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  • Articles  (3)
  • Geochemistry  (3)
  • Springer  (2)
  • Massachusetts Institute of Technology and Woods Hole Oceanographic Institution  (1)
  • 2005-2009  (3)
  • 1980-1984
  • 1965-1969
  • 1925-1929
  • 2009  (3)
  • 1
    Publication Date: 2017-04-04
    Description: In the Rocca Busambra area (mid-west Sicily, Italy), from November 1999 to July 2002, 23 water points including wells and springs were sampled and studied for their chemical and isotopic compositions. Two rain gauges were also installed at different altitudes, and rainwater was collected monthly to determine the isotopic composition. The obtained results revealed the Rocca Busambra carbonate complex as being the main recharge area on account of its high permeability value. From a chemical view point, two main groups of water can be distinguished: calcium– magnesium–bicarbonate-type and calcium–magnesium– chloride–sulphate-type waters. The first group reflects the dissolution of the carbonate rocks; the second group probably originates from circulation within flyschoid sediments. Three water wells differ from the other samples due to their relatively high Na and K content, which probably is to be referred to a marked interaction with the ‘‘Calcareniti di Corleone’’ formation, which is rich in glauconite [(K, Na)(Fe3+, Al, Mg)2(Si, Al)4O10(OH)2]. In accordance with WHO guidelines for drinking water (2004), almost all the samples collected can be considered drinkable, with the exception of four of them, whose NO3 -, F- and Na+ contents exceed the limits. On the contrary, the sampled groundwater studied is basically suitable for irrigation.
    Description: Published
    Description: 885-898
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Water quality ; Environmental isotopes ; Geochemistry ; Sicily ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Following the 2001 and 2002–2003 flank eruptions, activity resumed at Mt. Etna on 7 September 2004 and lasted for about 6 months. This paper presents new petrographic, major and trace element, and Sr–Nd isotope data from sequential samples collected during the entire 2004–2005 eruption. The progressive change of lava composition allowed defining three phases that correspond to different processes controlling magma dynamics inside the central volcano conduits. The compositional variability of products erupted up to 24 September is well reproduced by a fractional crystallization model that involves magma already stored at shallow depth since the 2002–2003 eruption. The progressive mixing of this magma with a distinct new one rising within the central conduits is clearly revealed by the composition of the products erupted from 24 September to 15 October. After 15 October, the contribution from the new magma gradually becomes predominant, and the efficiency of the mixing process ensures the emission of homogeneous products up to the end of the eruption. Our results give insights into the complex conditions of magma storage and evolution in the shallow plumbing system of Mt. Etna during a flank eruption. Furthermore, they confirm that the 2004–2005 activity at Etna was triggered by regional movements of the eastern flank of the volcano. They caused the opening of a complex fracture zone extending ESE which drained a magma stored at shallow depth since the 2002–2003 eruption. This process favored the ascent of a different magma in the central conduits, which began to be erupted on 24 September without any significant change in eruptive style, deformation, and seismicity until the end of eruption.
    Description: Published
    Description: 781–793
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Geochemistry ; Isotopic compositions ; Magma feeding system ; Magma mixing ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Massachusetts Institute of Technology and Woods Hole Oceanographic Institution
    Publication Date: 2022-05-25
    Description: Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2009
    Description: The application of elemental and isotopic metal palaeoredox tracers to the geologic past rests on an understanding of modern metal cycles. This study reevaluates the surface-cycling of Mo and Re in near-surface reservoirs. Revised river averages of Mo and Re are 1.8- and 7.9-fold larger than previous estimates. The river concentrations of 8.0 nmol Mo kg−1 and 11.2 pmol Re kg−1 (pre-anthropogenic), result in shorter seawater response times of 4.4×105 yr (τMo) and 1.3×105 yr (τRe pre-anthropogenic). These metals, especially Re, are more sensitive to changing source and sink fluxes than previously thought. Evaluation of Mo and Re concentrations in high temperature fluids from the Manus Basin indicate that Re is essentially absent from the hydrothermal end member and Mo is present at concentrations considerably lower than ambient seawater. The sink fluxes represented by hydrothermal circulation are negligible in comparison to the revised river source fluxes. Anthropogenic contributions to the Re flux to seawater are seen in the high concentrations of certain impacted water samples such as those associated with mining sites. It may also be seen in a significant, variable, Re enrichment feature in the Hudson River estuary. This Re enrichment feature is not the result of estuarine mixing or the remobilization of sediment-hosted Re. On the basis of a Re - SO2− 4 correlation we are able to quantify and correct for the anthropogenic Re, which corresponds to ~33% of the modern river average. This study documents the development of an analytical method for stable Re isotopes. Though complicated by analyte requirements and 187Re – 187Os decay, Re isotope measurements have a reproducibility of ±0.05h for analyte concentrations of 20 ng Re mL−1. Total Re isotopic variability to date is 0.9h. This includes 0.3h across five commercially available Re products, and 0.5h across a black shale weathering profile. δ187Re variability across the weathering profile was systematic with the most weathered samples showing the most significant 187Re depletions. The Re isotopic weathering profile is well described by both two-component mixing and Rayleigh fractionation. There are currently insufficient data to discriminate between the two models.
    Description: We would like to acknowledge financial support from NSF-EAR grant 0519387 and from the WHOI Academic Programs Office as well as support for the WHOI Plasma Mass Spectrometry Facility from NSF-EAR/IF grants 0318137 and 0651366.
    Keywords: Rhenium ; Isotopes ; Geochemistry ; Ian Fletcher (Ship) Cruise ; Tioga (Ship) Cruise ; Melville (Ship) Cruise
    Repository Name: Woods Hole Open Access Server
    Type: Thesis
    Format: application/pdf
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