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  • 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry  (6)
  • 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques  (5)
  • Elsevier  (11)
  • Essen : Verl. Glückauf
  • 2015-2019
  • 2005-2009  (11)
  • 2005  (11)
Sammlung
Verlag/Herausgeber
Erscheinungszeitraum
  • 2015-2019
  • 2005-2009  (11)
Jahr
  • 1
    Publikationsdatum: 2020-10-29
    Beschreibung: We have performed a parametric study on the dynamics of trachytic (alkaline) versus rhyolitic (calc-alkaline) eruptions by employing a steady, isothermal, multiphase non-equilibrium model of conduit flow and fragmentation. The employed compositions correspond to a typical rhyolite and to trachytic liquids from Phlegrean Fields eruptions, for which detailed viscosity measurements have been performed. The investigated conditions include conduit diameters in the range 30–90 m and total water contents from 2 to 6 wt%, corresponding to mass flow rates in the range 106–108 kg/s. The numerical results show that rhyolites fragment deep in the conduit and at a gas volume fraction ranging from 0.64 to 0.76, while for trachytes fragmentation is found to occur at much shallower levels and higher vesicularities (0.81–0.85). An unexpected result is that low-viscosity trachytes can be associated with lower mass flow rates with respect to more viscous rhyolites. This is due to the non-linear combined effects of viscosity and water solubility affecting the whole eruption dynamics. The lower viscosity of trachytes, together with higher water solubility, results in delayed fragmentation, or in a longer bubbly flow region within the conduit where viscous forces are dominant. Therefore, the total dissipation due to viscous forces can be higher for the less viscous trachytic magma, depending on the specific conditions and trachytic composition employed. The fragmentation conditions determined through the simulations agree with measured vesicularities in natural pumice clasts of both magma compositions. In fact, vesicularities average 0.80 in pumice from alkaline eruptions at Phlegrean Fields, while they tend to be lower in most calc-alkaline pumices. The results of numerical simulations suggest that higher vesicularities in alkaline products are related to delayed fragmentation of magmas with this composition. Despite large differences in the distribution of flow variables which occur in the deep conduit region and at fragmentation, the flow dynamics of rhyolites and trachytes in the upper conduit and at the vent can be very similar, at equal conduit size and total water content. This is consistent with similar phenomenologies of eruptions associated with the two magma types.
    Beschreibung: Published
    Beschreibung: 93-108
    Beschreibung: partially_open
    Schlagwort(e): trachytic magma ; conduit flow ; eruption dynamics and numerical simulations ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 2
    Publikationsdatum: 2017-04-04
    Beschreibung: In order to improve the microscopic understanding of the water-magma interaction process during explosive volcanism,volcanic glasses representative of deposits with sedimentological characteristics suggesting different water/melt ratios were studied by a combination of the nuclear magnetic resonance (NMR) and TIMS methods. The glasses were separated from pumices of two surge layers and one fallout bed of the Cretaio Tephra (Ischia Island,Italy), which is the product of an explosive eruption that occurred at Ischia in the second century BC. The 29Si CP^MAS NMR experiments indicate the occurrence of 1H^29Si dipolar couplings in glasses from the phreatomagmatic activity, suggesting the presence of hydrogen atoms in proximity of silicon atoms. This feature is not detected in the glass from the deposit of the magmatic explosion. 1H MAS NMR spectra reveal different peaks attributed to different hydrous species characterized by different motional properties. These include ‘rigid’ H2O groups isolated in the glass structure, more mobile water species and possibly structural hydroxyl groups. 1H MAS NMR spectra recorded after deuteration experiments of the glass at a temperature up to 300‡C revealed that the exchange reactions of the D2O vapor with hydrogen were limited to the most mobile water species,possibly on vesicle surfaces or in channels. The hydrogen concentration linearly correlates with the 87Sr/86Sr isotope ratio in glasses,suggesting isotopic tracer exchanges between the Sr dissolved in the water vapor and the Sr in the silicon-oxygen network during hydration. It is proposed that the uprising melt interacted with a hydrothermal system of seawater-derived fluids,characterized by relatively high Sr isotopic composition.
    Beschreibung: Published
    Beschreibung: 311-320
    Beschreibung: partially_open
    Schlagwort(e): Ischia ; Cretaio Tephra ; Water-melt interaction ; Nuclear magnetic resonance ; Sr isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 3
    Publikationsdatum: 2017-04-04
    Beschreibung: On July 18, 2001, two main eruptive vents opened on the southern flank of Mount Etna volcano (Italy) at ~2100 m and ~2550 m a.s.l., respectively. The former vent fed mild strombolian activity and lava flows, while the latter represented the main explosive vent, producing strong phreato-magmatic explosions. Explosions at this latter vent, however, shifted to a strombolian style in the following days, before switching back to phreato-magmatic activity towards the end of the eruption, which ended on August 9, 2001. On August 3, a small seismoacoustic array was deployed close to the eruptive vents. The array was composed of three stations, which recorded seismic and infrasonic waves coming from both of the eruptive vents. A further seismoacoustic station, equipped with a thermal-infrared sensor, was also installed several kilometers north of the first array. Seismic signals relating to the strombolian activity at the 2100-m vent were characterized by a strong decompression at the source. Analysis of the time delays between seismic, infrasonic and infrared event onsets also revealed that ejection velocities during explosions from both vents were subsonic. Time delays between the onset of explosive events apparent in the infrared and infrasound data indicated that the explosion source at the 2550-m vent was located 220–250 m below the crater rim. In comparison, the depth of the seismic source was estimated to be between 230 and 335 m below the rim. This converts to 120–150 and 130–235 m below the preexisting ground surface. In addition, time delays between seismic and infrasonic signals recorded for the lower (2100 m) vent also revealed a seismic source that was no more than a few tens of meters deeper than the fragmentation surface.
    Beschreibung: Published
    Beschreibung: 219-230
    Beschreibung: partially_open
    Schlagwort(e): Mt. Etna ; explosive eruptions ; arrays ; seismic ; infrasonic and thermal data ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 4
    Publikationsdatum: 2017-04-04
    Beschreibung: The northwestern flank of the Colli Albani, a Quaternary volcanic complex near Rome, is characterised by high CO2 values and Rn activities in the groundwater and by the presence of zones with strong emission of gas from the soil. The most significant of these zones is Cava dei Selci where many houses are located very near to the gas emission site. The emitted gas consists mainly of CO2 (up to 98 vol) with an appreciable content of H2S (0.8). The He and C isotopic composition indicates, as for all fluids associated with the Quaternary Roman and Tuscany volcanic provinces, the presence of an upper mantle component contaminated by crustal fluids associated with subducted sediments and carbonates. An advective CO2 flux of 37 tons/day has been estimated from the gas bubbles rising to the surface in a small drainage ditch and through a stagnant water pool, present in the rainy season in a topographically low central part of the area. A CO2 soil flux survey with an accumulation chamber, carried out in February-March 2000 over a 12 000 m2 surface with 242 measurement points, gave a total (mostly conductive) flux of 61 tons/day. CO2 soil flux values vary by four orders of magnitude over a 160-m distance and by one order of magnitude over several metres. A fixed network of 114 points over 6350 m2 has been installed in order to investigate temporal flux variations. Six surveys carried out from May 2000 to June 2001 have shown large variations of the total CO2 soil flux (8/25 tons/day). The strong emission of CO2 and H2S, which are gases denser than air, produces dangerous accumulations in low areas which have caused a series of lethal accidents to animals and one to a man. The gas hazard near the houses has been assessed by continuously monitoring the CO2 and H2S concentration in the air at 75 cm from the ground by means of two automatic stations. Certain environmental parameters (wind direction and speed; atm P, T, humidity and rainfall) were also continuously recorded. At both stations, H2S and CO2 exceeded by several times the recommended concentration thresholds. The highest CO2 and H2S values were recorded always with wind speeds less than 1.5 m/s, mostly in the night hours. Our results indicate that there is a severe gas hazard for people living near the gas emission site of Cava dei Selci, and appropriate precautionary and prevention measures have been recommended both to residents and local authorities.
    Beschreibung: - GNV funded research project Gas Hazard of Colli Albani
    Beschreibung: Published
    Beschreibung: 81^94
    Beschreibung: partially_open
    Schlagwort(e): Colli Albani ; CO2 flux ; H2S ; gas hazard ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 5
    Publikationsdatum: 2017-04-04
    Beschreibung: We have undertaken detailed observations of the formation of the `Laghetto´ cinder cone, a new cone that formed during a 2-week period of intense activity in Piano del Lago, on the upper slopes of Mount Etna in summer 2001. We describe the events leading to the formation of a small graben, the formation of pit craters on the base of the graben, the onset of phreatomagmatic activity, a transition to intense Strombolian activity, and a return to phreatomagmatic activity as the eruption came to an end. We discuss the reasons for these transitions, and describe the morphological development of the cone during these events. Arcuate cracks on the southern part of the cone were related to withdrawal of magma at the end of the eruption. Other slope instabilities that developed during the eruption include the formation of small radial grain flows on the outer flanks of the cone and the collapse into the crater of part of the crater rim. Some of the failure planes we observed were first identified using a FLIR TM 695 thermal infrared camera. This is the first time that infrared thermography has been used to detect instability of volcanic structures. Results obtained during this test case demonstrate that thermal cameras are a very useful tool for studies of volcanic instability.
    Beschreibung: Published
    Beschreibung: 225-239
    Beschreibung: partially_open
    Schlagwort(e): Etna volcano ; cinder cone ; volcano instability ; thermal images ; phreatomagmatic activity ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 6
    Publikationsdatum: 2017-04-04
    Beschreibung: Chlorine- and sulphur-bearing compounds in fumarole discharges of the La Fossa crater at Vulcano Island (Italy) can be modelled by a mixing process between magmatic gases and vapour from a boiling hydrothermal system. This allows estimating the compounds in both endmembers. Magma degassing cannot explain the time variation of sulphur and HCl concentrations in the deep endmember, which are more probably linked to reactions of solid phases at depth, before mixing with the hydrothermal vapours. Based on the P^T conditions and speciation of the boiling hydrothermal system below La Fossa, the HCl and Stot contents in the hydrothermal vapours were used to compute the redox conditions and pH of the aqueous solution. The results suggest that the haematite magnetite buffer controls the hydrothermal fO2 values, while the pH has increased since the end of the 1970s. The main processes affecting pH values may be linked to Na^Ca exchanges between evolved seawater, feeding the boiling hydrothermal system, and local rocks. While Na is removed from water, calcium enters the solution, undergoes hydrolysis and produces HCl,lowering the pH of the water. The increasing water^rock ratio within the hydrothermal system lowers the Ca availability, so the aqueous solution becomes less acidic. Seawater flowing towards the boiling hydrothermal brine dissolves a large quantity of pyrite along its path. In the boiling hydrothermal system, dissolved sulphur precipitates as pyrite and anhydrite, and becomes partitioned in vapour phase as H2S and SO2. These results are in agreement with the paragenesis of hydrothermal alteration minerals recovered in drilled wells at Vulcano and are also in agreement with the isotopic composition of sulphur emitted by the crater fumaroles.
    Beschreibung: Published
    Beschreibung: 137-150
    Beschreibung: partially_open
    Schlagwort(e): chlorine ; sulphur ; hydrothermal system ; genetic processes ; Vulcano Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 7
    Publikationsdatum: 2017-04-04
    Beschreibung: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Beschreibung: Published
    Beschreibung: 1^18
    Beschreibung: partially_open
    Schlagwort(e): Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 8
    Publikationsdatum: 2017-04-04
    Beschreibung: One of the seven potentially active andesite stratovolcanoes in southern Peru, Misti (5822 m), located 17 km northeast and 3.5 km above Arequipa, represents a major threat to the population (f900,000 inhabitants). Our recent geophysical and geochemical research comprises an extensive self-potential (SP) data set, an audioâ magnetotelluric (AMT) profile across the volcano and CO2 concentrations in the soil along a radial profile. The SP survey is the first of its kind in providing a complete mapping of a large andesitic stratovolcano 20 km in diameter. The SP mapping enables us to analyze the SP signature associated with a subduction-related active volcano. The general SP pattern of Misti is similar to that of most volcanoes with a hydrogeologic zone in the lower flanks and a hydrothermal zone in the upper central area. A quasi-systematic relationship exists between SP and elevation. Zones with constant SP/altitude gradients (Ce) are observed in both hydrogeologic (negative Ce) and hydrothermal (positive Ce) zones. Transition zones between the different Ce zones, which form a concentric pattern around the summit, have been interpreted in terms of lateral heterogeneities in the lithology. The highest amplitudes of SP anomalies seem to coincide with highly resistive zones. The hydrothermal system 6 km in diameter, which extends over an area much larger than the summit caldera, may be constrained by an older, concealed collapse caldera. A sealed zone has apparently developed through alteration in the hydrothermal system, blocking the migration of CO2 upward. Significant CO2 emanations are thus observed on the lower flanks but are absent above the hydrothermal zone.
    Beschreibung: - Institut de Recherche pour le Developpement (IRD) - Instituto Geofısico del Peru´ (IGP)
    Beschreibung: Published
    Beschreibung: 343-360
    Beschreibung: partially_open
    Schlagwort(e): Misti volcano ; self-potential ; audioâ magnetotelluric ; electrical resistivity ; structural discontinuity ; hydrothermal system ; Peru ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 9
    Publikationsdatum: 2017-04-04
    Beschreibung: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Beschreibung: Published
    Beschreibung: 91– 108
    Beschreibung: partially_open
    Schlagwort(e): Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 10
    Publikationsdatum: 2017-04-04
    Beschreibung: We have developed a quantitative model of CO2 and H2O isotopic mixing between magmatic and hydrothermal gases for the fumarolic emissions of the La Fossa crater (Vulcano Island, Italy). On the basis of isotope balance equations, the model takes into account the isotope equilibrium between H2O and CO2 and extends the recent model of chemical and energy two-end-member mixing by Nuccio et al. (1999). As a result,the H2O and CO2 content and the dD, d18O, and d13C isotope compositions for both magmatic and hydrothermal end-members have been assessed. Low contributions of meteoric steam, added at a shallow depth, have been also recognized and quantified in the fumaroles throughout the period from 1988 to 1998. Nonequilibrium oxygen isotope exchange also seems to be occurring between ascending gases and wall rocks along some fumarolic conduits. The d13CCO2 of the magmatic gases varies around -3 to 1‰ vs. Peedee belemnite (PDB), following a perfect synchronism with the variations of the CO2 concentration in the magmatic gases. This suggests a process of isotope fractionation because of vapor exsolution caused by magma depressurization. The hydrogen isotopes in the magmatic gases (-1 to -35‰ vs. standard mean ocean water [SMOW]), as well as the above d13CCO2 value, are coherent with a convergent tectonic setting of magma generation, where the local mantle is widely contaminated by fluids released from the subducted slab. Magma contamination in the crust probably amplifies this effect. The computed isotope composition of carbon and hydrogen in the hydrothermal vapors has been used to calculate the dD and d13C of the entire hydrothermal system, including mixed H2O-CO2 vapor, liquid water, and dissolved carbon. We have computed values of about 10‰ vs. SMOW for water and -2 to -6.5‰ vs. PDB for CO2. On these grounds, we think that Mediterranean marine water (dDH2O 10‰) feeds the hydrothermal system. It infiltrates at depth throughout the local rocks, reaching oxygen isotope equilibrium at high temperatures. Interaction processes between magmatic gases and the evolving seawater also seem to occur, causing the dissolution of isotopically fractionated aqueous CO2 and providing the source for hydrothermal carbon. These results have important implications concerning fluid circulation beneath Vulcano and address the more convenient routine of geochemical surveillance.
    Beschreibung: Published
    Beschreibung: 759–772
    Beschreibung: partially_open
    Schlagwort(e): isotope geochemistry ; volcanic gases ; mixing modeling ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 11
    Publikationsdatum: 2017-04-04
    Beschreibung: The results of the 7 years (1994-2000) of monthly monitoring of spring water before and during eruptions show response to volcanic activity. Low salinity and temperature characterize most of the springs, which are located on the flanks of Popocatepetl Volcano. The pH ranges from 5.8 to 7.8 and temperature from 3 to 36 jC. Oxygen and hydrogen isotopic data show that the water is of meteoric origin, but SO4 2 , Cl , F , HCO3 , B, and SO4 2- /Cl- variations precede main eruptive activity, which is considered linked to influx of magmatic gases and acid fluids that react with sublimates and host rock and mix with the large water system. Na +, Ca2 + , SiO2 and Mg2 + concentrations in the water also increased before eruptive activity. The computed partial pressure of CO2 in equilibrium with spring waters shows values higher than air-saturated water (ASW), with the highest values up to 0.73 bar of pCO2. Boron is detected in the water only preceding the larger eruptions. When present, boron concentration is normally under health standard limits, but in two cases the concentration was slightly above. Other components are within health standard limits, except for F- in one spring.
    Beschreibung: Published
    Beschreibung: 207– 229
    Beschreibung: partially_open
    Schlagwort(e): Volcano monitoring ; Spring water chemistry ; Popocatepetl ; Mexico ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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