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  • Elsevier  (90,657)
  • American Chemical Society  (33,141)
  • American Geophysical Union  (5,143)
  • 2005-2009  (128,941)
  • 2005  (128,941)
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  • 1
    Publication Date: 2023-04-25
    Description: Arabidopsis genes encoding enzymes for each of the eight steps in l-arginine (Arg) synthesis were identified, based upon sequence homologies with orthologs from other organisms. Except for N-acetylglutamate synthase (NAGS; EC 2.3.1.1), which is encoded by two genes, all remaining enzymes are encoded by single genes. Targeting predictions for these enzymes, based upon their deduced sequences, and subcellular fractionation studies, suggest that most enzymes of Arg synthesis reside within the plastid. Synthesis of the l-ornthine (Orn) intermediate in this pathway from l-glutamate occurs as a series of acetylated intermediates, as in most other organisms. An N-acetylornithine:glutamate acetyltransferase (NAOGAcT; EC 2.3.1.35) facilitates recycling of the acetyl moiety during Orn formation (cyclic pathway). A putative N-acetylornithine deacetylase (NAOD; EC 3.5.1.16), which participates in the “linear” pathway for Orn synthesis in some organisms, was also identified. Previous biochemical studies have indicated that allosteric regulation of the first and, especially, the second steps in Orn synthesis (NAGS; N-acetylglutamate kinase (NAGK), EC 2.7.2.8) by the Arg end-product are the major sites of metabolic control of the pathway in organisms using the cyclic pathway. Gene expression profiling for pathway enzymes further suggests that NAGS, NAGK, NAOGAcT and NAOD are coordinately regulated in response to changes in Arg demand during plant growth and development. Synthesis of Arg from Orn is further coordinated with pyrimidine nucleotide synthesis, at the level of allocation of the common carbamoyl-P intermediate.
    Type: Article , PeerReviewed
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  • 2
    Publication Date: 2023-03-30
    Description: This paper presents seasonal variations of the wind characteristics and wind turbine characteristics in the regions around Elazig, namely Maden, Agin and Keban. Mean wind speed data in measured hourly time series format is statistically analyzed for the six year period 1998–2003. The probability density distributions are derived from the time series data and their distributional parameters are identified. Two probability density functions are fitted to the measured probability distributions on a seasonal basis. The wind energy characteristics of all the regions is studied based on the Weibull and Rayleigh distributions. Energy calculations and capacity factors for the wind turbine characteristics were determined for wind machines of different sizes between 300 and 2300 kW. It was found that Maden is the best region, among the regions analyzed, for wind characteristics and wind turbine characteristics.
    Type: Article , PeerReviewed
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  • 3
    Publication Date: 2023-01-19
    Description: Measuring and modeling the surface charge of clays, and more especially smectites, has become an important issue in the use of bentonites as a waste confinement material aimed at retarding migration of water and solutes. Therefore, many studies of the acid–base properties of montmorillonite have appeared recently in the literature, following older studies principally devoted to cation exchange. It is striking that beyond the consensus about the complex nature of the surface charge of clays, there are many discrepancies, especially concerning the dissociable charge, that prevents intercomparison among the published data. However, a general trend is observed regarding the absence of common intersection point on raw titration curves at different ionic strengths. Analysis of the literature shows that these discrepancies originate from the experimental procedures for the preparation of the clays and for the quantification of their surface charge. The present work is an attempt to understand how these procedures can impact the final results. Three critical operations can be identified as having significant effects on the surface properties of the studied clays. The first one is the preparation of purified clay from the raw material: the use of acid or chelation treatments, and the repeated washings in deionized water result in partial dissolution of the clays. Then storage of the purified clay in dry or wet conditions strongly influences the equilibria in the subsequent experiments respectively by precipitation or enhanced dissolution. The third critical operation is the quantification of the surface charge by potentiometric titration, which requires the use of strong acids and bases. As a consequence, besides dissociation of surface sites, many secondary titrant consuming reactions were described in the literature, such as cation exchange, dissolution, hydrolysis, or precipitation. The cumulated effects make it difficult to derive proper dissociation constants, and to build adequate models. The inadequation of the classical surface complexation models to describe the acid–base behavior of clays is illustrated by the electrokinetic behavior of smectites, which is independent from the pH and the ionic strength. Therefore, there is still a need on one hand for accurate data recorded in controlled conditions, and on the other hand for new models taking into account the complex nature of the charge of clays.
    Type: Article , PeerReviewed
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  • 4
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    American Geophysical Union
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q11007, doi:10.1029/2005GC000975.
    Description: Binary mixing is one of the most common models used to explain variations in geochemical data. When the data being modeled are ratios of elements or isotopes, the mixtures follow hyperbolic trends with curvatures that depend on a cross-term representing the relative concentrations of the elements or isotopes under consideration in the mixing components. The inverse problem of estimating mixing components is difficult because of the cross-term in the hyperbolic equation, which requires the use of nonlinear methods to estimate the mixing parameters, and because the end-member ratio values are intrinsically underdetermined unless the mixing proportions of the samples are known a priori, which is not generally the case. I use maximum likelihood methods to address these issues and derive a general inversion for binary mixing model parameters from ratio-ratio data. I apply the method to synthetic test data and a global compilation of 230Th/232Th versus 87Sr/86Sr data from oceanic basalts and find that the concentration ratio parameter is well-constrained by the inversion while the end-member ratio estimates are strongly dependent on the initial guesses used to start the iterative solver, reflecting the underdetermined nature of the end-member positions on the mixing hyperbola. Monte Carlo methods that randomly perturb the initial guesses can be used to improve error estimates, and goodness-of-fit statistics can be used to assess the performance of the mixing model for explaining data variance.
    Keywords: Inverse theory ; Isotopes ; Mixing
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA4011, doi:10.1029/2005PA001150.
    Description: Monthly samples of stratified plankton tows taken from the slope waters off Cape Cod nearly 25 years ago are used to describe the seasonal succession of planktonic foraminifera and their oxygen isotope ratios. The 15°C seasonal cycle of sea surface temperature (SST) accounts for a diverse mixture of tropical to subpolar species. Summer samples include various Globigerinoides and Neogloboquadrina dutertrei, whereas winter and early spring species include Globigerina bulloides and Neogloboquadrina pachyderma (dextral). Globorotalia inflata lives all year but at varying water depths. Compared with the fauna in 1960–1961 (described by R. Cifelli), our samples seem warmer. Because sea surface salinity varies little during the year, δ18O is mostly a function of SST. Throughout the year, there are always species present with δ18O close to the calculated isotopic equilibrium of carbonate with surface seawater. This raises the possibility that seasonality can be estimated directly from the range of δ18O in a sediment sample provided that the δ18O-salinity relationship is the same as today.
    Description: Funding was provided by NSF grant OCE-0117149.
    Keywords: Plankton tow ; Foraminifera ; Stable isotopes
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 19 (2005): GB4006, doi:10.1029/2004GB002445.
    Description: We report iron measurements for water column and aerosol samples collected in the Sargasso Sea during July-August 2003 (summer 2003) and April-May 2004 (spring 2004). Our data reveal a large seasonal change in the dissolved iron (dFe) concentration of surface waters in the Bermuda Atlantic Time-series Study region, from ∼1–2 nM in summer 2003, when aerosol iron concentrations were high (mean 10 nmol m−3), to ∼0.1–0.2 nM in spring 2004, when aerosol iron concentrations were low (mean 0.64 nmol m−3). During summer 2003, we observed an increase of ∼0.6 nM in surface water dFe concentrations over 13 days, presumably due to eolian iron input; an estimate of total iron deposition over this same period suggests an effective solubility of 3–30% for aerosol iron. Our summer 2003 water column profiles show potentially growth-limiting dFe concentrations (0.02–0.19 nM) coinciding with a deep chlorophyll maximum at 100–150 m depth, where phytoplankton biomass is typically dominated by Prochlorococcus during late summer.
    Description: Funding for this work was provided by the U.S. National Science Foundation (OCE-0222053 to P. N. S., OCE-0222046 to T. M. C., and OCE-0241310 to D. J. M.), the U.S. National Aeronautics and Space Administration (NAG5-11265 to D. J. M.), the Australian Research Council (DP0342826 to A. R. B.), the Antarctic Climate and Ecosystems Cooperative Research Center, and the H. Unger Vetlesen Foundation.
    Keywords: Atmospheric deposition ; Iron ; Sargasso Sea
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 32 (2005): L19304, doi:10.1029/2005GL023457.
    Description: The effect of rheology on the evolution of the slab-tip during subduction initiation is analyzed using 2-D numerical flow models. Experimentally determined flow laws have both strong temperature- and stress-dependence, which leads to large local variations in viscosity with direct consequences for subduction initiation. We find that models with Newtonian viscosity lead to flat or coupled subduction due to hydrodynamic stresses that pull the slab-tip up towards the overriding plate. Non-Newtonian rheology reduces these hydrodynamic stresses by decreasing the wedge viscosity and the slab coupling to wedge-corner flow, rendering the small negative-slab buoyancy of the slab-tip sufficient to maintain its dip during the early stages of subduction.
    Keywords: Dynamics of lithosphere and mantle ; Plate boundary ; Rheology: mantle ; Subduction zone processes
    Repository Name: Woods Hole Open Access Server
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  • 8
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    American Geophysical Union
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 6 (2005): Q04009, doi:10.1029/2004GC000768.
    Description: The Hawaii-2 Observatory (H2O) is an excellent site for studying the source regions and propagation of microseisms since it is located far from shorelines and shallow water. During Leg 200 of the Ocean Drilling Program, the officers of the JOIDES Resolution took wind and wave measurements for comparison with double-frequency (DF) microseism data collected at nearby H2O. The DF microseism band can be divided into short period and long period bands, SPDF and LPDF, respectively. Comparison of the ship’s weather log with the seismic data in the SPDF band from about 0.20 to 0.45 Hz shows a strong correlation of seismic amplitude with wind speed and direction, implying that the energy reaching the ocean floor is generated locally by ocean gravity waves. Near-shore land seismic stations see similar SPDF spectra, also generated locally by wind seas. At H2O, SPDF microseism amplitudes lag sustained changes in wind speed and direction by several hours, with the lag increasing with wave period. This lag may be associated with the time necessary for the development of opposing seas for DF microseism generation. Correlation of swell height above H2O with the LPDF band from 0.085 to 0.20 Hz is often poor, implying that a significant portion of this energy originates at distant locations. Correlation of the H2O seismic data with NOAA buoy data, with hindcast wave height data from the North Pacific, and with seismic data from mainland and island stations, defines likely source areas of the LPDF signals. Most of the LPDF energy at H2O appears to be generated by high amplitude storm waves impacting long stretches of coastline nearly simultaneously, and the Hawaiian Islands appear to be a significant source of LPDF energy in the North Pacific when waves arrive from particular directions. The highest DF levels observed at mid-ocean site H2O occur in the SPDF band when two coincident nearby storm systems develop. Mid-ocean generated DF microseisms are not observed at interior continental sites, indicating high attenuation of these signals. At near-coastal seismic stations, both SPDF and LPDF microseism levels are generally dominated by local generation at nearby shorelines.
    Description: This work was supported by the U.S. Science Support Program (User Reference: 418920-BA372; Task Order F001602) associated with the Ocean Drilling Program and is sponsored by the National Science Foundation and the Joint Oceanographic Institutions, Inc. Additional support was provided by the California Energy Commission and the California Department of Boating and Waterways as part of their program to improve boating facilities, access, safety, and education. Support for Ralph Stephen was also provided by the National Science Foundation under Grant #OCE-0424633.
    Keywords: Microseisms ; Ocean gravity waves ; Seismic noise ; Rayleigh wave attenuation ; Oceanic Q ; Hawaii-2 Observatory
    Repository Name: Woods Hole Open Access Server
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  • 9
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA4005, doi:10.1029/2004PA001061.
    Description: Detailed deglacial and Holocene records of planktonic δ18O and Mg/Ca–based sea surface temperature (SST) from the Okinawa Trough suggest that at ∼18 to 17 thousand years before present (kyr B.P.), late spring/early summer SSTs were approximately 3°C cooler than today, while surface waters were up to 1 practical salinity unit saltier. These conditions are consistent with a weaker influence of the summer East Asian Monsoon (EAM) than today. The timing of suborbital SST oscillations suggests a close link with abrupt changes in the EAM and North Atlantic climate. A tropical influence, however, may have resulted in subtle decoupling between the North Atlantic and the Okinawa Trough/EAM during the deglaciation. Okinawa Trough surface water trends in the Holocene are consistent with model simulations of an inland shift of intense EAM precipitation during the middle Holocene. Millennial-scale alternations between relatively warm, salty conditions and relatively cold, fresh conditions suggest varying influence of the Kuroshio during the Holocene.
    Description: Funding for this research was provided by NSFC (grants 40106006 and 40206007), SKLLQG (grant LLQG0204), and the NSF (OCE-020776 to DWO). Y.S.'s visit to WHOI was supported via a NSF START Fellowship.
    Keywords: Okinawa Trough ; Deglaciation ; Holocene ; Kuroshio Current ; East Asian monsoon ; Mg/Ca ; Oxygen isotopes ; Foraminifera
    Repository Name: Woods Hole Open Access Server
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  • 10
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. Published in 2005 by the American Geophysical Union. The definitive version was published in Journal of Geophysical Research 110 (2005): B06404, doi:10.1029/2004JB003459.
    Description: The Puerto Rico trench exhibits great water depth, an extremely low gravity anomaly, and a tilted carbonate platform between (reconstructed) elevations of +1300 m and −4000 m. I argue that these features are manifestations of large vertical movements of a segment of the Puerto Rico trench, its forearc, and the island of Puerto Rico that took place 3.3 m.y. ago over a time period as short as 14–40 kyr. I explain these vertical movements by a sudden increase in the slab's descent angle that caused the trench to subside and the island to rise. The increased dip could have been caused by shearing or even by a complete tear of the descending North American slab, although the exact nature of this deformation is unknown. The rapid (14–40 kyr) and uniform tilt along a 250 km long section of the trench is compatible with scales of mantle flow and plate bending. The proposed shear zone or tear is inferred from seismic, morphological, and gravity observations to start at the trench at 64.5°W and trend southwestwardly toward eastern Puerto Rico. The tensile stresses necessary to deform or tear the slab could have been generated by increased curvature of the trench following a counterclockwise rotation of the upper plate and by the subduction of a large seamount.
    Keywords: Dynamic topography ; Slab tear ; Puerto Rico trench ; Caribbean plate ; Challenger Deep ; Seamount subduction
    Repository Name: Woods Hole Open Access Server
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