TiO2) films are deposited on a large area of 15.6 × 15.6 cm2 textured multicrystalline silicon solar cells to increase the incident light trapped within the device. For further improvement of the antireflective coatings (ARCs) quality, dimethylformamide (DMF) solution is added to the original SiO2-TiO2 solutions. DMF solution solves the cracking problem, thus effectively decreasing reflectance as well as surface recombination. The ARCs prepared by sol-gel process and plasma-enhanced chemical vapor deposition (PECVD) on multicrystalline silicon substrate are compared. The average efficiency of the devices with improved sol-gel ARCs is 16.3%, only 0.5% lower than that of devices with PECVD ARCs (16.8%). However, from equipment depreciation point of view (the expiration date of equipment is generally considered as 5 years), the running cost (USD/watt) of sol-gel technique is 80% lower than that of PECVD method for the first five years and 66% lower than that of PECVD method from the start of the sixth year. This result proves that sol-gel-deposited ARCs process has potential applications in manufacturing low-cost, large-area solar cells.
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  • 10
    Publication Date: 2013-09-19
    Description: The use of liquefied petroleum gas (LPG) is experimented with to improve the performance of a dual fuel compression ignition (CI) engine running on Karanja oil methyl ester (KOME) blends. Diesel is used as a reference fuel for the dual fuel engine results. During the experimentation, the engine performance is measured in terms of brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC), and exhaust emission is measured in terms of carbon monoxide (CO), hydrocarbon (HC), and oxides of nitrogen (). Dual fuel engine with LPG showed a reduction in and smoke emission; however, it suffers from high HC and CO emission, particularly, at lower loads due to poor ignition. Comparison of performance and emissions is done for diesel and blends of KOME. Results showed that using KOME blends (10% and 20%) has improved the CI engine performance with a reduction in HC and CO emissions.
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  • 11
    Publication Date: 2013-09-20
    Description: n-type ZnO:Cu photoanodes were fabricated by simple spray pyrolysis deposition technique. Influence of low concentration (range ~10−4–10−1%) of Cu doping in hexagonal ZnO lattice on its photoelectrochemical performance has been investigated. The doped photoanodes displayed 7-time enhanced conversion efficiencies with respect to their undoped counterpart, as estimated from the photocurrents generated under simulated solar radiation. This is the highest enhancement in the solar conversion efficiency reported so far for the Cu-doped ZnO. This performance is attributed to the red shift in the band gap of the Cu-doped films and is in accordance with the incident-photon-current-conversion efficiency (IPCE) measurements. Electrochemical studies reveal an n-type nature of these photoanodes. Thus, the study indicates a high potential of doped ZnO films for solar energy applications, in purview of the development of simple nanostructuring methodologies.
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  • 12
    Publication Date: 2013-09-25
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  • 13
    Publication Date: 2013-09-29
    Description: The singularly perturbed method (SPM) is proposed to obtain the analytical solution for the delayed supercritical process of nuclear reactor with temperature feedback and small step reactivity inserted. The relation between the reactivity and time is derived. Also, the neutron density (or power) and the average density of delayed neutron precursors as the function of reactivity are presented. The variations of neutron density (or power) and temperature with time are calculated and plotted and compared with those by accurate solution and other analytical methods. It is shown that the results by the SPM are valid and accurate in the large range and the SPM is simpler than those in the previous literature.
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  • 14
    Publication Date: 2013-09-29
    Description: An innovative process for fission based 99Mo production has been developed under Isotope Technologies Dresden (ITD) GmbH (former Hans Wälischmiller GmbH (HWM), Branch Office Dresden), and its functionality has been tested and proved at the Pakistan Institute of Nuclear Science and Technology (PINSTECH), Islamabad. Targets made from uranium aluminum alloy clad with aluminum were irradiated in the core of Pakistan Research Reactor-1 (PARR-1). In the mean time more than 50 batches of fission molybdenum-99 (99Mo) have been produced meeting the international purity/pharmacopoeia specifications using this ROMOL-99 process. The process is based on alkaline dissolution of the neutron irradiated targets in presence of NaNO3, chemically extracting the 99Mo from various fission products and purifying the product by column chromatography. This ROMOL-99 process will be described in some detail.
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  • 15
    Publication Date: 2013-10-01
    Description: This paper represents a novel modeling technique of PV module with a fuzzy logic based MPPT algorithm and boost converter in Simulink environment. The prime contributions of this work are simplification of PV modeling technique and implementation of fuzzy based MPPT system to track maximum power efficiently. The main highlighted points of this paper are to demonstrate the precise control of the duty cycle with respect to various atmospheric conditions, illustration of PV characteristic curves, and operation analysis of the converter. The proposed system has been applied for three different PV modules SOLKAR 36 W, BP MSX 60 W, and KC85T 87 W. Finally the resultant data has been compared with the theoretical prediction and company specified value to ensure the validity of the system.
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  • 16
    Publication Date: 2013-10-01
    Description: The study investigated the potential of water hyacinths and phytoplankton scum, an aquatic weed, as binder for production of fuel briquettes. It also evaluated some physical and combustion characteristics. The water hyacinths were manually harvested, cleaned, sun-dried, and milled to particle sizes distribution ranging from
    Print ISSN: 2090-1968
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  • 17
    Publication Date: 2013-10-03
    Description: A chitosan binder-based TiO2 photoelectrode is used in dye-sensitized solar cells (DSSCs). Field-emission scanning electron microscope (FE-SEM) images revealed that the grain size, thickness, and distribution of TiO2 films are affected by the chitosan content. With addition of 2.0 wt% chitosan to the TiO2 film (D2), the surface pore size became the smallest, and the pores were fairly evenly distributed. The electron transit time, electron recombination lifetime, diffusion coefficient, and diffusion length were analyzed by IMVS and IMPS. The best DSSC, with 2.0 wt% chitosan addition to the TiO2 film, had a shorter electron transit time, longer electron recombination lifetime, and larger diffusion coefficient and diffusion length than the other samples. The results of 2.0 wt% chitosan-added TiO2 DSSCs are an electron transit time of  s, electron recombination lifetime of  s, diffusion coefficient of  cm2 s−1, diffusion length of 14.81 μm, and a solar conversion efficiency of 4.18%.
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  • 18
    Publication Date: 2013-10-03
    Description: Nitrogen modified zinc sulfide photocatalysts were successfully prepared and characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), and surface area analysis. Thermal decomposition of the semisolid was carried out under nitrogen conditions at 500°C for 2 hours, and a series of nitrogen-doped ZnS photocatalysts were produced by controlling inflow flow rate of nitrogen at 15–140 mL/min. Optical characterizations of the synthesized N-doping ZnS substantially show the shifted photoabsorption properties from ultraviolet (UV) region to visible light. The band gaps of nitrogen-doped ZnS composite catalysts were calculated to be in the range of 2.58~2.74 eV from the absorptions edge position. The 15N/ZnS catalyst shows the highest photocatalytic activity, which results in 75.7% degradation of Orange II dye in 5 hrs by visible light irradiation, compared with pristine ZnS and higher percentage N-doping ZnS photocatalysts.
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  • 19
    Publication Date: 2013-10-03
    Description: This paper considers a composite cylindrical structure, with low-enriched uranium (LEU) foil enclosed between two aluminum 6061-T6 cylinders. A recess is cut all around the outer circumference of the inner tube to accommodate the LEU foil of open-cross section. To obtain perfect contact at the interfaces of the foil and the tubes, an internal pressure is applied to the inner tube, thereby plastically and elastically deforming it. The residual stresses resulting from the assembly process are used along with a thermal stress model to predict the stress margins in the cladding during irradiation. The whole process was simulated as a steady-state two-dimensional problem using the commercial finite element code Abaqus FEA. The irradiation behavior of the annular target has been presented, and the effect of the assembly residual stresses has been discussed.
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  • 20
    Publication Date: 2013-09-09
    Description: Diamond-like carbon films were electrodeposited on n-Si substrate to realize an n-Si/DLC PV structure. The films thus obtained were characterized by FESEM, XPS, FTIR, and Raman studies. Solar cell characteristics were also investigated critically. Maximum efficiency of 3.7% was obtained for the best n-Si(100)/DLC structure. Carrier life time was obtained from decay measurement. It was observed that photoinduced charge separation in n-Si(100)/DLC structure was associated with an increase in the dielectric constant and a decrease in the device resistance. The process, being reproducible, cheap, and scalable, involving significantly less process steps, is likely to usher a new hope to the current competitive scenario of PV technology.
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  • 21
    Publication Date: 2013-09-11
    Description: Molybdenum-99 is the parent of Technetium-99m, which is used in nearly 80% of all nuclear medicine procedures. The medical community has been plagued by Mo-99 shortages due to aging reactors, such as the NRU (National Research Universal) reactor in Canada. There are currently no US producers of Mo-99, and NRU is scheduled for shutdown in 2016, which means that another Mo-99 shortage is imminent unless a potential domestic Mo-99 producer fills the void. Argonne National Laboratory is assisting two potential domestic suppliers of Mo-99 by examining the effects of a uranyl nitrate versus a uranyl sulfate target solution configuration on Mo-99 production. Uranyl nitrate solutions are easier to prepare and do not generate detectable amounts of peroxide upon irradiation, but a high radiation field can lead to a large increase in pH, which can lead to the precipitation of fission products and uranyl hydroxides. Uranyl sulfate solutions are more difficult to prepare, and enough peroxide is generated during irradiation to cause precipitation of uranyl peroxide, but this can be prevented by adding a catalyst to the solution. A titania sorbent can be used to recover Mo-99 from a highly concentrated uranyl nitrate or uranyl sulfate solution; however, different approaches must be taken to prevent precipitation during Mo-99 production.
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  • 22
    Publication Date: 2013-09-12
    Description: We report results of combined experimental and theoretical studies of black tea waste extract (BTE) as a potential sensitizer for TiO2-dye-sensitized solar cells (DSSCs). UV-vis absorption data revealed that BTE contains theaflavin. DSSC sensitized with pigment complexes of BTE showed a photon-energy conversion efficiency of %, while a significant increase (%) is observed when pH of the pigment solution was lowered. The HOMO and LUMO energy levels were calculated using experimental data of UV-vis absorption and cyclic voltammetry. These calculations revealed a reduction of the band gap by 0.17 eV and more negativity of HOMO level of acidified pigment, compared to that of original pigment. Combined effect of these developments caused the enhanced efficiency of DSSC. Density functional theory (DFT) and time-dependent density functional theory (TDDFT) computational calculations were carried out to study the four theaflavin analogues which are responsible for the dark colour of BTE. According to the calculations, two theaflavin analogues, theaflavin and theaflavin digallate, are the most probable sensitizers in this dye-sensitized solar cell system.
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  • 23
    Publication Date: 2013-09-13
    Description: Piecewise linear parabolic trough collector (PLPTC) is designed and developed to concentrate solar radiation on monocrystalline silicon based photovoltaic module. A theoretical model is used to perform electrical energy and exergy analysis of low-concentration photovoltaic (LCPV) system working under actual test conditions (ATC). The exergy efficiency of LCPV system is in the range from 5.1% to 4.82% with increasing rate of input exergy rate from 30.81 W to 96.12 W, when concentration ratio changes from 1.85 to 5.17 Sun. Short-circuit current shows increasing trend with increasing input exergy rate of ≈0.011 A/W. Power conversion efficiency decreases from 7.07 to 5.66%, and open-circuit voltage decreases from 9.86 to 8.24 V with temperature coefficient of voltage  V/K under ATC. The results confirm that the commercially available silicon solar PV module performs satisfactorily under low concentration.
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  • 24
    Publication Date: 2013-09-18
    Description: Effects on the optical, electrical, and photocatalytic properties of undoped CuS thin films nanodisks vacuum annealed at different temperatures were investigated. The chemical bath prepared CuS thin films were obtained at 40°C on glass substrates. The grain size of  nm was computed directly from high-resolution transmission electron microscopy (HRTEM) images. The electrical properties were measured by means of both Hall effect at room temperature and dark resistivity as a function of the absolute temperature 100–330 K. The activation energy values were calculated as 0.007, 0.013, and 0.013 eV for 100, 150, and 200°C, respectively. The energy band gap of the films varied in the range of 1.98 up to 2.34 eV. The photocatalytic activity of the CuS thin film was evaluated by employing the degradation of aqueous methylene blue solution in the presence of hydrogen peroxide. The CuS sample thin film annealed in vacuum at 150°C exhibited the highest photocatalytic activity in presence of hydrogen peroxide.
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  • 25
    Publication Date: 2013-09-19
    Description: The removal of volatile radionuclides generated during used nuclear fuel reprocessing in the US is almost certain to be necessary for the licensing of a reprocessing facility in the US. Various control technologies have been developed, tested, or used over the past 50 years for control of volatile radionuclide emissions from used fuel reprocessing plants. The US DOE has sponsored, since 2009, an Off-gas Sigma Team to perform research and development focused on the most pressing volatile radionuclide control and immobilization problems. In this paper, we focus on the control requirements and methodologies for 85Kr and 129I. Numerous candidate technologies have been studied and developed at laboratory and pilot-plant scales in an effort to meet the need for high iodine control efficiency and to advance alternatives to cryogenic separations for krypton control. Several of these show promising results. Iodine decontamination factors as high as 105, iodine loading capacities, and other adsorption parameters including adsorption rates have been demonstrated under some conditions for both silver zeolite (AgZ) and Ag-functionalized aerogel. Sorbents, including an engineered form of AgZ and selected metal organic framework materials (MOFs), have been successfully demonstrated to capture Kr and Xe without the need for separations at cryogenic temperatures.
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  • 26
    Publication Date: 2013-09-20
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  • 27
    Publication Date: 2013-09-22
    Description: Decommissioning of the Ignalina Nuclear Power Plant involves multiple problems. One of them is personnel radiation safety during the performance of dismantling activities. In this paper, modeling results of radiation doses during the dismantling of the pressurized tank from the emergency core cooling system (ECCS PT) of RBMK-1500 reactor are presented. The radiological surveys indicate that the inner surface of the ECCS PT is contaminated with radioactive products of corrosion and sediments due to the radioactive water. The effective doses to the workers have been modeled for different strategies of ECCS PT dismantling. In order to select the optimal personnel radiation safety, the modeling has been performed by the means of computer code “VISIPLAN 3D ALARA Planning tool” developed by SCK CEN (Belgium). The impacts of dismantling tools, shielding types, and extract ventilation flow rate on effective doses during the dismantling of ECCS PT have been analyzed. The total effective personnel doses have been obtained by summarizing the effective personnel doses from various sources of exposure, that is, direct radiation from radioactive equipment, internal radiation due to inhalation of radioactive aerosols, and direct radiation from radioactive aerosols arising during hot cutting in premises. The uncertainty of the collective doses is also presented in this paper.
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  • 28
    Publication Date: 2013-09-27
    Description: The standard air density of 1.225 kg m−3 is often used in determining the energy output of a wind turbine although the energy output is dependent on a site's air density. By using measurements of temperature, dew-point temperature, and pressure, we calculate the monthly air density of moist tropical climates at two sites in the small-island state of Trinidad and Tobago. In addition, we calculate the energy output of a BOREAS 30 kW small wind turbine using the 10 m level wind speed distribution extrapolated to hub height. The average air densities at Crown Point and Piarco were 1.156 kg m−3 and 1.159 kg m−3, respectively, and monthly air densities at both sites were at most 6% less than standard air density. The difference in energy output of the BOREAS 30 kW calculated using standard air density over that using the local site's air density could provide electrical energy for the continuous monthly operation of 6 light bulbs rated at 50 W at Crown Point and 4 light bulbs at Piarco. Thus, communities interested in implementing wind turbine technologies must use the local air density of the site when sizing a wind turbine system for its needs.
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  • 29
    Publication Date: 2013-09-30
    Description: This work presented the successful fabrication of dye-sensitized solar cell using polyaniline base (EB), multiwalled carbon nanotubes (MWCNTs), organic dye (rhodamine B or riboflavin), zinc oxide (ZnO), and indium tin oxide (ITO). The electrical properties of the resultant devices were investigated by measuring the current density voltage (-), capacitance voltage (-), and impedance measurements under both dark and illuminated conditions. The photovoltaic cell characteristics, that is, open circuit voltage (), short circuit current density (), and energy conversion efficiency (), were evaluated under illumination and were found to be 0.48 mA/cm2, 400 mV, and 0.224%, respectively, for ITO/EB-MWCNTs/ZnO-rhodamine B/ITO heterostructure. Using impedance spectra, it was found that the series resistances of this type of solar cell are 62 and 60 Ω under darkness and illumination, respectively.
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  • 30
    Publication Date: 2013-06-06
    Description: Nanofiltration for water and wastewater treatment – a mini review Drinking Water Engineering and Science, 6, 47-53, 2013 Author(s): H. K. Shon, S. Phuntsho, D. S. Chaudhary, S. Vigneswaran, and J. Cho The application of membrane technology in water and wastewater treatment is increasing due to stringent water quality standards. Nanofiltration (NF) is one of the widely used membrane processes for water and wastewater treatment in addition to other applications such as desalination. NF has replaced reverse osmosis (RO) membranes in many applications due to lower energy consumption and higher flux rates. This paper briefly reviews the application of NF for water and wastewater treatment including fundamentals, mechanisms, fouling challenges and their controls.
    Print ISSN: 1996-9457
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  • 31
    Publication Date: 2013-06-06
    Description: Korea imports about 97% of its energy resources due to a lack of available energy resources. In this status, the role of nuclear power in electricity generation is expected to become more important in future years. In particular, a fast reactor system is one of the most promising reactor types for electricity generation, because it can utilize efficiently uranium resources and reduce radioactive waste. Acknowledging the importance of a fast reactor in a future energy policy, the long-term advanced SFR development plan was authorized by KAEC in 2008 and updated in 2011 which will be carried out toward the construction of an advanced SFR prototype plant by 2028. Based upon the experiences gained during the development of the conceptual designs for KALIMER, KAERI recently developed advanced sodium-cooled fast reactor (SFR) design concepts of TRU burner that can better meet the generation IV technology goals. The current status of nuclear power and SFR design technology development program in Korea will be discussed. The developments of design concepts including core, fuel, fluid system, mechanical structure, and safety evaluation have been performed. In addition, the advanced SFR technologies necessary for its commercialization and the basic key technologies have been developed including a large-scale sodium thermal-hydraulic test facility, super-critical Brayton cycle system, under-sodium viewing techniques, metal fuel development, and developments of codes, and validations are described as R&D activities.
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  • 32
    Publication Date: 2013-06-10
    Description: This study used natural dyes as sensitizers of dye-sensitized solar cells (DSSCs) to replace expensive chemical synthetic dyes. We prepared two natural dyes, chlorophyll dye and anthocyanin dye, by extracting them from wormwood and purple cabbage, respectively. Moreover, we mixed the prepared chlorophyll dye and anthocyanin dye at 5 different volume ratios to form cocktail dyes. For preparation of photoelectrode, P25 TiO2 nanoparticles were used to prepare paste, which was coated on fluorine-doped tin oxide (FTO) conductive glass by the spin coating method at different spin coating speeds in order to form TiO2 thin films with different thicknesses. The DSSC prepared by the cocktail dye achieves photoelectric conversion efficiency (η) of 1.95%, open-circuit voltage () of 0.765 V, and short-circuit current density () of 5.83 mA/cm2. Moreover, the prepared DSSC sensitized solely by chlorophyll extract of wormwood achieved a photoelectric conversion efficiency (η) of 0.9%, whereas the DSSC sensitized solely by anthocyanin extract of purple cabbage achieved a photoelectric conversion efficiency of 1.47%, achieving the longest lifetime of electrons amongst these three dyes.
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  • 33
    Publication Date: 2013-06-12
    Description: In the last decade, the fast increase of the global energy consumption, mainly related to the strong economic growth in the Far East, and the progressive depletion of the fossil fuels induced a run-up in the world oil price. Both these economic concerns and the growing global pollution pointed out that a transition toward renewable energies is mandatory. Among renewables, the conversion of sunlight into electricity by photovoltaic (PV) devices is a reliable choice to cope the growing energy consumption, due to the huge potentially extractable power (up to 120000 TW). The most important classes of inorganic PV devices developed in the last sixty years will be reviewed in this paper, in order to depict the state of the art of the technologies which dominate the PV market. Some novel concepts which could have an important role in the future of PV will be also described.
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  • 34
    Publication Date: 2013-06-07
    Description: The objective of the present research work is to design user friendly solar cooker which can be commercialized too. This cooker is designed, developed, and tested in our laboratory. The basic principle is to incorporate heating into material by photovoltaic effect and thermal treatment. Different temperatures inside the solar cooker were measured and profile of solar cooker was studied for several days during April, May, and June 2012. It is observed that the designed cooker needs the boosting of only 30 watt power which is generated by a small solar panel connected with it. Heater connected with it can be powered by a solar panel of 75 watt. This boosting can reduce the cooking time. Different recipes were prepared to test its actual performance.
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  • 35
    Publication Date: 2013-03-22
    Description: In this work, the nanostructured anatase mesoporous membranes were prepared for water ultrafiltration (UF) process with photocatalytic and physical separation capabilities. A macroporous substrate was synthesized from α-Al2O3, then a colloidal titania sol was used for the preparation of the intermediate layer. Also, the membrane top layer was synthesized by deposition and calcination of titania polymeric sol on the intermediate layer. The characterization was performed by DLS, TG-DTA, XRD, BET, FESEM, TEM, and AFM techniques. Also, the filtration experiments were carried out based on separation of methyl orange from aqueous solution by a membrane setup with a dead-end filtration cell. Photocatalytic activity of the membranes was evaluated by methyl orange photodegradation using UV-visible spectrophotometer. The mean particle size of the colloidal and polymeric sols was 14 and 1.5 nm, respectively. The anatase membranes exhibited homogeneity, with the surface area of 32.8 m2/g, the mean pore size of 8.17 nm, and the crystallite size of 9.6 nm. The methyl orange removal efficiency by the mesoporous membrane based on physical separation was determined to be 52% that was improved up to 83% by a coupling photocatalytic technique. Thus, the UF membrane showed a high potential due to its multifunctional capability for water purification applications.
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  • 36
    Publication Date: 2013-04-03
    Description: Application of DVC-FISH method in tracking Escherichia coli in drinking water distribution networks Drinking Water Engineering and Science, 6, 25-31, 2013 Author(s): L. Mezule, S. Larsson, and T. Juhna Sporadic detection of live (viable) Escherichia coli in drinking water and biofilm with molecular methods but not with standard plate counts has raised concerns about the reliability of this indicator in the surveillance of drinking water safety. The aim of this study was to determine spatial distribution of different viability forms of E. coli in a drinking water distribution system which complies with European Drinking Water Directive (98/83/EC). For two years coupons (two week old) and pre-concentrated (100 times with ultrafilters) water samples were collected after treatment plants and from four sites in the distribution network at several distances. The samples were analyzed for total, viable (able to divide as DVC-FISH positive) and cultivable E. coli . The results showed that low numbers of E. coli enters the distribution sytem from the treatment plants and tend to accumulate in the biofilm of water distribution system. Almost all of the samples contained metabolically active E. coli in the range of 1 to 50 cells per litre or cm 2 which represented approximately 53% of all E. coli detected. The amount of viable E. coli significantly increased into the network irrespective of the season. The study has shown that DVC-FISH method in combination with water pre-concentration and biofilm sampling allows to better understand the behaviour of E. coli in water distribution networks, thus, it provides new evidences for water safety control.
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  • 37
    Publication Date: 2013-03-31
    Description: This paper evaluates whether SFR metallic nuclear fuel can be economical. To make this determination, the cost of SFCF (SFR fuel cycle facilities) was estimated, and the break-even point of the manufacturing cost of SFR metallic nuclear fuel for direct disposal option was then calculated. As a result of the cost estimation, the levelized unit cost (LUC) for SFCF was calculated to be 5,311 $/kgHM, and the break-even point was calculated to be $5,267/kgHM. Therefore, the cost difference between LUC and the break-even point is not only small but is also within the relevant range of the uncertainty level of Class 3 in accordance with a generic cost estimate classification matrix of AACE (the Association for the Advancement of Cost Engineering). This means it is very difficult to judge the economical feasibility of SFR metallic nuclear fuel because as of today there are no commercial facilities in Korea or the world. The economic feasibility of SFR metallic nuclear fuel, however, will be enhanced if the mass production of SFCF becomes possible in the future.
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  • 38
    Publication Date: 2013-04-01
    Description: A compound of ZnO with 3 wt% Ga2O3 (ZnO : Ga2O3 = 97 : 3 in wt%, GZO) was sintered at C as a target. The GZO thin films were deposited on glass using a radio frequency magnetron sputtering system at C by changing the deposition power from 50 W to 150 W. The effects of deposition power on the crystallization size, lattice constant (c), resistivity, carrier concentration, carrier mobility, and optical transmission rate of the GZO thin films were studied. The blue shift in the transmission spectrum of the GZO thin films was found to change with the variations of the carrier concentration because of the Burstein-Moss shifting effect. The variations in the optical band gap () value of the GZO thin films were evaluated from the plots of , revealing that the measured value decreased with increasing deposition power. As compared with the results deposited at room temperature by Gong et al., (2010) the C deposited GZO thin films had apparent blue shift in the transmission spectrum and larger value. For the deposited GZO thin films, both the carrier concentration and mobility linearly decreased and the resistivity linearly increased with increasing deposition power. The prepared GZO thin films were also used as transparent electrodes to fabricate the amorphous silicon thin-film solar cells, and their properties were also measured.
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  • 39
    Publication Date: 2013-04-01
    Description: This paper aims at performing a human reliability analysis using THERP (Technique for Human Error Prediction) and ATHEANA (Technique for Human Error Analysis) to develop a qualitative and quantitative analysis of the latent operator error in leaving EFW (emergency feed-water) valves closed in the TMI-2 accident. The accident analysis has revealed a series of unsafe actions that resulted in permanent loss of the unit. The integration between THERP and ATHEANA is developed in a way such as to allow a better understanding of the influence of operational context on human errors. This integration provides also, as a result, an intermediate method with the following features: (1) it allows the analysis of the action arising from the plant operational context upon the operator (as in ATHEANA), (2) it determines, as a consequence from the prior analysis, the aspects that most influence the context, and (3) it allows the change of these aspects into factors that adjust human error probabilities (as in THERP). This integration provides a more realistic and comprehensive modeling of accident sequences by considering preaccidental and postaccidental contexts, which, in turn, can contribute to more realistic PSA (Probabilistic Safety Assessment) evaluations and decision making.
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  • 40
    Publication Date: 2013-04-10
    Description: In an attempt to allow nuclear power to reach its full economic potential, General Atomics is developing the Energy Multiplier Module (EM2), which is a compact gas-cooled fast reactor (GFR). The EM2 augments its fissile fuel load with fertile materials to enhance an ultra-long fuel cycle based on a “convert-and-burn” core design which converts fertile material to fissile fuel and burns it in situ over a 30-year core life without fuel supplementation or shuffling. A series of reactor physics trade studies were conducted and a baseline core was developed under the specific physics design requirements of the long-life small reactor. The EM2 core performance was assessed for operation time, fuel burnup, excess reactivity, peak power density, uranium utilization, etc., and it was confirmed that an ultra-long fuel cycle core is feasible if the conversion is enough to produce fissile material and maintain criticality, the amount of matrix material is minimized not to soften the neutron spectrum, and the reactor core size is optimized to minimize the neutron loss. This study has shown the feasibility, from the reactor physics standpoint, of a compact GFR that can meet the objectives of ultra-long fuel cycle, factory-fabrication, and excellent fuel utilization.
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  • 41
    Publication Date: 2013-09-06
    Description: Concentration solar arrays require greater solar tracking precision than conventional photovoltaic arrays. This paper presents a high precision low cost dual axis sun tracking system based on image processing for concentration photovoltaic applications. An imaging device is designed according to the principle of pinhole imaging, making sun rays to be received on a screen through pinhole and to be a sun spot. The location of the spot is used to adjust the orientation of the solar panel. A fuzzy logic controller is developed to achieve this goal. A prototype was built, and experimental results have proven the good performance of the proposed system and low error of tracking. The operation of this system is independent of geographical location, initial calibration, and periodical regulations.
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  • 42
    Publication Date: 2013-09-09
    Description: Thermal aspect of solar energy is widely used in the desalination plants. Experimental investigation and mathematical modeling of inverted V-type solar still integrated with drip system are presented in this paper. The experiment is performed in the Kerala climatic conditions (10.8439°N, 76.0328°E), March 2012 at M E S College of Engineering, Kuttippuram. A two segment still of 2 m2 is constructed. Experimental investigations on productivity and internal heat transfer are analyzed. The results indicate that the mean standard deviations between theoretical and experimental values are less than 7% (temperature of rippled wick), 8% (temperature of glass in rippled system), 11% (temperature of flat wick), and 7% (temperature of glass in flat system), an average for the working hours of the day.
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  • 43
    Publication Date: 2013-09-09
    Description: New strategies to reduce the environmental and economic costs of pesticides use are currently under study. Microencapsulation has been used as a versatile tool for the production of controlled release agricultural formulations. In this study, the photochemical degradation of the herbicides MCPA and mecoprop has been investigated in different aqueous media such as ultrapure and river water under simulated solar irradiation. To explore the possibility of introducing cyclodextrins in the herbicide formulations, the photodegradation study of the inclusion complexes of MCPA and mecoprop with (2-hydroxypropyl)-β-cyclodextrin (HP-β-CD) was also performed. The half-lives of MCPA and mecoprop inclusion complexes were increased approximately by a factor of three related to the free molecules. Additionally, it has been shown that the photodegradation of MCPA and mecoprop is influenced by their structural features. The additional methyl group existing in mecoprop molecular structure has a positive influence on the stabilization of the radical intermediate formed in the first stage of photodegradation of both herbicides. The results found indicated that MCPA and mecoprop form inclusion complexes with HP-β-CD showing higher photostability compared to free herbicides indicating that HP-β-CD may serve as ingredient in these herbicide formulations.
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  • 44
    Publication Date: 2013-09-10
    Description: The need to reduce energy consumptions and to optimize the processes of energy production has pushed the technology towards the implementation of hybrid systems for combined production of electric and thermal energies. In particular, recent researches look with interest at the installation of hybrid system PV/T. To improve the energy performance of these systems, it is necessary to know the operating temperature of the photovoltaic modules. The determination of the operating temperature is a key parameter for the assessment of the actual performance of photovoltaic panels. In the literature, it is possible to find different correlations that evaluate the referring to standard test conditions and/or applying some theoretical simplifications/assumptions. Nevertheless, the application of these different correlations, for the same conditions, does not lead to unequivocal results. In this work an alternative method, based on the employment of artificial neural networks (ANNs), was proposed to predict the operating temperature of a PV module. This methodology does not require any simplification or physical assumptions. In the paper is described the ANN that obtained the best performance: a multilayer perception network. The results have been compared with experimental monitored data and with some of the most cited empirical correlations proposed by different authors.
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  • 45
    Publication Date: 2013-09-10
    Description: Influences of hydrogen content in intrinsic hydrogenated amorphous silicon (i-a-Si:H) on performances of heterojunction (HJ) solar cells are investigated. The simulation result shows that in the range of 0–18% of the i-layer hydrogen content, solar cells with higher i-layer hydrogen content can have higher degree of dangling bond passivation on single crystalline silicon (c-Si) surface. In addition, the experimental result shows that HJ solar cells with a low hydrogen content have a poor a-Si:H/c-Si interface. The deteriorate interface is assumed to be attributed to (i) voids created by insufficiently passivated c-Si surface dangling bonds, (ii) voids formed by SiH2 clusters, and (iii) Si particles caused by gas phase particle formation in silane plasma. The proposed assumption is well supported and explained from the plasma point of view using optical emission spectroscopy.
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  • 46
    Publication Date: 2013-09-19
    Description: Chitosan (CS) anchored copper oxide (CuO) hybrid material was prepared by chemical precipitation method. Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) confirmed the formation of CS-CuO hybrid. Transmission electron microscopy (TEM) analysis showed the immobilization of CuO nanoparticles on the surface of CS. The hybrid was also characterized by thermogravimetric analysis (TGA) and zeta potential. The hybrid exhibited high photocatalytic activity as evident from the degradation of methylene blue (MB) dye. The result revealed substantial degradation of the MB dye (84%) under UV-light illumination. The antibacterial activity of hybrid against Escherichia coli was examined by colony forming units. It was proved that the CS encapsulated CuO hybrid exhibited excellent antibacterial activity.
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  • 47
    Publication Date: 2013-09-19
    Description: Starting from the results regarding a nonvacuum technique to fabricate CIGS thin films for solar cells by means of single-step electrodeposition, we focus on the methodological problems of modeling at cell structure and photovoltaic module levels. As a matter of fact, electrodeposition is known as a practical alternative to costly vacuum-based technologies for semiconductor processing in the photovoltaic device sector, but it can lead to quite different structural and electrical properties. For this reason, a greater effort is required to ensure that the perspectives of the electrical engineer and the material scientist are given an opportunity for a closer comparison and a common language. Derived parameters from ongoing experiments have been used for simulation with the different approaches, in order to develop a set of tools which can be used to put together modeling both at single cell structure and complete module levels.
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  • 48
    Publication Date: 2013-09-25
    Description: Relevant to the self-propagating high-temperature synthesis (SHS) process, an analytical study has been conducted to investigate the effects of electric field on the combustion behavior because the electric field is indispensable for systems with weak exothermic reactions to sustain flame propagation. In the present study, use has been made of the heterogeneous theory which can satisfactorily account for the premixed mode of the bulk flame propagation supported by the nonpremixed mode of particle consumption. It has been confirmed that, even for the SHS flame propagation under electric field, being well recognized to be facilitated, there exists a limit of flammability, due to heat loss, as is the case for the usual SHS flame propagation. Since the heat loss is closely related to the representative sizes of particles and compacted specimen, this identification provides useful insight into manipulating the SHS flame propagation under electric field, by presenting appropriate combinations of those sizes. A fair degree of agreement has been demonstrated through conducting an experimental comparison, as far as the trend and the approximate magnitude are concerned, suggesting that an essential feature has been captured by the present study.
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  • 49
    Publication Date: 2013-09-26
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  • 50
    Publication Date: 2013-09-27
    Description: MoS2/CdS photocatalyst was fabricated by a hydrothermal method for H2 production under visible light. This method used low toxic thiourea as a sulfur source and was carried out at 200°C. Thus, it was better than the traditional methods, which are based on an annealing process at relatively high temperature (above 400°C) using toxic H2S as reducing agent. Scanning electron microscopy and transmission electron microscopy images showed that the morphologies of MoS2/CdS samples were feather shaped and MoS2 layer was on the surface of CdS. The X-ray photoelectron spectroscopy testified that the sample was composed of stoichiometric MoS2 and CdS. The UV-vis diffuse reflectance spectra displayed that the loading of MoS2 can enhance the optical absorption of MoS2/CdS. The photocatalytic activity of MoS2/CdS was evaluated by producing hydrogen. The hydrogen production rate on MoS2/CdS reached 192 μmol·h−1. This performance was stable during three repeated photocatalytic processes.
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  • 51
    Publication Date: 2013-09-27
    Description: Novel graphitic carbon nitride (g-C3N4) coated TiO2 nanocomposites were prepared by a facile and cost-effective solid-state method by thermal treatment of the mixture of urea and commercial TiO2. Because the C3N4 was dispersed and coated on the TiO2 nanoparticles, the as-prepared g-C3N4/TiO2 nanocomposites showed enhanced absorption and photocatalytic properties in visible light region. The as-prepared g-C3N4 coated TiO2 nanocomposites under 450°C exhibited efficient visible light photocatalytic activity for degradation of aqueous MB due to the increased visible light absorption and enhanced MB adsorption. The g-C3N4 coated TiO2 nanocomposites would have wide applications in both environmental remediation and solar energy conversion.
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  • 52
    Publication Date: 2013-01-01
    Description: Global energy use has reached unprecedented levels and increasing human population, technological integration, and improving lifestyle will further fuel this demand. Fossil fuel based energy is our primary source of energy and it will remain to be in the near future. The effects from the use of this finite resource on the fate of our planet are only now being understood and recognised in the form of climate change. Renewable energy systems may offer a credible alternative to help maintain our lifestyle sustainably and there are a range of options that can be pursued. Biofuels, especially algae based, have gained significant publicity recently. The concept of making biofuels, biochemicals, and by-products works well theoretically and at small scale, but when considering scaleup, many solutions can be dismissed on either economical or ecological grounds. Even if an (cost-) effective method for algae cultivation is developed, other input parameters, namely, fixed nitrogen and fresh water, remain to be addressed. Furthermore, current processing routes for harvesting, drying, and extraction for conversion to subsequent products are economically unattractive. The strategies employed for various algae-based fuels are identified and it is suggested that ultimately only an integrated algal biorefinery concept may be the way forward.
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  • 53
    Publication Date: 2013-01-02
    Description: Cu2ZnSnS4 (CZTS) has attracted much attention recently as an absorber layer material in a heterojunction solar cell. Using the first-principles method, we calculate the band offsets for the CdS/CZTS heterojunction. The valence band offset is 1.2 eV for the (001) CdS/CZTS heterointerface and 1.0 eV for the (010) heterointerface, when CZTS is considered to crystallize in the kesterite structure. When CZTS is considered to crystallize in the stannite structure,  eV for the (001) heterointerface and  eV for the (010) heterointerface. In any case, the conduction band minimum of CZTS is higher than that of CdS, and the conduction band offset is in a range between 0.1 and 0.4 eV.
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  • 54
    Publication Date: 2013-02-21
    Description: Treatment of dye effluents resulting from the industrial scale dyeing of cotton, polyacrylic fibres, leather, and flax fabrics by photocatalytic methods was investigated. Photocatalytic processes were initiated by UV-a light ( 366 nm) and were conducted in the presence of TiO2, TiO2/FeCl3, or FeCl3 as photocatalysts. It was found that the photocatalytic process carried out with TiO2 and TiO2/FeCl3 was the most effective method for decolorization of textile dyeing effluents and degradation of dyes, except for effluents containing very high concentrations of stable azo dyes. During the photocatalytic degradation of anionic dyes, a mixture of TiO2/FeCl3 was more effective, while in the case of cationic dyes, more suitable seems to be TiO2 alone.
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  • 55
    Publication Date: 2013-02-21
    Description: This work projects photoluminescence (PL) as an alternative technique to estimate the order of resistivity of zinc oxide (ZnO) thin films. ZnO thin films, deposited using chemical spray pyrolysis (CSP) by varying the deposition parameters like solvent, spray rate, pH of precursor, and so forth, have been used for this study. Variation in the deposition conditions has tremendous impact on the luminescence properties as well as resistivity. Two emissions could be recorded for all samples—the near band edge emission (NBE) at 380 nm and the deep level emission (DLE) at ~500 nm which are competing in nature. It is observed that the ratio of intensities of DLE to NBE (/) can be reduced by controlling oxygen incorporation in the sample. - measurements indicate that restricting oxygen incorporation reduces resistivity considerably. Variation of / and resistivity for samples prepared under different deposition conditions is similar in nature. / was always less than resistivity by an order for all samples. Thus from PL measurements alone, the order of resistivity of the samples can be estimated.
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  • 56
    Publication Date: 2013-02-21
    Description: Highly efficient phosphorescent organic light-emitting devices (PhOLEDs) had been fabricated by using a novel iridium complex, bis[2-(,-di-tert-butylbiphenyl-4-yl)benzothiazolato-N,]iridium(III) (acetylacetonate) [(tbpbt)2Ir(acac)], as the emitter. With a wide doping ratio ranging from 15 wt% to 25 wt%, the PhOLEDs maintained a comparable high performance, indicating concentration-insensitive property of the (tbpbt)2Ir(acac). On the basis of the unique characteristic of concentration insensitivity, the application of this phosphor was explored by fabricating white organic light-emitting devices (WOLEDs) with altered doping ratio, indicating that trap effect of (tbpbt)2Ir(acac) could effectively tailor WOLEDs spectra. Typically, a high-power efficiency, current efficiency, and external quantum efficiency of 30.0 lm/W, 38.8 cd/A, 18.1%, were achieved by 20 wt% doped WOLEDs.
    Print ISSN: 1110-662X
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  • 57
    Publication Date: 2013-02-21
    Description: Self-organized TiO2 nanotubes (TNTs) with average inner diameter of 109 nm, wall thickness of 15 nm, and tube length of 7–10 μm were loaded with nickel oxide (NiO) nanoparticles via incipient wet impregnation method. The molar concentration of Ni(NO3)2·6H2O aqueous solution varied in a range of 0.5 M–2.5 M. The samples were characterized for crystalline phase, morphology, topography, chemical composition, Raman shift, and UV-Vis diffusion reflection properties. The finding shows that the loading of NiO did not influence the morphology, structure, and crystalline phase of TNTs but it exhibited significant effect on crystallite size and optical absorption properties. Further, the solar-energy-driven the photocatalytic activity of NiO/TNTs and pure TNTs was evaluated by degrading methylene blue (MB). The results confirm that photocatalytic efficiency of NiO/TNTs is higher than that of TNTs.
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  • 58
    Publication Date: 2013-02-21
    Description: The aim of the present study is to enhance photocatalytic performance of ZnO semiconductor by comodification with doping of nonmetal ions and coupling with another semiconductor. Therefore, we synthesized the N-doped ZnO/ZnS photocatalysts via a simple heat-treatment approach using L-cysteine as N and S source in this work. Anthraquinone dye (reactive brilliant blue KNR) is employed as the model contaminants to evaluate the photocatalytic activity of as-synthesized samples under sunlight illumination. The N-doped ZnO/ZnS synthesized by this method shows better photocatalytic activity as compared to that of pure ZnO. The enhanced photocatalytic activity of the N-doped ZnO/ZnS composites may be related to the existence of N doping, ZnS/ZnO heterostructure, and covered abundant carbon species on the photocatalyst surface, which causing high absorption efficiency of light, efficient separation of electron-hole pairs, and quick surface reaction in doped ZnO.
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  • 59
    Publication Date: 2013-02-21
    Description: We have systematically studied the photocatalytic mechanisms of nitrogen doping in anatase TiO2 using first-principles calculations based on density functional theory, employing Hubbard U (8.47 eV) on-site correction. The impurity formation energy, charge density, and electronic structure properties of TiO2 supercells containing substitutional nitrogen, interstitial nitrogen, or oxygen vacancies were evaluated to clarify the mechanisms under visible light. According to the formation energy, a substitutional N atom is better formed than an interstitial N atom, and the formation of an oxygen vacancy in N-doped TiO2 is easier than that in pure TiO2. The calculated results have shown that a significant band gap narrowing may only occur in heavy nitrogen doping. With light nitrogen doping, the photocatalysis under visible light relies on N-isolated impurity states. Oxygen vacancies existence in N-doped TiO2 can improve the photocatalysis in visible light because of a band gap narrowing and n-type donor states. These findings provide a reasonable explanation of the mechanisms of visible light photocatalysis in N-doped TiO2.
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  • 60
    Publication Date: 2013-02-21
    Description: This paper presents a grid-connected PV system in a centralized configuration constructed through a three-phase dual-stage inverter. For the DC-DC stage the three-phase series resonant converter is chosen thanks to the advantages that it exhibits. However, it is inadequate for the accomplishment of MPPT, due to its efficiency strongly depending on the implemented deadtime and switching frequency. Then, this paper proposes a conceptual modification, that is, a modified dual-stage inverter in which the inverter stage is responsible for both the MPPT and the grid-current control. In addition, the DC-DC converter operates with constant duty cycle and frequency. Such configuration requires a new concept, introduced as Behavior Matching. It serves as a fundamental feature for the DC-DC converter to reproduce the PV array I–V characteristic when they are connected, without control action. The maximum power operating point is found by maximizing the direct axis current, obtained by Park's transformation from the inverter, through the perturbation and observation algorithm. Any specific measurement to realize the MPPT is needed. The galvanic isolation is achieved by using a high-frequency transformer. The structure is appropriate for high power applications, above 10 kW.
    Print ISSN: 2090-7451
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  • 61
    Publication Date: 2013-02-21
    Description: Reduced-gravity experiments were performed on combustion of droplets composed of n-heptane mixed with methanol or ethanol. The initial alcohol mass fraction in a droplet was 0% (pure heptane) or 5%. The experiments were performed at 0.1 MPa and 25°C with air or with ambients of oxygen and helium with oxygen mole fractions of 0.3 or 0.4. Initial droplet diameters were in the range 0.67 mm to 0.92 mm. After considering measurement uncertainties, burning rates decreased appreciably as the initial droplet diameter increased for combustion in air but not for combustion in the oxygen/helium environments. It was also found that addition of either methanol or ethanol did not influence burning rates appreciably and that burning rates were larger for the oxygen/helium environments than for air if initial droplet diameter dependences were accounted for.
    Print ISSN: 2090-1968
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  • 62
    Publication Date: 2013-02-22
    Description: Fluoride in the drinking water of Pakistan and the possible risk of crippling fluorosis Drinking Water Engineering and Science, 6, 17-23, 2013 Author(s): M. A. Tahir and H. Rasheed To explore the possibility of fluoride toxicity, 747 water samples were collected from surface water and groundwater sources of 16 major cities of Pakistan, adopting a uniform sampling design with distribution of samples: Lahore (79), Kasur (46), Faisalabad (30), Khushab (50), Chakwal (51), Mianwali (30), Jhelum (53), Bahawalpur (60), Karachi (60), Mirpur Khas (55), Peshawar (38), Risalpur (35), Quetta (81), Ziarat (21), Loralai (21), and Mastung (37). Comparison of analytical findings with WHO Guidelines of Drinking Water for Fluoride (i.e., 1.5 ppm) has concluded that 16% of the monitored water sources have fluoride concentration beyond the permissible safe limit of 1.5 mg L −1 falling in the concentration range of 1.6–25 mg L −1 . The highest fluoride contamination (22%) is detected in the Balochistan province followed by 19% in Punjab province. Comparatively higher fluoride levels of 〉 20% in the groundwater sources like hand pumps supported the possibility of increased groundwater contamination as excessive fluoride concentrations are expected to come from calcium-poor aquifers and in areas where fluoride-bearing minerals are common or where cation exchange of sodium for calcium occurs. Field observations have also indicated the prevalence of fluoride-associated health implications in the study areas with excessive fluoride in water sources. Findings of this study have provided bidirectional vision for the epidemiological investigations as well as to mitigate the issues in the affected vicinities of fluoride-rich areas.
    Print ISSN: 1996-9457
    Electronic ISSN: 1996-9465
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Published by Copernicus on behalf of The Delft University of Technology.
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  • 63
    Publication Date: 2013-02-21
    Description: The OECD/NEA Uncertainty Analysis in Modeling (UAM) expert group organized and launched the UAM benchmark. Its main objective is to perform uncertainty analysis in light water reactor (LWR) predictions at all modeling stages. In this paper, multigroup microscopic cross-sectional uncertainties are propagated through the DRAGON (version 4.05) lattice code in order to perform uncertainty analysis on and 2-group homogenized macroscopic cross-sections. The chosen test case corresponds to the Three Mile Island-1 (TMI-1) lattice, which is a 15 15 pressurized water reactor (PWR) fuel assembly segment with poison and at full power conditions. A statistical methodology is employed for the uncertainty assessment, where cross-sections of certain isotopes of various elements belonging to the 172-group DRAGLIB library format are considered as normal random variables. Two libraries were created for such purposes, one based on JENDL-4 data and the other one based on the recently released ENDF/B-VII.1 data. Therefore, multigroup uncertainties based on both nuclear data libraries needed to be computed for the different isotopic reactions by means of ERRORJ. The uncertainty assessment performed on and macroscopic cross-sections, that is based on JENDL-4 data, was much higher than the assessment based on ENDF/B-VII.1 data. It was found that the computed Uranium 235 fission covariance matrix based on JENDL-4 is much larger at the thermal and resonant regions than, for instance, the covariance matrix based on ENDF/B-VII.1 data. This can be the main cause of significant discrepancies between different uncertainty assessments.
    Print ISSN: 1687-6075
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  • 64
    Publication Date: 2013-02-21
    Description: Germany is phasing-out the utilization of nuclear energy until 2022. Currently, nine light water reactors of originally nineteen are still connected to the grid. All power plants generate high-level nuclear waste like spent uranium or mixed uranium-plutonium dioxide fuel which has to be properly managed. Moreover, vitrified high-level waste containing minor actinides, fission products, and traces of plutonium reprocessing loses produced by reprocessing facilities has to be disposed of. In the paper, the assessments of German spent fuel legacy (heavy metal content) and the nuclide composition of this inventory have been done. The methodology used applies advanced nuclear fuel cycle simulation techniques in order to reproduce the operation of the German nuclear power plants from 1969 till 2022. NFCSim code developed by LANL was adopted for this purpose. It was estimated that ~10,300 tonnes of unreprocessed nuclear spent fuel will be generated until the shut-down of the ultimate German reactor. This inventory will contain ~131 tonnes of plutonium, ~21 tonnes of minor actinides, and 440 tonnes of fission products. Apart from this, ca.215 tonnes of vitrified HLW will be present. As fission products and transuranium elements remain radioactive from 104 to 106 years, the characteristics of spent fuel legacy over this period are estimated, and their impacts on decay storage and final repository are discussed.
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  • 65
    Publication Date: 2013-02-22
    Description: Cu2O is considered to be promising as an absorber layer material of solar cells, but its band gap (about 2.1 eV) is larger than the optimum one (about 1.5 eV). CuO has a smaller band gap of about 1.35 eV. Therefore, we attempted to oxidize Cu2O using H2O2 to increase oxygen ratio and decrease band gap. Cu2O thin films were deposited on indium-tin-oxide-coated glass from an aqueous solution containing CuSO4, lactic acid, and KOH by the galvanostatic electrochemical deposition at 40°C with current density of −1 mA/cm2. Then, the as-prepared copper oxide thin film was dipped in H2O2 (30%) at fixed temperature to oxidize for some time. By the H2O2 treatment at room temperature, the oxygen content was increased, and the band gap was decreased.
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  • 66
    Publication Date: 2013-02-25
    Description: This study applied the microwave/sol-gel method to prepare nitrogen-doped TiO2 (N-TiO2). The N-TiO2 was immobilized in glass balls to form N-TiO2/glass beads and applied to degrade Bisphenol A (BPA) under visible-light and sunlight irradiation. The characteristics of the prepared photocatalysts were analyzed by X-ray diffraction (XRD), UV-Vis spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Experimental results demonstrate that the percentage of anatase increased as the amount of N in N-TiO2 increased. Compared with the undoped TiO2 (420 nm), spectra show that the absorption edge shifted to a longer wavelength (445 nm) after N doping. The XPS characterization confirms the substitution of crystal lattice O to N species in N-TiO2, forming Ti–O–N and N–Ti–O. With an increased N/Ti ratio, photodegradation efficiency increased and then decreased; moreover, the optimal amount for N doping was determined as an N/Ti mole ratio of 0.08 (0.1 NT). The efficiency of 0.1 NT in doing BPA photodegradation was greater than that of Degussa P25. After reaction for 61 min, the mineralization percentage of 0.1 NT under visible-light irradiation reached 41%. Photocatalyst efficiency decreased as the number of repeats increased in the visible-light/N-TiO2 system; however, these systems were stable during reaction.
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  • 67
    Publication Date: 2013-03-07
    Description: We introduced a simple fabrication method of porous hematite films with tunable thickness in an aqueous solution containing FeCl3 as the single precursor. We demonstrated that the optimized thickness was necessary for high performance photoelectrochemical water splitting, by balancing photon absorption and charge carrier transport. The highest photocurrent of ca. 0.15 mA cm−2 at 1.0 V versus Ag/AgCl was achieved on the 300 nm thick porous hematite film as photoanode, with IPCE at 370 nm and 0.65 V versus Ag/AgCl to be 9.0%. This simple method allows the facile fabrication of hematite films with porous nanostructure for enabling high photon harvesting efficiency and maximized interfacial charge transfer. These porous hematite films fabricated by this simple solution-based method could be easily modified by metal doping for further enhanced photoelectrochemical activity for water splitting.
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  • 68
    Publication Date: 2013-03-07
    Description: This study employed a cerebellar model articulation controller (CMAC) neural network to conduct fault diagnoses on photovoltaic power generation systems. We composed a module array using 9 series and 2 parallel connections of SHARP NT-R5E3E 175 W photovoltaic modules. In addition, we used data that were outputted under various fault conditions as the training samples for the CMAC and used this model to conduct the module array fault diagnosis after completing the training. The results of the training process and simulations indicate that the method proposed in this study requires fewer number of training times compared to other methods. In addition to significantly increasing the accuracy rate of the fault diagnosis, this model features a short training duration because the training process only tunes the weights of the exited memory addresses. Therefore, the fault diagnosis is rapid, and the detection tolerance of the diagnosis system is enhanced.
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  • 69
    Publication Date: 2013-03-07
    Description: Cu(InGa)Se2 (CIGS) thin film absorbers are prepared using sputtering and selenization processes. The CuGa/In precursors are selenized during rapid thermal annealing (RTA), by the deposition of a Se layer on them. This work investigates the effect of the Cu content in precursors on the structural and electrical properties of the absorber. Using X-ray diffraction, field emission scanning electron microscopy, Raman spectroscopy, and Hall effect measurement, it is found that the CIGS thin films produced exhibit facetted grains and a single chalcopyrite phase with a preferred orientation along the (1 1 2) plane. A Cu-poor precursor with a Cu/() ratio of 0.75 demonstrates a higher resistance, due to an increase in the grain boundary scattering and a reduced carrier lifetime. A Cu-rich precursor with a Cu/() ratio of 1.15 exhibits an inappropriate second phase () in the absorber. However, the precursor with a Cu/() ratio of 0.95 exhibits larger grains and lower resistance, which is suitable for its application to solar cells. The deposition of this precursor on Mo-coated soda lime glass substrate and further RTA causes the formation of a MoSe2 layer at the interface of the Mo and CIGS.
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  • 70
    Publication Date: 2013-03-07
    Description: Antimicrobial paints were based on the aqueous acrylic dispersion and various nanoparticles of zinc oxide and titanium dioxide. Antimicrobial ability and photoactivity were assumed in these paints. It was possible to observe the photoactivity thanks to change of organic dyes due to oxidative-reductive reaction. The best photocatalytic effect showed the coating containing the mixture of the first type of TiO2 and nano-ZnO despite the fact that the first type of TiO2 was not better in the photocatalytic test than the other types of TiO2. The agar dilution method was used to test antimicrobial ability. The Escherichia coli, Pseudomonas aeruginosa, and Staphylococcus aureus were chosen as test bacteria and Penicillium chrysogenum and Aspergillus niger as test molds. The antimicrobial effect of coatings with the mixture of the first type of TiO2 and nano-ZnO was the best of all the tested samples.
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  • 71
    Publication Date: 2013-03-07
    Description: Effective control of oxygen impurity in multicrystalline silicon is required for the production of a high-quality crystal. The basic principle and some techniques for reducing oxygen impurity in multicrystalline silicon during the unidirectional solidification process are described in this paper. The oxygen impurity in multicrystalline silicon mainly originates from the silica crucible. To effectively reduce the oxygen impurity, it is essential to reduce the oxygen generation and enhance oxygen evaporation. For reduction of oxygen generation, it is necessary to prevent or weaken any chemical reaction with the crucible, and for the enhancement of oxygen evaporation, it is necessary to control convection direction of the melt and strengthen gas flow above the melt. Global numerical simulation, which includes heat transfer in global furnace, argon gas convection inside furnace, and impurity transport in both melt and gas regions, has been implemented to validate the above methods.
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  • 72
    Publication Date: 2013-03-07
    Description: Today, after more than 70 years of continued progress on silicon technology, about 85% of cumulative installed photovolatic (PV) modules are based on crystalline silicon (c-Si). PV devices based on silicon are the most common solar cells currently being produced, and it is mainly due to silicon technology that the PV has grown by 40% per year over the last decade. An additional step in the silicon solar cell development is ongoing, and it is related to a further efficiency improvement through defect control, device optimization, surface modification, and nanotechnology approaches. This paper attempts to briefly review the most important advances and current technologies used to produce crystalline silicon solar devices and in the meantime the most challenging and promising strategies acting to increase the efficiency to cost/ratio of silicon solar cells. Eventually, the impact and the potentiality of using a nanotechnology approach in a silicon-based solar cell are also described.
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  • 73
    Publication Date: 2013-03-07
    Description: This experiment is to study an absorption refrigerator driven by solar cells. Hand-held or carried in vehicle can be powered by solar energy in places without power. In the evenings or rainy days, it is powered by storage battery, and it can be directly powered by alternating current (AC) power supply if available, and the storage battery can be charged full as a backup supply. The proposed system was tested by the alternation of solar irradiance 550 to 700 W/m2 as solar energy and 500ml ambient temperature water as cooling load. After 160 minutes, the proposal refrigerator can maintain the temperature at 5–8°C, and the coefficient of performance (COP) of NH3-H2O absorption refrigeration system is about 0.25. Therefore, this system can be expected to be used in remote areas for refrigeration of food and beverages in outdoor activities in remote and desert areas or long-distance road transportation of food or low temperature refrigeration of vaccine to avoid the deterioration of the food or the vaccines.
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  • 74
    Publication Date: 2013-03-07
    Description: CuInSe2 (CIS) thin films are successfully prepared by electron beam evaporation. Pure Cu, In, and Se powders were mixed and ground in a grinder and made into a pellet. The pallets were deposited via electron beam evaporation on FTO substrates and were varied by varying the annealing temperatures, at room temperature, 250°C, 300°C, and 350°C. Samples were analysed by X-ray diffractometry (XRD) for crystallinity and field-emission scanning electron microscopy (FESEM) for grain size and thickness. I-V measurements were used to measure the efficiency of the CuInSe2/ZnS solar cells. XRD results show that the crystallinity of the films improved as the temperature was increased. The temperature dependence of crystallinity indicates polycrystalline behaviour in the CuInSe2 films with (1 1 1), (2 2 0)/(2 0 4), and (3 1 2)/(1 1 6) planes at 27°, 45°, and 53°, respectively. FESEM images show the homogeneity of the CuInSe2 formed. I-V measurements indicated that higher annealing temperatures increase the efficiency of CuInSe2 solar cells from approximately 0.99% for the as-deposited films to 1.12% for the annealed films. Hence, we can conclude that the overall cell performance is strongly dependent on the annealing temperature.
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  • 75
    Publication Date: 2013-03-07
    Description: Aluminum oxide films were deposited on crystalline silicon substrates by reactive RF magnetron sputtering. The influences of the deposition parameters on the surface passivation, surface damage, optical properties, and composition of the films have been investigated. It is found that proper sputtering power and uniform magnetic field reduced the surface damage from the high-energy ion bombardment to the silicon wafers during the process and consequently decreased the interface trap density, resulting in the good surface passivation; relatively high refractive index of aluminum oxide film is benefic to improve the surface passivation. The negative-charged aluminum oxide film was then successfully prepared. The surface passivation performance was further improved after postannealing by formation of an SiOx interfacial layer. It is demonstrated that the reactive sputtering is an effective technique of fabricating aluminum oxide surface passivation film for low-cost high-efficiency crystalline silicon solar cells.
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  • 76
    Publication Date: 2013-03-07
    Description: The top five solar cell supply countries in the world in sequential order are China, Taiwan, the United States of America, Japan, and Germany. The capacity of Taiwanese solar cell production is ranked top two in the globe. The competitive advantage of the Taiwanese electronics firms has facilitated the rapid developments to its solar photovoltaic industry. The Taiwanese solar photovoltaic industry possesses a large size and a complete value chain of upstream, midstream, and downstream sectors. In this study, I analyzed the trends and developments of the solar photovoltaic industry in Taiwan and in the globe. And I also investigated the positioning and competitive advantage of Taiwanese firms in the value chain of the global solar photovoltaic industry. I found that Taiwanese firms continue to have an important and indispensable role in the global solar photovoltaic industry by either differentiation or cost advantage.
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  • 77
    Publication Date: 2013-03-07
    Description: In this study we propose a suitable method for the solar-activated controlled release of volatile compounds from polymeric microcapsules bonded with photocatalytic nanoparticles. These reservoirs can find applications, for example, in the controlled release of insecticides, repellents, or fragrances, amongst other substances. The surfaces of the microcapsules have been functionalized with TiO2 nanoparticles. Upon ultraviolet irradiation, redox mechanisms are initiated on the semiconductor surface resulting in the dissociation of the polymer chains of the capsule wall and, finally, volatilization of the encapsulated compounds. The quantification of the output release has been performed by gas chromatography analysis coupled with mass spectroscopy.
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  • 78
    Publication Date: 2013-03-07
    Description: To investigate the effect of PdS as a cocatalyst for photocatalytic hydrogen evolution, nanostructured PdS/CdS were prepared by an in situ coprecipitation and hydrothermal method, respectively. The as-prepared photocatalysts were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), UV-visible absorption spectra, and photoluminescence spectra (PL). With PdS highly dispersed in the CdS nanostructures, the photoactivity was evaluated by hydrogen evolution from aqueous solution containing Na2S/Na2SO3 as sacrificial reagents under visible light irradiation. When the concentration of PdS was 1% by weight, PdS/CdS, prepared by the in situ coprecipitation, showed the highest photocatalytic activity, while that prepared by hydrothermal method showed the most stability for hydrogen evolution. The effect of highly dispersed PdS on the photoactivity was discussed.
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  • 79
    Publication Date: 2013-03-07
    Description: Solar aided coal-fired power plants utilize various types of solar thermal energy for coupling coal-fired power plants by using the characteristics of various thermal needs of the plants. In this way, the costly thermal storage system and power generating system will be unnecessary while the intermittent and unsteady way of power generation will be avoided. Moreover, the large-scale utilization of solar thermal power and the energy-saving aim of power plants will be realized. The contribution evaluating system of solar thermal power needs to be explored. This paper deals with the evaluation method of solar contribution based on the second law of thermodynamics and the principle of thermoeconomics with a case of 600 MW solar aided coal-fired power plant. In this study, the feasibility of the method has been carried out. The contribution of this paper is not only to determine the proportion of solar energy in overall electric power, but also to assign the individual cost components involving solar energy. Therefore, this study will supply the theoretical reference for the future research of evaluation methods and new energy resource subsidy.
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  • 80
    Publication Date: 2013-03-07
    Description: The progressive growing of single-phase photovoltaic (PV) systems makes the Distribution System Operators (DSOs) update or revise the existing grid codes in order to guarantee the availability, quality, and reliability of the electrical system. It is expected that the future PV systems connected to the low-voltage grid will be more active with functionalities of low-voltage ride-through (LVRT) and the grid support capability, which is not the case today. In this paper, the operation principle is demonstrated for a single-phase grid-connected PV system in a low-voltage ride-through operation in order to map future challenges. The system is verified by simulations and experiments. Test results show that the proposed power control method is effective and the single-phase PV inverters connected to low-voltage networks are ready to provide grid support and ride-through voltage fault capability with a satisfactory performance based on the grid requirements for three-phase renewable energy systems.
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  • 81
    Publication Date: 2013-03-07
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  • 82
    Publication Date: 2013-03-07
    Description: In this work we investigate the Ag nanoparticle doping of TiOx used as an intermediate layer between subcells of a tandem organic photovoltaic. We use a model polymer cell structure of P3HT:TiOx:PEDOT:P3HT to observe charge-trapping effects as a function of nanoparticle content in the TiOx, as determined by the shape of the dark and illuminated current voltage curves of the devices. There is a direct correlation between the amount of Ag nanoparticles in the TiOx, and interfacial charge buildup, and charge trapping being completely mitigated at around 0.2% mol. This suggests that such doping schemes might provide a simple approach to the creation and use of TiOx layers for tandem cells.
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  • 83
    Publication Date: 2013-03-07
    Description: The requirements of providing electric energy through the wind-forced generator to the heat pump for water cooling and hot water heating grow significantly by now. This study proposes a new technique to directly adopt the wind force to drive heat pump systems, which can effectively reduce the energy conversion losses during the processes of wind force energy converting to electric energy and electric energy converting to kinetic energy. The operation of heat pump system transfers between chiller and heat that are controlled by a four-way valve. The theoretical efficiency of the traditional method, whose heat pump is directly forced by wind, is 42.19%. The experimental results indicated average value for cool water producing efficiency of 54.38% in the outdoor temperature of 35°C and the indoor temperature of 25°C and the hot water producing efficiency of 52.25% in the outdoor temperature and the indoor temperature both of 10°C. We proposed a method which can improve the efficiency over 10% in both cooling and heating.
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  • 84
    Publication Date: 2013-02-08
    Description: Self-organized TiO2 nanotubes (TNTs) with average inner diameter of 109 nm, wall thickness of 15 nm, and tube length of 7–10 μm were loaded with nickel oxide (NiO) nanoparticles via incipient wet impregnation method. The molar concentration of Ni(NO3)2·6H2O aqueous solution varied in a range of 0.5 M–2.5 M. The samples were characterized for crystalline phase, morphology, topography, chemical composition, Raman shift, and UV-Vis diffusion reflection properties. The finding shows that the loading of NiO did not influence the morphology, structure, and crystalline phase of TNTs but it exhibited significant effect on crystallite size and optical absorption properties. Further, the solar-energy-driven the photocatalytic activity of NiO/TNTs and pure TNTs was evaluated by degrading methylene blue (MB). The results confirm that photocatalytic efficiency of NiO/TNTs is higher than that of TNTs.
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  • 85
    Publication Date: 2013-02-12
    Description: Technical Note: Wet validation of optical tomography for drinking water discolouration studies Drinking Water Engineering and Science Discussions, 6, 27-38, 2013 Author(s): R. Floris, P. van Thienen, and H. Beverloo This paper presents a set of validation experiments for the reconstruction of a cross-sectional particle concentration field in a transparent pipe filled with a fluid using optical tomography.
    Print ISSN: 1996-9473
    Electronic ISSN: 1996-9481
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 86
    Publication Date: 2013-02-11
    Description: The OECD/NEA Uncertainty Analysis in Modeling (UAM) expert group organized and launched the UAM benchmark. Its main objective is to perform uncertainty analysis in light water reactor (LWR) predictions at all modeling stages. In this paper, multigroup microscopic cross-sectional uncertainties are propagated through the DRAGON (version 4.05) lattice code in order to perform uncertainty analysis on and 2-group homogenized macroscopic cross-sections. The chosen test case corresponds to the Three Mile Island-1 (TMI-1) lattice, which is a 15 15 pressurized water reactor (PWR) fuel assembly segment with poison and at full power conditions. A statistical methodology is employed for the uncertainty assessment, where cross-sections of certain isotopes of various elements belonging to the 172-group DRAGLIB library format are considered as normal random variables. Two libraries were created for such purposes, one based on JENDL-4 data and the other one based on the recently released ENDF/B-VII.1 data. Therefore, multigroup uncertainties based on both nuclear data libraries needed to be computed for the different isotopic reactions by means of ERRORJ. The uncertainty assessment performed on and macroscopic cross-sections, that is based on JENDL-4 data, was much higher than the assessment based on ENDF/B-VII.1 data. It was found that the computed Uranium 235 fission covariance matrix based on JENDL-4 is much larger at the thermal and resonant regions than, for instance, the covariance matrix based on ENDF/B-VII.1 data. This can be the main cause of significant discrepancies between different uncertainty assessments.
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  • 87
    Publication Date: 2013-02-13
    Description: Reduced-gravity experiments were performed on combustion of droplets composed of n-heptane mixed with methanol or ethanol. The initial alcohol mass fraction in a droplet was 0% (pure heptane) or 5%. The experiments were performed at 0.1 MPa and 25°C with air or with ambients of oxygen and helium with oxygen mole fractions of 0.3 or 0.4. Initial droplet diameters were in the range 0.67 mm to 0.92 mm. After considering measurement uncertainties, burning rates decreased appreciably as the initial droplet diameter increased for combustion in air but not for combustion in the oxygen/helium environments. It was also found that addition of either methanol or ethanol did not influence burning rates appreciably and that burning rates were larger for the oxygen/helium environments than for air if initial droplet diameter dependences were accounted for.
    Print ISSN: 2090-1968
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  • 88
    Publication Date: 2013-02-18
    Description: We have systematically studied the photocatalytic mechanisms of nitrogen doping in anatase TiO2 using first-principles calculations based on density functional theory, employing Hubbard U (8.47 eV) on-site correction. The impurity formation energy, charge density, and electronic structure properties of TiO2 supercells containing substitutional nitrogen, interstitial nitrogen, or oxygen vacancies were evaluated to clarify the mechanisms under visible light. According to the formation energy, a substitutional N atom is better formed than an interstitial N atom, and the formation of an oxygen vacancy in N-doped TiO2 is easier than that in pure TiO2. The calculated results have shown that a significant band gap narrowing may only occur in heavy nitrogen doping. With light nitrogen doping, the photocatalysis under visible light relies on N-isolated impurity states. Oxygen vacancies existence in N-doped TiO2 can improve the photocatalysis in visible light because of a band gap narrowing and n-type donor states. These findings provide a reasonable explanation of the mechanisms of visible light photocatalysis in N-doped TiO2.
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  • 89
    Publication Date: 2013-02-09
    Description: Numerical and experimental investigation of leaks in viscoelastic pressurized pipe flow Drinking Water Engineering and Science, 6, 11-16, 2013 Author(s): S. Meniconi, B. Brunone, M. Ferrante, and C. Massari This paper extends the analysis concerning the importance in numerical models of unsteady friction and viscoelasticity to transients in plastic pipes with an external flow due to a leak. In fact recently such a benchmarking analysis has been executed for the cases of a constant diameter pipe (Duan et al., 2010), a pipe with a partially closed in-line valve (Meniconi et al., 2012a), and a pipe with cross-section changes in series (Meniconi et al., 2012b). Tests are based on laboratory experiments carried out at the Water Engineering Laboratory (WEL) of the University of Perugia, Italy, and the use of different numerical models. The results show that it is crucial to take into account the viscoelasticity to simulate the main characteristics of the examined transients.
    Print ISSN: 1996-9457
    Electronic ISSN: 1996-9465
    Topics: Energy, Environment Protection, Nuclear Power Engineering
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  • 90
    Publication Date: 2013-02-20
    Description: Highly efficient phosphorescent organic light-emitting devices (PhOLEDs) had been fabricated by using a novel iridium complex, bis[2-(,-di-tert-butylbiphenyl-4-yl)benzothiazolato-N,]iridium(III) (acetylacetonate) [(tbpbt)2Ir(acac)], as the emitter. With a wide doping ratio ranging from 15 wt% to 25 wt%, the PhOLEDs maintained a comparable high performance, indicating concentration-insensitive property of the (tbpbt)2Ir(acac). On the basis of the unique characteristic of concentration insensitivity, the application of this phosphor was explored by fabricating white organic light-emitting devices (WOLEDs) with altered doping ratio, indicating that trap effect of (tbpbt)2Ir(acac) could effectively tailor WOLEDs spectra. Typically, a high-power efficiency, current efficiency, and external quantum efficiency of 30.0 lm/W, 38.8 cd/A, 18.1%, were achieved by 20 wt% doped WOLEDs.
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  • 91
    Publication Date: 2013-02-20
    Description: This work projects photoluminescence (PL) as an alternative technique to estimate the order of resistivity of zinc oxide (ZnO) thin films. ZnO thin films, deposited using chemical spray pyrolysis (CSP) by varying the deposition parameters like solvent, spray rate, pH of precursor, and so forth, have been used for this study. Variation in the deposition conditions has tremendous impact on the luminescence properties as well as resistivity. Two emissions could be recorded for all samples—the near band edge emission (NBE) at 380 nm and the deep level emission (DLE) at ~500 nm which are competing in nature. It is observed that the ratio of intensities of DLE to NBE (/) can be reduced by controlling oxygen incorporation in the sample. - measurements indicate that restricting oxygen incorporation reduces resistivity considerably. Variation of / and resistivity for samples prepared under different deposition conditions is similar in nature. / was always less than resistivity by an order for all samples. Thus from PL measurements alone, the order of resistivity of the samples can be estimated.
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  • 92
    Publication Date: 2013-02-04
    Description: The aim of the present study is to enhance photocatalytic performance of ZnO semiconductor by comodification with doping of nonmetal ions and coupling with another semiconductor. Therefore, we synthesized the N-doped ZnO/ZnS photocatalysts via a simple heat-treatment approach using L-cysteine as N and S source in this work. Anthraquinone dye (reactive brilliant blue KNR) is employed as the model contaminants to evaluate the photocatalytic activity of as-synthesized samples under sunlight illumination. The N-doped ZnO/ZnS synthesized by this method shows better photocatalytic activity as compared to that of pure ZnO. The enhanced photocatalytic activity of the N-doped ZnO/ZnS composites may be related to the existence of N doping, ZnS/ZnO heterostructure, and covered abundant carbon species on the photocatalyst surface, which causing high absorption efficiency of light, efficient separation of electron-hole pairs, and quick surface reaction in doped ZnO.
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  • 93
    Publication Date: 2013-02-01
    Description: This paper presents a grid-connected PV system in a centralized configuration constructed through a three-phase dual-stage inverter. For the DC-DC stage the three-phase series resonant converter is chosen thanks to the advantages that it exhibits. However, it is inadequate for the accomplishment of MPPT, due to its efficiency strongly depending on the implemented deadtime and switching frequency. Then, this paper proposes a conceptual modification, that is, a modified dual-stage inverter in which the inverter stage is responsible for both the MPPT and the grid-current control. In addition, the DC-DC converter operates with constant duty cycle and frequency. Such configuration requires a new concept, introduced as Behavior Matching. It serves as a fundamental feature for the DC-DC converter to reproduce the PV array I–V characteristic when they are connected, without control action. The maximum power operating point is found by maximizing the direct axis current, obtained by Park's transformation from the inverter, through the perturbation and observation algorithm. Any specific measurement to realize the MPPT is needed. The galvanic isolation is achieved by using a high-frequency transformer. The structure is appropriate for high power applications, above 10 kW.
    Print ISSN: 2090-7451
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  • 94
    Publication Date: 2013-12-06
    Description: The performance of Dual-Axis Solar Tracker (DAST) and Static Solar System (SSS) with respect to clearness index in Malaysia is presented. An attempt to investigate the correlation between clearness index with energy gain and efficiency of DAST over SSS is being done experimentally. A good correlation could not be found out from the daily clearness index. It is due to the more profound advantage of DAST in the morning and evening compared to midday as it is able to follow the sun’s position. Hence, the daily clearness index is divided into three segments which are morning, midday, and evening to interpret the energy gain and efficiency better. A clearer correlation with low standard deviation can be observed on the segmented clearness index analysis. The energy gain and efficiency of seven cities in Malaysia is being estimated with the segmented clearness index and compared to the result generated from anisotropic radiation model. A similar trend is obtained and it has shown that the segmented clearness index could be utilized as a graphical method for estimation of energy gain and efficiency of DAST over SSS.
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  • 95
    Publication Date: 2013-12-06
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  • 96
    Publication Date: 2013-12-10
    Description: The effects of H2 plasma exposure on optical, electrical, and structural properties of fluorine-doped tin oxide (FTO) and AZO/FTO substrates have been investigated. With increasing the time of H2-plasma exposure, the hydrogen radical and ions penetrated through the FTO surface to form more suboxides such as SnO and metallic Sn, which was confirmed by the XPS analysis. The Sn reduction on the FTO surface can be effectively eliminated by capping the FTO with a very thin layer of sputtered aluminum-doped zinc oxide (AZO), as confirmed by the XPS analysis. By using the AZO/FTO as front TCO with the subsequent annealing, the p-i-n μc-Si:H cell exhibited a significantly enhanced from 15.97 to 19.40 mA/cm2 and an increased conversion efficiency from 5.69% to 7.09%. This significant enhancement was ascribed to the effective elimination of the Sn reduction on the FTO surface by the thin AZO layer during the Si-based thin-film deposition with hydrogen-rich plasma exposure. Moreover, the subsequent annealing of the sputtered AZO could lead to less defects as well as a better interface of AZO/FTO.
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  • 97
    Publication Date: 2013-12-11
    Description: Microfabrication cycles of III-V multijunction solar cells include several technological steps and end with a wafer dicing step to separate individual cells. This step introduces damage at lateral facets of the junctions that act as charge trapping centers, potentially causing performance and reliability issues, which become even more important with today’s trend of cell size reduction. In this paper we propose a process of wet etching of microtrenches that allows electrical isolation of individual solar cells with no damage to the sidewalls. Etching with bromine-methanol, the solution that is typically used for nonselective etching of III-V compounds, results in the formation of unwanted holes on the semiconductor surfaces. We investigate the origin of holes formation and discuss methods to overcome this effect. We present an implementation of the isolation step into a solar cell fabrication process flow. This improved fabrication process opens the way for improved die strength, yield, and reliability.
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  • 98
    Publication Date: 2013-12-11
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    Topics: Electrical Engineering, Measurement and Control Technology , Energy, Environment Protection, Nuclear Power Engineering
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  • 99
    Publication Date: 2013-12-06
    Description: The objective of this study is to find out the impact of instrumentation and control (I&C) components on the availability of I&C systems in terms of sensitivity analysis using Bayesian network. The analysis has been performed on I&C architecture of reactor protection system. The analysis results would be applied to develop I&C architecture which will meet the desire reliability features and save cost. RPS architecture unavailability and availability were estimated to and for failure (0) and perfect (1) states, respectively. The impact of I&C components on overall system risk has been studied in terms of risk achievement worth (RAW) and risk reduction worth (RRW). It is found that circuit breaker failure (TCB), bi-stable processor (BP), sensor transmitter (TR), and pressure transmitter (PT) have high impact on risk. The study concludes and recommends that circuit breaker bi-stable processor should be given more consideration while designing I&C architecture.
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  • 100
    Publication Date: 2013-12-09
    Description: The effect of temperature elements for PV array with tracking and concentrating features installed in the tropical ground condition is presented. The temperature segment covers ambient temperature and surface and bottom temperature for three types of PV generator systems, namely, Fixed Flat (FF), Tracking Flat (TF), and Concentrating PV (CPV) generators. The location of measuring the cell temperature, for the PV module is still being debated by researchers with the issue of how much the cell temperature () is being affected by the surface temperature (), bottom temperature (), and surrounding temperature () furthermore when it is located in fluctuating weather conditions. In this study, is calculated based on the difference between surface temperature and bottom-side temperaturewhichever the highest recorded at site for different kinds of PV generator systems but using the same CEEG 95 W monocrystalline PV module. The study embraces the direct correlation of various temperature elements in tropical-based condition with values of 2.19°C for FF module, 2.22°C for TF module, and 2.72°C for CPV module. These values which reflect the different unique configurations are further analyzed using multiple linear regression (MLR) and analysis of variance (ANOVA) test for models. This study supports the continuous research in adapting PV technology for Malaysia.
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