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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
  • 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
  • Elsevier  (8)
  • American Chemical Society
  • American Chemical Society (ACS)
  • 2005-2009  (8)
  • 2007  (8)
Collection
Years
  • 2005-2009  (8)
Year
  • 1
    Publication Date: 2017-04-04
    Description: New major and trace element analyses and Sr-isotope determinations of rocks from Mt. Somma–Vesuvius volcano produced from 25 ky BP to 1944 AD are part of an extensive database documenting the geochemical evolution of this classic region. Volcanic rocks include silica undersaturated, potassic and ultrapotassic lavas and tephras characterized by variable mineralogy and different crystal abundance, as well as by wide ranges of trace element contents and a wide span of initial Sr-isotopic compositions. Both the degree of undersaturation in silica and the crystal content increase through time, being higher in rocks produced after the eruption at 472 AD (Pollena eruption). Compositional variations have been generally thought to reflect contributions from diverse types of mantle and crust. Magma mixing is commonly invoked as a fundamental process affecting the magmas, in addition to crystal fractionation. Our assessment of geochemical and Srisotopic data indicates that compositional variability also reflects the influence of crustal contamination during magma evolution during upward migration to shallow crustal levels and/or by entrapment of crystal mush generated during previous magma storage in the crust. Using a variant of the assimilation fractional crystallization model (Energy Conservation– Assimilation Fractional Crystallization; [Spera and Bohrson, 2001. Energy-constrained open-system magmatic processes I: General model and energy-constrained assimilation and fractional crystallization (EC–AFC) formulation. J. Petrol. 999– 1018]; [Bohrson, W.A. and Spera, F.J., 2001. Energy-constrained open-system magmatic process II: application of energyconstrained assimilation–fractional crystallization (EC–AFC) model to magmatic systems. J. Petrol. 1019–1041]) we estimated the contributions from the crust and suggest that contamination by carbonate rocks that underlie the volcano (2 km down to 9–10 km) is a fundamental process controlling magma compositions at Mt. Somma–Vesuvius in the last 8 ky BP. Contamination in the mid- to upper crust occurred repeatedly, after the magma chamber waxed with influx of new mantle- and crustal-derived magmas and fluids, and waned as a result of magma withdrawal and production of large and energetic plinian and subplinian eruptions.
    Description: Published
    Description: 303– 329
    Description: reserved
    Keywords: Mt. Somma–Vesuvius volcano ; Sr isotopes ; Geochemistry ; Crustal contamination ; Mantle source ; Phenocryst entrapment ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: This paper presents and discusses the measurement of permeability of Neapolitan Yellow Tuff (NYT) samples obtained in the framework of a study concerning the phenomenon of bradyseism, i.e. the slow vertical movement of soil, in the Campi Flegrei caldera (Campania—Italy). Measurements have been performed under isothermal, non-isothermal and transient non-isothermal conditions using a specifically designed apparatus. Results of measurements of porosity of different samples are also reported. Experimental results in isothermal conditions show that the volume flux through the samples changes linearly with applied pressure. The values of permeability obtained turn out to be independent of the temperature and pressure gradients applied to the samples. This result is consistent with the fact that the permeability is a characteristic of the porous medium, and as such is not affected by temperature and pressure variation, at least in the range examined. The permeability values measured in our laboratories agree quite well with the ones measured in situ by the Agenzia Generale Italiana Petroli (AGIP) during a geothermal exploration of the Campi Flegrei area in 1980. An interesting, still unexplained phenomenon has been detected during transient phases when both pressure and temperature gradients were applied to the samples. The phenomenon consists in an enhancement of volume flux due to heat flux in the transient phase. The extra volume-flux disappears once the steady temperature gradient is reached.
    Description: Published
    Description: 125-136
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei sistemi vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; hydrothermal systems; ; resurgent calderas ; porous media ; hydraulic permeability ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2017-04-04
    Description: The “methane-led hypotheses” assume that gas hydrates and marine seeps are the sole geologic factors controlling Quaternary atmospheric and climate changes. Nevertheless, a wider class of geologic sources of methane exist which could have played a role in past climate changes. Beyond offshore seepage, relevant geologic emissions of methane (GEM) are from onshore seepage, including mud volcanism, microseepage and geothermal flux; altogether GEM are the second most important natural source of atmospheric methane at present. The amount of methane entering the atmosphere from onshore GEM seems to prevail on that from offshore seepage. Onshore sources inject a predominantly isotopically heavy (13C-enriched) methane into the atmosphere. They are controlled mainly by endogenic (geodynamic) processes, which induce large-scale gas flow variations over geologic and millennial time scales, and only partially by exogenic (surface) conditions, so that they are not affected by negative feedbacks. The eventual influence on atmospheric methane concentration does not necessarily require catastrophic or abrupt releases, as proposed for the “clathrate gun hypothesis”. Enhanced degassing from these sources could have contributed to the methane trends observed in the ice core records, and could explain the late Quaternary peaks of increased methane concentrations accompanied by the enrichment of isotopically heavy methane, as recently observed. This hypothesis shall be tested by means of robust multidisciplinary studies, mainly based on a series of atmospheric, biologic and geologic proxies.
    Description: Published
    Description: On line First
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; climate change ; seepage ; Quaternary ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-03
    Description: Central to any study of climate change is the development of an inventory that identifies and quantifies natural and anthropogenic sources and sinks of greenhouse gases (GHG). Recent studies have demonstrated that geologic emissions of methane (GEM), although not considered in the inventories of the IntergovernmentalPanel on Climate Change (IPCC), are an important GHG source. Etiope and Klusman (2002, Chemosphere 49, 777–789) documented that significant amounts of methane, produced within the Earth crust, are released naturally into the atmosphere through faults and fractured rocks. Major GEMs are related to hydrocarbon production in sedimentary basins (biogenic and thermogenic methane), through continuous exhalation and eruptions from more than 1200 onshore and offshore mud volcanoes (MVs), through diffuse soil microseepage, and shallow marine seeps; secondarily, methane is released from geothermal and volcano-magmatic systems. Minor geologic sources are those related to natural exhalation from coal-bearing rocks (influenced by mining activities), degassing from crystalline basement and mantle. While marine seeps have been studied for decades, methane flux from MVs has been the object of detailed measurements only since 2001, when hundreds of gas flux measurements were performed from vents and soilin the main terrestrial MVs of Europe, in Romania and Italy (Etiope et al.,2003, Geophysical Research Letters 30, 1094, doi:10.1029/2002GL016287; and references therein). In 2003 gas flux was measured in Azerbaijan, which hosts the world’s biggest MVs and densest MV population (Etiope et al., 2004, Geology, in press). In all areas investigated around 102–103 tons of methane per km2 are annually injected into the atmosphere. The global estimates of GEM from MVs range from 5 to 13Tg yr-1 (Etiope and Milkov, 2004, Environmental Geology, in press).
    Description: Published
    Description: 3099-3100
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; atmospheric gas budget ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-04
    Description: Volcanism at Mount Etna (Italy) has been observed for millennia and inspired ancient mythologies as well as scientific thought through countless generations.Yetmuch of our understanding of the way this volcano works stems fromstudies of the past 20 years, and in particular from strengthened monitoring since the late 1980s. In addition, the eruptive activity of Etna has undergone significant changes during the past 13 years, and these have led to an improved understanding of the relationship between the plumbing system of the volcano and instability of its eastern to southern f lanks. Following the end of the 1991–1993 eruption, a new eruptive cycle began, which so far has produced about 0.23 km3 of lavas and pyroclastics (dense-rock equivalent). The cycle evolved frominitial recharging of the plumbing system and inf lation, followed by powerful summit eruptions and slow spreading of the eastern to southern f lanks, to a sequence of f lank eruptions accompanied by accelerated f lank displacement. Structurally, the volcanic system has become increasingly unstable during this period. Volcanological, geophysical and geochemical data allow the cause–effect and feedback relationships between magma accumulation below the volcano, f lank instability, and the shift from continuous summit activity to episodic f lank eruptions to be investigated. In this scenario, the growth of magma storage areas at a depth of 3–5 km below sea level exerts pressure against those f lank sectors prone to displacement, causing them to detach from the stable portions of the volcanic edifice. Geochemical data indicate that magma remains stored belowthe volcano, even during phases of intense eruptive activity, thus causing a net volumetric increase that is accommodated by f lank displacement. Instability can be enhanced by the forceful uprise ofmagma through the f lanks, as in 2001, when the f irst f lank eruption of the current eruptive cycle took place. Subsequent f lank eruptions in 2002–2003 and 2004– 2004, on the other hand, were, at least in part, facilitated by the opening of fractures at the head of moving f lank sector, although the eruptions were significantly dissimilar from one another. Renewed inflation of the volcano after the 2004–2005 eruption, continued displacement of the unstable f lank sector, and gradual resumption of summit activity in late-2005, demonstrate that the same feedback mechanisms continue to be active, and the Etna system remains highly unstable. The evolution of earlier eruptive cycles shows that a return to a state of relative stability is only possible once a voluminous f lank eruption effectively drains the magmatic plumbing system.
    Description: Published
    Description: 85–114
    Description: reserved
    Keywords: Mount Etna ; eruptive cycle ; volcano monitoring ; seismicity ; deformation ; geochemistry ; structural geology ; magma storage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2017-04-04
    Description: A large database of major, trace and isotope (Sr, Nd, Pb, O) data exists for rocks produced by the volcanic activity of Somma-Vesuvius volcano. Variation diagrams strongly suggest a major role for evolutionary processes such as fractional crystallization, contamination, crystal trapping and magma mixing, occurring after magma genesis in the mantle. Most mafic magmas are enriched in LILE (K, Rb, Ba), REE (Ce, Sm) and Y, show small Nb–Ta negative anomalies, and have values of Nb/Zr at about 0.15. Enrichments in LILE, REE, Nb and Ta do not correlate with Sr isotope values or degree of both K enrichment and silica undersaturation. The results indicate mantle source heterogeneity produced by slab-derived components beneath the volcano. However, the Sr isotope values of Somma-Vesuvius increase from 0.7071 up to 0.7081 with transport through the uppermost 11–12 km of the crust. The Sr isotope variation suggests that the crustal component affected the magmas during ascent through the lithosphere to the surface. Our new geochemical assessment based on chemical, isotopic and fluid inclusion data points to the existence of three main levels of magma storage. Two of the levels are deep and may represent long-lived reservoirs, and an uppermost crustal level that probably coincides with the volcanic conduit. The deeper level of magma storage is deeper than 12 km and fed the 1944 AD eruption. The intermediate level coincides with the seismic discontinuity detected by Zollo et al. (1996) at about 8 km. This intermediate level supplies magmas with 87Sr/86Sr values between 0.7071 and 0.7074, and δO18 8‰ that typically erupted both during interplinian (i.e. 1906 AD) and sub-plinian (472 AD, 1631 AD) events. The shallowest level of magma storage at about 5 km was the site of magma chambers for the Pompei and Avellino eruptions. New investigations are necessary to verify the proposed magma feeding system.
    Description: Published
    Description: 183-204
    Description: open
    Keywords: NONE ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 7
    Publication Date: 2017-04-04
    Description: The first measurements of volcanic/hydrothermal water vapor and heat flux using eddy covariance (EC) were made at Solfatara crater, Italy, June 8–25, 2001. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes of water vapor varied between 680 and 11200g H2O m−2 d−1. Heat fluxes varied diurnally with the solar input, and the volcanic component of sensible heat ranged from ∼25 to 238W m−2. The highest measurements of both sensible and latent heat flux were made downwind of hot soil regions and degassing pools and during mid-day. The ratio of average volcanic heat (both latent and sensible) to CO2 flux resulted in an equivalent H2O/CO2 flux ratio of 2.2 by weight, which reflects the deep source H2O/CO2 gas ratio. The amount latent heat flux/evaporation was determined to be consistent both with what would be expected from the magnitude of CO2 fluxes and the fumarolic H2O/CO2 ratio, as well as with observed surface temperatures and wind speeds given a moist soil. This suggests that the water vapor that condenses in the shallow subsurface is remobilized at the soil–atmosphere interface through variable evaporation dependent on the deep heat flux and surface temperature. The results suggest that EC provides a quick and easy method to monitor average H2O/CO2 ratios continuously in volcanic regions, providing another important tool for volcanic hazards monitoring.
    Description: Published
    Description: 72–82
    Description: reserved
    Keywords: eddy covariance ; volcanic ; heat flux ; water vapor ; hydrothermal ; degassing ; flux ; emissions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2023-01-16
    Description: On April 5, 2003, Stromboli volcano (Italy) produced the most violent explosion of the past 50 years. The event was exceptionally well documented thanks to the presence on the island of several scientists and a large number of instruments deployed over the preceding months to monitor the effusive eruption that began in December 2002. Integration of visual documentation, deposit features and geophysical data allowed an accurate reconstruction of the explosive event and its dynamics. The eruption consisted of a 8-min long explosive event which evolved through four phases whose timing was precisely recorded by an infrared thermometer located about 450 m from the summit crater. Phases 2 and 3 lasted 39 and 42 s, respectively. Both had an impulsive character, were responsible for ejecting almost the entire mass of the pyroclastic products. Phases 1 and 4 represented, respectively, a short-lived precursory event and a waning tale. During Phase 2, meter-sized ballistic blocks were launched with velocities of 170 m/s to altitudes of up to 1400 m above the craters. These fell on the volcano flanks and on the village of Ginostra, about 2 km distant from the vent. A vertical jet rose above the craters which developed to feed a convective plume that reached a height of up to 4 km. The calculated mass of the Phase 2 fallout deposit and mass discharge rate were 1.1–1.4×108 kg and 2.8– 3.6×106 kg/s, respectively. During Phase 3 a scoria flow deposit, with an estimated volume of 0.9–1.1×104 m3, was erupted from the same vent that fed the ongoing sustained lava flow. The average mass discharge rate for this phase was 2.5–3.1×105 kg/s. Products emitted during Phases 2 and 3 consisted of lithic and fresh magmatic material in similar proportions. The juvenile fraction consisted of a deep-originated, almost aphyric, highly vesicular pumice mingled with a shallow-derived, crystal-rich, moderately vesicular scoria. Similarities with the eruption dynamics of other historical paroxysms at Stromboli makes the April 5, 2003 explosion representative of these highly energetic events that constitute the most hazardous volcanic phenomena at Stromboli volcano.
    Description: Published
    Description: 594-606
    Description: JCR Journal
    Description: reserved
    Keywords: stromboli ; Thermal monitoring; paroxysm ; explosive dynamics ; ballistic ejecta ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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