ALBERT

Description: A series of idealised numerical simulations of dense water flowing down a broad uniform slope are presented, employing both a z-coordinate model (the MIT general circulation model) and an isopycnal coordinate model (the Hallberg Isopycnal Model). Calculations are carried out at several different horizontal and vertical resolutions, and for a range of physical parameters. A subset of calculations are carried out at very high resolution using the non-hydrostatic variant of the MITgcm. In all calculations dense water descends the slope while entraining and mixing with ambient fluid. The dependence of entrainment, mixing and down-slope descent on resolution and vertical coordinate are assessed. At very coarse resolutions the z-coordinate model generates excessive spurious mixing, and dense water has difficulty descending the slope. However, at intermediate resolutions the mixing in the z-coordinate model is less than found in the high-resolution non-hydrostatic simulations, and dense water descends further down the slope. Isopycnal calculations show less resolution dependence, although entrainment and mixing are both reduced slightly at coarser resolution. At intermediate resolutions the z-coordinate and isopycnal models produce similar levels of mixing and entrainment. These results provide a benchmark against which future developments in overflow entrainment parameterizations in both z-coordinate and isopycnal models may be compared.

Description: We investigated the ability of accelerated solvent extraction (ASE) to extract selected lipid biomarkers (C19–C34 n-alkanes, n-alcohols and n-fatty acids as well as dehydroabietic acid and β-sitosterol) from a sandy soil profile under Corsican pine. Two organic layers (moss and F1) as well as two mineral soil horizons (EA and C1) were sampled and extracted with DCM/MeOH (93:7 v/v) by ASE at 75 °C and a pressure of 6.9 × 106 Pa or 17 × 106 Pa. Soxhlet extractions were used as the established reference method. After clean-up and derivatization with BSTFA, the extracts were analyzed on GC/MS. Using Soxhlet as a reference, we found ASE to extract all compounds adequately. The n-alkanes, especially, were found to be extracted very efficiently from all horizons studied. Only the n-fatty acids and β-sitosterol from the organic layers seemed to be extracted at a slightly lower efficiency by ASE. In all but two instances the relative abundance of extracted lipids within a component class was the same regardless of the extraction method used. Using a higher pressure in the ASE extractions significantly increased the extraction efficiency for all component classes in the moss layer, except β-sitosterol. The effect was most pronounced for the n-alkanes. In the EA horizon, a higher pressure slightly reduced the extraction efficiency for dehydroabietic acid. The observed differences between ASE and Soxhlet extractions as well as the pressure effect can be explained by a decrease in polarity of the extractant due to the elevated pressure and temperature applied during ASE extractions as compared to Soxhlet extractions. This would mainly increase the extraction efficiency of the least polar biomarkers: the n-alkanes as was observed. In addition, a better penetration of still partially water-filled micro pores under elevated pressure and temperature may have played a role.

Description: The historic record of large megathrust earthquakes suggests that the potential for great destructive events is much larger for Sumatra than Java. Bouguer gravity anomalies correlate well with the occurrence of large megathrust earthquakes in the Sunda subduction zone; negative anomalies mark segments characterized by larger earthquakes while positive anomalies indicate lower seismic potential. Thermal models and structural constraints derived from seismic and gravity data are used to explain the seismogenic behaviour in the Sunda subduction zone. With respect to Java, oblique subduction of young oceanic crust shifts the seismogenic coupling zone roughly 40 km trenchward offshore of northern Sumatra and increases the width of the locked megathrust. A prominent positive gravity anomaly offshore of Java is caused by a shallow mantle wedge underlying the forearc basin. A serpentinized mantle wedge would limit the width of the coupling zone off Java to only 30–40 km, compared to 〉 120 km offshore of Sumatra. Sumatra remains therefore the most vulnerable site for future megathrust earthquakes, while the shallow mantle wedge may limit the violence of rupture off Java.

Description: Granodiorite from the Gęsiniec Intrusion, Strzelin Crystalline Massif, SW Poland contains complexly zoned plagioclases. Five chemically and structurally distinct zones can be correlated among crystals: ‘cores’ (25–35% An), inner mantles (∼40–45% An), outer mantles (40–25% An), resorption zones (35–50% An) and rims (35–30% An). Good structural and chemical (major and trace elements) correlation of zones between crystals indicates that zonation was produced by changes in conditions of crystallization on a magma chamber scale. Plagioclase, being the liquidus phase, records a time span from the beginning of crystallization to emplacement and rapid cooling of granodiorite as thin dykes. Crystallization began with the formation of inner mantles. The paucity and different sizes of inner mantles suggests slow crystallization in high temperature magma. Normally zoned inner mantles were formed under increasing undercooling. Compositional trends in mantles suggest closed system crystallization. The major resorption zones were caused by injection of less evolved magma as indicated by the strontium increase in plagioclase. The injection triggered a rapid rise of magma and plagioclase crystals facilitating mixing but also inducing fast, kinetically controlled growth of complex multiple, oscillatory zonation within resorption zones. The ascent of magma caused decompression melting of plagioclase and produced melt inclusions within inner mantles—the ‘cores’. The decompression range is estimated at a minimum of 2 kbar. Emplacement of granodiorite as thin dykes allow rapid cooling and preservation of magmatic zonation in plagioclases. Melt inclusions crystallized completely during post-magmatic cooling. The zonation styles of plutonic plagioclase differ markedly from volcanic ones suggesting different magma evolution. Zones in plutonic plagioclase are well correlated indicating crystallization in quiescent magma where crystals accumulation and compositional magma stratification may occur. Crystals probably did not travel between different regimes. Resorption occurred but as single albeit complex episodes. Good correlation of zones in plutonic plagioclases allows a distinction between the main processes controlling zonation and superimposed kinetic effects.

Description: Compilation and interpretation of experimental and natural Nernst partition coefficient (plagioclase/meltD) data show that, with a few exceptions, increases in plagioclase/meltD correlate with decreasing anorthite-content of plagioclase. In contrast, increases of plagioclase/meltD for Ga, Sc, Cu, Zn, Zr, Hf and Ti, are better correlated against decreasing melt MgO or increasing melt SiO2 contents. plagioclase/meltD for Ti and the rare earth elements (REE) show little dependence on temperature, but increase as the melt water content increases. plagioclase/meltD for K and Sr are sensitive to pressure. Variations of D0 (the strain compensated partition coefficient), r0 (the size of the site into which REE substitute), and E (Young’s Modulus of this site) were parameterized against variations of melt SiO2, the An-content of plagioclase, and other combinations of variables, allowing plagioclase/meltDREE-Y to be calculated from a variety of input parameters. The interrelations of temperature, melt MgO and SiO2 content, and plagioclase anorthite-content for wet and dry systems were also parameterized to facilitate interpolation where such data are lacking. When combined, these semi-empirical parameterizations yield plagioclase/meltD results comparable to available experimental and natural data.

Description: Although Scotland and the wider UK is making good progress with research and development towards deployment of offshore carbon capture and storage, there is increasing divergence in opinion on the necessity of CCS for meeting climate change targets. Oil and gas operators appear optimistic about the technical feasibility of CCS; whereas civil society and NGOs are increasingly vocal in their scepticism towards the necessity of CCS in a net-zero society. Given that operators’ expertise may be required to support offshore CO2 storage given their subsea experience, and that civil society is important in shaping government and public opinion, this divergence may be a challenge to offshore CCS deployment in the UK and elsewhere. The purpose of this paper is to evaluate the grounds on which oil and gas operators’ views on CCS differ from a wider range of stakeholders, through a survey and in-depth interviews. Our results show that people with more knowledge of CCS are more likely to support its deployment, and that strong belief in anthropogenic climate change is lower – albeit rising – among oil and gas respondents. Our results also show concern that the net-zero transition may have negative effects for carbon-intensive regions, and that storage expertise is the UK’s strongest skill set for CCS deployment. We suggest that across a range of stakeholders, the value of CCS is thus most likely to lie in specific applications (e.g. hydrogen) and/or very specific localities (e.g. places with existing subsurface knowledge and skills), rather than widespread deployment as a mitigation

Description: The effects of variability in environmental conditions on species composition in benthic ecosystems are well established, but relatively little is known about how environmental variability relates to ecosystem functioning. Benthic invertebrate assemblages are heavily involved in the maintenance of ecological processes and investigation of the biological characteristics (traits) expressed in these assemblages can provide information about some aspects of functioning. The aim of this study was to establish and explore relationships between environmental variability and biological traits expressed in megafauna assemblages in two UK regions. Patterns of trait composition were matched to environmental conditions and subsets of variables best describing these patterns determined. The nature of the relationships were subsequently examined at two separate scales, both between and within the regions studied. Over the whole area, some traits related to size, longevity, reproduction, mobility, flexibility, feeding method, sociability and living habit were negatively correlated with salinity, sea surface temperature, annual temperature range and the level of fishing effort, and positively associated with fish taxon richness and shell content of the substratum. Between the two regions, reductions in temperature range and shell content were associated with infrequent relative occurrences of short-lived, moderately mobile, flexible, solitary, opportunistic, permanent-burrow dwelling fauna and those exhibiting reproductive strategies based on benthic development. Relationships between some traits and environmental conditions diverged within the two regions, with increases in fishing effort and shell content of the substratum being associated with low frequencies of occurrence of moderately mobile and moderately to highly flexible fauna within one region, but high frequencies in the other. These changes in trait composition have implications for ecosystem processes, with, for example, reductions in permanent-burrow dwellers within one of the regions potentially compromising the ability of the assemblages to process and store chemicals and waste products. However, the connections between environmental conditions and trait composition are complex and incorporate many factors. Experimental investigations will be necessary to determine the extent and consequences of these important relationships.

Description: The developmental changes in the concentration of 8 essential and non-essential heavy metals (Ag, Cd, Cu, Co, Fe, Pb, V, Zn) in the tissues (digestive gland, cuttlebone and whole animal) of the common cuttlefish Sepia officinalis collected in the bay of the river Seine were monitored from the end of the embryogenesis until the adult reproductive stage. Compared to embryos, juveniles after hatching displayed much higher concentrations of Ag, Cu, Fe and Zn, suggesting an efficient incorporation from seawater. Conversely, the amounts of Cd, Pb and V in hatchlings remained constant suggesting that these metals are barely bioavailable for juveniles. Once the juveniles start to feed, the digestive gland appears to play a major role in the storage of all metals. After only one month of benthic life, the digestive gland already contains up to 90% of the total metal body burden, indicating that it plays a major role in the storage and presumed detoxification of the selected metals. Metal concentrations in the digestive gland increase in a logarithmic fashion with age during the entire life of cuttlefish, except for Ag, which decreases as soon as cuttlefish migrate to open sea. This strongly suggests that (1) Ag is excreted from the digestive gland in relation to presumably lower exposure in less contaminated environments compared to coastal waters and (2) the digestive gland of cephalopods could be a very good indicator of Ag contamination in the marine environment.