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  • Sea surface temperature  (2)
  • American Geophysical Union  (2)
  • Essen : Verl. Glückauf
  • Hannover : BGR
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • Lower Hutt : Institute of Geological and Nuclear Sciences
  • München : Landesamt für Vermessung und Geoinformation Bayern
  • 2005-2009  (2)
  • 2006  (2)
Collection
Keywords
Publisher
  • American Geophysical Union  (2)
  • Essen : Verl. Glückauf
  • Hannover : BGR
  • Krefeld : Geologischer Dienst Nordhein-Westfalen
  • Lower Hutt : Institute of Geological and Nuclear Sciences
    • +
Years
  • 2005-2009  (2)
Year
  • 1
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    Growth and composition of high-Mg calcite in the skeleton of a Bermudian gorgonian (Plexaurella dichotoma) : potential for paleothermometry (2006)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q08010, doi:10.1029/2005GC000911.
    Description: We used Secondary Ion Mass Spectrometry (SIMS) ion microprobe to analyze magnesium-to-calcium (Mg/Ca) and strontium-to-calcium (Sr/Ca) ratios of high-Mg calcite loculi within the skeleton of a shallow water gorgonian, Plexaurella dichotoma, from Bermuda. A cross-section of the gorgonian skeleton reveals loculi embedded within proteinaceous gorgonin arranged in concentric rings about the axial core. Viewed in cross-section, the loculi are fan-shaped, 10-140 μm in diameter, and composed of bundles of needle-shaped crystals that appear to radiate out from a calcification center. Discrete sample spots, each 20 μm diameter, were sputtered from successive loculi along a sample track 3 mm long. Over this distance, twenty-five bands of high-low density gorgonin couplets were encountered, estimated to represent the period 1963 to 1988. Mg/Ca ratios show an overall, positive correlation with annual sea surface temperatures (SSTs) that is strongest in the autumn months (October- December). High-resolution analyses along the growth axes of individual loculi reveal low variability and no trend, consistent with our interpretation of seasonal growth of these calcite inclusions. The sensitivity of Mg/Ca to interannual changes in average autumn temperatures is 0.47 mmol/mol per ºC. Conversely, interannual variability in calcite Sr/Ca does not follow the interannual variability in SST and may be influenced primarily by growth rate.
    Description: This study was supported by an Independent Study Award from the Woods Hole Oceanographic Institution No. 270051.81; NERC grant GR3/12800; a WHOI Ocean Life Institute grant to ALC; Bermuda Government, in support of the Benthic Ecology Research Programme at BBSR to SRS. Support for the WHOI Northeast National Ion Microprobe Facility was provided by NSF EAR-9628749.
    Keywords: Gorgonian ; Octocoral ; Mg/Ca ; Sr/Ca ; Sea surface temperature ; Biomineralization ; Growth bands ; SIMS ion microprobe ; Bermuda
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: 438997 Bytes
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  • 2
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    Global temperature calibration of the alkenone unsaturation index (UK′37) in surface waters and comparison with surface sediments (2006)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q02005, doi:10.1029/2005GC001054.
    Description: In this paper, we compile the current surface seawater C37 alkenone unsaturation (UK′37) measurements (n=629, −1 to 30°C temperature range) to derive a global, field-based calibration of UK′37 with alkenone production temperature. A single nonlinear “global” surface water calibration of UK′37 accurately predicts alkenone production temperatures over the diversity of modern-day oceanic environments and alkenone-synthesizing populations (T=−0.957 + 54.293(UK′37) − 52.894(UK′37)2 + 28.321(UK′37)3, r2=0.97, n=567). The mean standard error of estimation is 1.2°C with insignificant bias in estimated production temperature among the different ocean regions sampled. An exception to these trends is regions characterized by strong lateral advection and extreme productivity and temperature gradients (e.g., the Brazil-Malvinas Confluence). In contrast to the surface water data, the calibration of UK′37 in surface sediments with overlying annual mean sea surface temperature (AnnO) is best fit by a linear model (AnnO=29.876(UK′37) − 1.334, r2=0.97, n=592). The standard error of estimation (1.1°C) is similar to that of the surface water production calibration, but a higher degree of bias is observed among the regional data sets. The sediment calibration differs significantly from the surface water calibration. UK′37 in surface sediments is consistently higher than that predicted from AnnO and the surface water production temperature calibration, and the magnitude of the offset increases as the surface water AnnO decreases. We apply the global production temperature calibration to the coretop UK′37 data to estimate the coretop alkenone integrated production temperature (coretop IPT) and compare this with the overlying annual mean sea surface temperature (AnnO). We use simple models to explore the possible causes of the deviation observed between the coretop temperature signal, as estimated by UK′37, and AnnO. Our results indicate that the deviation can best be explained if seasonality in production and/or thermocline production as well as differential degradation of 37:3 and 37:2 alkenones both affect the sedimentary alkenone signal.
    Description: C.R. acknowledges funding from the Deutsche Forschungsgemeinschaft (DFG).
    Keywords: Alkenones ; Paleoproxies ; Sea surface temperature ; UK′37
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: 7149777 bytes
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