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  • Articles  (223)
  • Blackwell Publishing Ltd  (223)
  • American Meteorological Society
  • International Union of Crystallography
  • Springer Nature
  • Springer Science + Business Media
  • 2000-2004  (223)
  • 1960-1964
  • 2001  (223)
  • Energy, Environment Protection, Nuclear Power Engineering  (223)
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  • Articles  (223)
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  • 2000-2004  (223)
  • 1960-1964
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  • 1
    Electronic Resource
    Electronic Resource
    AUTHORS' REPLY (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02468.x
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  • 2
    Electronic Resource
    Electronic Resource
    Fate of the Herbicides 2,4,5-T, Atrazine, and DNOC in a Shallow, Anaerobic Aquifer Investigated by In Situ Passive Diffusive Emitters and Laboratory Batch Experiments (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: The fate of the three herbicides 2,4,5-T (2,4,5-trichlorophenoxyacetic acid), atrazine (6-chloro-N-ethyl-N′-[l-methyl-ethyl]-l,3,5-triazine-2,4-diamine), and DNOC (4,6-dinitro-2-methylphenol) in an anaerobic sandy aquifer was investigated. In the field, each of the herbicides was released simultaneously with tritiated water (HTO) as tracer in the depth interval 3 to 4 mbs (meters below surface) by use of passive diffusive emitters. Atrazine and 2,4,5-T were persistent during the approximately 18 days residence time in the aquifer. In contrast, DNOC was rapidly removed from the water phase following first-order kinetics. The removal mechanism was likely an abiotic reduction. At day 25, the first-order rate constant was 1.47 d−1, but it decreased with time and seemed to stabilize at 0.35 d−1 after 150 to 200 days.In the laboratory, batch experiments were conducted with sediments from 3 to 4 mbs and from 8 to 9 mbs. In these incubations, formation of Fe2+ and depletion of sulfate showed iron and sulfate reduction in sediment from 3 to 3.5 mbs and sulfate reduction in 3.5 to 4 mbs sediment. In sediment from 8 to 9 mbs, the dominant redox process was methane formation. In sediment from 3 to 3.5 mbs, only 27% to 52% of the 2,4,5-T remained after 196 days. 2,4,5-trichlorophenol was identified as the major metabolite. A lag period of at least 50 days was observed, and no degradation occurred in HgCl2 amended controls, verifying that the process was microbially mediated. In the other 2,4,5-T incubations and all the atrazine incubations, concentrations decreased linearly, but less than 25 % was removed within 200 to 250 days. No degradation products could be detected, and slow sorption was the likely explanation. In all the laboratory incubations DNOC was degraded, following first-order kinetics, and when normalized to the sediment/water-ratio, the field and laboratory derived rate constants compared well. The DNOC degradation in the methanogenic incubations (8 to 9 mbs) was up to 50 times faster than in the sediments from 3 to 4 mbs, likely due to the low redox potential.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02470.x
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  • 3
    Electronic Resource
    Electronic Resource
    Improved Calculations for Dewatered Cells in MODFLOW (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Use of the United States Geological Survey ground water flow model MODFLOW is often hampered by the occurrence of “dry cells.” While MODFLOW allows such cells to “rewet” in the course of a simulation, stability of the heads solution process is often problematical with rewetting functionality operative. In many cases of practical interest (particularly in mining applications), MOD-FLOW simply fails to converge. However by making a number of adjustments to the MODFLOW Block-Centered Flow package, it is possible to overcome this problem in many instances of MODFLOW deployment. These adjustments are such as to allow a layer to transmit water, albeit with a vastly reduced transmissivity, even if the water level in that layer is below its base. With these alterations MODFLOW cells can remain active even if they lie within the unsaturated zone.Testing of the code has demonstrated its ability to perform well in situations where performance of the unmodified MODFLOW is degraded by the necessity to dry and rewet cells. Comparison of heads calculated using the modified MODFLOW with those calculated using MODFLOW-SURFACT (a MODFLOW-based code developed by HydroGeoLogic Inc. that prevents the occurrence of dry cells through use of pseudo soil functions) reveals near-identical results between the two codes. Comparison with analytical solutions of water table location also reveals near coincidence. An example of one such application is presented herein.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02474.x
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  • 4
    Electronic Resource
    Electronic Resource
    Determination of Specific Yield for the Biscayne Aquifer with a Canal-Drawdown Test (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Data from a large-scale canal-drawdown test were used to estimate the specific yield (s) of the Biscayne Aquifer, an uncon-fined limestone aquifer in southeast Florida. The drawdown test involved dropping the water level in a canal by about 30 cm and monitoring the response of hydraulic head in the surrounding aquifer. Specific yield was determined by analyzing data from the unsteady portion of the drawdown test using an analytical stream-aquifer interaction model (Zlotnik and Huang 1999). Specific yield values computed from drawdown at individual piezometers ranged from 0.050 to 0.57, most likely indicating heterogeneity of specific yield within the aquifer (small-scale variation in hydraulic conductivity may also have contributed to the differences in sy among piezometers). A value of 0.15 (our best estimate) was computed based on all drawdown data from all piezometers.We incorporated our best estimate of specific yield into a large-scale two-dimensional numerical MODFLOW-based ground water flow model and made predictions of head during a 183–day period at four wells located 337 to 2546 m from the canal. We found good agreement between observed and predicted heads, indicating our estimate of specific yield is representative of the large portion of the Biscayne Aquifer studied here. This work represents a practical and novel approach to the determination of a key hydrogeological parameter (the storage parameter needed for simulation and calculation of transient unconfined ground water flow), at a large spatial scale (a common scale for water resource modeling), for a highly transmissive limestone aquifer (in which execution of a traditional pump test would be impractical and would likely yield ambiguous results). Accurate estimates of specific yield and other hydrogeological parameters are critical for management of water supply, Everglades environmental restoration, flood control, and other issues related to the ground water hydrology of the Biscayne Aquifer.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02368.x
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  • 5
    Electronic Resource
    Electronic Resource
    Hydrogeological Research: Beginning of the End or End of the Beginning? (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: This paper uses citation data to assess whether articles published in key ground water journals such as Ground Water (GW) and Water Resources Research (WRR) are impacting research. Citation information was obtained from SCI Journal Citation Reports and The Web of Science—databases maintained by the Institute for Scientific Information (ISI). Information extracted from The Web of Science was processed further to remove corrections to papers, discussion/replies, and book reviews. Generally, there are many ground water papers published, but citations of these papers are limited. Approximately 10% to 15% of WRR articles, and 2% to 3% of GW articles attract more than 50 citations in their lifetimes. In both GW and WRR, the top 10% of papers eventually will contribute nearly half of the total yearly citations. Another emerging trend is a diminishing emphasis on citations to new work as compared to work more than 10 years in age. When articles in Ground Water or Journal of Hydrology cite papers in Water Resources Research, those papers cite work 10 or more years old half of the time. If one believes that citations are a measure of science impact, then there is cause for concern. Research is inefficient with much produced for little gain. On a typical industrial life-cycle curve, ground water research is likely ranked as mature and close to aging. At this stage, much work will have been completed and the number of truly impactful problems will have dwindled to just a few.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02337.x
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  • 6
    Electronic Resource
    Electronic Resource
    Ground Water/Surface Water Interactions in Lake Naivasha, Kenya, Using δ18O, δD, and 3H/3He Age-Dating (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: We have analyzed a series of ground water samples from the Lake Naivasha region, Kenya, for their helium isotopic composition. Lake Naivasha is unique among the East Africa Rift Valley lakes in that it is fresh. It has long been thought that the low salinity of this lake is due, in part, to rapid water loss from the lake into the local ground water system. Our results show that the Olkaria geothermal waters, south of the lake, are devoid of tritium and, thus, are more than 50 years old. An important implication of these results is that even if Olkaria geothermal reservoir water originated from Lake Naivasha, it has been underground for a long time, (〉50 years) and is not derived from present-day Lake Naivasha water. This flow time is of the same order of magnitude as conservative major solutes, such as chloride, as determined through residence time calculations. On the north side of Lake Naivasha, deep wells (91 m) have water ∼ 20 years old. Water from these wells has stable isotopic values resembling those of nearby rivers, and high-elevation eastern Rift water. This indicates that this water recharges from rains from high eastern Rift Valley escarpments. Many of the shallow wells on the south side of the lake have 3H/3He ages between four and 17 years. The young ages and the δ18 O-enriched signature of the water from these wells indicate that they are recharged by a mixture of water from the lake, Rift flanks, and water from deep pumping wells that is recharged during irrigation. Water mixing ratio calculations using δ18O and δD isotopes show that about 50% to 70% of the southern ground water system is derived from the lake, while the Olkaria geothermal reservoir water shows that 40% to 50% of this water is originally lake water. Calculated mean recharge rates range from 0.10 to 1.59 m/yr with a mean of 0.52±0.40 m/yr. Estimated horizontal velocity from 3H/3He age dating between Lake Naivasha and a well about 3 km to the south is 75 m/yr, giving average horizontal hydraulic conductivity of 6 m/day.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02341.x
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  • 7
    Electronic Resource
    Electronic Resource
    Exploitation of High-Yields in Hard-Rock Aquifers: Downscaling Methodology Combining GIS and Multicriteria Analysis to Delineate Field Prospecting Zones (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: Based on research work in the Truyàre River catchment of the Massif Central (Lozàre Department, France), a methodology has been developed for delineating favorable prospecting zones of a few square kilometers within basement areas of several hundred, if not thousand, square kilometers for the purpose of siting high-yield water wells. The methodology adopts a functional approach to hard-rock aquifers using a conceptual model of the aquifer structure and of the functioning of the main aquifer compartments: the alterites (weathered and decayed rock), the underlying weathered-fissured zone, and the fractured bedrock. It involves an economically feasible method of mapping the thickness and spatial distribution of the alterites and the weathered-fissured zone, on which the long-term exploitation of the water resource chiefly depends. This method is used for the first time in hydrogeology.The potential ground water resources were mapped by GIS multicriteria analysis using parameters characterizing the structure and functioning of the aquifer, i.e., lithology and hydrogeological properties of the substratum, nature and thickness of the alterites and weathered-fissured zone, depth of the water table, slope, fracture networks and present-day tectonic stresses, and forecasted ground water quality.The methodology involves a coherent process of downscaling that, through applying methods that are increasingly precise but also increasingly costly, enables the selection of sites with diminishing surface areas as the work advances. The resulting documents are used for ground water exploration, although they can also be applied to the broader domain of land-use management.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02345.x
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  • 8
    Electronic Resource
    Electronic Resource
    Evaluation of Recharge in a Small Temperate Catchment Using Natural and Applied δ18O Profiles in the Unsaturated Zone (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: A water balance study was used for determining recharge rate and mechanisms in the Enler Catchment, Northern Ireland. Here spatially limited data for the water balance resulted in varied calculation of the annual and monthly net infiltration rate. This paper outlines a method whereby high-resolution soil profiles (1 to 2 cm) were obtained from field cores in the upper 2 m of the unsaturated zone using δ18O of water. These profiles show changes in isotopic composition that range from individual rainfall events to annually integrated cycles of rainfall. Recharge rates were calculated from stable isotope profiles for each of the four main soil types in the study catchment and summed over each area resulting in an average recharge in the range 55 to 70 mm/a, which is comparable with previous findings. Applied isotopic tracer tests were also conducted to evaluate the extent of preferential flow through the two main soil types in the catchment. Rates of water movement found from these experiments show good agreement with natural isotopic profiles; however, evidence suggests that preferential flow is not the dominant process controlling water movement in this catchment. This type of data provides valuable information about recharge rates and mechanisms and may facilitate better prediction of contaminant transport pathways in the vadose zone.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02349.x
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  • 9
    Electronic Resource
    Electronic Resource
    In Situ Determination of Subsurface Microbial Enzyme Kinetics (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: The single-well, push-pull test has been used in previous field studies to measure in situ zero- and first-order rates for aerobic and anaerobic microbial respiration in the saturated zone. In this paper we demonstrate that the test can also be used to obtain more generalized descriptions of the kinetics of microbially mediated enzymatic reactions. Laboratory and field tests were performed with the model enzyme substrate p-nitrophenyl-β-D-glucopyranoside (PNG). During a push-pull test, injected PNG is hydrolyzed in situ to p-nitrophenol (PNP); the rate of PNP production is taken as a measure of the β-glucosidase activity expressed by indigenous microorganisms. Laboratory tests were performed in physical aquifer models packed with natural aquifer sediment; field tests were performed in a shallow unconfined alluvial aquifer at a petroleum contaminated site. The laboratory and field tests demonstrate that it is possible to compute the in situ rate of PNP production as a function of PNG concentration using only data from a single push-pull test. These data can then be used to estimate the Michaelis-Menton kinetic parameters Vmax and Km for the hydrolysis reaction. This approach potentially extends the range of applicability of the push-pull test approach for use in determining kinetic parameters for a wide range of microbial processes in situ. These could include the broad class of substituted nitrophenyl substrates used to assay other enzyme systems, as well as microbially mediated redox reactions that occur during contaminant transformations.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02317.x
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  • 10
    Electronic Resource
    Electronic Resource
    Analytical Procedure for Simultaneous Use of Seven Fluorobenzoates in Multitracer Tests (2001)
    Oxford, UK : Blackwell Publishing Ltd
    Ground water 39 (2001), S. 0 
    Details
    ISSN: 1745-6584
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Notes: An analytical procedure allowing simultaneous use of seven fluorobenzoate (FBA) isomers was developed and examined through column and field tracer experiments. The analytical method, based on high performance liquid chromatography (HPLC), included a reverse-phase separation method. This method was found to be very efficient for the FBA analysis, allowing accurate determination of seven FBAs in a single HPLC run, while avoiding analytical interference of other natural water constituents or pollutants. Consequently, this separation method allows the simultaneous use of seven isomers in multitracer tests in highly saline or contaminated environments. The mobility properties of the FBAs were examined in percolation experiments through a column filled with a mixture of crushed chalk and common fracture filling and coating material. The FBAs behaved conservatively as compared to bromid. All seven FBA isomers were successfully used in a multitracer test in a field percolation experiment designed to identify flowpath along a fracture plane.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1745-6584.2001.tb02320.x
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