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  • 05. General::05.02. Data dissemination::05.02.01. Geochemical data  (5)
  • 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques  (4)
  • American Geophysical Union  (9)
  • Nova Science Publishers, Inc., Hauppauge, NY
  • 2005-2009  (9)
  • 2005  (9)
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Keywords
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  • 2005-2009  (9)
Year
  • 1
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    Intercomparison of volcanic gas monitoring methodologies performed on Vulcano Island, Italy (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Volcanic gas emissions from fumaroles on the rim of La Fossa crater, Vulcano Island, Italy, were measured simultaneously using direct sampling (for H2O, CO2, total sulfur, HCl and HF), filter packs (for SO2, HCl, HF) and short-path active-mode FTIR measurements (for H2O, CO2,SO2, HCl and HF) in an intercomparison study in May 2002. The results show that Cl/F ratios were in good agreement between all three methods, and that FTIR and direct sampling determined comparable proportions of CO2 and H2O. Amounts of total S observed in direct sampling data were approximately double the amounts of SO2 measured with filter packs and FTIR. This difference could be attributed either to the fact FTIR and filter packs do not measure reduced sulfur species (e.g., H2S) or to sublimation of elemental S upon exit from the fumarole, after collection by direct sampling but before detection with FTIR and filter packs.
    Description: Published
    Description: L02610
    Description: partially_open
    Keywords: volcanic gas techniques ; gas geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Molecular and isotopic composition of free hydrocarbon gases from Sicily, Italy (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Chemical and isotopic data have been used as geochemical tracers for a genetic characterization of hydrocarbon gases from a total of eleven manifestations located in Eastern and Central-Southern Sicily (Italy). The molecular analysis shows that almost all the samples are enriched in methane (up to 93.2% Vol.), with the exception of four gas samples collected around Mt. Etna showing high mantle-derived CO2 content. Methane isotope signatures suggest that these are thermogenic gases or a mixture between thermogenic gases and microbial gases. Although samples from some mud volcanoes in Southern Sicily (Macalube di Aragona) show isotope signatures consistent with a mixing model between thermogenic and microbial, by combining the molecular compositions (C1/(C2 + C3))and the methane isotope ratios (d13C1), such a process seems to be excluded. Therefore, the occurrence of secondary post-genetic processes should be invoked. Two main hypotheses have been considered: the first hypothesis includes that the gas is produced by microbial activity and altered post-genetically by microbial oxidation of methane, while according to the second hypothesis thermogenic gas have modified their molecular ratios due to vertical migration.
    Description: Published
    Description: L06607
    Description: partially_open
    Keywords: Isotopic composition/chemistry ; Organic geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    A PTFE membrane for the in situ extraction of dissolved gases in natural waters: Theory and applications (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: A new method for extracting dissolved gases in natural waters has been developed and tested, both in the laboratory and in the field. The sampling device consists of a polytetrafluroethylene (PTFE) tube (waterproof and gas permeable) sealed at one end and connected to a glass sample holder at the other end. The device is pre-evacuated and subsequently dipped in water, where the dissolved gases permeate through the PTFE tube until the pressure inside the system reaches equilibrium. A theoretical model describing the time variation in partial gas pressure inside a sampling device has been elaborated, combining the mass balance and ‘‘Solution-Diffusion Model’’ which describes the gas permeation process through a PTFE membrane). This theoretical model was used to predict the temporal evolution of the partial pressure of each gas species in the sampling device. The model was validated by numerous laboratory tests. The method was applied to the groundwater of Vulcano Island (southern Italy). The results suggest that the new sampling device could easily extract the dissolved gases from water in order to determine their chemical and isotopic composition.
    Description: - European Social Fund.
    Description: Published
    Description: Q09005
    Description: partially_open
    Keywords: dissolved gases ; helium isotope ; PTFE membrane ; Vulcano Island ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Accurate measurement of volcanic SO2 flux: Determination of plume transport speed and integrated SO2 concentration with a single device (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Ground-based measurements of volcanic sulfur dioxide fluxes are important indicators of volcanic activity, with application in hazard assessment, and understanding the impacts of volcanic emissions upon the environment and climate. These data are obtained by making traverses underneath the volcanic plume a few kilometers from source with an ultraviolet spectrometer, measuring integrated SO2 concentrations across the plume’s cross section, and multiplying by the plume’s transport speed. However, plume velocities are usually derived from ground-based anemometers, located many kilometers from the traverse route and hundreds of meters below plume altitude, complicating the experimental design and introducing large flux (can be 〉100%) errors. Here we present the first report of a single instrument capable of (accurate) volcanic SO2 flux measurements. This device records integrated SO2 concentrations and plume heights during traverses. Between traverses, two in-plume SO2 time series are measured from underneath the plume with the instrument, corresponding to zenith and inclined (user-specified angle from vertical in the direction of the volcano) fields of view, respectively. The distance between the points of intersection of the two views with the plume is found on the basis of the determined plume height, and the two signals are cross-correlated to determine the lag between them, enabling accurate derivation of the wind speed. We present flux data (with errors ±12%) obtained in this way at Mt. Etna during July 2004.
    Description: Published
    Description: Q02003
    Description: partially_open
    Keywords: DOAS ; volcanic SO2 emissions. ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Geochemical precursors of the activity of an open-conduit volcano: The Stromboli 2002-2003 eruptive events (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Marked increases of CO2, H2 and He dissolved in thermal waters and changes in the dissolved carbon isotopic composition, were observed at Stromboli before the 28 December 2002 eruption and before a violent explosive paroxysm occurred on 5 April 2003. High anomalous CO2 flux values were recorded at the crater rim since a week before the eruption onset. The first anomalies in the thermal waters (dissolved CO2 amount) appeared some months before the eruption, when magma column rose at a very high level in the conduit. High peaks of dissolved H2 and He were recorded a few days before the paroxysm. Carbon isotopic composition indicates a magmatic origin of the dissolved CO2 whose increase, together with those of H2 and He, is attributed to an increasing output of deep gases likely produced by depressurization of a rising batch of a deep gas-rich magma, whose fragments have been emitted during the explosion.
    Description: Italian Civil Protection
    Description: Published
    Description: L07620
    Description: partially_open
    Keywords: Stromboli ; geochemical precursors ; CO2 flux ; pH ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
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    Nitrogen isotopes in thermal fluids of a forearc region (Jalisco Block, Mexico): evidence for heavy nitrogen from continental crust (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The Jalisco Block (JB) is a geologically and tectonically complex part of northwestern Mexico characterized by active subduction-type volcanism, rifting, and old stable structures. Thermal springs and groups of springs are widely distributed over JB. Bubbling gas from seven thermal springs located within different tectonic environments of the JB was analyzed for He, 20Ne, and N2 concentrations and d15N ratios. All gases are N2-dominant (〉84%) with the exception of one sample (Rio´ Purificacio´n), which has a significant CH4 content (about 50%). All collected gas samples are relatively high in He, up to 1500 ppm vol and with 3He/4He values ranging from 0.6 to 4.5 Ra. All measured nitrogen isotope ratios are heavier than air with d15N values ranging from 0.5 to 5.0%. The relative N2 excess with respect to air-saturated water computed on the basis of N2 and 20Ne contents indicates the contribution of a nonatmospheric N2 source. All the samples show a good correlation between d15N and the relative excess of N2 with d15N +5.3% for the maximum N2 excess of 100%. Due to a presumed lack of seafloor sediment involved in the subduction process, such a d15N positive value seems to reflect the addition to the fluids of a heavy nitrogen originating from metamorphism processes of rocks occurring within the overlying continental crust.
    Description: Published
    Description: 1-9
    Description: partially_open
    Keywords: bubbling gases ; forearc region ; Jalisco Block-Mexico ; nitrogen isotopes ; subduction-related volcanism ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
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    Geochemical evidence of seismogenic-induced anomalies in the dissolved gases of thermal waters: A case study of Umbria (Central Apennines, Italy) both during and after the 1997-1998 seismic swarm (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: In this paper we present the first geochemical data set regarding long-term monitoring of dissolved gases in thermal waters from a seismic area. Three sites in Umbria (Central Apennines, Italy) were studied both for the chemical and for the helium isotopic composition of the dissolved gases. Data were collected during and after the seismic crisis that struck the region in 1997â 1998. The chemical composition of the dissolved gases revealed that a CO2-rich gas phase was always mixed with an atmospheric-derived component dominated by N2. A normal faulting marked the beginning of the seismic activity enhancing the release of CO2 on a regional scale. Variations in both the chemical and isotopic compositions of the dissolved gases were also observed as preseismic, synseismic, and postseismic phenomena related to the seismic shock of March 1998. Those geochemical modifications were interpreted as being the consequence of a drop in the CO2 degassing rate, in good agreement with the compressive focal mechanism of that seismic event. Furthermore, this interpretation was also consistent with the geologic and tectonic setting of the study area and induced us to postulate that changes in the local rock permeability, due to crustal deformations (i.e., coseismic deformation and postseismic release), were responsible for the geochemical modifications observed. On the basis of the foregoing, we have concluded that the geochemistry of dissolved gases in groundwaters represents a useful tool for the investigation of the relationships between circulating fluids and seismic activity.
    Description: Published
    Description: partially_open
    Keywords: dissolved gases ; geochemistry ; seismic areas ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
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    Chemical mapping of a fumarolic field: La Fossa Crater, Vulcano Island (Aeolian Islands, Italy) (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The performance of a newly-developed portable gas analyzer, capable of real-time measurement of CO2, SO2 and H2S concentrations in volcanic gases, was tested at La Fossa Crater, Vulcano Island. The gas analyzer was used to acquire about 3000 determinations over the fumarolic field, allowing the definition of its chemical structure and heterogeneity. Our high-resolution analysis reveals that, in December 2004, the La Fossa fumarolic field was characterized by an oxidized inner core (SO2/H2S ratios of 3), and by more reducing conditions on its northern edge (SO2/H2S ratios of 1; range: 0.2–3.3). CO2/(SO2+H2S) molar ratios averaged 35 ± 21, with overlapping compositions for rim and inner crater fumaroles. S-poor compositions (CO2/(SO2+H2S) 50) characterized the field margins, probably due to deposition of native sulfur. Based on the above data and an SO2 flux of 18 ± 3 t.d-1, we estimate CO2 and H2S output rates from the volcano of 420 ± 250 and 4 ± 2 t.d-1, respectively.
    Description: Published
    Description: L13309
    Description: partially_open
    Keywords: electrochemical sensors ; fumarolic gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
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    Evidence of a recent input of magmatic gases into the quiescent volcanic edifice of Panarea, Aeolian Islands, Italy (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: On 2nd/3rd November 2002, a huge amount of gas, mainly composed of CO2, was suddenly released from the sea bottom off the coast of Panarea, producing a ‘‘crater’’20 by 10 meters wide and 7 meters deep. The gas output was estimated to be 109 l/d, two orders of magnitude higher than that measured in the 1980s. The anomalous degassing rate lasted for some weeks, slowly decreasing to an almost constant rate of about 4 x 107 l/d after two months. The geothermo- barometric estimations revealed an increase of both the temperature and pressure in the geothermal system feeding the sampled vents. The 3He/4He ratios were similar to those measured in nearby Stromboli. We have monitored the area for the last two decades, and based on our intensive and extensive geochemical measurements, have ascertained that the geothermal reservoir has lost its steady state. We maintain that a new magmatic input caused these phenomena.
    Description: - Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Vesuviano, Naples, Italy. - Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo, Palermo, Italy. - Dipartimento Chimica e Fisica della Terra ed Applicazioni, Palermo, Italy.
    Description: Published
    Description: L07619
    Description: partially_open
    Keywords: Submarine degassing ; magmatic fluids ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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